CN101643624A - UV curing high wear-resistant low luster coating and preparation method thereof - Google Patents

UV curing high wear-resistant low luster coating and preparation method thereof Download PDF

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Publication number
CN101643624A
CN101643624A CN200910160736A CN200910160736A CN101643624A CN 101643624 A CN101643624 A CN 101643624A CN 200910160736 A CN200910160736 A CN 200910160736A CN 200910160736 A CN200910160736 A CN 200910160736A CN 101643624 A CN101643624 A CN 101643624A
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minute
stirred
rotating speed
resin solution
high wear
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CN200910160736A
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Inventor
黄杰良
刘志辉
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Dongguan Jiazhuocheng Chemical Technology Co Ltd
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Dongguan Jiazhuocheng Chemical Technology Co Ltd
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Priority to CN200910160736A priority Critical patent/CN101643624A/en
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Abstract

The invention provides a UV curing high wear-resistant low luster coating and a preparation method thereof. The coating comprises the following components in percentage by weight: primer and a curingagent, wherein, the primer comprises 55-60 of hydroxyl acrylic resins, 10-13 of solution containing 20% of cellulose acetate butyrate resins, 4-6 of methyl isobutyl ketone, 0.1-0.2 of flow agent, 5-7of aluminum paste and 17-19 of ethyl acetate; the curing agent comprises 55-60 of hexamethylene diisocyanate, 10-15 of unsaturated aliphatic polyurethane acrylate and 26-32 of butyl acetate. The invention has the advantages as follows: the invention has low VOC discharge when being used for construction under common coating conditions; the invention can achieve the effects of high wear resistanceand difficult surface shining by using the common plastics coating method; the invention features simplicity and commonality of construction and has very good adhesion on the plastics and aluminum; the invention features thin film thickness and has cost lower than that of the common UV coatings.

Description

UV curing high wear-resistant low luster coating and preparation method thereof
Technical field
The present invention relates to a kind of UV curing high wear-resistant low luster coating and preparation method thereof, this coating is suitable for the plastics keyboard, as with using on ABS+PC keycap or the aluminium keyboard.
Background technology
The a large amount of of computer popularize; keyboard has become in our daily life and the work and has contacted maximum products; but present keyboard is still plastics or it is main adopting the conventional mute light ultraviolet-curing paint of a small amount of spraying mainly; because the defective of plastics itself and general ultraviolet photo-cured coating self design has caused it not anti-scratch; not wear-resisting; at the long-time shinny or coating loss in rear surface that uses, influenced the attractive in appearance of keyboard and reduced its protectiveness.
Summary of the invention
The present invention seeks to overcome above-mentioned defective, a kind of UV curing high wear-resistant low luster coating is provided, this coating has that coated membrane is thin, the strong characteristics of the good and anti-scratch performance of wear resistance.
Another object of the present invention provides a kind of method for preparing UV curing high wear-resistant low luster coating.
Technical scheme of the present invention is: a kind of UV curing high wear-resistant low luster coating is provided, comprises the following component of weight percent:
One, priming paint
(1), Hydroxylated acrylic resin 55-60;
(2), the broad 10-13 that contains 20% (weight percent) cellulose acetate butyrate resin;
(3), hexone 4-6;
(4), flow agent 0.1-0.2;
(5), aluminium-silver slurry 5-7;
(6), ethyl acetate 17-19;
Two, solidifying agent
(1), hexa-methylene two different hydrogen acid ether 55-60;
(2), unsaturated aliphatic polyurethane-type acrylate 10-15;
(3), acetate butyl 26-32.
To a kind of improvement of the present invention, described UV curing high wear-resistant low luster coating also comprises the finish paint of weight percent, and its component is as follows:
(1) Viscoat 295 5-10;
(2), caprolactone modification dipentaerythritol acrylate 5-10;
(3), aliphatic urethane acrylate 20-25;
(4), aliphatic carbamate methacrylic ester 5-15;
(5), aerosil flatting silica 5-10;
(6), the solution 5-10 that contains 10% (weight percent) nano fumed silica;
(7), wetting dispersing agent 1-2;
(8), acetate butyl 5-15;
(9), 1-hydroxyl-cyclohexyl-phenyl ketone 3-6;
(10), two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxide 0.5-1;
(11), methylethylketone 5-7;
(12), organic silicon modified by polyether oxygen alkane 0.3-0.6.
