CN101688260A - Utilize the core metal silk that contains of doping reductor to improve the recovery of molten steel bath interalloy - Google Patents
Utilize the core metal silk that contains of doping reductor to improve the recovery of molten steel bath interalloy Download PDFInfo
- Publication number
- CN101688260A CN101688260A CN200880023283A CN200880023283A CN101688260A CN 101688260 A CN101688260 A CN 101688260A CN 200880023283 A CN200880023283 A CN 200880023283A CN 200880023283 A CN200880023283 A CN 200880023283A CN 101688260 A CN101688260 A CN 101688260A
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- China
- Prior art keywords
- alloy
- reductor
- additive
- delivery device
- blend
- Prior art date
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D1/00—Treatment of fused masses in the ladle or the supply runners before casting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0006—Adding metallic additives
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0056—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 using cored wires
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/06—Deoxidising, e.g. killing
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/04—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbonitrides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
Abstract
The invention provides in the steel that increases additive or increase alloy, to improve and reclaim.Can be by deoxidation powder and additive alloy blending be realized.The reaction of deoxidizing powder and oxygen, thereby oxygen deprivation in should the zone.Alloy or additive zone enrichment, thereby the recovery of raising in molten steel.
Description
The cross reference of related application
The application requires the right of priority of No. the 60/938th, 671, the U.S. Provisional Application submitted on May 17th, 2007, and the content of this provisional application is by with reference to being incorporated into this paper.
Invention field
The present invention relates generally at molten metal, particularly add alloy in the steel.More specifically, the present invention relates in molten steel, add alloy and reductor to improve the recovery of metal.
Background of invention
As everyone knows,, comprise intensity and toughness, can in molten steel, add alloy and other additives in order to improve the material property of final steel product.
In the prior art field, adding alloy and additive are normally realized in the following manner in molten steel, powdery alloy and additive packed into forms " containing the core metal silk " in the metal shell, then in the molten steel that its " injection " comprised to the ladle (ladle) of most of steelworks steel refining devices.United States Patent (USP) the 4th, 128 is described this injecting method No. 414.The a part of material that injects molten steel does not remain on steel.For the molten steel that effectively the preparation additive increases or alloy increases, wish to improve " recovery " in the molten steel.
" recovery " is to the alloy that comprises in the molten steel after injecting and a kind of tolerance of additive capacity.Recovery is expressed as that injection back comprises in steel is injected at the alloy in the steel or the percentage ratio of additive.The percentage ratio that comprises in this steel after the injection is big more, and reclaiming also will be big more.Reclaim big more concerning steel manufacturers the expression cost low more because injection to contain the core metal silk few more.And the predictability and the repeatability that reclaim the chemical property of big more ordinary representation final steel can be high more.
As everyone knows, with containing in the core metal silk of additive alloy (being ground to diameter usually less than 1 millimeter powder) the ladle shell of packing into, the result who this wire degree of depth is injected the molten bath reclaims to significantly improve.But this area is also known is the disadvantageous effect that the recovery of special additive alloy is subjected to oxygen level in molten bath and top, the molten bath slag.Might reduce the oxygen level of molten bath and slag; But till the ass ascends the ladder oxygen level is reduced to zero.The most common is, has a certain amount of oxygen all the time and stays in molten metal and the slag, additive alloy is reclaimed have a negative impact.Oxygen level is high more, and this disadvantageous effect is big more.
The contriver believes, additive alloy powders particle 16 can become be dissolved in molten metal 10 before, the oxygen 13 in the molten metal 10 makes the surface oxidation of additive alloy 16.This situation as shown in Figure 1.In this case, zone of oxidation 19 covers additive alloy powders particle 16, therefore reduces the overall consistency of particle 16, makes particulate buoyancy greater than steel 10.For example, the density of Nb is 8.57gm/m
3, Nb
2O
5Density be 4.47gm/m
3, and the density of steel is 7.6gm/m
3Fig. 2 shows that more low-density oxide alloy rises towards the surface of molten steel 10.In other cases, oxide skin 19 becomes the blocking layer of additive for fusing alloy core 16.For example, the temperature of fusion of 70%FeTi is 1085 ℃, and TiO
2Temperature of fusion be 1850 ℃, still, the temperature of molten steel 10 is about 1600 ℃ usually.In Fig. 3, shown this problem.The effect of these mechanism is to rise to the slag surface at additive alloy particle 16 not make it be dissolved in melt metal 10 fully before being absorbed.
