CN101716019A - Antistatic antibiotic sock - Google Patents
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- CN101716019A CN101716019A CN200910188965A CN200910188965A CN101716019A CN 101716019 A CN101716019 A CN 101716019A CN 200910188965 A CN200910188965 A CN 200910188965A CN 200910188965 A CN200910188965 A CN 200910188965A CN 101716019 A CN101716019 A CN 101716019A
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Abstract
The invention discloses an antistatic antibiotic sock, which is formed by interweaving 10-70 parts of antibiotic chemical fiber filament, 0.5-5 parts of electrically-conducting filament and 10-70 parts of special section chemical fiber filament by weight. The invention provides an antistatic antibiotic sock having the characteristics of little falling possibility of fiber, excellent antibiotic and electrically-conducting performances and great durability.
Description
Technical field
The present invention relates to a kind of socks, relate in particular to a kind of semiconductor, precise electronic, bioengineering, medical and health, precision instrument, photoelectricity etc. of being used for clean, the antistatic special-purpose antistatic antibiotic sock that the high request industry is arranged.
Background technology
Present antistatic socks, antibiotic socks are mainly used in the commercial market, its anti-microbial property and antistatic property are general, and it is existing antistatic, antibiotic socks contain short fiber more, if the personnel of Clean room dress contains the socks of short fiber composition, wearing footwear, wear socks, take off one's shoes, take off socks, and in the process such as daily purification run, all unavoidably produce coming off of short fiber, overflow and loose, also do not have specialized application now at semiconductor, precise electronic, bioengineering, medical and health, precision instrument, photoelectricity etc. are to cleaning, the antistatic special-purpose antistatic antibiotic sock that the high request industry is arranged.
The antistatic treatment of existing socks mainly adopts following method:
1, by antistatic treatment to the raw material of socks own:
1. by containing macromolecular compound or polymer ionic and the hygroscopicity group form insoluble polymer at fiber surface by crosslinked action conductive layer, their antistatic additive is generally produced by the hydrophily of polyethers, in case ambient humidity is lower, antistatic effect then significantly descends;
2. in fiber-forming polymer, add hydrophilic monomer or polymer, improve hygroscopicity, to obtain antistatic usefulness, though this method washability improves, but for more and more high ESD (anti-electrostatic-discharge) industry requirement, such as according to the requirement among the GB12084-1989, wash 50 times after, be difficult to keep antistatic behaviour down in lower humidity (as 40%RH).
2, by the change on socks structure, the raw material:
1. on socks, be fixed with the strip-shaped conductive thing that connects socks body and the earth, but this kind design has a lot of inconvenience in practical application in industry, the ground connection conductive strips of ining succession on the socks first, in clean industry, the dust proof workshop that hollow sheeting is especially arranged, conductive strips tangle the cavity easily and make personnel Ke Pan during walking, second, the length of conductive strips itself, materials, tolerance all have higher requirements, long such as conductive strips one, personnel's oneself footwear all may slam, the incorrect words of material, conductive strips self also are adsorbed on footwear or trouser legs place, can not play due antistatic effect.
The antibacterial treatment of existing socks mainly adopts following method:
1, by antibacterial treatment to socks itself:
1. adopt organic class antibacterial finishing agent, but the high temperature resistant and poor stability of this antibacterial finishing agent, difficulty is used in the synthetic fibers spinning technique;
2. adopt natural antimicrobial agent, as some lawn plant, mineral, but its major part is serious to the coloured light influence of fabric, and many lawn plant short fibers, mineral grain come off under external force such as friction again easily, can't be applied to the requirement of industries such as semiconductor, electronics, bioengineering, medical and health, precision instrument;
3. adopt the mineral-type antiseptic, though this antiseptic has better heat-resisting, its poor durability, a lot of kinds also contain heavy metal, and the person is brought harm.
