CN101744004B - 凹凸棒二氧化氯杀菌消毒剂 - Google Patents
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Abstract
本发明公开了一种凹凸棒二氧化氯杀菌消毒剂，其技术方案的要点是，凹凸棒二氧化氯杀菌消毒剂由酸化后的膏状凹凸棒石粘土、二氧化氯、纳米二氧化钛银抗菌剂、椰油酰胺丙基甜菜碱和去离子水组成。将凹凸棒二氧化氯杀菌消毒剂的配料加入搅拌机内进行低速搅拌，研磨为糊状混合物，高速强力搅拌为膏状半成品后进行真空脱气工艺处理，罐装为凹凸棒二氧化氯杀菌消毒剂的成品；凹凸棒二氧化氯杀菌消毒剂具有附着力好，使用方便，喷洒均匀，用量少，杀菌消毒有效时间长和杀菌消毒效率高的特点。凹凸棒二氧化氯杀菌消毒剂安全无残留，有利于畜禽的正常生长，对人体无刺激：凹凸棒二氧化氯杀菌消毒剂适用于畜禽养殖场和其它场所的杀菌、消毒和除臭。
Description
技术领域
本发明涉及消毒剂，具体涉及一种凹凸棒二氧化氯杀菌消毒剂。
背景技术
畜禽养殖场内存在大量的有机物，如粪便、饲料残渣和污水等，这些有机物中藏匿着大量病毒、细菌、原生生物、藻类、真菌和各种孢子及孢子形成的菌体，细菌的大量繁殖体和许多致病菌、病原微生物对养殖场里的畜禽生长造成较大的侵害。
养殖场常用的一些消毒药物与有机物，尤其是与蛋白质有不同程度的亲和力，可结合成为不溶性的化合物，阻碍消毒药物药效的发挥。有的养殖场长期使用一种或两种消毒药物进行消毒，致使病原菌产生耐药性，影响了消毒效果。
二氧化氯是一种较好的消毒剂，它具有安全、无毒、用量少的优点，但是单一使用二氧化氯用于养殖场的杀菌消毒，往往会造成二氧化氯喷洒不均匀，二氧化氯流失的较多，直接影响到杀菌消毒的效果。
发明内容
本发明的目的是克服现有技术中不足之处，提供一种凹凸棒二氧化氯杀菌消毒剂。
凹凸棒二氧化氯杀菌消毒剂由酸化后的膏状凹凸棒石粘土、二氧化氯、纳米二氧化钛银抗菌剂、椰油酰胺丙基甜菜碱和去离子水组成。
凹凸棒石粘土是一种含水富镁纳米级多孔纤维状硅酸盐粘土矿物，当凹凸棒石粘土中的凹凸棒含量≥80％以上时，其比表面积较大，可达500m2/g以上，大部分的阳离子、水分子和一定大小的有机分子均可直接被吸附进孔道中，其吸水性可达150％以上。
使用凹凸棒矿造浆生产工艺，将凹凸棒石粘土中的水云母、石英、蛋白石和碳酸盐等矿物筛选去除掉，得到一种膏状凹凸棒石粘土，具有超细微粒、摩擦硬度小、无砂粒感和柔软细腻无异味的特点。
膏状凹凸棒石粘土经过高速强力搅拌，成为一种分散性、触变性和胶黏性特好的天然凝胶体，粘度高达10000mPa·s以上，附着力、吸附性能和保湿性能都得到了进一步的提高。
二氧化氯是一种广谱、高效的灭菌剂，能杀死病毒、细菌、原生生物、藻类、真菌和各种孢子及孢子形成的菌体；可杀灭所有细菌繁殖体和许多致病菌、细菌繁殖体、肝炎病毒、噬菌体和细菌芽孢；受温度和氨影响小。
纳米二氧化钛银抗菌剂具有抗菌、防霉杀菌净化功能，对真菌、大肠杆菌、金黄色葡萄球、乙肝病毒、口蹄疫、炭疽等细菌病毒抑杀率达99.9％以上。
椰油酰胺丙基甜菜碱是一种极其温和的两性表面活性剂，对皮肤、眼黏膜无刺激、无过敏性反应，其泡沫稳定、细腻，能提高凹凸棒二氧化氯杀菌消毒剂的附着力，增稠效果明显。
本发明通过下述技术方案予以实现：
1、凹凸棒二氧化氯杀菌消毒剂的配料按重量百分比由下列组分组成：酸化后的膏状凹凸棒石粘土20～65％、二氧化氯0.01～10％、纳米二氧化钛银抗菌剂0.01～5％、椰油酰胺丙基甜菜碱0.01～5％和去离子水25～70％；
2、凹凸棒二氧化氯杀菌消毒剂的生产方法：①将凹凸棒二氧化氯杀菌消毒剂的配料加入搅拌机内进行低速搅拌，搅拌混合均匀后为凹凸棒二氧化氯杀菌消毒剂的混合物；②将步骤①获得的混合物输入多功能胶体磨中进行研磨为糊状混合物，颗粒细度小于0.015毫米；③将步骤②获得的研磨后的糊状混合物，输入超高速搅拌机中进行高速强力搅拌为膏状半成品；④将步骤③获得的膏状半成品进行真空脱气工艺处理，罐装为凹凸棒二氧化氯杀菌消毒剂的成品；
所述酸化后的膏状凹凸棒石粘土的生产工艺：(1)选用凹凸棒矿泥浆为主体原料，凹凸棒矿泥浆按重量百分比由下列组分组成：凹凸棒石粘土15～35％和水65～85％；(2)酸化处理：将凹凸棒矿泥浆输送到搅拌机内，添加盐酸后进行搅拌，经过搅拌的凹凸棒矿泥浆，输送到酸化池中酸化处理1～3天为酸化后的膏状凹凸棒石粘土；酸化配料按重量百分比由下列组分组成：凹凸棒矿泥浆90～99.5％和盐酸0.5～10％，酸化后的膏状凹凸棒石粘土pH值控制在6.0～7.5；
所述盐酸采用浓度为31％的工业盐酸。
所述凹凸棒矿泥浆的生产工艺：将凹凸棒矿输入搅拌机内搅拌，经挤出机挤压成片状后，再次输入搅拌机内搅拌，经挤出机挤压成片状后自然晾晒，晾干的凹凸棒矿输送到原料池中浸泡，用气泵冲翻，沉淀后放出浸泡水，筛去杂质，输入半成品池中，重新加水浸泡，用气泵冲翻，沉淀后放出浸泡水，并将沉淀后的泥浆输送到成品池内，即为凹凸棒矿泥浆成品；
上述生产工艺是采用由本发明人于2004年1月6日申请的“凹凸棒矿造浆生产工艺”，中国专利授权公告号为：CN1287965C，授权公告日：2006年12月6日；
将凹凸棒二氧化氯杀菌消毒剂喷洒到畜禽舍内外的墙壁、地面，天棚、门窗、供水系统及粪便、饲料残渣和排污沟等处时，凹凸棒二氧化氯杀菌消毒剂将会附着在被喷洒物体的表面，达到杀菌消毒、防霉、除臭、除异味的效果。
凹凸棒二氧化氯杀菌消毒剂具有附着力好，使用方便，喷洒均匀，用量少，杀菌消毒有效时间长和杀菌消毒效率高的特点。
凹凸棒二氧化氯杀菌消毒剂只发生氧化作用不发生氯化作用，安全无残留，不与有机物发生氯代反应，不产生致癌、致畸、致变物质和其它有毒物质，有利于畜禽的正常生长，对人体无刺激：
凹凸棒二氧化氯杀菌消毒剂适用于畜禽养殖场和其它场所的杀菌、消毒和除臭。
具体实施方式
下面结合实施例对本发明作进一步的描述：
1、凹凸棒二氧化氯杀菌消毒剂的配料按重量百分比由下列组分组成：酸化后的膏状凹凸棒石粘土32％、二氧化氯6％、纳米二氧化钛银抗菌剂3％、椰油酰胺丙基甜菜碱0.5％和去离子水58.5％；
2、凹凸棒二氧化氯杀菌消毒剂的生产方法：①将凹凸棒二氧化氯杀菌消毒剂的配料加入搅拌机内进行低速搅拌，搅拌混合均匀后为凹凸棒二氧化氯杀菌消毒剂的混合物；②将步骤①获得的混合物输入多功能胶体磨中进行研磨为糊状混合物，颗粒细度小于0.015毫米；③将步骤②获得的研磨后的糊状混合物，输入超高速搅拌机中进行高速强力搅拌为膏状半成品；④将步骤③获得的膏状半成品进行真空脱气工艺处理，罐装为凹凸棒二氧化氯杀菌消毒剂的成品；
所述酸化后的膏状凹凸棒石粘土的生产工艺：(1)选用凹凸棒矿泥浆为主体原料，凹凸棒矿泥浆按重量百分比由下列组分组成：凹凸棒石粘土25％和水75％；(2)酸化处理：将凹凸棒矿泥浆输送到搅拌机内，添加盐酸后进行搅拌，经过搅拌的凹凸棒矿泥浆，输送到酸化池中酸化处理1天为酸化后的膏状凹凸棒石粘土；酸化配料按重量百分比由下列组分组成：凹凸棒矿泥浆97％和盐酸3％，酸化后的膏状凹凸棒石粘土pH值控制在6.0～7.5；
所述盐酸采用浓度为31％的工业盐酸。
Claims (1)
1.一种凹凸棒二氧化氯杀菌消毒剂，其特征在于，凹凸棒二氧化氯杀菌消毒剂的配料按重量百分比由下列组分组成：酸化后的膏状凹凸棒石粘土20～65％、二氧化氯0.01～10％、纳米二氧化钛银抗菌剂0.01～5％、椰油酰胺丙基甜菜碱0.01～5％和去离子水25～70％；
所述酸化后的膏状凹凸棒石粘土的生产工艺：(1)选用凹凸棒矿泥浆为主体原料，凹凸棒矿泥浆按重量百分比由下列组分组成：凹凸棒石粘土15～35％和水65～85％；(2)酸化处理：将凹凸棒矿泥浆输送到搅拌机内，添加盐酸后进行搅拌，经过搅拌的凹凸棒矿泥浆，输送到酸化池中酸化处理1～3天为酸化后的膏状凹凸棒石粘土；酸化配料按重量百分比由下列组分组成：凹凸棒矿泥浆90～99.5％和盐酸0.5～10％，酸化后的膏状凹凸棒石粘土pH值控制在6.0～7.5；
所述盐酸采用浓度为31％的工业盐酸；
所述凹凸棒二氧化氯杀菌消毒剂的生产方法：①将凹凸棒二氧化氯杀菌消毒剂的配料加入搅拌机内进行低速搅拌，搅拌混合均匀后为凹凸棒二氧化氯杀菌消毒剂的混合物；②将步骤①获得的混合物输入多功能胶体磨中进行研磨为糊状混合物，颗粒细度小于0.015毫米；③将步骤②获得的研磨后的糊状混合物，输入超高速搅拌机中进行高速强力搅拌为膏状半成品；④将步骤③获得的膏状半成品进行真空脱气工艺处理，罐装为凹凸棒二氧化氯杀菌消毒剂的成品。
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