CN101735357A - Method for improving ageing whiteness of vinyl chloride resin - Google Patents

Method for improving ageing whiteness of vinyl chloride resin Download PDF

Info

Publication number
CN101735357A
CN101735357A CN200810202352A CN200810202352A CN101735357A CN 101735357 A CN101735357 A CN 101735357A CN 200810202352 A CN200810202352 A CN 200810202352A CN 200810202352 A CN200810202352 A CN 200810202352A CN 101735357 A CN101735357 A CN 101735357A
Authority
CN
China
Prior art keywords
agent
vinyl chloride
resin
regulator
oxidation inhibitor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN200810202352A
Other languages
Chinese (zh)
Inventor
张利民
唐亮
高卫平
田延平
陆卫平
施宏标
陈勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Chlor Alkali Chemical Co Ltd
Original Assignee
Shanghai Chlor Alkali Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Chlor Alkali Chemical Co Ltd filed Critical Shanghai Chlor Alkali Chemical Co Ltd
Priority to CN200810202352A priority Critical patent/CN101735357A/en
Publication of CN101735357A publication Critical patent/CN101735357A/en
Pending legal-status Critical Current

Links

Landscapes

  • Polymerisation Methods In General (AREA)

Abstract

The invention provides a method for improving ageing whiteness of vinyl chloride resin. The method comprises the following steps: adding water, dispersing agent, vinyl chloride monomer, initiator, fisheye resisting agent and pH regulator in a reaction kettle for polymerization, and adding terminator and antioxidant in the reaction system simultaneously to obtain vinyl chloride resin, wherein the pH regulator is ammonium hydrogen carbonate, the antioxidant is imperfectly hindered phenol chain terminator antioxidant, the weight ratio of pH regulator to antioxidant is 1:1.76-2. In the inventive method, the resin particle size distribution width is lowered, resin particle shape is more regular, the heat resistance of the produced vinyl chloride resin is enhanced, the ageing whiteness index is obviously improved, and inherent quality of resin is enhanced. The polymerization in the production process is stable, quality repeatability of resin of each batch is good, and the new aid adopting composite preparation method can be applied in cauldron industrialized production.

Description

A kind of method that improves ageing whiteness of vinyl chloride resin
Technical field
The present invention relates to the preparation method of polyvinyl chloride (PVC) RESINS, particularly in the polyvinyl chloride resin production process, improve the method for aging of product whiteness.
Background technology
In the polyvinyl chloride resin production,, for example, require polyvinyl chloride (PVC) RESINS that higher ageing whiteness is arranged, and require resin that good plasticizing capacity is arranged, just need to improve production method, use New-type adjuvant for obtaining the polyvinyl chloride (PVC) RESINS product of better quality.Existing manufacturing technique only adopts reaction later stage adding sodium hydroxide solution to come stable polymerization system pH value mostly, and the back adds the mode of terminator termination reaction, and it is relatively poor that the product aging whiteness is improved effect.
Summary of the invention
The technical issues that need to address of the present invention provide a kind of method that improves ageing whiteness of vinyl chloride resin, improve difficult defective to overcome the ageing whiteness of vinyl chloride resin that exists in the prior art.
Method of the present invention, comprise the steps: water, dispersion agent, vinyl chloride monomer, initiator, anti-flake agent and pH regulator agent are added in the reactor, 50~65 ℃, reaction times is 4.5~5.5 hours, carry out polyreaction, then terminator and oxidation inhibitor are added in the reaction system simultaneously, obtain polyvinyl chloride (PVC) RESINS; The parts by weight of component are:
1000 parts of vinyl chloride monomers
1000~1500 parts in water
0.2~0.35 part of dispersion agent
0.15~0.25 part of initiator
0.4~0.7 part of anti-flake agent
0.005~0.015 part of pH regulator agent
0.2~0.3 part of terminator;
Described pH regulator agent is a bicarbonate of ammonia;
Described dispersion agent is selected from polyvinyl alcohol (KH20) that Japanese synthetic chemistry company produces or in the Vltra tears (being called for short HPMC) more than one;
Described initiator is selected from more than one among the own ester abbreviation EHP of peroxy dicarbonate two (2-ethyl) and TX-99 (peroxidation neodecanoic acid isopropyl benzene ester) or the TX-36 (bis oxide (3,5, the 5-trimethylammonium) hexanoyl);
Described anti-flake agent is a Tert. Butyl Hydroquinone;
Described terminator is the acetone amido thiocarbamide (be called for short ATSC) that contracts, and can adopt the product of Hua Lian, Beijing chemical industry company limited;
Described oxidation inhibitor is non-complete Hinered phenols chain terminator and oxidation inhibitor (being called for short EB44-34), and can adopt the Ciba company trade mark is the product of EB44-34, is the oxidation inhibitor of 40% water base corpuscle emulsion form for a kind of weight concentration;
What need specification sheets is that above-mentioned reaction conditions and dispersion agent, initiator and the anti-flake agent etc. adopted are technology well known in the art;
The weight ratio of pH regulator agent and oxidation inhibitor is:
PH regulator agent: oxidation inhibitor=1: 1.76~2;
According to the present invention, it is 5~10% solution that bicarbonate of ammonia is mixed with weight concentration earlier, adds reactor then;
The applicant finds that improving the rosin products whiteness generally has two methods, adds pH regulator agent, heat-resisting terminator.The height of the pH value of polymerization system is to influence one of the particle form of resin and key factor of resin ageing whiteness, and dispersion system is also had certain influence.
The present invention is in the Production of PVC process, use new pH regulator agent-bicarbonate of ammonia, replace present NaOH pH value conditioning agent, in the stable polymerization system pH, add novel oxidation inhibitor EB44-34, to reach the purpose that the stable polymerization system improves the resin resistance toheat.
Adopt the prepared polyvinyl chloride (PVC) RESINS of aforesaid method, the particle diameter distribution width of resin decreases, and the resin particle form is more regular, and the polyvinyl chloride (PVC) RESINS resistance toheat of producing improves, and the ageing whiteness index improves significantly, and has promoted the inner quality of resin.And polyreaction is stable in the production process, and each batch resin quality good reproducibility is so this employing New-type adjuvant composite preparation process can be applicable in the big still industrial production.
Embodiment
Embodiment 1
Water, dispersion agent, vinyl chloride monomer, anti-flake agent Tert. Butyl Hydroquinone and initiator are added in the polymerization reaction kettle, and its ratio of weight and number is:
Vinyl chloride monomer: water: dispersion agent: initiator: anti-flake agent: bicarbonate of ammonia: terminator=1000: 1280: 0.28: 0.19: 0.55: 0.01: 0.25;
The weight ratio of pH regulator agent and oxidation inhibitor is:
PH regulator agent: oxidation inhibitor=1: 2;
Bicarbonate of ammonia is that weight concentration is 6% solution adding;
Temperature of reaction is 56.8 ℃, after 5 hours polyreaction, adds oxidation inhibitor with terminator in polymeric kettle, obtains polyvinyl chloride (PVC) RESINS.
Dispersion agent is the polyvinyl alcohol (KH20) produced of Japanese synthetic chemistry company and the mixture of Vltra tears (abbreviation HPMC), and weight ratio is 1: 0.68;
Initiator is that the own ester of peroxy dicarbonate two (2-ethyl) is called for short EHP and TX-99 (peroxidation neodecanoic acid isopropyl benzene ester) or TX-36 (bis oxide (3,5, the 5-trimethylammonium) more than one hexanoyl), anti-flake agent is a Tert. Butyl Hydroquinone, oxidation inhibitor is EB44-34;
Employing detects by GB/T 15595 required standards, and it is average more than 80 that the whiteness of polyvinyl chloride (PVC) RESINS product can reach, and the particle diameter of resin particle is thicker, and size distribution is concentrated relatively.
Embodiment 2
Adopt the method identical with embodiment 1, wherein:
1000 parts of vinyl chloride monomers
1500 parts in water
0.35 part of dispersion agent
0.25 part of initiator
0.7 part of anti-flake agent
0.015 part of pH regulator agent
0.3 part of terminator;
The weight ratio of pH regulator agent and oxidation inhibitor is: the pH regulator agent: oxidation inhibitor=1: 1.76;
Bicarbonate of ammonia is that weight concentration is 10% solution adding;
Adopt GB/T 15595 required standards to detect, it is average more than 79 that the whiteness of polyvinyl chloride (PVC) RESINS product can reach, and the particle diameter of resin particle is thicker, and size distribution is concentrated relatively.

Claims (4)

1. method that improves ageing whiteness of vinyl chloride resin, it is characterized in that, comprise the steps: water, dispersion agent, vinyl chloride monomer, initiator, anti-flake agent and pH regulator agent are added in the reactor, carry out polyreaction, add terminator and oxidation inhibitor in the reaction system simultaneously then, obtain polyvinyl chloride (PVC) RESINS, described pH regulator agent is a bicarbonate of ammonia, described oxidation inhibitor is non-complete Hinered phenols chain terminator oxidation inhibitor, and the weight ratio of pH regulator agent and oxidation inhibitor is: the pH regulator agent: oxidation inhibitor=1: 1.76~2.
2. method according to claim 1 is characterized in that, the parts by weight of component are:
1000 parts of vinyl chloride monomers
1000~1500 parts in water
0.2~0.35 part of dispersion agent
0.15~0.25 part of initiator
0.4~0.7 part of anti-flake agent
0.005~0.015 part of pH regulator agent
0.2~0.3 part of terminator.
3. method according to claim 1 is characterized in that, temperature of reaction is 50~65 ℃, and the reaction times is 4.5~5.5 hours.
4. method according to claim 1 is characterized in that described dispersion agent is selected from more than one in polyvinyl alcohol or the Vltra tears; Described initiator is selected from more than one among the own ester abbreviation EHP of peroxy dicarbonate two (2-ethyl) and TX-99 (peroxidation neodecanoic acid isopropyl benzene ester) or the TX-36 (bis oxide (3,5, the 5-trimethylammonium) hexanoyl); Described anti-flake agent is a Tert. Butyl Hydroquinone; Described terminator is the acetone amido thiocarbamide that contracts.
CN200810202352A 2008-11-06 2008-11-06 Method for improving ageing whiteness of vinyl chloride resin Pending CN101735357A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200810202352A CN101735357A (en) 2008-11-06 2008-11-06 Method for improving ageing whiteness of vinyl chloride resin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN200810202352A CN101735357A (en) 2008-11-06 2008-11-06 Method for improving ageing whiteness of vinyl chloride resin

Publications (1)

Publication Number Publication Date
CN101735357A true CN101735357A (en) 2010-06-16

Family

ID=42459428

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200810202352A Pending CN101735357A (en) 2008-11-06 2008-11-06 Method for improving ageing whiteness of vinyl chloride resin

Country Status (1)

Country Link
CN (1) CN101735357A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102952219A (en) * 2011-08-30 2013-03-06 中国石油化工股份有限公司 Vinyl chloride monomer polymerization reaction system reaction termination method
CN102952225A (en) * 2011-08-30 2013-03-06 中国石油化工股份有限公司 Suspension polymerization method for reducing polyvinyl chloride resin fisheyes
CN105199026A (en) * 2014-06-17 2015-12-30 上海氯碱化工股份有限公司 Preparation method of special PVC resin for CPVC
CN106893011A (en) * 2017-03-20 2017-06-27 青海盐湖工业股份有限公司 A kind of whiteness Corvic high and preparation method thereof
CN107011589A (en) * 2016-07-21 2017-08-04 佛山瑞箭体育器材有限公司 A kind of method for improving polyvinyl chloride resin ageing whiteness
CN107011588A (en) * 2016-07-20 2017-08-04 佛山瑞箭体育器材有限公司 A kind of method for improving polyvinyl chloride resin ageing whiteness
CN108034015A (en) * 2017-12-27 2018-05-15 山西阿科达化工科技有限公司 A kind of preparation method of polyvinyl chloride
CN113651910A (en) * 2021-09-15 2021-11-16 金川集团股份有限公司 Preparation method of large-particle-size narrow-distribution polyvinyl chloride resin
CN115707719A (en) * 2021-08-18 2023-02-21 中国石油化工股份有限公司 PVC resin polymerization dispersing auxiliary agent, preparation method and resin preparation method

