CN101663383B - Floor cleaning composition with reduced foaming properties - Google Patents
Floor cleaning composition with reduced foaming properties Download PDFInfo
- Publication number
- CN101663383B CN101663383B CN200780052842XA CN200780052842A CN101663383B CN 101663383 B CN101663383 B CN 101663383B CN 200780052842X A CN200780052842X A CN 200780052842XA CN 200780052842 A CN200780052842 A CN 200780052842A CN 101663383 B CN101663383 B CN 101663383B
- Authority
- CN
- China
- Prior art keywords
- composition
- alkyl
- cleaning
- floor
- branching
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 77
- 238000004140 cleaning Methods 0.000 title claims abstract description 57
- 238000005187 foaming Methods 0.000 title description 4
- -1 polysiloxane Polymers 0.000 claims abstract description 49
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 30
- 239000013530 defoamer Substances 0.000 claims abstract description 16
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 15
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 12
- 239000012141 concentrate Substances 0.000 claims abstract description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 9
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- 229920001451 polypropylene glycol Polymers 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 4
- 239000000344 soap Substances 0.000 claims description 4
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 4
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 150000005215 alkyl ethers Chemical class 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims description 2
- 229920000151 polyglycol Polymers 0.000 claims description 2
- 239000010695 polyglycol Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229940071089 sarcosinate Drugs 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 2
- 229960003080 taurine Drugs 0.000 claims description 2
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 2
- 125000004429 atom Chemical group 0.000 abstract 1
- 239000006260 foam Substances 0.000 description 26
- 238000012360 testing method Methods 0.000 description 24
- 239000003795 chemical substances by application Substances 0.000 description 19
- 230000001804 emulsifying effect Effects 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 7
- 239000003153 chemical reaction reagent Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000012459 cleaning agent Substances 0.000 description 5
- 229920002545 silicone oil Polymers 0.000 description 5
- 238000009736 wetting Methods 0.000 description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000007046 ethoxylation reaction Methods 0.000 description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000011435 rock Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- DLRVVLDZNNYCBX-UHFFFAOYSA-N Polydextrose Polymers OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(O)O1 DLRVVLDZNNYCBX-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000009408 flooring Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229960001866 silicon dioxide Drugs 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000009795 derivation Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000002868 norbornyl group Chemical group C12(CCC(CC1)C2)* 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 239000001259 polydextrose Substances 0.000 description 1
- 229940035035 polydextrose Drugs 0.000 description 1
- 235000013856 polydextrose Nutrition 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- JREYOWJEWZVAOR-UHFFFAOYSA-N triazanium;[3-methylbut-3-enoxy(oxido)phosphoryl] phosphate Chemical compound [NH4+].[NH4+].[NH4+].CC(=C)CCOP([O-])(=O)OP([O-])([O-])=O JREYOWJEWZVAOR-UHFFFAOYSA-N 0.000 description 1
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/8305—Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C11D2111/14—
Abstract
The invention relates to a floor cleaning concentrate composition comprising a) a first non-ionic surfactant represented by the general formula (I), R<1>-(OC2H4)k-OH (I) wherein R<1> represents an unbranched or branched alkyl or alkenyl group having 1 to 10 atoms and k is 1 to 10, b) a second non-ionic surfactant represented by the general formula (II), R<2>-(OC2H4)m-(OC4H8)n-OH (II) wherein R<2>represents an unbranched or branched alkyl or alkenyl group having 5 to 20 carbon atoms, and n is 1 to 15, and m is 1 to 15, c) an anionic surfactant, d) a defoamer comprising crosslinked or partly crosslinked polysiloxane having a three dimensional structure. The invention further relates to a use solution and to a method of cleaning a surface.
Description
Technical field
The present invention relates to the floor-cleaning concentrate composition, comprise the applying soln of this floor-cleaning concentrate composition and the method on cleaning floor.
Composition according to the present invention is particularly useful for crust, the machines clean on preferred floor.
Background technology
Especially in mechanism's building, most of floor-cleanings are undertaken by using auto-cleaner.By means of these auto-cleaners, can be at short notice and very economical floor cleaning machine make up build in large-area floor.The coml cleaner is to clean suction machine.They comprise the rotating disk on one or several scouring floor.The brush roll machine also is known.By means of these cleaners, cleaning soln is taken on the floor.Come the machines clean floor the machine by cleaning and afterwards sanitising agent being sucked back from the floor.
The cleaning on floor is complicated task, because depend on the type and the architectural applications of building, several dissimilar dust and dirt may be present on the floor.In addition, the type on floor may be very different with floor surface, for example natural rock, malthoid, PVC, ceramic tile etc.Floor surface also may be very different, and for example it can be very coarse surface or slick surface.Good sanitising agent must be on all these different surface and is accompanied by different dirts and the cleaning result that produces.Therefore, good sanitising agent must satisfy several comprehensive requirements.
In order to satisfy this requirement, sanitising agent should have additional features.Sanitising agent must have good wettability and fast reaction times from the teeth outwards.Wetting ability is important because otherwise sanitising agent can not be distributed on the floor fifty-fifty and can not work effectively.
Another important requirement to the sanitising agent that is used for the floor is that this reagent must have good foam performance.If too much at auto-cleaner on period sanitising agent foam, the then blocked and cleaning interruption of cleaner.
Another requirement to the sanitising agent that is used for the floor is that it must have good cleaning and emulsifying capacity, makes that the cleaning result is satisfactory.
Be used for the residue performance that the sanitising agent on floor must show.This is meant after the floor drying of cleaning should not have visible spot or ring on the floor, and these spots or ring have been upset the glossy appearance on the floor of cleaning.
In the prior art, several floor cleaners have been described.US5,858,956 have described the general liquid cleansing composition of the nonionogenic tenside of the nonionogenic tenside that comprises anion surfactant, ethoxylation and ethoxylation/butoxyization.As defoamer, use lipid acid or fatty acid soaps.Yet said composition has such shortcoming: it still has high foam performance, so that it can not be used for the auto-cleaner that the floor is used.
US6,323,170 have described the floor cleaner that improved polishing response is provided.This floor cleaner comprise amine oxide as nonionogenic tenside and line style polydimethylsiloxane as defoamer.The sanitising agent of describing in this reference has its shortcoming that comprises amine oxide, and this is crucial, because they cause the environmental problem in the waste water and therefore will stimulate the malthoid floor owing to high pH value in addition.
EP0916717A1 has described the moisture floor cleaner of the nonionogenic tenside that comprises the group that derives from ethoxylation and propenoxylated C18-C22 Fatty Alcohol(C12-C14 and C12-C18).This cleaning compositions does not contain anion surfactant, and this is owing to their height foaming trend.The shortcoming of said composition is only to be very difficult to obtain gratifying cleaning result with nonionogenic tenside, if especially dirt is present on the floor, it more is difficult to remove.In addition, independent nonionogenic tenside special floor for example not polishing or unencapsulated natural rock floor or ceramic floor than rough surface structure on can not work well.
Summary of the invention
Therefore, technical purpose of the present invention provides the new cleaning compositions that is used for the floor, the environmental performance that the foam performance that said composition shows, good wettability, good cleaning result become reconciled and can using in the auto-cleaner that the floor is used.
This technical purpose solves by a kind of floor-cleaning concentrate composition, and said composition comprises:
A) first nonionogenic tenside of representing by general formula (I),
R
1-(OC
2H
4)
k-OH (I)
R wherein
1Expression has a 1-10, and the not branching of preferred 4-8 carbon atom or the alkyl or alkenyl and the k of branching are 1-10, preferred 4-9, and 6-8 most preferably,
B) second nonionogenic tenside of representing by general formula (II),
R
2-(OC
2H
4)
m-(OC
4H
8)
n-OH (II)
R wherein
2Expression has a 5-20, and the not branching of preferred 8-14 carbon atom or the alkyl or alkenyl and the n of branching are 1-15, preferred 5-10, and most preferably 7-10 and m are 1-15, preferred 5-10,7-10 most preferably,
C) anion surfactant,
D) comprise the defoamer of crosslinked or partial cross-linked polysiloxane with three-dimensional structure.
In preferred embodiments, based on total enriched material, this floor-cleaning enriched material comprises 1-10wt%, first nonionogenic tenside of preferred 2-6wt%, 0.5-15, second nonionogenic tenside of preferred 3-8wt%, 1-10wt%, the anion surfactant of preferred 2-7wt%, 0.01-1.5wt%, the defoamer of preferred 0.1-0.5wt%.
Be surprisingly found out that the floor-cleaning enriched material that the combination results that comprises the specific surfactant system of two kinds of nonionogenic tensides and anion surfactant and specific polysiloxane defoamers meets all essential requirements of being used for floor cleaning composition and can use at auto-cleaner.
Compositions table of the present invention reveals good wettability, good emulsifying property and cleaning result, good foam performance and do not have the visible resistates on the floor of cleaning after cleaning.
In addition, it is applicable to all types of flooring materials of cleaning, even the responsive material of cleaning also is possible such as malthoid or some natural rock, and flooring material does not stimulate.
If also find to use, then clean all types of dirts, particular pollutant, oil contamination, dust etc. with satisfactory way according to composition of the present invention.
In floor cleaning composition, using silicone oil is known as foaming control agent in principle.The typical froth conditioning agent that uses in the cleaning compositions that the floor is used can be the mixture of silicone oil and silicon-dioxide for example, and wherein silica dioxide granule can preferably be silylated.Normally used silicone oil is the linear polysiloxanes compound.Also other froth suppressor that uses in the prior art is an alkali metal salt of paraffin, hydrocarbon, saturated fatty acid or soap, phosphate monoester or dialkyl.
Also known defoamer is the organically-modified polyether silicone that has organo-functional group in their side chain.This compounds for example can obtain from GE Silicones, for example Y-14765.The polysiloxane defoamers that is surprisingly found out that these common type does not produce essential so that composition at the cleaning compositions that is used for the floor can be no problem and interruptedly be not used for the antifoam performance of auto-cleaner.
In contrast, find that the crosslinked or partial cross-linked polysiloxane with three-dimensional structure meets these froth breaking requirements.This three-dimensional polysiloxane is generally and contains preferably by the emulsion form of the crosslinking silicone drop of organo-functional group modification.In addition, polysiloxane compound comprises the polyoxyalkylene compound.The partial cross-linked polysiloxane of this class with three-dimensional structure for example can be at trade name FOAMBAN
RObtain from M ü nzing Chemie down.Preferably, FOAM BAN HV820G and/or FOAMBAN CL-100E use in composition according to the present invention.
In addition, when except crosslinked or partial cross-linked polysiloxane, be preferred when not comprising other polysiloxane compound or silicone oil according to composition of the present invention with three-dimensional structure.In preferred embodiments, polysiloxane compound uses with the form of dispersion or emulsion.
In a further preferred embodiment, polysiloxane has organo-functional group.These organo-functional groups can be the alkyl with 1-20 carbon atom.Preferably, these organo-functional groups are selected from C
1-C
20Alkyl, C
1-C
20Thiazolinyl, C
1-C
20Alkoxyl group, C
4-C
20Aryl or C
4-C
20Aralkyl.In addition, alkyl can replace.
The example of alkyl is methyl, ethyl, vinyl, propyl group, sec.-propyl, normal-butyl, n-pentyl, cyclopentyl, n-hexyl, new hexyl, n-heptyl, norcamphyl (norbornyl), 2-ethylhexyl, n-octyl, iso-octyl, dodecyl, tetradecyl, hexadecyl and octadecyl.The substituting group of these groups can be for example trifluoro propyl, cyano ethyl, glycidoxypropyl, polyalkylene glycol propyl group, aminopropyl or aminoethyl aminopropyl.Also possible is unsaturated group, for example vinyl, methacryloxypropyl or allyl group, perhaps for example phenyl, 2-phenylethyl or 2-phenyl propyl of aromatic group.
In another embodiment, defoaming composition can further comprise filler particles.Filler particles is selected from silicon-dioxide, titanium dioxide, zirconium dioxide, Al
2O
3Or their mixture.
Preferably being substantially free of other according to composition of the present invention does not have three-dimensional structure and is not compatible polysiloxane oil of film and polyorganosiloxane resin.Most preferably be substantially free of line style polydimethylsiloxane (silicone oil) according to composition of the present invention.
Word " is substantially free of " and is meant based on whole composition, and said composition comprises and be lower than 0.001wt%, preferably is lower than the 0.0001wt% and the compound of the amount of 0wt% most preferably.Most preferred, word " is substantially free of " and is meant that relevant compound is not present in the composition fully.
In defoaming agent composition according to the present invention, use crosslinked or partial cross-linked polysiloxane with three-dimensional structure.
These polysiloxane are crosslinked or partial cross-linked, this means that they contain the chaining that links to each other with three-dimensional network by three or four functional silicone unit or become the toroidal molecule group.In contrast, word " the crosslinked or partial cross-linked polysiloxane with three-dimensional structure " does not comprise that linear polysiloxanes is such as polydimethylsiloxane, only have a branched polysiloxane of two-dirnentional structure and equally only have the cyclic polysiloxanes of two-dirnentional structure.
In addition, the cross linking polysiloxane with three-dimensional structure according to the present invention is preferably fluid, and therefore with as the severe crosslinking polymer network and at room temperature be the description of solid silicone resin.
Therefore, the crosslinked or partial cross-linked polysiloxane with three-dimensional structure that preferably uses in defoamer is fluid down in room temperature (20 ℃).
In preferred embodiments, this floor-cleaning concentrate composition comprises 0.01-2.5wt%, the C of preferred 0.1-1wt%
8-C
22, preferred C
8-C
14Lipid acid or fatty acid soaps.The example of these lipid acid is stearic acid, palmitinic acid, oleic acid, fatty acid distribution of coconut oil, soya fatty acid etc.
Further comprise anion surfactant according to composition of the present invention.As anion surfactant, be preferably selected from following anion surfactant: C
8-C
18Alkyl-sulphate, C
8-C
18Sulfated alkyl ether, C
8-C
18Alkylsulfonate, C
8-C
18Sulfonated, sulfonated C
8-C
18Lipid acid, C
8-C
18Alkylbenzene sulfonate, sulfo-succinic acid list and two-C
1-C
12Alkyl ester, C
8-C
18Alkyl polyglycol ether carboxylate salt, C
8-C
18N-acyl group taurine thing (N-acyl tauride), C
8-C
18N-sarcosinate, C
8-C
18Alkyl isethionate and their mixture.
In addition, composition preferably according to the present invention comprises other tensio-active agent.It can be the 3rd nonionogenic tenside by general formula (III) expression
R
3-(OC
2H
4)
o-(OC
3H
6)
p-OH (III)
R wherein
3Expression has 5-20, and the not branching of preferred 8-14 carbon atom or the alkyl or alkenyl and the o of branching are 1-15, preferred 5-10, and most preferably 7-10 and p are 1-15, preferred 5-10, most preferably 7-10.
Tensio-active agent (for example positively charged ion, nonionic, amphoterics), protein hydrolyzate, silicone compounds, phosphoric acid ester and their salt that also can have other.Based on total concentrate composition, with 1-10wt%, the amount of preferred 2-6wt% is present in the composition according to the 3rd nonionogenic tenside of general formula (III).
