CN101613845A - A kind of Zirconium-base non-crystalline alloy compound material and preparation method thereof - Google Patents
A kind of Zirconium-base non-crystalline alloy compound material and preparation method thereof Download PDFInfo
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Abstract
The invention provides a kind of Zirconium-base non-crystalline alloy compound material, this matrix material comprises the zirconium-base amorphous alloy matrix, and wherein, this matrix material also comprises attached to the metal plating on the described zirconium-base amorphous alloy matrix surface.The present invention also provides the preparation method of this Zirconium-base non-crystalline alloy compound material.Zirconium-base non-crystalline alloy compound material of the present invention and preparation method thereof, can make this material surface obtain exterior decorative effect light, attractive in appearance, the erosion resistance of the metal plating of this composite material surface and wear resistance are still fine simultaneously, and the sticking power of this metal plating and zirconium-base amorphous alloy matrix surface is fine.
Description
Technical field
The present invention relates to a kind of Zirconium-base non-crystalline alloy compound material, also relate to the preparation method of this Zirconium-base non-crystalline alloy compound material.
Background technology
Bulk amorphous alloys is because of its unique microtexture, have crystal alloy incomparable mechanical property, as intensity and hardness height, good springiness, corrosion-resistant, wear-resisting etc., in the Aeronautics and Astronautics field, industry such as IT electronics, machinery, chemical industry has a wide range of applications.Zirconium-base amorphous alloy is with its amorphous formation ability height, and excellent performances such as intensity and hardness height, shock-resistance are good, good corrosion resistance, and successful being applied to prepares golf club, tennis racket and space flight with on the products such as solar wind collector; At present also have zirconium-base amorphous condensation material is applied to phone housing, MP3 shell and other electronic product shell, this has more expanded the range of application of zirconium-base amorphous alloy material to a certain extent, thereby brings into play the advantage of zirconium-base amorphous alloy material more widely.
Yet, the appearance of existing zirconium-base amorphous alloy material is single, the surface that does not also make the surface of zirconium-base amorphous alloy material obtain exterior decorative effect attractive in appearance has the Zirconium-base non-crystalline alloy compound material of metal plating, does not also form the technology of metal plating at the zirconium-base amorphous alloy matrix surface.
Summary of the invention
The object of the present invention is to provide a kind of Zirconium-base non-crystalline alloy compound material that adopts electro-plating method and prepare, a kind of preparation method of this zirconium-base amorphous alloy also is provided.
The invention provides a kind of Zirconium-base non-crystalline alloy compound material, this matrix material comprises the zirconium-base amorphous alloy matrix, and wherein, described matrix material also comprises attached to the electrodeposition of metals on the described zirconium-base amorphous alloy matrix surface.
The present invention also provides a kind of preparation method of Zirconium-base non-crystalline alloy compound material, and this method is included in the zirconium-base amorphous alloy matrix surface and forms metal plating.
Preparation method according to Zirconium-base non-crystalline alloy compound material provided by the invention and this zirconium-base amorphous alloy, can make this material surface obtain exterior decorative effect light, attractive in appearance, the erosion resistance of the metal plating of this composite material surface and wear resistance are still fine simultaneously, and the sticking power of this metal plating and zirconium-base amorphous alloy matrix surface is fine.
Embodiment
Zirconium-base non-crystalline alloy compound material provided by the invention comprises the zirconium-base amorphous alloy matrix, and wherein, described matrix material also comprises attached to the metal plating on the described zirconium-base amorphous alloy matrix surface.
According to matrix material provided by the invention, in the preferred case, fine for the sticking power that makes zirconium-base amorphous alloy matrix and metal plating, and can fully reach the decorative effect of metal plating, the thickness of described metal plating is the 0.5-100 micron, more preferably the 10-30 micron.
According to matrix material provided by the invention, the material of described metal plating can be any metal or metal alloy, and for example described metal plating is titanium, copper, nickel, palladium, silver, gold, tin, cobalt, chromium or at least 2 kinds alloy in them.Preferred titanium, copper, nickel or the alloy of at least 2 kinds of metals in them.
The present invention also provides a kind of preparation method of Zirconium-base non-crystalline alloy compound material, and this method is included in the zirconium-base amorphous alloy matrix surface and forms metal plating.