A kind of method for preparing described UV curing high wear-resistant low luster coating comprises the steps:
One, the preparation of priming paint
(1), with Hydroxylated acrylic resin, broad, the hexone that contains 20% (weight percent) cellulose acetate butyrate resin and flow agent by after the described mixed of claim 1, in dispersion machine with rotating speed 1000RPM-1200RPM, stirred 5-15 minute, and made mixed resin solution;
(2), aluminium-silver slurry is put into ethyl acetate, soaked 15-25 minute, stirred 5-15 minute with rotating speed 300-500RPM with dispersion machine again, after fully disperseing, join again in the prepared mixed resin solution of (1) step,, stirred 15-25 minute again with rotating speed 500-700RPM.
Two, the preparation of solidifying agent
Hexa-methylene two different hydrogen acid ethers, unsaturated aliphatic polyurethane-type acrylate and acetate butyl by after the described mixed of claim 1, with rotating speed 1000RPM-1200RPM, were stirred 5-15 minute in dispersion machine, make mixed resin solution.
A kind of method for preparing described UV curing high wear-resistant low luster coating is characterized in that the preparation of its finish paint comprises the steps:
(1), Viscoat 295, caprolactone modification dipentaerythritol acrylate, aliphatic urethane acrylate and aliphatic carbamate methacrylic ester are pressed the described mixed of claim 2, in dispersion machine with rotating speed 1000RPM-1200RPM, stirred 10-20 minute, and made mixed resin solution A;
(2), with the aerosil flatting silica, contain 10% (weight percent) nano fumed silica, wetting dispersing agent and acetate butyl by the described mixed of claim 2, in dispersion machine with rotating speed 400RPM-600RPM, stirred 5-15 minute, and made mixed resin solution B;
(3) 1-hydroxyl-cyclohexyl-phenyl ketone and two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxide are pressed the described mixed of claim 2, in dispersion machine,, stirred 5-15 minute, make mixed resin solution C with rotating speed 400RPM-600RPM;
(4), put into mixed resin solution A respectively, in dispersion machine, stirred 5-15 minute with rotating speed 500-700RPM with mixed resin solution B, mixed resin solution C with in the organic silicon modified by polyether oxygen alkane of the described ratio of claim 2.
The present invention has following advantage:
1, under common application condition, constructs, have low VOC discharging;
2, use the common plastics coating process, it can reach high abrasion, and the surface is difficult for shinny effect;
3, Shi Gong simplification, versatility all has extraordinary sticking power simultaneously on plastic cement and aluminium;
4, low thickness, cost is lower than common UV coating.
Embodiment
One, the embodiment of finish paint
Example 1 (unit: KG)
(1), Hydroxylated acrylic resin 55;
(2), contain broad 13 of 20% (weight percent) cellulose acetate butyrate resin;
(3), hexone 6;
(4), flow agent 0.1;
(5), aluminium-silver slurry 7;
(6), ethyl acetate 18.9.
Example 2 (units: KG)
(1), Hydroxylated acrylic resin 56;
(2), contain broad 12 of 20% (weight percent) cellulose acetate butyrate resin;
(3), hexone 6;
(4), flow agent 0.2;
(5), aluminium-silver slurry 7;
(6), ethyl acetate 18.8.
Example 3 (units: KG)
(1), Hydroxylated acrylic resin 57;
(2), contain broad 12.8 of 20% cellulose acetate butyrate resin;
(3), hexone 4;
(4), flow agent 0.2;
(5), aluminium-silver slurry 7;
(6), ethyl acetate 19.
Example 4 (units: KG)
(1), Hydroxylated acrylic resin 58;
(2), contain broad 11.8 of 20% (weight percent) cellulose acetate butyrate resin;
(3), hexone 6;
(4), flow agent 0.2;
(5), aluminium-silver slurry 6;
(6), ethyl acetate 18.
Example 5 (units: KG)
(1), Hydroxylated acrylic resin 59;
(2), contain broad 12.8 of 20% (weight percent) cellulose acetate butyrate resin;
(3), hexone 6;
(4), flow agent 0.2;
(5), aluminium-silver slurry 5;
(6), ethyl acetate 17.
Example 6 (units: KG)
(1), Hydroxylated acrylic resin 60;
(2), contain broad 11 of 20% (weight percent) cellulose acetate butyrate resin;
(3), hexone 5;
(4), flow agent 0.2;
(5), aluminium-silver slurry 5;
(6), ethyl acetate 18.8.
The all available following method preparation of above-mentioned each example, preparation side is as follows:
(1), with Hydroxylated acrylic resin, broad, the hexone that contains 20% (weight percent) cellulose acetate butyrate resin and flow agent by after the described mixed of above-mentioned each example, in dispersion machine with rotating speed 1000RPM-1200RPM, stirred 5-15 minute, and made mixed resin solution;
(2), aluminium-silver slurry is put into ethyl acetate, soaked 15-25 minute, stirred 5-15 minute with rotating speed 300-500RPM with dispersion machine again, after fully disperseing, join again in the above-mentioned prepared mixed resin solution of (1) step,, stirred 15-25 minute again with rotating speed 500-700RPM.
Two, solidifying agent
Example 7 (units: KG)
(1), hexa-methylene two different hydrogen acid ethers 55;
(2), unsaturated aliphatic polyurethane-type acrylate 15;
(3), acetate butyl 30.
Example 8 (units: KG)
(1), hexa-methylene two different hydrogen acid ethers 56;
(2), unsaturated aliphatic polyurethane-type acrylate 13;
(3), acetate butyl 31.
Example 9 (units: KG)
(1), hexa-methylene two different hydrogen acid ethers 57;
(2), unsaturated aliphatic polyurethane-type acrylate 11;
(3), acetate butyl 32.
Example 10 (units: KG)
(1), hexa-methylene two different hydrogen acid ethers 58;
(2), unsaturated aliphatic polyurethane-type acrylate 13;
(3), acetate butyl 29.
Example 11 (units: KG)
(1), hexa-methylene two different hydrogen acid ethers 59;
(2), unsaturated aliphatic polyurethane-type acrylate 13;
(3), acetate butyl 28.
Example 12 (units: KG)
(1), hexa-methylene two different hydrogen acid ethers 60;
(2), unsaturated aliphatic polyurethane-type acrylate 10;
(3), acetate butyl 30.
Example 13 (units: KG)
(1), hexa-methylene two different hydrogen acid ethers 60;
(2), unsaturated aliphatic polyurethane-type acrylate 14;
(3), acetate butyl 26.
The all available following method preparation of each example in the solidifying agent, preparation side is as follows:
Hexa-methylene two different hydrogen acid ethers, unsaturated aliphatic polyurethane-type acrylate and acetate butyl are pressed in the solidifying agent after the described mixed of each example, in dispersion machine,, stirred 5-15 minute, make mixed resin solution with rotating speed 1000RPM-1200RPM.
Three, finish paint
Example 14 (units: KG)
(1) Viscoat 295 5.2;
(2), the caprolactone modification dipentaerythritol acrylate 10;
(3), aliphatic urethane acrylate 25;
(4), the aliphatic carbamate methacrylic ester 15;
(5), the aerosil flatting silica 10;
(6), the solution 5 that contains 10% (weight percent) nano fumed silica;
(7), wetting dispersing agent 1;
(8), acetate butyl 15;
(9), 1-hydroxyl-cyclohexyl-phenyl ketone 6;
(10), two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxides 0.5;
(11), methylethylketone 7;
(12), organic silicon modified by polyether oxygen alkane 0.3.
Example 15 (units: KG)
(1) Viscoat 295 10;
(2), the caprolactone modification dipentaerythritol acrylate 9;
(3), aliphatic urethane acrylate 25;
(4), the aliphatic carbamate methacrylic ester 13;
(5), the aerosil flatting silica 9;
(6), the solution 6 that contains 10% (weight percent) nano fumed silica;
(7), wetting dispersing agent 2;
(8), acetate butyl 15;
(9), 1-hydroxyl-cyclohexyl-phenyl ketone 4;
(10), two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxides 0.7;
(11), methylethylketone 6;
(12), organic silicon modified by polyether oxygen alkane 0.3.
Example 16 (units: KG)
(1) Viscoat 295 10;
(2), the caprolactone modification dipentaerythritol acrylate 10;
(3), aliphatic urethane acrylate 24;
(4), the aliphatic carbamate methacrylic ester 11;
(5), the aerosil flatting silica 10;
(6), the solution 7 that contains 10% (weight percent) nano fumed silica;
(7), wetting dispersing agent 2;
(8), acetate butyl 14.5;
(9), 1-hydroxyl-cyclohexyl-phenyl ketone 5;
(10), two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxides 1;
(11), methylethylketone 5;
(12), organic silicon modified by polyether oxygen alkane 0.5.
Example 17 (units: KG)
(1) Viscoat 295 10;
(2), the caprolactone modification dipentaerythritol acrylate 10;
(3), aliphatic urethane acrylate 23;
(4), the aliphatic carbamate methacrylic ester 9;
(5), the aerosil flatting silica 10;
(6), the solution 9.4 that contains 10% (weight percent) nano fumed silica;
(7), wetting dispersing agent 2;
(8), acetate butyl 15;
(9), 1-hydroxyl-cyclohexyl-phenyl ketone 3;
(10), two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxides 1;
(11), methylethylketone 7;
(12), organic silicon modified by polyether oxygen alkane 0.6.
Example 18 (units: KG)
(1) Viscoat 295 9;
(2), the caprolactone modification dipentaerythritol acrylate 10;
(3), aliphatic urethane acrylate 24;
(4), the aliphatic carbamate methacrylic ester 9.5;
(5), the aerosil flatting silica 10;
(6), the solution 9 that contains 10% (weight percent) nano fumed silica;
(7), wetting dispersing agent 2;
(8), acetate butyl 15;
(9), 1-hydroxyl-cyclohexyl-phenyl ketone 3;
(10), two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxides 1;
(11), methylethylketone 7;
(12), organic silicon modified by polyether oxygen alkane 0.5.
Example 19 (units: KG)
(1) Viscoat 295 10;
(2), the caprolactone modification dipentaerythritol acrylate 10;
(3), aliphatic urethane acrylate 25;
(4), the aliphatic carbamate methacrylic ester 5;
(5), the aerosil flatting silica 10;
(6), the solution 10 that contains 10% (weight percent) nano fumed silica;
(7), wetting dispersing agent 2;
(8), acetate butyl 13.4;
(9), 1-hydroxyl-cyclohexyl-phenyl ketone 6;
(10), two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxides 1;
(11), methylethylketone 7;
(12), organic silicon modified by polyether oxygen alkane 0.6.
Example 20 (units: KG)
(1) Viscoat 295 5;
(2), the caprolactone modification dipentaerythritol acrylate 5;
(3), aliphatic urethane acrylate 23.4;
(4), the aliphatic carbamate methacrylic ester 15;
(5), the aerosil flatting silica 10;
(6), the solution 10 that contains 10% (weight percent) nano fumed silica;
(7), wetting dispersing agent 2;
(8), acetate butyl 15;
(9), 1-hydroxyl-cyclohexyl-phenyl ketone 6;
(10), two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxides 1;
(11), methylethylketone 7;
(12), organic silicon modified by polyether oxygen alkane 0.6.
Example 21 (units: KG)
(1) Viscoat 295 10;
(2), the caprolactone modification dipentaerythritol acrylate 10;
(3), aliphatic urethane acrylate 20;
(4), the aliphatic carbamate methacrylic ester 13.4;
(5), the aerosil flatting silica 5;
(6), the solution 10 that contains 10% (weight percent) nano fumed silica;
(7), wetting dispersing agent 2;
(8), acetate butyl 15;
(9), 1-hydroxyl-cyclohexyl-phenyl ketone 6;
(10), two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxides 1;
(11), methylethylketone 7;
(12), organic silicon modified by polyether oxygen alkane 0.6.
Example 22 (units: KG)
(1) Viscoat 295 10;
(2), the caprolactone modification dipentaerythritol acrylate 10;
(3), aliphatic urethane acrylate 23.4;
(4), the aliphatic carbamate methacrylic ester 15;
(5), the aerosil flatting silica 10;
(6), the solution 10 that contains 10% (weight percent) nano fumed silica;
(7), wetting dispersing agent 2;
(8), acetate butyl 5;
(9), 1-hydroxyl-cyclohexyl-phenyl ketone 6;
(10), two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxides 1;
(11), methylethylketone 7;
(12), organic silicon modified by polyether oxygen alkane 0.6.
The all available following method preparation of each example in the finish paint, preparation side is as follows:
(1), Viscoat 295, caprolactone modification dipentaerythritol acrylate, aliphatic urethane acrylate and aliphatic carbamate methacrylic ester are pressed the described mixed of example 14-22, in dispersion machine with rotating speed 1000RPM-1200RPM, stirred 10-20 minute, and made mixed resin solution A;
(2), with the aerosil flatting silica, contain 10% (weight percent) nano fumed silica, wetting dispersing agent and acetate butyl and press the described mixed of example 14-22, in dispersion machine with rotating speed 400RPM-600RPM, stirred 5-15 minute, and made mixed resin solution B;
(3) 1-hydroxyl-cyclohexyl-phenyl ketone and two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxide are pressed the described mixed of claim 2, in dispersion machine,, stirred 5-15 minute, make mixed resin solution C with rotating speed 400RPM-600RPM;
(4), put into mixed resin solution A respectively, in dispersion machine, stirred 5-15 minute with rotating speed 500-700RPM with mixed resin solution B, mixed resin solution C with in the organic silicon modified by polyether oxygen alkane of the described ratio of example 14-22.
" ABS+PC " herein is meant the plastics of the mixed injection molding moulding of acrylonitrile-butadiene-styrene copolymer and polycarbonate.
The various examples of the above are preferred embodiments of the present invention, are not to be used for limiting practical range of the present invention, so all equivalences of being done according to the described feature of the present patent application claim change or modify, are included in the present patent application claim.

Claims (4)

1, a kind of UV curing high wear-resistant low luster coating is characterized in that, comprises the following component of weight percent:
One, priming paint
(1), Hydroxylated acrylic resin 55-60;
(2), the broad 10-13 that contains the cellulose acetate butyrate resin of 20% weight percent;
(3), hexone 4-6;
(4), flow agent 0.1-0.2;
(5), aluminium-silver slurry 5-7;
(6), ethyl acetate 17-19;
Two, solidifying agent
(1), hexa-methylene two different hydrogen acid ether 55-60;
(2), unsaturated aliphatic polyurethane-type acrylate 10-15;
(3), acetate butyl 26-32.
2, UV curing high wear-resistant low luster coating according to claim 1 is characterized in that, described UV curing high wear-resistant low luster coating also comprises the finish paint of weight percent, and its component is as follows:
(1) Viscoat 295 5-10;
(2), caprolactone modification dipentaerythritol acrylate 5-10;
(3), aliphatic urethane acrylate 20-25;
(4), aliphatic carbamate methacrylic ester 5-15;
(5), aerosil flatting silica 5-10;
(6), the solution 5-10 that contains the nano fumed silica of 10% weight percent;
(7), wetting dispersing agent 1-2;
(8), acetate butyl 5-15;
(9), 1-hydroxyl-cyclohexyl-phenyl ketone 3-6;
(10), two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxide 0.5-1;
(11), methylethylketone 5-7;
(12), organic silicon modified by polyether oxygen alkane 0.3-0.6.
3, a kind of method for preparing the described UV curing high wear-resistant low luster coating of claim 1 is characterized in that, comprises the steps:
One, the preparation of priming paint
(1), with Hydroxylated acrylic resin, broad, the hexone of cellulose acetate butyrate resin that contains 20% weight percent and flow agent by the described mixed of claim 1 after, in dispersion machine with rotating speed 1000RPM-1200RPM, stirred 5-15 minute, and made mixed resin solution;
(2), aluminium-silver slurry is put into ethyl acetate, soaked 15-25 minute, stirred 5-15 minute with rotating speed 300-500RPM with dispersion machine again, after fully disperseing, join again in the prepared mixed resin solution of (1) step,, stirred 15-25 minute again with rotating speed 500-700RPM.
Two, the preparation of solidifying agent
Hexa-methylene two different hydrogen acid ethers, unsaturated aliphatic polyurethane-type acrylate and acetate butyl by after the described mixed of claim 1, with rotating speed 1000RPM-1200RPM, were stirred 5-15 minute in dispersion machine, make mixed resin solution.
4, a kind of method for preparing the described UV curing high wear-resistant low luster coating of claim 2 is characterized in that, comprises the steps:
(1), Viscoat 295, caprolactone modification dipentaerythritol acrylate, aliphatic urethane acrylate and aliphatic carbamate methacrylic ester are pressed the described mixed of claim 2, in dispersion machine with rotating speed 1000RPM-1200RPM, stirred 10-20 minute, and made mixed resin solution A;
(2), with aerosil flatting silica, the nano fumed silica that contains 10% weight percent, wetting dispersing agent and acetate butyl by the described mixed of claim 2, in dispersion machine with rotating speed 400RPM-600RPM, stirred 5-15 minute, and made mixed resin solution B;
(3) 1-hydroxyl-cyclohexyl-phenyl ketone and two (2,4, the 6-trimethylbenzoyl)-phenyl phosphine oxide are pressed the described mixed of claim 2, in dispersion machine,, stirred 5-15 minute, make mixed resin solution C with rotating speed 400RPM-600RPM;
(4), put into mixed resin solution A respectively, in dispersion machine, stirred 5-15 minute with rotating speed 500-700RPM with mixed resin solution B, mixed resin solution C with in the organic silicon modified by polyether oxygen alkane of the described ratio of claim 2.
CN200910160736A 2009-07-08 2009-07-08 UV curing high wear-resistant low luster coating and preparation method thereof Pending CN101643624A (en)

Priority Applications (1)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101891996A (en) * 2010-07-05 2010-11-24 江门市制漆厂有限公司 Acrylic resin metallic brilliant baking paint
CN102167919A (en) * 2011-01-18 2011-08-31 南通大学 Ultraviolet-curable coating material for glass slide and preparation method thereof
CN103351802A (en) * 2013-06-18 2013-10-16 苏州皇冠涂料科技发展有限公司 Ultraviolet light curing colored paint
CN106566405A (en) * 2016-11-06 2017-04-19 江苏四方威凯科技有限公司 Highly-arranged super-texture scratch-resistant coating used for electric car plastic parts, and preparation method thereof
CN111704838A (en) * 2020-06-04 2020-09-25 广东省漆色彩新型材料有限公司 Integrated plastic part coating matte paint and preparation method and coating method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101891996A (en) * 2010-07-05 2010-11-24 江门市制漆厂有限公司 Acrylic resin metallic brilliant baking paint
CN102167919A (en) * 2011-01-18 2011-08-31 南通大学 Ultraviolet-curable coating material for glass slide and preparation method thereof
CN102167919B (en) * 2011-01-18 2013-04-17 南通大学 Ultraviolet-curable coating material for glass slide and preparation method thereof
CN103351802A (en) * 2013-06-18 2013-10-16 苏州皇冠涂料科技发展有限公司 Ultraviolet light curing colored paint
CN106566405A (en) * 2016-11-06 2017-04-19 江苏四方威凯科技有限公司 Highly-arranged super-texture scratch-resistant coating used for electric car plastic parts, and preparation method thereof
CN111704838A (en) * 2020-06-04 2020-09-25 广东省漆色彩新型材料有限公司 Integrated plastic part coating matte paint and preparation method and coating method thereof

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Open date: 20100210