CN102382507B - Hydrophilic ink for intaglio printing on surfaces of aluminum foils and preparation method thereof - Google Patents

Hydrophilic ink for intaglio printing on surfaces of aluminum foils and preparation method thereof Download PDF

Info

Publication number
CN102382507B
CN102382507B CN 201110262262 CN201110262262A CN102382507B CN 102382507 B CN102382507 B CN 102382507B CN 201110262262 CN201110262262 CN 201110262262 CN 201110262262 A CN201110262262 A CN 201110262262A CN 102382507 B CN102382507 B CN 102382507B
Authority
CN
China
Prior art keywords
parts
water
preparation
ink
color ink
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN 201110262262
Other languages
Chinese (zh)
Other versions
CN102382507A (en
Inventor
熊远钦
梁鉴锋
熊竹
郭锐强
徐伟箭
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FOSHAN SHUNDE LECONG SHENGCHANG INK Co Ltd
Hunan University
Original Assignee
FOSHAN SHUNDE LECONG SHENGCHANG INK Co Ltd
Hunan University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FOSHAN SHUNDE LECONG SHENGCHANG INK Co Ltd, Hunan University filed Critical FOSHAN SHUNDE LECONG SHENGCHANG INK Co Ltd
Priority to CN 201110262262 priority Critical patent/CN102382507B/en
Publication of CN102382507A publication Critical patent/CN102382507A/en
Application granted granted Critical
Publication of CN102382507B publication Critical patent/CN102382507B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses hydrophilic ink for intaglio printing on surfaces of aluminum foils and a preparation method thereof. The hydrophilic ink for intaglio printing on the surfaces of the aluminum foils comprises the following raw materials: by weight, 15 to 30 parts of hydrophilic polyacrylic resin liquid containing 20% to 50% solid materials (solid content for short), 40 to 50 parts of propyl benzene emulsion with solid content 25% to 60%, 10 to 15 parts of hydrophilic polyurethane and acrylate ester composited emulsion with solid content 30% to 58%, 8 to 12 parts of colorant, 1 to 2 parts of dispersant, 0.5 to 1 part of slip agent, 0.5 to 1 part of flatting agent, 1 to 5 parts of hydrophilic wax syrup, 1 to 5 parts of butyl ether, 1 to 5 parts of isopropanol and 1 to 5 parts of deionized water. The hydrophilic ink is faster in drying speed, fine in adhesion, better in water resistance, moisture resistance and friction resistance, and better in after-tack property. Besides, the hydrophilic ink has fine film formation and color retention and better color development for pigments and also has high glossiness.