In reagent according to the present invention, can use traditionally on technical scale can by Fatty Alcohol(C12-C14 and C12-C18) and glucose or the poly-dextrose condensation obtains and at the commercial alkyl polyglucoside that can various variants obtains as other nonionogenic tenside.The special example that very is suitable for alkyl polyglucoside used according to the invention is following product: derive from Henkel
600 and derive from Rohm﹠amp; The Triton of Haas
RBG10.
In addition, not dropping on other alkoxylated alkyl alcohol under the compound that defines among formula I and the II can be used as ionic surfactant pack and draws together in reagent according to the present invention.
Being preferably included in according to other surfactant compounds in the reagent of the present invention is to derive from those of phosphoric acid ester, preferably include the salt of at least a phosphoric acid partial ester, and in a particularly preferred form, there is an alkali metal salt of the phosphoric acid partial ester of at least a alkoxylated alkylphenol.
Above-mentioned phosphoric acid ester is the surfactant materials of preferred derivation of self-long chain fatty alcohol or aryl fatty alcohol.The salt of phosphoric acid partial ester, and especially in this situation, be found suitable especially for those of alkoxylated alkylphenol.Preferably, use sodium and sylvite, wherein preferred especially sylvite as an alkali metal salt.The commercially available acquisition of preferred surface-active phosphoric acid partial ester according to the present invention.According to the present invention, an example of special this class active substance of available is a product
H66 (Rohm﹠amp; Haas).
Reagent according to the present invention preferably includes polyoxyethylene glycol and/or polypropylene glycol as annexing ingredient, and described polyoxyethylene glycol and/or polypropylene glycol preferably have the molecular weight of 100-2000.Find that when based on total reagent, above-mentioned polyoxyethylene glycol and/or polypropylene glycol account for 0.01-5wt%, more preferably particularly advantageous during 0.05-1wt%.
Another object of the present invention is to comprise 0.001-10wt% in water, preferred 0.01-5wt%, the most preferably applying soln according to composition of the present invention of 0.1-5wt%.This applying soln is directly used in the artificial cleaning on floor or is used to use the machines clean of automatic floor cleaner.It also can be used for the industry cleaning of surface and industrial part.
Another object of the present invention is a kind of method that cleans the floor, it may further comprise the steps: provide according to composition of the present invention and with the applying soln of said composition as dilution to apply, this applying soln comprises 0.001-10wt%, preferred 0.01-5wt%, most preferably 0.1-5wt%'s according to composition of the present invention.In preferred embodiments, the method on cleaning floor is carried out as artificial or machines clean.
The present composition can comprise the other additive that generally is used for floor cleaning composition, such as for example complexing agent, organic solvent, the additive that is used for other alkalescence, stablizer, release agent, spices, sterilizing agent, corrosion inhibitor, dyestuff.
To further describe the present invention in following examples, these embodiment only are intended to exemplify the present invention, do not limit the scope of the invention.
Embodiment
Embodiment
1. the foam performance of automatic washer sanitising agent
The product that 50ml is to be tested is packed in the 250ml graduated cylinder and is sealed up with stopper.Graduated cylinder is put into rotary apparatus.Starting rotary apparatus and the axle that makes graduated cylinder center on it rotate 200 times.Rotating machine stops automatically afterwards.Immediately and again after 1 and 5 minute, the ml scale from the graduated cylinder is read the foamy amount of generation after stopping.From total lather volume, deduct the 50ml product of packing at first.
Each product uses at least 4 graduated cylinders to be used for test.Write down the foamy amount that produces in each graduated cylinder and with the mean value of each product relatively.In addition, how soon must compare foam breaks.
Few more foam gathering and lather collapse are fast more, and the froth breaking ability of sanitising agent is good more, and this is the key character that is used for the automatic washer sanitising agent of automatic cleaning.
Following table 1 shows the component of each composition of testing in following examples.All concentration in the table provide with weight percent.Embodiment 1 is according to composition of the present invention.Comparative Examples 2 also is according to composition of the present invention, yet does not have defoamer.Comparative Examples 3,4 and 5 is the care cleaning agents according to prior art.Comparative Examples 3 and 5 is used for artificial cleaning and Comparative Examples 4 is used for automatic cleaning.Table 2 shows the result of frothing test.
Table 1
Comprise the correlated aqueous cleaning agent [wt%] of various components
Table 2
Foaming properties [ml]
As can be seen, compare with the foam performance according to prior art combinations, the foam performance according to composition of the present invention among the embodiment 1 is very good.In addition, advantage is to compare with composition according to the present invention, and foam is in very short time implosion.After 1 minute and 5 minutes, for enriched material according to the present invention, there is not foam to exist as can be seen.On the contrary, even after 1 minute and 5 minutes, the care cleaning agent according to prior art in the Comparative Examples 3 and 5 also shows high foam height.If use FOAM BAN CL-100E to replace FOAM BANHV820G, then obtain similar result as defoamer.
Therefore, compare with the product of prior art as can be seen, the enriched material according to the present invention shown in the embodiment 1 has better foam performance.Therefore, it is applicable to automatic cleaning better.
