CN101705641A - Wear-resistant decorative paper and production method thereof - Google Patents

Wear-resistant decorative paper and production method thereof Download PDF

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Publication number
CN101705641A
CN101705641A CN200910216266A CN200910216266A CN101705641A CN 101705641 A CN101705641 A CN 101705641A CN 200910216266 A CN200910216266 A CN 200910216266A CN 200910216266 A CN200910216266 A CN 200910216266A CN 101705641 A CN101705641 A CN 101705641A
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paper
wear
alundum
veneer
layer
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CN101705641B (en
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刘一山
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CHENGDU HAOSHI WOODEN Co Ltd
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CHENGDU HAOSHI WOODEN Co Ltd
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Abstract

The invention relates to wear-resistant decorative paper processed and produced by taking decorative paper as veneer paper, and a production method thereof. The wear-resistant decorative paper consists of a base paper layer and a wear-resistant layer. The wear-resistant decorative paper can be produced by either of the following two methods: 1, in the process of dipping the veneer paper in resin, dry aluminum sesquioxide fine particles are uniformly distributed on the surface of the veneer paper by airflow dispersion, mechanical dispersion or other methods, and the aluminum sesquioxide is bonded to the surface of the veneer paper through the function of undried resin or other binder so as to form a wear-resistant layer; and 2, paint prepared from aluminum sesquioxide, chemical substances with bonding function and other chemical reagents is smeared on the surface of the veneer paper by a coating method, and then drying treatment is performed to finish manufacture. The method has the advantages of simple processing-producing course, easy control, high utilization rate of aluminum sesquioxide, and capability of greatly reducing production cost.

Description

A kind of wear-resistant decorative paper and production method thereof
Technical field
The present invention relates to a kind of paper and production method thereof, particularly a kind ofly produce facing paper and production method thereof for veneer paper conversion with anti-wear performance with the facing paper.
Background technology
Wood-based plate also is fiberboard, is to be composited by the fiber base material of sandwich layer and the paper material on surface.The purposes difference of wood-based plate, the structure of base material and the characteristic of surface composite layer also have very big difference.
Laminated flooring is to use one of more wood-based plate, generally all forms by four layer materials are compound, i.e. wearing layer, decorative layer, base material and bottom.Substrate layer is the main part of laminated flooring, and most laminated floorings are to adopt high density fiberboard as base material, because high-density plate has the advantage that many log scales do not have.In laminated flooring, except base material, which floor all is to have the paper of special composition and performance through being processed to form for other.Be decorative layer above the substrate layer, just flower-pattern layer makes the floor have attractive in appearance, durable surface, and waterproof, antiultraviolet and don't fade.This layer paper is called facing paper.Uppermost one deck is a wearing layer, makes the floor have anti-wear performance, and uses for a long time.This layer paper is called abrasion-proof paper.Bottom is a damp-proof layer, can intercept the moisture and the moisture that come from ground, thereby the protection floor is not subjected to the ground moisture effect; Which floor simultaneously because the tension that produces can prevent the ground slab warping, play and top balanced action.So this layer paper also is called balance paper.In laminated flooring, three kinds of paper roles are different, and its composition, structure and performance also have nothing in common with each other.After three kinds of paper are handled through resin impregnation respectively, form laminated flooring with the compound back of fiberboard substrate hot pressing.
Currently used abrasion-proof paper mainly is made up of fiber and alundum (Al, and what wherein play wear-resisting effect is alundum (Al, and is the carrier of alundum (Al by the paper that fiber constituted, and is convenient to following process.By the formed wearing layer of abrasion-proof paper, not only need certain anti-wear performance behind the formation floor, also must have very high transparency simultaneously, just be unlikely to hide decorative layer decorative pattern, pattern.Like this, increased the production difficulty of abrasion-proof paper, increased production cost greatly, its price is also very high.So development has substitute products wear-resisting, decoration function concurrently very high value and market prospects.
Facing paper with anti-wear performance not only can be used for laminated flooring, and there is the wood-based plate of the requirement of anti-wear performance on the surface that also can be used for other types.Wear-resistant decorative paper is used for laminated flooring, is about to abrasion-proof paper used in the current production and facing paper and unites two into one, and replaces two kinds of paper, can simplify the laminated flooring production process like this, also can reduce production costs.
Summary of the invention
It is low that purpose of the present invention promptly provides a kind of production cost, meets the facing paper with anti-wear performance and the method for producing thereof of customer requirements, adopts the wear-resistant decorative paper of this method processing can replace facing paper and abrasion-proof paper.
The present invention mainly comprises structure and two aspects of processing method of wear-resistant decorative paper.
1, the structure of wear-resistant decorative paper
The finished paper wear-resistant decorative paper of processing mainly is made of base paper layer and wearing layer.Base paper layer is the used veneer paper of processing, quantitatively is 80~120gm -2Wearing layer is a processed, and at the alundum (Al layer that basic paper surface forms, it quantitatively is 5~35gm -2
Further technical scheme is that veneer paper is any one in facing paper, titanium white paper, the light gray paper.
2, production method of wear-resisting decorative paper, its technical scheme is that veneer paper is immersed in melmac or the Lauxite, adopt the method for air-flow dispersion or mechanical dispersion, the fine particle of the alundum (Al of drying is dispersed in veneer paper surface, by the solidification behind the resin drying, alundum (Al is bonded in veneer paper surface, forms wearing layer, promptly made wear-resistant decorative paper.
Further technical scheme is that veneer paper is any one in facing paper, titanium white paper, the light gray paper, quantitatively is 80~120gm -2Alundum (Al is a granular solids, and particle diameter is 20~50 μ m.
3, production method of wear-resisting decorative paper, its technical scheme can also be to be modulated into aqueous coating by alundum (Al and adhesive, dispersant with cementation, again with the coating method with paint finishing on the body paper surface, pass through dried again, the formed coating layer of dried coating just has the wearing layer of anti-wear performance, has promptly made wear-resistant decorative paper.
Further technical scheme is that adhesive is a kind of in melmac, Lauxite, polyvinyl alcohol, propyl benzene latex, the styrene-butadiene latex, and dispersant is compound phosphate.
Further technical scheme is that veneer paper is any one in facing paper, titanium white paper, the light gray paper, quantitatively is 80~120gm -2Alundum (Al is a granular solids, and particle diameter is 20~50 μ m.
Further technical scheme is that the method for coating metering is any in air knife, scraper, roll-type or the spraying, adjusts that the alundum (Al scope is 5~45gm in the wearing layer -2
Method among the present invention, the alundum (Al that will have wear-resisting effect is compounded in the surface of facing paper, forms wearing layer, thereby makes facing paper obtain anti-wear performance, and the bonding between alundum (Al and the paper is that the effect by adhesive realizes.
The used veneer paper of processing is veneer paper used in furniture, the Wood-based Panel Production among the present invention, and as facing paper, titanium white paper, light gray paper etc., these paper are used for the veneer paper of wood-based plate.Its type is a lot, have stamp or stamp not, color is white, grey, brown, yellow etc., can select for use according to the appearance requirement of product, these paper have the total characteristic of veneer paper, as absorbability, light resistance, wet strength, covering power etc. except color, pattern difference.The wearing layer main component is the graininess alundum (Al with wear-resisting effect, and the bonding on itself and ply of paper surface is the effect by adhesive, also has a small amount of other to help the chemical substance of process operation in the wearing layer.
The wear-resistant decorative paper that this method is produced has ABRASION RESISTANCE and decoration function, can substitute the long used facing paper and the abrasion-proof paper of wood-based plate sound of present laminated flooring and other types.Simple, the control easily of processing process, and the utilization rate of alundum (Al is very high, so can reduce production costs greatly.
The specific embodiment
Below by embodiment the present invention is carried out concrete description; be necessary to be pointed out that at this present embodiment only is used for the present invention is further specified; can not be interpreted as limiting the scope of the invention, the person skilled in the art in this field can make some nonessential improvement and adjustment according to the content of the invention described above.
Embodiment 1: the method for processing wear-resistant decorative paper in the present embodiment is characterized in that carrying out according to the following steps
A, the dispersant of 100 part of 200 order alundum (Al, 100~500 parts of water and 1~5 part is placed in the agitator, mix 10~20min, the melamine resin that adds 10~30 parts then stirs 5~10min again, and the aqueous mixture of making is coating;
B, in dipping machine equipment, facing paper is carried out impregnation process, the impregnating agent that uses is melamine resin, concentration is 5%~15%, the resin uptake of facing paper is 50~200gm -2, enter again and carry out drying in the baking oven;
C, the paper web behind the dipping among the B is sent into coating machine, evenly cover with paint, lacquer, colour wash, etc. with the coating for preparing among the A and decorating recto, formation 5~35gm -2Coating layer;
D, the paper web that obtains among the C is entered in the drier dry, resin drying makes alundum (Al be fixed;
E, the paper web that obtains among the D is sent in the glue spreader, scribbled a coating melamine formaldehyde resin of alundum (Al, concentration is 5%~15%, and coating weight is 10~100gm -2
F, the paper web among the E is entered in the drier, carry out drying, evaporate the moisture in the resin, behind the resin solidification alundum (Al is bonded in the surface of paper;
G, with the paper web that obtains among the F through cutting, can be made into the wear-resistant decorative paper of different size specification.
Method in the present embodiment is a wet method, and in order to increase the thickness of wearing layer, the step of C, D can repeat once.
Embodiment 2: the method for processing wear-resistant decorative paper in the present embodiment is characterized in that carrying out according to the following steps
A, the dispersant of 100 part of 220 order alundum (Al, 100~500 parts of water and 1~5 part is placed in the agitator, mixes 10~20min, add 10~30 parts Lauxite then, stir 5~10min again, the aqueous mixture of making is coating;
B, in dipping machine equipment, facing paper is carried out impregnation process, the impregnating agent that uses is Lauxite, concentration is 5%~15%, the resin uptake of facing paper is 50~200gm -2, and send into and carry out drying in the baking oven;
C, the paper web behind the dipping among the B is sent into coating machine, evenly cover with paint, lacquer, colour wash, etc. with the coating for preparing among the A and decorating recto, formation 5~45gm -2Coating layer;
D, the paper web that obtains among the C is entered in the drier dry, resin drying makes alundum (Al be fixed;
E, the paper web that obtains among the D is sent in the glue spreader, be stained with a coating melamine formaldehyde resin of alundum (Al, concentration is 5%~15%, and coating weight is 10~100gm -2
F, the paper web among the E is entered in the drier, carry out drying, evaporate the moisture in the resin, behind the resin solidification alundum (Al is bonded in the surface of paper;
G, with the paper web that obtains among the F through cutting, can be made into the wear-resistant decorative paper of different size specification.
Method in the present embodiment is a wet method, and in order to increase the thickness of wearing layer, the step of C, D can repeat once.
Embodiment 3: the method for processing wear-resistant decorative paper in the present embodiment is characterized in that carrying out according to the following steps
A, the dispersant of 100 part of 180 order alundum (Al, 100~500 parts of water and 1~5 part is placed in the agitator, mixes 10~20min, add 10~30 parts Lauxite then, stir 5~10min again, the aqueous mixture of making is coating;
B, in dipping machine equipment, facing paper is carried out impregnation process, the impregnating agent that uses is Lauxite, concentration is 5%~15%, the resin uptake of facing paper is 50~200gm -2
C, coatings formulated among the A is pumped up, be sprayed at by shower nozzle and obtain decorating recto among the B, form 5~45gm -2Coating layer;
D, the paper web that obtains among the C is entered in the drier dry, resin drying makes alundum (Al be fixed;
E, the paper web that obtains among the D is sent in the glue spreader, be stained with a coating melamine formaldehyde resin of alundum (Al, concentration is 5%~15%, and coating weight is 10~100gm -2
F, the paper web among the E is entered in the drier, carry out drying, evaporate the moisture in the resin, behind the resin solidification alundum (Al is bonded in the surface of paper;
G, with the paper web that obtains among the F through cutting, can be made into the wear-resistant decorative paper of different size specification.
Method in the present embodiment is a wet method, and in order to increase the thickness of wearing layer, the step of C, D can repeat once.
Embodiment 4: the method for processing wear-resistant decorative paper in the present embodiment is characterized in that carrying out according to the following steps
A, facing paper is carried out impregnation process, the impregnating agent that uses is melamine resin, and concentration is 5%~15%, and the resin uptake of facing paper is 50~200gm -2
B, the dried particulate alundum (Al is placed in the former feed bin, the outlet at bottom in storehouse is provided with automatics, can accurately control rate of discharge;
The pressure that C, blower fan produce is 0.1~0.5Mpa air flow, mixes with the alundum (Al of bin outlet among the B, and the pressure effect of air disperses alundum (Al, forms mixed airflow;
Mixed airflow among D, the C enters in the tuyere, and the wind nozzle outlet that is stitched shape by bar blows to moistening facing paper surface, dipping back among the A, and undried resin sticks the alchlor particle in the air-flow;
E, the paper web that obtains among the D is entered in the drier dry, resin drying makes alundum (Al be fixed;
F, the paper web that obtains among the E is sent in the glue spreader, be stained with a coating melamine formaldehyde resin of alundum (Al, concentration is 5%~15%, and coating weight is 10~100gm -2
G, the paper web among the F is entered in the drier, carry out drying, evaporate the moisture in the resin, behind the resin solidification alundum (Al is bonded in the surface of paper;
H, with the paper web that obtains among the G through cutting, can be made into the wear-resistant decorative paper of different size specification.
Method in the present embodiment is a dry method.Flow-rate adjustment by alundum (Al among the B, the facing paper translational speed in system is regulated, and alundum (Al in the wearing layer what can be adjusted, and changes the anti-wear performance of product, and its scope is 5~45gm -2If desired, for the amount that increases resin in the product and the thickness of wearing layer, the step of B, C, D, E can repeat once.
Embodiment 5: the method for processing wear-resistant decorative paper in the present embodiment is characterized in that carrying out according to the following steps:
A, facing paper is carried out impregnation process, the impregnating agent that uses is melamine resin, and concentration is 5%~15%, and the resin uptake of facing paper is 50~200gm -2
B, dried particulate alundum (Al are placed in the former feed bin, and the outlet at bottom in storehouse is provided with automatics, can accurately control rate of discharge;
The alundum (Al of discharging among C, the B enters in the dispersion machine of a rotation, through peptizaiton, makes alundum (Al axially evenly distributing at dispersion machine;
D, dispersion machine are installed in the top 20~50mm of paper web, and the alundum (Al particle after disperseing among the C is discharged by the dispersion machine outlet of bar seam shape, relies on the gravity effect, drop to moistening facing paper surface, dipping back among the A;
Facing paper among E, the D enters in the drier, carries out drying, and resin drying makes alundum (Al be fixed;
F, the paper web that obtains among the E is sent in the glue spreader, be stained with a coating melamine formaldehyde resin of alundum (Al, concentration is 5%~15%, and coating weight is 10~100gm -2
G, the paper web among the F is entered in the drier, carry out drying, evaporate the moisture in the resin, behind the resin solidification alundum (Al is bonded in the surface of paper;
H, with the paper web that obtains among the G through cutting, can be made into the wear-resistant decorative paper of different size specification.
Method in the present embodiment is a dry method.Flow-rate adjustment by alundum (Al among the B, the facing paper translational speed in system is regulated, and alundum (Al in the wearing layer what can be adjusted, and changes the anti-wear performance of product, and scope is 5~45gm -2If desired, for the amount that increases resin in the product and the thickness of wearing layer, the step of B, C, D, E can repeat once.
Embodiment 6: the method for processing wear-resistant decorative paper in the present embodiment is characterized in that carrying out according to the following steps
A, facing paper carry out impregnation process, and the impregnating agent that uses is melamine resin, and concentration is 5%~15%, and the resin uptake of facing paper is 50~200gm -2
B, dried particulate alundum (Al are placed in the former feed bin, and the outlet at bottom in storehouse is provided with automatics, can accurately control rate of discharge;
The alundum (Al of discharging among C, the step B falls on the belt conveyer, and its speed can be regulated;
Belt among paper web in D, the steps A and the step C carries alundum (Al and enters between the charged pole plate, paper web is higher than belt 50~300mm, the alundum (Al particle vertically moves upward under electrostatic interaction, be attached on the lower surface of paper web with the collision of moistening paper web lower surface by the resin of bone dry not, form the alundum (Al wearing layer;
E, the paper web that obtains among the D is entered in the drier, carry out drying, evaporate the moisture in the resin, behind the resin solidification alundum (Al is bonded in the surface of paper;
F, the paper web that obtains among the E is sent in the glue spreader, be stained with a coating melamine formaldehyde resin of alundum (Al, concentration is 5%~15%, and coating weight is 10~100gm -2
G, the paper web among the F is entered in the drier, carry out drying, evaporate the moisture in the resin, behind the resin solidification alundum (Al is bonded in the surface of paper;
H, with the paper web that obtains among the G through cutting, can be made into the wear-resistant decorative paper of different size specification.
Method in the present embodiment is a dry method.Flow-rate adjustment by alundum (Al among the B, the facing paper translational speed in system is regulated, also can be by regulating voltage, the frequency between battery lead plate, can adjust what of alundum (Al in the wearing layer, and change the anti-wear performance of product, scope is 5~45gm -2
Embodiment 7: the method for processing wear-resistant decorative paper in the present embodiment is characterized in that carrying out according to the following steps
A, facing paper carry out impregnation process, and the impregnating agent that uses is Lauxite, and concentration is 5%~15%, and the resin uptake of facing paper is 50~200gm -2
B, the dried particulate alundum (Al is placed in the former feed bin, the outlet at bottom in storehouse is provided with automatics, can accurately control rate of discharge;
The pressure that C, blower fan produce is 0.1~0.5Mpa air flow, mixes with the alundum (Al of bin outlet among the B, and the pressure effect of air disperses alundum (Al, forms mixed airflow;
Mixed airflow among D, the C enters in the tuyere, and the wind nozzle outlet that is stitched shape by bar blows to moistening facing paper surface, dipping back among the A, and undried resin sticks the alchlor particle in the air-flow;
Facing paper among E, the D enters in the drier, carries out drying, evaporates moisture in the resin, coheres the alundum (Al particle behind the resin solidification securely;
F, the paper web that obtains among the E is sent in the glue spreader, be stained with a coating melamine formaldehyde resin of alundum (Al, concentration is 5%~15%, and coating weight is 10~100gm -2
G, the paper web among the F is entered in the drier, carry out drying, evaporate the moisture in the resin, behind the resin solidification alundum (Al is bonded in the surface of paper;
H, with the paper web that obtains among the G through cutting, can be made into the wear-resistant decorative paper of different size specification.
Method in the present embodiment is a dry method.Flow-rate adjustment by alundum (Al among the B, the facing paper translational speed in system is regulated, and alundum (Al in the wearing layer what can be adjusted, and changes the anti-wear performance of product, and its scope is 5~45gm -2If desired, for the amount that increases resin in the product and the thickness of wearing layer, the step of B, C, D, E can repeat once.
Embodiment 8: the method for processing wear-resistant decorative paper in the present embodiment is characterized in that carrying out according to the following steps
A, facing paper carry out impregnation process, and the impregnating agent that uses is Lauxite, and concentration is 5%~15%, and the resin uptake of facing paper is 50~200gm -2
B, dried particulate alundum (Al are placed in the former feed bin, and the outlet at bottom in storehouse is provided with automatics, can accurately control rate of discharge;
The alundum (Al of discharging among C, the B enters in the dispersion machine of a rotation, through peptizaiton, makes alundum (Al axially evenly distributing at dispersion machine;
D, dispersion machine are installed in the top 20~50mm of paper web, and the alundum (Al particle after disperseing among the C is discharged by the dispersion machine outlet of bar seam shape, relies on the gravity effect, drop to moistening facing paper surface, dipping back among the A;
Facing paper among E, the D enters in the drier, carries out drying, and resin drying makes alundum (Al be fixed;
F, the paper web that obtains among the E is sent in the glue spreader, be stained with a coating melamine formaldehyde resin of alundum (Al, concentration is 5%~15%, and coating weight is 10~100gm -2
G, the paper web among the F is entered in the drier, carry out drying, evaporate the moisture in the resin, behind the resin solidification alundum (Al is bonded in the surface of paper;
H, with the paper web that obtains among the G through cutting, can be made into the wear-resistant decorative paper of different size specification.
Method in the present embodiment is a dry method.Flow-rate adjustment by alundum (Al among the B, the facing paper translational speed in system is regulated, and alundum (Al in the wearing layer what can be adjusted, and changes the anti-wear performance of product, and scope is 5~45gm -2If desired, for the amount that increases resin in the product and the thickness of wearing layer, the step of C, D, E, F can repeat once.
Embodiment 9: the method for processing wear-resistant decorative paper in the present embodiment is characterized in that carrying out according to the following steps
A, facing paper is sent into impregnation equipment carry out impregnation process, the impregnating agent that uses is Lauxite, and concentration is 5%~15%, and the resin uptake is 50~200gm -2
B, dried particulate alundum (Al are placed in the former feed bin, and the outlet at bottom in storehouse is provided with automatics, can accurately control rate of discharge;
The alundum (Al of discharging among C, the step B falls on the belt conveyer, and its speed can be regulated;
Belt among paper web that obtains in D, the steps A and the step C carries alundum (Al and enters between the pole plate of static electrification, paper web is higher than belt 50~300mm, the alundum (Al particle vertically moves upward under electrostatic interaction, be attached on the lower surface of paper web with the collision of moistening paper web lower surface by the resin of bone dry not, form the alundum (Al wearing layer;
E, the paper web among the D is sent in the drier, carried out drying, evaporate the moisture in the resin, behind the resin solidification alundum (Al is bonded in the surface of paper;
F, the paper web that obtains among the E is sent in the glue spreader, be stained with a coating melamine formaldehyde resin of alundum (Al, concentration is 5%~15%, and coating weight is 10~100gm -2
G, the paper web among the F is entered in the drier, carry out drying, evaporate the moisture in the resin, behind the resin solidification alundum (Al is bonded in the surface of paper;
H, with the paper web that obtains among the G through cutting, can be made into the wear-resistant decorative paper of different size specification.
Method in the present embodiment is a dry method.Flow-rate adjustment by alundum (Al among the B, the facing paper translational speed in system is regulated, also can be by regulating the voltage between battery lead plate, can adjust what of alundum (Al in the wearing layer, and change the anti-wear performance of product, scope is 5~45gm -2

Claims (8)

1. wear-resistant decorative paper is made of base paper layer and wearing layer, it is characterized in that: base paper layer is the used veneer paper of processing, quantitatively is 80~120gm -2Wearing layer is the alundum (Al layer that forms on basic paper surface, quantitatively is 5~35gm -2
2. wear-resistant decorative paper according to claim 1 is characterized in that: described veneer paper is any one in facing paper, titanium white paper, the light gray paper.
3. claim 1 or 2 described production method of wear-resisting decorative paper, it is characterized in that: veneer paper is immersed in melmac or the Lauxite, adopt the method for air-flow dispersion or mechanical dispersion, the fine particle of the alundum (Al of drying is dispersed in veneer paper surface, by the solidification behind the resin drying, alundum (Al is bonded in veneer paper surface, forms wearing layer, promptly made wear-resistant decorative paper.
4. production method of wear-resisting decorative paper according to claim 3 is characterized in that: veneer paper is any one in facing paper, titanium white paper, the light gray paper, quantitatively is 80~120gm -2Alundum (Al is a granular solids, and particle diameter is 20~50 μ m.
5. claim 1 or 2 described production method of wear-resisting decorative paper, it is characterized in that: will be modulated into aqueous coating by alundum (Al and adhesive, dispersant with cementation, again with the coating method with paint finishing on the body paper surface, pass through dried again, the formed coating layer of dried coating just has the wearing layer of anti-wear performance, has promptly made wear-resistant decorative paper.
6. production method of wear-resisting decorative paper according to claim 5 is characterized in that: described adhesive is a kind of in melmac, Lauxite, polyvinyl alcohol, propyl benzene latex, the styrene-butadiene latex, and dispersant is compound phosphate.
7. production method of wear-resisting decorative paper according to claim 5 is characterized in that: veneer paper is any one in facing paper, titanium white paper, the light gray paper, quantitatively is 80~120gm -2Alundum (Al is a granular solids, and particle diameter is 20~50 μ m.
8. production method of wear-resisting decorative paper according to claim 5, it is characterized in that: further technical scheme is that the method for coating metering is any in air knife, scraper, roll-type or the spraying, adjusts that the alundum (Al scope is 5~45gm in the wearing layer -2
CN2009102162669A 2009-11-20 2009-11-20 Production method of wear-resistant decorative paper Expired - Fee Related CN101705641B (en)

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CN106835848A (en) * 2017-03-22 2017-06-13 山东东宇鸿翔装饰材料有限公司 45 grams of preparation methods of facing paper
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CN111455720A (en) * 2020-04-27 2020-07-28 佛山市高明金湘坊装饰材料有限公司 Wear-resistant decorative paper and manufacturing method thereof
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