CN101637176A - Pesticide suspension - Google Patents
Pesticide suspension Download PDFInfo
- Publication number
- CN101637176A CN101637176A CN200910189767A CN200910189767A CN101637176A CN 101637176 A CN101637176 A CN 101637176A CN 200910189767 A CN200910189767 A CN 200910189767A CN 200910189767 A CN200910189767 A CN 200910189767A CN 101637176 A CN101637176 A CN 101637176A
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- CN
- China
- Prior art keywords
- agent
- agricultural chemicals
- iprodione
- dimethomorph
- suspension agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000575 pesticide Substances 0.000 title abstract description 4
- 239000000725 suspension Substances 0.000 title abstract 3
- 239000005867 Iprodione Substances 0.000 claims abstract description 38
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 claims abstract description 38
- QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 claims abstract description 37
- 239000005761 Dimethomorph Substances 0.000 claims abstract description 37
- -1 polysiloxane Polymers 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 14
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 14
- 239000000080 wetting agent Substances 0.000 claims abstract description 13
- 239000003755 preservative agent Substances 0.000 claims abstract description 9
- 230000002335 preservative effect Effects 0.000 claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 8
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 7
- 239000000375 suspending agent Substances 0.000 claims description 30
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 21
- 239000003905 agrochemical Substances 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 230000002528 anti-freeze Effects 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 8
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 8
- 239000004299 sodium benzoate Substances 0.000 claims description 8
- 235000010234 sodium benzoate Nutrition 0.000 claims description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 8
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 7
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 6
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 claims description 6
- 229920000084 Gum arabic Polymers 0.000 claims description 6
- 235000010489 acacia gum Nutrition 0.000 claims description 6
- 239000000205 acacia gum Substances 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 229920005551 calcium lignosulfonate Polymers 0.000 claims description 6
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims description 6
- 150000004002 naphthaldehydes Chemical class 0.000 claims description 6
- 229920001568 phenolic resin Polymers 0.000 claims description 6
- 229920001285 xanthan gum Polymers 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 5
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 239000004310 lactic acid Substances 0.000 claims description 4
- 235000014655 lactic acid Nutrition 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 235000010413 sodium alginate Nutrition 0.000 claims description 4
- 239000000661 sodium alginate Substances 0.000 claims description 4
- 229940005550 sodium alginate Drugs 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 2
- 235000011613 Pinus brutia Nutrition 0.000 claims description 2
- 241000018646 Pinus brutia Species 0.000 claims description 2
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims description 2
- 235000018927 edible plant Nutrition 0.000 claims description 2
- 241000978776 Senegalia senegal Species 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000007798 antifreeze agent Substances 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 31
- 239000004576 sand Substances 0.000 description 30
- 238000003801 milling Methods 0.000 description 20
- 238000005303 weighing Methods 0.000 description 11
- 239000002245 particle Substances 0.000 description 10
- 244000215068 Acacia senegal Species 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 235000013399 edible fruits Nutrition 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 241000227653 Lycopersicon Species 0.000 description 4
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 2
- 241000223600 Alternaria Species 0.000 description 2
- 241000222290 Cladosporium Species 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 241000233654 Oomycetes Species 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 238000005338 heat storage Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000003405 preventing effect Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 241000198596 Alternaria tomatophila Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241001465180 Botrytis Species 0.000 description 1
- 241001157813 Cercospora Species 0.000 description 1
- 241000371644 Curvularia ravenelii Species 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 239000004117 Lignosulphonate Substances 0.000 description 1
- 206010027146 Melanoderma Diseases 0.000 description 1
- 241000131448 Mycosphaerella Species 0.000 description 1
- 241000228143 Penicillium Species 0.000 description 1
- 241001503951 Phoma Species 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 241001361634 Rhizoctonia Species 0.000 description 1
- 241000221662 Sclerotinia Species 0.000 description 1
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a pesticide suspension comprising effective amount of active components of iprodione and dimethomorph as well as a wetting agent, a dispersing agent, a defoaming agent, a thickening agent, a preservative and water with or without an antifreeze agent, wherein the wetting agent is one or more of alkylphenol formaldehyde resin polyethenoxy ether, polyether modified polysiloxane, fatty alcohol-polyoxyethylene ether and nekal. The iprodione and dimethomorph pesticide suspension is prepared by selecting the suitable wetting agent and compounding with other additives, has highsuspension rate and good stability, lowers the resistance risk of using the compound and enables the compound to have control effect obviously superior to that of a single preparation.
