CN101628798A - Method for preparing vitrified micro bubbles and polystyrene particle composite thermal insulation mortar by modification of foaming agent - Google Patents
Method for preparing vitrified micro bubbles and polystyrene particle composite thermal insulation mortar by modification of foaming agent Download PDFInfo
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- CN101628798A CN101628798A CN200910115906A CN200910115906A CN101628798A CN 101628798 A CN101628798 A CN 101628798A CN 200910115906 A CN200910115906 A CN 200910115906A CN 200910115906 A CN200910115906 A CN 200910115906A CN 101628798 A CN101628798 A CN 101628798A
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- thermal insulation
- foaming agent
- composite thermal
- insulation mortar
- glass bead
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/0076—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials characterised by the grain distribution
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention relates to a preparation method for composite thermal insulation mortar. The method comprises the following steps: cement, fly ash, redispersible latex powder, polypropylene fiber, animal protein foaming agent and lauryl sodium sulfate foaming agent are poured into a high speed mixer to be evenly mixed, and then the mixture is added with vitrified micro bubbles and polystyrene particles to be evenly mixed to obtain the composite thermal insulation mortar. The invention has the advantages that the lauryl sodium sulfate foaming agent modified by using the animal protein foaming agent is rapidly dry-mixed and stirred to obtain the composite thermal insulation solid mortar, and the rapid production is favorable for saving energy and reducing consumption; the composite thermal insulation mortar during the construction is easy to uniformly stir, is not easy to layer, is long in opening time and also has the advantages of easy sale by bulk, easy coating and easy scraping, heat preservation, energy saving, simple operation and convenient construction; and the coefficient of heat conductivity is 0.055-0.067 W/m.k..
Description
Technical field
The present invention relates to a kind of preparation method of composite thermal insulation mortar, mainly is the method that modification of foaming agent prepares glass bead and polystyrene particle composite thermal insulation mortar.
Background technology
The consumption of composite thermal insulation mortar is increasing, and it is low to use the composite thermal insulation mortar of whipping agent to have a cost, and thermal and insulating performance is good, and the ultimate compression strength that has good workability and pressure are cut characteristics such as cohesive strength height.Though the whipping agent usage quantity is very little, whipping agent is selected the performance impact of preparation or composite thermal insulation mortar big.
Summary of the invention
The object of the present invention is to provide a kind of modification of foaming agent to prepare the method for glass bead and polystyrene particle composite thermal insulation mortar.
The present invention adopts the mixed and modified technology of animal protein foaming agent and sodium lauryl sulphate whipping agent, has obtained the effect that is better than the sodium lauryl sulphate whipping agent.
Technical scheme of the present invention:
Modification of foaming agent prepares the method for glass bead and polystyrene particle composite thermal insulation mortar; follow these steps to the operation: with cement, flyash, redispersable latex powder, polypropylene fibre, whipping agent pour into mix in the high-speed mixer after; add glass bead again and granules of polystyrene is mixed into homogeneous material, obtain composite thermal insulation mortar.
The preparation method of animal protein foaming agent is as follows:
(1) liquefaction: with the bone of Powdered animal or skin and hair as the source material of animal proteinum and calcium hydroxide, sodium hydroxide by 1: the part by weight of 1-1.5: 0.2-0.4 mixes, the 3-6 water doubly that adds the bone of Powdered animal or skin and hair weight again is as solvent, stir and form the heavy-gravity mashed prod, standby;
(2) hydrolysis: mashed prod is joined in the container that has agitator arm, stir, load onto condensing tube condensation, be warming up to 100 ℃; React and stopped in 10 hours, the cooling suction filtration is collected filtrate, uses the hydrochloric acid neutralization filtrate to pH value 7.0, adding thermal distillation, to be concentrated into density be the 1.1-1.25 grams per milliliter, adds Sodium Benzoate sanitas spraying drying by the weight percent 2% of concentrated solution and obtain animal protein foaming agent.
