CN101705028A - Black ink composition for inkjet - Google Patents
Black ink composition for inkjet Download PDFInfo
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- CN101705028A CN101705028A CN 200910228091 CN200910228091A CN101705028A CN 101705028 A CN101705028 A CN 101705028A CN 200910228091 CN200910228091 CN 200910228091 CN 200910228091 A CN200910228091 A CN 200910228091A CN 101705028 A CN101705028 A CN 101705028A
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- black
- pigment
- dispersion
- dispersion liquid
- ink composition
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Abstract
The invention discloses a black ink composition, comprising dispersion solution, moisturizing agent, surfactant and deionized water, wherein, the dispersion solution is prepared by grinding colorant, dispersing agent, deionized water and other assistants, and is characterized in that the colorant at least contains black pigment C.I.P.B.7 and blue pigment C.I.Pigment Blue 61, the weight ratio of which ranges from 20:1 to 2:1. The black ink composition of the invention has the advantage that a* is less than 0 and b* is less than 0 when L* value is 50-60 in an L*a*b* colormetric system of the ink stipulated by CIE, so that the black and gray printed by the ink can not be inclined to be red, the color is neutral and the printing effect is good.
Description
(1) technical field:
The present invention relates to a kind of black ink, particularly a kind of black ink composition that is used for the ink-jet field and preparation method thereof.
(2) background introduction:
L
*a
*b
*Be the color space of human vision, it according to be the vision exclusivity principle, promptly identical amount of movement causes chromatic change to feel at eyes to be the same, to be uniform color space in color space.L
*, a
*And b
*All parameters that can see, L are described in expression
*The brightness of expression tone, a
*And b
*Expression colourity, a
*And b
*Can represent on the occasion of and negative value.A kind of a of tone
*It is red or green that part is described it, a
*Red partially for just representing, a
*For negative indication green partially; b
*Part shows that it is yellow or blue, b
*For just representing inclined to one side Huang, b
*For negative indication blue partially, if a
*, b
*All go to zero, show color neutrality.
Use the photosensitive silve halide material processing, bright in luster, the image transition nature.In order to reach the imaging effect identical with photosensitive silve halide material, ink-jet printer needs different black inks.Natural in this wherein light black image transition that can make, the black color range scope that can improve colour density and increase black of photo.The used tinting material of spray ink Printing black ink generally adopts charcoal blacks.Though carbon black is all deceived as the black pigment color, carbon black was red phase when the particle size carbon black grinding was very little, because carbon black has this shortcoming: black was red partially when particularly lower concentration was printed when printing, and the ruddiness phenomenon clearly.In order to eliminate red phase, available blue pigments is done the complementary color agent.These some patent documentations there is report.
U.S. Pat 6565202 has been introduced a kind of dispersion liquid by black ink and C.I.Pigment Blue 60 and has been mixed in proportion the black ink composition that forms.The ratio of black pigment and blue pigments is about 1.7: 1 in this composition for ink, and the proportion of blue pigments is excessive like this, and it is low excessively to be easy to occur the serious colour density blue partially and black of black like this when image print.When testing, our company finds to work as L
*The ratio of value black pigment and blue pigments between 50～60 time from 20: 1 to 20: 2 o'clock colour density can reduce to 0.58 from 0.62.Also have the excessive cost that also can cause of addition of blue pigments too high.
U.S. Pat 7503968 has been introduced a kind of black ink composition that contains carbon black, phthalocyanine pigment and benzimidazolone pigment.The shared weight percent of black pigment, phthalocyanine pigment and benzimidazolone pigment is respectively 0.172～0.287 in this composition for ink, and 0.041～0.069 and 0.032～0.054.Like this owing to the existence of benzimidazolone pigment is arranged, a of CIE regulation
*Value is all the time greater than 0, so this ink printed output back black and grey color part are red partially.
(3) summary of the invention:
The present invention relates to a kind of black ink, particularly a kind of black ink composition that is used for the ink-jet field, when using this ink printed black document, color lump or image, the black part is not red partially, and it is neutral that color is.
Technical scheme of the present invention: a kind of black ink composition, comprise dispersion liquid, wetting Agent for Printing Inks, tensio-active agent and deionized water, wherein dispersion liquid grinds the preparation gained by tinting material, dispersion agent, deionized water and other auxiliary agent, it is characterized in that said tinting material contains black pigment C.I.P.B.7 and blue pigments C.I.Pigment Blue 61 at least, wherein the part by weight of black pigment C.I.P.B.7 and blue pigments C.I.Pigment Blue 61 is between 20: 1 to 2: 1.
Between preferred 10: 1 to 20: 3 of the part by weight of above-mentioned said black pigment C.I.P.B.7 and blue pigments C.I.Pigment Blue 61.
The weight percent that above-mentioned said black pigment C.I.P.B.7 accounts for whole ink is 1～10%.
Above-mentioned said black pigment is selected for use following wherein a kind of: Mongul-L, REGAL 400R, Monarch 1300, Monarch 900, the REGAL 330R of Cabot (Cabot) company; MA-7, MA100, the MA40 of Mitsubishi Chemical Ind (Mitsubishi Chemical Corporation); The Special black 4 of goldschmidt chemical corporation (Degussa); Raven 3500, Raven1255, the Raven 3600ultra of Columbian Chemicals Co. (Columbian Chemical).
Above-mentioned said dispersion agent can be selected the EDPLAN 482 of bright icepro (Munzing Chemie Gmbh) company for use.
Above-mentioned said wetting Agent for Printing Inks can be selected Virahol, N-N-methyl-2-2-pyrrolidone N-, 2-pyrrolidone, ethylene glycol ethyl ether, butyl glycol ether, diethylene glycol ether, Diethylene Glycol butyl ether, triethylene glycol butyl ether, propylene glycol butyl ether and dipropylene glycol butyl ether, glycerol, ethylene glycol, Diethylene Glycol, triethylene glycol, TriMethylolPropane(TMP), 1 for use, 2-propylene glycol, 1, ammediol, 1,4-butyleneglycol, 1,5-pentanediol, 1,2-hexylene glycol, 1,2, at least a in 6-hexanetriol, poly(oxyethylene glycol) 400, the Polyethylene Glycol-600.
Above-mentioned said auxiliary agent comprises pH regulator agent and sterilant.Wherein the pH regulator agent can be selected trolamine for use; Sterilant can be selected the Nipacide BIT-20 of Clariant company (Clariant) for use.
Above-mentioned said tensio-active agent can be selected the product Surfynol465 of air chemical company (Air Products) and among the Surfynol 485 any one for use.
A kind of preparation method of black ink composition is characterized in that comprising the preparation of dispersion liquid and the preparation of ink, wherein:
(1) preparation of dispersion liquid may further comprise the steps:
1. dispersion agent and deionized water proportionally are mixed in the container, and stir;
2. add black pigment and blue pigments in proportion, fully wetting;
3. with high-speed shearing machine with the 2. dispersion liquid high speed shear 0.5～8 hour of gained of step, rotating speed is 1000～10000rpm, shears and finishes back placement 10～20 minutes;
4. with step 3. the shearing dispersion liquid of gained pump into and grind dispersion in the shredder;
5. the 4. middle shredder discharge port gained dispersion liquid of step is entered the stock chest of shredder, pump into shredder once more and carried out circular grinding 0.5～24 hour;
6. in the process of lapping, carried out granularity Detection every 15 minutes, reach requirement, obtain dispersion liquid up to the particle diameter of dispersion liquid.
Step is 1.-3. for shearing dispersion steps, and wherein mainly to act on be to make the dispersion agent dispersion and emulsion even to the high speed shear of step in 3., smash in the part black pigment than macroparticle, the preferred 1-2 of shear time hour; Above-mentioned steps is 4.-6. for grinding dispersion steps; Wherein the shredder of step in 4. is pin bar type shredder, and rotating speed is 600～4200rpm, and it is the zirconium oxide bead of 0.05～1mm that grinding medium adopts diameter, between preferred diameter 0.05～0.2mm; The grinding purposes of said step in 4. is to make the black nano-water dispersible pigment dispersion particle diameter continue to reduce the preferred 1-2 of milling time hour; The temperature of the discharge port of said step in 5. is controlled between 20～40 ℃; 6. said step is the pigment granularity Detection, and particle diameter requires D
50About 100nm.。
(2) preparation of ink may further comprise the steps:
Get the 6. prepared dispersion liquid 50% of above-mentioned steps by weight percentage, other adds 2-pyrrolidone 4%, ethylene glycol 3%, 1,2-propylene glycol 3%, 1,2-hexylene glycol 6%, Surfynol 4651.2%, trolamine 0.2%, sterilant and surplus deionized water are made composition for ink.
Annotate: D
50: the cumulative particle sizes volume of distribution percentage ratio of a sample reaches 50% o'clock pairing particle diameter.
Superiority of the present invention and technique effect are: this ink is at the L of CIE regulation
*a
*b
*Work as L in the colorimeter system
*Value is between 50～60 the time, a
*＜0, b
*＜0. such this ink printed is come out black and grey can be not red partially, and it is neutral that color is, and printing effect is good.
(4) embodiment:
The color assessment:
The technique effect of estimating ink of the present invention adopts CIE (Commission Internationale deL ' Eclairage; The world luminouslighting council) formulates the international standard of measuring color, colour is measured.CIE has formulated L
*, a
*And b
*Value is measured colour, and this measuring method is called CIELAB.L
*Representing lightness, from bright (this moment L
*=100) to dark (this moment L
*=0) changes between.a
*The value representation color is from green (a
*) to red (+a
*) between change and b
*The value representation color is from yellow (+b
*) to blue (b
*) between change.
The composition for ink that embodiment 1～3 and comparative example 1～3 the described print cartridge of packing into, put into ink-jet printer Stylus Photo R230 (Seiko Epson Corporation's system) and on the quartzy photo papers in Lekai, print specimen page with 1440*720dpi, Eye-one Pro with X. Rite Inc.'s system passes through at light source D50, angle of visibility 2 degree are worked as L down
*Value is measured a between 50～60 the time
*, b
*Value.
" part " among the embodiment by weight.
The prescription of each embodiment of table 1 and comparative example (unit: part, the weight meter)
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | |
| The 2-pyrrolidone | ??4 | ??4 | ??4 | ??4 | ??4 | ??4 |
| Ethylene glycol | ??3 | ??3 | ??3 | ??3 | ??3 | ??3 |
| 1, the 2-propylene glycol | ??3 | ??3 | ??3 | ??3 | ??3 | ??3 |
| 1, the 2-hexylene glycol | ??6 | ??6 | ??6 | ??6 | ??6 | ??6 |
| ??Surfynol?465 | ??1.2 | ??1.2 | ??1.2 | ??1.2 | ??1.2 | ??1.2 |
| ??Nipacide?BIT-20 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 |
| Trolamine | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 |
| ??EDAPLAN?482 | ??4 | ??4 | ??4 | ??4 | ??4 | ??4 |
| Water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus |
| ??Carbon?black | ??4 | ??4 | ??4 | ??4 | ??4 | ??4 |
| ??C.I.Pigment?Blue?61 | ??0.2 | ??0.4 | ??0.6 |
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | |
| ??C.I.Pigment?Blue?15:3 | ??0.4 | |||||
| ??C.I.Pigment?Blue?15:4 | ??0.4 |
Preceding 8 identical components tabulation of table 23 embodiment
| Numbering | Composition | Proportion |
| ??1 | The 2-pyrrolidone | ??4 |
| ??2 | Ethylene glycol | ??3 |
| ??3 | 1, the 2-propylene glycol | ??3 |
| ??4 | 1, the 2-hexylene glycol | ??6 |
| ??5 | ??Surfynol?465 | ??1.2 |
| ??6 | ??Nipacide?BIT-20 | ??0.2 |
| ??7 | Trolamine | ??0.2 |
| ??8 | ??EDAPLAN?482 | ??4 |
Embodiment 1
See Table 1, at first make dispersion liquid, wherein with the black pigment MA-7 of 8 parts of Mitsubishi Chemicals (Mitsubishi ChemicalCorporation), 0.4 the blue pigments Alkali Blue D6101 (C.I.Pigment Blue 61) of part BASF (BASF), the EDPLAN482 of 8 parts of bright icepros (Munzing Chemie Gmbh) company, its active constituent content 85% and 83.6 parts of deionized waters mix with the high speed shear agitator must shear dispersion liquid in 1 hour after evenly, shearing dispersion liquid to 300g ground 1 hour in 0.14L volumetrical shredder again, obtained water dispersible pigment dispersion.The ratio of pigment and dispersion agent is 1.18: 1.
With 8 kinds of additives mixed in above-mentioned dispersion liquid that is prepared into and the table 2, normal temperature stirred 20 minutes down, with 0.5 μ strainer filter composition for ink, promptly obtain embodiment product 1.
Embodiment 2
See Table 1, at first make dispersion liquid, wherein with the black pigment MA-7 of 8 parts of Mitsubishi Chemicals (Mitsubishi ChemicalCorporation), 0.8 the blue pigments Alkali Blue D6101 (C.I.Pigment Blue 61) of part BASF (BASF), the EDPLAN482 of 8 parts of bright icepros (Munzing Chemie Gmbh) company, its active constituent content 85% and 83.2 parts of deionized waters mix with the high speed shear agitator must shear dispersion liquid in 1 hour after evenly, shearing dispersion liquid to 300g ground 1 hour in 0.14L volumetrical shredder again, obtained water dispersible pigment dispersion.The ratio of pigment and dispersion agent is 1.18: 1.
With 8 kinds of additives mixed in above-mentioned dispersion liquid that is prepared into and the table 2, normal temperature stirred 20 minutes down, with 0.5 μ strainer filter composition for ink, promptly obtain embodiment product 2.
Embodiment 3
See Table 1, at first make dispersion liquid, wherein with the black pigment MA-7 of 8 parts of Mitsubishi Chemicals (Mitsubishi ChemicalCorporation), 1.2 the blue pigments Alkali Blue D6101 (C.I.Pigment Blue 61) of part BASF (BASF), the EDPLAN482 of 8 parts of bright icepros (Munzing Chemie Gmbh) company, its active constituent content 85% and 82.8 parts of deionized waters mix with the high speed shear agitator must shear dispersion liquid in 1 hour after evenly, shearing dispersion liquid to 300g ground 1 hour in 0.14L volumetrical shredder again, obtained water dispersible pigment dispersion.The ratio of pigment and dispersion agent is 1.18: 1.
With 8 kinds of additives mixed in above-mentioned dispersion liquid that is prepared into and the table 2, normal temperature stirred 20 minutes down, with 0.5 μ strainer filter composition for ink, promptly obtain embodiment product 3.
Comparative example 1
See Table 1, at first make dispersion liquid, wherein with the black pigment MA-7 of 8 parts of Mitsubishi Chemicals (Mitsubishi ChemicalCorporation), the EDPLAN 482 of 8 parts of bright icepros (Munzing Chemie Gmbh) company, its active constituent content 85% and 84 parts of deionized waters mix with the high speed shear agitator must shear dispersion liquid in 1 hour after evenly, shearing dispersion liquid to 300g ground 1 hour in 0.14L volumetrical shredder again, obtained water dispersible pigment dispersion.The ratio of pigment and dispersion agent is 1.18: 1.
With 8 kinds of additives mixed in above-mentioned dispersion liquid that is prepared into and the table 2, normal temperature stirred 20 minutes down, with 0.5 μ strainer filter composition for ink, promptly obtain comparative example 1.
Comparative example 2
See Table 1, at first make dispersion liquid, wherein with the black pigment MA-7 of 8 parts of Mitsubishi Chemicals (Mitsubishi ChemicalCorporation), 0.8 part Clariant (Clariant) blue pigments PV Fast BlueBG (C.I.Pigment Blue 15:3), the EDPLAN482 of 8 parts of bright icepros (Munzing Chemie Gmbh) company, its active constituent content 85% and 83.2 parts of deionized waters mix with the high speed shear agitator must shear dispersion liquid in 1 hour after evenly, shearing dispersion liquid to 300g ground 1 hour in 0.14L volumetrical shredder again, obtained water dispersible pigment dispersion.The ratio of pigment and dispersion agent is 1.18: 1.
With 8 kinds of additives mixed in above-mentioned dispersion liquid that is prepared into and the table 2, normal temperature stirred 20 minutes down, with 0.5 μ strainer filter composition for ink, promptly obtain comparative example 2.
Comparative example 3
See Table 1, at first make dispersion liquid, wherein with the black pigment MA-7 of 8 parts of Mitsubishi Chemicals (Mitsubishi ChemicalCorporation), 0.8 part vapour crust (Ciba) blue pigments IRGALITE Blue GLVO (C.I.Pigment Blue 15:4), the EDPLAN 482 of 8 parts of bright icepros (Munzing Chemie Gmbh) company, its active constituent content 85% and 83.2 parts of deionized waters mix with the high speed shear agitator must shear dispersion liquid in 1 hour after evenly, shearing dispersion liquid to 300g ground 1 hour in 0.14L volumetrical shredder again, obtained water dispersible pigment dispersion.The ratio of pigment and dispersion agent is 1.18: 1.
With 8 kinds of additives mixed in above-mentioned dispersion liquid that is prepared into and the table 2, normal temperature stirred 20 minutes down, with 0.5 μ strainer filter composition for ink, promptly obtain comparative example 3.
Blue pigments C.I.Pigment Blue 61 in the table 1 has following structure, and this structural formula is the complete structure formula of C.I.PigmentBlue 61, but pigment structure is identical sometimes, crystal formation not simultaneously, performance gap is also very big.Present patent application is mainly protected and is related to this constructed products.
Table 3 embodiment and the corresponding L of comparative example ink
*, a
*, b
*Value
| ??L * | ??a * | ??b * | |
| Embodiment 1 | ??58.1 | ??1.1 | ??1.6 |
| Embodiment 2 | ??57.5 | ??-0.1 | ??-0.1 |
| Embodiment 3 | ??59.2 | ??-0.9 | ??-1.5 |
| Comparative example 1 | ??56.6 | ??2.3 | ??3.1 |
| Comparative example 2 | ??54.1 | ??0.5 | ??1.2 |
| Comparative example 3 | ??54.6 | ??0.7 | ??1.9 |
L according to the CIE regulation
*a
*b
*The colorimeter system method, our a of embodiment 1～3 as can be seen from table 3
*Value and b
*Value is than a of comparative example 1
*Value and b
*Be worth all for a short time, illustrate that the ink that adds C.I.Pigment Blue 61 is better than not adding the ink of C.I.Pigment Blue 61.Embodiment 2 is identical with the addition of comparative example 2～3 blue pigmentss, the kind difference.Our a of embodiment 2 as can be seen from table 3
*Value and b
*Value is than a of comparative example 2～3
*Value and b
*Be worth all for a short time, illustrate that the ink that adds C.I.Pigment Blue 61 is better than adding the ink of C.I.Pigment Blue 15:3 and C.I.Pigment Blue 15:4.
Claims (10)
1. black ink composition, comprise dispersion liquid, wetting Agent for Printing Inks, tensio-active agent and deionized water, wherein dispersion liquid grinds the preparation gained by tinting material, dispersion agent, deionized water and other auxiliary agent, it is characterized in that said tinting material contains black pigment C.I.P.B.7 and blue pigments C.I.Pigment Blue 61 at least, wherein the part by weight of black pigment C.I.P.B.7 and blue pigments C.I.Pigment Blue 61 is between 20: 1 to 2: 1.
