CN101705042B - Laser information coating for gold stamping - Google Patents
Laser information coating for gold stamping Download PDFInfo
- Publication number
- CN101705042B CN101705042B CN2009101926389A CN200910192638A CN101705042B CN 101705042 B CN101705042 B CN 101705042B CN 2009101926389 A CN2009101926389 A CN 2009101926389A CN 200910192638 A CN200910192638 A CN 200910192638A CN 101705042 B CN101705042 B CN 101705042B
- Authority
- CN
- China
- Prior art keywords
- gold stamping
- percent
- information coating
- coating
- formula rate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention provides a laser information coating for gold stamping, which comprises the following raw material components in percentage by weight: 40 to 50 percent of maleic acid resin, 20 to 30 percent of malamine resin, 5 to 15 percent of butanone, 1 to 5 percent of normal butanol, 1 to 5 percent of dimethylbenzene, 1 to 5 percent of ethylene glycol monobutyl ether acetate and 1 to 2 percent of paratoluenesulfonic acid. The laser information coating for gold stamping solves the problems that thermoplastic acryl series general gold stamping laser information coatings generally used on the market at present have lower temperature resistance and poor solvent resistance, and greatly reduces the loss caused by the shortages of temperature resistance and solvent resistance during the use of customers; and the product has the advantages of high brightness, good toughness, difficult breakage, strong repairability, environment-friendly materials, low cost, simple process and the like, and is suitable for large-scale popularization and application.
Description
Technical field
The invention belongs to paint field, be specifically related to a kind of gold stamping usefulness
and penetrate information coating.
Background technology
In the packages printing industry; Gold stamping radium-shine printing has become a kind of trend of commodity packaging printing; It can bring luxurious, noble, exquisite sensation for commodity; Therefore all can see gold stamping application on many high-grade goods, the printed matter, for example cosmetic package, wine box, wine mark, tobacco bale, catalog, monthly calendar, senior with pen, stationery or the like.
The quality of gold stamping radium-shine printing effect is somewhat dependent upon the quality of laser information coating.The gold stamping laser information coating of using of thermoplasticity acryl series that generally uses on the market at present; Though acryl figure layer has advantages such as high brightness, good toughness, cracky, reparation property be not strong; But this figure layer exists heatproof low; The problem of anti-dissolubility difference exists significant limitation in the lifting of the selection of thermoprint ground and thermoprint speed.Simultaneously, because acrylic production difficulty is big, cost is high, therefore caused the coating cost too high.
One Chinese patent application number: 200810029355.8 disclose a kind of laser transfer coatings and preparation method thereof; Mainly make a kind of laser transfer coatings through reacting by heating by TEB 3K, NSC 20956, vinylformic acid, vinyl acetate, vinyl acetic monomer, propylene glycol monomethyl ether, n-butyl acetate, Lucidol and nitro-cotton; But still exist heatproof on the low side after this coating coating, the problem of poor solvent resistance.
One Chinese patent application number: 200510031854.7 disclose a kind of environmental protection type laser transfer composite aluminium foil paper and preparation technology thereof; Its coating is by water soluble amino resin or water soluble polyurethane resin or water soluble alkyd resin or water-soluble acrylic fat resin or celluosic resin; Add auxiliary agent, colorant, solubility promoter, water, or its arbitrary combination, be modulated into the water-based laser transfer coatings through synthetic, wetting dispersion; But high temperature resistant, performances such as anti-solvent are still not ideal enough.
Summary of the invention
The invention provides a kind of gold stamping usefulness
and penetrate information coating; Solve above-mentioned technological deficiency, had advantages such as high temperature resistant, anti-solvent, high brightness, good toughness, cracky, reparation property be not strong.
