CN101620492A - Preparation method for touch screen - Google Patents
Preparation method for touch screen Download PDFInfo
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- CN101620492A CN101620492A CN200810068319A CN200810068319A CN101620492A CN 101620492 A CN101620492 A CN 101620492A CN 200810068319 A CN200810068319 A CN 200810068319A CN 200810068319 A CN200810068319 A CN 200810068319A CN 101620492 A CN101620492 A CN 101620492A
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Abstract
The invention discloses a preparation method for a touch screen, which comprises the following steps: providing a first matrix; forming a carbon nanotube composite material layer on the surface of the first matrix to obtain a first battery lead plate; repeating the steps to prepare a second battery lead plate; and encapsulating the first battery lead plate and the second battery lead plate to form the touch screen.
Description
Technical field
The present invention relates to a kind of preparation method of touch-screen, relate in particular to a kind of preparation method of the touch-screen based on carbon nano-tube.
Background technology
In recent years, be accompanied by the high performance and the diversified development of various electronic equipments such as mobile phone and touch navigation system, the electronic equipment that the touch-screen of light transmission is installed in the front of display elements such as liquid crystal progressively increases.The user of such electronic equipment is by touch-screen, on one side the displaying contents of the display element that is positioned at the touch-screen back side is carried out visual confirmation, utilize modes such as finger or pen to push touch-screen on one side and operate.Thus, various functions that can operating electronic equipment.
Different according to the principle of work of touch-screen and transmission medium, existing touch-screen is divided into four types usually, is respectively resistance-type, capacitor induction type, infrared-type and surface acoustic wave type.Wherein being most widely used of resistive touch screen sees also document " Production of Transparent ConductiveFilms with Inserted SiO
2Anchor Layer, and Application to a Resistive TouchPanel " Kazuhiro Noda, Kohtaro Tanimura.Electronics and Communications inJapan, Part 2, Vol.84, P39-45 (2001).
Existing resistive touch screen generally comprises a upper substrate, and the lower surface of this upper substrate is formed with transparency conducting layer on; One infrabasal plate, the upper surface of this infrabasal plate is formed with transparency conducting layer; And a plurality of point-like spacers (Dot Spacer) are arranged between transparency conducting layer and the following transparency conducting layer.Wherein, transparency conducting layer and this time transparency conducting layer adopt indium tin oxide (Indium Tin Oxide, ITO) layer (calling the ITO layer in the following text) with conductive characteristic usually on this.When using finger or pen to push upper substrate, upper substrate is distorted, and makes the last transparency conducting layer at the place of pushing and following transparency conducting layer contact with each other.Upwards transparency conducting layer and following transparency conducting layer apply voltage successively respectively by external electronic circuit, touch screen controller is by measuring change in voltage on first conductive layer and the change in voltage on second conductive layer respectively, and carry out accurate Calculation, convert it to contact coordinate.Touch screen controller passes to central processing unit with digitized contact coordinate.Central processing unit sends command adapted thereto according to contact coordinate, and the various functions that start electronic equipment are switched, and shows by display controller control display element.
Yet, growing along with display technique, the flexible display device that adopts flexible material to make is manufactured and produce, as organic electroluminescent display (OLED) and Electronic Paper (e-paper).The touch-screen that is provided with on these flexible display devices must be a flexible touch screen.The substrate of touch-screen is a non deformable glass substrate in the prior art, and transparency conducting layer adopts the ITO layer usually.The ITO layer have machinery as transparency conducting layer and chemical durability bad, shortcoming such as can't bend, therefore, above-mentioned touch-screen only is fit to be arranged on the non deformable conventional display apparatus, can't be used for flexible display device.In addition, the ITO layer is main at present to adopt methods such as sputter or evaporation to prepare, and in the process of preparation, needs higher vacuum environment and is heated to 200 ℃～300 ℃, therefore, makes that the preparation cost of ITO layer is higher.Further, adopt ITO layer producing transparent conductive layer to have resistance phenomenon pockety, cause existing resistive touch screen to have problems such as resolution is low, degree of accuracy is not high.
Therefore, necessaryly provide a kind of method for preparing flexible touch screen, and this method has, and technology is simple, low cost and other advantages.
Summary of the invention
A kind of preparation method of touch-screen, it may further comprise the steps: one first matrix is provided; Form a carbon nanotube composite material layer on the surface of first matrix, make first battery lead plate; Repeat above-mentioned steps, prepare second battery lead plate; Encapsulate first battery lead plate and second battery lead plate, form a touch-screen.
Compare with the preparation method of the touch-screen of prior art, the preparation method of the touch-screen that the technical program provides has the following advantages: one, because carbon nanotube layer has excellent mechanical characteristic and anti-bending, so, adopt above-mentioned carbon nanotube layer producing transparent conductive layer, can make transparency conducting layer have good toughness and physical strength.Further, cooperate, can prepare a flexible touch screen, thereby be suitable on the flexible display apparatus with flexible substrate.They are two years old, owing to being pulled by a stretching tool, carbon nano-tube film that present embodiment provided obtains, this method needing no vacuum environment and heating process, so adopt the touch-screen of the carbon nano-tube film of above-mentioned method preparation, have that cost is low, environmental protection and an energy-saving advantages as transparency conducting layer and preparation.Its three, the process that present embodiment prepares touch-screen is lower to temperature requirement, thereby less to the temperature limitation of matrix material.
Description of drawings
Fig. 1 is the perspective view of the touch-screen that provides of the technical program embodiment.
Fig. 2 is the side-looking structural representation of the touch-screen that provides of the technical program embodiment.
Fig. 3 is the stereoscan photograph of the carbon nanotube composite material layer that provides of the technical program embodiment.
Fig. 4 is the resistance linear graph of the carbon nanotube composite material layer that provides of the technical program embodiment.
Fig. 5 is the stereoscan photograph of the carbon nano-tube film that provides of the technical program embodiment.
Fig. 6 is the preparation method's of the touch-screen that provides of the technical program embodiment a process flow diagram.
Fig. 7 is the stereoscan photograph of the carbon nano-tube film before the laser treatment that provided of the technical program embodiment.
Fig. 8 is the stereoscan photograph of the carbon nano-tube film after the laser treatment that provided of the technical program embodiment.
Fig. 9 is continuous preparation first battery lead plate that provides of the technical program embodiment or the schematic flow sheet of second battery lead plate.
Describe touch-screen that the technical program embodiment provides and preparation method thereof in detail below with reference to accompanying drawing.
See also Fig. 1 and Fig. 2, the technical program embodiment provides a kind of touch-screen 10, this touch-screen 10 comprise one first battery lead plate, 12, one second battery lead plates 14 and be arranged on this first battery lead plate 12 and second battery lead plate 14 between a plurality of transparent point-like spacer 16.
This first battery lead plate 12 comprises one first matrix, 120, one first conductive layers 122 and two first electrodes 124.This first matrix 120 is a planar structure, and this first conductive layer 122 and two first electrodes 124 all are arranged on the lower surface of first matrix 120.Two first electrodes 124 are separately positioned on first conductive layer 122 and are electrically connected along the two ends of first direction and with first conductive layer 122.This second battery lead plate 14 comprises one second matrix, 140, one second conductive layers 142 and two second electrodes 144.This second matrix 140 is a planar structure, and this second conductive layer 142 and two second electrodes 144 all are arranged on the upper surface of second matrix 140.Two second electrodes 144 are separately positioned on second conductive layer 142 and are electrically connected along the two ends of second direction and with second conductive layer 142.This first direction is perpendicular to this second direction, i.e. two first electrodes 124 and two second electrode 144 quadrature settings.
This first conductive layer 122 and second conductive layer 142 all adopt a carbon nanotube composite material layer, see also Fig. 3, and this carbon nanotube composite material layer comprises a carbon nanotube layer and the macromolecular material of uniformly penetrating in this carbon nanotube layer.The thickness of described carbon nanotube composite material layer is not limit, and is preferably 0.5 nanometer-1 millimeter.Described macromolecular material is a transparent polymer material, and it comprises polystyrene, tygon, polycarbonate, polymethylmethacrylate (PMMA), polycarbonate (PC), ethylene glycol terephthalate (PET), phenylpropyl alcohol cyclobutane (BCB), poly-cycloolefin etc.In the present embodiment, described macromolecular material is PMMA.Macromolecular material in the carbon nanotube composite material layer can make carbon nanotube layer combine with flexible substrate firmly, simultaneously, see also Fig. 4, because macromolecular material permeates in carbon nanotube layer, short circuit phenomenon between the carbon nano-tube in the carbon nanotube layer is eliminated, made the resistance of carbon nanotube layer be the better linearity relation.
This carbon nanotube layer layer structure with uniform thickness that orderly or unordered carbon nano-tube forms of serving as reasons, described carbon nano-tube evenly distributes in carbon nanotube layer and is in contact with one another.The thickness of carbon nanotube layer is 0.5 nanometer-100 micron.Particularly, this carbon nanotube layer comprises one deck carbon nano-tube film at least, and this carbon nano-tube film comprises unordered carbon nano-tube film or orderly carbon nano-tube film.In the unordered carbon nano-tube film, carbon nano-tube is unordered or isotropy is arranged.In the orderly carbon nano-tube film, carbon nano-tube is for to be arranged of preferred orient or to be arranged of preferred orient along different directions along same direction.Carbon nano-tube in the described carbon nanotube layer comprises one or more in Single Walled Carbon Nanotube, double-walled carbon nano-tube and the multi-walled carbon nano-tubes.Wherein, the diameter of Single Walled Carbon Nanotube is 0.5 nanometer～50 nanometers, and the diameter of double-walled carbon nano-tube is 1.0 nanometers～50 nanometers, and the diameter of multi-walled carbon nano-tubes is 1.5 nanometers～50 nanometers.
Preferably, described orderly carbon nano-tube film comprises that one deck directly pulls acquisition carbon nano-tube membrane structure from carbon nano pipe array at least.Particularly, see also Fig. 5, this carbon nano-tube membrane structure further comprises a plurality of carbon nano-tube, and this carbon nano-tube joins end to end and arranges along the draw direction of carbon nano-tube film.Described even carbon nanotube distributes, and is parallel to the surface of carbon nano-tube membrane structure.Carbon nano-tube in the described carbon nano-tube membrane structure connects by Van der Waals force, and on the one hand, end to end carbon nano-tube is end to end by Van der Waals force; On the other hand, parallel carbon nano-tube part is also by the Van der Waals force combination.Be formed with uniform gap between the carbon nano-tube in this carbon nano-tube membrane structure, the diameter in this gap is 1 nanometer-10 micron.Macromolecular material evenly is filled in the gap between the carbon nano-tube.When described ordered carbon nanotube film comprises a plurality of carbon nano-tube membrane structure, the overlapping setting of carbon nano-tube membrane structure, the orientation of the carbon nano-tube in the adjacent two layers carbon nano-tube membrane structure forms an angle α, wherein, α is more than or equal to zero degree and smaller or equal to 90 degree (0≤α≤90 °).The length and the width of the thin membrane structure of this carbon nano-tube are not limit, and can prepare according to the actual requirements, and this carbon nano-tube membrane thickness of structure is 0.5 nanometer～100 micron.In the present embodiment, this first conductive layer 122 and second conductive layer 142 all adopt the carbon nano-tube membrane structure of individual layer and the carbon nanotube composite material layer that PAMM forms, PAMM is filled in the carbon nano-tube membrane structure in the gap between the carbon nano-tube, carbon nano-tube aligns along above-mentioned first direction in first conductive layer 122, and carbon nano-tube aligns along above-mentioned second direction in second conductive layer 142.
First electrode 124 of described touch-screen 10 and second electrode 144 are formed by conductive material, specifically can be chosen as metal material, conducting polymer materials or carbon nanotube layer.The material of described metal level can be chosen as the metal of good conductivity such as gold, silver or copper.The material of described conductive polymer coating can be chosen as polyacetylene, polyparaphenylene, polyaniline, poly-miaow fen, poly-adjoin cough up, polythiophene etc.Preferably, this carbon nanotube layer comprises at least one carbon nano-tube membrane structure.In the present embodiment, this first electrode 124 and second electrode 144 are the silver slurry layer of conduction.
Further, in described touch-screen 10, this second battery lead plate 14 is provided with an insulation course 18 near the surface periphery of first battery lead plate 12.The first above-mentioned battery lead plate 12 is arranged on this insulation course 18, and first conductive layer 122 of this first battery lead plate 12 is over against second conductive layer, 142 settings of second battery lead plate 14.Above-mentioned a plurality of point-like spacer 16 is arranged on second conductive layer 142 of second battery lead plate 14, and these a plurality of point-like spacers 16 are intervally installed.Distance between first battery lead plate 12 and second battery lead plate 14 is 2～10 microns.This insulation course 18 all can adopt insulating resin or other insulating material to make with point-like spacer 16, and this point-like spacer 16 should be a transparent material and makes.Insulation course 18 is set makes win battery lead plate 14 and second battery lead plate, 12 electrical isolations with point-like spacer 16.Be appreciated that when touch-screen 10 sizes hour, point-like spacer 16 be selectable structure, need guarantee that first battery lead plate 14 and second battery lead plate, 12 electrical isolations get final product.
During use, first battery lead plate 12 and second battery lead plate 14 feed 5V voltage respectively, when the user pushes touch-screen 10 first battery lead plates 12 and operates by finger or pen, first matrix 120 bends in first battery lead plate 12, feasible first conductive layer 122 at place and the second electrode lay 142 formation one contact point of second battery lead plate 14 pushed, form conducting at this contact point, because the place of pushing is not simultaneously, the contact point difference that forms, the electric signal that each contact point is corresponding different, and then can realize the signal transmission.
The employing carbon nanotube composite material layer that the technical program embodiment provides has the following advantages as the touch-screen of transparency conducting layer: one, carbon nano-tube has excellent mechanical characteristic, the composite structure that carbon nanotube layer is arranged at macromolecular material formation makes transparency conducting layer have good toughness and physical strength, die, can improve the durability of touch-screen accordingly; They are two years old, because carbon nano-tube has excellent electric conductivity, above-mentioned this carbon nanotube layer comprises a plurality of equally distributed carbon nano-tube, so, adopt above-mentioned carbon nanotube composite material layer producing transparent conductive layer, can make transparency conducting layer have uniform resistance and distribute, thereby improve touch-screen and use the resolution and the degree of accuracy of the display device of this touch-screen.Its three because polymer material layer to small part permeates in carbon nanotube layer, make carbon nanotube layer firm with combining of matrix, increased the serviceable life of touch-screen.
See also Fig. 6, the technical program embodiment provides a kind of method for preparing above-mentioned touch-screen 10, and it specifically may further comprise the steps:
Step 1: one first matrix is provided.
Described first matrix is a flexible planar member, and thickness is 0.1 millimeter～1 centimetre.This first matrix is by plastics, and flexible materials such as resin form.Particularly, the material of described first matrix can be polycarbonate (PC), polymethylmethacrylate (PMMA), polyethylene terephthalate polyester materials such as (PET), and materials such as polyethersulfone (PES), pi (PI), cellulose esters, benzocyclobutene (BCB), Polyvinylchloride (PVC) and acryl resin.Be appreciated that the material that forms described first matrix is not limited to the above-mentioned material of enumerating, as long as guarantee that described flexible substrate has certain flexibility and reaches transparency preferably.
Among the technical program embodiment, described first matrix is a polyethylene terephthalate (PET) film (hereinafter to be referred as the PET film).The thickness of this PET film is 2 millimeters, and width is 20 centimetres, and length is 30 centimetres.
The described method that forms a carbon nanotube composite material layer at first matrix surface may further comprise the steps:
(1) surface-coated at first matrix forms one deck macromolecule material solution.
Adopt brush or other instrument to pick a certain amount of macromolecule material solution, evenly be coated on the surface of flexible substrate or the surface of flexible substrate is immersed in and directly pick a certain amount of macromolecule material solution in the macromolecule material solution, form a macromolecule material solution layer.The mode that is appreciated that described surface applied macromolecule material solution at this flexible substrate is not limit, as long as can form uniform one deck macromolecule material solution on the surface of flexible substrate.
Described macromolecule material solution comprises that macromolecular material is dissolved in the formed solution of organic solvent, and it has certain viscosity, and preferably, the viscosity of macromolecule material solution is greater than 1Pa.s.Described macromolecular material is solid-state at normal temperatures, and has certain transparency.Described organic solvent comprises ethanol, methyl alcohol, acetone, ethylene dichloride or chloroform etc.Described macromolecular material comprises polystyrene, tygon, polycarbonate, polymethylmethacrylate (PMMA), polycarbonate (PC), ethylene glycol terephthalate (PET), phenylpropyl alcohol cyclobutane (BCB), poly-cycloolefin etc.In the present embodiment, described macromolecular material is PMMA, and described macromolecule material solution is that PMMA is dissolved in the solution that ethanol forms.
(2) preparation one carbon nano-tube film.
Described carbon nano-tube film is ordered carbon nanotube film or disordered carbon nano-tube film, and this carbon nano-tube film can or directly pull acquisition by rolling method, waddingization method from carbon nano pipe array.Preferably, in the present embodiment, this carbon nano-tube film is a direct carbon nano-tube membrane structure that pulls acquisition from carbon nano pipe array.The preparation method of described carbon nano-tube membrane structure specifically may further comprise the steps:
At first, provide a carbon nano pipe array, preferably, this array is super in-line arrangement carbon nano pipe array.
The carbon nano-pipe array that the technical program embodiment provides is classified one or more in single-wall carbon nanotube array, double-walled carbon nano-tube array and the array of multi-walled carbon nanotubes as.In the present embodiment, the preparation method of being somebody's turn to do super in-line arrangement carbon nano pipe array adopts chemical vapour deposition technique, its concrete steps comprise: a smooth substrate (a) is provided, this substrate can be selected P type or N type silicon base for use, or select for use the silicon base that is formed with oxide layer, present embodiment to be preferably and adopt 4 inches silicon base; (b) evenly form a catalyst layer at substrate surface, this catalyst layer material can be selected one of alloy of iron (Fe), cobalt (Co), nickel (Ni) or its combination in any for use; (c) the above-mentioned substrate that is formed with catalyst layer was annealed in 700 ℃～900 ℃ air about 30 minutes～90 minutes; (d) substrate that will handle places reacting furnace, is heated to 500 ℃～740 ℃ under the blanket gas environment, feeds carbon-source gas then and reacts about 5～30 minutes, and growth obtains super in-line arrangement carbon nano pipe array, and it highly is 50 microns～5 millimeters.Should super in-line arrangement carbon nano-pipe array classify as a plurality of parallel to each other and perpendicular to the pure nano-carbon tube array of the carbon nano-tube formation of substrate grown.By above-mentioned control growth conditions, do not contain impurity substantially in this super in-line arrangement carbon nano pipe array, as agraphitic carbon or residual catalyst metal particles etc.Carbon nano-tube in this carbon nano pipe array closely contacts the formation array by Van der Waals force each other.This carbon nano pipe array and above-mentioned area of base are basic identical.
Carbon source gas can be selected the more active hydrocarbons of chemical property such as acetylene, ethene, methane for use in the present embodiment, and the preferred carbon source gas of present embodiment is acetylene; Blanket gas is nitrogen or inert gas, and the preferred blanket gas of present embodiment is an argon gas.
Be appreciated that the carbon nano pipe array that present embodiment provides is not limited to above-mentioned preparation method.Also can be graphite electrode Constant Electric Current arc discharge sedimentation, laser evaporation sedimentation etc.
Secondly, adopt a stretching tool from carbon nano pipe array, to pull and obtain a carbon nano-tube membrane structure.It specifically may further comprise the steps: (a) selected part carbon nano-tube from above-mentioned carbon nano pipe array, present embodiment are preferably and adopt the adhesive tape contact carbon nano pipe array with certain width with selected part carbon nano-tube; (b) with certain speed along being basically perpendicular to the carbon nano pipe array direction of growth this part carbon nano-tube that stretches, to form a continuous carbon nano-tube membrane structure.
In above-mentioned drawing process, this part carbon nano-tube is when pulling force effect lower edge draw direction breaks away from substrate gradually, because Van der Waals force effect, carbon nano-tube in part carbon nano-tube that should be selected respectively with carbon nano pipe array in other carbon nano-tube be drawn out continuously end to end, thereby form a carbon nano-tube membrane structure.The width of described carbon nano-tube membrane structure and thickness and the width of carbon nano pipe array and highly relevant, in the present embodiment, the width of carbon nano-tube membrane structure is 20 centimetres, thickness is 0.5 nanometer-100 micron.
(3) adopt the above-mentioned carbon nano-tube film of laser treatment.
Because have the Van der Waals example between the carbon nano-tube itself in the carbon nano-tube film, some carbon nano-tube in the carbon nano-tube film is assembled the formation carbon nano-tube bundle easily, this carbon nano-tube beam diameter is bigger, has influenced the electric conductivity of carbon nano-tube film.Be to improve the light transmission of carbon nano-tube film, with power density greater than 0.1 * 10
4Watt/square metre this carbon nano-tube film of laser radiation is removed the relatively poor carbon nano-tube bundle of light transmission in the carbon nano-tube film.Adopt the step of laser treatment carbon nano-tube film in aerobic environment, to carry out, preferably, carry out at air ambient.
Adopt the above-mentioned carbon nano-tube film of laser treatment can lead to the fixed carbon nano-tube film, moving laser device shines the method realization of this carbon nano-tube film or passes through fixed laser then, and mobile carbon nano-tube film is realized the method for this carbon nano-tube film of laser radiation.
In the process of above-mentioned laser radiation carbon nano-tube film, because carbon nano-tube has good absorption characteristic to laser, and laser is one to have the light of higher-energy, can produce certain heat after being absorbed by carbon nano-tube film, and the carbon nano-tube in the carbon nano-tube film is heated up.In the carbon nano-tube film, in the carbon nano-tube film, the heat that the carbon nano-tube bundle that diameter is bigger absorbs is more, therefore, temperature in the intrafascicular carbon nano-tube of carbon nano-tube is higher, and when the temperature of carbon nano-tube reaches enough high (generally greater than 600 ℃), carbon nano-tube bundle is burnt by laser.See also Fig. 7 and Fig. 8, with respect to the carbon nano-tube film before the laser treatment.The light transmission of the carbon nano-tube film after the laser treatment increases significantly, and its transmittance is greater than 70%.
Be appreciated that the purpose that adopts laser treatment carbon nano-tube membrane structure is the further transparency that improves carbon nano-tube membrane structure, so this step is a selectable step.
(4) above-mentioned at least one carbon nano-tube film is laid on the surface of the macromolecule material solution on the described flexible substrate, forms a carbon nanotube layer.
At least one deck carbon nano-tube film can be laid immediately on the surface of polymer material layer, and a plurality of carbon nano-tube films can parallel gapless laying or overlapping laying.When carbon nano-tube film is a carbon nano-tube membrane structure, when carbon nanotube layer comprises two-layer at least carbon nano-tube membrane structure, the orientation of the carbon nano-tube in this carbon nanotube layer in the adjacent carbon nano-tube membrane structure forms an angle α, wherein, and 0 °≤α≤90 °.In the present embodiment, described carbon nanotube layer comprises one deck carbon nano-tube membrane structure.
After carbon nanotube layer is formed on the polymer material layer, promptly formed a sandwich structure that comprises first matrix, polymer material layer and carbon nanotube layer successively.
(5) macromolecule material solution is permeated in carbon nanotube layer, macromolecular material and carbon nanotube layer are solidified, form a carbon nanotube composite material layer.
Adopt external force that carbon nanotube layer is applied certain pressure, blow carbon nanotube layer with the wind-force of 10 meters-20 meter per seconds as adopting air knife, and then carbon nano-tube lamination polymer material layer, polymer material layer is permeated in carbon nanotube layer.The method that macromolecule material solution permeates in carbon nanotube layer when described is not limited only to the method for above-mentioned employing wind, as long as macromolecule material solution is permeated in carbon nanotube layer.When macromolecular material permeates behind carbon nanotube layer, said structure is heated to uniform temperature, make the solvent evaporates in the macromolecule material solution, the compound and curing of macromolecular material and carbon nanotube layer, thus form a carbon nanotube composite material layer on the surface of flexible substrate.Described method to the heating of macromolecule material solution and carbon nanotube layer can be said structure directly is positioned over and is heated to uniform temperature in the stove, or the mode of use ultra-violet curing, promptly the composite structure of forming with the ultraviolet light heating macromolecule material solution and the carbon nanotube layer of certain energy makes it reach uniform temperature.Described temperature is relevant with the solvent in the macromolecule material solution, and temperature is higher than the volatilization temperature of flux, and in the present embodiment, temperature is 100 ℃.
Macromolecular material in the carbon nanotube composite material layer can make carbon nanotube layer combine with flexible substrate firmly, simultaneously, because macromolecular material permeates in carbon nanotube layer, short circuit phenomenon between the carbon nano-tube in the carbon nanotube layer is eliminated, made the resistance of carbon nanotube layer be the better linearity relation.
Be appreciated that among the preparation method of described first motor plate, after forming carbon nanotube composite material layer, comprise that further a compartment of terrain forms two first electrodes in the surface of above-mentioned carbon nanotube composite material layer or the step at the two ends of flexible substrate.
The material of described two electrodes is silver slurry layer or other conductive material of metal, carbon nano-tube film, conduction.Among the technical program embodiment, described two electrodes are the silver slurry layer of conduction.The formation method of described two electrodes comprises: modes such as serigraphy, bat printing or spraying.In the present embodiment, respectively the silver slurry is coated in the surface of above-mentioned carbon nanotube composite material layer or the two ends of first matrix.Then, put into the baking oven baking silver slurry is solidified, baking temperature is 100 ℃-120 ℃, can obtain described two electrodes.Above-mentioned preparation method need guarantee that described two electrodes are electrically connected with described carbon nanotube layer.
Described second battery lead plate comprises one second matrix, one second carbon nanotube layer and two second electrodes.
The method of described encapsulation first battery lead plate and second battery lead plate may further comprise the steps:
(1) forms an insulation course is formed with a side of carbon nanotube composite material layer in described second battery lead plate periphery.
The formation step of described insulation course is: apply an insulation course forms a side of carbon nanotube composite material layer in described second battery lead plate periphery.The material of described insulation course comprises transparent resin or other insulation transparent materials.
Described insulation course can adopt insulation transparent resin or other insulation transparent materials to make.
(2) cover first battery lead plate on described insulation course, and carbon nanotube composite material layer in described first battery lead plate and the carbon nanotube composite material layer in described second battery lead plate are oppositely arranged.Two first electrodes on first battery lead plate and two second electrode crossing settings on second battery lead plate.
(3) periphery with first battery lead plate, second battery lead plate and insulation course adopts fluid sealant to seal, and forms a touch-screen.Present embodiment, described fluid sealant are 706B model sulphurated siliastic.Sealing glue is coated on the edge of first battery lead plate, second battery lead plate and insulation course, and placing one day is solidifiable.
Further, need make two electrodes in described first conductive layer and two electrode crossing settings in described second conductive layer.
In addition, described preparation method can further comprise the step of a plurality of transparent point-like spacers of formation between described first battery lead plate and second battery lead plate.The formation method of this transparent point-like spacer is: will comprise the zone of slurry coating outside insulation course on second battery lead plate or first battery lead plate of these a plurality of transparent point-like spacers, and promptly form described transparent point-like spacer after the oven dry.Described insulation course and described transparent point-like spacer all can adopt insulating resin or other insulating material to make.Insulation course and point-like spacer are set make the win battery lead plate and the second battery lead plate electrical isolation.Be appreciated that when the touch-screen size hour, the point-like spacer is selectable structure, only need guarantee that first battery lead plate and the second battery lead plate electrical isolation get final product.
In the present embodiment, can realize the preparation of battery lead plate by the device of working continuously in the described method for preparing touch-screen.
See also Fig. 9, the device 200 of working continuously described in the present embodiment comprises one first rotating shaft 202, second rotating shaft 204, one the 3rd rotating shaft, 206, one large containers 208, an objective table 210, a tubular furnace 212, a draw-gear 214, an air knife 216, a scratch device 230, a laser instrument 232 and a power supply (figure does not show).Described first rotating shaft 202, second rotating shaft 204 and one the 3rd rotating shaft 206 are provided with at interval, and it axially is positioned at same direction.The 3rd rotating shaft 206 is arranged at the axial two ends of tubular furnace with draw-gear 214.Between blowing device 216 settings and the 3rd rotating shaft 206 and the tubular furnace 212.Described large container 208 is arranged at the below of second rotating shaft 204, and second rotating shaft, 204 parts are arranged in large container 208.Described scratch device 230 is provided with near second rotating shaft 204, and an end of scratch device 230 and second rotating shaft 204 keep a fixed range.Twine by a flexible substrate 218 in first rotating shaft 202, fill macromolecule material solution 220 in the large container 208.
The method that the above-mentioned device of working continuously of described employing prepares first battery lead plate or second battery lead plate specifically may further comprise the steps:
(1) with flexible substrate 218 successively by second rotating shaft 204, the 3rd rotating shaft 206 and pass tubular furnace and draw-gear 214 downlink connection mutually, make the surface of flexible substrate 218 form one deck macromolecule material solution.
In this process, because second rotating shaft, 204 parts are arranged in large container 208, the macromolecule material solution 220 in the large container 208 adheres to the surface of flexible substrate 218, forms one deck macromolecule material solution layer 226.Maintain a certain distance between the scratch device 230 and second rotating shaft 204, when the thickness of macromolecule material solution layer 226 surpass this apart from the time, scraped by scratch device 230, therefore, scratch device 230 can make the thickness of Polymer Solution certain and keep homogeneity.
(2) fix and one surpass in-line arrangement carbon nano pipe array 222 on objective table 210, from this super in-line arrangement carbon nano pipe array 222, pull out a continuous carbon nano-tube membrane structure 224, an end of carbon nano-tube membrane structure 224 is adhered on the flexible substrate 218 lip-deep macromolecule material solution layers 226.After carbon nano-tube film 224 is pulled out from carbon nano pipe array 222, when not contacting with macromolecule material solution layer 226, this carbon nano-tube film 224 of laser radiation that can adopt laser instrument 234 to send, the transparency of raising carbon nano-tube film 224.Its radiation modality and concrete parameter are as mentioned before.
(3) opening power, make draw-gear 214 draw flexible substrate 218 along being parallel to tubular furnace 212 axial directions with certain speed, polymer material layer 226 and carbon nano-tube film 224, when carbon nano-tube film 224 arrives air knife 216 bottoms, the wind that air knife 216 blows out applies certain pressure to carbon nano-tube film 224, make carbon nano-tube film 224 be absorbed in polymer material layer 226, be that macromolecular material penetrates into carbon and receives in the nano-tube film 224, pass through tubular furnace 212 then, the high temperature of tubular furnace 212 inside solidifies the macromolecular material that infiltrates to carbon nano-tube film 224, forms carbon nanotube composite material layer 228 on the surface of flexible substrate 218.
(4) flexible substrate 218 that will be formed with carbon nanotube composite material layer 228 cuts, and forms battery lead plate.
Further, two electrodes are set, can form a plurality of first battery lead plates or second battery lead plate at the spaced surface of carbon nanotube composite material layer 228.
Adopt above-mentioned steps on matrix, to apply macromolecule material solution, thereby form carbon nanotube composite material layer, can realize the production of serialization, enhance productivity, the save operation time, further save cost on the surface of matrix.
In addition, those skilled in the art also can do other and change in spirit of the present invention, and these variations of doing according to spirit of the present invention certainly all should be included in the present invention's scope required for protection.
Claims (18)
1. the preparation method of a touch-screen, it may further comprise the steps:
One first matrix is provided;
Form the surface of a carbon nanotube composite material layer, make first battery lead plate in first matrix;
Repeat above-mentioned steps, prepare second battery lead plate;
Encapsulate first battery lead plate and second battery lead plate, form a touch-screen.
2. the preparation method of touch-screen as claimed in claim 1 is characterized in that, the method for described formation one carbon nanotube composite material layer in the surface of first matrix may further comprise the steps:
Surface-coated one deck macromolecule material solution at first matrix;
Prepare a carbon nano-tube film;
Adopt the above-mentioned carbon nano-tube film of laser treatment, improve the transparency of carbon nano-tube film;
Above-mentioned at least one carbon nano-tube film is laid on the surface of the macromolecule material solution on the described flexible substrate, forms a carbon nanotube layer;
Macromolecule material solution is permeated in carbon nanotube layer, solidify macromolecular material, form a carbon nanotube composite material layer.
3. the preparation method of touch-screen as claimed in claim 2 is characterized in that, the power density of described laser is greater than 0.1 * 10
4Watt/square metre.
4. the preparation method of touch-screen as claimed in claim 2 is characterized in that, the step that described one deck carbon nano-tube film at least is laid on the surface of the macromolecule material solution on the described flexible substrate is:
One deck carbon nano-tube film directly laid or with parallel no gap of a plurality of carbon nano-tube films or overlapping laying.
5. the preparation method of touch-screen as claimed in claim 2 is characterized in that, described carbon nano-tube film comprises a carbon nano-tube membrane structure, and the carbon nano-tube in this carbon nano-tube membrane is arranged of preferred orient along same direction.
6. the preparation method of touch-screen as claimed in claim 5 is characterized in that, the method for described preparation one carbon nano-tube membrane structure may further comprise the steps: a carbon nano pipe array is provided; Selected part carbon nano-tube from above-mentioned carbon nano pipe array; With certain speed along being basically perpendicular to the carbon nano pipe array direction of growth this part carbon nano-tube that stretches, to form a continuous carbon nano-tube membrane structure.
7. the preparation method of touch-screen as claimed in claim 2, it is characterized in that, the described method that macromolecular material is permeated in carbon nanotube layer is to adopt wind-force and then the carbon nano-tube lamination polymer material layer of air knife with the 10-20 meter per second, and polymer material layer is permeated in carbon nanotube layer.
8. the preparation method of touch-screen as claimed in claim 2 is characterized in that, the method for described curing macromolecular material comprises macromolecule material solution is heated to uniform temperature.
9. the preparation method of touch-screen as claimed in claim 2 is characterized in that, the method for described heating macromolecule material solution is for being positioned over Polymer Solution the UV-irradiation macromolecule material solution that heats or adopt certain energy in the stove.
10. the preparation method of touch-screen as claimed in claim 1 is characterized in that, the described method for preparing battery lead plate can adopt the device of working continuously to finish continuously.
11. the preparation method of touch-screen as claimed in claim 10, it is characterized in that, the described device of working continuously comprises one first rotating shaft, second rotating shaft, one the 3rd rotating shaft, a large container, an objective table, a tubular furnace, a draw-gear, an air knife, a scratch device, a laser instrument and a power supply.
12. the preparation method of touch-screen as claimed in claim 11 is characterized in that, described first rotating shaft, second rotating shaft and one the 3rd rotating shaft are provided with at interval, and it axially is positioned at same direction.
13. the preparation method of touch-screen as claimed in claim 11 is characterized in that, described the 3rd rotating shaft and draw-gear are arranged at the axial two ends of tubular furnace.
14. the preparation method of touch-screen as claimed in claim 11 is characterized in that, between described blowing device setting and the 3rd rotating shaft and the tubular furnace.
15. the preparation method of touch-screen as claimed in claim 11 is characterized in that, described large container is arranged at the below of second rotating shaft, and second rotating shaft partly is arranged in large container.
16. the preparation method of touch-screen as claimed in claim 11 is characterized in that, described described scratch device is near the second rotating shaft setting, and an end and second rotating shaft of scratch device keep a fixed range.
17. the preparation method of touch-screen as claimed in claim 11 is characterized in that, twines a flexible substrate in described first rotating shaft, fills macromolecule material solution in the large container.
18. the preparation method of touch-screen as claimed in claim 11 is characterized in that, the described employing method that device prepares battery lead plate of working continuously may further comprise the steps:
Successively by second rotating shaft, the 3rd rotating shaft and pass tubular furnace and draw-gear downlink connection mutually, make the surface of flexible substrate form one deck macromolecule material solution flexible substrate;
Fix and one surpass the in-line arrangement carbon nano-pipe array and list on the objective table, from this super in-line arrangement carbon nano pipe array, pull out a continuous carbon nano-tube membrane structure, an end of carbon nano-tube membrane structure is adhered on the lip-deep polymer material layer of flexible substrate; Opening power, make draw-gear along being parallel to tubular furnace axial direction traction flexible substrate, polymer material layer and carbon nano-tube film, air knife makes macromolecular material penetrate into carbon and receives in the nano-tube film, solidify macromolecular material through tubular furnace, form carbon nanotube composite material layer on the surface of flexible substrate; Promptly obtain battery lead plate after will being formed with the flexible substrate cutting of composite layer.