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102952219A (en) * 2011-08-30 2013-03-06 中国石油化工股份有限公司 Vinyl chloride monomer polymerization reaction system reaction termination method
CN102952225A (en) * 2011-08-30 2013-03-06 中国石油化工股份有限公司 Suspension polymerization method for reducing polyvinyl chloride resin fisheyes
CN102952225B (en) * 2011-08-30 2014-12-10 中国石油化工股份有限公司 Suspension polymerization method for reducing polyvinyl chloride resin fisheyes
CN105199026A (en) * 2014-06-17 2015-12-30 上海氯碱化工股份有限公司 Preparation method of special PVC resin for CPVC
CN107011588A (en) * 2016-07-20 2017-08-04 佛山瑞箭体育器材有限公司 A kind of method for improving polyvinyl chloride resin ageing whiteness
CN107011589A (en) * 2016-07-21 2017-08-04 佛山瑞箭体育器材有限公司 A kind of method for improving polyvinyl chloride resin ageing whiteness
CN106893011A (en) * 2017-03-20 2017-06-27 青海盐湖工业股份有限公司 A kind of whiteness Corvic high and preparation method thereof
CN108034015A (en) * 2017-12-27 2018-05-15 山西阿科达化工科技有限公司 A kind of preparation method of polyvinyl chloride
CN108034015B (en) * 2017-12-27 2020-08-04 山西阿科达化工科技有限公司 Preparation method of polyvinyl chloride
CN115707719A (en) * 2021-08-18 2023-02-21 中国石油化工股份有限公司 PVC resin polymerization dispersing auxiliary agent, preparation method and resin preparation method
CN115707719B (en) * 2021-08-18 2023-10-20 中国石油化工股份有限公司 PVC resin polymerization dispersion auxiliary agent, preparation method and resin preparation method
CN113651910A (en) * 2021-09-15 2021-11-16 金川集团股份有限公司 Preparation method of large-particle-size narrow-distribution polyvinyl chloride resin

Similar Documents

Publication Publication Date Title
CN101735357A (en) Method for improving ageing whiteness of vinyl chloride resin
CN110790854A (en) Tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer and preparation method thereof
CN104277169A (en) Production method of special chlorinated polyvinyl chloride (CPVC) resin
CN105754179A (en) Flame retardant HDPE cable material and preparation method thereof
EP3597674B1 (en) Method for preparing copolymer
CN106854256B (en) Melt-processable modified polyvinyl alcohol and preparation method thereof
US10047180B2 (en) Vinyl-based thermoplastic resin composition, method for manufacturing thereof and vinyl-based thermoplastic resin manufactured therefrom
KR20160047141A (en) Vinylchloride resin and preparing method thereof
CN111253512A (en) Tetrafluoroethylene-alkyl acrylate-perfluoroalkyl vinyl ether dispersion resin and microporous membrane prepared from same
KR101133962B1 (en) Method for the preparation of vinyl chloride-based polymer by suspension polymerization
CN103539899A (en) Preparation method of weather-resistant anti-aging ABS (acrylonitrile-butadiene-styrene) resin
KR20130026621A (en) A method for preparing polyvinyl chloride resin having increased productivity
KR101411098B1 (en) Method of preparing polyvinyl chloride comprising butyl acrylate
KR101515674B1 (en) ABS Graft Resin Having Superior Heat Resistance And Method For Preparing The Same
CN108017738B (en) Environment-friendly aqueous composite terminator
CN104211848A (en) Preparation method of N-phenyl maleimide heat-resistant modifier
CN112940204A (en) Preparation method of polybutadiene latex for agglomeration and prepared ABS resin
CN109651541B (en) Linear chain dialdehyde modified polyvinyl alcohol and preparation method and application thereof
CN105199026A (en) Preparation method of special PVC resin for CPVC
KR102242546B1 (en) Ethylene vinyl acetate and molded article produced therefrom
CN109824806A (en) A kind of production method and gained resin of polyvinyl chloride resin
KR102665728B1 (en) Method for preparing polymer
CN111269342B (en) Preparation method of high-purity polytetrafluoroethylene
EP3789410A1 (en) Vinyl chloride polymer and method for preparing same
CN112812222B (en) Preparation method of AS resin modifier and obtained product

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Open date: 20100616