In order to achieve the above object, realize through following proposal:
A kind of gold stamping usefulness
is penetrated information coating, is made up of following raw materials by weight percent:
More preferably; A kind of gold stamping usefulness
is penetrated information coating, is made up of following raw materials by weight percent:
More excellent again; A kind of gold stamping usefulness
is penetrated information coating, is made up of following raw materials by weight percent:
A kind of gold stamping usefulness
is penetrated information coating, is processed by following steps:
A, butanone, propyl carbinol, YLENE and ethylene glycol monomethyl ether acetate are added in the agitation vat in regular turn according to above-mentioned formula rate, constant temperature evenly stirs 5～10min for 25～30 ℃;
B, again Malin's acid resin and melamine resin are poured in the agitation vat according to formula rate successively, fully continued stir about 5～10min;
C, according to formula rate tosic acid is added in the agitation vat again; Add while stirring, lasting again stir about 10～15min can obtain gold stamping usefulness
and penetrate information coating after adding.
More excellent; A kind of gold stamping usefulness
is penetrated information coating, is processed by following steps:
A, butanone, propyl carbinol, YLENE and ethylene glycol monomethyl ether acetate are added in the agitation vat in regular turn according to above-mentioned formula rate, constant temperature evenly stirs 8～10min for 28～30 ℃;
B, again Malin's acid resin and melamine resin are poured in the agitation vat according to formula rate successively, fully continued to stir 8～10min;
C, according to formula rate tosic acid is added in the agitation vat again; Add while stirring, lasting again stirring 14～15min can obtain gold stamping usefulness
and penetrate information coating after adding.
The present invention is through combining the successful exploitation of melamine resin at coating formula, and with the technology contrast of existing coated coating, the present invention has following advantage and effect:
1, having solved the thermoplasticity acryl general gold stamping usefulness of generally using on the market at present of series
penetrates information coating and exists heatproof on the low side; The problem of poor solvent resistance; It is not enough and the loss that causes has reduced the production of substandard product to greatly reduce Yin Naiwen and the anti-solvent of client when using.
2, with other laser transfer coatings of tradition compare, product of the present invention has advantages such as high brightness, good toughness, cracky, reparation property be not strong.
3, material environment friendly of the present invention, cost is low, technology is simple, is fit to large-scale promotion application.
Embodiment
Below in conjunction with instance the present invention is done further description, but the present invention is not limited only to this instance:
Embodiment one
The first step: elder generation adds 10 parts of butanone (all components amount to 100 parts, and every part 100 restrains, down together), 5 parts of propyl carbinols, 4 parts of YLENE and 4.5 parts of ethylene glycol monomethyl ether acetates in the agitation vat in regular turn, and constant temperature evenly stirs 8min for 26 ℃;
Second step: again 50 parts of Malin's acid resins and 25 parts of melamine resins are poured in the agitation vat according to formula rate successively, fully continued stir about 10min;
The 3rd step: again 1.5 parts of tosic acid are added in the agitation vat; Add while stirring, continue stir about 12min after adding again and can obtain the liquid coating that gold stamping usefulness
is penetrated information coating.
In order to verify effect of the present invention; Penetrate the liquid coating of information coating with the gold stamping usefulness
of method for preparing; After being coated on PET Electroplating Aluminum film, detecting the baking oven heatproof and can reach 140～150 ℃; The coating back does not have the phenomenon of turning white with its solvent resistance of butanone test; With gold stamping film with the thermoprinting machine thermoprint on ivory board, test tangent plane effect can reach E～H tangent plane, brightness is high; Do from the detection of shape power, from shape power about 2～4 with gold stamping film; Medium layer coated on the aluminium plating film again detect VOC content with meteorological chromatograph, the result is up to standard.
Embodiment two
The first step: elder generation adds 10 parts of butanone (all components amount to 100 parts, and every part 100 restrains, down together), 5 parts of propyl carbinols, 4.8 parts of YLENE and 4.05 parts of ethylene glycol monomethyl ether acetates in the agitation vat in regular turn, and constant temperature evenly stirs 10min for 28 ℃;
Second step: again 45 parts of Malin's acid resins and 30 parts of melamine resins are poured in the agitation vat according to formula rate successively, fully continued stir about 10min;
The 3rd step: again 1.15 parts of tosic acid are added in the agitation vat; Add while stirring, continue stir about 15min after adding again and can obtain the liquid coating that gold stamping usefulness
is penetrated information coating.