Description

Be used for water color ink of aluminium foil surface intaglio printing and preparation method thereof
Technical field
The present invention relates to the printing-ink technical field, relate in particular to a kind of water color ink for the aluminium foil surface intaglio printing and preparation method thereof, especially for the aluminium foil of food and drug packaging. ?
Technical background
In recent years, aluminium foil because quality is light, the characteristics such as good, the environmental protection of good leak tightness, covering property, be widely used in a plurality of fields such as food, medicine, aerospace.From 2006, Chinese aluminium foil production capacity, output continued to keep the whole world the first.The aluminium foil market demand increases swift and violent.Within 2008, Chinese aluminium foil output is 1,570,000 tons, accounts for 44% of the whole world.At present, the annual consumption of China aluminium foil amount has become the world's second largest aluminium foil country of consumption that is only second to the U.S..
Grocery trade and pharmacy industry are the staple markets of aluminium foil packing.They are aqueous non-toxics for the requirement of printing-ink, nonpolarity, smooth aluminium foil is had to good sticking power, just the dry time short, the high speed printing that to be suitable for line of travel speed be 60~130 m/mins, printed matter has water resisting property, moisture-proof frictional property and anti-after tackiness preferably.And the rate of drying of existing water color ink, attachment fastness, water resisting property, anti-after tackiness etc. all not have well solution. ?
Summary of the invention
The present invention has made a kind of water color ink for the aluminium foil surface intaglio printing, and its purpose is that the technical indicator that solves existing water color ink is difficult to meet the requirements of problem.
The present invention has adopted following technical scheme:
A kind of water color ink for the aluminium foil surface intaglio printing, it comprises following raw materials according and weight part proportioning thereof:
15~30 parts of the aqueous polyacrylamide acid resin liquid that solid content is 20%~50%;
40~50 parts of the propyl benzene emulsions that solid content is 25%~60%;
Solid content is 10~15 parts of 30%~58% aqueous polyurethane-acrylate composite emulsions;
8~12 parts, colorant;
1~2 part of dispersion agent;
0.5~1 part of surface slip agent;
0.5~1 part of flow agent;
1~5 part, water-based wax slurry;
1~5 part of butyl ether;
1~5 part of Virahol;
1~5 part of deionized water.
The pH value of the described water color ink for the aluminium foil surface intaglio printing is 6.0~9.5.
The described water color ink for the aluminium foil surface intaglio printing, under 20 ℃ with butyl ether with or Virahol with or the viscosity of deionized water adjusting printing ink.
The described water color ink for the aluminium foil surface intaglio printing, its viscosity is 15~40 s.With examining grace 3# cup, record
The described water color ink for the aluminium foil surface intaglio printing, its fineness is less than 20 μ m.
The described water color ink for the aluminium foil surface intaglio printing, its solid content is 20%~30%.
The present invention also provides the preparation method of above-mentioned printing ink, and the preparation method of described food, drug packaging use aluminium foil printing ink comprises the following steps:
Steps A: get the raw materials ready and weighing; Synthesize or purchase above specified various raw materials, and weighing is standby one by one by the weight part indicated;
Step B: grind the preparation standby color paste: aqueous polyacrylamide acid resin liquid, colorant, dispersion agent are stirred in container by formula ratio, drop in iron flask and ground again, the sealing iron flask, insert iron flask on swinging dispersion machine or sand mill and disperse to make standby color paste;
Step C: preparation printing ink: after joining in standby color paste by propyl benzene emulsion, aqueous polyurethane-acrylate composite emulsion, surface slip agent, flow agent, water-based wax slurry, butyl ether, Virahol and deionized water by recipe ratio, the good seal iron flask, be placed in swinging dispersion machine and continue to disperse to make the water color ink product;
Step D: check and packing: after sand milling has disperseed, sampling is done contrast with standard ink swatch, and adjusts its depth of shade, fullness of shade with mill base; Then sampling detects fineness, pH value, viscosity, the solid content all technical of printing ink, qualified rear discharging barrelling, packing warehouse-in.
Add a certain amount of granulated glass sphere to carry out ball milling or carry out sand milling in grinding preparation standby color paste process; And the time of waving dispersion on swinging dispersion machine is 2~3h, make the fineness of mill base be less than 15 μ m.The time that swinging dispersion machine continues to disperse in preparation printing ink makes the process of water color ink product is 30~60min.
Compared with prior art, the present invention has following unusual effect:
The water color ink rate of drying that the present invention makes is very fast, and attachment fastness is good, and water resisting property is better, and better, anti-after tackiness is better in the moisture-proof friction.Just dry time≤15s, attachment fastness >=98%, the metal to-metal contact of China ink layer fallen China ink≤5% 30 times, and the China ink layer is falling China ink >=10%, anti-after tackiness≤5h with 10 left and right of friction after water-wet.Owing to adopting aqueous polyurethane-acrylate composite emulsion and the benzene emulsion binding material of deciding, this printing ink also has following distinguishing feature: 1. film forming properties is good, and tint retention is good, and good to the color developing of pigment, 2. glossiness is high.
The accompanying drawing explanation
Fig. 1 is the method flow diagram for preparing water color ink provided by the invention. ?
Embodiment
For making purpose of the present invention, technical scheme and advantage clearer, clear and definite, referring to embodiment, the present invention is described in more detail.
A kind of water color ink for the aluminium foil surface intaglio printing, it comprises following raw materials according and weight part proportioning thereof: 15~30 parts of the aqueous polyacrylamide acid resin liquid that solid content (abbreviation solid content) is 20%~50%; 40~50 parts of the propyl benzene emulsions of solid content 25%~60%; 10~15 parts of solid content 30%~58% aqueous polyurethane-acrylate composite emulsions; 8~12 parts, colorant; 1~2 part of dispersion agent; 0.5~1 part of surface slip agent; 0.5~1 part of flow agent; 1~5 part, water-based wax slurry; 1~5 part of butyl ether; 1~5 part of Virahol; 1~5 part of deionized water.
The pH value of the described water color ink for the aluminium foil surface intaglio printing is 6.0~9.5.
The described water color ink for the aluminium foil surface intaglio printing, with butyl ether with or Virahol with or the viscosity of deionized water adjusting printing ink.Generally under 20 ℃, debugged.
The described water color ink for the aluminium foil surface intaglio printing, its viscosity is 15~40 s.Embodiment of the present invention employing is examined grace 3# cup and is recorded.
The described water color ink for the aluminium foil surface intaglio printing, its fineness is less than 20 μ m.
The described water color ink for the aluminium foil surface intaglio printing, its solid content is 20%~30%.
Toner or the slurry of the black that selected colouring matter is all kinds of water-baseds, white, redness, orange, yellow, green, cyan, blueness or purple, or their intermediate colors to each other or toner or the slurry of its mixture colors, comprise Lithol Red, bronze red, pink, rose-red, organic yellow, lemon yellow, diarylide yellow, permanent yellow, solid beautiful Huang, gorgeous beauty Huang, phthalocyanine blue, phthalein viridescent, permanent violet, carbon black and titanium dioxide thoroughly.
Slipping agent is amine hydroxybenzene, erucicamide, stearic amide or imperial husky EBS etc.The emulsified olefin that water-based wax slurry is oxidic polyethylene emulsifying wax or chemical modification.The butyl ether that selected solvent is technical grade or SILVER REAGENT and Virahol.
Dispersion agent and flow agent are dispersion agent and the flow agent that general Chemical market all has sale.Dispersion agent comprises the polyamino amidophosphoric acid salt of sodium oleate, carboxylate salt, sulfuric acid, sulfonate, oleyl amine acetate, alkyl quaternary ammonium salts, amino propylamine dioleate, quaternary amine, special modification, the high molecular polymer of the affixture of lipid acid oxyethane, polyethylene glycol type polyvalent alcohol, polyethylenimine derivates, phosphate ester salt type or oily amino oleic acid ester etc.; Flow agent comprises acrylic copolymer flow agent, organosilicon flow agent or fluorocarbon class flow agent.
Referring to Fig. 1, the present invention also provides the preparation method of above-mentioned printing ink, and the preparation method of described food, drug packaging use aluminium foil printing ink comprises the following steps:
Steps A: get the raw materials ready and weighing;
Its concrete operations are: synthesize or purchase above specified various raw materials, and weighing is standby one by one by the weight part indicated.