2. emulsifying capacity
Measure the emulsifying capacity of composition according to oscillation method by using waste oil.The diluted product that 200ml is to be tested is put into the 250ml graduated cylinder and is added the filtering waste oil of 2g.Graduated cylinder is sealed up with stopper.In 20 seconds, graduated cylinder is rotated 10 times with 180 °.Afterwards graduated cylinder is put down and determine oily stowage capacity according to the time.Range estimation is estimated immediately after graduated cylinder is put down.After 30,60 and 120 seconds, estimate in addition.The result constitutes with following design:
The extraordinary emulsifying capacity of 1=, the oil particles uniformly dispersing is in solution.
The emulsifying capacity that 2=is good, the part oil particles deposits from the teeth outwards.
The emulsifying capacity that 3=is average, most of oil particles deposition is stayed in the solution from the teeth outwards on a small quantity.
The emulsifying capacity of 4=difference, all particle depositions from the teeth outwards.
In addition, observing sample 2 minutes and Measuring Time with grade 1 again dies down up to emulsifying capacity.Following table 3 shows and is accompanied by 0.5wt% concentration result in the water.
Table 3
Emulsifying capacity:
Table 3 shows the emulsifying capacity of embodiment 1 and Comparative Examples 3,4 and 5.Can be it can be seen from the table, even after 120 seconds, the emulsifying capacity of embodiment 1 is also very high.The emulsifying capacity of Comparative composition is poorer, except Comparative Examples 5.Yet Comparative Examples 5 has poor foam performance result.If use FOAM BAN CL-100E to replace FOAM BAN HV820G, then obtain similar result as defoamer.
3. wetting test
800 grams diluted product to be tested is packed in the beaker.Beaker has 1 liter of volume and has high shape.Be placed on the cotton pad in the through metal and put into beaker, make the arm of support stay on the beaker edge.When cotton pad contact solution, start stopwatch to measure time up to the cotton pad begins to drop on beaker bottom.Measure this time and revision test at least 5 times.Cotton pad falls fast more, and then the wetting ability of composition is good more.
The results are shown in the table 4 of wetting test:
Table 4
Wettability [min:sec]
Table 4 show in water 0.5,1 and the different concns of the composition concentration of 2wt% under the wetting test result.Even under the lower concentration of 0.5wt%, also have extraordinary wettability according to embodiments of the invention 1.Cotton pad began to fall the bottom after 23 seconds.On the contrary, need much more time and therefore have lower wettability with product contrast, especially Comparative Examples 3 of the present invention and 4.The care cleaning agent that Comparative Examples 5 has been described prior art also has good wettability.Yet, the non-constant of the foam performance of this sanitising agent.
If use FOAM BAN CL-100E to replace FOAM BAN HV820G, then obtain similar result as defoamer.
4. use the cleaning capacity of wet abrasion wiping tester (Gardner)
Cleaning soln to be tested is poured in artificial contamination's the white PVC test piece.Sponge is moved 10 times forward and backward.Afterwards, the whiteness by the color comparator test piece.
Equipment:
1.Gardner wet abrasion wiping tester device model 494 (DIN-ASTM-515); Supplier: Erichsen GmbH﹠amp; Co.KG
2.Minolta Chroma Meter CR-200; Supplier: Minolta
3. sponge press
4. white PVC-film Benova 4812080,1.3m/50m/0.12mm; Supplier: Benecke-Kaoliko AG
5. sheets of paperboard is as base material (size: 40x554x1mm); Supplier: KappaVerpackungswerk Neuss
6. derive from the pressure sensitive adhesive J 6251 (with ethyl acetate dilution 1: 1) of Henkel
7. the template of making by hard PVC
8. polyester sponge
9. have the flat painting brush of flat seta, about 55mm is wide, is used for the coated test dirt
10. watch-glass is used for the experiment with measuring dirt
11. standard test dirt IPP 83/21, supplier: wfk Krefeld
12. carpet pocket knife
13. laboratory scale, scope: 2000g, measuring accuracy 0.01g
The preparation of test piece:
1. use the template of making by hard PVC to cut white PVC-film.
2. and then 7 cardboard sheet are glued on the coarse side of PVC-film with straight line each other, therefore obtain the respective area of 280x554cm.Between cardboard sheet and PVC-paillon foil, should there be bubble or folding.
3. allow the sheet dried overnight.
Be used for the other preparation of care method:
The purpose of care products is to form dirt from the teeth outwards to repel film so that cleaning subsequently is easier.For this purpose, the sheet of preparation is necessary:
A. with the nursing solution wiping of working concentration 10 times-make its drying at least 30 minutes-or
B. with twice of undiluted care products wiping-make its dry 2-3 hour.
The coated test dirt:
1. the PVC template is placed on the top of PVC paillon foil, this PVC paillon foil is glued on the cardboard sheet.
2. weighing 2g test dirt is on watch-glass.
3. will test dirt with flat brush is coated on the interior white PVC paillon foil of template.Carry out level and vertical stroke successively.On each direction, repeat its 7 times.Last coating must be moved into the right angle with washing away.
4. made dirt dry 1 hour.
Measure clean-up performance (RV-value):
Spend the night in the polyester sponge immersion tap water with aequum.Each sheet needs a sponge.
1. (dirt on the top) cuts the PVC film with cardboard sheet along the edge with the carpet pocket knife.
2. sheet is placed on the guide rail on wet abrasion wiping tester (Gardner) top.
3. from bucket, take out a sponge and make water droplet intact.
4. compressed sponge 10 seconds in the sponge press.
Sponge is placed in the anchor clamps of Gardner device.
Important: sponge should be accompanied by 400g weight and lie low from the teeth outwards.
5. with measuring spoon cleaning product is poured on the top of the sheet of pollution and sponge.For the product that concentrates and dilute, use the cumulative volume of 25ml.
6. the guide rail under the mobile sponge anchor clamps and sponge is placed on the top of polluting sheet.
7. cycle counter be set be 10 and connect the Gardner device.
8. after wiping cycle finishes, take out sponge and throw away (not reusing).
9. take out test piece and under the mobile deionized water, wash.Allowing water run through whole test flows to guarantee identical hydraulic pressure impact test piece.
10. test piece is hung with drying.
11. the test piece of 6 pollutions of each testing liquid cleaning.
12. for relatively, only with 6 test pieces of tap water cleaning.
Measure whiteness (%RV):
1. rectify an instrument with the white ceramic tiles of preparing.
2. each sheet reflection of measuring all 6 sheets at 7 different some places.Result's mean value provides cleaning capacity per-cent.
3. single big deviation result is given up from calculate.
Result's evaluation:
For test products and possible contrast diluent, all are measured calculating mean value:
N=measures number of times (6x7=42)
The whiteness of each measurement point of x=
x
Arithm=average clean-up performance
Standard deviation:
Contrast:
The quality of water and the envrionment conditions in the laboratory are measured such as the temperature and humidity influence.Therefore, only be at one day and be that the result who obtains on the same day can compare.
Table 5 shows the result:
Table 5
Clean-up performance (Gardner) [%]
The STDEV=standard deviation
In test, in water, test the product concentration of 0.5wt%, 1wt% and 2wt%.Average clean-up performance is measured and the base of calculation deviation with per-cent.As can be seen from Table 5, compare with other care cleaning agent of 5, have the highest clean-up performance according to the composition in the embodiments of the invention 1 with the Comparative Examples 3,4 of prior art.For comparing reason, this table has also illustrated the clean-up performance of water.
Fig. 1 shows the clean-up performance of 4 products that are accompanied by standard deviation.From this table and Fig. 1 as can be seen, composition according to the present invention has the highest clean-up performance.If use FOAM BANCL-100E to replace FOAM BAN HV820G, then obtain similar result as defoamer.
Claims (19)
1. floor-cleaning concentrate composition, it comprises:
A) first nonionogenic tenside of representing by general formula (I),
R
1-(OC
2H
4)
k-OH (I)
R wherein
1Expression has the not branching of 1-10 carbon atom or the alkyl or alkenyl and the k of branching is 1-10,
B) second nonionogenic tenside of representing by general formula (II),
R
2-(OC
2H
4)
m-(OC
4H
8)
n-OH (II)
R wherein
2Expression has the not branching of 5-20 carbon atom or the alkyl or alkenyl and the n of branching is that 1-15 and m are 1-15,
C) anion surfactant,
D) comprise the defoamer of crosslinked or partial cross-linked polysiloxane with three-dimensional structure.
2. according to the floor-cleaning concentrate composition of claim 1, based on total enriched material, it comprises:
This of 1-10wt% first nonionogenic tenside,
This of 0.5-15wt% second nonionogenic tenside,
This anion surfactant of 1-10wt%,
This defoamer of 0.01-1.5wt%.
3. according to the floor-cleaning concentrate composition of claim 1 or 2, wherein this enriched material further comprises C8-C22 lipid acid or the fatty acid soaps of 0.01-2.5wt%.
4. according to each composition of claim 1-2, be characterised in that this defoamer is an emulsion.
5. according to each composition of claim 1-2, be characterised in that this defoamer comprises the polysiloxane with organo-functional group.
6. according to the composition of claim 5, be characterised in that this organo-functional group is the alkyl with 1-20 carbon atom.
7. according to the composition of claim 6, be characterised in that this alkyl is selected from C1-C20 alkyl, C1-C20 thiazolinyl, C1-C20 alkoxyl group, C4-C20 aryl or aralkyl.
8. according to claim 1 or 2 each compositions, be characterised in that said composition comprises that other that be lower than 0.001wt% do not have the polysiloxane oil and the polyorganosiloxane resin of three-dimensional structure.
9. composition according to Claim 8 is characterised in that said composition comprises the line style polydimethylsiloxane that is lower than 0.001wt%.
10. according to each composition of claim 1-2, be characterised in that this anion surfactant is selected from: C
8-C
18Alkyl-sulphate, C
8-C
18Sulfated alkyl ether, C
8-C
18Alkylsulfonate, C
8-C
18Sulfonated, sulfonated C
8-C
18Lipid acid, C
8-C
18Alkylbenzene sulfonate, sulfo-succinic acid list-C
1-C
12Alkyl ester and sulfo-succinic acid two-C
1-C
12Alkyl ester, C
8-C
18Alkyl polyglycol ether carboxylate salt, C
8-C
18N-acyl group taurine thing, C
8-C
18N-sarcosinate, C
8-C
18Alkyl isethionate and their mixture.
11. according to each composition of claim 1-2, be characterised in that it comprises the 3rd nonionogenic tenside by general formula (III) expression in addition,
R
3-(OC
2H
4)
o-(OC
3H
6)
p-OH (III)
R wherein
3Expression has the not branching of 5-20 carbon atom or the alkyl or alkenyl and the o of branching is that 1-15 and p are 1-15.
12., be characterised in that based on total enriched material, the 3rd nonionogenic tenside exists with the amount of 1-10wt% according to the composition of claim 11.
13., be characterised in that it comprises polyoxyethylene glycol and/or polypropylene glycol as other component according to each composition of claim 1-2.
14., be characterised in that this polyoxyethylene glycol and/or polypropylene glycol have the molecular weight of 100-2000 according to the composition of claim 13.
15., be characterised in that said composition comprises the amine oxide that is lower than 0.001wt% according to each composition of claim 1-2.
16. comprise 0.001-10wt% according to each the applying soln of composition of claim 1-15.
17. the method for clean surface, it may further comprise the steps:
Provide according to claim 1-15 each composition and the applying soln of said composition as the dilution of using according to claim 16 be coated on the floor.
18. according to the method for claim 17, wherein this cleaning is artificial cleaning or machines clean.
19. according to the method for claim 17 or 18, wherein this cleaning is the industry cleaning.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2007/053642 WO2008125143A1 (en) | 2007-04-13 | 2007-04-13 | Floor cleaning composition with reduced foaming properties |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101663383A CN101663383A (en) | 2010-03-03 |
| CN101663383B true CN101663383B (en) | 2011-09-07 |
Family
ID=38870254
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200780052842XA Active CN101663383B (en) | 2007-04-13 | 2007-04-13 | Floor cleaning composition with reduced foaming properties |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP5243522B2 (en) |
| CN (1) | CN101663383B (en) |
| BR (1) | BRPI0721554B1 (en) |
| MX (1) | MX2009010849A (en) |
| WO (1) | WO2008125143A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010073067A1 (en) * | 2008-12-24 | 2010-07-01 | Ecolab Inc. | Cleaner composition |
| US8338356B2 (en) | 2008-12-25 | 2012-12-25 | Dow Global Technologies Llc | Surfactant compositions with wide pH stability |
| EP3115094A1 (en) * | 2015-07-09 | 2017-01-11 | Rhodia Poliamida e Especialidades LTDA | Foam control composition for phosphoric acid production |
| CN107418746A (en) * | 2017-07-28 | 2017-12-01 | 北京中奥金苗文化体育有限公司 | A kind of cleaning agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4311608A (en) * | 1980-10-08 | 1982-01-19 | Maurice Joe G | All purpose cleaner |
| WO2004003122A1 (en) * | 2002-06-29 | 2004-01-08 | Ecolab Inc. | Floor cleaning and/or floor care product |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3862243A (en) * | 1972-02-17 | 1975-01-21 | Int Flavors & Fragrances Inc | Mixed oxyalkylates employed as antifoamers |
| DE2952287A1 (en) * | 1979-12-24 | 1981-07-02 | Henkel KGaA, 4000 Düsseldorf | METHOD FOR PRODUCING A POLYSILOXANE BLOCK POLYMERISATE AND THE USE THEREOF AS A FOAM INHIBITOR |
| WO1993025647A1 (en) * | 1992-06-15 | 1993-12-23 | The Procter & Gamble Company | Liquid laundry detergent compositions with silicone antifoam agent |
| SG55157A1 (en) * | 1993-06-09 | 1998-12-21 | Procter & Gamble | Stable aqueous emulsions of nonionic surfactants |
| GB9225075D0 (en) * | 1992-12-01 | 1993-01-20 | Ici Plc | Low foam polyglycoside formulations |
| JP3426322B2 (en) * | 1994-02-03 | 2003-07-14 | 花王株式会社 | Detergent composition |
| GB2287947A (en) * | 1994-03-19 | 1995-10-04 | Procter & Gamble | Detergent composition comprising lactase |
| EP0709451A1 (en) * | 1994-10-28 | 1996-05-01 | The Procter & Gamble Company | Stable liquid detergent compositions |
| US6323170B1 (en) * | 1994-10-28 | 2001-11-27 | The Procter & Gamble Co. | Floor cleaners which provide improved burnish response |
| ES2230558T3 (en) * | 1996-03-29 | 2005-05-01 | THE PROCTER & GAMBLE COMPANY | COMPOSITIONS DETERGENT LIQUIDS WITH LOW FOAM FORMATION. |
| CN1093876C (en) * | 1996-04-16 | 2002-11-06 | 普罗格特-甘布尔公司 | Liquid cleaning compsns. containing selected mid-chain branched surfactants |
| EP0816480A1 (en) * | 1996-06-26 | 1998-01-07 | The Procter & Gamble Company | Low sudsing liquid detergent compositions |
| JP4026873B2 (en) * | 1996-07-05 | 2007-12-26 | 株式会社ニイタカ | Detergent composition for dishwashers |
| SK5112000A3 (en) * | 1997-10-07 | 2001-05-10 | Procter & Gamble | Detergent composition for hard surfaces comprising hydrophilic shear-thinning polymer at very low level |
| JP3364608B2 (en) * | 1998-12-09 | 2003-01-08 | 三洋化成工業株式会社 | Builders and cleaners for cleaning agents |
| JP2002534595A (en) * | 1999-01-14 | 2002-10-15 | ザ、プロクター、エンド、ギャンブル、カンパニー | Detergent composition containing pectate lyase and low foaming nonionic surfactant |
| CA2362945C (en) * | 1999-02-22 | 2004-03-30 | The Procter & Gamble Company | Cleaning compositions containing selected nonionic surfactants |
| WO2002044311A2 (en) * | 2000-11-29 | 2002-06-06 | The Procter & Gamble Company | Hand dishwashing composition containing a suds suppresser and a method of use therefor |
| JP2004067707A (en) * | 2002-08-01 | 2004-03-04 | Nof Corp | Liquid detergent composition for kitchen |
| GB0219073D0 (en) * | 2002-08-16 | 2002-09-25 | Dow Corning | Silicone foam control compositions |
| US20050129643A1 (en) * | 2003-06-20 | 2005-06-16 | Lepilleur Carole A. | Hydrocolloids and process therefor |
| JP4170240B2 (en) * | 2004-02-20 | 2008-10-22 | 三洋化成工業株式会社 | Antifoam composition |
| EP1580302A1 (en) * | 2004-03-23 | 2005-09-28 | JohnsonDiversey Inc. | Composition and process for cleaning and corrosion inhibition of surfaces of aluminum or colored metals and alloys thereof under alkaline conditions |
| DE102004035709A1 (en) * | 2004-07-23 | 2006-03-16 | Wacker Chemie Ag | defoamer |
| JP2006104390A (en) * | 2004-10-07 | 2006-04-20 | Dai Ichi Kogyo Seiyaku Co Ltd | Liquid detergent composition |
| DE102004051897A1 (en) * | 2004-10-26 | 2006-04-27 | Wacker Chemie Ag | defoamer |
-
2007
- 2007-04-13 CN CN200780052842XA patent/CN101663383B/en active Active
- 2007-04-13 JP JP2010502426A patent/JP5243522B2/en active Active
- 2007-04-13 MX MX2009010849A patent/MX2009010849A/en active IP Right Grant
- 2007-04-13 WO PCT/EP2007/053642 patent/WO2008125143A1/en active Application Filing
- 2007-04-13 BR BRPI0721554-1A patent/BRPI0721554B1/en active IP Right Grant
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4311608A (en) * | 1980-10-08 | 1982-01-19 | Maurice Joe G | All purpose cleaner |
| WO2004003122A1 (en) * | 2002-06-29 | 2004-01-08 | Ecolab Inc. | Floor cleaning and/or floor care product |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5243522B2 (en) | 2013-07-24 |
| BRPI0721554B1 (en) | 2017-11-28 |
| CN101663383A (en) | 2010-03-03 |
| MX2009010849A (en) | 2009-11-05 |
| JP2010523773A (en) | 2010-07-15 |
| WO2008125143A1 (en) | 2008-10-23 |
| BRPI0721554A2 (en) | 2013-01-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2021013C (en) | Dispersible silicone wash and rinse cycle antifoam formulations | |
| US6251849B1 (en) | Cleaning agent for hard surfaces based on cationic polymer soil-release compounds | |
| DE60016744T2 (en) | DETERGENT COMPOSITION FOR THE REMOVAL OF COMPLEX ORGANIC OR FATTY DIRT | |
| EP0578424B1 (en) | Foam control agents based on organopolysiloxanes | |
| CN101663383B (en) | Floor cleaning composition with reduced foaming properties | |
| KR102147473B1 (en) | Detergent composition comprising carbinol functional trisiloxane | |
| JP2012122076A (en) | Microemulsion detergent composition and method for removing hydrophobic soil from article | |
| GB1600981A (en) | Detergent composition | |
| CN107474978B (en) | Leather and/or vinyl resin cleaning and wetting agent and method for producing same | |
| CA2999035A1 (en) | Hard surface cleaning compositions comprising ethoxylated alkoxylated nonionic surfactants or a copolymer and cleaning pads and methods for using such cleaning compositions | |
| EP0357976A2 (en) | Method of boosting foam in low sudsing detergents | |
| EP1939260A2 (en) | Three-phase liquid polishing and cleaning composition | |
| US7776158B2 (en) | Floor cleaning and care compositions | |
| JP3361568B2 (en) | Foaming suppression method and detergent composition | |
| JP2008169361A (en) | Detergent for resin surface and cleaning method for resin surface | |
| JPH08500377A (en) | Pourable liquid aqueous detergent concentrate | |
| WO2000077142A1 (en) | Gloss retention compositions | |
| JP2006070215A (en) | Detergent composition | |
| WO2023014851A1 (en) | Surfactant compositions | |
| EP3535360A1 (en) | Hard surface cleaning composition and method of improving drying time using the same | |
| JP2007231176A (en) | Low-foaming nonionic surfactant | |
| JP2003534448A (en) | Surface cleaning | |
| US6323170B1 (en) | Floor cleaners which provide improved burnish response | |
| CN107075426B (en) | Defoaming agent and its purposes in detergent | |
| EP0914313A1 (en) | Non-ionic surfactant compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |