CN101605657B - Backing sheet for photovoltaic and method for repairing same - Google Patents
Backing sheet for photovoltaic and method for repairing same Download PDFInfo
- Publication number
- CN101605657B CN101605657B CN200880002193.7A CN200880002193A CN101605657B CN 101605657 B CN101605657 B CN 101605657B CN 200880002193 A CN200880002193 A CN 200880002193A CN 101605657 B CN101605657 B CN 101605657B
- Authority
- CN
- China
- Prior art keywords
- backboard
- layer
- polyester
- lamination
- fluorinated copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title description 16
- 238000000576 coating method Methods 0.000 claims description 41
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 40
- 239000011248 coating agent Substances 0.000 claims description 39
- 229920001577 copolymer Polymers 0.000 claims description 27
- 229920000728 polyester Polymers 0.000 claims description 25
- 239000000377 silicon dioxide Substances 0.000 claims description 19
- 239000000853 adhesive Substances 0.000 claims description 16
- 230000001070 adhesive effect Effects 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
- 238000004544 sputter deposition Methods 0.000 claims description 15
- 238000003475 lamination Methods 0.000 claims description 14
- 239000003431 cross linking reagent Substances 0.000 claims description 13
- 229920002313 fluoropolymer Polymers 0.000 claims description 12
- 239000004811 fluoropolymer Substances 0.000 claims description 12
- -1 alkyl vinyl ethers Chemical class 0.000 claims description 11
- 239000003960 organic solvent Substances 0.000 claims description 9
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical compound FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims description 8
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 8
- 229910052582 BN Inorganic materials 0.000 claims description 5
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 229920000515 polycarbonate Polymers 0.000 claims description 5
- 239000004417 polycarbonate Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229920000106 Liquid crystal polymer Polymers 0.000 claims description 4
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 4
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 229910017083 AlN Inorganic materials 0.000 claims description 2
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 239000010410 layer Substances 0.000 claims 11
- 235000012239 silicon dioxide Nutrition 0.000 claims 2
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 claims 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims 1
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 claims 1
- 229910052570 clay Inorganic materials 0.000 claims 1
- 239000011229 interlayer Substances 0.000 claims 1
- 239000012860 organic pigment Substances 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 239000008393 encapsulating agent Substances 0.000 abstract description 5
- 230000014759 maintenance of location Effects 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 230000001681 protective effect Effects 0.000 abstract description 2
- 230000006866 deterioration Effects 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 25
- 239000000049 pigment Substances 0.000 description 19
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 18
- 239000000463 material Substances 0.000 description 15
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 229920002620 polyvinyl fluoride Polymers 0.000 description 12
- 239000002904 solvent Substances 0.000 description 11
- 229910052581 Si3N4 Inorganic materials 0.000 description 8
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 8
- 229920000554 ionomer Polymers 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000565 sealant Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 7
- 230000004888 barrier function Effects 0.000 description 6
- 239000008199 coating composition Substances 0.000 description 6
- 229920001897 terpolymer Polymers 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 150000002513 isocyanates Chemical class 0.000 description 4
- 229920006267 polyester film Polymers 0.000 description 4
- 230000008439 repair process Effects 0.000 description 4
- 229920004439 Aclar® Polymers 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 3
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229920001780 ECTFE Polymers 0.000 description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- SIXOAUAWLZKQKX-UHFFFAOYSA-N carbonic acid;prop-1-ene Chemical compound CC=C.OC(O)=O SIXOAUAWLZKQKX-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 229940113088 dimethylacetamide Drugs 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 239000013557 residual solvent Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920002397 thermoplastic olefin Polymers 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- ODACNRQBNVVGAI-UHFFFAOYSA-N 5-[2-chloroethyl(2-fluoroethyl)amino]-6-methyl-1h-pyrimidine-2,4-dione Chemical compound CC=1NC(=O)NC(=O)C=1N(CCF)CCCl ODACNRQBNVVGAI-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000005779 cell damage Effects 0.000 description 1
- 208000037887 cell injury Diseases 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical compound C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229940117958 vinyl acetate Drugs 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/12—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a coating with specific electrical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0216—Coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/049—Protective back sheets
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Laminated Bodies (AREA)
- Photovoltaic Devices (AREA)
Abstract
The present invention provides a protective backing sheet for photovoltaic modules. The backing sheets of the current invention possess excellent weather resistance, heat resistance, color retention, adhesion between layers and encapsulant, and scratch resistance. The backing sheet can minimize the deterioration in the performance of the solar module due to moisture permeation. It also can achieve desirable photoelectric conversion efficiency over a long period of time. Additionally the described backing sheet, or alternately referred to backskin, can be made in an aesthetically pleasing form.