Step B: grind and prepare mill base: aqueous polyacrylamide acid resin liquid, colorant, dispersion agent are stirred in container by formula ratio, then drop in iron flask and ground, the sealing iron flask, insert iron flask on swinging dispersion machine or sand mill and disperse to make standby color paste.
The present invention adds a certain amount of granulated glass sphere to carry out ball milling or carries out sand milling in iron flask; The time of disperseing on swinging dispersion machine or sand mill is 2~3h, makes the fineness of mill base be less than 15 μ m.
Step C: preparation printing ink: after joining in standby color paste by propyl benzene emulsion, aqueous polyurethane-acrylate composite emulsion, surface slip agent, flow agent, water-based wax slurry, butyl ether, Virahol and deionized water by recipe ratio, the good seal iron flask, be placed in swinging dispersion machine or sand mill and continue to disperse to make the water color ink product.
The time that in the present invention, this step continues to disperse in swinging dispersion machine is 30~60min.
Step D: check and packing: after sand milling has disperseed, sampling is done contrast with standard ink swatch, and adjusts its depth of shade, fullness of shade with mill base; Then sampling detects fineness, pH value, viscosity, the solid content all technical of printing ink, qualified rear discharging barrelling, packing warehouse-in.
With reference to following examples and Comparative Examples, can explain the present invention, but the present invention is not limited to these for example.Now various raw materials and the weight part in formula thereof are listed as follows with 5 embodiment:
5 embodiment that table 1 is listed are followed successively by white (1#), black (2#), red (3#), the basic recipe of yellow (4#) and blue (5#) five kinds of water-based look China inks:
Figure 2011102622621100002DEST_PATH_IMAGE001
table 1 is for the water color ink material proportion (weight part) of aluminium foil
embodiment 1:
15 parts of the water-borne acrylic resin liquid that to take solid content be 20%~50%, 10 parts of white pigments, 1 part of dispersion agent, join in container and stir successively, transfer in the iron flask that carries out ball milling (or sand milling) processing, drop into a certain amount of granulated glass sphere (or steel ball), the sealing iron flask, iron flask is inserted to the upper 2~3h of dispersion of swinging dispersion machine (or sand mill), treat that fineness reaches below 15 μ m, can make standby color paste.
Then the propyl benzene emulsion of 42 part 25%~60%, the aqueous polyurethane-acrylate composite emulsion of 15 part 30%~58%, 3 parts of water-based wax slurries, 0.5 part of flow agent, 0.8 part of surface slip agent, 5 parts of butyl ether, 2 parts of Virahols and 2 parts of deionized waters are joined in above-mentioned standby color paste, good seal iron flask again, be placed in swinging dispersion machine (or sand mill) and continue to disperse 30~60min, can make the water color ink product.Inspection by sampling, its fineness is 18 μ m, viscosity 25 s (25 ℃ are examined grace 3# cup), sticking power 100%(surveys by the frame method), solid content 25.3%, pH=8.5, color is pure white.
embodiment 2:
30 parts of the water-borne acrylic resin liquid that to take solid content be 20%~50%, 8 parts of black pigments, 1.2 parts of dispersion agents, join in container and stir successively, transfer in the iron flask that carries out ball milling (or sand milling) processing, drop into a certain amount of granulated glass sphere (or steel ball), the sealing iron flask, iron flask is inserted to the upper 2~3h of dispersion of swinging dispersion machine (or sand mill), treat that fineness reaches below 15 μ m, can make standby color paste.
Then the propyl benzene emulsion of 45 part 25%~60%, the aqueous polyurethane-acrylate composite emulsion of 10 part 30%~58%, 2 parts of water-based wax slurries, 1 part of flow agent, 0.5 part of surface slip agent, 2 parts of butyl ether, 4 parts of Virahols and 3 parts of deionized waters are joined in above-mentioned standby color paste, good seal iron flask again, be placed in swinging dispersion machine (or sand mill) and continue to disperse 30~60min, can make the water color ink product.Inspection by sampling, its fineness is 20 μ m, viscosity 31 s (25 ℃ are examined grace 3# cup), sticking power 99%(surveys by the frame method), solid content 27.2%, pH=7.8, color is consistent with the black standard specimen.
embodiment 3:
18 parts of the water-borne acrylic resin liquid that to take solid content be 20%~50%, 12 parts of golden red pigment, 1.5 parts of dispersion agents, join in container and stir successively, transfer in the iron flask that carries out ball milling (or sand milling) processing, drop into a certain amount of granulated glass sphere (or steel ball), the sealing iron flask, iron flask is inserted to the upper 2~3h of dispersion of swinging dispersion machine (or sand mill), treat that fineness reaches below 15 μ m, can make standby color paste.
Then 50 parts of 25%~60% propyl benzene emulsions, 30%~58% 14 parts of aqueous polyurethane-acrylate composite emulsions, 4 parts, water-based wax slurry, 0.7 part of flow agent, 1 part of surface slip agent, 4 parts, 3 parts Virahols of butyl ether and 3 parts of deionized waters are joined in above-mentioned standby color paste, good seal iron flask again, be placed in swinging dispersion machine (or sand mill) and continue to disperse 30~60min, can make the water color ink product.Inspection by sampling, its fineness is 16 μ m, viscosity 36 s (25 ℃ are examined grace 3# cup), sticking power 98%(records by the frame method), solid content 29.4%, pH=8.3, color is consistent with standard specimen.
embodiment 4:
26 parts of the water-borne acrylic resin liquid that to take solid content be 20%~50%, 12 parts of water-based lemon yellow pigment, 2 parts of dispersion agents, join in container and stir successively, transfer in the iron flask that carries out ball milling (or sand milling) processing, drop into a certain amount of granulated glass sphere (or steel ball), the sealing iron flask, iron flask is inserted to the upper 2~3h of dispersion of swinging dispersion machine (or sand mill), treat that fineness reaches below 15 μ m, can make standby color paste.
Then the propyl benzene emulsion of 40.5 part 25%~60%, the aqueous polyurethane-acrylate composite emulsion of 12 part 30%~58%, 5 parts of water-based wax slurries, 0.8 part of flow agent, 0.9 part of surface slip agent, 3 parts of butyl ether, 5 parts of Virahols and 1 part of deionized water are joined in above-mentioned standby color paste, good seal iron flask again, be placed in swinging dispersion machine (or sand mill) and continue to disperse 30~60min, can make the water color ink product.Inspection by sampling, its fineness is 16 μ m, viscosity 30 s (25 ℃ are examined grace 3# cup), sticking power 99%(surveys by the frame method), solid content 26.8 %, pH=7.6, color and standard specimen solid colour.
embodiment 5:
Take the water-borne acrylic resin liquid that 23 parts of solid contents are 20%~50%, 10 parts of compound blue pigment through allotment, 1.8 part dispersion agent, join in container and stir successively, transfer in the iron flask that carries out ball milling (or sand milling) processing, drop into a certain amount of granulated glass sphere (or steel ball), the sealing iron flask, iron flask is inserted to the upper 2~3h of dispersion of swinging dispersion machine (or sand mill), treat that fineness reaches below 15 μ m, can make standby color paste.
Then 48 parts of 25%~60% propyl benzene emulsions, 30%~58% 11 parts of aqueous polyurethane-acrylate composite emulsions, 1 part, water-based wax slurry, 0.5 part of flow agent, 1 part of surface slip agent, 1 part, 3 parts Virahols of butyl ether and 5 parts of deionized waters are joined in above-mentioned standby color paste, good seal iron flask again, be placed in swinging dispersion machine (or sand mill) and continue to disperse 30~60min, can make the water color ink product.Inspection by sampling, its fineness is 18 μ m, viscosity 40 s (25 ℃ are examined grace 3# cup), sticking power 100%(records by the frame method), solid content 29.4%, pH=8.3, color conforms to standard specimen.
The technical performance index of water color ink product lists in Table 2.
Figure 2011102622621100002DEST_PATH_IMAGE002
[0042] table 2 is for the water color ink performance index of aluminium foil
The water color ink rate of drying that the present invention makes is very fast, and attachment fastness is good, and water resisting property is better, and better, anti-after tackiness is better in the moisture-proof friction.Just dry time≤15s, attachment fastness >=98%, the metal to-metal contact of China ink layer fallen China ink≤5% 30 times, and the China ink layer is falling China ink >=10%, anti-after tackiness≤5h with 10 left and right of friction after water-wet.Owing to adopting aqueous polyurethane-acrylate composite emulsion and the benzene emulsion binding material of deciding, this printing ink also has following distinguishing feature: 1. film forming properties is good, and tint retention is good, and good to the color developing of pigment, 2. glossiness is high.
Should be understood that, application of the present invention is not limited to above-mentioned giving an example, and for those of ordinary skills, can be improved according to the above description or convert, and all these improvement and conversion all should belong to the protection domain of claims of the present invention.