In order to verify effect of the present invention; Penetrate the liquid coating of information coating with the gold stamping usefulness
of method for preparing; After being coated on PET Electroplating Aluminum film, detecting the baking oven heatproof and can reach 130～140 ℃; The coating back does not have the phenomenon of turning white with its solvent resistance of butanone test; With gold stamping film with the thermoprinting machine thermoprint on ivory board, test tangent plane effect can reach E～G tangent plane, brightness is high; Do from the detection of shape power, from shape power about 2.5～4 with gold stamping film; Medium layer coated on the aluminium plating film again detect VOC content with meteorological chromatograph, the result is up to standard.
Above content is merely preferred embodiment of the present invention, and for those of ordinary skill in the art, according to thought of the present invention, the part that on embodiment and range of application, all can change, this description should not be construed as limitation of the present invention.
Claims (5)
1. a gold stamping usefulness
is penetrated information coating, it is characterized in that: be made up of following raw materials by weight percent:
2. a kind of gold stamping usefulness according to claim 1
is penetrated information coating, it is characterized in that: be made up of following raw materials by weight percent:
3. penetrate information coating according to claim 1 or the described a kind of gold stamping usefulness of claim 2
, it is characterized in that: form by following raw materials by weight percent:
4. any described a kind of gold stamping usefulness of claim 1-3
is penetrated the preparation method of information coating, it is characterized in that: comprise following preparation process:
A, butanone, propyl carbinol, YLENE and ethylene glycol monomethyl ether acetate are added in the reaction kettle in regular turn according to above-mentioned formula rate, constant temperature evenly stirs 5～10min for 25～30 ℃;
B, again Malin's acid resin and melamine resin are poured in the mixing drum according to formula rate successively, fully continued to stir 5～10min;
C, according to formula rate tosic acid is added in the reaction kettle again; Add while stirring, lasting again stirring 10～15min can obtain gold stamping usefulness
and penetrate information coating after adding.
5. a kind of gold stamping usefulness according to claim 4
is penetrated the preparation method of information coating, it is characterized in that: comprise following preparation process:
A, butanone, propyl carbinol, YLENE and ethylene glycol monomethyl ether acetate are added in the agitation vat in regular turn according to above-mentioned formula rate, constant temperature evenly stirs 8～10min for 28～30 ℃;
B, again Malin's acid resin and melamine resin are poured in the agitation vat according to formula rate successively, fully continued to stir 8～10min;
C, according to formula rate tosic acid is added in the agitation vat again; Add while stirring, lasting again stirring 14～15min can obtain gold stamping usefulness
and penetrate information coating after adding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101926389A CN101705042B (en) | 2009-09-24 | 2009-09-24 | Laser information coating for gold stamping |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101926389A CN101705042B (en) | 2009-09-24 | 2009-09-24 | Laser information coating for gold stamping |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101705042A CN101705042A (en) | 2010-05-12 |
| CN101705042B true CN101705042B (en) | 2012-01-04 |
Family
ID=42375299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009101926389A Expired - Fee Related CN101705042B (en) | 2009-09-24 | 2009-09-24 | Laser information coating for gold stamping |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101705042B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102993967A (en) * | 2012-12-16 | 2013-03-27 | 青岛中科润美润滑材料技术有限公司 | High-temperature-resistant coating |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102358813B (en) * | 2011-07-29 | 2013-09-04 | 湖北联合天诚防伪技术股份有限公司 | Alumite information layer coating with standard heavy metal content |
| CN103287147A (en) * | 2013-06-27 | 2013-09-11 | 上海申永烫金材料有限公司 | Manufacturing method of color-changing electric aluminum hot stamping foil |
| CN103434292A (en) * | 2013-09-06 | 2013-12-11 | 上海申永烫金材料有限公司 | Method for manufacturing anti-counterfeiting color-changeable and transparent stamping foil |
| CN105606768B (en) * | 2015-12-28 | 2018-08-10 | 上海维凯光电新材料有限公司 | Detect the test fluid and test pen of aluminizing transfer paint solvent resistance |
| CN112606588A (en) * | 2021-01-17 | 2021-04-06 | 彭亮 | Optical color-changing gold stamping material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1103419A (en) * | 1993-11-30 | 1995-06-07 | 广州市白云区白云精细化工研究所 | Method for producing fast low-temp. setting baking finish of acrylate resin without benzene toxicity |
| CN101270258A (en) * | 2008-03-14 | 2008-09-24 | 天津大田包装容器有限公司 | Steel drum paint special for baking type alcohol acid amido and method of preparing the same |
| CN101402804A (en) * | 2008-09-02 | 2009-04-08 | 东莞光群雷射科技有限公司 | Information coating formula without plate seam |
-
2009
- 2009-09-24 CN CN2009101926389A patent/CN101705042B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1103419A (en) * | 1993-11-30 | 1995-06-07 | 广州市白云区白云精细化工研究所 | Method for producing fast low-temp. setting baking finish of acrylate resin without benzene toxicity |
| CN101270258A (en) * | 2008-03-14 | 2008-09-24 | 天津大田包装容器有限公司 | Steel drum paint special for baking type alcohol acid amido and method of preparing the same |
| CN101402804A (en) * | 2008-09-02 | 2009-04-08 | 东莞光群雷射科技有限公司 | Information coating formula without plate seam |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102993967A (en) * | 2012-12-16 | 2013-03-27 | 青岛中科润美润滑材料技术有限公司 | High-temperature-resistant coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101705042A (en) | 2010-05-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101705042B (en) | Laser information coating for gold stamping | |
| CN102643588B (en) | Holographic laser cold-turning gold stamping transfer coating composition and preparation method thereof | |
| CN102964914B (en) | Water-based narrow coated paper flexible printing ink and method for preparing same | |
| CN104073103A (en) | Thermal sublimation transferring-printing coating pulp and method for carrying out thermal sublimation transferring-printing by using same | |
| JP2012214674A (en) | Quick-drying and coat layer-unnecessary inkjet ink composition | |
| CN104845446A (en) | High-weather-resistance printing ink, as well as preparation method and application thereof | |
| CN102643585A (en) | Laser electrolytic aluminum coating composition and preparation method thereof | |
| US11945951B2 (en) | Formulation and its use as defoamer | |
| EP3668933B1 (en) | Water-based inks with high renewable content | |
| CN106752338B (en) | A kind of water-soluble ink for screen printing and preparation method thereof | |
| CN105925085A (en) | Water-based coloring layer coating for transfer film and preparation method of water-based coloring layer coating | |
| CN105555883B (en) | Polyvinyl chloride-based timber-used ink jet printing metal ink composition | |
| CN105419485A (en) | Anti-counterfeiting aqueous irreversible thermochromic printing ink and preparation method therefor | |
| CN106046940A (en) | Environment-friendly inkjet printing ink composition for common printing media and raw wallpaper, as well as preparation method and application thereof | |
| CN101981144A (en) | Printing ink composition for seamless can | |
| CN105647310B (en) | A kind of PVC base bottom-coating composition and preparation method thereof | |
| CN105542601A (en) | Release-color coat two-in-one transfer coating and preparation method and application thereof | |
| CN103343482A (en) | Environment-friendly electron beam cured gold surface coating used for aluminized paperboard and preparation method thereof | |
| CN108368371A (en) | Including the coating or printing ink composition of starch derivatives, its purposes and the substrate for including the composition | |
| CN102816490A (en) | Holographic transfer single coating material and its preparation method | |
| CN102702860B (en) | Ink-jet pigment ink composition and application thereof | |
| CN110028809A (en) | A kind of water-based ink of PVC coloured silk film easily disperses blue pigment and preparation method | |
| CN101654574A (en) | Macromolecule metallic printing ink with hot-melt transfer function | |
| CN101851448B (en) | High-resolution code-spraying printing ink and preparation process thereof | |
| CN110804338A (en) | Blue pigment for water-based ink and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120104 Termination date: 20170924 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |