CN101717592A - Method for synthesizing color attapulgite clay - Google Patents
Method for synthesizing color attapulgite clay Download PDFInfo
- Publication number
- CN101717592A CN101717592A CN200910212922A CN200910212922A CN101717592A CN 101717592 A CN101717592 A CN 101717592A CN 200910212922 A CN200910212922 A CN 200910212922A CN 200910212922 A CN200910212922 A CN 200910212922A CN 101717592 A CN101717592 A CN 101717592A
- Authority
- CN
- China
- Prior art keywords
- attapulgite clay
- color
- primary colors
- raw ore
- clay
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Abstract
The invention discloses a method for synthesizing a color attapulgite clay, which comprises the following steps: firstly, performing water immersion on an attapulgite clay raw ore for a certain period of time, then filtering impurities except quartz sand and the like in the raw ore, and concentrating and drying the filtrate to obtain a pure attapulgite clay; secondly, mixing the pure attapulgite clay with dyes with three primary colors including red, blue and yellow respectively in certain weight ratio to prepare solution, and putting the solution in a reaction kettle to perform hydro-thermal reaction for a certain period of time at the certain temperature; thirdly, filtering, water washing and drying the mixture to obtain a primary color attapulgite clay with the three primary colors; and finally, mixing and grinding the attapulgite clays with the three primary colors and different proportions according to the requirements on color deployment so as to obtain the color attapulgite clay with different colors. The method uses the low-price attapulgite clay raw ore as a raw material to synthesize the color attapulgite clay with a greater economic value, the product of the color attapulgite clay has the characteristics of wide application range, bright color, convenient color mixing, low cost and the like, and the method widens the application value of the attapulgite clay.
Description
Technical field
The present invention relates to a kind of synthetic method of color attapulgite clay, specifically a kind of is the method for the synthetic color attapulgite clay of raw material with the attapulgite clay raw ore, belongs to field of inorganic materials, also belongs to mineral and utilizes the field.
Background technology
Attapulgite clay be a kind of natural have a layer chain-like structure contain Shuifu County's zeopan clay mineral, desirable molecular formula is: Mg
5Si
8O
20(OH)
2(OH
2)
44H
2O, the theoretical chemistry composition is: SiO
256.96%; (Fe) O 23.83% for Mg, Al; H
2O 19.21%.The pure palygorskite clay should be white, and is widely used in industries such as chemical industry, coating, papermaking, washing auxiliary detergent.Difference according to purposes, whiteness to attapulgite clay has different requirements, but because its extraneous ionic in forming process enters, make attapulgite clay because of containing color such as apparent red, grey, the Huang of impurity such as Fe, this has limited the application of attapulgite clay greatly.Whiteness is one of main factor of the product performance, price and the business economic benefit that influence attapulgite clay.
According to existing bibliographical information, about the research and the technology of attapulgite clay color mainly concentrates on brightening in the research of attapulgite clay.But in some industry,, might not need the attapulgite clay of white such as colo(u)r coating, paint etc.Attapulgite clay is as the additive of coating (Yunnan chemical, 2006,33 (5): 18～21) can improve the performance of coating; Can improve the storage sedimentation problem of high resin-pigment ratio solvent based coating, better with some anti-settling agent and dispersion agent matching effect, little to paint finishes and viscosity influence, cheap and have an environment protecting (Chinese coating, 2003,6:31～32); Can improve (Anhui chemical industry, 2006,143 (5): 24～26) such as the pull resistance of coating and ageing-resistant performance; With the attapulgite clay is the patent of invention open (CN101077951A) of the environmental protection coating material of main component, and this patent is not used any batching that contains formaldehyde, has avoided formaldehyde pollution fully, has protected HUMAN HEALTH; As fully visible, attapulgite clay can be applicable to coating and paint industry.
Summary of the invention
The objective of the invention is: the synthetic method that a kind of color attapulgite clay is provided, is the synthetic bigger color attapulgite clay of economic worth of raw material by this method with inexpensive attapulgite clay raw ore, characteristics such as that product has is widely applicable, bright in luster, toning is convenient, with low cost, the using value of expansion attapulgite clay.