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100683192A CN101620492B (en) | 2008-07-04 | 2008-07-04 | Preparation method for touch screen |
| US12/459,566 US8237677B2 (en) | 2008-07-04 | 2009-07-02 | Liquid crystal display screen |
| JP2009160173A JP4944167B2 (en) | 2008-07-04 | 2009-07-06 | Manufacturing method of touch panel |
| US12/583,160 US8228308B2 (en) | 2008-07-04 | 2009-08-13 | Method for making liquid crystal display adopting touch panel |
| US12/583,161 US8237679B2 (en) | 2008-07-04 | 2009-08-13 | Liquid crystal display screen |
| US12/583,162 US8237680B2 (en) | 2008-07-04 | 2009-08-13 | Touch panel |
| US12/584,415 US8105126B2 (en) | 2008-07-04 | 2009-09-03 | Method for fabricating touch panel |
| US12/584,410 US8199123B2 (en) | 2008-07-04 | 2009-09-03 | Method for making liquid crystal display screen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100683192A CN101620492B (en) | 2008-07-04 | 2008-07-04 | Preparation method for touch screen |
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| Publication Number | Publication Date |
|---|---|
| CN101620492A true CN101620492A (en) | 2010-01-06 |
| CN101620492B CN101620492B (en) | 2011-03-30 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2008100683192A Active CN101620492B (en) | 2008-07-04 | 2008-07-04 | Preparation method for touch screen |
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| Country | Link |
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| JP (1) | JP4944167B2 (en) |
| CN (1) | CN101620492B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101859216A (en) * | 2010-06-11 | 2010-10-13 | 北京富纳特创新科技有限公司 | Touch screen |
| CN103534668A (en) * | 2011-03-22 | 2014-01-22 | 波利Ic有限及两合公司 | Layered body, method for producing said layered body, and use of said layered body |
| CN104599746A (en) * | 2015-01-27 | 2015-05-06 | 京东方科技集团股份有限公司 | Touch element, preparation method thereof and touch screen |
| CN109599270A (en) * | 2017-09-30 | 2019-04-09 | 清华大学 | A kind of preparation method of photoelectricity from energy storage device |
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| KR20110104406A (en) * | 2010-05-14 | 2011-09-22 | 삼성전기주식회사 | Apparatus for the production of touch panel |
| US20140063360A1 (en) * | 2010-06-17 | 2014-03-06 | Yousuke KUNISHI | Input device |
| JP5534437B2 (en) * | 2010-07-28 | 2014-07-02 | 信越ポリマー株式会社 | Input device |
| US9995956B2 (en) * | 2015-03-20 | 2018-06-12 | Opton (Shunchang) Optics Co., Ltd | Integrated fully-sealed liquid cryatal screen and manufacturing process for same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2004230690A (en) * | 2003-01-30 | 2004-08-19 | Takiron Co Ltd | Antistatic transparent resin sheet |
| JP4539241B2 (en) * | 2004-09-02 | 2010-09-08 | パナソニック株式会社 | Touch panel and manufacturing method thereof |
| US20070298253A1 (en) * | 2004-09-17 | 2007-12-27 | Kenji Hata | Transparent Conductive Carbon Nanotube Film and a Method for Producing the Same |
| US7645497B2 (en) * | 2005-06-02 | 2010-01-12 | Eastman Kodak Company | Multi-layer conductor with carbon nanotubes |
| JP2007011997A (en) * | 2005-07-04 | 2007-01-18 | Fujitsu Component Ltd | Touch panel |
| US8329065B2 (en) * | 2005-12-06 | 2012-12-11 | Mitsubishi Rayon Co., Ltd. | Carbon nanotube-containing composition, composite, and methods for producing them |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101859216A (en) * | 2010-06-11 | 2010-10-13 | 北京富纳特创新科技有限公司 | Touch screen |
| US9304630B2 (en) | 2010-06-11 | 2016-04-05 | Beijing Funate Innovation Technology Co., Ltd. | Touch panel |
| CN103534668A (en) * | 2011-03-22 | 2014-01-22 | 波利Ic有限及两合公司 | Layered body, method for producing said layered body, and use of said layered body |
| CN103534668B (en) * | 2011-03-22 | 2017-09-19 | 波利Ic有限及两合公司 | Body ply, manufacture method and application thereof |
| CN104599746A (en) * | 2015-01-27 | 2015-05-06 | 京东方科技集团股份有限公司 | Touch element, preparation method thereof and touch screen |
| CN104599746B (en) * | 2015-01-27 | 2017-06-09 | 京东方科技集团股份有限公司 | A kind of touch control component and preparation method thereof and touch-screen |
| US9684399B2 (en) | 2015-01-27 | 2017-06-20 | Boe Technology Group Co., Ltd. | Touch element and manufacturing method thereof, and touch screen |
| CN109599270A (en) * | 2017-09-30 | 2019-04-09 | 清华大学 | A kind of preparation method of photoelectricity from energy storage device |
| CN109599270B (en) * | 2017-09-30 | 2020-08-11 | 清华大学 | Preparation method of photoelectric self-energy storage device |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4944167B2 (en) | 2012-05-30 |
| JP2010015577A (en) | 2010-01-21 |
| CN101620492B (en) | 2011-03-30 |
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| CI01 | Correction of invention patent gazette |
Correction item: Patentee|Address|Co-patentee Correct: Tsinghua University| 100084. Haidian District 1, Tsinghua Yuan, Beijing, Tsinghua University, Room 401, research center of Tsinghua Foxconn nanometer science and technology|Hung Fujin Precision Industrial (Shenzhen) Co., Ltd. False: Hongfujin Precision Industry (Shenzhen) Co., Ltd.|518109 Guangdong city of Shenzhen province Baoan District Longhua Town Industrial Zone tabulaeformis tenth East Ring Road No. 2 two Number: 13 Volume: 27 |
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| CI03 | Correction of invention patent |
Correction item: Patentee|Address|Co-patentee Correct: Tsinghua University| 100084. Haidian District 1, Tsinghua Yuan, Beijing, Tsinghua University, Room 401, research center of Tsinghua Foxconn nanometer science and technology|Hung Fujin Precision Industrial (Shenzhen) Co., Ltd. False: Hongfujin Precision Industry (Shenzhen) Co., Ltd.|518109 Guangdong city of Shenzhen province Baoan District Longhua Town Industrial Zone tabulaeformis tenth East Ring Road No. 2 two Number: 13 Page: The title page Volume: 27 |
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| ERR | Gazette correction |
Free format text: CORRECT: PATENTEE; ADDRESS; CO-PATENTEE; FROM: HONGFUJIN PRECISION INDUSTRY (SHENZHEN) CO., LTD.;518109 NO. 2, EAST RING 2ND ROAD, YOUSONG 10TH INDUSTRIAL ZONE, LONGHUA TOWN, BAOAN DISTRICT, SHENZHEN CITY, GUANGDONG PROVINCE TO: TSINGHUA UNIVERSITY;100084 ROOM 401, TSINGHUA-FOXCONN NANOTECHNOLOGY RESEARCH CENTER, TSINGHUA UNIVERSITY, NO. 1, TSINGHUA PARK, HAIDIAN DISTRICT, BEIJING; HONGFUJIN PRECISION INDUSTRY (SHENZHEN) CO., LTD. |