2. according to the said a kind of black ink composition of claim 1, it is characterized in that between preferred 10: 1 to 20: 3 of the part by weight of said black pigment C.I.P.B.7 and blue pigments C.I.Pigment Blue 61.
3. according to the said a kind of black ink composition of claim 1, it is characterized in that the weight percent that said black pigment C.I.P.B.7 accounts for whole ink is 1～10%.
4. according to the said a kind of black ink composition of claim 1, it is characterized in that said black pigment selects for use following wherein a kind of: Mongul-L, REGAL 400R, Monarch1300, Monarch 900, the REGAL 330R of Cabot (Cabot) company; MA-7, MA100, the MA40 of Mitsubishi Chemical Ind (Mitsubishi Chemical Corporation); The Special black 4 of goldschmidt chemical corporation (Degussa); Raven 3500, the Raven 1255 of Columbian Chemicals Co. (Columbian Chemical), Raven 3600 ultra.
5. according to the said a kind of black ink composition of claim 1, it is characterized in that said dispersion agent can select the EDPLAN 482 of bright icepro (Munzing Chemie Gmbh) company for use.
6. according to the said a kind of black ink composition of claim 1, it is characterized in that said wetting Agent for Printing Inks can select Virahol for use, the N-N-methyl-2-2-pyrrolidone N-, the 2-pyrrolidone, ethylene glycol ethyl ether, butyl glycol ether, diethylene glycol ether, the Diethylene Glycol butyl ether, the triethylene glycol butyl ether, propylene glycol butyl ether and dipropylene glycol butyl ether, glycerol, ethylene glycol, Diethylene Glycol, triethylene glycol, TriMethylolPropane(TMP), 1, the 2-propylene glycol, 1, ammediol, 1, the 4-butyleneglycol, 1, the 5-pentanediol, 1, the 2-hexylene glycol, 1,2, the 6-hexanetriol, poly(oxyethylene glycol) 400, at least a in the Polyethylene Glycol-600.
7. according to the said a kind of black ink composition of claim 1, it is characterized in that said auxiliary agent comprises pH regulator agent and sterilant.Wherein the pH regulator agent can be selected trolamine for use; Sterilant can be selected the Nipacide BIT-20 of Clariant company (Clariant) for use.
8. according to the said a kind of black ink composition of claim 1, it is characterized in that said tensio-active agent can select the product Surfynol 465 of air chemical company (Air Products) and among the Surfynol 485 any one for use.
9. the preparation method of a black ink composition is characterized in that comprising the preparation of dispersion liquid and the preparation of ink, wherein:
(1) preparation of dispersion liquid may further comprise the steps:
1. dispersion agent and deionized water proportionally are mixed in the container, and stir;
2. add black pigment and blue pigments in proportion, fully wetting;
3. with high-speed shearing machine with the 2. dispersion liquid high speed shear 0.5～8 hour of gained of step, rotating speed is 1000～10000rpm, shears and finishes back placement 10～20 minutes;
4. with step 3. the shearing dispersion liquid of gained pump into and grind dispersion in the shredder;
5. the 4. middle shredder discharge port gained dispersion liquid of step is entered the stock chest of shredder, pump into shredder once more and carried out circular grinding 0.5～24 hour;
6. in the process of lapping, carried out granularity Detection every 15 minutes, reach requirement, obtain dispersion liquid up to the particle diameter of dispersion liquid.
(2) preparation of ink may further comprise the steps:
Get the 6. prepared dispersion liquid 50% of above-mentioned steps by weight percentage, other adds 2-pyrrolidone 4%, ethylene glycol 3%, 1,2-propylene glycol 3%, 1,2-hexylene glycol 6%, Surfynol 4651.2%, trolamine 0.2%, sterilant and surplus deionized water are made composition for ink.
10. according to the preparation method of the said a kind of black ink composition of claim 9, it is characterized in that said step is 1.-3. for shearing dispersion steps, wherein mainly to act on be to make the dispersion agent dispersion and emulsion even to the high speed shear of step in 3., smash in the part black pigment than macroparticle, the preferred 1-2 of shear time hour; Above-mentioned steps is 4.-6. for grinding dispersion steps; Wherein the shredder of step in 4. is pin bar type shredder, and rotating speed is 600～4200rpm, and it is the zirconium oxide bead of 0.05～1mm that grinding medium adopts diameter, between preferred diameter 0.05～0.2mm; The grinding purposes of said step in 4. is to make the black nano-water dispersible pigment dispersion particle diameter continue to reduce the preferred 1-2 of milling time hour; The temperature of the discharge port of said step in 5. is controlled between 20～40 ℃; 6. said step is the pigment granularity Detection, and particle diameter requires D
50About 100nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910228091 CN101705028B (en) | 2009-11-09 | 2009-11-09 | Black ink composition for inkjet |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910228091 CN101705028B (en) | 2009-11-09 | 2009-11-09 | Black ink composition for inkjet |
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| Publication Number | Publication Date |
|---|---|
| CN101705028A true CN101705028A (en) | 2010-05-12 |
| CN101705028B CN101705028B (en) | 2012-06-27 |
Family
ID=42375285
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|---|---|---|---|
| CN 200910228091 Expired - Fee Related CN101705028B (en) | 2009-11-09 | 2009-11-09 | Black ink composition for inkjet |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453352A (en) * | 2010-10-14 | 2012-05-16 | 研能科技股份有限公司 | Composition for improving pigment stability |
| CN106661337A (en) * | 2014-07-04 | 2017-05-10 | 富士胶片株式会社 | Novel compound, coloring composition for dyeing or printing, inkjet ink, method for printing fabric, and dyed or printed fabric |
| CN109972425A (en) * | 2017-12-28 | 2019-07-05 | 沈阳化工研究院有限公司 | A kind of carbon black color paste and preparation method thereof |
| CN112300626A (en) * | 2020-11-24 | 2021-02-02 | 上海贝通色彩科技有限公司 | Black ink composition for thermal transfer printing and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2371553A (en) * | 2000-12-23 | 2002-07-31 | Ilford Imaging Uk Ltd | Inks for Ink Jet Printers |
| JP4900763B2 (en) * | 2005-01-27 | 2012-03-21 | セイコーエプソン株式会社 | Black ink composition, and recording method and recorded matter using the same |
| CN101358051A (en) * | 2008-07-30 | 2009-02-04 | 曾观涛 | Jet ink for digital print and preparation method thereof |
-
2009
- 2009-11-09 CN CN 200910228091 patent/CN101705028B/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453352A (en) * | 2010-10-14 | 2012-05-16 | 研能科技股份有限公司 | Composition for improving pigment stability |
| CN106661337A (en) * | 2014-07-04 | 2017-05-10 | 富士胶片株式会社 | Novel compound, coloring composition for dyeing or printing, inkjet ink, method for printing fabric, and dyed or printed fabric |
| EP3165574A4 (en) * | 2014-07-04 | 2017-11-15 | Fujifilm Corporation | Novel compound, coloring composition for dyeing or printing, inkjet ink, method for printing fabric, and dyed or printed fabric |
| CN109972425A (en) * | 2017-12-28 | 2019-07-05 | 沈阳化工研究院有限公司 | A kind of carbon black color paste and preparation method thereof |
| CN109972425B (en) * | 2017-12-28 | 2023-04-11 | 沈阳化工研究院有限公司 | Carbon black color paste and preparation method thereof |
| CN112300626A (en) * | 2020-11-24 | 2021-02-02 | 上海贝通色彩科技有限公司 | Black ink composition for thermal transfer printing and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN101705028B (en) | 2012-06-27 |
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