In the preferred case, the formation method of metal plating of the present invention comprises the formation decorative coating, and this decoration plating provides the coating with decorative effect for the outside surface of zirconium-base amorphous alloy matrix.The preparation method of described decorative coating comprises, the zirconium base alloy matrix is immersed in the electrolyte solution, with described matrix as negative electrode, will electroplated metal as anode, be 0.5-5A/dm in current density
2, the temperature of electrolyte solution is to electroplate 1-30 minute under 20-80 ℃ the condition; Described electrolyte solution is one or more the aqueous solution of vitriol, muriate, phosphoric acid salt or nitrate in titanium, copper, nickel, palladium, silver, gold, tin, cobalt and the chromium, the aqueous solution of at least 2 kinds vitriol, muriate, phosphoric acid salt or nitrate in titanium, copper, the nickel; The described electroplated metal of wanting is selected from titanium, copper, nickel, palladium, silver, gold, tin, cobalt, chromium or at least 2 kinds alloy in them, the alloy of at least 2 kinds of metals in preferred titanium, copper, the nickel.
According to preparation method provided by the invention, in the preferred case, before the zirconium-base amorphous alloy matrix decorated plating, earlier this matrix surface is carried out pre-treatment, make this matrix surface become smooth, smooth this matrix surface polishing, and remove grease, dirt and the oxide skin of this matrix surface, described pre-treatment process comprises polishing, paraffin removal, oil removing and etch.
Adopt polishing step certain ablation to be arranged to the zirconium-base amorphous alloy matrix, can remove burr, oxide skin, the defective of scuffing and the forming residual stress layer that produces through mechanical workout of this matrix surface, to reduce the roughness on zirconium-base amorphous alloy surface, make this smooth surface, smooth.The method of polishing is to well known to a person skilled in the art to be used for method that various metals are polished, for example adopts mechanical polishing, chemical rightenning or electrochemical etching.
Adopting the paraffin removal step is in order to remove the buffing wax of the zirconium-base amorphous alloy matrix surface after the polishing, thereby makes decorative coating and the good sticking power of zirconium-base amorphous alloy matrix surface generation.The method of paraffin removal is to well known to a person skilled in the art the whole bag of tricks that can be used for various metals are carried out paraffin removal, does not repeat them here.
Adopt deoiling step can remove grease, the dirt of zirconium-base amorphous alloy matrix surface and the clean buffing wax that do not eliminate, make decorative coating have the good surface appearance effect and make this decorative coating and the sticking power of zirconium-base amorphous alloy matrix surface better.The method of oil removing can adopt and well known to a person skilled in the art the whole bag of tricks that can be used for various metals are carried out oil removing, for example can adopt Solvent degreasing, electrochemical deoiling, electrolytic degreasing or ultrasonic wave oil removing.Preferably adopt electrochemical deoiling in the present invention.
Adopt the etch step can remove oxide film, oxide skin and the corrosion product of zirconium-base amorphous alloy matrix surface.Generally speaking, for the etch of other metal, adopt sulfuric acid, hydrochloric acid, phosphoric acid, nitric acid or hydrofluoric acid to carry out usually.And for the zirconium-base amorphous alloy matrix among the present invention, use these acid all can't remove the oxide film on surface, oxide skin and corrosion product, the present inventor is through discovering extensively and profoundly, even to the zirconium-base amorphous alloy matrix use " chloroazotic acid (and the colourless liquid that mixes by a volume concentrated nitric acid and three volumes concentrated hydrochloric acid; corrodibility is extremely strong; in addition can dissolve gold and platinum) " all can't remove the oxide compound of this matrix surface, but use fluoroboric acid that the zirconium-base amorphous alloy matrix is carried out etch and can remove the oxide compound of this matrix surface well fully, thereby can improve the sticking power of decorative coating and zirconium-base amorphous alloy matrix surface.
Therefore according to preparation method provided by the invention, in the preferred case, the method for described etch is included under 18-60 ℃ the temperature, described zirconium-base amorphous alloy matrix is immersed in the aqueous solution of fluoroboric acid 1-5 minute; In the aqueous solution of described fluoroboric acid, the concentration of fluoroboric acid is 1-20ml/L.Also need neutralize after immersing fluoborate solution, for example, the neutral method comprises soaks this matrix 3-10 minute in alkaline aqueous solution under 18-40 ℃.Described alkaline aqueous solution is one or more the aqueous solution in sodium hydroxide, potassium hydroxide, the yellow soda ash, and the concentration of described alkali is 10-30g/L.
In addition, except containing the metal zirconium element, also contain the metal or the non-metallic element that are insoluble to fluoroboric acid on a small quantity, therefore in the zirconium-base amorphous alloy matrix, with after the fluoroboric acid pickling often in this matrix surface dust, the ash of this grey black loosely is present in this matrix surface.Therefore, preferred underway and the time carry out ultrasonic vibration.Like this, in the spent acid of this matrix surface of neutralization, also shaken the ash of loose grey black.
According to preparation method provided by the invention, in the preferred case, the zirconium-base amorphous alloy matrix is carried out also soaking copper after the pre-treatment, the described copper that soaks makes the sticking power of decorative coating and this matrix surface stronger for the zirconium-base amorphous alloy matrix is carried out preplating.Described method of soaking copper can adopt the method that is used for other metal is soaked copper as well known to those skilled in the art, and for example this method is included under 18-40 ℃ the temperature, will immerse in the copper leaching liquid 1-5 minute through the zirconium-base amorphous alloy matrix after the pre-treatment.
Described copper leaching liquid can adopt and well known to a person skilled in the art the various copper leaching liquids that are used for other metal is soaked copper, preferred described copper leaching liquid is the aqueous solution that contains copper sulfate, fluoroboric acid, and in described copper leaching liquid, the concentration of copper sulfate is 5-100g/L, and the concentration of described fluoroboric acid is 1-10ml/L.
According to preparation method provided by the invention, in the preferred case, in order to improve the bonding force of coating leveling property and coating, the zirconium-base amorphous alloy matrix is soaked the laggard electroplating acid of copper copper, the method of described sour copper can be for well known to a person skilled in the art the various sour copper method that can be used for other metal, and for example, this method comprises with the stainless steel plate being anode, with the zirconium-base amorphous alloy matrix that soaks behind the copper is negative electrode, is 0.5-5A/dm in current density
2Condition under, in 5-60 ℃ sour copper liquid, electroplated 10-30 minute; Described sour copper liquid is for containing CuSO
47H
2O and the vitriolic aqueous solution, wherein CuSO
47H
2The concentration of O is 5-100g/L, and vitriolic concentration is 0.5-50g/L.Before acid coppering, this matrix is immersed in the dilute sulphuric acid carry out activation treatment earlier, to remove oxide film and the carbonic acid film that soaks the copper layer, the concentration of employed dilute sulphuric acid is 3-5 weight %.
In the preferred case, in carrying out above-mentioned electroplating process, all need water flushing sample 1 to 3 time between each step.
Adopt the mode of embodiment that the present invention is described in further detail below.
Embodiment 1
The zirconium-base amorphous alloy foundry goods (model vit.1) of sample: 5cm * 5cm * 2mm
1, pre-treatment
(1) mechanical polishing
Rough polishing ointment (SBT-600 model) and white essence throwing ointment (SBW-804 model) carry out mechanical polishing to sample in the yellow that the polishing machine (JM-101 model) of the close mechanical means of employing Dongguan City crystalline substance company limited production and Jiangmen outstanding person's profit are believed the production of rubbing down Materials Co., Ltd, at first carried out rough polishing 20 minutes, carried out finishing polish 15 minutes with 1500 rev/mins polishing wheel rotating speed then with 1200 rev/mins polishing wheel rotating speed.
Wash twice in sample after polishing with water.
(2) ultrasonic wave paraffin removal
Sample after the mechanical polishing was soaked 5 minutes under 50 ℃ condition in the Ultrasonic Cleaners of degreasing fluid is housed, carry out degreasing.The power of Ultrasonic Cleaners is 2.4Kw, contains 50 milliliters/liter of the powerful La Shui of removing (Shanghai base chemical industry (Shanghai) Co., Ltd., model is MTJ 6), sodium phosphate 15 grams per liters, yellow soda ash 15 grams per liters in the degreasing fluid.
Carry out washing sample with water twice behind the paraffin removal.
(3) electrochemical deoiling
Sample behind the paraffin removal is immersed 55 ℃ of middle oil removal treatment of electrochemical deoiling liquid (Science and Technology Ltd. starts) down 5 minutes, carry out ultrasonic vibration simultaneously.
Carry out washing sample with water twice behind the electrochemical deoiling.
(4) etch
Sample behind the electrochemical deoiling immersed to soak in 20 ℃ of fluoborate aqueous solutions down carried out the etch processing in 1 minute.The concentration of the fluoroboric acid in this fluoborate aqueous solution is 2ml/L.
Carry out washing sample with water twice after the etch.
Then this sample being immersed temperature is that 20 ℃ of concentration are in the 20g/L aqueous sodium hydroxide solution, vibrates under power is the ultrasonic wave of 2.4Kw simultaneously, handles 3 minutes.
Wash sample with water twice.
2, soak copper
Sample after the etch immersed soak copper processing 3 minutes in 20 ℃ of copper leaching liquids down.Contain copper sulfate 20g/L in this copper leaching liquid, fluoroboric acid 3ml/L, surplus is a water.
Then, wash sample with water twice.
3, sour copper
To soak sample behind the copper and immerse in the dilute sulphuric acid that concentration is 3 weight % and soak activation 1 minute, wash with water then twice.
Then this sample being inserted in the acid copper plating solution (production of Atotech company), is anode with the stainless steel plate, is negative electrode with the sample, is that 20 ℃, current density are 4A/dm at bath temperature
2Condition under, electroplated 10 minutes.
Wash sample with water twice.
4, bright nickel plating
The sample that will carry out behind the sour copper immerses in the light nickel plating bath (production of Atotech company), is anode with the nickel plate, is negative electrode with the sample, is that 20 ℃, current density are 4A/dm at bath temperature
2Condition under light-plated nickel 20 minutes.
Wash sample with water twice.
5, electroplate white chromium
Sample after the bright nickel plating is immersed in the chromium plating plating bath (production of wheat dolantin company limited), is anode with the tinsel plate, is negative electrode with the sample, is that 20 ℃, current density are 2A/dm at bath temperature
2Condition under chromium plating 3 minutes.
Wash sample with water twice, dry up, obtain thickness of coating and be 25 microns Zirconium-base non-crystalline alloy compound material.
Embodiment 2
The zirconium-base amorphous alloy foundry goods (model vit.1) of sample: 5cm * 5cm * 2mm.
1, pre-treatment
(1) mechanical polishing
Carry out the mechanical polishing process according to the method for describing among the embodiment 1.
(2) ultrasonic wave paraffin removal
Carry out the ultrasonic wave wax removing process according to the method for describing among the embodiment 1.
(3) electrochemical deoiling
Carry out the electrochemical deoiling process according to the method for describing among the embodiment 1.
(4) etch
Sample behind the electrochemical deoiling immersed to soak in 30 ℃ of fluoborate aqueous solutions down carried out the etch processing in 3 minutes.The concentration of the fluoroboric acid in this fluoborate aqueous solution is 5ml/L.
Carry out washing sample with water twice after the etch.
Then this sample being immersed temperature is that 25 ℃ of concentration are in the 20g/L aqueous sodium hydroxide solution, vibrates under power is the ultrasonic wave of 2.4Kw simultaneously, handles 3 minutes.
Wash sample with water twice.
2, soak copper
Sample after the etch immersed soak copper processing 2 minutes in 25 ℃ of copper leaching liquids down.Contain copper sulfate 30g/L in this copper leaching liquid, fluoroboric acid 5ml/L, surplus is a water.
Then, wash sample with water twice.
3, sour copper
To soak sample behind the copper and immerse in the dilute sulphuric acid that concentration is 4 weight % and soak activation 2 minutes, wash with water then twice.
Then this sample being inserted in the acid copper plating solution (production of Atotech company), is anode with the stainless steel plate, is negative electrode with the sample, is that 25 ℃, current density are 4A/dm at bath temperature
2Condition under, electroplated 20 minutes.
Wash sample with water twice.
4, silver-plated
The sample that will carry out behind the sour copper immerses in the silver-plated plating bath (lucky and prosperous Fine Chemical Co., Ltd), thinks anode, is negative electrode with the sample, is that 25 ℃, current density are 0.8A/dm at bath temperature
2Condition under silver-plated 10 minutes.
Wash sample twice then with water, and dry up.Obtain thickness of coating and be 19 microns Zirconium-base non-crystalline alloy compound material.
Embodiment 3
The zirconium-base amorphous alloy foundry goods (model vit.1) of sample: 5cm * 5cm * 2mm.
1, pre-treatment
(1) mechanical polishing
Carry out the mechanical polishing process according to the method for describing among the embodiment 1.
(2) ultrasonic wave paraffin removal
Carry out the ultrasonic wave wax removing process according to the method for describing among the embodiment 1.
(3) electrochemical deoiling
Carry out the electrochemical deoiling process according to the method for describing among the embodiment 1.
(4) etch
Sample behind the electrochemical deoiling immersed to soak in 20 ℃ of fluoborate aqueous solutions down carried out the etch processing in 5 minutes.The concentration of the fluoroboric acid in this fluoborate aqueous solution is 10ml/L.
Carry out washing sample with water twice after the etch.
Then this sample being immersed temperature is that 30 ℃ of concentration are in the 20g/L aqueous sodium hydroxide solution, vibrates under power is the ultrasonic wave of 2.4Kw simultaneously, handles 3 minutes.
Wash sample with water twice.
2, soak copper
Sample after the etch immersed soak copper processing 1 minute in 30 ℃ of copper leaching liquids down.Contain copper sulfate 25g/L in this copper leaching liquid, fluoroboric acid 2ml/L, surplus is a water.
Then, wash sample with water twice.
3, sour copper
To soak sample behind the copper and immerse in the dilute sulphuric acid that concentration is 5 weight % and soak activation 5 minutes, wash with water then twice.
Then this sample being inserted in the acid copper plating solution (production of Atotech company), is anode with the stainless steel plate, is negative electrode with the sample, is that 30 ℃, current density are 4A/dm at bath temperature
2Condition under, electroplated 30 minutes.
Wash sample with water twice.
4, imitation gold plating
The sample that will carry out behind the sour copper immerses in the imitative golden plating bath, is anode with graphite, is negative electrode with the sample, is that 30 ℃, current density are 4A/dm at bath temperature
2Condition under electroplated 3 minutes.
In imitative golden plating bath, contain cupric pyrophosphate (Cu
2P
2O
7) 10g/L, contain zinc sulfate (ZnSO
47H
2O) 30g/L contains potassium pyrophosphate (K
4P
2O
73H
2O) 120g/L contains tartrate first sodium (NaKC
4H
4O
64H
2O) 40g/L, surplus is a deionized water.
Sample soaked in sexavalent chrome passivating solution (production of wheat dolantin company limited) carried out passivation in 3 seconds.Wash sample twice then with water, and dry up.Obtain thickness of coating and be 26 microns Zirconium-base non-crystalline alloy compound material.
Performance evaluation
1, erosion resistance
Sample is placed in the salt fog cabinet, at 35 ℃ is that the sodium chloride aqueous solution of 5 weight % sprays this sample and takes out after 2 hours with concentration down, this sample being placed temperature is that 40 ℃, relative humidity are 80% climatic chamber again, observe this sample, the unusual time appears in the record specimen surface, the results are shown in the table 1.
2, wear resistance
The 7-IBB type RCA abrasion instrument that uses U.S. Nuo Man Instrument and Equipment Company to produce, with the power friction sample of 175 grams, when this sample exposed base material or base material distortion, the number of turns that the record rubber wheel rotates the results are shown in the table 1.
3, the sticking power of electrolytic coating and matrix
With being inspected sample after heating 1 hour under 160 ℃ the temperature, in air, be cooled to envrionment temperature.Observe failure phenomenon such as have or not peeling after the cooling of this sample, peel off.The results are shown in the table 1.
Principle is: the different differences that deform with the matrix metal thermal expansivity of coating, and the gas of electroplating process infiltration matrix is overflowed under heating state, coating is produced pressure, when this reactive force between coating and the matrix metal during greater than their bonding strength, peeling or plating exfoliation take place.
Table 1
| Erosion resistance (hour) | Wear resistance (circle) | Sticking power | Outward appearance | |
| Embodiment 1 | More than 240 | ??5000 | No peeling, peeling phenomenon | The silvery white coating of light |
| Embodiment 2 | More than 240 | ??4700 | No peeling, peeling phenomenon | The silvery white coating of light |
| Embodiment 3 | More than 240 | ??4500 | No peeling, peeling phenomenon | The golden yellow coating of light |
From the result shown in the table 1 as can be seen, the decorative appearance on the Zirconium-base non-crystalline alloy compound material surface of embodiment of the invention 1-3 is fine, very attractive in appearance, the erosion resistance of this matrix material and wear resistance are all good simultaneously, and the sticking power of the zirconium-base amorphous alloy matrix electrolytic coating surperficial with it is good.
Claims (11)
1, a kind of Zirconium-base non-crystalline alloy compound material, this matrix material comprises the zirconium-base amorphous alloy matrix, it is characterized in that, this matrix material also comprises attached to the metal plating on the described zirconium-base amorphous alloy matrix surface.
2, matrix material according to claim 1, wherein, the thickness of described metal plating is the 0.5-100 micron.
3, matrix material according to claim 1, wherein, the material of described metal plating is titanium, copper, nickel, palladium, silver, gold, tin, cobalt, chromium or the alloy of at least 2 kinds of metals in them.
4, matrix material according to claim 3, wherein, the material of described metal plating is the alloy of at least 2 kinds of metals in titanium, copper, zinc and the nickel.
5, the preparation method of the described Zirconium-base non-crystalline alloy compound material of a kind of claim 1 is characterized in that, this method is included in the zirconium-base amorphous alloy matrix surface and forms metal plating.
6, method according to claim 5, wherein, described method at zirconium-base amorphous alloy matrix surface formation metal plating comprises the formation decorative coating, the formation method of described decorative coating comprises, the zirconium base alloy matrix is immersed in the electrolyte solution, with described matrix as negative electrode, will electroplated metal as anode, be 0.5-5A/dm in current density
2, the temperature of electrolyte solution is to electroplate 1-30 minute under 20-80 ℃ the condition; Described electrolyte solution is one or more the aqueous solution of vitriol, muriate, phosphoric acid salt or nitrate in titanium, copper, nickel, palladium, silver, gold, tin, cobalt and the chromium; The described alloy of wanting electroplated metal to be selected from titanium, copper, nickel, palladium, silver, gold, tin, cobalt, chromium or at least 2 kinds of metals in them.
7, preparation method according to claim 6, wherein, describedly carry out pre-treatment at zirconium-base amorphous alloy matrix body, described pre-treatment comprises etch, the method of described etch is included under 18-60 ℃ the temperature, described zirconium-base amorphous alloy matrix is immersed in the aqueous solution of fluoroboric acid 1-5 minute.
8, preparation method according to claim 7, wherein, in the aqueous solution of described fluoroboric acid, the concentration of fluoroboric acid is 1-20ml/L.
9, preparation method according to claim 7, wherein, the described method that forms metal plating at the zirconium-base amorphous alloy matrix surface also comprise the zirconium-base amorphous alloy matrix carried out pre-treatment after and form decorative coating before soak copper, described method of soaking copper is included under 18-40 ℃ the temperature, will immerse in the copper leaching liquid 1-5 minute through the zirconium-base amorphous alloy matrix after the pre-treatment.
10, preparation method according to claim 9, wherein, described copper leaching liquid is the aqueous solution that contains copper sulfate, fluoroboric acid, and in described copper leaching liquid, the concentration of copper sulfate is 5-100g/L, the concentration of described fluoroboric acid is 1-10ml/L.
11, preparation method according to claim 9, wherein, the described method that forms metal plating at the zirconium-base amorphous alloy matrix surface also comprise the zirconium-base amorphous alloy matrix soaked copper after and form decorative coating before carry out sour copper, the method of described sour copper comprises with the stainless steel plate being anode, with the zirconium-base amorphous alloy matrix that soaks behind the copper is negative electrode, is 0.5-5A/dm in current density
2Condition under, in 5-60 ℃ sour copper liquid, electroplated 10-30 minute; Described sour copper liquid is for containing the copper sulfate and the vitriolic aqueous solution, and wherein the concentration of copper sulfate is 5-100g/L, and vitriolic concentration is 0.5-50g/L.
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