Description
Background of invention
Description of Related Art
The solar energy that photovoltaic module uses is one of most promising alternative energy source of oil, and in this century, oil is just depleted.But, to produce and the process of installation photovoltaic component remains costliness.Typical photovoltaic module is made up of the protective seal at the transparent front sheet of glass or flexibility, solar cell, sealant, protectiveness backboard, covering assemblies edge and the aluminum frame that covers sealing.As shown in Figure 1, front panel 10, backboard 20 and sealant 30 and 30 ' are designed to protect the impact of array 40 not climate factor, humidity, mechanical load and impact.And these parts provide the electrical isolation for personal security and electric leakage.Protectiveness backboard 20 is intended to the service life and the efficiency that improve photovoltaic module, thus reduces the unit power cost of photovoltaic electric current.In order to realize the Transmission light of height, front panel 10 and sealant 30 and 30 ' must be transparent, but must be highly opaque to obtain backboard attractive in appearance, and must have highly reflective for functional object backboard.For a lot of reasons, expect that solar module is frivolous, these reasons comprise and are particularly useful for building (with the photovoltaic (PV) of building one) and the weight applied of space reduces, and Military Application (be combined in soldier's equipment etc. in).In addition, frivolous element assists is in reducing costs.The reduction of the quantity of material used also makes this technology " green " more, thus has saved more natural resources.
The present arrangements manufacturing frivolous solar cell is in conjunction with frivolous backboard.But back cladding material also must have certain moisture resistance and infiltrate to prevent moisture and water, and the capped parts of such as photovoltaic element, wire and electrode may be caused to get rusty for the infiltration of moisture and water and solar cell damages.In addition, backboard should provide electrical isolation, mechanical protection, certain ultraviolet (UV) stability, to the tack of sealant and the ability connecting output line.
The protectiveness backboard normally laminated product of current use.Fig. 2 provides the diagram of typical laminate backing sheet 20.Lamination by as the most common of critical component is
polyvinyl fluoride rete 22, polyester (PET) rete 24 and ethene-vinyl acetate (EVA) copolymer rete 26 form.EVA layer 26 bonds with the sealant layer 30 in assembly and is used as dielectric layer, and EVA layer 26 has good moisture barrier characteristics.The size of this EVA is stable.White EVA makes power significantly improve.Polyester layer 24 is very firm, has excellent dielectricity, dimensionally stable, and also has good moisture barrier characteristics.Polyvinyl fluoride layer 22 is used as very weather-proof layer.
Even if these retes have met the performance standard in the actual use procedure of required test neutralization, but still there is some limitation, as high in cost and acquisition
rete is restricted.Such as PVF
eCTFE
at the temperature that cannot raise in environment temperature or appropriateness, such material is processed with another shortcoming of the material of the prior art of other fluoropolymer.Such as, use high boiler (usually, to orientation
use dimethyl acetamide, right
sP uses propene carbonate) make PVF rete by casting technique by diffusion.The boiling point of dimethyl acetamide is 164-166 DEG C, and the boiling point of propene carbonate is 200 DEG C.Must 160 DEG C and 90% or higher solvent under spread.Due to the thermal instability of PVF resin, higher temperature can not be accepted: the melting Sum decomposition temperature of PVF resin too close to such an extent as to PVF can decompose in the process of curing.Therefore, exist
there is residual solvent in rete always.DuPont is reported in all orientations
dimethylacetylamide (DMAC) residual quantity of 0.05wt% to 1.0wt% is there is in PVF rete.
Or, ECTFE
rete is made by melt extruding technique at 350 DEG C-375 DEG C.Therefore, ECTFE
rete can not easily mix with pigment, clay etc., and this rete is also expensive.
5th, 741, No. 370 United States Patent (USP)s propose, manufacture and assembly installation cost can be reduced by thermoplastic olefin is used as backsheet material, described thermoplastic olefin comprises two kinds of different ionomeric combinations, the such as combination of sodium ionomer and zinc ionomer, and this combination is described to produce synergy, and the water vapor barrier property of back veneer material is increased on the barrier properties of any single ionomer component by described synergy.This patent also discloses the use of the ionomer encapsulant with two ionomer tergite.
But National Renewable Energy laboratory (NREL) report, ionomer resin comprises methacrylic acid that is free and that combine, and its needs use stainless steel instrument in melt-processed process, thus add manufacturing cost.PVMaT in the subcontract report of Solarex photovoltaic module manufacturing technology year improves (PVMaT Improvements in the Solarex PhotovoltaicModule Manufacturing Technology Annual Subcontract Report), on April 30 ,-1999 years on the 5th May in 1998, National Renewable Energy Laboratory, in January, 2000 NREL/SR-520-27643.
Technical field
The present invention relates to photovoltaic module.More specifically, the present invention relates to protectiveness backboard.
Summary of the invention
The invention provides the protectiveness backboard for photovoltaic module.Backboard of the present invention has excellent weatherability, heat resistance, colour retention, tack between layer and sealant and resistance to marring.The degeneration of the solar module performance caused because moisture infiltrates can be down to minimum by this backboard.This backboard can also obtain the long-term photoelectric transformation efficiency of expectation.In addition, described backboard, or claim tergite, form attractive in appearance can be made with.
By adopting liquid coating application technology then to make backboard of the present invention by EVA compound, and can require to prune this backboard according to application.And, adopt the benefit of the solar module of described backsheet material to comprise the remarkable reduction of manufacturing cost.
In tergite, use liquid coating formulations to overcome one or more defects of the tergite of prior art.Tergite can be made thinner than current obtainable tergite.Backsheet material comprises the material more easily obtained, and described material can be processed at ambient temperature or at the temperature of appropriateness rising.Can directly by these liquid coating application on the second layer of lamination, thus do not need adhesive.In addition, can easily the additive of these liquid coatings with such as pigment, clay etc. be mixed.
