CN101665891A - Stainless heat-resistant alloy steel seamless steel tube and preparation method thereof - Google Patents

Stainless heat-resistant alloy steel seamless steel tube and preparation method thereof Download PDF

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Publication number
CN101665891A
CN101665891A CN200910101878A CN200910101878A CN101665891A CN 101665891 A CN101665891 A CN 101665891A CN 200910101878 A CN200910101878 A CN 200910101878A CN 200910101878 A CN200910101878 A CN 200910101878A CN 101665891 A CN101665891 A CN 101665891A
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resistant alloy
seamless steel
alloy steel
steel tube
temperature
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蒋淮海
陈培良
苏诚
王长城
丁文炎
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Zhejiang Jiuli Hi Tech Metals Co Ltd
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Abstract

The invention relates to a stainless heat-resistant alloy steel seamless steel tube and a preparation method thereof. The seamless steel tube comprises the following chemical compositions by weight percent: 0.04-0.10% of C, 0.75% or less of Si, 2.00% or less of Mn, 0.03% or less of P, 0.03% or less of S, 17.00-23.00% of Ni, 24.00-26.00% of Cr, 0.20-0.60% of Nb+Ta, 0.15-0.35% of N and the balance Fe and inevitable trace elements. The preparation method of the invention adopts hot extrusion and cold rolling, computer automatic control solution heat treatment and other advanced technologies. Theproduct of the invention has excellent mechanical performance, high temperature resistant and corrosion resistance and various technical indexes of the product all meet or exceed Chinese relevant technical standards, thus successfully providing a new kind of qualified tube for the ultra supercritical power station boiler.

Description

Stainless heat-resistant alloy steel seamless steel tube and production method thereof
Technical field
The present invention relates to a kind of alloy steel pipe and production method thereof.
Background technology
Ultra supercritical station boiler pipe is a kind of high performance alloys steel pipe, and it must possess the performance of mechanical behavior under high temperature, creep rupture strength and high temperature resistance flue gas corrosion, high temperature resistance carbonated drink dielectric corrosion, also should possess good welding and process industrial art performance simultaneously.At present, China still can not produce with pipe for this high performance boiler, can only rely on import, and inlet pipe not only costs an arm and a leg, and inadequate resource, and it is untimely to supply, thereby has seriously restricted the production and the development of China's ultra supercritical station boiler.
Summary of the invention
Purpose of the present invention provides a kind of be particularly suitable for ultra supercritical station boiler stainless heat-resistant alloy steel seamless steel tube and production method thereof.
Technical solution of the present invention is: a kind of stainless heat-resistant alloy steel seamless steel tube, its Chemical Composition is by weight percentage: C 0.04~0.10, Si≤0.75, Mn≤2.00, P≤0.03, S≤0.03, Ni 17.00~23.00, and Cr 24.00~26.00, and Nb+Ta 0.20~0.60, N 0.15~0.35, and surplus is Fe and inevitably micro-.
The normal temperature mechanical property technical indicator of described stainless heat-resistant alloy steel seamless steel tube is: yield strength 〉=295MPa, tensile strength 〉=655MPa, unit elongation A% 〉=30, hardness≤256HB/100HRB; Metallographic structure is an austenite; Grain fineness number is 4~7 grades.
The production method of described stainless heat-resistant alloy steel seamless steel tube comprises following processing step:
The heating of pipe bar → examination → aligning → crop end → peeling → segmentation → boring → end face processing → reconditioning → cleaning → preheating → once → lubricated → reaming → second-heating → lubricate → be squeezed into female pipe → hardening → aligning → sawing → pickling → inspection → cold rolling → deoil → solution heat treatment → aligning → sawing → pickling → nondestructive testing → finishing reconditioning → finished product packing is put in storage.
Described bar is that the Chemical Composition that adopts " electric furnace+external refining " production technique to reach described stainless heat-resistant alloy steel seamless steel tube requires.
Described preheating temperature is 800~850 ℃.
The described once temperature of heating is that the reaming temperature is controlled to be 1180~1200 ℃.
The temperature that the temperature of described second-heating promptly is squeezed into female pipe is controlled to be 1200~1220 ℃.
Described cold rolling be to adopt one roughing to add two passage cold-rolling process of one finish rolling.
The temperature of described solution heat treatment: the semifinished tube of roughing system is controlled to be 1100~1150 ℃, and the production tube after the finish rolling is controlled to be 1180~1250 ℃.
The invention has the beneficial effects as follows: successfully for the ultra supercritical station boiler provides a kind of qualified new variety with managing, its every technical indicator all meets or exceeds the regulation of national relevant technologies standard.The outstanding advantage of the inventive method is: the pipe bar that, has adopted " electric furnace+external refining " production technique to produce has guaranteed that product chemistry ingredient stability is qualified; Two, adopted hot extrusion+cold rolling weldless steel tube moulding advanced technologies, earlier with hot reaming and the female pipe of twice deformation process explained hereafter of hot extrusion, has three-dimensional compressive stress, the advantage of aximal deformation value, improved the compactness of pipe metal, refinement crystal grain, reduced each to performance difference, and wherein pipe is held in both hands and is expected to add thermal recovery " preheating+high temperature section rapid heating " technology, guaranteed that the pipe low-temperature prewarming is even, secondary pollution when preventing high temperature, reduce the pipe surface oxidation, adopted one roughing to add two passage cold-rolling process of one finish rolling then, guaranteed that moulding tube-surface quality is good, dimensional precision height and high comprehensive performance; Three, in the steel pipe solution heat treatment technology, heating fuel adopts the Sweet natural gas of cleaning, can effectively prevent the pollution of steel pipe harmful elements such as S, P when high temperature, combustion system adopts the high combustion rate burner burning, the furnace atmosphere good fluidity, the temperature field boundary is even, and adopts computer controlled automatic to comprise the processing parameters such as furnace roller speed, furnace atmosphere ratio of combustion and cooling injection flow rate of Heating temperature, regulation and control heating and soaking time, makes steel pipe solution heat treatment technological process accurate, stable, reliable.
Description of drawings
Fig. 1 is that the high temperature, short time tensile strength of this product steel pipe (φ 63.4 * 12) varies with temperature graphic representation.
Fig. 2 is 700 ℃ of high-temperature and durable graphic representations of this product steel pipe.
Embodiment
The invention will be further described with embodiment below.
A kind ofly be particularly suitable for ultra supercritical station boiler stainless heat-resistant alloy steel seamless steel tube, the pipe bar that is adopted is Ф 210mm, and its Chemical Composition is by weight percentage: C 0.04~0.10, Si≤0.75, Mn≤2.00, P≤0.03, S≤0.03, Ni 17.00~23.00, Cr 24.00~26.00, Nb+Ta0.20~0.60, N 0.15~0.35, and surplus is Fe and inevitably micro-.
The production method of described stainless heat-resistant alloy steel seamless steel tube comprises following processing step:
The heating of pipe bar → examination → aligning → crop end → peeling → segmentation → boring → end face processing → reconditioning → cleaning → preheating → once → lubricated → reaming → second-heating → lubricate → be squeezed into female pipe → hardening → aligning → sawing → pickling → inspection → slightly cold rolling → deoil → solution heat treatment → aligning → sawing → pickling → inspection → pinch pass → deoil → solution heat treatment → aligning → sawing → pickling → nondestructive testing → finishing reconditioning → finished product packing is put in storage.
Wherein:
The peeling operation is by long material peeling machine peeling to be carried out on pipe bar surface, pricks defectives such as trace and crack with oxide skin, the forging of eliminating pipe bar surface, and pipe bar diameter tolerance is 204 ± 0.5mm after the peeling, surfaceness≤1.6 μ m.
The pipe bar through boring processing before the extruding adds thermal recovery syllogic heating process, i.e. preheating, once heating, second-heating.Preheating is to carry out full and uniform low-temperature heat in the ring furnace that is medium with the Sweet natural gas, and temperature is controlled at 800~850 ℃, and the time is 120~180 minutes, and purpose is the secondary pollution that prevents when high temperature, reduces the oxidation on pipe surface; Once heating is the pipe bar after the preheating to be sent into controlled line frequency induction furnace be heated rapidly to the reaming temperature, promptly 1180~1200 ℃, delivers to staving press then and adopts glass lubricant to carry out reaming and get the uniform hollow billet of wall thickness; Second-heating is the reaming hollow billet to be sent into controlled line frequency induction furnace be heated rapidly to extrusion temperature, promptly 1200~1220 ℃, and be sent to 3500 tons of extruding units immediately and be squeezed into female pipe, extrusion lubricant adopts glass lubricant.The female pipe of present embodiment moulding specification is Ф 108 * 17mm and Ф 108 * 9mm.
Cold rolling process, female pipe is after hardening cooling, aligning, pickling, adopt one roughing to add two passage cold-rolling process of one finish rolling, make the semifinished tube of Ф 89 * 14.75mm and Ф 89 * 6.5mm through roughing, the production tube of Ф 63.4 * 12mm and Ф 60 * 4mm is made in finish rolling again.
The solution heat treatment operation, with the semifinished tube surface of roughing system deoil handle after, send into and carry out solution heat treatment in the roller bottom type continuous heat treating furnace, thermal treatment temp is controlled to be 1100~1150 ℃, soaking time 20~40 minutes; And the production tube solution heat treatment temperature after the finish rolling is controlled to be 1180~1250 ℃, soaking time 15~40 minutes; The solution heat treatment heating fuel adopts the Sweet natural gas of cleaning, can effectively prevent the pollution of steel pipe harmful elements such as S, P when high temperature, combustion system adopts the high combustion rate burner burning, the furnace atmosphere good fluidity, the temperature field boundary is even, and adopt computer controlled automatic to comprise processing parameters such as Heating temperature, the furnace roller speed of regulation and control heat tracing time and furnace atmosphere air-fuel ratio, make steel pipe solution heat treatment technological process accurate, stable, reliable.
The stainless steel tube that comes out from finished product solution heat treatment operation promptly gets product after aligning, sawing, trimming and detection.The quality examination result of this product is as follows:
(1), above-mentioned Ф 63.4 * 12mm and Ф 60 * 4mm stainless heat-resistant alloy steel seamless steel tube product be through actual measurement, the external diameter of steel pipe, wall thickness and surface quality all meet the requirement of ASME SA213/SA213M-08 standard.
(2), the conventional chemical analysis of components of steel pipe table (Shanghai Power Equipment Research Institute's review report) as a result
Figure GA20185555200910101878301D00041
(3), the room temperature tensile performance test of steel pipe table (Shanghai Power Equipment Research Institute's review report) as a result
Figure GA20185555200910101878301D00042
The hardness test of steel pipe is table (Shanghai Power Equipment Research Institute's review report) as a result
Figure GA20185555200910101878301D00051
(4), Erichsen test table (Shanghai Power Equipment Research Institute's review report) as a result under each test temperature of steel pipe (φ 63.4 * 12)
Figure GA20185555200910101878301D00052
Figure GA20185555200910101878301D00061
The high temperature, short time tensile strength of steel pipe (φ 63.4 * 12) varies with temperature graphic representation, sees accompanying drawing 1.
(5), the grain fineness number of steel pipe and microstructure test-results table (Shanghai Power Equipment Research Institute's review report)
Figure GA20185555200910101878301D00062
(6), 700 ℃, 100,000 hours creep rupture strength of extrapolated sample pipe is 71.2Mpa, its 700 ℃ of high-temperature and durable graphic representations (Harbin Boiler Co., Ltd.'s evaluation report) are seen accompanying drawing 2.
(7), Steel Welded Joint tensile test at room temperature table (Shanghai Furnace Factory Co., Ltd's evaluation report) as a result
Material Heat treatment state ??Rp0.2(Mpa) ?Rm(Mpa) Fracture position
φ 63.4 * 12 steel pipes As-welded ??494 ??471 ?761 ?759 Outside the weldering matter outside weld matter
(8), SA-213-TP310HCbN welding joint high-temperature short delay stretching performance table (Shanghai Furnace Factory Co., Ltd's evaluation report)
(9), Steel Welded Joint Impulse Test Result table (Shanghai Furnace Factory Co., Ltd's evaluation report)
The extension performance and the impact property of Steel Welded Joint are good.
(10), welding joint pliability test table (Shanghai Furnace Factory Co., Ltd's evaluation report) as a result
Material Face is bent (D=3T, a=180 °) The back of the body curved (D=3T, a=180 °)
φ 63.4 * 12 steel pipes Qualified, qualified Qualified, qualified
The unit elongation of steel pipe is better, and process industrial art performance is good, can satisfy the distortion bend pipe of different demands.
Show that by last detected result this stainless heat-resistant alloy steel seamless steel tube product can satisfy the ultra supercritical station boiler with technical requirementss such as the mechanical behavior under high temperature of pipe, creep rupture strength and good welding and process industrial art performances.

Claims (9)

1, a kind of stainless heat-resistant alloy steel seamless steel tube, it is characterized in that its Chemical Composition is by weight percentage: C 0.04~0.10, Si≤0.75, Mn≤2.00, P≤0.03, S≤0.03, Ni 17.00~23.00, and Cr 24.00~26.00, and Nb+Ta 0.20~0.60, N 0.15~0.35, and surplus is Fe and inevitably micro-.
2, by the described stainless heat-resistant alloy steel seamless steel tube of claim 1, it is characterized in that the technical indicator of its normal temperature mechanical property is: yield strength 〉=295MPa, tensile strength 〉=655MPa, unit elongation A% 〉=30, hardness≤256HB/100HRB; Metallographic structure is an austenite; Grain fineness number is 4~7 grades.
3, a kind of production method of stainless heat-resistant alloy steel seamless steel tube according to claim 1 is characterized in that comprising following processing step:
The heating of pipe bar → examination → aligning → crop end → peeling → segmentation → boring → end face processing → reconditioning → cleaning → preheating → once → lubricated → reaming → second-heating → lubricate → be squeezed into female pipe → hardening → aligning → sawing → pickling → inspection → cold rolling → deoil → solution heat treatment → aligning-→ sawing → pickling → nondestructive testing → finishing reconditioning → finished product packing puts in storage.
4,, it is characterized in that described bar is that the Chemical Composition that adopts " electric furnace+external refining " production technique to reach described stainless heat-resistant alloy steel seamless steel tube requires by the production method of the described stainless heat-resistant alloy steel seamless steel tube of claim 3.
5, by the production method of the described stainless heat-resistant alloy steel seamless steel tube of claim 3, it is characterized in that described preheating temperature is 800~850 ℃.
6,, it is characterized in that the described once temperature of heating is that the reaming temperature is controlled to be 1180~1200 ℃ by the production method of the described stainless heat-resistant alloy steel seamless steel tube of claim 3.
7, by the production method of the described stainless heat-resistant alloy steel seamless steel tube of claim 3, the temperature that the temperature that it is characterized in that described second-heating promptly is squeezed into female pipe is controlled to be 1200~1220 ℃.
8, by the production method of the described stainless heat-resistant alloy steel seamless steel tube of claim 3, it is characterized in that described cold rolling be to adopt one roughing to add two passage cold-rolling process of one finish rolling.
9, by the production method of claim 3 or 8 described stainless heat-resistant alloy steel seamless steel tubes, it is characterized in that the temperature of described solution heat treatment: the semifinished tube of roughing system is controlled to be 1100~1150 ℃, and the production tube after the finish rolling is controlled to be 1180~1250 ℃.
CN200910101878A 2009-08-29 2009-08-29 Stainless heat-resistant alloy steel seamless steel tube and preparation method thereof Pending CN101665891A (en)

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Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102434725A (en) * 2011-10-10 2012-05-02 刘群联 Method for manufacturing stainless steel seamless steel pipe with large caliber
CN102513388A (en) * 2011-11-30 2012-06-27 常州盛德无缝钢管有限公司 Manufacture method for inner-threaded steel pipe applied to supercritical or ultra supercritical fossil power unit
CN102925653A (en) * 2012-10-24 2013-02-13 安徽应升钢管制造有限公司 Technology for processing high-precision stainless steel seamless pipe through solution heat treatment
CN102974635A (en) * 2012-12-12 2013-03-20 山西太钢不锈钢股份有限公司 Extrusion method for molybdenum alloy seamless pipe
CN103056180A (en) * 2013-02-04 2013-04-24 山西太钢不锈钢股份有限公司 Hot extrusion process of thin-walled 23000mm ultralong pipe
CN103225011A (en) * 2013-04-24 2013-07-31 浙江久立特材科技股份有限公司 Solid melting annealing furnace hearth roll and manufacture method thereof
CN103243213A (en) * 2013-04-26 2013-08-14 山西太钢不锈钢股份有限公司 Method for preventing super duplex stainless steel seamless tube from hole reaming cracking before extrusion
CN103447760A (en) * 2013-08-12 2013-12-18 新兴铸管股份有限公司 Manufacturing method of N08028 seamless alloy steel pipe
CN103599957A (en) * 2013-11-18 2014-02-26 山西太钢不锈钢股份有限公司 Extruding molding method of austenitic stainless steel seamless pipe for hydrogenation cracking furnace
CN103695799A (en) * 2013-12-26 2014-04-02 浙江德传管业有限公司 Production process of heat-resistance stainless steel seamless steel pipes with ultra-fine grains
CN103692167A (en) * 2013-12-20 2014-04-02 攀钢集团江油长城特殊钢有限公司 Method for fabricating UNSN08028 oil sleeve
CN103981421A (en) * 2014-05-13 2014-08-13 南安市国高建材科技有限公司 Wear-resistant, heatproof, and anticorrosive pipe
CN104307921A (en) * 2014-10-20 2015-01-28 张家港市人和高精管有限公司 Seamless steel tube production process
CN104328324A (en) * 2014-11-12 2015-02-04 邯郸新兴特种管材有限公司 Production technique of iron-nickel-base alloy tube
CN104357760A (en) * 2014-12-06 2015-02-18 常熟市东鑫钢管有限公司 Heat-resistant stainless steel seamless steel pipe for high-pressure boiler
WO2015135343A1 (en) * 2014-03-14 2015-09-17 常熟市兰达兰基钢管附件有限公司 Multifunctional boiler pipe
CN112281084A (en) * 2020-11-06 2021-01-29 河北恒通管件集团有限公司 Processing technology of hydrogen-contacting high-pressure large-caliber thick-wall stainless steel pipe fitting
CN112760569A (en) * 2020-12-28 2021-05-07 湖州盛特隆金属制品有限公司 Heat-resistant pipe for nitrogen-containing and niobium-containing boiler and preparation method thereof
CN112846659A (en) * 2020-12-31 2021-05-28 上海久砾不锈钢管有限公司 Seamless method for stainless steel welded pipe and application thereof
CN114657322A (en) * 2022-04-20 2022-06-24 德新钢管(中国)有限公司 Large-caliber duplex stainless steel seamless steel pipe and preparation method and application thereof
CN116408363A (en) * 2023-04-06 2023-07-11 浙江久立特材科技股份有限公司 Preparation method of nickel-molybdenum corrosion-resistant alloy seamless pipe and prepared seamless pipe

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102434725A (en) * 2011-10-10 2012-05-02 刘群联 Method for manufacturing stainless steel seamless steel pipe with large caliber
CN102434725B (en) * 2011-10-10 2016-05-25 江西金盈新材料科技股份有限公司 A kind of manufacture method of large-caliber stainless steel seamless pipe
CN102513388A (en) * 2011-11-30 2012-06-27 常州盛德无缝钢管有限公司 Manufacture method for inner-threaded steel pipe applied to supercritical or ultra supercritical fossil power unit
CN102925653A (en) * 2012-10-24 2013-02-13 安徽应升钢管制造有限公司 Technology for processing high-precision stainless steel seamless pipe through solution heat treatment
CN102974635A (en) * 2012-12-12 2013-03-20 山西太钢不锈钢股份有限公司 Extrusion method for molybdenum alloy seamless pipe
CN102974635B (en) * 2012-12-12 2015-08-05 山西太钢不锈钢股份有限公司 The pressing method of molybdenum alloy seamless pipe
CN103056180A (en) * 2013-02-04 2013-04-24 山西太钢不锈钢股份有限公司 Hot extrusion process of thin-walled 23000mm ultralong pipe
CN103225011B (en) * 2013-04-24 2015-04-29 浙江久立特材科技股份有限公司 Solid melting annealing furnace hearth roll and manufacture method thereof
CN103225011A (en) * 2013-04-24 2013-07-31 浙江久立特材科技股份有限公司 Solid melting annealing furnace hearth roll and manufacture method thereof
CN103243213A (en) * 2013-04-26 2013-08-14 山西太钢不锈钢股份有限公司 Method for preventing super duplex stainless steel seamless tube from hole reaming cracking before extrusion
CN103447760A (en) * 2013-08-12 2013-12-18 新兴铸管股份有限公司 Manufacturing method of N08028 seamless alloy steel pipe
CN103447760B (en) * 2013-08-12 2015-12-02 新兴铸管股份有限公司 A kind of manufacture method of N08028 alloy seamless steel pipe
CN103599957A (en) * 2013-11-18 2014-02-26 山西太钢不锈钢股份有限公司 Extruding molding method of austenitic stainless steel seamless pipe for hydrogenation cracking furnace
CN103599957B (en) * 2013-11-18 2016-03-30 山西太钢不锈钢股份有限公司 A kind of extrusion process of hydrocracking stove austenitic stainless steel seamless pipe
CN103692167A (en) * 2013-12-20 2014-04-02 攀钢集团江油长城特殊钢有限公司 Method for fabricating UNSN08028 oil sleeve
CN103692167B (en) * 2013-12-20 2016-04-20 攀钢集团江油长城特殊钢有限公司 Manufacture the method for UNSN08028 tubing and casing
CN103695799A (en) * 2013-12-26 2014-04-02 浙江德传管业有限公司 Production process of heat-resistance stainless steel seamless steel pipes with ultra-fine grains
CN103695799B (en) * 2013-12-26 2016-08-31 浙江德传管业有限公司 A kind of production technology of ultra-fine grain heat-resistance stainless steel seamless steel pipe
WO2015135343A1 (en) * 2014-03-14 2015-09-17 常熟市兰达兰基钢管附件有限公司 Multifunctional boiler pipe
CN103981421A (en) * 2014-05-13 2014-08-13 南安市国高建材科技有限公司 Wear-resistant, heatproof, and anticorrosive pipe
CN104307921A (en) * 2014-10-20 2015-01-28 张家港市人和高精管有限公司 Seamless steel tube production process
CN104328324B (en) * 2014-11-12 2016-11-30 邯郸新兴特种管材有限公司 A kind of production technology of iron nickel base alloy pipe
CN104328324A (en) * 2014-11-12 2015-02-04 邯郸新兴特种管材有限公司 Production technique of iron-nickel-base alloy tube
CN104357760A (en) * 2014-12-06 2015-02-18 常熟市东鑫钢管有限公司 Heat-resistant stainless steel seamless steel pipe for high-pressure boiler
CN112281084A (en) * 2020-11-06 2021-01-29 河北恒通管件集团有限公司 Processing technology of hydrogen-contacting high-pressure large-caliber thick-wall stainless steel pipe fitting
CN112281084B (en) * 2020-11-06 2022-02-08 河北恒通管件集团有限公司 Processing technology of hydrogen-contacting high-pressure large-caliber thick-wall stainless steel pipe fitting
CN112760569A (en) * 2020-12-28 2021-05-07 湖州盛特隆金属制品有限公司 Heat-resistant pipe for nitrogen-containing and niobium-containing boiler and preparation method thereof
CN112846659A (en) * 2020-12-31 2021-05-28 上海久砾不锈钢管有限公司 Seamless method for stainless steel welded pipe and application thereof
CN114657322A (en) * 2022-04-20 2022-06-24 德新钢管(中国)有限公司 Large-caliber duplex stainless steel seamless steel pipe and preparation method and application thereof
CN116408363A (en) * 2023-04-06 2023-07-11 浙江久立特材科技股份有限公司 Preparation method of nickel-molybdenum corrosion-resistant alloy seamless pipe and prepared seamless pipe

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Application publication date: 20100310