Method of the present invention may further comprise the steps: at first, with attapulgite clay raw ore water logging bubble certain hour, filter the impurity of removing in the raw ore such as quartz sand, concentrate drying filtrate obtains pure attapulgite clay; Then, pure attapulgite clay is red in tricolor dye, blue respectively, yellow certain weight ratio wiring solution-forming, put in the reactor, at a certain temperature the hydro-thermal reaction certain hour; Secondly, after filtration washing and dry trichromatic primary colors attapulgite clay; At last, the three primary colors attapulgite clay that will ask for Different Weight according to mixing color mixes, grinds, and obtains the color attapulgite clay of different colours.
Method concrete steps of the present invention are as follows:
1) the attapulgite clay raw ore flooded in water 24 hours, filtered the impurity of removing in the raw ore such as quartz sand, and concentrate drying filtrate gets pure attapulgite clay;
2) with the pure attapulgite clay of exsiccant respectively with the aqueous solution of red, blue, yellow three kinds of dyestuffs according to feed intake weight ratio 1: 0.005～0.5 preparation attapulgite clay and dyestuff, wherein the mass concentration of attapulgite clay is 1～20%;
3) above-mentioned solution is transferred in the reactor, carried out hydro-thermal reaction, hydrothermal temperature is 105～180 ℃, and the hydro-thermal time is 1～24 hour, after filtration, washing and dry three primary colors attapulgite clay;
4) the three primary colors attapulgite clay that requires to take by weighing Different Weight according to mixing color mixes, grinds, and obtains the color attapulgite clay of different colours.
Method of the present invention is the synthetic bigger color attapulgite clay of economic worth of resource with the attapulgite clay raw ore of cheapness, has expanded the using value of attapulgite clay.
Description of drawings
Fig. 1 is a three primary colors attapulgite clay photo, and wherein 01 is red, and 02 is blue, and 03 is yellow.
The color attapulgite clay photo of Fig. 2 different colours.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.Should be understood that these embodiment just in order to demonstrate the invention, but not limit technical scheme of the present invention by any way.
Embodiment 1:
The attapulgite clay raw ore was flooded in water 24 hours, filter the impurity of removing in the raw ore such as quartz sand, concentrate drying filtrate obtains pure attapulgite clay; Pure attapulgite clay of 2g and 0.505g magenta are joined in the 17.5mL water, stir, move into reactor, 140 ℃ of hydro-thermal reactions 12 hours are filtered, and are washed to elutant and are colourless; 60 ℃ of dryings obtain red primary colors attapulgite clay, the color shown in Fig. 1-01.
Embodiment 2:
The purification of attapulgite clay raw ore is with example 1; Pure attapulgite clay of 0.5g and 0.0025g alkali indigo plant are joined in the 50mL water, stir, move into reactor, 105 ℃ of hydro-thermal reactions 24 hours are filtered, and are washed to elutant and are colourless; 60 ℃ of dryings obtain blue primary colors attapulgite clay, the color shown in Fig. 1-02.
Embodiment 3:
The purification of attapulgite clay raw ore is with example 1; Pure attapulgite clay of 10g and 5g titan yellow are joined in the 35mL water, stir, move into reactor, 180 ℃ of hydro-thermal reactions 1 hour are filtered, and are washed to elutant and are colourless; 60 ℃ of dryings obtain xanchromatic primary colors attapulgite clay, the color shown in Fig. 1-03.
Embodiment 4:
Get the primary colors attapulgite clay of 0.1904g redness and the primary colors attapulgite clay of 0.1026g blueness, mix, grind the color attapulgite clay that obtains shown in Fig. 2-01.
Embodiment 5:
Get the primary colors attapulgite clay and the 0.4533g xanchromatic primary colors attapulgite clay of 0.101g redness, obtain the color attapulgite clay shown in Fig. 2-02 after mixing, grinding.
Embodiment 6:
Get the primary colors attapulgite clay and the 0.5734g xanchromatic primary colors attapulgite clay of 0.0656g redness, obtain the color attapulgite clay shown in Fig. 2-03 after mixing, grinding.
Embodiment 7:
Get the primary colors attapulgite clay and the 0.3991g xanchromatic primary colors attapulgite clay of 0.1535g redness, obtain the color attapulgite clay shown in Fig. 2-04 after mixing, grinding.
Embodiment 8:
Get the primary colors attapulgite clay and the 0.4527g xanchromatic primary colors attapulgite clay of 0.1326g blueness, obtain the color attapulgite clay shown in Fig. 2-05 after mixing, grinding.
Embodiment 9:
Get the primary colors attapulgite clay and the 0.4465g xanchromatic primary colors attapulgite clay of 0.0768g blueness, mix, grind the color attapulgite clay that obtains shown in Fig. 2-06.
