CN101654767A - Vacuum protection atmosphere annealing process of industrial pure titanium roll - Google Patents
Vacuum protection atmosphere annealing process of industrial pure titanium roll Download PDFInfo
- Publication number
- CN101654767A CN101654767A CN200910307848A CN200910307848A CN101654767A CN 101654767 A CN101654767 A CN 101654767A CN 200910307848 A CN200910307848 A CN 200910307848A CN 200910307848 A CN200910307848 A CN 200910307848A CN 101654767 A CN101654767 A CN 101654767A
- Authority
- CN
- China
- Prior art keywords
- protection atmosphere
- vacuum protection
- titanium roll
- atmosphere annealing
- annealing process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a vacuum protection atmosphere annealing process of an industrial pure titanium roll, which comprises the following steps: charging a titanium roll with clean surface into a vacuum protection atmosphere annealing furnace; evacuating and heating to 430-500 DEG C and keeping the temperature for 1.5-2.5 hours; circulating in the furnace by a high-purity inert gas under the condition of micro-negative pressure; heating to 600-750 DEG C to insulate for 2-8 hours and then cooling to 400-550 DEG C; starting a forced cooling system to accelerate cooling; and discharging till the titanium roll is cooled to 170 DEG C. The mechanical performance, the chemical component and the surface quality of the annealed titanium roll can meet the requirements of a user; after the forced cooling system with a heat exchanger is adopted, the inert gas can be cooled by the heat exchanger, thereby greatly shortening the annealing period and reducing the annealing energy consumption and theproduction cost.
Description
Technical field
The invention belongs to the metal material processing technical field, specifically a kind of vacuum protection atmosphere annealing process of industrial pure titanium roll.
Background technology
Because the chemical property of titanium is active, at high temperature react with elements such as airborne O, N, H easily, form pollution layer on the surface, cause the reduction of its intensity and plasticity, hardness to increase, have a strong impact on following process and use.Therefore at present the finished products of the titanium volume full-hydrogen hood-type annealing furnace that adopts vacuum furnace more or transform original annealing coil carries out protective atmosphere thermal treatment.It is inconsistent that but the anneal of carrying out the employing vacuum oven causes titanium volume Internal and external cycle to organize easily, and the processing cycle is elongated, has increased tooling cost.If transform the full-hydrogen hood-type annealing furnace of annealing coil, adopt the annealing of argon gas or protective atmosphere displaced air, cause the air purge in the stove unclean easily, cause the titanium volume surface contamination after the annealing, foreign matter content increases.And the impurity component of titanium volume and deformation rate can influence the thermal treatment temp of titanium volume, influences final mechanical property, so must control vacuum heat treatment atmosphere, temperature and soaking time well.Too high and the overlong time of thermal treatment temp causes titanium volume bonding easily, and the uncoiling rear surface produces bonding, and surface quality can not meet the demands.
Summary of the invention
The objective of the invention is to overcome the problems referred to above that exist in the existing titanium volume annealing process, provide a kind of when high temperature the inside have the technology that rare gas element round-robin vacuum protection atmosphere annealing furnace carries out anneal, can both satisfy customer requirements with mechanical property, chemical ingredients and the surface quality that realizes the titanium volume after the annealing; And can shorten the annealing cycle greatly, reduce the annealed energy consumption, reduce cost.
Technical scheme of the present invention may further comprise the steps:
(1) the titanium package of cleaning surfaces is gone in the vacuum protection atmosphere annealing furnace, be evacuated to vacuum tightness and reach 1.0 * 10
-3Behind the Pa, be raised to 430 ~ 500 ℃, be incubated 1.5 ~ 2.5 hours with the heat-up rate of 100 ~ 200 ℃/h;
(2) with high purity inert gas pressure for-10kPa～-in stove, circulate under the little condition of negative pressure of 5kPa, and be warmed up to 600 ~ 750 ℃ by the titanium volume with the heat-up rate of 80 ~ 150 ℃/h, be incubated 2 ~ 8 hours;
(3) closing heating system, is 100 ~ 200 ℃/h by cooling rate, cools to 400-550 ℃, opens pressure cooling system and quickens cooling, comes out of the stove after being cooled to 170 ℃.
Described pressure cooling system has interchanger.
Described rare gas element is that purity is higher than 99.99% argon gas.
The present invention improves the surface quality of annealing back titanium volume, and the tissue and the performance homogeneous of titanium volume Internal and external cycle detect the rear surface and do not inhale the hydrogen phenomenon, and its mechanical property, chemical ingredients and surface quality can both satisfy customer requirements.After employing had the pressure cooling system of interchanger, rare gas element cooled off rare gas element by interchanger at circulation time, thereby took away the heat in the stove, can shorten the annealing cycle greatly, reduced the annealed energy consumption, and production cost reduces accordingly.