Description
Technical field
The invention belongs to technical field of pesticide, relate in particular to a kind of agricultural chemicals suspension agent.
Background technology
Iprodione is a kind of broad spectrum activity contact killing type protective fungicide, and it both can suppress the sprouting and the generation of fungal spore, and the also mycelial growth of controlled is promptly all influential to disease fungus each developmental stage in the history of life.Main controlling object is various crop, fruit tree and the fruit storage phase disease that Botrytis, clump stalk spore genus, Penicillium, Sclerotinia, Alternaria, Helminthosporium, Rhizoctonia, Phoma, mycosphaerella, Cercospora etc. cause, as the gray molds of the stalk break on grape grey mould, the tone fruit trees, alternaria leaf spot of apple, pears black spot, early blight of tomato, strawberry, vegetables etc.Though iprodione diseases prevention spectrum is wide, safety, preventive effect, its result of treatment is relatively poor, often wants the remarkably productive drug use of partner treatment.
Dimethomorph is the single-minded Oomycete fungi bactericide that kills, its effect characteristics are to destroy the formation of cell envelope, all there is effect in each stage to oomycetes history of life, the formation stage at sporangiophore and egg spore is particularly responsive, (＜0.25 μ g/ml) promptly is suppressed under extremely low concentration, and result of treatment is outstanding.Have than higher resistance risk but use separately, thus normal and the composite use of protective fungicide, with the generation of delaying drug resistance.
In process of crop growth, when usually can be subjected to multiple various pathogenic bacteria or infect harm in succession, this requires the control medicament that the activity profile of broad is arranged.Obviously, the independent use of iprodione or dimethomorph all can not reach this requirement.
At present, also not about the report of the suspending agent of iprodione and dimethomorph.
Summary of the invention
The purpose of the embodiment of the invention is to provide a kind of suspensibility height, good stability, and also the composition for preventing and controlling effect obviously is better than the agricultural chemicals suspension agent of single agent.
The embodiment of the invention is to realize like this, a kind of agricultural chemicals suspension agent, comprise effective amount of actives iprodione and dimethomorph, and wetting agent, dispersant, defoamer, thickener, preservative and water, contain or do not contain antifreeze, wherein, wetting agent is an alkyl phenol formaldehyde resin polyoxyethylene ether, polyether-modified polysiloxane, fatty alcohol-polyoxyethylene ether and draw back in the powder one or more.
Compared with prior art, technique scheme is selected suitable wetting agent, cooperates other auxiliary agent to make the suspending agent of iprodione and dimethomorph, referring to embodiment table 1 and table 2 data, this suspending agent suspensibility height, good stability, the composition for preventing and controlling effect obviously is better than single agent.In addition, owing to use composition, its resistance risk has also reduced.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer,, the present invention is further elaborated below in conjunction with embodiment.Should be appreciated that specific embodiment described herein only in order to explanation the present invention, and be not used in qualification the present invention.
The agricultural chemicals suspension agent of the embodiment of the invention comprises effective amount of actives iprodione and dimethomorph, and wetting agent, dispersant, defoamer, thickener, preservative and water, contains or do not contain antifreeze.Wherein, wetting agent is an alkyl phenol formaldehyde resin polyoxyethylene ether, polyether-modified polysiloxane, fatty alcohol-polyoxyethylene ether, draw back in the powder one or more, preferred alkyl fluosite APEO, one or more in polyether-modified polysiloxane and the fatty alcohol-polyoxyethylene ether.
More specifically, above-mentioned suspension agent composition, each component and weight content thereof are as follows:
Iprodione 5-30%
Dimethomorph 5-30%
Wetting agent 1-5%
Dispersant 2-8%
Antifreeze 0-10%
Defoamer 0.1-2%
Thickener 0.1-3%
Preservative 0.1-3%
Water supplies 100%.
There is no particular restriction for the antifreeze of the embodiment of the invention, is the antifreeze that this area is commonly used, for example, can select in ethylene glycol, propane diols, glycerine, glycerine, the urea one or more.
There is no particular restriction for the defoamer of the embodiment of the invention, is the defoamer that this area is commonly used, for example, can select in dimethyl silicone polymer, isooctanol, the n-octyl alcohol one or more.
There is no particular restriction for the thickener of the embodiment of the invention, is the thickener that this area is commonly used, for example, can select in xanthans, gum Arabic, sodium alginate, the aluminium-magnesium silicate one or more.
There is no particular restriction for the preservative of the embodiment of the invention, is this area preservative commonly used, for example one or more in Sodium Benzoate, card pine, the lactic acid.
There is no particular restriction for the embodiment of the invention, is the dispersant that this area is commonly used, for example, can select in calcium lignosulfonate, alkyl phenolic group polyoxyethylene groups phosphate, poly-naphthaldehyde sulfonate sodium, the di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate one or more.
Embodiment 1
Weighing iprodione (content 94%) 5.3g, dimethomorph (content 97%) 15.5g, alkyl phenol formaldehyde resin polyoxyethylene ether 2g, calcium lignosulfonate 4g, ethylene glycol 3g, dimethyl silicone polymer 0.4g, xanthans 0.25g, Sodium Benzoate 0.25g, water 69.3g fully mixes, disperses, enter the sand mill sand milling after being uniformly dispersed, sand milling to particle diameter 90% promptly gets 20% iprodione dimethomorph suspending agent less than 5 microns.
Embodiment 2
Weighing iprodione (content 94%) 21.3g, dimethomorph (content 97%) 20.6g, extraordinary polyether-modified polysiloxane 2g, alkyl phenolic group polyoxyethylene groups phosphate 5g, propane diols 4g, isooctanol 0.8g, gum Arabic 0.2g blocks loose 0.2g, and water 45.9g fully mixes, disperses, enter the sand mill sand milling after being uniformly dispersed, sand milling to particle diameter 90% promptly gets 40% iprodione dimethomorph suspending agent less than 5 microns.
Embodiment 3
Weighing iprodione (content 94%) 31.9g, dimethomorph (content 97%) 5.2g, fatty alcohol-polyoxyethylene ether 2g, poly-naphthaldehyde sulfonate sodium 4g, glycerine 4g, n-octyl alcohol 1g, sodium alginate 0.5g, lactic acid 0.5g, water 50.9g fully mixes, disperses, enter the sand mill sand milling after being uniformly dispersed, sand milling to particle diameter 90% promptly gets 35% iprodione dimethomorph suspending agent less than 5 microns.
Embodiment 4
Weighing iprodione (content 94%) 5.3g, dimethomorph (content 97%) 5.2g, draw back powder 2g, alkyl phenolic group polyoxyethylene groups phosphate 3g, propane diols 4g, isooctanol 0.8g, gum Arabic 0.3g, Sodium Benzoate 0.3g, water 79.1g fully mixes, disperses, enter the sand mill sand milling after being uniformly dispersed, sand milling to particle diameter 90% promptly gets 10% iprodione dimethomorph suspending agent less than 5 microns.
Embodiment 5
Weighing iprodione (content 94%) 16.0g, dimethomorph (content 97%) 30.9g, alkyl phenol formaldehyde resin polyoxyethylene ether 2g, calcium lignosulfonate 5g, ethylene glycol 4g, dimethyl silicone polymer 0.4g, xanthans 0.2g, Sodium Benzoate 0.2g, water 41.3g fully mixes, disperses, enter the sand mill sand milling after being uniformly dispersed, sand milling to particle diameter 90% promptly gets 45% iprodione dimethomorph suspending agent less than 5 microns.
Embodiment 6
Weighing iprodione (content 94%) 21.3g, dimethomorph (content 97%) 30.9g, fatty alcohol-polyoxyethylene ether 2g, poly-naphthaldehyde sulfonate sodium 5g, ethylene glycol 4g, isooctanol 1g, sodium alginate 0.3g, lactic acid 0.3g, water 35.2g fully mixes, disperses, enter the sand mill sand milling after being uniformly dispersed, sand milling to particle diameter 90% promptly gets 50% iprodione dimethomorph suspending agent less than 5 microns.
Embodiment 7
Weighing iprodione (content 94%) 31.9g, dimethomorph (content 97%) 30.9g, draw back powder 2g, poly-naphthaldehyde sulfonate sodium 6g, urea 4g, dimethyl silicone polymer 0.4g, xanthans 0.1g, Sodium Benzoate 0.1g, water 24.6g fully mixes, disperses, enter the sand mill sand milling after being uniformly dispersed, sand milling to particle diameter 90% promptly gets 60% iprodione dimethomorph suspending agent less than 5 microns.
Comparative Examples 1
Weighing iprodione (content 94%) 16.0g, dimethomorph (content 97%) 15.5g, alkyl phenolic group polyoxyethylene groups ether 2g, alkyl naphthalene sulfonic acid condensation product Morwet D-4253g, ethylene glycol 4g, dimethyl silicone polymer 0.4g, xanthans 0.1g, Sodium Benzoate 0.1g, water 58.9g fully mixes, disperses, enter the sand mill sand milling after being uniformly dispersed, sand milling to particle diameter 90% promptly gets 30% iprodione dimethomorph suspending agent less than 5 microns.Cohesion occurs after the heat storage, and knot end phenomenon is arranged, suspensibility is 67%.
Comparative Examples 2
Weighing iprodione (content 94%) 10.6g, dimethomorph (content 97%) 30.9g, phenethyl phenol polyethenoxy ether 2g, MODIFIED LIGNOSULPHONATE 4g, propane diols 4g, isooctanol 2g, gum Arabic 0.15g, Sodium Benzoate 0.15g, water 46.2g fully mixes, disperses, enter the sand mill sand milling after being uniformly dispersed, sand milling to particle diameter 90% promptly gets 40% iprodione dimethomorph suspending agent less than 5 microns.Cohesion occurs after the heat storage, and knot end phenomenon is arranged, suspensibility is 72%.
Comparative Examples 3
Weighing dimethomorph (content 97%) 51.5g, calcium lignosulfonate 5g, poly-naphthaldehyde sulfonate sodium 4g, draw back powder 3g, white carbon 10g, kaolin 26.5g, fully mix, disperse, enter airslide disintegrating mill after being uniformly dispersed and pulverize, promptly get 50% dimethomorph wetting powder.
Comparative Examples 4
Weighing iprodione (content 94%) 27.1g, calcium lignosulfonate 3g, phenethyl phenol polyethenoxy ether 1g, ethylene glycol 4g, dimethyl silicone polymer 0.4g, gum Arabic 0.2g, water 64.3g.Enter the sand mill sand milling after all materials are mixed, sand milling to particle diameter 90% less than 5 microns, promptly get 25.5% iprodione suspending agent.
Embodiments of the invention 1～7 iprodione dimethomorph suspending agent the key technical indexes is as shown in table 1:
Table 1
By above result as can be known, the agricultural chemicals suspension agent good stability of the embodiment of the invention.
3～4 pairs of graw mold of tomato of the iprodione dimethomorph suspending agent of the embodiment of the invention 1～7 and Comparative Examples, cladosporium leaf and fruit mould of tomato pot experiment effect, result of the test is as shown in table 2:
Table 2
Result of the test shows, iprodione, dimethomorph and iprodione dimethomorph compounded formula control graw mold of tomato, cladosporium leaf and fruit mould of tomato, iprodione dimethomorph compounded formula control efficiency is better than single agent, and is the most outstanding with 40% iprodione dimethomorph prescription control efficiency especially.
The above only is preferred embodiment of the present invention, not in order to restriction the present invention, all any modifications of being done within the spirit and principles in the present invention, is equal to and replaces and improvement etc., all should be included within protection scope of the present invention.
Claims (8)
1, a kind of agricultural chemicals suspension agent, comprise effective amount of actives iprodione and dimethomorph, and wetting agent, dispersant, defoamer, thickener, preservative and water, contain or do not contain antifreeze, wherein, described wetting agent is an alkyl phenol formaldehyde resin polyoxyethylene ether, polyether-modified polysiloxane, fatty alcohol-polyoxyethylene ether and draw back in the powder one or more.
2, as agricultural chemicals suspension agent as described in the claim 2, it is characterized in that, with in alkyl phenol formaldehyde resin polyoxyethylene ether, polyether-modified polysiloxane and the fatty alcohol-polyoxyethylene ether one or more as wetting agent.
3, agricultural chemicals suspension agent as claimed in claim 1 is characterized in that, wherein each component and percentage by weight thereof are as follows:
Iprodione 5-30%
Dimethomorph 5-30%
Wetting agent 1-5%
Dispersant 2-8%
Antifreeze 0-10%
Defoamer 0.1-2%
Thickener 0.1-3%
Preservative 0.1-3%
Water supplies 100%.
4, agricultural chemicals suspension agent as claimed in claim 1 is characterized in that, described antifreeze is selected from one or more in ethylene glycol, propane diols, glycerine, glycerine, the urea.
5, agricultural chemicals suspension agent as claimed in claim 1 is characterized in that, described defoamer is selected from one or more in dimethyl silicone polymer, isooctanol, the n-octyl alcohol.
6, agricultural chemicals suspension agent as claimed in claim 1 is characterized in that, described thickener is selected from one or more in xanthans, gum Arabic, sodium alginate, the aluminium-magnesium silicate.
7, agricultural chemicals suspension agent as claimed in claim 1 is characterized in that, described preservative is selected from one or more in Sodium Benzoate, card pine, the lactic acid.
8, agricultural chemicals suspension agent as claimed in claim 1 is characterized in that, described dispersant is one or more in calcium lignosulfonate, alkyl phenolic group polyoxyethylene groups phosphate, poly-naphthaldehyde sulfonate sodium, the di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910189767 CN101637176B (en) | 2009-08-27 | 2009-08-27 | Pesticide suspension |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910189767 CN101637176B (en) | 2009-08-27 | 2009-08-27 | Pesticide suspension |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101637176A true CN101637176A (en) | 2010-02-03 |
| CN101637176B CN101637176B (en) | 2013-09-18 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN 200910189767 Active CN101637176B (en) | 2009-08-27 | 2009-08-27 | Pesticide suspension |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101836627A (en) * | 2010-05-17 | 2010-09-22 | 天津师范大学 | Dimethomorph-containing pesticide suspension concentrate and preparation method thereof |
| CN103734164A (en) * | 2013-12-28 | 2014-04-23 | 上海艳紫化工科技有限公司 | Pesticide bactericidal suspension liquid |
| CN107114368A (en) * | 2017-06-01 | 2017-09-01 | 中国农业科学院植物保护研究所 | A kind of dimethomorph dispersible oil-suspending agent and preparation method and application |
| CN109769851A (en) * | 2019-04-02 | 2019-05-21 | 陕西省石油化工研究设计院 | A kind of agricultural chemicals suspension agent of Tebuconazole and dithiocyano-methane compounding |
| CN115735909A (en) * | 2022-11-07 | 2023-03-07 | 河北威远生物化工有限公司 | Preparation method of stable and synergistic pesticide suspending agent |
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| DE3689506D1 (en) * | 1985-10-09 | 1994-02-17 | Shell Int Research | New acrylic acid amides. |
| DE3805235A1 (en) * | 1988-02-19 | 1989-08-31 | Shell Int Research | METHOD FOR PRODUCING 3,3-DIARYLACRYLIC ACID AMIDES |
| CN1155977A (en) * | 1995-08-28 | 1997-08-06 | 化学工业部沈阳化工研究院 | Acrylamide germicide containing fluoro-diphenyl |
| CN1864485A (en) * | 2006-05-12 | 2006-11-22 | 江苏耕耘化学有限公司 | Myclobutani suspension composition and method for preparing same |
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| CN101836627A (en) * | 2010-05-17 | 2010-09-22 | 天津师范大学 | Dimethomorph-containing pesticide suspension concentrate and preparation method thereof |
| CN101836627B (en) * | 2010-05-17 | 2013-05-29 | 天津师范大学 | Dimethomorph-containing pesticide suspension concentrate and preparation method thereof |
| CN103734164A (en) * | 2013-12-28 | 2014-04-23 | 上海艳紫化工科技有限公司 | Pesticide bactericidal suspension liquid |
| CN103734164B (en) * | 2013-12-28 | 2016-01-20 | 上海艳紫化工科技有限公司 | Pesticide bactericidal suspension liquid |
| CN107114368A (en) * | 2017-06-01 | 2017-09-01 | 中国农业科学院植物保护研究所 | A kind of dimethomorph dispersible oil-suspending agent and preparation method and application |
| CN107114368B (en) * | 2017-06-01 | 2020-02-14 | 中国农业科学院植物保护研究所 | Dimethomorph dispersible oil suspending agent and preparation method and application thereof |
| CN109769851A (en) * | 2019-04-02 | 2019-05-21 | 陕西省石油化工研究设计院 | A kind of agricultural chemicals suspension agent of Tebuconazole and dithiocyano-methane compounding |
| CN115735909A (en) * | 2022-11-07 | 2023-03-07 | 河北威远生物化工有限公司 | Preparation method of stable and synergistic pesticide suspending agent |
| CN115735909B (en) * | 2022-11-07 | 2024-04-26 | 河北威远生物化工有限公司 | Preparation method of stable and synergistic pesticide suspending agent |
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| CN101637176B (en) | 2013-09-18 |
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