A kind of liquid blast furnace slag granulation method and device thereof
Technical field
The present invention relates to a kind of liquid blast furnace slag granulation method and device thereof, belong to the technical field of blast furnace utilization of metallurgy industry.
Background technology
Blast furnace slag is a kind of well behaved silicate material, can be used as the raw material of producing material of construction and chemical fertilizer by processing.Liquid blast furnace is through quick cooling, its inside has little time to form crystallizable mineral and a part of chemical energy is stored in the vitreum of formation, thereby has a higher activity, blast furnace slag after chilling is handled has potential hydraulic gelling property, be good cement raw material, so the blast furnace slag that chilling is handled have great demand.
Simultaneously, the liquid blast furnace temperature belongs to high-grade residual heat resources between 1350 ℃ to 1500 ℃, has very high recycling and is worth.
China's liquid blast furnace mainly adopts the water quenching chilling to handle at present, and the blast furnace slag after the shrend can be used for making material of construction such as cement, and the problem that water quenching exists is: the water consumption is high; The a large amount of H that produce in the Water Quenching Slag process
2S and SO
xEnter atmosphere with steam, promote acid rain to form environmental pollution; The sensible heat of blast furnace slag does not obtain recycling; Water Quenching Slag water ratio height still needs drying treatment as cement raw material, needs to consume certain energy; System's power consumption is big; Contained subparticle is very serious to the wearing and tearing and the obstruction of parts such as water pump and valve in the flush slag recirculated water, and the system maintenance work amount is very big, has increased maintenance cost.
Shortcoming at blast furnace cinder water quenching technology; the seventies in 20th century external dry type chilling granulated bf slag that just begun one's study method; mainly contain wind quench method and centrifugal granulation method; the two all be at first that liquid blast furnace is fast broken, be solidified as small-particle, take technique means to reclaim the method for its sensible heat again.The wind method of quenching be with high-power granulation blower fan produce high pressure, high velocity air with slag stream dispel, the method for granulation, main drawback is that power consumption is big, equipment bulky complex, floor space are big, investment and working cost height.The centrifugal granulation method is to rely on centrifugal force that the high speed rotating of rotating disk or revolving cup produces with liquid blast furnace slag granulation; though do not need the such highly energy-consuming equipment of granulation blower fan; and the size distribution of grain slag is also less; but at high temperature the mechanical reliability of high speed rotating granulating device is relatively poor, and its adaptability to load change also remains to be proved conclusively.
The granulation of liquid blast furnace reclaims all significant for the utilization again of the such solid waste of blast furnace slag and liquid blast furnace sensible heat, study that a kind of power consumption is low, granulation is effective, simple structure, high reliability granulating method be very important.
Summary of the invention
The purpose of this invention is to provide a kind of power consumption dry granulation methods low, simple in structure and device.
Technical scheme of the present invention is as follows:
A kind of liquid blast furnace dry granulation methods; this method is that liquid blast furnace is flowed into the dry granulation device by diversion trench; carry the Dual-Phrase Distribution of Gas olid of solid particulate by the ejection of granulation nozzle; liquid blast furnace slag is broken under the impact of Dual-Phrase Distribution of Gas olid; and cooled and solidified is small-particle, discharges through slag-drip opening then.Gas in this method in the Dual-Phrase Distribution of Gas olid is pressurized air, high-pressure inert gas or high pressure steam; The pressure of described pressurized air and high-pressure inert gas is 0.05~1.0MPa, and the pressure of high pressure steam is 0.1~10.0MPa.Chemical reaction does not take place and remains solid-stately in flow process in solid particulate that the air-flow in the described Dual-Phrase Distribution of Gas olid carries and air-flow, and particle size range is 80% of the quality of the solid particulate of the 0.1~0.5mm solid particulate total mass that accounts for gas-entrained.
The invention provides a kind of liquid blast furnace dry granulation device, it is characterized in that: described liquid blast furnace slag granulation device comprises diversion trench, the cinder notch that falls, pelletizer, granulation nozzle and slag-drip opening, described diversion trench is built by laying bricks or stones with refractory materials and is formed, be arranged on the pelletizer top, the described cinder notch that falls is arranged on the bottom of diversion trench, and is communicated with the dry granulation device; The described cinder notch that falls is a taper shape wide at the top and narrow at the bottom; Pelletizer top is provided with at least one granulation nozzle, and granulation jet exit central axis and vertical direction angle α are greater than 0 ° and smaller or equal to 90 °; Described slag-drip opening is arranged on the lowest part of the bottom of dry granulation device.
In the technique scheme, described granulation nozzle can be single-sided arrangement, and the bottom surface of dry granulation device tilts along the axis direction of granulation nozzle.
In the technique scheme, described granulation nozzle can also be the bilateral symmetric arrangement, or is that center of circle hoop is arranged with the cinder notch center vertical line that falls.
The present invention compared with prior art has the following advantages and the high-lighting effect: the present invention adopts the air-flow that carries solid particulate as the granulation medium, has strengthened the surging force of liquid towards blast furnace slag, has strengthened the effect of dry granulation, and can reduce the air-flow consumption; Advantages such as that the present invention also has is simple in structure, environmental protection and energy saving.
Description of drawings
Fig. 1 is a liquid blast furnace slag granulation device granulation nozzle single-sided arrangement embodiment synoptic diagram provided by the present invention.
Fig. 2 is a liquid blast furnace slag granulation device granulation set of nozzles symmetric arrangement embodiment synoptic diagram provided by the present invention.
Among the figure: the 1-diversion trench; The 2-cinder notch that falls; 3-dry granulation device; 4-granulation nozzle; The 5-slag-drip opening.
Embodiment
Describe concrete structure, principle of work and the embodiment of this device in detail below in conjunction with accompanying drawing.
The present invention includes diversion trench 1, the cinder notch 2 that falls, dry granulation device 3, granulation nozzle 4, slag-drip opening 5.Diversion trench 1 is built by laying bricks or stones with refractory materials and is formed, and is arranged on the pelletizer top, and the diversion trench lower-most point is provided with cinder notch 2 and is communicated with dry granulation device 3, and the cinder notch 2 that falls is truncated cone-shaped, and is wide at the top and narrow at the bottom.Flow into diversion trench 1 from the liquid blast furnace of blast furnace residue channel or slag ladle, flow out and vertical drop enters pelletizer 3 from the cinder notch 2 that falls of diversion trench 1 bottom.Pelletizer 3 tops are provided with granulation nozzle 4, and granulation nozzle 4 outlet axis and vertical direction angle α are 0~90 °, can make the oblique cutting liquid blast furnace of granulation medium.Medium is the high velocity air that carries solid particulate in the granulation nozzle 4, forms the high speed Dual-Phrase Distribution of Gas olid.Be used for cutting, the Dual-Phrase Distribution of Gas olid entrained solids particulate carrier gas stream of granulation high-temperature liquid state blast furnace slag is pressurized air or high-pressure inert gas or high pressure steam; the pressure of employed pressurized air or high-pressure inert gas is 0.05~1.0MPa, and the pressure of high pressure steam is 0.1~10.0MPa.Chemical reaction does not take place and remains solid-state in flow process in solid particulate that carrier gas stream is carried and carrier gas stream.In the dirty process of liquid blast furnace, the high speed Dual-Phrase Distribution of Gas olid blows to liquid blast furnace with specific direction, and liquid blast furnace is broken, cooled and solidified is a small-particle fast in high speed Dual-Phrase Distribution of Gas olid striking process therewith.Because its density and momentum improve behind the air-flow entrained solids particle; can strengthen the surging force of air-flow liquid towards blast furnace slag greatly; thereby obtain the littler granulated bf slag particle of median size; strengthened the effect of granulation; under the prerequisite that guarantees the granulation effect; the consumption of high pressure gas be can reduce, thereby the power consumption of granulating device and the investment of equipment reduced.Granulation moving gaseouse medium entrained solid particle; can be blast furnace slag particle with certain grain size distribution, sand grains etc.; also can adopt other not with carrier gas stream generation chemical reaction and in flow process, remain solid-state solid particulate; can also be by carrying the particle that special component constitutes secretly; constitute with the composition that changes blast furnace slag, for the back utilization of blast furnace slag facilitates.Usually, the particle size range of carrying secretly in the Dual-Phrase Distribution of Gas olid is 80% of the quality of the solid particulate of the 0.1~0.5mm solid particulate total mass that accounts for gas-entrained, that is the solid grain size of 80wt% concentrates on 0.1~0.5mm in the Dual-Phrase Distribution of Gas olid, and the solid grain size of having only 10wt% is less than 0.1mm, and other has an appointment the solid grain size of 10wt% greater than 0.5mm.
Discharge pelletizer 3 smoothly for the ease of slag particle, the pelletizer bottom is for being in tilted layout, and slag-drip opening is located at the lowest part of pelletizer bottom.The granulation particle is discharged pelletizer 3 from slag-drip opening 5, enters in the follow-up heat-exchanger rig.
The granulation nozzle can be provided with two or more, and the granulation nozzle can single-sided arrangement, or symmetric arrangement, or is that center of circle hoop is arranged with the cinder notch center vertical line that falls.Fig. 1 is a liquid blast furnace dry granulation device granulation nozzle single-sided arrangement embodiment synoptic diagram; single or two be arranged on pelletizer top one side to plural granulation nozzle; as be more than two, then the granulation nozzle forms the granulation set of nozzles for being arranged in parallel up and down.Fig. 2 is a liquid blast furnace slag granulation system granulation nozzle symmetric arrangement synoptic diagram, and two or more granulation nozzles are arranged on the both sides on pelletizer top, symmetric arrangement; The granulation nozzle of the same side forms one group of granulation set of nozzles for being arranged in parallel up and down.Plural nozzle or set of nozzles can also be that center of circle hoop is arranged with the cinder notch center vertical line that falls.
Enter follow-up heat-exchanger rig heat exchange through the blast furnace slag particle of discharging from slag-drip opening after the granulation, produce hot blast or steam and use or generating for producing; From the hot gas that contains dust in addition that slag-drip opening is discharged, its heat content can be recycled, and for preventing dust pollution, this gas discharges after the fly-ash separator dedusting.
Blast furnace slag dry granulation methods involved in the present invention, its principle is to utilize the barotropic gas of having carried solid particulate secretly, form the high speed Dual-Phrase Distribution of Gas olid, under the guiding of variable capacity atomizer, high-speed impact mobile blast furnace slag, the pyritous molten slag is carried out horizontal or oblique cutting, and it is granular that the momentum exchange of gas-solid dual-phase jet and fluid slag is fragmented into molten slag; Cracked at molten slag is in the process that falls of particle and flight aloft because the radiating effect, and solidify rapidly on the blast furnace slag surface after cracked, finishes the dry granulation process.Control the flow of molten slag, and control direction, the gentle phase pressure of gas-solid flow rate of Dual-Phrase Distribution of Gas olid, can obtain the blast furnace slag solid particulate of different-grain diameter scope, so that follow-up Btu utilization.