Embodiment 10:
Get the primary colors attapulgite clay of 0.0455g redness and the primary colors attapulgite clay of 0.2216g blueness, mix, grind the color attapulgite clay that obtains shown in Fig. 2-07.
Embodiment 11:
Get the primary colors attapulgite clay of 0.1774g xanchromatic primary colors attapulgite clay and 0.2308g blueness, mix, grind the color attapulgite clay that obtains shown in Fig. 2-08.
Embodiment 12:
Get the primary colors attapulgite clay of 0.2968g xanchromatic primary colors attapulgite clay and 0.1054g blueness, mix, grind the color attapulgite clay that obtains shown in Fig. 2-09.
Embodiment 13:
Get the primary colors attapulgite clay of 0.3994g xanchromatic primary colors attapulgite clay, 0.1159g blueness and the primary colors attapulgite clay of 0.0323g redness, mix, grind the color attapulgite clay that obtains shown in Fig. 2-10.
Embodiment 14:
Get the primary colors attapulgite clay of 0.3979g xanchromatic primary colors attapulgite clay, 0.1124g blueness and the primary colors attapulgite clay of 0.02g redness, mix, grind the color attapulgite clay that obtains shown in Fig. 2-11.
Claims (2)
1. the synthetic method of a color attapulgite clay is characterized in that may further comprise the steps: at first, with attapulgite clay raw ore water logging bubble certain hour, filter the impurity of removing in the raw ore such as quartz sand, concentrate drying filtrate obtains pure attapulgite clay; Then, pure attapulgite clay is red in tricolor dye, blue respectively, yellow certain weight ratio wiring solution-forming, put in the reactor, at a certain temperature the hydro-thermal reaction certain hour; Secondly, after filtration washing and dry trichromatic primary colors attapulgite clay; At last, the trichromatic primary colors attapulgite clay that will ask for Different Weight according to mixing color mixes, grinds, and obtains the color attapulgite clay of different colours.
2. the synthetic method of a kind of color attapulgite clay according to claim 1 is characterized in that these method concrete steps are as follows:
1) the attapulgite clay raw ore flooded in water 24 hours, filtered the impurity of removing in the raw ore such as quartz sand, and concentrate drying filtrate obtains pure attapulgite clay;
2) with the pure attapulgite clay of exsiccant respectively with the aqueous solution of red, blue, yellow three kinds of dyestuffs according to feed intake weight ratio 1: 0.005～0.5 preparation attapulgite clay and dyestuff, wherein the mass concentration of attapulgite clay is 1～20%;
3) above-mentioned solution is transferred in the reactor, carried out hydro-thermal reaction, hydrothermal temperature is 105～180 ℃, and the hydro-thermal time is 1～24 hour, after filtration, washing and dry trichromatic primary colors attapulgite clay;
4) the trichromatic primary colors attapulgite clay that requires to take by weighing Different Weight according to mixing color mixes, grinds, and obtains the color attapulgite clay of different colours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910212922A CN101717592A (en) | 2009-11-06 | 2009-11-06 | Method for synthesizing color attapulgite clay |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910212922A CN101717592A (en) | 2009-11-06 | 2009-11-06 | Method for synthesizing color attapulgite clay |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101717592A true CN101717592A (en) | 2010-06-02 |
Family
ID=42432236
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910212922A Pending CN101717592A (en) | 2009-11-06 | 2009-11-06 | Method for synthesizing color attapulgite clay |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101717592A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101973061A (en) * | 2010-07-30 | 2011-02-16 | 许庆华 | Method for producing soft silvery attapulgite clay |
| CN101973065A (en) * | 2010-07-30 | 2011-02-16 | 许庆华 | Method for producing yellow attapulgite polymer clay mud |
| CN102757666A (en) * | 2012-07-03 | 2012-10-31 | 中国科学院兰州化学物理研究所盱眙凹土应用技术研发中心 | Method for preparing concave-convex clay-based nanometer composite pigment by high-pressure induction |
| CN103044970A (en) * | 2012-12-31 | 2013-04-17 | 中国科学院兰州化学物理研究所盱眙凹土应用技术研发中心 | Preparation method of wet-process Maya-blue-like dye |
| CN104755443A (en) * | 2012-12-26 | 2015-07-01 | 土路生活有限公司 | Earth-finishing-material production method and construction method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3723174A (en) * | 1971-01-06 | 1973-03-27 | Engelhard Min & Chem | Pigment for pressure sensitive record material |
| WO1992021726A1 (en) * | 1991-06-03 | 1992-12-10 | Kompopigment Ltd | Composite pigment and method for the production |
| WO2001055263A1 (en) * | 2000-01-28 | 2001-08-02 | Carlo Ghisalberti | New coated pigments and composition containing them |
-
2009
- 2009-11-06 CN CN200910212922A patent/CN101717592A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3723174A (en) * | 1971-01-06 | 1973-03-27 | Engelhard Min & Chem | Pigment for pressure sensitive record material |
| WO1992021726A1 (en) * | 1991-06-03 | 1992-12-10 | Kompopigment Ltd | Composite pigment and method for the production |
| WO2001055263A1 (en) * | 2000-01-28 | 2001-08-02 | Carlo Ghisalberti | New coated pigments and composition containing them |
Non-Patent Citations (1)
| Title |
|---|
| 杨桂琴等: "《黄色含硫硅酸盐类无毒新颜料的制备", 《应用化学》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101973061A (en) * | 2010-07-30 | 2011-02-16 | 许庆华 | Method for producing soft silvery attapulgite clay |
| CN101973065A (en) * | 2010-07-30 | 2011-02-16 | 许庆华 | Method for producing yellow attapulgite polymer clay mud |
| CN102757666A (en) * | 2012-07-03 | 2012-10-31 | 中国科学院兰州化学物理研究所盱眙凹土应用技术研发中心 | Method for preparing concave-convex clay-based nanometer composite pigment by high-pressure induction |
| CN104755443A (en) * | 2012-12-26 | 2015-07-01 | 土路生活有限公司 | Earth-finishing-material production method and construction method |
| CN103044970A (en) * | 2012-12-31 | 2013-04-17 | 中国科学院兰州化学物理研究所盱眙凹土应用技术研发中心 | Preparation method of wet-process Maya-blue-like dye |
| CN103044970B (en) * | 2012-12-31 | 2014-03-12 | 中国科学院兰州化学物理研究所盱眙凹土应用技术研发中心 | Preparation method of wet-process Maya-blue-like dye |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101717592A (en) | Method for synthesizing color attapulgite clay | |
| CN1329455C (en) | Method for the production of phthalocyanine pigment preparations | |
| CN102031023A (en) | Calcined kaolin-based compound titanium dioxide and preparation method thereof | |
| DE3106906A1 (en) | PIGMENT COMPOSITIONS | |
| CN102382507B (en) | Hydrophilic ink for intaglio printing on surfaces of aluminum foils and preparation method thereof | |
| JPS6088185A (en) | Pigment dispersant | |
| CN1934197A (en) | Pigment preparations based on phthalocyanine pigments | |
| CN100392022C (en) | Pigment dispersing agent and pigment composition containing the same dispersing agent | |
| CN102031024A (en) | Kaolin-based compound titanium dioxide and preparation method thereof | |
| JPS63305173A (en) | Pigment dispersant | |
| CN103146253B (en) | Preparation method of special phthalocyamine blue 15:4 pigment for methylbenzene ink | |
| CN101955689A (en) | Triarylmethane class and rhodamine class color compositions and the pigment dispersion that uses this color compositions | |
| CN101845252A (en) | Water-based color paste and preparation method thereof | |
| JP2004123866A (en) | Azo pigment for inkjet ink, inkjet ink and their manufacturing processes | |
| CN102020864B (en) | Method for manufacturing yellow dye by utilizing 1-amino anthraquinone production waste residues | |
| CN101544406B (en) | Method for producing red iron oxide pigment | |
| CN105385185B (en) | A kind of clean method for preparing of alkalescent arylamine azo dispersion dyes | |
| CN101679767A (en) | Based on the C.I. pigment Blue 15: 6 pigment preparation | |
| CA1111606A (en) | Dyestuff solutions | |
| CN102596966A (en) | Phthalocyanine compound, preparation method therefor, and coloring composition including said phthalocyanine compound | |
| CN102786814A (en) | Preparation method for high energy saving environmental protection type phthalocyanine green pigment | |
| CA1136127A (en) | Process for conditioning a phthalocyanine pigment | |
| CN1303159C (en) | Method for preparing perylene pigments with high hiding power | |
| CN101294005A (en) | Red naphtocyclinon solvent dye and preparation method thereof | |
| CN100396731C (en) | Manufacturing and conditioning of solid solution organic pigments |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20100602 |