Modification of foaming agent prepares the method for glass bead and polystyrene particle composite thermal insulation mortar, is cement 30-65 part of 42.5 grades with the model of following parts by weight; Flyash 10-15 part; Diameter is glass bead 30-60 part of 0.5-2mm; Diameter is granules of polystyrene 10-20 part of 3-5mm; Redispersable latex powder 1.5-3 part; Length is polypropylene fibre 0.1-0.2 part of 5-15 millimeter; Animal proteinum is sent out whipping agent 0.1-0.2 part; The raw material that sodium lauryl sulphate whipping agent 0.1-0.2 part is formed; it is characterized in that following these steps to the operation: with cement, flyash, redispersable latex powder, polypropylene fibre, whipping agent pour into mix in the high-speed mixer after; add glass bead again and granules of polystyrene is mixed into homogeneous material, obtain composite thermal insulation mortar.
Using method: get modification of foaming agent and prepare glass bead and polystyrene particle composite thermal insulation mortar and add suitable quantity of water and stir and form slurry, directly smear, promptly form the excellent insulating thermofin after the drying in basal plane.
The redispersable latex powder that existing market is mainly used has: vinyl acetate and ethylene copolymer rubber powder (Vac/E), ethene and vinylchlorid and month silicic acid vinyl acetate terpolymer rubber powder (E/Vc/VL), vinyl acetate and ethene and higher fatty acid vinyl acetate terpolymer rubber powder (Vac/E/VeoVa), vinyl acetate and higher fatty acid vinyl acetate copolymerization rubber powder (Vac/VeoVa), acrylate and styrene copolymerized rubber powder (A/S), vinyl acetate and acrylate and higher fatty acid vinyl acetate terpolymer rubber powder (Vac/A/VeoVa), vinyl acetate homopolymerization rubber powder (PVac), vinylbenzene and butadiene copolymer rubber powder (SBR).
Redispersable latex powder belongs to conventional composition in the composite thermal insulation mortar field, its wide material sources, and kind is numerous, and various redispersable latex powders mostly have good sticking and performance, thereby as additive adding composite thermal insulation mortar similar effect are arranged all.
Granules of polystyrene also belongs to conventional composition in the composite thermal insulation mortar field, have a lot of suppliers that granules of polystyrene can be provided.Can provide such as in the Zhengzhou day building energy conservation company limited.
Glass bead also belongs to conventional composition in the composite thermal insulation mortar field, have a lot of suppliers that glass bead can be provided.Can provide such as a Chifeng Mount Everest lagging material company limited and the strange letter of an Xinyang gold novel environment friendly building materials company limited.
Animal proteinum is sent out the whipping agent wide material sources, also can produce or consigned processing by method provided by the invention.
Effect data of the present invention has:
| Group | ??A | ??B | ?C |
| Technical scheme and consumption | Animal proteinum is sent out whipping agent and sodium lauryl sulphate whipping agent each half and is used with, amounts to 0.2% | Sodium lauryl sulphate whipping agent 0.2% | Do not add whipping agent 0% |
| 50 kilograms material adds the open hour that 30 kg of water stir the permission that forms slurry | 4 hours | 1 hour | The easy layering of each component, constructional difficulties |
The open hour of the permission of slurry are meant and need in time slurry be directly smeared in basal plane at the appointed time, promptly form the time of excellent insulating thermofin after the drying.Long more helping more of the open hour that allow constructs.
| Performance | ??A | ??B | ??C |
| Dry density kg/m 3 | ??250-280 | ??320-350 | ??350 |
| Thermal conductivity W/m.k | ??0.055-0.067 | ??0.055-0.067 | ??0.081-0.091 |
| Ultimate compression strength KPa | ??450-790 | ??450-790 | ??270-410 |
| Cohesive strength KPa | ??200-330 | ??160-180 | ??35-61 |
| Volumetric shrinkage % | ??5-10 | ??5-10 | ??10-20 |
| Hydrophobic rate % | ??85-95 | ??85-95 | ??79-89 |
Advantage of the present invention: use the sodium lauryl sulphate whipping agent of sending out modification of foaming agent through animal proteinum to mix fast and obtain the powdery composite insulation mortar, produce fast and help save energy, reduce consuming.The composite thermal insulation mortar impact of performance of gained of the present invention is good, and particularly cohesive strength also is better than traditional sodium lauryl sulphate whipping agent, makes that quality product of the present invention is better.
