CN101654573A - Yellow pigment jet ink - Google Patents
Yellow pigment jet ink Download PDFInfo
- Publication number
- CN101654573A CN101654573A CN 200910070136 CN200910070136A CN101654573A CN 101654573 A CN101654573 A CN 101654573A CN 200910070136 CN200910070136 CN 200910070136 CN 200910070136 A CN200910070136 A CN 200910070136A CN 101654573 A CN101654573 A CN 101654573A
- Authority
- CN
- China
- Prior art keywords
- yellow
- pigment
- agent
- jet ink
- yellow pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
A yellow pigment jet ink contains penetrant, humectant, surfactant and color paste and is characterized in that the color paste contains yellow pigment and dispersant, wherein the yellow pigment is pigment yellow C.I.P.Y.74 and pigment yellow C.I.P.Y.155, and the ratio of the pigment yellow C.I.P.Y.74 and the pigment yellow C.I.P.Y.155 is 0.25-4. the preparation method thereof includes that: (1) pigment, dispersant and water are ground; (2) water, penetrant, humectant, surfactant and germicide, pH regulator, adhesion promoter and sequestering agent are mixed to be uniform; (3) the two are mixed; (4) filtering is carried out by a filter membrane. The ink of the invention is good in rub-resistance and good in gloss, can obtain satisfied reflection density and chromaticity and effectively reduces sedimentation problem.
Description
(1) technical field:
The present invention relates to a kind of yellow ink, particularly a kind of Yellow pigment jet ink and compound method thereof.
(2) background technology:
The image of pigment-type ink-jet ink output has waterproof, sun-proof, the shelf time advantage of waiting so long, so pigment more and more is applied in the ink-jet printing ink as tinting material.To consider when selecting pigment whether pigment is easy to disperse, and whether anti-fadedness is good, and whether color is saturated, color expression range factor such as whether meet the demands.Though pigment type is various, but the pigment that is applicable to the ink-jet field is not a lot, through technician's continuous exploration, has found some to be applicable to the pigment in ink-jet field, they are just making great efforts to study these pigment and how to use in the ink-jet field, and the new pigment variety of active development.
The pigment that is applied to the ink-jet field has Pigment blue, Pigment green, Pigment red, Pigment Yellow 73, pigment violet etc. usually.Also have several pigment to select for each pigment classification to tens kinds of different pigment call numbers.For example Pigment Yellow 73 can be found Pigment Yellow 73 C.I.P.Y.55 on technical information and patent documentation, Pigment Yellow 73 C.I.P.Y.74, Pigment Yellow 73 C.I.P.Y.79, Pigment Yellow 73 C.I.P.Y.93, Pigment Yellow 73 C.I.P.Y.110, Pigment Yellow 73 C.I.P.Y.120, Pigment Yellow 73 C.I.P.Y.128, Pigment Yellow 73 C.I.P.Y.138C, Pigment Yellow 73 C.I.P.Y.139, Pigment Yellow 73 C.I.P.Y.150, Pigment Yellow 73 C.I.P.Y.151, Pigment Yellow 73 C.I.P.Y.155, Pigment Yellow 73 C.I.P.Y.156, Pigment Yellow 73 C.I.P.Y.175, Pigment Yellow 73 C.I.P.Y.180, Pigment Yellow 73 C.I.P.Y.185 and Pigment Yellow 73 C.I.P.Y.213 etc. are ink-jet field yellow ultramarines commonly used.
Consider the jet performance and the stability in storage of paint ink, the granularity of paint ink is generally about 100 nanometers at present, and the preparation method mainly takes the method for physical grinding.The image of output should have anti-ly fade, characteristics such as water-fast, rub resistance, glossiness height, saturation ratio height.Publication number is that 1863878 Chinese patent has been studied Pigment Yellow 73 C.I.P.Y.74 as the application of tinting material in jetted ink, and the method for the yellow C.I.P.Y.74 of dispersed color and the yellow ink-jet ink of preparation thus are provided.Publication number is that yellow ultramarine that 101270246 Chinese patent uses is wherein more than one a pigment of Pigment Yellow 73 C.I.P.Y.213, Pigment Yellow 73 C.I.P.Y.185 and Pigment Yellow 73 C.I.P.Y.155, and the preparation method of comprehensive good yellow ink-jet ink aspect photostabilization, color developing, storage stability is provided.Publication number is that 101389718 Chinese patent has also studied how better to disperse the good Pigment Yellow 73 C.I.P.Y.155 of photostabilization.These patents have just been studied the characteristic when being used alone yellow pigment, in addition to being applicable to that the dispersing of pigments agent done big quantity research, do not find the exploration of using pigment to mixing.The ink researchist finds to use separately Pigment Yellow 73 C.I.P.Y.74 that certain deficiency is arranged on erasibility and glossiness, and with Pigment Yellow 73 C.I.P.Y.74 be the ink of colorant through after the standing storage, sedimentary problem appears easily.Use Pigment Yellow 73 C.I.P.Y.155 can not obtain satisfied reflection density and chroma separately.
(3) summary of the invention:
The objective of the invention is to obtain a kind of Yellow pigment jet ink and compound method thereof, this ink is at the comprehensive evaluation optimum of aspects such as erasibility, glossiness, reflection density and chroma, and reduced the sedimentation problem of yellow pigment ink.
Technical scheme of the present invention: a kind of Yellow pigment jet ink, it contains permeate agent, wetting Agent for Printing Inks, tensio-active agent and mill base, it is characterized in that containing in the said mill base yellow ultramarine and dispersion agent, yellow ultramarine is Pigment Yellow 73 C.I.P.Y.74 and Pigment Yellow 73 C.I.P.Y.155, and wherein the ratio range of Pigment Yellow 73 C.I.P.Y.74 and Pigment Yellow 73 C.I.P.Y.155 is 0.25～4; Permeate agent accounts for 1～25% in the said Yellow pigment jet ink, and wetting Agent for Printing Inks accounts for 1～30%, surfactant comprise 0.01～5%, and mill base accounts for 15～60%; Above-mentioned each percentage composition is mass percent.
Above-mentioned said permeate agent is at least a in 2-pyrrolidone, N-methyl-2-pyrrolidone, butyl glycol ether, Diethylene Glycol butyl ether, triethylene glycol butyl ether, propylene glycol butyl ether, dipropylene glycol butyl ether, ethanol, the Virahol.
Above-mentioned said wetting Agent for Printing Inks is glycerol, ethylene glycol, Diethylene Glycol, triethylene glycol, TEG, PEG400, PEG600,1,2-propylene glycol, 1, ammediol, 1,2-butyleneglycol, 1,4-butyleneglycol, 1,2-pentanediol, 1,5-pentanediol, 1,2-hexylene glycol, 1,2, at least a in 6-hexanetriol, the TriMethylolPropane(TMP).
Above-mentioned said tensio-active agent is Air Products (air chemical industry) product Surfynol 420, Surfynol 440, Surfynol 465, Surfynol 485, Surfynol 104E, Surfynol 2502, Dynol604, Dynol607, Dow Corning (DOW CORNING) product DC-67, BYK-Chemie (Bi Ke chemistry) product B YK345, BYK346, BYK347, BYK348, at least a among Rhodia (Luo Diya) product DS-4, the DS-10.
Above-mentioned said dispersion agent is at least a among Air Products (air chemical industry) product: the Zetasperse 1200,1400,1600,2100,2300,2500,3400,3700.
Can also contain sterilant, pH regulator agent, adhesion promoter and metal ion chelation agent in the above-mentioned said Yellow pigment jet ink.
Above-mentioned said sterilant can be 1,2-phenylpropyl alcohol isothiazoline-3-ketone.
Above-mentioned said pH regulator agent can be at least a in sodium hydroxide, potassium hydroxide, triethylamine, ammoniacal liquor, the trolamine.
Above-mentioned said adhesion promoter can be at least a among BASF (BASF) product: Joncryl56, Joncryl58, Joncryl63, Joncryl67, the Joncryl611.
Above-mentioned said metal ion chelation agent can be a disodium EDTA.
A kind of Yellow pigment jet ink and compound method thereof is characterized in that the pigment inkjet ink takes the preparation of following method:
(1) pigment, dispersion agent and water are ground, to mean particle size less than 200 nanometers, obtain ink for ink-jet print use dispersible pigment color paste;
(2) with water, permeate agent, wetting Agent for Printing Inks, tensio-active agent and sterilant, pH regulator agent, adhesion promoter, metal ion chelation agent mix, and obtain mixing solutions;
(3) described mixing solutions of step (2) and the described water-based pigment colour paste of step (1) are mixed;
(4) ink that step (3) gained is mixed is 0.8 micron membrane filtration with the aperture;
(5) obtain the related Yellow pigment jet ink of the present invention.
The mill base of making in the above-mentioned said step (1) can be made different mill bases in advance, and is standby to do.
The grinding plant that grinding in the above-mentioned said step (1) is adopted be pin bar type shredder, ball mill and novel nano performance shredder-
A kind of among the-MILL NPM; Said pin bar type shredder, rotating speed is 600～4000rpm, it is the zirconium oxide bead of 0.05～1mm that grinding medium adopts diameter, between preferred diameter 0.05～0.2mm.
Testing method explanation to products obtained therefrom of the present invention:
The Yellow pigment jet ink of preparation is filled in the compatible print cartridge, uses Epson Stylus PhototR230 printer test, print 100% yellow color lump during test.
Reflection density: use X-Rite 418 type reflection densitometers to measure the yellow color lump that above-mentioned printing is finished.
Glossiness: use BYK Gardner vancometer to measure the yellow color lump that above-mentioned printing is finished.
Rub resistance: print finish after 30 seconds, smear the yellow color lump that above-mentioned printing is finished with pointing.Observe color lump and whether fade, whether have finger mark to stay on the color lump.
1-does not have finger mark, does not fade;
2-has finger mark, does not fade;
3-has finger mark, has to fade.
Chroma: the color of the yellow color lump that the above-mentioned printing of Eye oney instrument test of use GretagMacbethg company was finished after printing was finished, obtain L, a and the b value of color, the bright-dark degree of L representative color wherein, the degree that the degree that a representative color is red partially or green partially, b representative color are yellow partially or blue partially.Chroma is calculated as follows, chroma=(a
2+ b
2)
1/2
Precipitation capacity: 15 milliliters of ink sealings to be measured are kept in the glass reagent bottle, are positioned in 60 ℃ of baking ovens, the back taking-up of two weeks.Vial is tilted, and observation beds of precipitation thickness is recorded as many greater than 1 millimeter, and beds of precipitation thickness is recorded as few less than 1 millimeter, as does not have tangible beds of precipitation liquid flow record for not having.
Superiority of the present invention is: use method of the present invention to prepare yellow ink-jet paint ink, it is good to have rub resistance, the advantage that glossiness is good, and can obtain satisfied reflection density and chroma, and effectively reduced the sedimentation problem of using a certain yellow ultramarine to bring because of separately.
(4) embodiment:
With 10 parts of Pigment Yellow 73 C.I.P.Y.74,10 parts of Zetasperse 2500 and 80 parts of water, mix.Being ground to granularity is 100nm, measures mill base A.
With 10 parts of Pigment Yellow 73 C.I.P.Y.155,10 parts of Zetasperse 2500 and 80 parts of water, mix.Being ground to granularity is 100nm, measures mill base B.
With 6.9 parts of Pigment Yellow 73 C.I.P.Y.74 and 8.1 parts of Pigment Yellow 73 C.I.P.Y.155,15 parts of Zetasperse 2500 and 70 parts of water, mix.Being ground to granularity is 100nm, measures mill base C.
Embodiment 1
According to the listed formula rate of table 1,4 parts of 2-pyrrolidone, 4 parts of glycerol, 1.5 parts of Diethylene Glycol butyl ether, 0.5 part of Surfynol465,0.1 part of Dynol 604 and 23.3 parts of water are mixed; Above-mentioned mixing solutions is added drop-wise among 16.6 parts of mill base C, and mixing the back is 0.8 micron membrane filtration with the aperture, obtains Yellow pigment jet ink.
Embodiment 2
According to the listed formula rate of table 1,4 parts of 2-pyrrolidone, 4 parts of glycerol, 1.5 parts of Diethylene Glycol butyl ether, 0.5 part of Surfynol465,604,1.5 parts of Joncryl 67 solution of 0.1 part of Dynol and 21.8 parts of water are mixed; Above-mentioned mixing solutions is added drop-wise among 16.6 parts of mill base C, and mixing the back is 0.8 micron membrane filtration with the aperture, obtains Yellow pigment jet ink.
Embodiment 3
According to the listed formula rate of table 1,4 parts of 2-pyrrolidone, 4 parts of glycerol, 1.5 parts of Diethylene Glycol butyl ether, 0.5 part of Surfynol465,604,1.5 parts of Joncryl 67 solution of 0.1 part of Dynol and 13.4 parts of water are mixed; Above-mentioned mixing solutions is added drop-wise in the mixing mill base that contains 11.9 parts of mill base A and 13.1 parts of mill base B, and mixing with the aperture is 0.8 micron membrane filtration, obtains Yellow pigment jet ink.
Comparative example 1
According to the listed formula rate of table 1,4 parts of 2-pyrrolidone, 4 parts of glycerol, 1.5 parts of Diethylene Glycol butyl ether, 0.5 part of Surfynol465,0.1 part of Dynol 604 and 14.9 parts of water are mixed; Above-mentioned mixing solutions is added drop-wise among 25 parts of mill base A, and mixing with the aperture is 0.8 micron membrane filtration, obtains Yellow pigment jet ink.
Comparative example 2
According to the listed formula rate of table 1,4 parts of 2-pyrrolidone, 4 parts of glycerol, 1.5 parts of Diethylene Glycol butyl ether, 0.5 part of Surfynol465,0.1 part of Dynol 604 and 14.9 parts of water are mixed; Above-mentioned mixing solutions is added drop-wise among 25 parts of mill base B, and mixing with the aperture is 0.8 micron membrane filtration, obtains Yellow pigment jet ink.
Comparative example 3
According to the listed formula rate of table 1,8 parts of 2-pyrrolidone, 8 parts of glycerol, 3 parts of Diethylene Glycol butyl ether, 1 part of Surfynol465,604,3 parts of Joncryl 67 solution of 0.2 part of Dynol and 26.8 parts of water are mixed; Above-mentioned mixing solutions is added drop-wise among 50 parts of mill base A, and mixing with the aperture is 0.8 micron membrane filtration, obtains Yellow pigment jet ink.
Comparative example 4
According to the listed formula rate of table 1,8 parts of 2-pyrrolidone, 8 parts of glycerol, 3 parts of Diethylene Glycol butyl ether, 1 part of Surfynol465,604,3 parts of Joncryl 67 solution of 0.2 part of Dynol and 26.8 parts of water are mixed; Above-mentioned mixing solutions is added drop-wise among 50 parts of mill base B, and mixing with the aperture is 0.8 micron membrane filtration, obtains Yellow pigment jet ink.
Table 1 formula table
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | |
| The 2-pyrrolidone | ??4 | ??4 | ??4 | ??4 | ??4 | ??8 | ??8 |
| Glycerol | ??4 | ??4 | ??4 | ??4 | ??4 | ??8 | ??8 |
| The Diethylene Glycol butyl ether | ??1.5 | ??1.5 | ??1.5 | ??1.5 | ??1.5 | ??3 | ??3 |
| ??Surfynol?465 | ??0.5 | ??0.5 | ??0.5 | ??0.5 | ??0.5 | ??1 | ??1 |
| ??Dynol?604 | ??0.1 | ??0.1 | ??0.1 | ??0.1 | ??0.1 | ??0.2 | ??0.2 |
| Joncryl 67 solution | ??1.5 | ??1.5 | ??3 | ??3 | |||
| Water | ??23.3 | ??21.8 | ??13.4 | ??14.9 | ??14.9 | ??26.8 | ??26.8 |
| Mill base A | ??11.9 | ??25 | ??50 | ||||
| Mill base B | ??13.1 | ??25 | ??50 | ||||
| Mill base C | ??16.6 | ??16.6 |
(1) prescription does not contain adhesion promoter effect assessment (seeing Table 2)
When not containing adhesion promoter in the prescription, use PY74 pigment (comparative example 1) separately, glossiness is low; When using PY155 pigment (comparative example 2) separately, the reflection density deficiency; Then can obtain the promising result of ° angle glossiness＞90, ° angle glossiness＞50,60, reflection density＞1,20 and chroma＞90 when using hybrid pigment (embodiment 1) simultaneously.
Table 2 prescription does not contain the adhesion promoter effect assessment
| Pigment content | Rub resistance | Glossiness/20 ° | Glossiness/60 ° | Reflection density | Chroma | |
| Embodiment 1 | ??5％ | ??3 | ??66.7 | ??97 | ??1.08 | ??93.4 |
| Comparative example 1 | ??5％ | ??3 | ??46.8 | ??81.1 | ??1.08 | ??97.1 |
| Comparative example 2 | ??5％ | ??3 | ??62.6 | ??98.5 | ??0.86 | ??80.6 |
(2) prescription contains adhesion promoter effect assessment (seeing Table 3)
When containing adhesion promoter in the prescription, use PY74 pigment (comparative example 3) separately, glossiness is low, and rub resistance is still relatively poor; When using PY155 pigment (comparative example 4) separately, the reflection density deficiency, chroma is low; Then can obtain satisfied reflection density, glossiness and chroma preferably when using hybrid pigment (embodiment 2) simultaneously, and erasibility is good.
Table 3 prescription contains the adhesion promoter effect assessment
| Pigment content | Rub resistance | Glossiness/20 ° | Glossiness/60 ° | Reflection density | Chroma | Precipitation capacity | |
| Embodiment 2 | ??5％ | ??1 | ??59.8 | ??97.8 | ??1.06 | ??93.3 | Few |
| Comparative example 3 | ??5％ | ??2 | ??43.7 | ??81.9 | ??1.05 | ??95 | Many |
| Comparative example 4 | ??5％ | ??1 | ??52.1 | ??87.8 | ??0.8 | ??78.9 | Do not have |
Claims (10)
1, a kind of Yellow pigment jet ink, it contains permeate agent, wetting Agent for Printing Inks, tensio-active agent and mill base, it is characterized in that containing in the said mill base yellow ultramarine and dispersion agent, yellow ultramarine is Pigment Yellow 73 C.I.P.Y.74 and Pigment Yellow 73 C.I.P.Y.155, and wherein the ratio range of Pigment Yellow 73 C.I.P.Y.74 and Pigment Yellow 73 C.I.P.Y.155 is 0.25～4; Permeate agent accounts for 1～25% in the said Yellow pigment jet ink, and wetting Agent for Printing Inks accounts for 1～30%, surfactant comprise 0.01～5%, and mill base accounts for 15～60%; Above-mentioned each percentage composition is mass percent.
2,, it is characterized in that said permeate agent is at least a in 2-pyrrolidone, N-methyl-2-pyrrolidone, butyl glycol ether, Diethylene Glycol butyl ether, triethylene glycol butyl ether, propylene glycol butyl ether, dipropylene glycol butyl ether, ethanol, the Virahol according to the said a kind of Yellow pigment jet ink of claim 1.
3, according to the said a kind of Yellow pigment jet ink of claim 1, it is characterized in that said wetting Agent for Printing Inks is glycerol, ethylene glycol, Diethylene Glycol, triethylene glycol, TEG, PEG400, PEG600,1,2-propylene glycol, 1, ammediol, 1,2-butyleneglycol, 1,4-butyleneglycol, 1,2-pentanediol, 1,5-pentanediol, 1,2-hexylene glycol, 1,2, at least a in 6-hexanetriol, the TriMethylolPropane(TMP).
4, according to the said a kind of Yellow pigment jet ink of claim 1, it is characterized in that said tensio-active agent is Air Products (air chemical industry) product Surfynol 420, Surfynol 440, Surfynol465, Surfynol 485, Surfynol 104E, Surfynol 2502, Dynol604, Dynol607, Dow Corning (DOW CORNING) product DC-67, BYK-Chemie (Bi Ke chemistry) product B YK345, BYK346, BYK347, BYK348, at least a among Rhodia (Luo Diya) product DS-4, the DS-10.
5,, it is characterized in that said dispersion agent is at least a among Air Products (air chemical industry) product: the Zetasperse 1200,1400,1600,2100,2300,2500,3400,3700 according to the said a kind of Yellow pigment jet ink of claim 1.
6,, it is characterized in that to contain in the said Yellow pigment jet ink sterilant, pH regulator agent, adhesion promoter and metal ion chelation agent according to the said a kind of Yellow pigment jet ink of claim 1.
7,, it is characterized in that said sterilant can be 1,2-phenylpropyl alcohol isothiazoline-3-ketone according to the said a kind of Yellow pigment jet ink of claim 6; Said pH regulator agent can be at least a in sodium hydroxide, potassium hydroxide, triethylamine, ammoniacal liquor, the trolamine; Said adhesion promoter can be at least a among BASF (BASF) product: Joncryl56, Joncryl58, Joncryl63, Joncryl67, the Joncryl611; Said metal ion chelation agent can be a disodium EDTA.
8, a kind of compound method of Yellow pigment jet ink is characterized in that Yellow pigment jet ink takes the preparation of following method:
(1) pigment, dispersion agent and water are ground, to mean particle size less than 200 nanometers, obtain ink for ink-jet print use dispersible pigment color paste;
(2) with water, permeate agent, wetting Agent for Printing Inks, tensio-active agent and sterilant, pH regulator agent, adhesion promoter, metal ion chelation agent mix, and obtain mixing solutions;
(3) described mixing solutions of step (2) and the described water-based pigment colour paste of step (1) are mixed;
(4) ink that step (3) gained is mixed is 0.8 micron membrane filtration with the aperture;
(5) obtain the related Yellow pigment jet ink of the present invention.
9, the compound method of said a kind of Yellow pigment jet ink according to Claim 8 is characterized in that the mill base of making in the step (1) can make different mill bases in advance, and is standby to do.
10, the compound method of said a kind of Yellow pigment jet ink according to Claim 8, it is characterized in that grinding plant that the grinding in the step (1) is adopted be pin bar type shredder, ball mill and novel nano performance shredder-
A kind of among the-MILL NPM; Said pin bar type shredder, rotating speed is 600～4000rpm, it is the zirconium oxide bead of 0.05～1mm that grinding medium adopts diameter, between preferred diameter 0.05～0.2mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910070136 CN101654573B (en) | 2009-08-14 | 2009-08-14 | Yellow pigment jet ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910070136 CN101654573B (en) | 2009-08-14 | 2009-08-14 | Yellow pigment jet ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101654573A true CN101654573A (en) | 2010-02-24 |
| CN101654573B CN101654573B (en) | 2011-11-30 |
Family
ID=41709034
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910070136 Expired - Fee Related CN101654573B (en) | 2009-08-14 | 2009-08-14 | Yellow pigment jet ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101654573B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312449A (en) * | 2014-11-19 | 2015-01-28 | 湖南盈博数码科技产业发展有限公司 | Colorless adhesive ink for 3D printer and preparation method of colorless adhesive ink |
| CN104356961A (en) * | 2014-11-19 | 2015-02-18 | 湖南盈博数码科技产业发展有限公司 | Colored adhesive ink for 3D printers and preparation method thereof |
| CN105694591A (en) * | 2016-04-25 | 2016-06-22 | 广州市番禺区协运来化工用品有限公司 | Digital printing ink and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4510421B2 (en) * | 2003-10-20 | 2010-07-21 | キヤノンファインテック株式会社 | Ink jet recording ink, ink jet recording method, ink cartridge, and ink jet recording apparatus |
| DE102004010448A1 (en) * | 2004-03-01 | 2005-09-22 | Clariant Gmbh | Use of a pigment composition with mixed crystals based on C.I. Pigment Yellow 74 |
| JP2009173853A (en) * | 2007-12-28 | 2009-08-06 | Seiko Epson Corp | Ink set for inkjet recording and inkjet recording method |
-
2009
- 2009-08-14 CN CN 200910070136 patent/CN101654573B/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312449A (en) * | 2014-11-19 | 2015-01-28 | 湖南盈博数码科技产业发展有限公司 | Colorless adhesive ink for 3D printer and preparation method of colorless adhesive ink |
| CN104356961A (en) * | 2014-11-19 | 2015-02-18 | 湖南盈博数码科技产业发展有限公司 | Colored adhesive ink for 3D printers and preparation method thereof |
| CN105694591A (en) * | 2016-04-25 | 2016-06-22 | 广州市番禺区协运来化工用品有限公司 | Digital printing ink and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101654573B (en) | 2011-11-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103450740B (en) | Sublimation ink-jetting ink used for industrial nozzle and manufacturing method thereof | |
| CN100406527C (en) | Black pigment ink for ink-jet printer and method for preparing the same | |
| CN102140270B (en) | Water-based ink for ink jet recording | |
| EP2376583B1 (en) | Inkjet ink, ink cartridge, image forming device, image forming method, and image formed matter | |
| EP3403840A1 (en) | Pretreatment solution, ink set and method for producing printed matter | |
| EP3564347B1 (en) | Cleaning liquid for aqueous ink | |
| CN102140271A (en) | Water-based ink for ink jet recording | |
| JP5310583B2 (en) | Water-based ink and ink cartridge for inkjet recording | |
| JP5198759B2 (en) | Water-based ink for inkjet recording | |
| CN105348919B (en) | Thermal transfer ink jet ink composition and preparation method thereof | |
| CN101654573B (en) | Yellow pigment jet ink | |
| CN1926202A (en) | Recording liquids | |
| JPWO2020162270A1 (en) | Ink, inkjet recording method and recording media | |
| JP5310584B2 (en) | Water-based ink and ink cartridge for inkjet recording | |
| CN102558943A (en) | Black water-based pigment ink | |
| JP2009057502A (en) | Inkjet recording ink | |
| JP2014091798A (en) | Water-based ink composition | |
| CN101544858B (en) | Set of pigment-type jet inks with larger color expression range | |
| JP2018150401A (en) | Ink composition for inkjet printing and printing method of hydrophobic fiber | |
| JP5310581B2 (en) | Water-based ink and ink cartridge for inkjet recording | |
| CN102558950A (en) | Water-based inkjet ink containing metal oxide | |
| JP2009143971A (en) | Ink-jet recording ink | |
| JP5310582B2 (en) | Water-based ink and ink cartridge for inkjet recording | |
| US11407911B2 (en) | Water-based ink for ink-jet recording and ink-jet recording method | |
| CN102516843A (en) | Magenta aqueous pigment ink |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20111130 Termination date: 20150814 |
|
| EXPY | Termination of patent right or utility model |