In an aspect, describe the backboard for photovoltaic module, it has the layer comprising the crosslinkable amorphous fluoropolymer dissolving in organic solvent.This fluoropolymer can be the fluorinated copolymer of CTFE (CTFE) and one or more alkyl vinyl ethers comprising the alkyl vinyl ether with reactive OH function.This backboard can comprise the crosslinking agent mixed with this fluorinated copolymer.
This backboard also can comprise the extra play of such as polyester layer.Another act one example, this backboard also can comprise EVA layer.Other optional extra play can comprise following one: with polyester, Merlon, polyolefin, polyurethanes, liquid crystal polymer, aclar, aluminium, the sputtering aluminum oxide polyester of EVA coextrusion, sputter silica or silicon nitride polyester, sputtering aluminum oxide polycarbonate and sputter silica or silicon nitride Merlon.
Can by or by adhesive, the fluorinated copolymer layer of backboard is not coated to the layer of polyester layer or other type.And, this fluorinated copolymer layer can be applied to single or multiple lift.In one embodiment, the thickness of fluorinated copolymer layer is less than 1 Mill.In another aspect, the thickness of fluorinated copolymer layer is greater than 1 Mill.In another embodiment, backboard comprises silica.
Another aspect of the present invention describes the backboard for photovoltaic module.This backboard has the layer of the copolymer of the alkene comprising tetrafluoroethene (TFE) and have reactive OH function.This backboard also can comprise the crosslinking agent mixed with this fluorinated copolymer.In one embodiment, the thickness of fluorinated copolymer layer is less than 1 Mill.In another embodiment, the thickness of fluorinated copolymer layer is greater than 1 Mill.In another embodiment, backboard also has ionomer layer.
Fluorinated copolymer can be the terpolymer that maybe can comprise one or more fluorochemical monomers.In one embodiment, described terpolymer comprises vinylidene fluoride, tetrafluoroethene and hexafluoropropene.
And described backboard also can comprise the extra play of such as polyester layer.By adhesive or by adhesive, fluorinated copolymer layer is not coated to polyester layer.The combination of individual layer or transparent with coloured multilayer described fluorinated copolymer layer can be applied.Can corona discharge be carried out to polyester film extraly or carry out chemical treatment to improve adhesive force.Described backboard also can comprise EVA layer.In another embodiment, described backboard comprises silica.Other optional extra play can comprise following one: Merlon, with polyester, polyolefin, polyurethanes, liquid crystal polymer, aclar, aluminium, the sputtering aluminum oxide polyester of EVA coextrusion, sputter silica or silicon nitride polyester, sputtering aluminum oxide polycarbonate, sputter silica or silicon nitride Merlon, sputter aluminium oxide
sputtering aluminium oxide
sputtering silica or silicon nitride Lumiflon, sputtering silica or silicon nitride
In one aspect of the method, the method for the backboard of maintenance photovoltaic module is provided.Described method is included in the step in region when needing repairing, preparation being coated to described backboard, and described preparation comprises CTFE (CTFE) and the amorphous fluorinated copolymer of one or more alkyl vinyl ethers comprising the alkyl vinyl ether with reactive OH function.In one embodiment, under environment temperature or the appropriate temperature raised, described preparation is coated to described backboard.In another embodiment, described preparation is made up of the first component and second component, and described first and second components are arranged in the twin-chamber syringe being equipped with static mixer, and are applied by the coating unit being connected to described injector.
In one embodiment, the first component of described preparation is made up of the mixture of crosslinking agent and solvent, and second component is made up of the mixture of solvent and fluorinated copolymer.
Accompanying drawing explanation
In order to understand the present invention better, can with reference to accompanying drawing.
Fig. 1 shows the expanded view of the parts of typical photovoltaic module.
Fig. 2 shows an embodiment of typical backing sheet.
The chart of Fig. 3 demonstrates compared with the backboard based on Tedlar, based on the backboard of Lumiflon as the tensile strength of the function of " damp and hot " exposed amount.
The chart of Fig. 4 demonstrates compared with the backboard based on Tedlar, based on the backboard of Lumiflon as the elongation at break of the function of " damp and hot " exposed amount.
The chart of Fig. 5 demonstrates the backboard based on Lumiflon and compares with the UV stability of the backboard based on Tedlar.
Fig. 6 shows and the example of repairing the coating unit that external member uses jointly.
Detailed Description Of The Invention
The invention provides the protectiveness backboard for photovoltaic module.In one embodiment, by adopting liquid coating application technology to make backboard.In a preferred embodiment, after liquid coating application, EVA compound is used.Can according to coating need the combination process of EVA is adjusted.
In another embodiment, encapsulant is provided.This encapsulant has the excellent colour retention of excellent weatherability, heat resistance, UV stability, adhesive force to other parts of back veneer material and solar module, electrical separation and not yellowing.By spraying, described encapsulant is applied, thus the vacuum lamination process eliminated at elevated temperatures and reduce manufacturing cost.
In another aspect, employing " repairing external member " is provided to be torn or otherwise impaired tergite carries out the method for keeping in repair fast and easily.Described method and repair external member and allow to apply on the backboard of breakage when not adopting extreme temperature and pressure attractive in appearance and firmly coating.And such " repairing external member " allows to carry out at the scene fast and effective maintenance.The coating repairing external member coating is used to meet all requirements of EC60664-1, IEC61730, IEC1646 and ASTMF1249 according to method of the present invention.In preferred embodiment in this aspect of the invention, by using the twin-chamber syringe and coating unit coating " repairing " preparation that are equipped with static mixer.
Liquid coating formulations used in the present invention is applied at the temperature that can raise in environment temperature or appropriateness.The key component of liquid coating formulations is fluoropolymer, preferably dissolve in organic solvent or water dispersible, crosslinkable amorphous fluoropolymer.
The preferred ingredient of coating comprises the fluorinated copolymer with following structure:
And
The fluoropolymer that can use in liquid preparation includes but not limited to
(Asahi Glass) and
(Daikin).Other material comprises FluoroPel
tMand FluoroThane
tM(Cytonix Corporation), FluoroLink
tMpolymer Modifiers (Solvay Solexis).Annexing ingredient in liquid coating formulations comprises the inorganic material of crosslinking agent, catalyst, solvent and optional filler and such as boron nitride (Zyp Coatings).
A kind of particularly preferred fluoropolymer is developed in nineteen eighty-two by Asahi Glass
it is the amorphous fluorinated copolymer of CTFE (CTFE) and some specific alkyl vinyl ethers (VE).
The polymer that is combined as of alkyl vinyl ether monomer and oh group provides significant characteristic, as the compatibility of solubility, pigment, cross-linking reaction, adhesive force, hardness and flexibility to substrate.
Another preferred fluoropolymer is
resin (Daikin), it is the copolymer of tetrafluoroethene (TFE) and the alkene dissolving in organic solvent.More specifically,
be the tetrafluoroethene based on solvent and the copolymer of alkene with reactive OH function, and be prepared as the base resin in high performance paints and coating.
In another embodiment, fluoropolymer is terpolymer.Terpolymer can comprise one or more different fluorochemical monomers.Such as, terpolymer comprises vinylidene fluoride, tetrafluoroethene and hexafluoropropene.Dyneon
tMtHV is a kind of such terpolymer, and provides the combination of performance advantage, as low processing temperature, is bonded to elastomer and based on the ability of the plastics of hydrocarbon, flexibility and optical transparence.As transparent rete, can by Dyneon
tMtHV is used as front panel to replace glass.Add pigment and provide the rete that can be used as the backboard of photovoltaic module.
Can be used for including but not limited to such as following organic solvent with the organic solvent forming liquid coating formulations in the present invention: methyl ethyl ketone (MEK), acetone, methyl iso-butyl ketone (MIBK) (MIBK), toluene, dimethylbenzene, methyl alcohol, isopropyl alcohol, ethanol, heptane, ethyl acetate, isopropyl acetate, n-butyl acetate, n-butanol or their mixture.Preferred solvent comprises dimethylbenzene, cyclohexanone and methyl ethyl ketone (MEK).Following solvent is suitable: all components are all dissolved in wherein, and the low retention to being enough to make residual solvent in coating of boiling point is minimum or remove.
Can be used for including but not limited to titanium dioxide, carbon black, perylene pigment, pigment, dyestuff, mica, polyamide powder, boron nitride, zinc oxide, aluminium oxide, silica, UV absorbent, corrosion inhibitor and drier with the optional pigment and filler that form protective coating in the present invention.A kind of preferred pigment is titanium dioxide Ti-
r-105 (DuPont).A kind of preferred hydrophobically modified silica is Cab-o-sil TS 720 (Cabot).The function of pigment, UV absorbent and corrosion inhibitor is to provide opacity and weatherability.
ultrafine is preferred polyamide powder (Arkema Inc), and can be involved for reduction gloss.Carbon black, pigment and dyestuff can be comprised to change the color of backboard.Mica can be comprised to provide anti-flammability.Boron nitride, aluminium nitride and/or aluminium oxide can be comprised to improve heat conductivity.Preferably comprise
nanoclays (Southern Clay Products), 3M
tMglass Bubbles and drier are to improve moisture barrier characteristics.Silica and/or boron nitride can be comprised to improve dielectric property.Also can comprise silica to reduce gloss and to provide anti-flammability.
Formed in protective coating preferably adopt crosslinking agent with obtain be insoluble to organic solvent do not peel off rete.Preferred crosslinking agent includes but not limited to DuPont
organic titanate, silane, isocyanates and melamine.Because these retes can use usually out of doors more than 30 years, therefore preferred aliphat isocyanates is to guarantee weatherability.
Such as, can by mixing
solution, pigment, crosslinking agent and catalyst preparing based on
the liquid preparation of coating composition.Utilize dibutyl tin laurate to accelerate the cross-linking reaction between Lumiflon (polyol) in organic solvent and isocyanates.By mixing preferably 3 to 80 parts and even more preferably about 46 parts by weight
solution, 5 to 60 parts of (more preferably about 17 parts) pigment by weight and 20 to 80 parts (more preferably about 32 parts) organic solvent (mixtures of MEK and dimethylbenzene or cyclohexanone) by weight prepare this composition.
Backboard also can comprise extra play.By or by adhesive, extra play is not coated to fluorinated copolymer layer.Optional extra play can comprise such as following one: the coextrusion layer of the polymer of polyester, EVA, Merlon, polyolefin, polyurethanes, acrylic resin, polyimides, polyamide, liquid crystal polymer, aclar, aluminium, sputtering aluminum oxide polyester, sputtering silica or silicon nitride polyester, sputtering aluminum oxide polycarbonate, sputtering silica or silicon nitride Merlon, clear fluoropolymer and clear fluorocopolymers, such as polyester and EVA, and polybutadiene.
Embodiment 1
Example 1 illustrates of the present invention based on
the preparation of protectiveness backboard.For in this embodiment
for LF200 level, the xylene solution (200g) as 60% obtains from Asahi Glass.The Ti-obtained from DuPont for the pigment in this embodiment
r-105 (76.2g).Crosslinking agent obtains from Bayer
n3300 (21.4g).By use high-shear mixer by pigment with
solution mixes, and then adds solvent and crosslinking agent.
Then preparation is applied.By applicator roll, liquid preparation is transferred to rete from disk container, and by Mayer Rod, the coating weight obtaining expectation is measured to liquid preparation.Coating is directly coated in
(DuPont) on (5 Mill) polyester film.Without any need for adhesive, and do not use any adhesive in this embodiment yet.With 10-120g/m
2, preferred 30-90g/m
2and more preferably 30-45g/m
2coating weight coating coating.
Dry paint is by 60-65%'s by weight
the pigment composition of by weight 35%.In this embodiment, by using polyester-urethane composite adhesive, will by based on
preparation cover polyester film and EVA (vinylacetate containing 4%) compound.Then by obtained lamination and EVA sealant and assembly vacuum compound.
Table 1 show with
backboard prepared by SP is compared, based on
with
the characteristic of protectiveness backboard.
Table 1
Table 2 show with by orientation
the backboard of preparation is compared, based on
the characteristic of protectiveness backboard.
Table 2
These results suggest that, thickness be 0.5 Mill based on
with
coating to demonstrate than thickness be the nondirectional of 1 Mill
the barrier properties (lower moisture permeability and the proof voltage of Geng Gao) that SP is more excellent, and thickness is the nondirectional of 1 Mill
the thickness of SP is
with
the twice of layer thickness.In addition, based on
backboard than based on
backboard more cost-effective.
Table 3 show with by orientation
the backboard of preparation is compared, based on
the weatherability of protectiveness backboard.Sample is placed in 85 DEG C and 85% relative humidity (" damp and hot ") condition under environmental chamber 2000 hours.Peel off test, the test of ASTM D 3359 cross cut tape adhesion and ASTM D882 and measure adhesive force between outer and polyester by bonding according to ASTM D 903-98, as the tensile strength of the function of " damp and hot " exposed amount and elongation at break, estimate outer field weatherability.Adopt following abbreviation in table 3: TB tears combination (tear bond); 5B=loses the coating of 0%; 4B=loses the coating lower than 5%; 3B=loses the coating of 5-15%; 2B=loses the coating of 15-35%; IB=loses the coating of 35%-65%; And 0B=loses the coating more than 65%.
Table 3
As shown in table 3, thin based on
backboard weatherability with based on orientation
backboard suitable.
Fig. 3 and 4 shows, as " damp and hot " exposed amount function based on
the tensile strength of backboard and elongation at break than based on
backboard much lower.
In order to assess UV stability, sample is placed in Atlas ci 4000 Xenon weather-ometer 4600 hours being equipped with xenon arc lamp, periodic measurement L
*a
*b
*.B
*-value represents " yellowing " of material.As shown in Figure 5, based on
backboard UV stability with based on
backboard suitable.
Embodiment 2
Example 2 illustrates of the present invention based on
the preparation of Alternate embodiments of protectiveness backboard.For embodiment 2
for LF 200 grades, the xylene solution (150g) as 60% obtains from Asahi Glass.Pigment for this embodiment is the Ti-obtained from DuPont
r-105 (57g).Hydrophobically modified silica for this embodiment is the Cab-o-sil TS-720 (10g) obtained from Cabot.Crosslinking agent used obtains from Bayer
n3300 (16g).Catalyst for this embodiment is the dibutyl tin laurate MEK solution of 0.1% (0.15g) obtained from Aldrich.By using high-shear mixer by pigment and silica and
solution mixes, and then adds solvent, crosslinking agent and catalyst.
Then preparation is applied.By applicator roll, liquid preparation is transferred to rete from disk container, and carries out by Mayer Rod the coating weight measuring to obtain expectation.Coating is directly coated in
(DuPont) on (5 Mill) polyester film.Without any need for adhesive, and do not use any adhesive in this embodiment yet.With 10-120g/m
2, preferred 30-90g/m
2and more preferably 30-45g/m
2coating weight coating coating.
Table 4
As shown in table 4, comprise add silica embodiment 2 without silica based on
backboard basis on produce the increase of 45V (maximum permissible voltage), and based on
backboard basis on produce the increase of 40V.
Embodiment 3
Example 3 illustrates another embodiment of the present invention (based on
" repairing assembly " preparation) preparation.
Repairing kit formulation based on Lumiflon is preferably prepared by the preparation of the component (A and B) comprising two kinds of isolation.
Component A is made up of the mixture of crosslinking agent (Isocyanate Desmodur N3300 (2.5g, Bayer)) and solvent (being dimethylbenzene in this embodiment).
B component is made up of the mixture of solvent, pigment and fluorinated copolymer.In this embodiment, B component is prepared as follows.By dispersant (Disperbyk 111 (0.25g, BYK-Chemie)) and 14.1g's
lF 200 dimethylbenzene, Ti-
r101 pigment (10g, DuPont),
the mixture mixing of 2002D (4.7g, Arkema Inc) and coloring agent (Microlith Blue, Microlith Yellow, Microlith Brown and Orasol Black).Different coloring agents can be added to mate the color of the backboard be torn.
In use, component A and B is placed in the twin-chamber syringe being equipped with static mixer.On the broken parts of backboard, preparation is applied by using coating unit.Can obtain a kind of such coating unit from BrandywineAssociates, Fig. 6 shows this coating unit, and in the drawings, blender is labeled as 50, and coating unit threshold marker is 52, and the repairing kit formulation of coating is labeled as 54.But, the coating unit of any type of such as brush can be used to apply preparation.
Repair assembly and be applicable to a variety of backboard, such as those are by such as
backboard prepared by the material of the prior art of/polyester/EVA or backboard prepared in accordance with the present invention.Shelf depreciation test has been carried out to the preparation be coated to based on the backboard of Tedlar.The result of this test is summarized in table 5.
The result of table 5. shelf depreciation test
In addition, by cross cut tape test ASTM D 3359-97, said preparation demonstrates the excellent adhesive attraction of the bottom to back veneer material, i.e. 5B.
Exist the apparent disclosed various amendment of the present invention of those skilled in the art, adjustment and application, and the application is intended to comprise these embodiments.Although by some preferred embodiment, invention has been described, and the gamut of these embodiments is determined by referring to the scope of appending claims.
Be incorporated to reference to mode entirety quote as proof herein various publications, patent and patent application disclosure.
Claims (9)
1., for the backboard lamination of photovoltaic module, it comprises:
Comprise skin that is that dissolve in organic solvent and/or water dispersible, crosslinkable amorphous fluoropolymer, described skin is coated on one or more layers Polymer interlayers, wherein said amorphous fluoropolymer be CTFE (CTFE) with the fluorinated copolymer of one or more alkyl vinyl ethers and with not containing the liquid coating application of adhesive in described intermediate layer; And on the face relative with skin in one or more layers intermediate layer described lamination comprise the EVA of coextrusion and the layer of polyester.
2. backboard lamination as claimed in claim 1, it comprises the crosslinking agent mixed with described fluorinated copolymer further.
3. backboard lamination as claimed in claim 2, described intermediate layer comprises further and comprises one or more layer following: polyester, Merlon, polyolefin, polyurethanes, liquid crystal polymer, polytrifluorochloroethylene and aluminium.
4. backboard lamination as claimed in claim 3, described polyester is selected from sputtering aluminum oxide polyester and sputtering silicon dioxide polyester.
5. backboard lamination as claimed in claim 3, described Merlon is selected from sputtering aluminum oxide polycarbonate and sputtering silicon dioxide polycarbonate.
6. the backboard lamination as described in claim arbitrary in claim 3-5, is wherein coated to described polyester layer when adhesive-free by the described layer comprising described fluorinated copolymer.
7. backboard lamination as claimed in claim 6, the thickness of wherein said fluorinated copolymer layer is less than 1 Mill.
8. backboard lamination as claimed in claim 6, the thickness of wherein said fluorinated copolymer layer is greater than 1 Mill.
9. the backboard lamination as described in claim arbitrary in claim 3-5, it comprises silica, titanium oxide, aluminium oxide, zinc oxide, beryllium oxide, mica, clay, boron nitride, aluminium nitride, titanium nitride, carbon black and/or organic pigment further.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US90198207P | 2007-02-16 | 2007-02-16 | |
| US60/901,982 | 2007-02-16 | ||
| US12/011,962 US20080264484A1 (en) | 2007-02-16 | 2008-01-30 | Backing sheet for photovoltaic modules and method for repairing same |
| US12/011,962 | 2008-01-30 | ||
| PCT/US2008/001351 WO2008143719A2 (en) | 2007-02-16 | 2008-02-01 | Backing sheet for photovoltaic modules and method for repairing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101605657A CN101605657A (en) | 2009-12-16 |
| CN101605657B true CN101605657B (en) | 2015-01-14 |
Family
ID=41091652
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200880002193.7A Expired - Fee Related CN101605657B (en) | 2007-02-16 | 2008-02-01 | Backing sheet for photovoltaic and method for repairing same |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP2121311A4 (en) |
| JP (1) | JP2010519742A (en) |
| KR (2) | KR20130027038A (en) |
| CN (1) | CN101605657B (en) |
| AU (1) | AU2008253723A1 (en) |
| CA (1) | CA2673018A1 (en) |
| MX (1) | MX2009008763A (en) |
| TW (1) | TW200933902A (en) |
| WO (1) | WO2008143719A2 (en) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9735298B2 (en) | 2007-02-16 | 2017-08-15 | Madico, Inc. | Backing sheet for photovoltaic modules |
| US8507029B2 (en) | 2007-02-16 | 2013-08-13 | Madico, Inc. | Backing sheet for photovoltaic modules |
| EP2309551B1 (en) * | 2008-06-23 | 2014-08-13 | Asahi Glass Company, Limited | Backsheet for solar cell module and solar cell module |
| TW201041131A (en) * | 2009-03-09 | 2010-11-16 | Sekisui Chemical Co Ltd | Underside protective sheet for solar cell, solar cell module, and gas-barrier film |
| EP2430665A4 (en) * | 2009-05-14 | 2015-08-05 | Madico Inc | Heat dissipating protective sheets and encapsulant for photovoltaic modules |
| JP2010278256A (en) * | 2009-05-28 | 2010-12-09 | Ma Packaging:Kk | Back sheet for solar cell module |
| KR101293898B1 (en) * | 2009-12-07 | 2013-08-06 | 주식회사 엘지화학 | Backsheet for solar cell having high reflectivity |
| FR2955117B1 (en) * | 2010-01-14 | 2012-06-01 | Arkema France | FILM BASED ON ACRYLIC FREE ODOR-FREE POLYMERIC POLYMER FOR PHOTOVOLTAIC APPLICATION |
| JP5540828B2 (en) * | 2010-03-30 | 2014-07-02 | 旭硝子株式会社 | Manufacturing method of back sheet for solar cell module and manufacturing method of solar cell module |
| KR101519183B1 (en) * | 2010-05-06 | 2015-05-11 | 주식회사 엘지화학 | Multi-layered Sheet and Method for Preparing the same |
| US20130092235A1 (en) * | 2010-06-03 | 2013-04-18 | Kaneka Corporation | Back sheet for solar battery and solar battery module |
| JP5484293B2 (en) * | 2010-11-12 | 2014-05-07 | 富士フイルム株式会社 | SOLAR CELL BACK SHEET, MANUFACTURING METHOD THEREOF, AND SOLAR CELL MODULE |
| KR101721577B1 (en) * | 2011-01-06 | 2017-03-31 | 에스케이씨 주식회사 | Backsheet for solor cells having Polyvinylidene fluoride film |
| JP5700415B2 (en) * | 2011-02-05 | 2015-04-15 | 三菱樹脂株式会社 | Polyester film for solar cell back surface protection material |
| KR101371856B1 (en) * | 2011-03-17 | 2014-03-10 | 주식회사 엘지화학 | Environmentally friendly backsheet for solar cell and preparation method thereof |
| JP2012231029A (en) * | 2011-04-26 | 2012-11-22 | Fujifilm Corp | Protective sheet for solar cell and method for producing the same, and solar cell module |
| KR101349734B1 (en) * | 2011-04-26 | 2014-01-16 | 율촌화학 주식회사 | Back sheet for solar cell module and solar cell module comprising the same |
| WO2013008917A1 (en) * | 2011-07-14 | 2013-01-17 | 富士フイルム株式会社 | Protective sheet for solar cells, method for producing same, back sheet for solar cells, and solar cell module |
| CN103765599A (en) * | 2011-08-29 | 2014-04-30 | 法国圣戈班玻璃厂 | Thin-film photovoltaic module with hydrophobic rear-side coating |
| TW201313848A (en) * | 2011-09-30 | 2013-04-01 | Eternal Chemical Co Ltd | Packaging material for solar cell module and uses thereof |
| KR101315936B1 (en) * | 2011-12-09 | 2013-10-08 | 율촌화학 주식회사 | Back sheet for solar cell module, solar cell module having the same and method for manufacturing the same |
| JP5753110B2 (en) | 2012-02-03 | 2015-07-22 | 富士フイルム株式会社 | Back surface protection sheet for solar cell module and solar cell module |
| JP6200131B2 (en) | 2012-03-28 | 2017-09-20 | 富士フイルム株式会社 | Polymer sheet, back surface protection sheet for solar cell, and solar cell module |
| TW201349515A (en) * | 2012-05-16 | 2013-12-01 | Saint Gobain Performance Plast | Photovoltaic backsheet |
| CN103794670A (en) * | 2014-02-28 | 2014-05-14 | 英利能源（中国）有限公司 | Flexible backplane and photovoltaic module |
| MX2016015038A (en) * | 2014-05-16 | 2017-04-11 | Basf Coatings Gmbh | Use of a coating agent for coating the rear face film of a photovoltaic module and photovoltaic module. |
| KR20170027956A (en) | 2015-09-03 | 2017-03-13 | 엘지전자 주식회사 | Solar cell module |
| CN106206850B (en) * | 2016-08-25 | 2018-03-13 | 迅力光能（昆山）有限公司 | The restorative procedure of flexible thin-film solar cell |
| KR102219790B1 (en) * | 2017-04-18 | 2021-02-24 | 엘지전자 주식회사 | Solar cell module |
| JP6655828B2 (en) * | 2017-10-31 | 2020-02-26 | パナソニックＩｐマネジメント株式会社 | Solar cell module |
| JP7035653B2 (en) | 2018-03-14 | 2022-03-15 | 大日本印刷株式会社 | Transparent protective sheet for solar cell modules and its manufacturing method |
| KR102250714B1 (en) | 2019-09-25 | 2021-05-11 | 청주대학교 산학협력단 | Method for repairing crystalline solar cell module using separation mask |
| KR102285924B1 (en) | 2019-09-25 | 2021-08-04 | 청주대학교 산학협력단 | Method for repairing crystalline solar cell module using photolithography process |
| KR102285925B1 (en) | 2019-12-20 | 2021-08-04 | 청주대학교 산학협력단 | Method for repairing crystalline solar cell module using laser irradiation |
| CN114262551B (en) * | 2022-01-13 | 2022-10-28 | 中国乐凯集团有限公司 | Coating and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060280922A1 (en) * | 2005-06-13 | 2006-12-14 | 3M Innovative Properties Company | Fluoropolymer containing laminates |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2756082B2 (en) * | 1994-04-28 | 1998-05-25 | キヤノン株式会社 | Method of manufacturing solar cell module |
| JP3397443B2 (en) * | 1994-04-30 | 2003-04-14 | キヤノン株式会社 | Solar cell module and method of manufacturing the same |
| US6207236B1 (en) * | 1996-06-19 | 2001-03-27 | Daikin Industries, Ltd. | Coating composition, coating film, and method for producing coating film |
| US5741370A (en) * | 1996-06-27 | 1998-04-21 | Evergreen Solar, Inc. | Solar cell modules with improved backskin and methods for forming same |
| JPH10256580A (en) * | 1997-03-13 | 1998-09-25 | Daikin Ind Ltd | Material for solar cell |
| KR100542783B1 (en) * | 1997-06-23 | 2006-01-11 | 다이낑 고오교 가부시키가이샤 | Tetrafluoroethylene copolymer and use thereof |
| JP2000091610A (en) * | 1998-09-17 | 2000-03-31 | Dainippon Printing Co Ltd | Cover film for solar battery and its manufacture and solar battery module using the same |
| JP2001094135A (en) * | 1999-09-21 | 2001-04-06 | Canon Inc | Solar cell module |
| US6422777B1 (en) * | 2000-08-24 | 2002-07-23 | Foster-Miller, Inc. | Protective coating underwater applicator |
| JP4177590B2 (en) * | 2002-02-27 | 2008-11-05 | 株式会社 デンギケン | Electrical / electronic insulation sheet |
| JP2004214641A (en) * | 2002-12-16 | 2004-07-29 | Dainippon Printing Co Ltd | Filler sheet for solar cell module, and the solar cell module using the same |
| JP5127123B2 (en) * | 2005-07-22 | 2013-01-23 | ダイキン工業株式会社 | Solar cell backsheet |
-
2008
- 2008-02-01 KR KR1020137001154A patent/KR20130027038A/en not_active Application Discontinuation
- 2008-02-01 JP JP2009550092A patent/JP2010519742A/en active Pending
- 2008-02-01 MX MX2009008763A patent/MX2009008763A/en unknown
- 2008-02-01 WO PCT/US2008/001351 patent/WO2008143719A2/en active Application Filing
- 2008-02-01 CN CN200880002193.7A patent/CN101605657B/en not_active Expired - Fee Related
- 2008-02-01 CA CA002673018A patent/CA2673018A1/en not_active Abandoned
- 2008-02-01 KR KR1020097013982A patent/KR101388381B1/en not_active IP Right Cessation
- 2008-02-01 AU AU2008253723A patent/AU2008253723A1/en not_active Abandoned
- 2008-02-01 EP EP08794278A patent/EP2121311A4/en not_active Withdrawn
- 2008-10-07 TW TW097138537A patent/TW200933902A/en unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060280922A1 (en) * | 2005-06-13 | 2006-12-14 | 3M Innovative Properties Company | Fluoropolymer containing laminates |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2008143719A3 (en) | 2009-02-26 |
| AU2008253723A1 (en) | 2008-11-27 |
| CA2673018A1 (en) | 2008-11-27 |
| CN101605657A (en) | 2009-12-16 |
| KR101388381B1 (en) | 2014-04-28 |
| JP2010519742A (en) | 2010-06-03 |
| KR20130027038A (en) | 2013-03-14 |
| EP2121311A4 (en) | 2012-10-31 |
| MX2009008763A (en) | 2009-10-08 |
| TW200933902A (en) | 2009-08-01 |
| WO2008143719A2 (en) | 2008-11-27 |
| EP2121311A2 (en) | 2009-11-25 |
| KR20090121273A (en) | 2009-11-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101605657B (en) | Backing sheet for photovoltaic and method for repairing same | |
| CN101909768B (en) | Backing sheet for photovoltaic modules | |
| US9735298B2 (en) | Backing sheet for photovoltaic modules | |
| US8507029B2 (en) | Backing sheet for photovoltaic modules | |
| EP2372782A1 (en) | Protective sheet for back surface of solar cell module | |
| JP5540840B2 (en) | Solar cell backside sealing sheet | |
| JP2015513478A (en) | Weatherproof composite for flexible thin film photovoltaic and light emitting diode devices | |
| JP2013516073A (en) | High performance backsheet for photovoltaic applications and method of manufacturing the same | |
| KR101350557B1 (en) | Back sheet for solar cell module and solar cell module comprising the same | |
| JP2010232513A (en) | Back protective sheet for solar cell module, and solar cell module | |
| JP2024050833A (en) | Transparent protective sheet for solar cell modules | |
| JP5692706B2 (en) | Film for solar cell backside sealing sheet | |
| EP2732970A1 (en) | Module structure | |
| JP2010272834A (en) | Backsheet for solar cell and solar cell module using the same | |
| JP2017183618A (en) | Backside protection sheet for solar battery module | |
| CN117304831A (en) | Externally-attached building glass film, and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150114 Termination date: 20170201 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |