CN101633529B - Method for manufacturing ionic enzymatic suspended filler for highly difficult waste water treatment - Google Patents
Method for manufacturing ionic enzymatic suspended filler for highly difficult waste water treatment Download PDFInfo
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- CN101633529B CN101633529B CN2008100408528A CN200810040852A CN101633529B CN 101633529 B CN101633529 B CN 101633529B CN 2008100408528 A CN2008100408528 A CN 2008100408528A CN 200810040852 A CN200810040852 A CN 200810040852A CN 101633529 B CN101633529 B CN 101633529B
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- fiber
- fabric
- supatex fabric
- suspended filler
- filler
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- 239000000945 filler Substances 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 29
- 230000002255 enzymatic effect Effects 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000004065 wastewater treatment Methods 0.000 title claims abstract description 13
- 239000000835 fiber Substances 0.000 claims abstract description 98
- 239000004744 fabric Substances 0.000 claims abstract description 85
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 6
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 5
- -1 polyethylene Polymers 0.000 claims description 17
- 244000005700 microbiome Species 0.000 claims description 14
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 238000001467 acupuncture Methods 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 9
- 229920002717 polyvinylpyridine Polymers 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 238000009736 wetting Methods 0.000 claims description 9
- 239000004743 Polypropylene Substances 0.000 claims description 8
- 230000004927 fusion Effects 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000009775 high-speed stirring Methods 0.000 claims description 8
- 238000002074 melt spinning Methods 0.000 claims description 8
- 229920001155 polypropylene Polymers 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 229920005594 polymer fiber Polymers 0.000 claims description 3
- 230000000813 microbial effect Effects 0.000 abstract description 4
- 238000002844 melting Methods 0.000 abstract 2
- 230000008018 melting Effects 0.000 abstract 2
- 230000007227 biological adhesion Effects 0.000 abstract 1
- 238000009998 heat setting Methods 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 238000009987 spinning Methods 0.000 abstract 1
- 239000010865 sewage Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000002957 persistent organic pollutant Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Landscapes
- Biological Treatment Of Waste Water (AREA)
Abstract
The invention relates to a method for manufacturing an ionic enzymatic suspended filler for highly difficult waste water treatment, which belongs to the technical field of waste water treatment. The ionic enzymatic suspended filler is manufactured by processes of fiber spinning, needling, fluffing, heat setting and the like. The ionic enzymatic suspended filler is made from a fabric consisting of first fibers of polyolefin resin and second fibers of the polyolefin resin with a melting temperature lower than that of the first fibers, and a non-woven fabric as an underlayer; the fabric is connected to the non-woven fabric by a needling method; and the first fibers are mutually adhered, and are adhered to the non-woven fabric by melting the second fibers. The method has the advantage that: the suspended filler obtained by the method has the characteristics of large specific surface area, good mechanical strength, strong tolerance, good biological adhesion performance, easy membrane hanging, promotion of microbial growth, easy filling and the like.
Description
Technical field
The present invention relates to technical field of sewage, particularly a kind of method of manufacture that is applied to the ionic enzymatic suspended filler of high-leveled and difficult wastewater treatment.
Background technology
In the sewage purification treatment technology, biomembrance process is a kind of common treatment process, and is good to being rich in organic high-leveled and difficult water treatment effect, is widely used in the processing of municipal effluent and high-concentration organic industrial waste water.Biomembrance process is meant in effluent stream the method that surface growth has biomembranous immobilization carrier is set through the place that its principle is that effluent stream is utilized the organic pollutant in the biological oxidation degradation of sewage when microbial film.The essence of this treatment process is to make microfaunas such as mikrobe and protozoon, metazoan attached to growing on filler or other carriers, and forms membranaceous biological sludge---microbial film above that.Sewage is with after microbial film contacts, and the organic pollutant in the sewage by the picked-up of the Institute of Micro-biology on the microbial film, is purified sewage as nutritive substance.
Filler is as biomembranous main carrier, and the quality of its performance directly has influence on the effect of WWT.The filler of using in the existing WWT generally can only play simple carrier about, how much absorption mikrobe and microfauna depends on microorganism concn and the microfauna concentration in the sewage fully on the filler.Microorganism concn is all lower in multiple high-leveled and difficult waste water, and its breeding speed of growth is slow, can the serious effect that limits WWT.In addition, filler itself is generally not charged, only leans on the adsorption of the negative charge on mikrobe surface, and the affinity of filling surface and mikrobe is limited, and biomembranous absorption sedimentation velocity is slower, also can limit the speed and the effect of sewage purification.
Summary of the invention
The method of manufacture that the purpose of this invention is to provide the ionic enzymatic suspended filler that is applied to high-leveled and difficult wastewater treatment efficiently solves that biofilm packing surface adsorption mikrobe speed of the prior art is slow, the problems such as affinity difference of filling surface and mikrobe.
The present invention relates to a kind of method of manufacture that is applied to the ionic enzymatic suspended filler of high-leveled and difficult wastewater treatment, it is characterized in that, comprise the steps:
1) in 10000 parts of (weight part) polyolefin resin section; The wetting ability superpolymer polyethylene alcohol or the SEPIGEL 305 that add 500-4500 part; Add the polyvinylpyridine salt of 300-2000 part, the microorganism growth promotor of adding 5-500 part; Mix the back high-speed stirring, obtain first fiber behind the melt-spinning;
2) with the ES fiber as second fiber, get first fiber and become fabric with second fibrage, wherein first fiber and second fibre weight ratio are 0.667: 1～4: 1;
3) get polypropylene non-woven fabric as supatex fabric, as bottom, it is alternately laminated that fabric is positioned over supatex fabric, with rope fabric and supatex fabric is fixed together, and obtains the duplexer of fabric and supatex fabric with supatex fabric.
4) use the fluffing pin from fabric one side acupuncture duplexer, the fluffing of first fiber is set on the surface of supatex fabric.
5) do not have nappy duplexer with the heating of 100-170 ℃ temperature, fusion second fiber makes between first fiber bondingly mutually, and the fiber of winning is bonded on the supatex fabric.
Described filler is a kind of ionic enzymatic polymer fiber filler.Described wetting ability superpolymer polyethylene alcohol can replace with SEPIGEL 305.Described wetting ability superpolymer polyethylene alcohol can use the mixture of the pure and mild SEPIGEL 305 of wetting ability superpolymer polyethylene to replace.The rugosity of described first fiber was 40～400 dawn.The rugosity of described second fiber was 3～20 dawn.The weight of the supatex fabric of described bottom is 20-600g/m2.
The invention has the advantages that: the principle that can utilize different electric charge to inhale mutually effectively improves the affinity of filling surface and mikrobe, accelerates the mikrobe rate of adsorption of filling surface; Filling surface is rich in the ionic enzyme, has the enzymatic effect, and effectively catalysis microorganism growth and reproduction speed have accelerated to improve the speed of microorganism concn, have effectively improved the effect of WWT.
Embodiment
The present invention relates to a kind of method of manufacture that is applied to the ionic enzymatic suspended filler of high-leveled and difficult wastewater treatment, it is characterized in that, comprise the steps:
1) in 10000 parts of (weight part) polyolefin resin section; The wetting ability superpolymer polyethylene alcohol or the SEPIGEL 305 that add 500-4500 part; Add the polyvinylpyridine salt of 300-2000 part, the microorganism growth promotor of adding 5-500 part; Mix the back high-speed stirring, obtain first fiber behind the melt-spinning;
2) with the ES fiber as second fiber, get first fiber and become fabric with second fibrage, wherein first fiber and second fibre weight ratio are 0.667: 1～4: 1;
3) get polypropylene non-woven fabric as supatex fabric, as bottom, it is alternately laminated that fabric is positioned over supatex fabric, with rope fabric and supatex fabric is fixed together, and obtains the duplexer of fabric and supatex fabric with supatex fabric.
