CN101696287A - Antibacterial composite sports protective gear material and preparation method thereof - Google Patents
Antibacterial composite sports protective gear material and preparation method thereof Download PDFInfo
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- CN101696287A CN101696287A CN200910198123A CN200910198123A CN101696287A CN 101696287 A CN101696287 A CN 101696287A CN 200910198123 A CN200910198123 A CN 200910198123A CN 200910198123 A CN200910198123 A CN 200910198123A CN 101696287 A CN101696287 A CN 101696287A
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- protective gear
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Abstract
The invention relates to an antibacterial composite sports protective gear material and a preparation method thereof. The antibacterial composite sports protective gear material comprises the following raw material components in percentage by mass: 1 to 15 percent of antibacterial capsule and the balance of SBR; and the antibacterial capsule comprises the following raw material components in percentage by mass: 1 to 5 percent of nano silver, 1 to 5 percent of nano selenium, 1 to 5 percent of nano bamboo charcoal and the balance of SBR. The preparation method comprises a step of blending the antibacterial capsule and the SBR to prepare the antibacterial composite sports protective gear material, wherein the blending time is 0.5 to 5h; and the temperature is between 50 and 300 DEG C. The antibacterial composite sports protective gear material and the preparation method have the advantages of simple process flow and easy industrial production.
Description
[technical field]
The present invention relates to protective gear material technical field in the sports, specifically, is a kind of antibacterial composite sports protective gear material and preparation method thereof.
[background technology]
Styrene-butadiene rubber(SBR) is the elastomerics that 1,3-butadiene and vinylbenzene make through copolymerization.Emulsion-polymerized styrene butadiene rubber (E-SBR) styrene-butadiene rubber(SBR) is elastomeric a kind of.
Styrene-butadiene rubber(SBR) is the general purpose synthetic rubber of output maximum, and emulsion polymerized styrene butadiene rubber, solution polymerized butadiene styrene rubber are arranged.The butylbenzene rubber is the light tan Hookean body, and density becomes greatly with the increase of styrene content, and oil-proofness is poor, but dielectric properties are better; Rubber tensile strength has only 20-35 kilogram force/square centimeter, and behind the adding black-reinforced, tensile strength can reach 250-280 kilogram force/square centimeter; Its tackiness, elasticity and deformation thermal value be all not as natural rubber, but wear resistance, anti-weather aging, water tolerance, resistance to air loss etc. are better than natural rubber, are a kind of good comprehensive properties rubber therefore.Styrene-butadiene rubber(SBR) is the key product of rubber industry, and it is the first kind of synthetic rubber, and over-all properties is good, price is low, can replace natural rubber to use in most occasions, be mainly used in tire industry, trolley part, sebific duct, adhesive tape, rubber overshoes, electric wire and other rubber item.
Carried out free-radical emulsion polymerization at low temperatures and made by divinyl and vinylbenzene, its product performance normal temperature is white solid or transparent no suspended substance liquid down, and little aromatising flavour is arranged, and is the Betengent product raw material that more is better than industrial linear alkylbenzene on a kind of performance.With it is raw material deutero-surfactant product, excellent property, and biodegradability is good, anti-hard water, skin feel is soft, and degreasing power is little, is more suitable for cold washing, still has remarkable soil removability at low temperature.
SBR-1500 is the typical species of general contamination type cold styrene butadiene rubber, and the tackiness of rubber and processing characteristics are all excellent, and the wear resisting property of cross-linked rubber, tensile strength, tear strength and ageing-resistant performance are better.SBR-1502 is the typical species of general without pollution cold styrene butadiene rubber, and its performance and SBR-1500 are suitable, and good tensile, abrasion performance and flexural property are arranged.SBR-1712 is a kind of contaminative kind of filling the cold styrene butadiene rubber of high fragrant hydrocarbon ils, and it has good tackiness, wear resistance and advantages such as workability and low price.
[summary of the invention]
The objective of the invention is to overcome the deficiencies in the prior art, a kind of antibacterial composite sports protective gear material and preparation method thereof is provided.
The objective of the invention is to be achieved through the following technical solutions:
A kind of antibiotic capsule, its raw material are formed mass percent and are:
Nanometer silver 1～5%
Nanometer selenium 1～5%
Nano-bamboo carbon 1～5%
The SBR surplus
Described compatilizer is NBR 270, NBR P65 or CPE;
Described SBR is a styrene-butadiene rubber(SBR), SBR-1500;
The mass percent of described nanometer silver is preferably 2%
The mass percent of described nanometer selenium is preferably 2%;
The mass percent of described nano-bamboo carbon is preferably 2%;
Described bamboo charcoal nano, because bamboo carbon has special structure, its molecular structure is sexangle, the carbonaceous densification, than great, hole is many, content of mineral substances is abundant, contain the material to the human body beneficial such as potassium, magnesium, iron, manganese, calcium, zirconium, and specific surface area is big, has stronger adsorptive power, antibiotic, smelly, the moisture absorption of disappearing, drying and good electrical conductivity, bamboo carbon; And have bamboo carbon, an anion emission function;
Described nanometer silver, nano-Ag particles directly enter thalline and oxygen metabolism enzyme, and (SH) combine, the unique effect mechanism that thalline is choked to death can be killed microorganisms such as most of bacteriums of being in contact with it, fungi, mould, spore.Discover through domestic eight big authoritative institutions: it is to pathogenic bacteria of drug-resistant such as resistance intestinal bacteria, resistance golden staphylococci, drug-resistant pseudomonas aeruginosa, streptococcus pyogenes, resistance faecalis, and anerobe etc. have comprehensive anti-microbial activity; The common bacterium of burn and scald and wound surface such as streptococcus aureus, intestinal bacteria, Pseudomonas aeruginosa, Candida albicans and other G+, G-pathogenic bacterium all there is germicidal action; To chlamydia trachomatis, cause that the gonococcus of sexually transmitted disease also has powerful germicidal action; Perviousness is strong: nano-Ag particles has superpower perviousness, can infiltrate subcutaneous 2mm sterilization rapidly, and common bacteria, obstinate bacterium, drug-resistant bacteria and fungus-caused tissue infection than the depths are all had good germicidal action; Nanometer silver can promote wound healing, promotes the reparation and the regeneration of damaged cell, removes necrosis and promote granulation, and antisepsis and anti-inflammation improves the microcirculation of wound surrounding tissue, activates effectively and promotes histiocytic growth, and the healing of accelerated in wounds reduces the generation of scar;
Described nanometer selenium has high biological activity and high security, also has following characteristics simultaneously: high immunomodulator, cell, body fluid, the nonspecific immunity function of nanometer selenium energy significant stimulation organism, thereby diseases prevention, the resistance against diseases of raising body; High anti-oxidation, nanometer selenium are small units that is formed by several ten thousand selenium compounds, it anti-oxidant, to remove the free radical ability stronger, can suppress free radical well, the protection cell is avoided infringement; High-absorbility because the granularity of nanometer selenium is superfine, is easily directly absorbed by the animal gi tract, makes full use of, and can bring into play its function to a greater extent;
A kind of antibiotic capsular preparation method, its concrete steps are: above-mentioned raw materials is mixed, carry out blend after, make antibiotic capsule, wherein, the blend time is 0.5～5h, temperature is 50～300 ℃;
A kind of antibacterial composite sports protective gear material, the mass percent of the component of its raw material is:
Antibiotic capsule 1～15%
The SBR surplus
Described antibiotic capsular mass percent is preferably 10%;
A kind of preparation method of antibacterial composite sports protective gear material, antibiotic capsule and SBR carried out blend after, make antibacterial composite sports protective gear material; Wherein, the blend time is 0.5～5h, and temperature is 50～300 ℃.
Compared with prior art, positively effect of the present invention is:
(1) the present invention adopts antibiotic capsule, makes antiseptic-germicide keep efficient permanent antibacterial effect in protective gear material;
(2) contain nano material in the antibiotic capsule component of the present invention, such as nanometer silver, nano-bamboo carbon, nanometer selenium has the effect of environment protection health to human body;
(3) technical process of the present invention is simple, carries out suitability for industrialized production easily.
[embodiment]
The present invention below is provided a kind of embodiment.
Embodiment 1
(1) a kind of antibiotic capsule, its raw material are formed mass percent and are:
Nanometer silver 1%
Nanometer selenium 1%
Nano-bamboo carbon 1%
SBR 97％
Described compatilizer is respectively NBR 270
Described SBR is a styrene-butadiene rubber(SBR);
(2) a kind of antibiotic capsular preparation method, its concrete steps are: above-mentioned raw materials is mixed, carry out blend after, make antibiotic capsule, wherein, the blend time is 0.5～5h, temperature is 50～300 ℃;
(3) a kind of antibacterial composite sports protective gear material, the mass percent of the component of its raw material is:
Antibiotic capsule 3%
SBR 97％
(4) a kind of preparation method of antibacterial composite sports protective gear material, antibiotic capsule and SBR carried out blend after, make antibacterial composite sports protective gear material; Wherein, the blend time is 0.5～5h, and temperature is 50～300 ℃;
Embodiment 2
(1) a kind of antibiotic capsule, its raw material are formed mass percent and are:
Nanometer silver 2%
Nanometer selenium 2%
Nano-bamboo carbon 2%
SBR 94％
Described compatilizer is NBR P65
(2) a kind of antibiotic capsular preparation method is with embodiment 1;
(3) a kind of antibacterial composite sports protective gear material, the mass percent of the component of its raw material is:
Antibiotic capsule 6%
SBR 94％
(4) a kind of preparation method of antibacterial composite sports protective gear material is with embodiment 1.
Embodiment 3
(1) a kind of antibiotic capsule, its raw material are formed mass percent and are:
Nanometer silver 3%
Nanometer selenium 3%
Nano-bamboo carbon 3%
SBR 91％
Described compatilizer is CPE
Described SBR is a styrene-butadiene rubber(SBR);
(2) a kind of antibiotic capsular preparation method is with embodiment 1;
(3) a kind of antibacterial composite sports protective gear material, the mass percent of the component of its raw material is:
Antibiotic capsule 10%
SBR 90％
(4) a kind of preparation method of antibacterial composite sports protective gear material is with embodiment 1.
Embodiment 4
(1) a kind of antibiotic capsule, its raw material are formed mass percent and are:
Nanometer silver 4%
Nanometer selenium 4%
Nano-bamboo carbon 4%
SBR 88％
Described compatilizer is NBR 270
(2) a kind of antibiotic capsular preparation method is with embodiment 1;
(3) a kind of antibacterial composite sports protective gear material, the mass percent of the component of its raw material is:
Antibiotic capsule 12%
SBR 88％
(4) a kind of preparation method of antibacterial composite sports protective gear material is with embodiment 1.
Embodiment 5
(1) a kind of antibiotic capsule, its raw material are formed mass percent and are:
Nanometer silver 5%
Nanometer selenium 5%
Nano-bamboo carbon 5%
SBR 85％
Described compatilizer is CPE;
(2) a kind of antibiotic capsular preparation method is with embodiment 1;
(3) a kind of antibacterial composite sports protective gear material, the mass percent of the component of its raw material is:
Antibiotic capsule 15%
SBR 85％
(4) a kind of preparation method of antibacterial composite sports protective gear material is with embodiment 1.
The above only is a preferred implementation of the present invention; should be pointed out that for those skilled in the art, without departing from the inventive concept of the premise; can also make some improvements and modifications, these improvements and modifications also should be considered within the scope of protection of the present invention.
Claims (7)
1. an antibacterial composite sports protective gear material is characterized in that, the mass percent of the component of raw material is:
Antibiotic capsule 1～15%
The SBR surplus.
2. a kind of antibacterial composite sports protective gear material as claimed in claim 1 is characterized in that, described antibiotic capsular mass percent is 10%.
3. a kind of antibacterial composite sports protective gear material as claimed in claim 1 is characterized in that, described antibiotic capsular material component mass percent is:
Nanometer silver 1～5%
Nanometer selenium 1～5%
Nano-bamboo carbon 1～5%
The SBR surplus.
4. a kind of antibacterial composite sports protective gear material as claimed in claim 3 is characterized in that, the mass percent of described nanometer silver is 2%.
5. a kind of antibacterial composite sports protective gear material as claimed in claim 3 is characterized in that, the mass percent of described nanometer selenium is 2%.
6. a kind of antibacterial composite sports protective gear material as claimed in claim 3 is characterized in that, the mass percent of described nano-bamboo carbon is 2%.
7. the preparation method of a kind of antibacterial composite sports protective gear material as claimed in claim 1, antibiotic capsule and SBR carried out blend after, make antibacterial composite sports protective gear material; It is characterized in that the blend time is 0.5～5h, temperature is 50～300 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN200910198123XA CN101696287B (en) | 2009-11-03 | 2009-11-03 | Antibacterial composite sports protective gear material and preparation method thereof |
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| CN200910198123XA CN101696287B (en) | 2009-11-03 | 2009-11-03 | Antibacterial composite sports protective gear material and preparation method thereof |
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| CN101696287A true CN101696287A (en) | 2010-04-21 |
| CN101696287B CN101696287B (en) | 2011-06-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN200910198123XA Expired - Fee Related CN101696287B (en) | 2009-11-03 | 2009-11-03 | Antibacterial composite sports protective gear material and preparation method thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102504372A (en) * | 2011-10-28 | 2012-06-20 | 丁金标 | Production method of anti-bacterial SBR (styrene butadiene rubber) foaming material |
| CN102532676A (en) * | 2011-12-16 | 2012-07-04 | 朱晓娜 | Protector material with health-care function in athletic sports field and preparation method thereof |
| CN102558648A (en) * | 2011-12-16 | 2012-07-11 | 李胜春 | Functional protective clothing material for sports goods and preparation method for functional protective clothing material |
| CN103159996A (en) * | 2011-12-16 | 2013-06-19 | 李胜春 | Multifunctional protective clothing material in sports field and preparation method thereof |
| CN103159997A (en) * | 2011-12-16 | 2013-06-19 | 李胜春 | Protective clothing material with self-repairing function in sports field and preparation method thereof |
| CN103160057A (en) * | 2011-12-16 | 2013-06-19 | 李胜春 | Composite functional pad material for sporting goods and preparation method thereof |
| CN103205037A (en) * | 2012-01-17 | 2013-07-17 | 贾振勇 | Multifunctional protector material in field of sports, and preparation method thereof |
| CN104231356A (en) * | 2011-12-16 | 2014-12-24 | 李胜春 | Preparation method of protective clothing material with self-repairing function in sports field |
| CN104231357A (en) * | 2011-12-16 | 2014-12-24 | 李胜春 | Preparation method of multifunctional protective clothing material used in sports field |
| CN104886819A (en) * | 2015-05-12 | 2015-09-09 | 无锡世强休闲用品有限公司 | Motion kneecap |
| CN104890840A (en) * | 2015-05-12 | 2015-09-09 | 无锡世强休闲用品有限公司 | Diving suit material |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1887946A (en) * | 2006-06-21 | 2007-01-03 | 张家港宏裕乳胶手套有限公司 | Recipe and making process of antibiotic rubber gloves |
| CN101298511A (en) * | 2007-07-30 | 2008-11-05 | 北京中科普惠科技发展有限公司 | Antibiotic polymer composite material, and preparation and use thereof |
| CN101255274A (en) * | 2008-04-22 | 2008-09-03 | 东南大学 | Composite nano silver-polyurethane antibiotic material and preparation thereof |
| CN101544718B (en) * | 2009-05-06 | 2011-04-20 | 河北科技大学 | Method for preparing antibacterial composite material with nano silver particles evenly dispersed in polymeric matrix |
-
2009
- 2009-11-03 CN CN200910198123XA patent/CN101696287B/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102504372A (en) * | 2011-10-28 | 2012-06-20 | 丁金标 | Production method of anti-bacterial SBR (styrene butadiene rubber) foaming material |
| CN104231356A (en) * | 2011-12-16 | 2014-12-24 | 李胜春 | Preparation method of protective clothing material with self-repairing function in sports field |
| CN102558648A (en) * | 2011-12-16 | 2012-07-11 | 李胜春 | Functional protective clothing material for sports goods and preparation method for functional protective clothing material |
| CN103159996A (en) * | 2011-12-16 | 2013-06-19 | 李胜春 | Multifunctional protective clothing material in sports field and preparation method thereof |
| CN103159997A (en) * | 2011-12-16 | 2013-06-19 | 李胜春 | Protective clothing material with self-repairing function in sports field and preparation method thereof |
| CN103160057A (en) * | 2011-12-16 | 2013-06-19 | 李胜春 | Composite functional pad material for sporting goods and preparation method thereof |
| CN102532676B (en) * | 2011-12-16 | 2013-11-06 | 周口师范学院 | Protector material with health-care function in athletic sports field and preparation method thereof |
| CN102558648B (en) * | 2011-12-16 | 2014-03-19 | 唐坤 | Functional protective clothing material for sports goods and preparation method for functional protective clothing material |
| CN102532676A (en) * | 2011-12-16 | 2012-07-04 | 朱晓娜 | Protector material with health-care function in athletic sports field and preparation method thereof |
| CN104231357A (en) * | 2011-12-16 | 2014-12-24 | 李胜春 | Preparation method of multifunctional protective clothing material used in sports field |
| CN103205037A (en) * | 2012-01-17 | 2013-07-17 | 贾振勇 | Multifunctional protector material in field of sports, and preparation method thereof |
| CN104886819A (en) * | 2015-05-12 | 2015-09-09 | 无锡世强休闲用品有限公司 | Motion kneecap |
| CN104890840A (en) * | 2015-05-12 | 2015-09-09 | 无锡世强休闲用品有限公司 | Diving suit material |
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| CN101696287B (en) | 2011-06-29 |
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Owner name: HOU ZHANYING Free format text: FORMER OWNER: WANG DEHUA Effective date: 20110420 |
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Free format text: CORRECT: INVENTOR; FROM: WANG DEHUA FU KONGHUI XIAO YUMEI LIU BO LIU GANG TO: HOU ZHANYING LIANG QIXIONG SU YING ZHAO TAO YU XIUTAO WANG DEHUA FU KONGHUI XIAO YUMEI LIU BO LIU GANG Free format text: CORRECT: ADDRESS; FROM: 464000 NO. 237, CHANG AN ROAD, SHIHE DISTRICT, XINYANG CITY, HE NAN PROVINCE TO: 467036 PHYSICAL EDUCATION DEPARTMENT, HE NAN UNIVERSITY OF URBAN CONSTRUCTION, MINGYUE ROAD, XINCHENG DISTRICT, PINGDINGSHAN CITY, HE NAN PROVINCE |
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Effective date of registration: 20110420 Address after: 467036 Mingyue Road, Henan University Of Urban Construction, Pingdingshan City, Henan Province Department of Physical Education Applicant after: Hou Zhanying Address before: 464000 No. 237, Changan Road, the Shihe River District, Henan, Xinyang Applicant before: Wang Dehua |
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