In other currently known methodss, the purpose that additive alloy 16 is injected molten bath 10 is to be formed with nitride and/or the carbide that benefits the finished product.For many years, in order to increase the nitrogen content in its molten bath 10, the steel manufacturer uses calcium cyanamide (CaCN
2).Referring to, for example United States Patent (USP) the 3rd, 322, No. 530.In addition, find when adopting that No. 114 described contains the core metal silk and be injected in the molten bath 10 and add CaCN according to United States Patent (USP) the 4th, 897
2The time, significantly improved the nitrogen recovery.
Although the improvement in these prior art fields is arranged, still need to improve at molten metal the particularly recovery in the molten steel.
Summary of the invention
The present invention includes alloy delivery device.This delivery device can comprise the blend with at least a additive alloy and at least a reductor.This blend can cover with elongated shell.This shell can be the wire of basic hollow, and described blend is packed into wherein.
At least a additive alloy can be FeNb, FeV or FeTi.At least a reductor can be Ca, CaSi, Si, Al or CaCN
2Reductor can be to comprise diameter usually less than 1 millimeter particulate powder.Additive alloy can be general diameter less than 1 millimeter abrasive flour particle.Reductor content is generally the 5-50% of mixture weight or volume.
The present invention includes the method that additive alloy is provided to molten metal, wherein, at least a reductor and at least a additive alloy blending provide blend.This blend can be packed in the metal shell, and alloy delivery device is provided.Can prepare molten metal, and alloy delivery device is sent in the molten metal.This delivery device can be sent in the molten metal, shell is melted in molten metal.After the blend fusing, it is mixed with molten metal, thereby blend is distributed in the molten metal.
In an embodiment of the invention, can improve the recovery of the alloying additive in the molten steel in the following manner, deoxidizing powder and additive alloy mixed with different amount (typically but be not limited to the 5-50% of mixture weight or volume), and described additive alloy is such as but not limited to Ca, CaSi, Si, Al, CaCN
2Deng.Be not wishing to be bound by theory, the inventor believes, when deoxidation powder and additive alloy agent blending, and is included in and contains in the core metal silk, when this is contained the core metal silk and injects the molten bath, discharging described deoxidizing powder near the additive alloy powders place.The dissolved oxygen component reaction of deoxidation powder and molten metal is producing oxygen-depleted zone with additive alloy particulate same area.Equally, in containing the core metal silk with CaCN
2The situation of the additive alloy blending of powder and formation nitride and/or carbide, the zone that discharges described powder in the molten bath is oxygen deprivation and is rich in carbon and nitrogen.Therefore, the invention provides molten steel that additive increases or that alloy increases, improve simultaneously and reclaim.
Accompanying drawing is briefly described
For understanding characteristic of the present invention and purpose fully, should be with reference to the accompanying drawings and following description.Speak briefly, accompanying drawing is as follows:
Fig. 1 shows the method for prior art, in this method, and oxygen enriched molten bath and additive alloy reaction, thereby on additive alloy core, form oxide skin.
Fig. 2 shows that oxide skin has reduced density in art methods, therefore increases the buoyancy of additive alloy in molten steel pond (mo1ten steel bath).
Fig. 3 shows the oxide skin of high melting temperature, and this layer is used as the additive alloy core dissolved blocking layer to low melting temperature.
Fig. 4 shows an embodiment of the invention, wherein CaCN
2Particle and oxygen react in the molten bath and produce oxygen-depleted zone.Carbon and nitrogen are discharged in the molten bath simultaneously, make it to be enriched in the oxygen-depleted zone.
Fig. 5 shows an embodiment of the invention, and wherein, reductor is not discharged into carbon or nitrogen in the molten bath.
Fig. 6 is the schematic flow sheet of the inventive method.
Detailed Description Of The Invention
The present invention is used in to make to reclaim in the molten steel additive increase or that alloy increases and improves.Be not wishing to be bound by theory, the inventor believes, adds deoxidizing powder 31 to the additive alloy powders that contains the core metal silk 28 that is used for injecting the molten bath and can cause deoxidizing powder 31 and be included in reaction between the Sauerstoffatom in molten bath 10.This reaction reduces the oxygen level of regional area 34, at this zone release additives powdered alloy 28.This situation can be known from Fig. 4 and Fig. 5.By reducing the oxygen level of molten bath in zone 34, additive alloy powders 28 is in the mode that this zone 34 discharges, and can significantly reduce the oxidized amount of these additive alloy powders 28, the therefore recovery that improves additive alloy 28.By improving the recovery of additive alloy 28, can reduce the amount that needs to inject molten metal 10, therefore saved Metal Production merchant's time and money.In addition, by improve reclaiming, the predictability of the final chemical property of molten steel and repeatability become higher-these two all be the desired process characteristic.
In an embodiment of the invention, provide alloy delivery device.Alloy delivery device can comprise the blend of additive alloy and reductor, and additive alloy for example has FeNb, FeV or FeTi, and reductor is Ca, CaSi, Si, Al or CaCN
2This blend can be contained in the elongated metal shell.
Unlike the prior art, the inventor has recognized that, if with CaCN
2(as FeNb, FeV FeTi) makes up, and adds the molten bath by containing core metal silk injection system then, and deoxidation and/or carbonization and nitrogenize might take place to form thing with specific oxidable nitride and/or carbide.CaCN is worked as in Fig. 4 demonstration
2Particle 31 with form nitride/or the additive alloy 28 of carbide in containing the core metal silk during blending, CaCN
2Particle 31 forms zone 34 around additive alloy particle 28, oxygen level reduces in this zone, and carbon content and nitrogen content increase.
In preferred embodiment, reductor is a powder type, and the particle diameter of its particle is usually less than 1 millimeter, and additive alloy is the abrasive flour form, and the particle diameter of its particle is usually less than 1 millimeter.In another preferred implementation, the content of reductor is generally the 5-50% of the weight or meausurement of mixture.
Fig. 6 shows method of the present invention.In a kind of such method, 100, Ca, CaSi, Si, Al or CaCN
2Reductor and additive alloy blending, additive alloy can be FeNb, FeV or FeTi.103, in the metal shell of the material of blending can being packed into, so that alloy delivery device to be provided.Then, 106,,, described alloy delivery device is sent in the molten metal just 109 in case form molten metal such as molten steel pond.112, make the shell fusing, the material of blending is dispersed in the molten metal.Fig. 6 illustrates a kind of like this method.
The inventor believes, can make molten metal deoxidation and enriched in nitrogen and carbon compound (as CaCN simultaneously by blending in containing the core metal silk is a kind of
2) with form oxidable nitride and/powder of carbide, the zone that discharges this blend will show oxygen deprivation and enriched in nitrogen and carbon.The result is as previously described, has improved the additive recovery, have simultaneously in the finished product produce more nitride and/benefit of carbide.In this situation, can reduce the amount of the additive alloy of the formation nitride that injects the molten bath and/or carbide, the finished product will show the benefit of the increase that has increased nitride and/or carbide simultaneously.Therefore, can reduce production costs and improve product property.
Though described the present invention with regard to one or more embodiments, however, it should be understood that, under without departing from the spirit and scope of the present invention, can constitute other embodiments of the present invention.Therefore, the present invention only is subjected to the restriction of appended claims and its proper explanations.
Claims (12)
1. alloy delivery device, this device comprises:
At least a additive alloy; With
At least a reductor, this reductor and described alloy blending provide blend; With
Elongated shell around this blend.
2. alloy delivery device as claimed in claim 1 is characterized in that at least a additive alloy is selected from down group: FeNb, FeV and FeTi.
3. alloy delivery device as claimed in claim 1 is characterized in that described reductor is selected from down group: Ca, CaSi, Si, Al and CaCN
2
4. alloy delivery device as claimed in claim 1 is characterized in that, at least a reductor is to comprise diameter less than 1 millimeter particulate powder.
5. alloy delivery device as claimed in claim 1 is characterized in that, at least a additive alloy comprises that diameter is less than 1 millimeter abrasive flour particle.
6. alloy delivery device as claimed in claim 1 is characterized in that, the content of at least a reductor is the 5-50% of the weight or meausurement of mixture.
7. one kind provides the method for additive alloy to molten metal, and this method comprises:
With at least a reductor and at least a additive alloy blending, provide blend;
The blend of reductor and additive alloy is packed in the metal shell, alloy delivery device is provided;
The preparation molten metal;
Described alloy delivery device is sent in the molten metal.
8. method as claimed in claim 7 is characterized in that described molten metal is a steel.
9. method as claimed in claim 7 is characterized in that at least a reductor is selected from down group: Ca, CaSi, Si, Al and CaCN
2
10. method as claimed in claim 7 is characterized in that at least a additive alloy is selected from down group: FeNb, FeV and FeTi.
11. method as claimed in claim 7 is characterized in that, described method also comprises the step that makes the shell fusing.
12. method as claimed in claim 7 is characterized in that, described method also comprises blend dispersive step.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US93867107P | 2007-05-17 | 2007-05-17 | |
| US60/938,671 | 2007-05-17 | ||
| PCT/US2008/064062 WO2008144617A1 (en) | 2007-05-17 | 2008-05-19 | Enhanced alloy recovery in molten steel baths utilizing cored wires doped with deoxidants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101688260A true CN101688260A (en) | 2010-03-31 |
Family
ID=40122183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200880023283A Pending CN101688260A (en) | 2007-05-17 | 2008-05-19 | Utilize the core metal silk that contains of doping reductor to improve the recovery of molten steel bath interalloy |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US20080314199A1 (en) |
| EP (1) | EP2158337A4 (en) |
| JP (1) | JP2010527410A (en) |
| KR (1) | KR20100029078A (en) |
| CN (1) | CN101688260A (en) |
| AT (1) | AT507365A2 (en) |
| BR (1) | BRPI0811753A2 (en) |
| CA (1) | CA2686285A1 (en) |
| CZ (1) | CZ2009857A3 (en) |
| DE (1) | DE112008001288T5 (en) |
| ES (1) | ES2343302B1 (en) |
| FI (1) | FI20096347A (en) |
| GB (1) | GB2461239A (en) |
| MX (1) | MX2009012438A (en) |
| PL (1) | PL390678A1 (en) |
| RU (1) | RU2529132C2 (en) |
| SE (1) | SE0901523L (en) |
| SK (1) | SK500572009A3 (en) |
| TR (1) | TR200908693T1 (en) |
| WO (1) | WO2008144617A1 (en) |
| ZA (1) | ZA200908515B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2007006005A (en) * | 2004-11-22 | 2007-06-08 | Invista Tech Sarl | Process for crystallizing and solid state polymerizing polymers and the coated polymer. |
| AU2007240780B2 (en) | 2006-04-20 | 2014-01-16 | Sonendo, Inc. | Apparatus and methods for treating root canals of teeth |
| US7980854B2 (en) | 2006-08-24 | 2011-07-19 | Medical Dental Advanced Technologies Group, L.L.C. | Dental and medical treatments and procedures |
| JP5157889B2 (en) * | 2008-12-26 | 2013-03-06 | 日立電線株式会社 | Copper alloy ingot manufacturing method and active element addition method |
| WO2014210220A2 (en) | 2013-06-26 | 2014-12-31 | Sonendo, Inc. | Apparatus and methods for filling teeth and root canals |
| CN114807729A (en) * | 2018-08-01 | 2022-07-29 | 浙江大隆合金钢有限公司 | Production method of 05Cr17Ni4Cu4Nb steel |
| CA3031491C (en) | 2019-01-03 | 2020-03-24 | 2498890 Ontario Inc. | Systems, methods, and cored wires for treating a molten metal |
| USD997355S1 (en) | 2020-10-07 | 2023-08-29 | Sonendo, Inc. | Dental treatment instrument |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4917930B1 (en) | 1962-08-24 | 1974-05-07 | ||
| US3829312A (en) * | 1972-01-04 | 1974-08-13 | Nat Res Inst Metals | Process for the manufacture of steel of good machinability |
| US3915693A (en) * | 1972-06-21 | 1975-10-28 | Robert T C Rasmussen | Process, structure and composition relating to master alloys in wire or rod form |
| BE819608A (en) * | 1974-09-06 | 1974-12-31 | FURNISHED WIRES FOR ELECTROGAS WELDING. | |
| GB1554104A (en) * | 1975-07-23 | 1979-10-17 | British Steel Corp | Refining liquid metal |
| GB1504250A (en) | 1975-12-05 | 1978-03-15 | Hoesch Werke Ag | Addition of wire to a metal melt |
| FR2476542B1 (en) * | 1980-02-26 | 1983-03-11 | Vallourec | |
| US4483710A (en) * | 1981-03-31 | 1984-11-20 | Union Carbide Corporation | Addition agent for adding vanadium to iron base alloys |
| US4663244A (en) * | 1983-09-09 | 1987-05-05 | Messer Griesheim Gmbh | Filler containing easily oxidizable elements |
| FR2612945B1 (en) * | 1987-03-24 | 1993-08-13 | Affival | PROCESS FOR PREPARING LEAD-CONTAINING FERROUS METALS AND FILLED WIRE FOR IMPLEMENTING THE PROCESS |
| DE3739154A1 (en) * | 1987-11-19 | 1989-06-01 | Sueddeutsche Kalkstickstoff | LEADING ADDITIVE FOR STEEL MELTING |
| DE3739156A1 (en) * | 1987-11-19 | 1989-06-01 | Sueddeutsche Kalkstickstoff | NITROGEN ADDITIVE FOR STEEL MELTING |
| DE3924558C1 (en) * | 1989-07-25 | 1990-11-22 | Skw Trostberg Ag, 8223 Trostberg, De | |
| DE4138231C1 (en) * | 1991-11-21 | 1992-10-22 | Skw Trostberg Ag, 8223 Trostberg, De | |
| RU2000335C1 (en) * | 1992-01-08 | 1993-09-07 | Владимир Андреевич Паршин | Method of treating molten steel |
| DE4236727C2 (en) * | 1992-10-30 | 1997-02-06 | Sueddeutsche Kalkstickstoff | Melting agent and its use |
| RU2061762C1 (en) * | 1993-02-18 | 1996-06-10 | Институт новой металлургической технологии | Method of treating steel in ladle |
| ES2195768B1 (en) * | 2002-02-13 | 2005-03-01 | Juan Asensio Lozano | MANUFACTURING PROCEDURE OF A STEEL AUSTENITICO TO THE MICROALEATED STEEL AND STEEL AS OBTAINED. |
| GB2422618A (en) * | 2005-01-28 | 2006-08-02 | Injection Alloys Ltd | Molten metal refining wire |
-
2008
- 2008-05-19 TR TR2009/08693T patent/TR200908693T1/en unknown
- 2008-05-19 MX MX2009012438A patent/MX2009012438A/en unknown
- 2008-05-19 DE DE112008001288T patent/DE112008001288T5/en not_active Withdrawn
- 2008-05-19 CA CA002686285A patent/CA2686285A1/en not_active Abandoned
- 2008-05-19 PL PL390678A patent/PL390678A1/en not_active Application Discontinuation
- 2008-05-19 CN CN200880023283A patent/CN101688260A/en active Pending
- 2008-05-19 US US12/122,889 patent/US20080314199A1/en not_active Abandoned
- 2008-05-19 CZ CZ20090857A patent/CZ2009857A3/en unknown
- 2008-05-19 KR KR1020097024596A patent/KR20100029078A/en not_active Application Discontinuation
- 2008-05-19 BR BRPI0811753-5A2A patent/BRPI0811753A2/en not_active Application Discontinuation
- 2008-05-19 RU RU2009146821/02A patent/RU2529132C2/en active
- 2008-05-19 EP EP08769509A patent/EP2158337A4/en not_active Withdrawn
- 2008-05-19 AT AT0916108A patent/AT507365A2/en not_active Application Discontinuation
- 2008-05-19 SK SK50057-2009A patent/SK500572009A3/en unknown
- 2008-05-19 JP JP2010508627A patent/JP2010527410A/en active Pending
- 2008-05-19 SE SE0901523A patent/SE0901523L/en not_active Application Discontinuation
- 2008-05-19 WO PCT/US2008/064062 patent/WO2008144617A1/en active Application Filing
- 2008-05-19 ES ES200950056A patent/ES2343302B1/en not_active Withdrawn - After Issue
-
2009
- 2009-11-16 GB GB0919971A patent/GB2461239A/en not_active Withdrawn
- 2009-12-01 ZA ZA200908515A patent/ZA200908515B/en unknown
- 2009-12-17 FI FI20096347A patent/FI20096347A/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| SE0901523A0 (en) | 2010-02-12 |
| FI20096347A (en) | 2009-12-18 |
| CZ2009857A3 (en) | 2010-03-03 |
| AT507365A2 (en) | 2010-04-15 |
| US20080314199A1 (en) | 2008-12-25 |
| JP2010527410A (en) | 2010-08-12 |
| EP2158337A4 (en) | 2010-11-03 |
| CA2686285A1 (en) | 2008-11-27 |
| ZA200908515B (en) | 2010-08-25 |
| KR20100029078A (en) | 2010-03-15 |
| SK500572009A3 (en) | 2010-03-08 |
| ES2343302B1 (en) | 2011-06-17 |
| MX2009012438A (en) | 2010-04-27 |
| SE0901523L (en) | 2010-02-12 |
| RU2529132C2 (en) | 2014-09-27 |
| GB0919971D0 (en) | 2009-12-30 |
| PL390678A1 (en) | 2010-10-25 |
| BRPI0811753A2 (en) | 2014-11-11 |
| WO2008144617A1 (en) | 2008-11-27 |
| RU2009146821A (en) | 2011-06-27 |
| EP2158337A1 (en) | 2010-03-03 |
| ES2343302A1 (en) | 2010-07-27 |
| TR200908693T1 (en) | 2010-04-21 |
| GB2461239A (en) | 2009-12-30 |
| DE112008001288T5 (en) | 2010-07-15 |
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