4) use the fluffing pin from fabric one side acupuncture duplexer, the fluffing of first fiber is set on the surface of supatex fabric.
5) do not have nappy duplexer with the heating of 130 ℃ temperature, fusion second fiber makes between first fiber bondingly mutually, and the fiber of winning is bonded on the supatex fabric.
Described filler is a kind of ionic enzymatic polymer fiber filler.Described wetting ability superpolymer polyethylene alcohol can replace with SEPIGEL 305.Described wetting ability superpolymer polyethylene alcohol can use the mixture of the pure and mild SEPIGEL 305 of wetting ability superpolymer polyethylene to replace.The rugosity of described first fiber was 40～400 dawn.The rugosity of described second fiber was 3～20 dawn.The weight of the supatex fabric of described bottom is 20-600g/m2.
Add polyvinylpyridine salt and microorganism growth promotor in first fiber that the preparation filler that the present invention proposes is used, make carrier surface have positive charge and promote microorganism growth simultaneously.
The melt temperature of second fiber is hanged down about 10～100 ℃ than the melt temperature of first fiber, and the temperature difference of melt temperature is best 30～80 ℃ of effects.
If the weight ratio of first fiber and second fiber is lower than 0.667: 1; Then the shape-holding property of carrier can, physical strength is not good; If the weight ratio of first fiber and second fiber is higher than 4: 1, each other bonding insufficient of first fiber then, the physical strength of carrier is not good.
The rugosity of first fiber was 40～400 dawn, and 50～200 dawn preferably, less than is during 40 dawn, the shape-holding property of carrier can, physical strength is not good, when surpassing for 400 dawn, the surface-area of carrier is too small.The rugosity of second fiber is 3～20 dawn preferably, and in the time of outside this scope, first fiber can not obtain bonding fully each other, and the physical strength of carrier is not good.
Under weight 20g/m as the supatex fabric of bottom
2The time, then the destruction during acupuncture excessive, can not suppress to shrink, surpass 600g/m as the weight of the supatex fabric of bottom
2The time, then circular degree of finish is not good, be difficult to the processing that is shaped, and cost is high.
The method of manufacture of supatex fabric is restriction not, but the most handy mull technique is made.The weight per unit area of supatex fabric is 100～3000g/m
2, 200～1000g/m
2Effect is best.
The filler that produces according to the inventive method can be used for processing the goods of different shape, generally selects tabular or tubulose.
Embodiment 1
In melt temperature is to add 10% Z 150PH in 160 ℃ the polypropylene chip, adds 5% polyvinylpyridine salt, adds 1% microorganism growth accelerant C
0 2+, after high-speed stirring was mixed, melt-spinning obtained first fiber at 100 dawn.
Using first fiber and melt temperature is that 120 ℃ 10 dawn ES fibers (second fiber) make fabric, wherein the usage rate 5: 5 of first fiber and second fiber; With fabric that obtains and weight is 50g/m
2Supatex fabric as bottom is range upon range of, the repeated puncture method connects, and obtains the duplexer of fabric and supatex fabric; From the resulting sandwich of fabric one side acupuncture, the fluffing of first fiber is set on the surface of supatex fabric with the fluffing pin; Heating is provided with nappy duplexer under 140 ℃ temperature, and fusion second fiber makes first fiber bonding each other, and is bonded on the supatex fabric therefrom.
After handling through above-mentioned each step ground, this kind filler can be used for processing en plaque.
Embodiment 2
In melt temperature is to add 5% SEPIGEL 305 in 170 ℃ the polypropylene chip, adds 3% polyvinylpyridine salt, adds 0.5% microorganism growth accelerant C
0 2+, after high-speed stirring was mixed, melt-spinning obtained first fiber at 120 dawn.