2, by the change on the socks raw material:
The raw material of socks itself has used anti-bacterial fibre, blending is made into socks but anti-bacterial fibre is mostly with cotton class short fiber, in addition, also use as bamboo fibre, flaxen fiber etc. and have the fiber of natural antibacterial function as raw material, the problem that exists is: antibacterial efficacy is limited first, second the caducous cause of short fiber can't adapt to industries such as semiconductor that clean demand is arranged, electronics, bioengineering, medical and health, precision instrument.
Summary of the invention
The technical problem to be solved in the present invention is, at the above-mentioned defective of prior art, provides a kind of fiber difficult drop-off, anti-microbial property and the good and permanent antistatic antibiotic sock of electric conductivity.
The technical solution adopted for the present invention to solve the technical problems is: a kind of antistatic antibiotic sock, be to adopt 10~70 parts antibacterial functions chemical fibre long filament, 0.5~5 part conducting function long filament to be woven into socks with 10~70 parts special-shaped chemical-fibres filaments, wherein umber by weight.
Antistatic antibiotic sock preferably adopts 30~50 parts antibacterial functions chemical fibre long filament, 1~2 part conducting function long filament to be woven into socks with 30~50 parts special-shaped chemical-fibres filaments, and wherein umber by weight.
Described antibacterial functions chemical fibre long filament and special-shaped chemical-fibres filaments evenly are woven into socks, at least a portion in the stocking leg of socks, instep portion, rear heel, vola portion, toe section inweaves described conducting function long filament, is interconnected to form network between the electrically conductive filament.
Described special-shaped chemical-fibres filaments is preferably the special-shaped chemical-fibres filaments of moisture absorbing and sweat releasing.
It is modified polyester fiber, the compound cospin fiber of PET/PA bi-component, spinneret orifice fiber, graft copolymer fibre, the surface attachment of hygroscopicity group fiber that hydrophilic compounds is arranged, the fiber that is compounded with cellulose fibre that the special-shaped chemical-fibres filaments of described moisture absorbing and sweat releasing is preferably with the sulfonate radical, by internal layer hydrophobic type long filament and intermediate layer hydrophilic short fiber and the three-decker composite filament of outermost layer hydrophobic type multifilament parcel or multi-layer fiber with capillary effect.
Described antibacterial functions long filament is preferably at least a in co-blended spinning class anti-bacterial fibre, composite spinning class anti-bacterial fibre, the grafting modification class anti-bacterial fibre.
At least a in inorganic antibacterial polyester filament, antibacterial nylon, antibiotic thin special polypropylene fibre silk, aseptic antibacterial dacron, mite-proofing and antimicrobial multifunctional fibre, the antibacterial acrylic fibre spun in the blend that described co-blended spinning class anti-bacterial fibre is preferably silver-containing inorganic zeolite AgION.
Described composite spinning class anti-bacterial fibre is preferably PET/PA bi-component polyster fibre.
Described grafting modification class anti-bacterial fibre is preferably by graft copolymerization and introduces carboxyl, amide groups, hydroxyl or amino modified fibre in the macromolecular structure of fiber.
Described conducting function long filament is preferably at least a in 22D/3F conductive filament, 75D/48F silver plated fiber, the wire.
The present invention's's functional by selecting for use (comprising antistatic behaviour, antibiotic property, washability) antibacterial functions chemical fibre long filament, conducting function long filament, special-shaped chemical-fibres filaments by necessarily becoming socks than column interleaving, make socks reach lasting washable, antistatic, antibacterial functions.The present invention adopts fiber filament to knit socks, and the long fibre difficult drop-off of long filament has at first solved the caducous problem of short fiber.
The present invention evenly inweaves the antiseptic long filament in socks, guaranteed the anti-microbial property of socks, and at least a portion inweaves conductive filament in the stocking leg of socks, rear heel, vola portion, toe section, instep portion, the conductive filament of zones of different interconnects, form a network, conductive filament is derived static by the electric installation of shoes or conduction clothes.
The specific embodiment
The making step of antistatic antibiotic sock:
1, according to the client to antistatic, antibiotic requirement, antistatic antibiotic sock is designed, draws a design;
2,, select raw material and ratio thereof according to designing requirement;
3, utilizing the footwear machine platform to be woven into the socks semi-finished product is stocking leg part, sews up its heel and tiptoe part then; If silk stocking then must be sewed up its heel and tiptoe part again after the stocking leg is pieced together crotch;
4, then socks are embroidered dyed yarn or dyeing processing;
5, at last it is carried out high-temperature shaping and handle, packing.
Following examples all are to adopt above-mentioned making step, and step does not describe in detail in an embodiment one by one.
The raw material that following examples are selected is:
Sulfonate radical is that the modified polyester fiber of hygroscopicity group is the high moisture absorption yarn of dri-release;
The compound cospin fiber of PET/PA bi-component is the secotec fiber;
The spinneret orifice fiber is the coolmax fiber;
Graft copolymer fibre is the fcls-75 fiber;
It is the Ekslive fiber that surface attachment has the fiber of hydrophilic compounds;
The fiber that is compounded with cellulose fibre is a soybean protein composite fibre cellulose fiber;
Three-decker composite filament by internal layer hydrophobic type long filament and intermediate layer hydrophilic short fiber and outermost layer hydrophobic type multifilament parcel is Toyo Rayon CM1011SSC;
Multi-layer fiber with capillary effect is the coolbest fiber;
Described grafting modification class anti-bacterial fibre is the synthetic fibre SS-N of SED.
Embodiment 1, a kind of antistatic antibiotic sock, adopting the blend of 10 parts 100D/36F silver-containing inorganic zeolite AgION to spin inorganic antibacterial polyester filament, 5 parts 22D/3F conductive filament and 70 parts the special-shaped polyester filament of 75D/34F Coolmax is raw material (umber by weight), wherein, the inorganic antibacterial polyester filament is spun in the blend of 100D/36F silver-containing inorganic zeolite AgION and the special-shaped polyester filament of 75D/34F Coolmax evenly is woven into socks, the 22D/3F conductive filament evenly inweaves the stocking leg, vola portion two parts form network, and this two parts network also is electrically connected by the 22D/3F conductive filament.
Embodiment 2, a kind of antistatic antibiotic sock, adopting 70 parts 75D/36F antibacterial nylon, 2 parts copper wire (75D) and 10 parts spandex is raw material (umber by weight), wherein, 75D/36F antibacterial nylon and spandex evenly are woven into socks, the copper wire evenly inweaves the stocking leg, toe section, vola portion three parts formation network, and this three part also is communicated with by the 22D/3F conductive filament.
Embodiment 3, a kind of antistatic antibiotic sock, adopting 30 parts antibiotic thin special polypropylene fibre silk, 1 part 75D/48F silver plated fiber and 50 parts the special-shaped polyester filament of 75D/34F Coolmax is raw material (umber by weight), wherein, the special-shaped polyester filament of antibiotic thin special polypropylene fibre silk and 75D/34F Coolmax evenly is woven into socks, the 75D/48F silver plated fiber evenly inweaves the stocking leg, vola portion two parts form network, and these two parts also are communicated with by the 22D/3F conductive filament.
Embodiment 4, a kind of antistatic antibiotic sock, adopting 50 parts mite-proofing and antimicrobial multifunctional fibre, 2 parts conductive filament and 30 parts the special-shaped polyester filament of 75D/34F Coolmax is raw material (umber by weight), wherein, the special-shaped polyester filament of mite-proofing and antimicrobial multifunctional fibre and 75D/34F Coolmax evenly is woven into socks, the stocking leg, rear heel, vola portion, toe section, instep portion that conductive filament evenly inweaves socks form network, and these two parts also are communicated with by conductive filament.
The mite-proofing and antimicrobial multifunctional fibre: be that anti-mite finishing agent, antiseptic are added in the fibre-forming polymer, the anti-mite fiber of after spinning, making.
Embodiment 5, a kind of antistatic antibiotic sock, adopting 25 parts antibacterial acrylic fibre, 0.5 part conductive filament and 40 parts the special-shaped polyester filament of 75D/34F Coolmax is raw material (umber by weight), wherein, the special-shaped polyester filament of antibacterial acrylic fibre and 75D/34F Coolmax evenly is woven into socks, conductive filament evenly inweaves the stocking leg, vola portion two parts form network, and these two parts also are communicated with by conductive filament.
Antibacterial acrylic fibre: in the acrylic fibers fabrication stage, with ionic bond metals such as silver are anchored on the bone stone frame that boils, antiseptic is joined mixing spinning in the polyacrylonitrile again, make antiseptic be dispersed in fibrous inside and surface, fiber itself just contains antiseptic like this.This method demonstrates antibacterial action by the antiseptic of antiseptic on the fiber surface and part stripping.
Embodiment 6, a kind of antistatic antibiotic sock, adopting 15 parts aseptic antibacterial dacron, 1.5 parts 75D/48F silver plated fiber and 15 parts the high moisture absorption yarn of dri-release is raw material (umber by weight), wherein, aseptic antibacterial dacron and dri-release are high, and the moisture absorption yarn evenly is woven into socks, the 75D/48F silver plated fiber evenly inweaves the stocking leg, vola portion two parts form network, and these two parts also are communicated with by the 22D/3F conductive filament.
Embodiment 7, a kind of antistatic antibiotic sock, adopting 25 parts antibiotic thin special polypropylene fibre silk, 2 parts 75D/48F silver plated fiber and 30 parts secotec fiber is raw material (umber by weight), wherein, antibiotic thin special polypropylene fibre silk and secotec fiber evenly are woven into socks, rear heel, vola portion, toe section three parts that the 75D/48F silver plated fiber evenly inweaves socks form network, and these two parts also are communicated with by the 22D/3F conductive filament.
Embodiment 8, a kind of antistatic antibiotic sock, adopting 60 parts antibacterial nylon, 2.5 parts conductive filament and 28 parts fcls-75 fiber is raw material (umber by weight), wherein, antibacterial nylon and fcls-75 fiber evenly are woven into socks, rear heel, vola portion, toe section, instep portion four parts that conductive filament evenly inweaves socks form network, and these two parts also are communicated with by the 22D/3F conductive filament.
Embodiment 9, a kind of antistatic antibiotic sock, adopting 22 parts antibiotic thin special polypropylene fibre silk, 4.5 parts wire and 65 parts Toyo Rayon CM1011SSC fiber is raw material (umber by weight), wherein, antibiotic thin special polypropylene fibre silk and Toyo Rayon CM1011SSC fiber evenly are woven into socks, wire evenly inweaves rear heel, vola portion two parts form network, and these two parts also are communicated with by the 22D/3F conductive filament.
Embodiment 10, a kind of antistatic antibiotic sock, adopting 55 parts antibiotic thin special polypropylene fibre silk, 3 parts 75D/48F silver plated fiber and 45 parts coolbest fiber is raw material (umber by weight), wherein, antibiotic thin special polypropylene fibre silk and coolbest fiber evenly are woven into socks, the 75D/48F silver plated fiber evenly inweaves the stocking leg, vola portion two parts form network, and these two parts also are communicated with by the 22D/3F conductive filament.
Embodiment 11, a kind of antistatic antibiotic sock, adopting 62 parts antibiotic thin special polypropylene fibre silk, 2.8 parts conductive filament and SED's synthetic fibre SS-N fiber of 12 parts is raw material (umber by weight), wherein, antibiotic thin special polypropylene fibre silk and SED's synthetic fibre SS-N fiber evenly are woven into socks, conductive filament evenly inweaves instep portion and forms network, and these two parts also are communicated with by the 22D/3F conductive filament.
Embodiment 12, a kind of antistatic antibiotic sock, adopting 50 parts antibiotic thin special polypropylene fibre silk, 2 parts 75D/48F silver plated fiber and 52 parts soybean protein composite fibre cellulose fiber is raw material (umber by weight), wherein, antibiotic thin special polypropylene fibre silk and soybean protein composite fibre cellulose fiber evenly are woven into socks, the 75D/48F silver plated fiber evenly inweaves vola portion two parts and forms network, and these two parts also are communicated with by the 22D/3F conductive filament.
One, antistatic test: the electric conductivity of the embodiment of the invention and commercially available common antistatic socks is detected according to GB12084-1989 " anti-static clothing national standard ", employed instrument is a 3M-701 sheet resistance tester, test condition is: after 50 washings, under 25 ℃, 45%RH, testing result sees Table 1:
Table 1 electric conductivity test result
Sample | Sheet resistance value (Ω) |
Embodiment 1 | 4.5*10E7 |
Embodiment 2 | 7.2*10E7 |
Embodiment 3 | 6.3*10E7 |
Commercial anti static socks | 10E8-10E9 |
Because resistance value is at zero point during a little Europe, object has just had electric conductivity, but words in that event, our antistatic socks have just become a conductor, when some industries (such as electron trade) are used, human electric shock's danger when contacting with metal object, socks is just arranged, so, in antistatic industry, the human external dressing comprises cap, clothes, shoes, socks etc., general resistance is optimum at 10E6-10E7, the electrostatic charge of human body can promptly be led away in the interval safety of this resistance, and in the table 1, embodiment 1~3 sheet resistance value is all between 10E6~10E7, static can be derived fast, human body safety can be guaranteed again.
Two, antibacterial tests: according to AATCC100-2004 " evaluation of textile material antibacterial finishing agent ", wherein AATCC (American Association of Textile Chemists and Colorists) is dying of U.S. textile product Shi Xiehui, and the antibiotic property of the embodiment of the invention 1~12 and commercially available common antistatic socks is detected.
Testing conditions: under the ambient temperature and moisture normal pressure, antibacterial antistatic socks and commercially available common antistatic socks are washed (washing methods is with reference to GB12014-1989) simultaneously 50 times, test its antibiotic property after drying again.
Detecting instrument:
1. spectrophotometer detects wavelength 660nm;
2. constant incubator, temperature can remain on 37 ℃ ± 2 ℃;
3. water-bath, temperature can remain on 45 ℃ ± 2 ℃;
4. the flat speed of constant temperature is shaken a bottle cabinet;
5. high-pressure sterilizing pot, 101 ℃ of temperature, pressure 103Kpa;
6. vial, flat cylinder, the 30ml capacity, with cover;
7. glass or poly-stupid ethene plate, diameter 90mm-100mm or 55mm-60mm;
8. spiral vortex type oscillator;
9. two stage biological safety cabinet;
10. vessel are used in laboratory such as test tube, flask always
Testing result is as shown in table 2:
Table 2 antibiotic property test result
Test microbes | Clump count cfu/ ware on " 0 " style time of contact | Regularly cultivate the clump count cfu/ ware on the style | " 0 " tester time of contact clump count cfu/ ware | Clump count cfu/ ware on the regular tester of cultivating | Bacterium reduces percentage (%) |
ETEC Escherichia coil ATCC 25922 | ??2.4*10E5/2.6*10E5 | ??<100/3.7*10E6 | ?2.4*10E5 | ??7.1*10E6 | ??>99.96/0 |