Composite thermal insulation mortar of the present invention has easily in construction process and stirs, and mortar is difficult for layering, and the open hour are long, easily the advantage of criticizing, easily being coated with, easily scraping.Thermal conductivity has good heat preservation energy-saving effect in the scope of 0.055-0.067W/m.k, and simple to operate, easy construction.
Specific embodiment
Embodiment 1, modification of foaming agent prepare the method for glass bead and polystyrene particle composite thermal insulation mortar; follow these steps to the operation: with cement, flyash, redispersable latex powder, polypropylene fibre, whipping agent pour into mix in the high-speed mixer after; add glass bead again and granules of polystyrene is mixed into homogeneous material, obtain composite thermal insulation mortar.
The preparation method of embodiment 2, animal protein foaming agent is as follows:
(1) liquefaction: the bone of Powdered animal or the skin and hair source material as animal proteinum is mixed by 1: 1: 0.2 part by weight with calcium hydroxide, sodium hydroxide, 3 times the water that adds the bone of Powdered animal or skin and hair weight again is as solvent, stir and form the heavy-gravity mashed prod, standby;
(2) hydrolysis: mashed prod is joined in the container that has agitator arm, stir, load onto condensing tube condensation, be warming up to 100 ℃; React and stopped in 10 hours, the cooling suction filtration is collected filtrate, and to pH value 7.0, adding thermal distillation, to be concentrated into density be 1.1 grams per milliliters with the hydrochloric acid neutralization filtrate, obtains animal protein foaming agent by the weight percent 2% adding Sodium Benzoate sanitas spraying drying of concentrated solution.
The preparation method of embodiment 3, animal protein foaming agent is as follows:
(1) liquefaction: the bone of Powdered animal or the skin and hair source material as animal proteinum is mixed by 1: 1.5: 0.4 part by weight with calcium hydroxide, sodium hydroxide, 6 times the water that adds the bone of Powdered animal or skin and hair weight again is as solvent, stir and form the heavy-gravity mashed prod, standby;
(2) hydrolysis: mashed prod is joined in the container that has agitator arm, stir, load onto condensing tube condensation, be warming up to 100 ℃; React and stopped in 10 hours, the cooling suction filtration is collected filtrate, uses the hydrochloric acid neutralization filtrate to pH value 7.0, adding thermal distillation, to be concentrated into density be 1.25 grams per milliliters, adds Sodium Benzoate sanitas spraying drying by the weight percent 2% of concentrated solution and obtain animal protein foaming agent.
The preparation method of embodiment 4, animal protein foaming agent is as follows:
(1) liquefaction: with the bone of Powdered animal or skin and hair as the source material of animal proteinum and calcium hydroxide, sodium hydroxide by 1: 1-1.3: 0.3 part by weight mixes, 5 times the water that adds the bone of Powdered animal or skin and hair weight again is as solvent, stir and form the heavy-gravity mashed prod, standby;
(2) hydrolysis: mashed prod is joined in the container that has agitator arm, stir, load onto condensing tube condensation, be warming up to 100 ℃; React and stopped in 10 hours, the cooling suction filtration is collected filtrate, uses the hydrochloric acid neutralization filtrate to pH value 7.0, adding thermal distillation, to be concentrated into density be 1.20 grams per milliliters, adds Sodium Benzoate sanitas spraying drying by the weight percent 2% of concentrated solution and obtain animal protein foaming agent.
Embodiment 5, modification of foaming agent prepare the method for glass bead and polystyrene particle composite thermal insulation mortar, are 30 parts of the cement of 42.5 grades with the model of following parts by weight; 10 parts in flyash; Diameter is 30 parts of the glass beads of 0.5mm; Diameter is 10 parts of the granules of polystyrene of 3mm; 1.5 parts of redispersable latex powders; Length is 5 millimeters 0.1 part of polypropylene fibre; Animal proteinum is sent out 0.1 part of whipping agent; The raw material of 0.1 part of composition of sodium lauryl sulphate whipping agent; follow these steps to the operation: with cement, flyash, redispersable latex powder, polypropylene fibre, whipping agent pour into mix in the high-speed mixer after; add glass bead again and granules of polystyrene is mixed into homogeneous material, obtain composite thermal insulation mortar.All the other are with embodiment 2.
Embodiment 6, modification of foaming agent prepare the method for glass bead and polystyrene particle composite thermal insulation mortar, are 65 parts of the cement of 42.5 grades with the model of following parts by weight; 15 parts in flyash; Diameter is 60 parts of the glass beads of 2mm; Diameter is 20 parts of the granules of polystyrene of 5mm; 3 parts of redispersable latex powders; Length is 15 millimeters 0.2 part of polypropylene fibre; Animal proteinum is sent out 0.2 part of whipping agent; The raw material of 0.2 part of composition of sodium lauryl sulphate whipping agent; follow these steps to the operation: with cement, flyash, redispersable latex powder, polypropylene fibre, whipping agent pour into mix in the high-speed mixer after; add glass bead again and granules of polystyrene is mixed into homogeneous material, obtain composite thermal insulation mortar.All the other are with embodiment 3.
Embodiment 7, modification of foaming agent prepare the method for glass bead and polystyrene particle composite thermal insulation mortar, are 45 parts of the cement of 42.5 grades with the model of following parts by weight; 12 parts in flyash; Diameter is 40 parts of the glass beads of 1mm; Diameter is 15 parts of the granules of polystyrene of 4mm; 2 parts of redispersable latex powders; Length is 8 millimeters 0.15 part of polypropylene fibre; Animal proteinum is sent out 0.15 part of whipping agent; The raw material of 0.15 part of composition of sodium lauryl sulphate whipping agent; follow these steps to the operation: with cement, flyash, redispersable latex powder, polypropylene fibre, whipping agent pour into mix in the high-speed mixer after; add glass bead again and granules of polystyrene is mixed into homogeneous material, obtain composite thermal insulation mortar.All the other are with embodiment 4.
The redispersable latex powder that adopts among the above embodiment can be vinyl acetate and ethylene copolymer rubber powder (Vac/E), ethene and vinylchlorid and month silicic acid vinyl acetate terpolymer rubber powder (E/Vc/VL), vinyl acetate and ethene and higher fatty acid vinyl acetate terpolymer rubber powder (Vac/E/VeoVa), vinyl acetate and higher fatty acid vinyl acetate copolymerization rubber powder (Vac/VeoVa), acrylate and styrene copolymerized rubber powder (A/S), vinyl acetate and acrylate and higher fatty acid vinyl acetate terpolymer rubber powder (Vac/A/VeoVa), vinyl acetate homopolymerization rubber powder (PVac), in vinylbenzene and the butadiene copolymer rubber powder (SBR) any one.
Claims (3)
1, modification of foaming agent prepares the method for glass bead and polystyrene particle composite thermal insulation mortar; it is characterized in that: with cement, flyash, redispersable latex powder, polypropylene fibre, whipping agent pour into mix in the high-speed mixer after; add glass bead again and granules of polystyrene is mixed into homogeneous material, obtain composite thermal insulation mortar.
2, modification of foaming agent prepares the method for glass bead and polystyrene particle composite thermal insulation mortar, is cement 30-65 part of 42.5 grades with the model of following parts by weight; Flyash 10-15 part; Diameter is glass bead 30-60 part of 0.5-2mm; Diameter is granules of polystyrene 10-20 part of 3-5mm; Redispersable latex powder 1.5-3 part; Length is polypropylene fibre 0.1-0.2 part of 5-15 millimeter; Animal proteinum is sent out whipping agent 0.1-0.2 part; The raw material that sodium lauryl sulphate whipping agent 0.1-0.2 part is formed; it is characterized in that following these steps to the operation: with cement, flyash, redispersable latex powder, polypropylene fibre, whipping agent pour into mix in the high-speed mixer after; add glass bead again and granules of polystyrene is mixed into homogeneous material, obtain composite thermal insulation mortar.
3, modification of foaming agent according to claim 2 prepares the method for glass bead and polystyrene particle composite thermal insulation mortar, it is characterized in that: the preparation method of animal protein foaming agent is as follows:
(1) liquefaction: with the bone of Powdered animal or skin and hair as the source material of animal proteinum and calcium hydroxide, sodium hydroxide by 1: the part by weight of 1-1.5: 0.2-0.4 mixes, the 3-6 water doubly that adds the bone of Powdered animal or skin and hair weight again is as solvent, stir and form the heavy-gravity mashed prod, standby;
(2) hydrolysis: mashed prod is joined in the container that has agitator arm, stir, load onto condensing tube condensation, be warming up to 100 ℃; React and stopped in 10 hours, the cooling suction filtration is collected filtrate, uses the hydrochloric acid neutralization filtrate to pH value 7.0, adding thermal distillation, to be concentrated into density be the 1.1-1.25 grams per milliliter, adds Sodium Benzoate sanitas spraying drying by the weight percent 2% of concentrated solution and obtain animal protein foaming agent.
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Cited By (20)
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| CN102219452A (en) * | 2011-04-13 | 2011-10-19 | 河北建筑工程学院 | Pumice straw lightweight aggregate concrete and preparation method thereof |
| CN102276202A (en) * | 2011-06-02 | 2011-12-14 | 王建国 | Three-component thermal-insulation, fire-proof and sound-insulation material and preparation method thereof |
| CN102336553A (en) * | 2010-07-26 | 2012-02-01 | 贵州中建建筑科研设计院有限公司 | Preparation method of composite insulating mortar with red mud as a water-retaining thickener |
| CN102491663A (en) * | 2011-12-20 | 2012-06-13 | 河北科技大学 | Composite polyphenyl particle surfactant |
| CN102503523A (en) * | 2011-10-08 | 2012-06-20 | 王敬尊 | Method for manufacturing lightweight heat-insulating material from coal gangue and nanoscale inorganic silicone |
| CN102746019A (en) * | 2011-07-19 | 2012-10-24 | 江苏尼高科技有限公司 | High performance polymer foaming cement thermal insulation material and preparation method thereof |
| CN102795878A (en) * | 2012-08-03 | 2012-11-28 | 中国科学院深圳先进技术研究院 | Light heat-insulation foamed cement and preparation method thereof |
| CN102850024A (en) * | 2012-09-28 | 2013-01-02 | 江苏尼高科技有限公司 | Fireproof foaming compound insulation board and preparation method thereof |
| CN102910934A (en) * | 2012-10-19 | 2013-02-06 | 济南大学 | Light and flexible foaming cement insulation board and preparation method thereof |
| CN103011712A (en) * | 2012-12-25 | 2013-04-03 | 湖南省中政建材有限公司 | Vitrified micro bubble thermal mortar aggregate and preparation method thereof |
| CN103626448A (en) * | 2013-11-29 | 2014-03-12 | 中建四局第六建筑工程有限公司 | Thermal insulation mortar prepared from solid waste |
| CN103641407A (en) * | 2013-11-08 | 2014-03-19 | 许炜 | Preparation of insulation mortar by solid waste |