Using first fiber and melt temperature is that 110 ℃ 5 dawn ES fibers (second fiber) make fabric, wherein the usage rate 4: 6 of first fiber and second fiber; With fabric that obtains and weight is 100g/m
2Supatex fabric as bottom is range upon range of, the repeated puncture method connects, and obtains the duplexer of fabric and supatex fabric; From the resulting sandwich of fabric one side acupuncture, the fluffing of first fiber is set on the surface of supatex fabric with the fluffing pin; Heating is provided with nappy duplexer under 150 ℃ temperature, and fusion second fiber makes first fiber bonding each other, and is bonded on the supatex fabric therefrom.
After handling through above-mentioned each step ground, this kind filler can be used for processing en plaque.
Embodiment 3
In melt temperature is to add 10% SEPIGEL 305 in 165 ℃ the polypropylene chip, adds 5% polyvinylpyridine salt, adds 0.7% microorganism growth accelerant C
0 2+, after high-speed stirring was mixed, melt-spinning obtained first fiber at 80 dawn.
Using first fiber and melt temperature is that 110 ℃ 6 dawn ES fibers (second fiber) make fabric, wherein the usage rate 7: 3 of first fiber and second fiber; With fabric that obtains and weight is 100g/m
2Supatex fabric as bottom is range upon range of, the repeated puncture method connects, and obtains the duplexer of fabric and supatex fabric; From the resulting sandwich of fabric one side acupuncture, the fluffing of first fiber is set on the surface of supatex fabric with the fluffing pin; Heating is provided with nappy duplexer under 145 ℃ temperature, and fusion second fiber makes first fiber bonding each other, and is bonded on the supatex fabric therefrom.
After handling through above-mentioned each step ground, this kind filler can be used for processing tubulose.
Embodiment 4
In melt temperature is to add 7% SEPIGEL 305 in 180 ℃ the polypropylene chip, adds 5% polyvinylpyridine salt, adds 1% microorganism growth accelerant C
0 2+, after high-speed stirring was mixed, melt-spinning obtained first fiber at 100 dawn.
Using first fiber and melt temperature is that 110 ℃ 7 dawn ES fibers (second fiber) make fabric, wherein the usage rate 7: 3 of first fiber and second fiber; With fabric that obtains and weight is 80g/m
2Supatex fabric as bottom is range upon range of, the repeated puncture method connects, and obtains the duplexer of fabric and supatex fabric; From the resulting sandwich of fabric one side acupuncture, the fluffing of first fiber is set on the surface of supatex fabric with the fluffing pin; Heating is provided with nappy duplexer under 160 ℃ temperature, and fusion second fiber makes first fiber bonding each other, and is bonded on the supatex fabric therefrom.
After handling through above-mentioned each step ground, this kind filler can be used for processing en plaque.
Embodiment 5
In melt temperature is to add 5% SEPIGEL 305 in 180 ℃ the polypropylene chip, adds 3% polyvinylpyridine salt, adds 1% microorganism growth accelerant C
0 2+, after high-speed stirring was mixed, melt-spinning obtained first fiber at 120 dawn.
Using first fiber and melt temperature is that 110 ℃ 5 dawn ES fibers (second fiber) make fabric, wherein the usage rate 5: 5 of first fiber and second fiber; With fabric that obtains and weight is 90g/m
2Supatex fabric as bottom is range upon range of, the repeated puncture method connects, and obtains the duplexer of fabric and supatex fabric; From the resulting sandwich of fabric one side acupuncture, the fluffing of first fiber is set on the surface of supatex fabric with the fluffing pin; Heating is provided with nappy duplexer under 160 ℃ temperature, and fusion second fiber makes first fiber bonding each other, and is bonded on the supatex fabric therefrom.
After handling through above-mentioned each step ground, this kind filler can be used for processing tubulose.
Claims (5)
1. be applied to the method for manufacture of the ionic enzymatic suspended filler of high-leveled and difficult wastewater treatment, it is characterized in that, comprise the steps:
1) in the polyolefin resin section of 10000 parts of weight parts; The wetting ability superpolymer polyethylene alcohol or the SEPIGEL 305 that add 500-4500 part; Add the polyvinylpyridine salt of 300-2000 part, the microorganism growth promotor of adding 5-500 part; Mix the back high-speed stirring, obtain first fiber behind the melt-spinning;
2) with the ES fiber as second fiber, get first fiber and become fabric with second fibrage, wherein first fiber and second fibre weight ratio are 0.667: 1～4: 1;
3) get polypropylene non-woven fabric as supatex fabric, as bottom, it is alternately laminated that fabric is positioned over supatex fabric, with rope fabric and supatex fabric is fixed together, and obtains the duplexer of fabric and supatex fabric with supatex fabric;
4) use the fluffing pin from fabric one side acupuncture duplexer, the fluffing of first fiber is set on the surface of supatex fabric;
5) do not have nappy duplexer with the heating of 100-170 ℃ temperature, fusion second fiber makes between first fiber bondingly mutually, and the fiber of winning is bonded on the supatex fabric.
2. the method for manufacture that is applied to the ionic enzymatic suspended filler of high-leveled and difficult wastewater treatment according to claim 1 is characterized in that: described filler is a kind of ionic enzymatic polymer fiber filler.
3. the method for manufacture that is applied to the ionic enzymatic suspended filler of high-leveled and difficult wastewater treatment according to claim 1 is characterized in that: the rugosity of described first fiber was 40～400 dawn.
4. the method for manufacture that is applied to the ionic enzymatic suspended filler of high-leveled and difficult wastewater treatment according to claim 1 is characterized in that: the rugosity of described second fiber was 3～20 dawn.
5. the method for manufacture that is applied to the ionic enzymatic suspended filler of high-leveled and difficult wastewater treatment according to claim 1 is characterized in that: the weight of the supatex fabric of described bottom is 20-600g/m
2
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100408528A CN101633529B (en) | 2008-07-22 | 2008-07-22 | Method for manufacturing ionic enzymatic suspended filler for highly difficult waste water treatment |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100408528A CN101633529B (en) | 2008-07-22 | 2008-07-22 | Method for manufacturing ionic enzymatic suspended filler for highly difficult waste water treatment |
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| CN101633529A CN101633529A (en) | 2010-01-27 |
| CN101633529B true CN101633529B (en) | 2012-05-02 |
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| CN2008100408528A Active CN101633529B (en) | 2008-07-22 | 2008-07-22 | Method for manufacturing ionic enzymatic suspended filler for highly difficult waste water treatment |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101973678A (en) * | 2010-11-03 | 2011-02-16 | 上海泓济环保工程有限公司 | Bioaugmentation treatment technology of high ammonia nitrogen wastewater |
| CN103145247A (en) * | 2013-04-02 | 2013-06-12 | 上海泓济环保工程有限公司 | Composite HBF (Honess Hybrid Biological&Fixed film Technology) module reactor and sewage treatment process |
| CN103896396B (en) * | 2013-04-15 | 2016-03-30 | 上海泓济环保工程有限公司 | A kind of upflowing coupling hydrolysis acidification pond |
| CN105819574B (en) * | 2016-05-11 | 2018-08-24 | 上海泓济环保科技股份有限公司 | The biochemical equipment and its processing method of integrated processing exhaust gas and sewage |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1187469A (en) * | 1997-01-07 | 1998-07-15 | 重庆建筑大学 | Method of producing granular enzymetic filling for treating waste water |
| CN1597564A (en) * | 2004-08-26 | 2005-03-23 | 娄性义 | Technology and special equipment for preparing regenerated water using sewage |
-
2008
- 2008-07-22 CN CN2008100408528A patent/CN101633529B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1187469A (en) * | 1997-01-07 | 1998-07-15 | 重庆建筑大学 | Method of producing granular enzymetic filling for treating waste water |
| CN1597564A (en) * | 2004-08-26 | 2005-03-23 | 娄性义 | Technology and special equipment for preparing regenerated water using sewage |
Non-Patent Citations (2)
| Title |
|---|
| JP特公平6-32824B2 1994.05.02 |
| 龙腾锐等.水处理酶促生物填料的生产性试验研制.《重庆建筑大学学报》.2000,第22卷(第3期), * |
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