Staphylococcus aureus Staphylococ uus aureus ATCC6358 | ??1.6*10E5/1.7*10E5 | ??<100/9.1*10E5 | ?1.7*10E5 | ??8.2*10E5 | ??>99.94/0 |
Candida albicans Candia alibicans ATCC 10231 | ??1.6*10E5/1.8*10E5 | ??<100/2.5*10E6 | ?1.7*10E5 | ??6.2*10E5 | ??>99.94/0 |
Pseudomonas aeruginosa Pseudomona s aeruginosa ATCC9027 | ??1.8*10E5/1.7*10E5 | ??<100/2.9*10E6 | ?1.9*10E5 | ??8.4*10E6 | ??>99.94/0 |
Three, BA: the present invention has anti-microbial property except itself, also has sterilizing function simultaneously, below is BA of the present invention:
1, bacterium is used in experiment: staphylococcus aureus, Friedlander, Escherichia coli;
2, the preparation of experimental bacteria liquid: the activation of freezing bacillus will be frozen bacillus and be melted in the nutrient broth that is dispersed in 5ml or become suspension, cultivate 18h-24h down at 37 ℃ ± 2 ℃, getting bacteria suspension with oese is inoculated on the agar culture plate with method of scoring, cultivate 18h-24h down at 37 ℃ ± 2 ℃, get colonies typical from culture dish and be seeded in the agar medium slant tube, cultivate 18h-24h down at 37 ℃ ± 2 ℃.Slant tube is stored in the refrigerator, and under 5 ℃-10 ℃, as preserving bacterium, storage life is no more than one month, goes down to posterity once in every month, and passage number was no more than for 10 generations.
3, the preparation of test organisms liquid:
1), go bail for oese and to deposit bacterium, be inoculated on the agar culture plate with method of scoring, cultivate 24h down at 37 ℃ ± 2 ℃.This plate is preserved a week down at 5 ℃-10 ℃.
2), get the conical flask that nutrient broth 20ml puts into 100ml, get colonies typical on the 7.2.1 plate with oese and be seeded in the meat soup and cultivate, condition of culture is: 37 ℃ ± 2 ℃, 110 times/min of vibration frequency, time 18h-24h.
3), with 20 times of distilled water dilution nutrient broth, be 1*10E8CFU/ml-5*10E8CFU/ml with its bacteria concentration of regulating after cultivating, as test organisms liquid, adopt spectrophotometer or proper method to measure bacterial concentration.Ice-cold 3 ℃-4 ℃ of this experimental liquid uses in 4h.
4, the preparation of sample:
1), sample: the sample from the embodiment of the invention 1~12 is chosen representational style, every kind of 4 of bacterial classification test (positive 2,2 of reverse side)
Circular specimen, diameter are 25mm ± 5mm, and this sample is not sterilized.
2), in the same old way: get the identical but material that do not pass through antibiotic finish of 1 sample material sample in contrast, size is identical with sample, if do not have, then without any processing.
5, step:
1) prepares lower floor's aseptic culture medium.In aseptic plate, pour into the 10ml agar medium, and it is condensed.
2) prepare the upper strata aseptic culture medium.The agar medium 150ml that gets 45 ℃ ± 2 ℃ puts into flask, adds 1ml test organisms liquid, and the vibration flask is evenly distributed bacterium, upwards pours into 5ml in each plate in the step, and it is condensed, and the agar of inoculating used in 1 hour.
3) with aseptic nipper with sample with to be put in plate central authorities respectively in the same old way, equably by being pressed on the agar medium, contact well between sample and agar medium.
4) after being placed on sample on the agar medium, putting into 37 ℃ ± 2 ℃ incubator immediately and cultivate 18h-24h, guarantee that sample and agar medium keep in touch in the whole culture period.
Concrete outcome sees Table 3:
Table 3 sterilization test result
Sample | Sterilizing rate (%) |
Embodiment 3 | 99.97 |
Embodiment 4 | 99.98 |
Embodiment 5 | 99.97 |
Commercial anti static socks | 0 |
To sum up; antibacterial antistatic socks of the present invention; more common commercially available antistatic socks are in the durable antibacterial performance contrast; the advantage that highly significant is arranged; be suitable for industries such as precise electronic, semiconductor, bio-pharmaceuticals, Aero-Space; also be applicable to civilianly, human body is had rapid dissipate it lotus, antibiotic protection and the double effects of health care.
Claims (10)
1. an antistatic antibiotic sock is characterized in that, is to adopt 10~70 parts antibacterial functions chemical fibre long filament, 0.5~5 part conducting function long filament to be woven into socks with 10~70 parts special-shaped chemical-fibres filaments, and wherein umber by weight.
2. antistatic antibiotic sock according to claim 1 is characterized in that, is to adopt 30~50 parts antibacterial functions chemical fibre long filament, 1~2 part conducting function long filament to be woven into socks with 30~50 parts special-shaped chemical-fibres filaments, and wherein umber by weight.
3. antistatic antibiotic sock according to claim 2, it is characterized in that, described antibacterial functions chemical fibre long filament and special-shaped chemical-fibres filaments evenly are woven into socks, at least a portion in the stocking leg of socks, instep portion, rear heel, vola portion, toe section inweaves described conducting function long filament, is interconnected to form network between the electrically conductive filament.
4. according to any described antistatic antibiotic sock of claim 1~3, it is characterized in that described special-shaped chemical-fibres filaments is the special-shaped chemical-fibres filaments of moisture absorbing and sweat releasing.
5. antistatic antibiotic sock according to claim 4, it is characterized in that the special-shaped chemical-fibres filaments of described moisture absorbing and sweat releasing is three-decker composite filament that is modified polyester fiber, the compound cospin fiber of PET/PA bi-component, spinneret orifice fiber, graft copolymer fibre, the surface attachment of hygroscopicity group fiber that hydrophilic compounds is arranged, the fiber that is compounded with cellulose fibre with the sulfonate radical, is wrapped up by internal layer hydrophobic type long filament and intermediate layer hydrophilic short fiber and outermost layer hydrophobic type multifilament or the multi-layer fiber with capillary effect.
6. antistatic antibiotic sock according to claim 5 is characterized in that, described antibacterial functions long filament is at least a in co-blended spinning class anti-bacterial fibre, composite spinning class anti-bacterial fibre, the grafting modification class anti-bacterial fibre.
7. antistatic antibiotic sock according to claim 6, it is characterized in that at least a in inorganic antibacterial polyester filament, antibacterial nylon, antibiotic thin special polypropylene fibre silk, aseptic antibacterial dacron, mite-proofing and antimicrobial multifunctional fibre, the antibacterial acrylic fibre spun in the blend that described co-blended spinning class anti-bacterial fibre is silver-containing inorganic zeolite AgION.
8. antistatic antibiotic sock according to claim 6 is characterized in that, described composite spinning class anti-bacterial fibre is a PET/PA bi-component polyster fibre.
9. antistatic antibiotic sock according to claim 6 is characterized in that, described grafting modification class anti-bacterial fibre is for introducing carboxyl, amide groups, hydroxyl or amino modified fibre in the macromolecular structure of fiber by graft copolymerization.
10. according to any described antistatic antibiotic sock of claim 1~3, it is characterized in that described conducting function long filament is at least a in 22D/3F conductive filament, 75D/48F silver plated fiber, the wire.
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CN108391859A (en) * | 2018-04-16 | 2018-08-14 | 海宁市依丽袜业有限公司 | A kind of movement socks |
CN108477680A (en) * | 2018-05-25 | 2018-09-04 | 海宁市红枫针织有限责任公司 | A kind of wear-resisting type sports socks |
CN109554813A (en) * | 2018-11-22 | 2019-04-02 | 际华三五四三针织服饰有限公司 | Antistatic, the antibacterial, thread water absorben perspiring shell fabric made of original liquid coloring fiber |
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