CN101747942A - Oxygen-enriched melting gasification method for lake sediment and device therefor - Google Patents

Oxygen-enriched melting gasification method for lake sediment and device therefor Download PDF

Info

Publication number
CN101747942A
CN101747942A CN200910163265A CN200910163265A CN101747942A CN 101747942 A CN101747942 A CN 101747942A CN 200910163265 A CN200910163265 A CN 200910163265A CN 200910163265 A CN200910163265 A CN 200910163265A CN 101747942 A CN101747942 A CN 101747942A
Authority
CN
China
Prior art keywords
mud
oxygen
pond
vapourizing furnace
coal slurry
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN200910163265A
Other languages
Chinese (zh)
Inventor
宁平
殷在飞
田森林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kunming University of Science and Technology
Original Assignee
Kunming University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kunming University of Science and Technology filed Critical Kunming University of Science and Technology
Priority to CN200910163265A priority Critical patent/CN101747942A/en
Publication of CN101747942A publication Critical patent/CN101747942A/en
Pending legal-status Critical Current

Links

Images

Landscapes

  • Treatment Of Sludge (AREA)

Abstract

The invention relates to an oxygen-enriched melting gasification method for lake sediment and a device therefor, which belong to the field of a solid waste treatment device and are a device and a method used for treating the lake sediment through oxygen-enriched melting gasification, producing mixed combustible gases and having slag with wide use. The hydrous lake sediment and pulverized coal are prepared to mud coal according to certain proportion, the components containing carbon and hydrogen in the coal and the sediment are mixed to the combustible gases by using oxygen-enriched gasifying agent, inorganic non-volatile components in the sediment and the coal are together melted to slag which can be used for cement additive and paving material, the reduction and harmless treatment for the sediment can be carried out under the condition of no secondary pollution, products such as combustible gases with higher economic value can be produced, and the resource utilization of the sediment is realized.

Description

Pond, lake bed mud oxygen-enriched air smelting gasification process and device
Technical field:
The present invention relates to pond, a kind of lake bed mud oxygen-enriched air smelting gasification process and device, belong to solid waste disposal and dispose the field.
Background technology:
Natural or man-made lake pond is important multi-functional surface water resources, has functions such as irrigation, flood control, shipping, breed, to regulating the climate, keep the eubiosis important ecological functions is arranged.Bed mud is as the important component part of lake ecological environment, the pollutent of bed mud in can adsorbed water body reduces the water pollution degree, in case condition changes, N, the P that bed mud discharges is one of important nutrition source of supporting nutrition enriched shallow amber blue-green alga bloom, influences the water quality of water body; Along with the continuous development of industrial economy, the pollution of bottom mud in lake has seriously hindered the normal performance of lake function, and is therefore, significant to recovering lake ecological environment to the improvement of bottom mud in lake.
The bed mud dredging is an important means of improving pond, lake water body environment, is to implement maximum mature technologies in the bed mud control.Pond, lake dredging engineering produces a large amount of bed muds.The processing of Hu Chi dredging bed mud and utilization are the hot subjects in the current environmental protection field.Owing to contain a large amount of moisture, heavy metal, pathogenic micro-organism and parasitic ovum etc. in the bed mud,, can cause secondary pollution as mishandling.How to realize sludge stabilization, minimizing, innoxious and resource utilization, become the focus that people pay close attention to.
Pond, lake bed mud has the characteristics of biological energy raw material, contain organic matters such as a large amount of soluble saccharides, Mierocrystalline cellulose, xylogen, fat, protein, fixed carbon wherein, protium content are higher, and under the condition of empty butt, its net calorific value is about 8000kJ/kg, so have higher energy development and utility value.As certain lake dredging bed mud through ultimate analysis (empty butt): moisture 12.68%; C 20.83%; H 2: 1.86%; O 2: 12.63%; N 2: 0.84%; S:0.67%; Ash content: 50.49%.
Countries in the world extensively adopt sanitary landfill, composting process, burning, soil utilization etc. to be main processing mode in the processing of mud.Sanitary landfill faces the in short supply and masses of the land resources equipressure of resisting, difficult Buddhist monk's open question that composting also has many reality as: composting process is handled mud needs very big place, soil will be spaced, to prevent by deleterious contaminants, and the lot of energy that contains of mud itself, in this treatment process, can be wasted.Burning method can reduce the volume of mud significantly, and can utilize energy wherein to improve utilization efficiency of heat energy, owing to contain a large amount of objectionable impuritiess in the mud, be under aerobic environment, to carry out combustion reactions and burn, the gas of generation causes secondary pollution to environment.The soil utilization is based on the farmland utilization method, but after being used too much, will cause the content of the heavy metal in the agricultural land soil to raise.
Chinese patent 200710126149.4 is openly known clearly a kind of supercritical water oxidation technical finesse oily sludge that utilizes to produce the method for hydrogen-containing gas, but this invention is primarily aimed at and contains mud, and need gasification condition is controlled in the emergent pressure and temperature range of water in the technology that this invention is adopted; Chinese patent 200510041633.8 discloses a kind of coal and the biomass apparatus and method of overcritical catalytic gasification hydrogen manufacturing altogether, and this invention relates to the biomass with certain calorific value gasifies altogether with coal and produce inflammable gas, does not still relate to pond, lake bed mud.Chinese patent 200810063091.8 discloses the method for a kind of mud preparing hydrogen-rich gas by continuous catalysis gasification in supercritical water, and its process object is a sludge of sewage treatment plant.It is that main raw material mixes the method for producing industrial shaping coal with coal with the bed mud that Chinese patent 02133623.7 discloses a kind of, with the present invention moisture bed mud is mixed with coal and produces mud coal slurry, and the starting point that gasifies then is all different with technology.Chinese patent 200610030071.1 discloses and a kind of mud has been mixed the method for producing mud coal slurry with coal, and the mud of employing is sewage disposal mud, Industrial Wastewater Treatment mud and paper mill sludge etc., does not relate to mud coal slurry gasification process and technology.
Summary of the invention
The purpose of this invention is to provide kind of pond, a lake bed mud oxygen-enriched air smelting gasification process and a device, utilize the method for oxygen-rich gasification to be converted into available mixed combustible gas body the organic matter in the long-term sedimentary bed mud of Hu Chi, with the inorganics fusion in the bed mud is that solid is as pavior, to reach the purpose of eliminating environmental pollution.
Characteristic and constituent content thereof according to pond, lake bed mud, take bed mud and coal to be mixed into mud coal slurry, method with oxygen-rich gasification in vapourizing furnace is converted into the mixed combustible gas body with the organism in the bed mud, deleterious heavy metal is melt into the inorganic salt solid, as pavior, solve the pollution problem of bed mud more up hill and dale.Inflammable gas quality of the present invention is good, and purposes is wide, can be used as fuel gas-steam-generating combined cycle, also it can be carried out after part conversion and the methanation as town gas; Gasification itself is polluted few, good environmental protection; The sewage that produces seldom, a small amount of sewage can discharge after simple process; But thick, the thin slag of discharging is the making cement spike or the usefulness of paving the way both, to the environment non-secondary pollution; For a new road has been opened up in a large amount of pond, lake bed mud processing.
The bed mud that principle of the present invention: Hu Chi dredging produces becomes mud coal slurry with the coal mixed grinding, sprays in the vapourizing furnace by nozzle with oxygen enrichment, finishes moisture evaporation, burning and a series of conversion reaction of mud coal slurry in the short period of time at the utmost point:
Primary first-order equation: 1.0C+1.0O 2=1.0CO 2
1.5C+1.5H 2O=1.5CO+1.5H 2
Secondary reaction: 1.3C+1.3CO 2=2.6CO
1.15CO+1.15H 2 O=1.15CO 2 +1.15H 2
Net reaction 3.8C+2.65H 2O+O 2=0.85CO 2+ 2.95CO+2.65H 2
Temperature is controlled in 1300~1400 ℃ of scopes in the vapourizing furnace, and under this temperature, ash content is in molten state and gets rid of.
The present invention realizes by major equipments such as filter, pulverizer, wet wheeling machine, oxygen enrichment Ya Shrink machine, vapourizing furnace and washing towers.Filter 1, pulverizer 2 connect wet wheeling machine 3 respectively, wet wheeling machine 3 connects mud coal slurry make-up tank 4, mud coal slurry make-up tank 4 is by coal water slurry pump 5 logical vapourizing furnaces 7, nozzle is arranged at vapourizing furnace 7 tops, oxygen enrichment connects the nozzle that vapourizing furnace 7 pushes up with oxygen enrichment Ya Shrink machine 6, and lock slag ladle 8 is arranged at vapourizing furnace 7 bottoms, and lock slag ladle 8 bottoms connect slag bath 9, grey water handing pond 12 is arranged at washing tower 11 bottoms, and grey water handing pond 12 is by cold shock pump 10 logical vapourizing furnaces 7.
Pond, lake bed mud (I) is filtered into filter cake with filter 1 and adds wet wheeling machine 3, bituminous coal (II) is crushed to 10mm with pulverizer 2 and enters wet wheeling machine 3 when as follows, in wet wheeling machine 3, be ground to below 200 orders, enter mud coal slurry make-up tank 4, add dispersion agent and stablizer at this, and control concentration of hydraulic mixture, deployed mud coal slurry water coal slurry pump 5 is sent in the nozzle at vapourizing furnace 7 tops, oxygen enrichment is forced in the nozzle that 2.5MPa is sent to vapourizing furnace 7 top with oxygen enrichment Ya Shrink machine 6, mud coal slurry and oxygen enrichment are in nozzle after the thorough mixing atomizing, enter in vapourizing furnace 7 burner hearths and carry out gasification reaction, the thick mixed combustible gas body of generation and the lime-ash of molten state are downward together, through vapourizing furnace 7 bottom cold shocking waters, most of slag is behind cooling curing, fall into bottom, cold shock chamber,, regularly enter in the slag bath 9 by lock slag ladle 8.Thick mixed combustible gas body imports washing tower 11 from the cold shock chamber, the mixed combustible gas body after further dedusting is sent to subsequent processing, further purifies the back as required and uses.The washing water of washing tower 11 enter uses cold shock pump 10 pressurization backs for vapourizing furnace cold shocking water usefulness after handle in grey water handing pond 12.
The present invention realizes by following processing method:
(1) preparation of mud coal slurry:
Bed mud (butt) and coal (butt) mix by a certain percentage, and bed mud condition ratio is 10% ~ 80%, is ground to after the mixing below 200 orders.
The concentration 40%~70% of control mud coal slurry.
Add dispersion agent Sodium salts humic acids and stablizer PVA, each is 0.4%~0.5% years old.
(2) mud coal slurry gasification:
As vaporized chemical, mud coal slurry per ton needs oxygen enrichment 180~200m with oxygen level 80% ~ 100% oxygen-rich mixture body 3
Gasifying process condition: pressure 1.0 ~ 2.5MPa, 1200~1500 ℃ of gasification temperatures.
Thick mixed combustible gas body temperature degree is 200~250 ℃ after the cold shock.
The technical indicator that the present invention reaches:
(1) the mixed combustible gas body component of mud coal slurry production: CO:45~48%, H 2: 35~38%, CO 2: 15~17%, N 2: 0.5~0.6%, Di Re Zhi Approximately: 9780kJ/m 3
(2) mud coal slurry gas production rate: mud coal slurry 900~1000m per ton 3
Advantage that the present invention has and effect:
(1) mixed combustible gas physique amount is good, and purposes is wide.The mixed combustible gas body of producing can be used as fuel gas-steam-generating combined cycle, also the mixed combustible gas body can be carried out after part conversion and the methanation as city mixed combustible gas body.
(2) gasification itself is polluted and is lacked good environmental protection.The sewage that produces seldom, a small amount of sewage can discharge after simple process; But thick, the thin slag of discharging is the making cement spike or the usefulness of paving the way both, to the environment non-secondary pollution.
(3) opened up a new road for a large amount of pond, lake bed mud processing.
(4) turndown ratio of the present invention is big, during as if Wu Hu pond bed mud, and available various coal productions, equipment can not leave unused.The mixed combustible gas body component that mud coal slurry is produced: CO:45~48%, H 2: 35~38%, CO 2: 15~17%, N 2: 0.5~0.6%, Di Re Zhi Approximately: 9780kJ/m 3
Description of drawings
Fig. 1 is a schema of the present invention.
Embodiment
Among Fig. 1, filter 1, pulverizer 2 connect wet wheeling machine 3 respectively, wet wheeling machine 3 connects mud coal slurry make-up tank 4, mud coal slurry make-up tank 4 is by coal water slurry pump 5 logical vapourizing furnaces 7, and nozzle is arranged at vapourizing furnace 7 tops, and oxygen enrichment presses Shrink machine 6 to connect the nozzle on vapourizing furnace 7 tops with oxygen enrichment, lock slag ladle 8 is arranged at vapourizing furnace 7 bottoms, lock slag ladle 8 bottoms connect slag bath 9, and grey water handing pond 12 is arranged at washing tower 11 bottoms, and grey water handing pond 12 is by cold shock pump 10 logical vapourizing furnaces 7.
Pond, lake bed mud (I) is filtered into filter cake with filter 1 and adds wet wheeling machine 3, bituminous coal (II) is crushed to 10mm with pulverizer 2 and enters wet wheeling machine 3 when as follows, in wet wheeling machine 3, be ground to below 200 orders, enter mud coal slurry make-up tank 4, add dispersion agent and stablizer at this, and control concentration of hydraulic mixture, deployed mud coal slurry water coal slurry pump 5 is sent in the nozzle at vapourizing furnace 7 tops, oxygen enrichment is forced in the nozzle that 2.5MPa is sent to vapourizing furnace 7 top with oxygen enrichment Ya Shrink machine 6, mud coal slurry and oxygen enrichment are in nozzle after the thorough mixing atomizing, enter in vapourizing furnace 7 burner hearths and carry out gasification reaction, the thick mixed combustible gas body of generation and the lime-ash of molten state are downward together, through vapourizing furnace 7 bottom cold shocking waters, most of slag is behind cooling curing, fall into bottom, cold shock chamber,, regularly enter in the slag bath 9 by lock slag ladle 8.Thick mixed combustible gas body imports washing tower 11 from the cold shock chamber, the mixed combustible gas body after further dedusting is sent to subsequent processing, further purifies the back as required and uses.The washing water of washing tower 11 enter uses cold shock pump 10 pressurization backs for vapourizing furnace cold shocking water usefulness after handle in grey water handing pond 12.
Embodiment 1: processing power: 5 tons of mud coal slurry/times, handle 90 tons of pond, lake bed muds (moisture 60%) every day, and need 38 tons in bituminous coal, need oxygen enrichment 2.4 ten thousand m 3, produce the mixed combustible gas scale of construction 11.4 ten thousand m 3
Embodiment 2: processing power: 10 tons of mud coal slurry/times, handle 180 tons of pond, lake bed muds (moisture 60%) every day, and need 76 tons in bituminous coal, need oxygen enrichment 4.8 ten thousand m 3, produce the mixed combustible gas scale of construction 22.8 ten thousand m 3
Embodiment 3: processing power: 20 tons of mud coal slurry/times, handle 360 tons of pond, lake bed muds (moisture 60%) every day, and need 150 tons in bituminous coal, need oxygen enrichment 9.5 ten thousand m 3, produce the mixed combustible gas scale of construction 460,000 m 3

Claims (5)

1. pond, lake bed mud oxygen-enriched air smelting gasification process, it is characterized in that: according to the characteristic and the constituent content thereof of pond, lake bed mud, take bed mud and coal to be mixed into mud coal slurry, method with oxygen-rich gasification in vapourizing furnace is converted into the mixed combustible gas body with the organism in the bed mud, deleterious heavy metal is melt into the inorganic salt solid, as pavior.
2. pond, lake as claimed in claim 1 bed mud oxygen-enriched air smelting gasification process, it is characterized in that its processing step is: the preparation of (1) mud coal slurry: butt bed mud and butt coal mix by a certain percentage, bed mud condition ratio is 10% ~ 80%, is ground to after the mixing below 200 orders; The concentration 40%~70% of control mud coal slurry; Add dispersion agent Sodium salts humic acids and stablizer PVA, each is 0.4%~0.5% years old; (2) mud coal slurry gasification: as vaporized chemical, mud coal slurry per ton needs oxygen enrichment 180~200m3 with oxygen level 80% ~ 100% oxygen-rich mixture body; Gasifying process condition: pressure 1.0 ~ 2.5MPa, 1200~1500 ℃ of gasification temperatures; Thick mixed combustible gas body temperature degree is 200~250 ℃ after the cold shock.
3. bed mud oxygen-enriched air smelting gasification installation in pond, a lake is characterized in that: comprise filter (1), pulverizer (2), wet wheeling machine (3), oxygen enrichment compressor (6), vapourizing furnace (7) and washing tower (11) equipment.
4. pond, lake as claimed in claim 3 bed mud oxygen-enriched air smelting gasification installation, it is characterized in that: filter (1), pulverizer (2) connects wet wheeling machine (3) respectively, wet wheeling machine (3) connects mud coal slurry make-up tank (4), mud coal slurry make-up tank (4) is by the logical vapourizing furnace (7) of coal water slurry pump (5), nozzle is arranged at vapourizing furnace (7) top, oxygen enrichment connects the nozzle on vapourizing furnace (7) top with oxygen enrichment compressor (6), lock slag ladle (8) is arranged at vapourizing furnace (7) bottom, lock slag ladle (8) bottom connects slag bath (9), grey water handing pond (12) is arranged at washing tower (11) bottom, and grey water handing pond (12) are by the logical vapourizing furnace (7) of cold shock pump (10).
5. root a tree name claim 1 or pond, 2 described lake bed mud oxygen-enriched air smelting gasification process, it is characterized in that: pond, lake bed mud (I) is filtered into filter cake with filter (1) and adds wet wheeling machine (3), bituminous coal (II) is crushed to 10mm with pulverizer (2) and enters wet wheeling machine (3) when as follows, in wet wheeling machine (3), be ground to below 200 orders, enter mud coal slurry make-up tank (4), add dispersion agent and stablizer at this, and control concentration of hydraulic mixture, deployed mud coal slurry water coal slurry pump (5) is sent in the nozzle at vapourizing furnace (7) top, oxygen enrichment is forced in the nozzle that 2.5MPa is sent to vapourizing furnace (7) top with oxygen enrichment compressor (6), mud coal slurry and oxygen enrichment are in nozzle after the thorough mixing atomizing, enter in vapourizing furnace (7) burner hearth and carry out gasification reaction, the thick mixed combustible gas body that generates and the lime-ash of molten state are downward together, through vapourizing furnace (7) bottom cold shocking water, most of slag falls into bottom, cold shock chamber behind cooling curing, by lock slag ladle (8), regularly enter in the slag bath (9).Thick mixed combustible gas body imports washing tower (11) from the cold shock chamber, mixed combustible gas body after further dedusting is sent to subsequent processing, further purify the back as required and use, the washing water of washing tower (11) enter processing back, grey water handing pond (12) and supply the vapourizing furnace cold shocking water to use with cold shock pump (10) pressurization back.
CN200910163265A 2009-12-30 2009-12-30 Oxygen-enriched melting gasification method for lake sediment and device therefor Pending CN101747942A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200910163265A CN101747942A (en) 2009-12-30 2009-12-30 Oxygen-enriched melting gasification method for lake sediment and device therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN200910163265A CN101747942A (en) 2009-12-30 2009-12-30 Oxygen-enriched melting gasification method for lake sediment and device therefor

Publications (1)

Publication Number Publication Date
CN101747942A true CN101747942A (en) 2010-06-23

Family

ID=42475564

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200910163265A Pending CN101747942A (en) 2009-12-30 2009-12-30 Oxygen-enriched melting gasification method for lake sediment and device therefor

Country Status (1)

Country Link
CN (1) CN101747942A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110804465A (en) * 2019-11-20 2020-02-18 张俊霞 Device and method for producing hydrogen by gasifying plastic biomass
CN115013102A (en) * 2022-04-26 2022-09-06 成都科衡环保技术有限公司 Coal clean utilization thermodynamic system and operation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0795595A1 (en) * 1996-01-19 1997-09-17 Texas Instruments Inc. A method for processing industrial liquid and solid waste material
CN1330701A (en) * 1998-12-17 2002-01-09 德士古发展公司 Gasification of biosludge
CN1908134A (en) * 2006-08-14 2007-02-07 华东理工大学 High concentration sludge coal slurry and method for preparing the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0795595A1 (en) * 1996-01-19 1997-09-17 Texas Instruments Inc. A method for processing industrial liquid and solid waste material
CN1330701A (en) * 1998-12-17 2002-01-09 德士古发展公司 Gasification of biosludge
CN1908134A (en) * 2006-08-14 2007-02-07 华东理工大学 High concentration sludge coal slurry and method for preparing the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110804465A (en) * 2019-11-20 2020-02-18 张俊霞 Device and method for producing hydrogen by gasifying plastic biomass
CN115013102A (en) * 2022-04-26 2022-09-06 成都科衡环保技术有限公司 Coal clean utilization thermodynamic system and operation method thereof

Similar Documents

Publication Publication Date Title
Tyagi et al. Sludge: a waste or renewable source for energy and resources recovery?
CN101708938B (en) Sludge or organic garbage high-low temperature coupling themolysis method
CN101433904B (en) Processing technique for energy sources regeneration of urban domestic garbage and non-waste comprehensive utilization
CN100390255C (en) Sludge fuel stick and its prepn
CN105542808A (en) All-closed zero-emission household refuse energy regeneration and comprehensive utilization production process
CN108423959A (en) A kind of Sludge resource utilization method based on pyrohydrolysis-pyrolysis charring
CN101486563B (en) Biological haydite burned from mine tailings, and preparation and use method thereof
Zhang et al. A hybrid biological and thermal waste-to-energy system with heat energy recovery and utilization for solid organic waste treatment
CN102703155B (en) Biomass fuel based on sludge, straw and raw coal, preparation method of biomass fuel and application of fuel slag
CN103359898B (en) Method and apparatus for sludge deep treatment and resource utilization
CN107365593A (en) A kind of method that antibiotic bacterium dregs prepare charcoal
CN101987984A (en) Method for making compound solid waste derived fuel
Tyagi et al. Energy and resource recovery from sludge: Full-scale experiences
CN107880967A (en) A kind of production method of sewage sludge biomass fuel combination
CN101054541B (en) Sludge petroleum charred slurry and preparing process and application thereof
CN104974812A (en) Method for producing clean coal (carbon) spheres by using municipal sludge and agricultural wastes
CN105060669A (en) Sludge comprehensive utilization method by anaerobic fermentation-carbonization combination technique
CN202543012U (en) Fluid sludge treatment device for generating clean combustible gas
Zhou et al. Waste to worth: a new approach to treat wastewater sludge
CN107586579A (en) Briquettes with sludge and preparation method thereof
CN101812313B (en) Sludge fuel oil
CN101747942A (en) Oxygen-enriched melting gasification method for lake sediment and device therefor
CN104194861B (en) Sludge of sewage treatment plant low combustion value anthracite synthesizes
CN103242929A (en) Low calorific value blind coal prepared from sludge of domestic sewage treatment plant, and production technology and catalyst thereof
CN103629659A (en) Process for producing heat by wastewater and biomass

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20100623