Claims (7)

1. the water color ink for the aluminium foil surface intaglio printing, it comprises following raw materials according and weight part proportioning thereof:
15~30 parts of polyacrylic resin liquid;
40~50 parts of propyl benzene emulsions;
10~15 parts of aqueous polyurethane-acrylate composite emulsions;
8~12 parts, colorant;
1~2 part of dispersion agent;
0.5~1 part of surface slip agent;
0.5~1 part of flow agent;
1~5 part, water-based wax slurry;
1~5 part of butyl ether;
1~5 part of Virahol;
1~5 part of deionized water;
Described propyl benzene emulsion adopts the semi-continuous emulsion polymerization preparation, and its solid content is 25%~60%; Described aqueous polyurethane-acrylate composite emulsion adopts semicontinuous soap-free emulsion legal system standby, and its solid content is 30%~58%; Described polyacrylic resin liquid is aqueous polyacrylamide acid resin liquid, and its solid content is 20%~50%.
2. the water color ink for the aluminium foil surface intaglio printing claimed in claim 1, is characterized in that, the pH value of water color ink is 6.0~9.5; Viscosity is 15~40s; Fineness is less than 20 μ m; Solid content is 20%~30%.
3. the water color ink for the aluminium foil surface intaglio printing claimed in claim 2, is characterized in that, by the viscosity of butyl ether and/or Virahol and/or deionized water adjusting printing ink.
4. the preparation method of the water color ink for the aluminium foil surface intaglio printing as described as claim 1-3 any one, it comprises the following steps:
A: get the raw materials ready and weighing is standby one by one by formula ratio;
B: grind the preparation standby color paste: aqueous polyacrylamide acid resin liquid 15-30 part, colorant 8-12 part, dispersion agent 1-2 part are stirred in container, drop in iron flask and ground again, the sealing iron flask, insert iron flask on swinging dispersion machine or sand mill and disperse to make standby color paste;
C: preparation printing ink: after joining in standby color paste by propyl benzene emulsion 40-50 part, aqueous polyurethane-acrylate composite emulsion 10-15 part, surface slip agent 0.5-1 part, flow agent 0.5-1 part, water-based wax slurry 1-5 part, butyl ether 1-5 part, Virahol 1-5 part and deionized water 1-5 part, the good seal iron flask, be placed in swinging dispersion machine or sand mill and continue to disperse to make the water color ink product.
5. the preparation method of the water color ink for the aluminium foil surface intaglio printing claimed in claim 4, it is characterized in that, iron flask is inserted on swinging dispersion machine or sand mill and disperseed to make in the process of standby color paste: the time that swinging dispersion machine or sand mill are disperseed is 2~3h, makes the fineness of mill base be less than 15 μ m.
6. the preparation method of the water color ink for the aluminium foil surface intaglio printing claimed in claim 4, is characterized in that, grinds the mode of being ground in preparation standby color paste process to be: in iron flask, add a certain amount of granulated glass sphere to carry out ball milling or carry out sand milling.
7. the preparation method of the water color ink for the aluminium foil surface intaglio printing claimed in claim 4, is characterized in that, in preparation printing ink makes the step of water color ink product, the time of disperseing in swinging dispersion machine is 30~60min.
CN 201110262262 2011-09-06 2011-09-06 Hydrophilic ink for intaglio printing on surfaces of aluminum foils and preparation method thereof Active CN102382507B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201110262262 CN102382507B (en) 2011-09-06 2011-09-06 Hydrophilic ink for intaglio printing on surfaces of aluminum foils and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201110262262 CN102382507B (en) 2011-09-06 2011-09-06 Hydrophilic ink for intaglio printing on surfaces of aluminum foils and preparation method thereof

Publications (2)

Publication Number Publication Date
CN102382507A CN102382507A (en) 2012-03-21
CN102382507B true CN102382507B (en) 2013-12-25

Family

ID=45822368

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 201110262262 Active CN102382507B (en) 2011-09-06 2011-09-06 Hydrophilic ink for intaglio printing on surfaces of aluminum foils and preparation method thereof

Country Status (1)

Country Link
CN (1) CN102382507B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015189639A3 (en) * 2014-06-12 2016-03-24 Fujifilm Speciality Ink Systems Limited Printing ink

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103254689B (en) * 2013-05-31 2014-07-02 苏州凹凸彩印厂 Gravure ink for aluminium foil and preparation method of gravure ink
CN104629523A (en) * 2015-01-22 2015-05-20 阜阳丰成机械有限公司 Rust-proof metal printing ink containing pepper essential oil
CN106433297A (en) * 2016-10-20 2017-02-22 浏阳市源友印务包装有限公司 Waterborne polyurethane plastic ink and preparation method thereof
CN107556815A (en) * 2017-10-19 2018-01-09 区汉女 A kind of water-based printing ink and preparation method thereof
CN108504177A (en) * 2018-04-11 2018-09-07 佛山市顺德区乐从镇盛昌油墨有限公司 A kind of water-base ink for intaglio printing on aluminium foil and preparation method and application
CN109021688B (en) * 2018-07-27 2021-07-16 广东顺德艾司科科技股份有限公司 Environment-friendly water-based printing ink and preparation method thereof
CN109385195A (en) * 2018-10-12 2019-02-26 中山市富日印刷材料有限公司 A kind of environment-friendly water-based bloom gloss oil and preparation method thereof
CN110760221A (en) * 2019-12-12 2020-02-07 惠州德斯坤化工有限公司 Water-based plastic gravure ink and preparation method thereof
CN111363403B (en) * 2020-04-27 2021-12-07 中国印刷科学技术研究院有限公司 Water-based thin film gravure composite ink and preparation method and application thereof
CN115141512B (en) * 2022-08-30 2023-08-29 山东东宇鸿翔装饰材料有限公司 Water-based ink for pre-impregnated paper gravure printing and synthesis process thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1289616C (en) * 2002-10-31 2006-12-13 汕头市金园区东风包装印刷厂有限公司 Aquosity intaglio printing ink and its preparation method
CN101134864A (en) * 2007-10-15 2008-03-05 山西精华科工贸有限公司 Cigarette label high-speed intaglio printing water-based ink
CN101942243A (en) * 2009-07-06 2011-01-12 盛威科比荷卢集团公司 White ink for aqueous intaglio printing

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015189639A3 (en) * 2014-06-12 2016-03-24 Fujifilm Speciality Ink Systems Limited Printing ink
US10076909B2 (en) 2014-06-12 2018-09-18 Fujifilm Specialty Ink Systems Limited Printing ink

Also Published As

Publication number Publication date
CN102382507A (en) 2012-03-21

Similar Documents

Publication Publication Date Title
CN102382507B (en) Hydrophilic ink for intaglio printing on surfaces of aluminum foils and preparation method thereof
CN101679794B (en) Aqueous pigment preparations having nonionic additives on the basis of alyl and vinyl ether
CN101679795B (en) Aqueous pigment preparations comprising anionic additives based on allyl ether and vinyl ether
CN102153909B (en) Water-based ink for plastic table printing
CN107735460B (en) Universal pigment dispersion based on N- alkylated glucamine
CN102964914B (en) Water-based narrow coated paper flexible printing ink and method for preparing same
US20110094412A1 (en) Metal effect pigment with additive
CN102153910B (en) Composite special water-based ink for plastic inner printing
CN108250835B (en) Water-based PET heat shrinkable film plastic printing ink and preparation method thereof
CN101864210A (en) Alcohol-soluble printing ink and preparation method thereof
IE903390A1 (en) Colored metallic pigments
CN103797076A (en) Interference pigment having higher color intensity and method for preparing same
WO1991004293A9 (en) Colored metallic pigments
CN102146245B (en) Lanxiang ultra black automobile refinishing coating and preparation method thereof
CN103572617A (en) Water-based anti-settling non-laminated fluorescent pigment paste
CN105062221A (en) Preparation method for cationic type phthalocyanine or carbon black water-based color paste
CN114836079A (en) High-permeability direct-injection advertising color paste and ink and preparation method thereof
JP4073534B2 (en) Pigment mixtures for intaglio printing inks with improved rheological properties
CN109705654A (en) A kind of printing water ink and preparation method thereof with waterproof effect
CN108373651A (en) A kind of aqueous PE heat shrink films printing ink and preparation method thereof
CN111449988B (en) Iron-based water-based pigment color paste for cosmetics, preparation method of color paste and preparation method of color cosmetic product
CN102485812B (en) Medicinal printing ink and preparation process thereof
CN101353496A (en) Manufacture and new use of transparent fluorescent red ink
WO2022142749A1 (en) High-stability fluorescent color paste and preparation method therefor
CN102702854A (en) Super-weatherable external color water-based ink

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant