CN101691476B - Binding agent, preparation method and application thereof - Google Patents
Binding agent, preparation method and application thereof Download PDFInfo
- Publication number
- CN101691476B CN101691476B CN2009101708416A CN200910170841A CN101691476B CN 101691476 B CN101691476 B CN 101691476B CN 2009101708416 A CN2009101708416 A CN 2009101708416A CN 200910170841 A CN200910170841 A CN 200910170841A CN 101691476 B CN101691476 B CN 101691476B
- Authority
- CN
- China
- Prior art keywords
- tackiness agent
- polyurethane prepolymer
- base polyurethane
- tree elastomer
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 239000011230 binding agent Substances 0.000 title abstract description 5
- 229920001971 elastomer Polymers 0.000 claims abstract description 45
- 239000000463 material Substances 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 52
- 239000000806 elastomer Substances 0.000 claims description 31
- 239000004814 polyurethane Substances 0.000 claims description 20
- 229920005906 polyester polyol Polymers 0.000 claims description 18
- 229920002635 polyurethane Polymers 0.000 claims description 18
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 14
- 244000043261 Hevea brasiliensis Species 0.000 claims description 13
- 229920003052 natural elastomer Polymers 0.000 claims description 13
- 229920001194 natural rubber Polymers 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 230000004048 modification Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 4
- 238000006068 polycondensation reaction Methods 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical class OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 3
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical class OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 239000001384 succinic acid Substances 0.000 claims description 2
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims description 2
- 239000002649 leather substitute Substances 0.000 abstract description 2
- 238000004026 adhesive bonding Methods 0.000 abstract 1
- 208000018747 cerebellar ataxia with neuropathy and bilateral vestibular areflexia syndrome Diseases 0.000 abstract 1
- 239000010985 leather Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 46
- 239000000126 substance Substances 0.000 description 15
- 238000010559 graft polymerization reaction Methods 0.000 description 9
- 239000003960 organic solvent Substances 0.000 description 9
- 239000003292 glue Substances 0.000 description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000007062 hydrolysis Effects 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 6
- 238000005987 sulfurization reaction Methods 0.000 description 6
- 244000286663 Ficus elastica Species 0.000 description 5
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 229920001195 polyisoprene Polymers 0.000 description 5
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000012046 mixed solvent Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- DSCFFEYYQKSRSV-UHFFFAOYSA-N 1L-O1-methyl-muco-inositol Natural products COC1C(O)C(O)C(O)C(O)C1O DSCFFEYYQKSRSV-UHFFFAOYSA-N 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- 229920003232 aliphatic polyester Polymers 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- ANJPRQPHZGHVQB-UHFFFAOYSA-N hexyl isocyanate Chemical class CCCCCCN=C=O ANJPRQPHZGHVQB-UHFFFAOYSA-N 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- XFEWMFDVBLLXFE-UHFFFAOYSA-N 1-isocyanatodecane Chemical compound CCCCCCCCCCN=C=O XFEWMFDVBLLXFE-UHFFFAOYSA-N 0.000 description 1
- VRVUKQWNRPNACD-UHFFFAOYSA-N 1-isocyanatopentane Chemical class CCCCCN=C=O VRVUKQWNRPNACD-UHFFFAOYSA-N 0.000 description 1
- AIDLAEPHWROGFI-UHFFFAOYSA-N 2-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=C(C(O)=O)C=CC=C1C(O)=O AIDLAEPHWROGFI-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005662 electromechanics Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- HNHVTXYLRVGMHD-UHFFFAOYSA-N n-butyl isocyanate Chemical compound CCCCN=C=O HNHVTXYLRVGMHD-UHFFFAOYSA-N 0.000 description 1
- 229920006173 natural rubber latex Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Images
Landscapes
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
With the footwear material of rubber to pasting | Later stage pulling force (kg/cm) | MV (kg/cm) | Destroy type | Creep (cm) | Pulling force standard (kg/cm) | Creep standard (cm) |
Corium | 8.0,7.7,8.4 | 8.0 | Rubber destroys | 0.0 | 2.7 | 1.27 |
Anti-fur | 7.4,7.5,7.7 | 7.5 | Rubber destroys | 0.0 | 2.7 | 1.27 |
With the footwear material of rubber to pasting | Later stage pulling force (kg/cm) | MV (kg/cm) | Destroy type | Aging back tension (kg/cm) | MV (kg/cm) | Destroy type | Pulling force standard (kg/cm) |
Corium | 5.3,5.3,5.3 | 5.3 | Rubber destroys | 5.3,5.4,5.4 | 5.4 | Rubber destroys | 2.7 |
Anti-fur | 5.0,5.0,5.0 | 5.0 | Rubber destroys | 5.1,5.2,5.1 | 5.1 | Rubber destroys | 2.7 |
With the footwear material of rubber to pasting | Later stage pulling force (kg/cm) | MV (kg/cm) | Destroy type | Hydrolysis back tension (kg/cm) | MV (kg/cm) | Destroy type | Pulling force standard (kg/cm) |
Corium | 6.4,6.5, 6.9 | 6.6 | Corium destroys | 5.7,6.3,5.7 | 5.7 | Cohesion destroys | 2.7 |
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009101708416A CN101691476B (en) | 2009-09-09 | 2009-09-09 | Binding agent, preparation method and application thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009101708416A CN101691476B (en) | 2009-09-09 | 2009-09-09 | Binding agent, preparation method and application thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101691476A CN101691476A (en) | 2010-04-07 |
CN101691476B true CN101691476B (en) | 2012-07-04 |
Family
ID=42080193
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2009101708416A Expired - Fee Related CN101691476B (en) | 2009-09-09 | 2009-09-09 | Binding agent, preparation method and application thereof |
Country Status (1)
Country | Link |
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CN (1) | CN101691476B (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102898984B (en) * | 2012-09-11 | 2014-04-02 | 苏州市胶粘剂厂有限公司 | Preparation method for aqueous adhesive for vulcanized shoes |
CN105017993B (en) * | 2015-08-10 | 2017-09-19 | 万华化学(广东)有限公司 | A kind of vulcanized shoes aqueous binder and preparation method thereof |
CN106010365B (en) * | 2016-07-07 | 2018-06-26 | 芜湖风雪橡胶有限公司 | Rubber adhesive and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1995258A (en) * | 2006-11-17 | 2007-07-11 | 广州市化学工业研究所 | Aqueous adhesive for shoes and its production method |
CN101173031A (en) * | 2006-11-01 | 2008-05-07 | 北京林氏精化新材料有限公司 | Polyurethane prepolymer, aquosity polyurethane binder and uses thereof |
CN101508879A (en) * | 2009-03-17 | 2009-08-19 | 陕西科技大学 | Method of preparing watersoluble polyurethane adhesive |
-
2009
- 2009-09-09 CN CN2009101708416A patent/CN101691476B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101173031A (en) * | 2006-11-01 | 2008-05-07 | 北京林氏精化新材料有限公司 | Polyurethane prepolymer, aquosity polyurethane binder and uses thereof |
CN1995258A (en) * | 2006-11-17 | 2007-07-11 | 广州市化学工业研究所 | Aqueous adhesive for shoes and its production method |
CN101508879A (en) * | 2009-03-17 | 2009-08-19 | 陕西科技大学 | Method of preparing watersoluble polyurethane adhesive |
Non-Patent Citations (1)
Title |
---|
JP特开2002-188071A 2002.07.05 |
Also Published As
Publication number | Publication date |
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CN101691476A (en) | 2010-04-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: XINGQIAN CHEMICAL MACAO COMMERCIAL OFFSHORE SERVIC Free format text: FORMER OWNER: CHUBU RESIN CHEMICALS CO., LTD. Effective date: 20140529 |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20140529 Address after: G, 16 floor, Macao financial center, 202A-246 street, Macao, Beijing, China Patentee after: Star Chemical Macao offshore business services Ltd. Address before: A-D, sixteen floor, Macao financial center, 202A-246 street, Macao, Beijing, China Patentee before: CHUBU RESIN CHEMICALS Co.,Ltd. |
|
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20100407 Assignee: ZHUHAI ZETAO ADHESIVE PRODUCTS CO.,LTD. Assignor: Star Chemical Macao offshore business services Ltd. Contract record no.: 2014990000899 Denomination of invention: Stopping bleeding spraying adhesive, preparing method and use thereof Granted publication date: 20120704 License type: Exclusive License Record date: 20141202 |
|
LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20171205 Address after: Guangdong province Zhuhai city harbor industrial zone, Jinwan District fine chemical Dongrong Lucy Patentee after: ZHUHAI ZETAO ADHESIVE PRODUCTS CO.,LTD. Address before: G, 16 floor, Macao financial center, 202A-246 street, Macao, Beijing, China Patentee before: Star Chemical Macao offshore business services Ltd. |
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TR01 | Transfer of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120704 |
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CF01 | Termination of patent right due to non-payment of annual fee |