| CN105152583A (en) * | 2015-07-03 | 2015-12-16 | 枞阳县天筑新型建筑材料有限公司 | Mothproof and synergistic thermal insulation mortar and preparation method thereof |
| CN105198298A (en) * | 2015-10-13 | 2015-12-30 | 安徽芜湖飞琪水泥制品有限公司 | Foam cement pile material composition and preparation method thereof |
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| CN105481283A (en) * | 2014-10-11 | 2016-04-13 | 王路明 | Composite protein foaming agent for foamed concrete, preparation method for composite protein foaming agent and use of composite protein foaming agent |
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| CN102219452A (en) * | 2011-04-13 | 2011-10-19 | 河北建筑工程学院 | Pumice straw lightweight aggregate concrete and preparation method thereof |
| CN102276202A (en) * | 2011-06-02 | 2011-12-14 | 王建国 | Three-component thermal-insulation, fire-proof and sound-insulation material and preparation method thereof |
| CN102276202B (en) * | 2011-06-02 | 2012-12-12 | 王建国 | Three-component thermal-insulation, fire-proof and sound-insulation material and preparation method thereof |
| CN102746019A (en) * | 2011-07-19 | 2012-10-24 | 江苏尼高科技有限公司 | High performance polymer foaming cement thermal insulation material and preparation method thereof |
| CN102503523A (en) * | 2011-10-08 | 2012-06-20 | 王敬尊 | Method for manufacturing lightweight heat-insulating material from coal gangue and nanoscale inorganic silicone |
| CN102491663B (en) * | 2011-12-20 | 2015-07-29 | 河北科技大学 | A kind of composite polyphenyl particle surfactant |
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| CN102795878A (en) * | 2012-08-03 | 2012-11-28 | 中国科学院深圳先进技术研究院 | Light heat-insulation foamed cement and preparation method thereof |
| CN102795878B (en) * | 2012-08-03 | 2014-05-21 | 中国科学院深圳先进技术研究院 | Light heat-insulation foamed cement and preparation method thereof |
| CN102850024A (en) * | 2012-09-28 | 2013-01-02 | 江苏尼高科技有限公司 | Fireproof foaming compound insulation board and preparation method thereof |
| CN102910934A (en) * | 2012-10-19 | 2013-02-06 | 济南大学 | Light and flexible foaming cement insulation board and preparation method thereof |
| CN103011712A (en) * | 2012-12-25 | 2013-04-03 | 湖南省中政建材有限公司 | Vitrified micro bubble thermal mortar aggregate and preparation method thereof |
| CN103011712B (en) * | 2012-12-25 | 2014-06-11 | 湖南省中政建材有限公司 | Vitrified micro bubble thermal mortar aggregate and preparation method thereof |
| CN103641407A (en) * | 2013-11-08 | 2014-03-19 | 许炜 | Preparation of insulation mortar by solid waste |
| CN103626448A (en) * | 2013-11-29 | 2014-03-12 | 中建四局第六建筑工程有限公司 | Thermal insulation mortar prepared from solid waste |
| CN105481283A (en) * | 2014-10-11 | 2016-04-13 | 王路明 | Composite protein foaming agent for foamed concrete, preparation method for composite protein foaming agent and use of composite protein foaming agent |
| WO2017004154A1 (en) * | 2015-06-29 | 2017-01-05 | Allied Foam Tech Corp. | Fiber containing aqueous foam composite, the process and use |
| CN105152583A (en) * | 2015-07-03 | 2015-12-16 | 枞阳县天筑新型建筑材料有限公司 | Mothproof and synergistic thermal insulation mortar and preparation method thereof |
| CN105198298A (en) * | 2015-10-13 | 2015-12-30 | 安徽芜湖飞琪水泥制品有限公司 | Foam cement pile material composition and preparation method thereof |
| CN105198366A (en) * | 2015-10-13 | 2015-12-30 | 安徽芜湖飞琪水泥制品有限公司 | Air-entraining cement column material composition and preparation method of air-entraining cement column |
| CN105777190A (en) * | 2016-03-25 | 2016-07-20 | 姚勇 | Foam concrete |
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| CN107740593B (en) * | 2017-09-06 | 2020-05-15 | 江苏尼高科技有限公司 | External thermal insulation repair reinforcing method for divided bin type external wall |
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