Embodiment
Below in conjunction with accompanying drawing and a plurality of embodiment, the circuit board of the technical program is described in further detail.
See also Fig. 1, the circuit board 10 of the technical program first embodiment comprise first conductive layer 11, second conductive layer 12 and be arranged at first conductive layer 11 and second conductive layer 12 between composite layer 13.
First conductive layer 11 has first conducting wire 110 and first conductive junction point 111.Second conductive layer 12 has second conducting wire 120 and second conductive junction point, 121, the second conductive junction points 121 are corresponding with first conductive junction point 111.First conducting wire 110 and second conducting wire 120 all are used to realize the transmission of signal, and first conductive junction point 111 and second conductive junction point 121 all are used for being connected with electronic component.
Composite layer 13 has opposite first 130 and second surface 131.Described first surface 130 contacts with first conductive layer 11, and described second surface 131 contacts with second conductive layer 12.Composite layer 13 comprises insulating body 132 and Duo Gen carbon nano-tube 133.Insulating body 132 is used for first conducting wire 110 and second conducting wire 120 at interval, so that first conducting wire 110 and 120 insulation of second conducting wire.The material of insulating body 132 can be the hard resin layer, as epoxy resin, glass cloth etc., also can be the flexible resin layer, as polyimides (Polyimide, PI), polyethylene terephthalate glycol (Polyethylene Terephtalate, PET), polytetrafluoroethylene (Teflon), poly-thiamines (Polyamide), polymethyl methacrylate (Polymethylmethacrylate), Merlon (Polycarbonate) or polyimides-polyethylene-terephthaldehyde's ester copolymer (Polyamide polyethylene-terephthalate copolymer) etc.Many carbon nano-tube 133 are closely arranged, and constitute a carbon nano tube bundle, and this carbon nano tube bundle is corresponding with first conductive junction point 111 and second conductive junction point 121, are used to be electrically connected first conductive junction point 111 and second conductive junction point 121.Particularly, the length of each carbon nano-tube 133 all equates with the thickness of insulating body 132, and the axis of each carbon nano-tube 133 is all perpendicular to first conductive layer 11 and second conductive layer 12.Each carbon nano-tube 133 all has the first relative end 134 and second end 135, and described first end 134 directly contacts with first conductive junction point 111, and described second end 135 directly contacts with second conductive junction point 121.In the present embodiment, the cross-sectional area of the carbon nano tube bundle that a plurality of carbon nano-tube 133 form is corresponding with the cross-sectional area of first conductive junction point 111 or second conductive junction point 121.
The manufacture method of circuit board 10 can may further comprise the steps:
The first step provides a substrate that is formed with catalyst film.
Second step, adopt chemical vapour deposition technique in described substrate, to grow carbon nano tube bundle with many carbon nano-tube 133, first end 134 of each carbon nano-tube 133 is connected with substrate, and second end 135 extends toward the direction away from substrate perpendicular to substrate.
The 3rd step made a plurality of carbon nano-tube 133 and insulating body 132 form one in modes such as pressing or castings, removed substrate again to obtain composite layer 13.Wherein, carbon nano tube bundle only is arranged at the precalculated position of composite layer 13, and first end 134 of carbon nano-tube 133 and second end 135 are exposed to the first surface 130 and the second surface 131 of composite layer 13 respectively.
The 4th step is at the first surface 130 and second surface 131 difference pressing first conductive layer 11 and second conductive layers 12 of composite layer 13.Wherein, first conductive layer 11 and second conductive layer 12 all can be Copper Foil, and combine with composite layer 13 by the mode of hot pressing.
The 5th step formed conductive pattern with first conductive layer 11, promptly formed first conducting wire 110 and first conductive junction point 111, and second conductive layer 12 is also formed conductive pattern, promptly formed second conducting wire 120 and second conductive junction point 121.Described first conductive junction point 111 is corresponding with first end 134, described second conductive junction point 121 is corresponding with second end 135, so that realize being electrically connected reliably by carbon nano-tube 133 between first conductive junction point 111 and second conductive junction point 121, thereby acquisition circuit board 10 as shown in Figure 1.
See also Fig. 2, the circuit board 10 that the circuit board 20 of the technical program second embodiment and first embodiment provide is roughly the same, and its difference is that many carbon nano-tube 233 disperse to be embedded in the insulating body 232 insulated from each otherly.That is, 233 one-tenth array-likes of a plurality of carbon nano-tube are evenly disperseed, and are filled with insulating body 232 between the adjacent carbon nano-tube 233.In the present embodiment, the length of each carbon nano-tube 233 is all less than the thickness of insulating body 232.Described first end 234 is embedded in the insulating body 232, is electrically connected with first conductive junction point 211 by first guide hole 236, and second end 235 is embedded in the insulating body 232, is electrically connected with second conductive junction point 221 by second guide hole 237.
Described first guide hole 236 is offered to first end 234 of carbon nano-tube 233 from first surface 230, fills full electric conducting material in it and is electrically connected with first the reliable of end 234 to realize first conductive junction point 211.Described second guide hole 237 is offered to second end 235 of carbon nano-tube 233 from second surface 231, also fills full electric conducting material in it and is electrically connected with second the reliable of end 235 to realize second conductive junction point 221.
This circuit board 20 can adopt following steps to make:
The first step provides a substrate 40 that is formed with catalyst film 41, as shown in Figure 3.
In second step, adopt chemical vapour deposition technique in described substrate 40, to grow many carbon nano-tube 233 of evenly disperseing to arrange, as shown in Figure 4.Second end 235 of each carbon nano-tube 233 is connected with the catalyst film 41 of substrate 40, and first end 234 extends toward the direction away from substrate 40 perpendicular to substrate 40.
In the 3rd step, form composite layer 23.
At first insulating material or its solution are put on many carbon nano-tube 233 in modes such as dip-coating, coating, pressing or castings, so that insulating material fully is filled in the space between the many carbon nano-tube 233, and coat first end 234 of each carbon nano-tube 233, and solidify described insulating material, as shown in Figure 5.
Secondly, see also Fig. 6, remove substrate 40.
Once more, apply one deck insulating material and solidify,, thereby obtain composite layer 23 as shown in Figure 7 so that insulating material coats second end 235 of each carbon nano-tube 233 at second end 235 of carbon nano-tube 233.
The 4th step, first hole 2360 is bored to expose first end 234 of carbon nano-tube 233 in precalculated position at the first surface 230 of composite layer 23, second hole 2370 is bored to expose second end 235 of carbon nano-tube 233, as shown in Figure 8 in the precalculated position on second surface 231.
Be appreciated that first hole 2360 and second hole 2370 can form by modes such as laser drill, machine drilling or chemical etchings.The degree of depth in first hole 2360 and second hole 2370 is as the criterion to expose carbon nanotube layer 231, in the present embodiment, for reduce the degree of depth in hole as far as possible, the degree of depth in first hole 2360 equals the distance between first end 234 of first surface 230 and carbon nano-tube 233, and the degree of depth in second hole 2370 equals the distance between second end 235 of second surface 231 and carbon nano-tube 233.
In the 5th step, respectively the hole conducting is carried out in described first hole 2360 and second hole 2370 and obtained first guide hole 236 and second guide hole 237.
Be appreciated that the hole conduction mode can be filling perforation conducting or plating hole conducting, adopts the filling perforation conduction mode in the present embodiment, promptly, to obtain first guide hole 236, the filled conductive materials are to obtain second guide hole 237, as shown in Figure 9 in past second hole 2370 toward first hole, 2360 interior filled conductive materials.Electric conducting material can be copper cream, silver paste, tin cream or conducting resinl etc.
The 6th step, first surface 230 and second surface 231 difference pressing first conductive layer 21 and second conductive layers 22 at composite layer 23, and with first conductive layer, 21 formation first conducting wires 210 and first conductive junction point, 211, the second conductive layers, 22 formation second conducting wire 220 and second conductive junction points 221.First conductive junction point 211 is corresponding with first guide hole 236, second conductive junction point 221 is corresponding with second guide hole 237, so that realize being electrically connected by first guide hole 236, carbon nano-tube 233 and second guide hole 237 successively between first conductive junction point 211 and second conductive junction point 221.Wherein, first conducting wire 210 and second conducting wire 220 can form by steps such as influence transfer, etchings.
See also Figure 10, circuit board 30 that the technical program the 3rd embodiment provides and the circuit board 20 of second embodiment are roughly the same, its difference is that composite layer 33 comprises first insulating barrier 330, carbon nano pipe array layer 331 and second insulating barrier 332 that stacks gradually.Carbon nano pipe array layer 331 comprises many equal in length and compact arranged carbon nano-tube 333.
Particularly, described first insulating barrier 330 has opposite first 3300 and second surface 3301, and wherein, second surface 3301 contacts with first end 334 of carbon nano-tube 333.Second insulating barrier 332 has the 3320 and the 4th surface 3321, relative the 3rd surface, and wherein, described the 3rd surface 3320 contacts with second end 335 of carbon nano-tube 333.First guide hole 336 is opened in first insulating barrier 330, and corresponding with first conductive junction point 311.First guide hole 336 runs through first surface 3300 and second surface 3301, fills full electric conducting material in it, is electrically connected with first the reliable of end 334 to realize first conductive junction point 311.Second guide hole 337 is opened in second insulating barrier 332, and corresponding with second conductive junction point 312.Second guide hole 337 runs through the 3320 and the 4th surface 3321, the 3rd surface, fills full electric conducting material in it, is electrically connected with second the reliable of end 335 to realize second conductive junction point 312.
The step of the manufacture method of this circuit board 30 and circuit board 20 roughly the same.In the present embodiment, composite layer 33 is first insulating barrier 330, carbon nano pipe array layer 331 and second insulating barrier 332 to be formed at one by the pressing mode obtain.
The circuit board of the technical program comprises composite layer, described composite layer has insulating body and carbon nano-tube, insulating body is used for the conducting wire of different conductive layers at interval, carbon nano-tube is used for the conductive junction point of different conductive layers is electrically connected, thereby improves the electrical connection between each conductive layer of circuit board.Because carbon nano-tube has high conductivity and favorable mechanical performance, therefore, the electrical connection between each conductive layer of circuit board has high-reliability, in addition, because carbon nano-tube has high-termal conductivity, can make that also circuit board has good heat-conducting.
Be understandable that, for the person of ordinary skill of the art, can make other various corresponding changes and distortion by technical conceive according to the present invention, and all these change the protection range that all should belong to claim of the present invention with distortion.