Embodiment
Below in conjunction with embodiment the present invention is described further.
Embodiment 1:
(1) the titanium package of cleaning surfaces is gone in the vacuum protection atmosphere annealing furnace, be evacuated to vacuum tightness and reach 1.0 * 10
-3Behind the Pa, beginning is raised to 450 ℃ with the heat-up rate of 150 ℃/h, is incubated 2 hours;
(2) adopt purity be higher than 99.99% argon gas, pressure for-10kPa～-in stove, circulate under the 5kPa condition, be warmed up to 680 ℃ with the heat-up rate of 100 ℃/h by the titanium volume, be incubated 4 hours;
(3) after insulation finishes, closing heating system, is that 150 ℃/h cools to 540 ℃ by cooling rate, opens the pressure cooling system that has interchanger and quickens cooling, comes out of the stove after being cooled to 170 ℃.
Embodiment 2:
(1) the titanium package of cleaning surfaces is gone in the vacuum protection atmosphere annealing furnace, open pumping high vacuum after closing fire door, when vacuum tightness reaches 1.0 * 10
-3Behind the Pa, beginning is warmed up to 500 ℃ with the heat-up rate of 100 ℃/h by the titanium volume, is incubated 1.5 hours;
(2) adopt purity to be higher than 99.99% argon gas at the stove internal recycle, in the control stove pressure of argon gas be-10kPa～-little negative pressure of 5kPa.Heat-up rate with 150 ℃/h is warmed up to 740 ℃ by the titanium volume, is incubated 2 hours;
(3) after insulation finishes, closing heating system, is after 140 ℃/h cools to 460 ℃ with cooling rate again, opens the pressure cooling system that has interchanger and quickens cooling, is cooled to 170 ℃ and comes out of the stove.
Embodiment 3:
(1) the titanium package of cleaning surfaces is gone in the vacuum protection atmosphere annealing furnace, be evacuated to vacuum tightness and reach 1.0 * 10
-3Behind the Pa, beginning is raised to 430 ℃ with the heat-up rate of 150 ℃/h, is incubated 2.5 hours;
(2) adopt purity be higher than 99.99% argon gas, pressure for-10kPa～-in stove, circulate under the 5kPa condition, be warmed up to 620 ℃ with the heat-up rate of 100 ℃/h by the titanium volume, be incubated 6 hours:
(3) after insulation finishes, closing heating system, is that 150 ℃/h cools to 500 ℃ by cooling rate, opens pressure cooling system and quickens cooling, comes out of the stove after being cooled to 170 ℃.
Claims (3)
1. the vacuum protection atmosphere annealing process of an industrial pure titanium roll is characterized in that, may further comprise the steps:
(1) the titanium package of cleaning surfaces is gone in the vacuum protection atmosphere annealing furnace, after being evacuated to vacuum tightness and reaching 1.0 * 10-3Pa, be raised to 430 ~ 500 ℃, be incubated 1.5 ~ 2.5 hours with the heat-up rate of 100 ~ 200 ℃/h;
(2) with high purity inert gas pressure for-10kPa～-in stove, circulate under the little condition of negative pressure of 5kPa, and be warmed up to 600 ~ 750 ℃ by the titanium volume with the heat-up rate of 80 ~ 150 ℃/h, be incubated 2 ~ 8 hours;
(3) closing heating system, is 100 ~ 200 ℃/h by cooling rate, cools to 400-550 ℃, opens pressure cooling system and quickens cooling, comes out of the stove after being cooled to 170 ℃.
2. the vacuum protection atmosphere annealing process of industrial pure titanium roll according to claim 1 is characterized in that, described pressure cooling system has interchanger.
3. the vacuum protection atmosphere annealing process of industrial pure titanium roll according to claim 1 is characterized in that, described rare gas element is that purity is higher than 99.99% argon gas.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910307848A CN101654767A (en) | 2009-09-28 | 2009-09-28 | Vacuum protection atmosphere annealing process of industrial pure titanium roll |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910307848A CN101654767A (en) | 2009-09-28 | 2009-09-28 | Vacuum protection atmosphere annealing process of industrial pure titanium roll |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101654767A true CN101654767A (en) | 2010-02-24 |
Family
ID=41709214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910307848A Pending CN101654767A (en) | 2009-09-28 | 2009-09-28 | Vacuum protection atmosphere annealing process of industrial pure titanium roll |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101654767A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002658A (en) * | 2010-11-24 | 2011-04-06 | 莱芜钢铁股份有限公司 | Annealing process of cold rolled titanium roll |
| CN102409146A (en) * | 2011-11-14 | 2012-04-11 | 云南钛业股份有限公司 | Titanium roll tape cover annealing method and device thereof |
| CN102517529A (en) * | 2011-11-28 | 2012-06-27 | 洛阳双瑞精铸钛业有限公司 | Vacuum heat treatment process of cold rolled titanium strip coil for plate heat exchanger |
| CN102899472A (en) * | 2011-07-26 | 2013-01-30 | 张家港华裕有色金属材料有限公司 | Titanium and titanium alloy U-shaped bend vacuum heat treatment method and apparatus thereof |
| CN104152831A (en) * | 2014-08-26 | 2014-11-19 | 攀钢集团攀枝花钢铁研究院有限公司 | Vacuum annealing method of cold-rolled industrial pure titanium roll |
| CN104152828A (en) * | 2014-08-26 | 2014-11-19 | 攀钢集团攀枝花钢铁研究院有限公司 | Vacuum annealing process of cold-rolled industry pure titanium roll |
| CN104152829A (en) * | 2014-08-26 | 2014-11-19 | 攀钢集团攀枝花钢铁研究院有限公司 | Vacuum annealing method of cold-rolled commercial pure titanium coil |
| CN104152832A (en) * | 2014-08-26 | 2014-11-19 | 攀钢集团攀枝花钢铁研究院有限公司 | A vacuum annealing technology of cold rolled commercial pure titanium coils |
| CN104152830A (en) * | 2014-08-26 | 2014-11-19 | 攀钢集团攀枝花钢铁研究院有限公司 | Vacuum annealing process of cold-rolled high-purity large titanium coil |
| CN104561870A (en) * | 2015-01-07 | 2015-04-29 | 宝鸡子扬双金属材料有限公司 | Vacuum annealing method of titanium or titanium alloy material in low-vacuum unit and gas protection cooperation way |
| CN105887133A (en) * | 2016-06-28 | 2016-08-24 | 湖南新发科技有限责任公司 | Method for preparing high-deformation resistance titanium anode from electrolytic manganese dioxide |
| CN106435423A (en) * | 2016-11-11 | 2017-02-22 | 广汉程明新材料科技有限公司 | Continuous heating annealing method for cold-rolled titanium roll |
| CN109023187A (en) * | 2018-08-17 | 2018-12-18 | 成都先进金属材料产业技术研究院有限公司 | Eliminate the vacuum annealing process of cold rolled titanium roll annealing bonding |
| CN109252121A (en) * | 2018-10-30 | 2019-01-22 | 江苏希诺实业有限公司 | A kind of processing method of the pure titanium article surface acicular crystal decorative pattern of thin-walled |
-
2009
- 2009-09-28 CN CN200910307848A patent/CN101654767A/en active Pending
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002658A (en) * | 2010-11-24 | 2011-04-06 | 莱芜钢铁股份有限公司 | Annealing process of cold rolled titanium roll |
| CN102002658B (en) * | 2010-11-24 | 2012-11-07 | 山东钢铁股份有限公司 | Annealing process of cold rolled titanium roll |
| CN102899472A (en) * | 2011-07-26 | 2013-01-30 | 张家港华裕有色金属材料有限公司 | Titanium and titanium alloy U-shaped bend vacuum heat treatment method and apparatus thereof |
| CN102409146A (en) * | 2011-11-14 | 2012-04-11 | 云南钛业股份有限公司 | Titanium roll tape cover annealing method and device thereof |
| CN102517529A (en) * | 2011-11-28 | 2012-06-27 | 洛阳双瑞精铸钛业有限公司 | Vacuum heat treatment process of cold rolled titanium strip coil for plate heat exchanger |
| CN102517529B (en) * | 2011-11-28 | 2013-07-31 | 洛阳双瑞精铸钛业有限公司 | Vacuum heat treatment process of cold rolled titanium strip coil for plate heat exchanger |
| CN104152830A (en) * | 2014-08-26 | 2014-11-19 | 攀钢集团攀枝花钢铁研究院有限公司 | Vacuum annealing process of cold-rolled high-purity large titanium coil |
| CN104152829B (en) * | 2014-08-26 | 2016-06-01 | 攀钢集团攀枝花钢铁研究院有限公司 | The vacuum annealing method of cold rolling industry pure titanium coil |
| CN104152829A (en) * | 2014-08-26 | 2014-11-19 | 攀钢集团攀枝花钢铁研究院有限公司 | Vacuum annealing method of cold-rolled commercial pure titanium coil |
| CN104152832A (en) * | 2014-08-26 | 2014-11-19 | 攀钢集团攀枝花钢铁研究院有限公司 | A vacuum annealing technology of cold rolled commercial pure titanium coils |
| CN104152831A (en) * | 2014-08-26 | 2014-11-19 | 攀钢集团攀枝花钢铁研究院有限公司 | Vacuum annealing method of cold-rolled industrial pure titanium roll |
| CN104152831B (en) * | 2014-08-26 | 2016-09-28 | 攀钢集团攀枝花钢铁研究院有限公司 | A kind of vacuum annealing method of cold rolling industry pure titanium coil |
| CN104152830B (en) * | 2014-08-26 | 2016-05-25 | 攀钢集团攀枝花钢铁研究院有限公司 | The vacuum annealing process of the heavy pure titanium roll of cold rolling large volume |
| CN104152828A (en) * | 2014-08-26 | 2014-11-19 | 攀钢集团攀枝花钢铁研究院有限公司 | Vacuum annealing process of cold-rolled industry pure titanium roll |
| CN104152832B (en) * | 2014-08-26 | 2016-06-01 | 攀钢集团攀枝花钢铁研究院有限公司 | The vacuum annealing process of cold rolling industry pure titanium coil |
| CN104561870A (en) * | 2015-01-07 | 2015-04-29 | 宝鸡子扬双金属材料有限公司 | Vacuum annealing method of titanium or titanium alloy material in low-vacuum unit and gas protection cooperation way |
| CN105887133A (en) * | 2016-06-28 | 2016-08-24 | 湖南新发科技有限责任公司 | Method for preparing high-deformation resistance titanium anode from electrolytic manganese dioxide |
| CN106435423A (en) * | 2016-11-11 | 2017-02-22 | 广汉程明新材料科技有限公司 | Continuous heating annealing method for cold-rolled titanium roll |
| CN109023187A (en) * | 2018-08-17 | 2018-12-18 | 成都先进金属材料产业技术研究院有限公司 | Eliminate the vacuum annealing process of cold rolled titanium roll annealing bonding |
| CN109023187B (en) * | 2018-08-17 | 2020-12-15 | 成都先进金属材料产业技术研究院有限公司 | Vacuum annealing process for eliminating annealing adhesion of cold-rolled titanium coil |
| CN109252121A (en) * | 2018-10-30 | 2019-01-22 | 江苏希诺实业有限公司 | A kind of processing method of the pure titanium article surface acicular crystal decorative pattern of thin-walled |
| CN109252121B (en) * | 2018-10-30 | 2021-07-20 | 希诺股份有限公司 | Processing method of needle-shaped crystal patterns on surface of thin-wall pure titanium product |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101654767A (en) | Vacuum protection atmosphere annealing process of industrial pure titanium roll | |
| CN102517529B (en) | Vacuum heat treatment process of cold rolled titanium strip coil for plate heat exchanger | |
| CN101323938A (en) | Process for cold rolling industry pure titanium coil annealing by cover-type annealing furnace | |
| CN201648477U (en) | High-temperature strong-convection circulatory atmosphere cover type heat treating furnace with separated fan and heat area | |
| CN105112617A (en) | Novel high-temperature annealing process of cold-rolled oriented silicone steel | |
| CN106591555B (en) | A kind of annealing process after non-directional cold-rolling silicon steel disc cold rolling | |
| CN102002658B (en) | Annealing process of cold rolled titanium roll | |
| CN103578734A (en) | Sintering technique for neodymium iron boron magnet | |
| CN101054619A (en) | Three-chamber oil-quenching gas-quenching continuous vacuum furnace | |
| CN108296487A (en) | A kind of preparation method of pure rhenium plate | |
| CN102392261A (en) | Double-vacuum annealing device and process for improving magnetic property of soft magnetic material | |
| CN101724799A (en) | Degreasing annealing process of titanium and titanium alloy strips and profiles | |
| CN113000844A (en) | Preparation method of large-size molybdenum plate | |
| CN104152828B (en) | The vacuum annealing process of a kind of cold rolling industry pure titanium coil | |
| CN101445861A (en) | Air-cooling equipment for external-circulation multi-heat exchanger furnace | |
| CN101086056B (en) | Quick annealing method for titanium seamless pipe | |
| CN104152831B (en) | A kind of vacuum annealing method of cold rolling industry pure titanium coil | |
| CN104630676A (en) | Annealing process of titanium plate | |
| CN113621905A (en) | Thermal hydrogen treatment process for improving softening effect of TC21 titanium alloy in room-temperature plastic deformation process | |
| CN102691110A (en) | Annealing process for ingot furnace | |
| CN104152832A (en) | A vacuum annealing technology of cold rolled commercial pure titanium coils | |
| CN101864511B (en) | Annealing process of sealing welding flux | |
| CN111910139A (en) | Method for preventing annealing adhesion of ultrathin titanium strip coil through texturing process | |
| CN102392204B (en) | Vacuum high temperature annealing method of copper alloy parts with high zinc contents | |
| CN108396265A (en) | A kind of aluminium alloy and its heat treatment method of graphene-containing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Open date: 20100224 |