CN101604606A - 废灯管资源化回收方法 - Google Patents
废灯管资源化回收方法 Download PDFInfo
- Publication number
- CN101604606A CN101604606A CNA2009100407271A CN200910040727A CN101604606A CN 101604606 A CN101604606 A CN 101604606A CN A2009100407271 A CNA2009100407271 A CN A2009100407271A CN 200910040727 A CN200910040727 A CN 200910040727A CN 101604606 A CN101604606 A CN 101604606A
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- Prior art keywords
- metal
- mercury
- sent
- fragmentation
- separating
- Prior art date
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- 239000002699 waste material Substances 0.000 title claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 25
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims abstract description 22
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- 238000006062 fragmentation reaction Methods 0.000 claims abstract description 12
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- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound 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- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound 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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/60—Glass recycling
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/82—Recycling of waste of electrical or electronic equipment [WEEE]
Abstract
本发明涉及一种废灯管资源化回收方法，其方法工艺是：将废灯管投入破碎机中在负压状态下进行破碎，把破碎后的物料送入接料箱：接料箱上部的抽风机将废气吸入冷凝系统中对汞和荧光粉实现分离，其中，汞通过真空加热器实现回收；破碎后的玻璃和金属物料送入磁选机中从而实现玻璃和金属的分离；将分离后的金属送入洗涤机，通过三级逆流喷淋洗涤回收金属。本发明能有效回收荧光粉、汞、金属。实现废水、废液、废气达标排放。
Description
废灯管资源化回收方法
技术领域
本发明涉及一种废灯管资源化回收方法。 技术背景
目前，处置含汞废灯管和废灯泡的方法大致有三种：加硫填埋法、焚烧法、 回收利用法。
(1) 加硫填埋是一种比较简单有效的方法,根据美国电器制造者协会的报告 介绍，经过近十年的实验研究，尚未发现填埋对人类健康有明显危险，而美国 环境保护署对填埋场的浸出液的检测也很少检出汞的水平超过饮用水的标准。
(2) 对于焚烧法，根据美国电器制造者协会的报告介绍，效果不理想，含汞 废灯管和废灯泡中的90%的汞将进入大气中。
(3) 国外废旧灯管回收利用的处理技术主要有直接破碎分离和切端吹扫分 离。直接破碎分离工艺的处理流程是:先将灯管整体粉碎洗净干操后回收汞和玻 璃管的混合物，然后经焙烧、蒸发并凝结回收粗汞，再经汞生产装置精制后供 荧光灯用汞，每支灯管回收汞10〜20mg。该工艺的特点是结构紧凑、占地面积 小、投资省，但荧光粉较难被再利用。
切端吹扫分离工艺是先将灯管的两端切掉，吹入高压空气将含汞的荧光粉 吹出后收集，再通过真空加热器回收汞，其生成汞的纯度为99.9%。该技术可 有效地将可再回收利用的稀土荧光粉分类收集，但投资较大，推广性差。 发明内容
所要解决的技术问题：本发明针对现有技术不足，提供了一种成本低、能 有效回收荧光粉、汞、金属的废灯管资源化回收方法。
技术方案：发明废灯管资源化回收方法，其方法工艺是：
将废灯管投入破碎机中在负压状态下进行破碎，把破碎后的物料送入接料箱;接料箱上部的抽风机将废气吸入冷凝系统中对汞和荧光粉实现分离， 其中，汞通过真空加热器实现回收；
破碎后的玻璃和金属物料送入磁选机中从而实现玻璃和金属的分离；
将分离后的金属送入洗涤机，通过三级逆流喷淋洗涤回收金属。
本发明与现有技术相比优点是：本发明针对我国每年产生数量庞大的废旧 灯管，以及破碎后无序排放的金属汞，缺乏有效的处理手段而提供了一种成本 低、能有效回收荧光粉、汞、金属的废灯管资源化回收方法。
本发明通过研制出特定的粉碎及吸收净化设备、洗涤机、分选器。实用性 及分选效率高，且克服了废灯管处理中的汞污染，并经过生产试运行证实其经
济实用。废玻璃回收利用率98%;废铝等金属回收利用率100%;重金属汞无害化 处理率99.9%。实现废水、废液、废气达标排放；废渣安全填埋。
具体实施方式
一种废灯管资源化回收方法工艺如下：
将废灯管投入破碎机中在负压状态下进行破碎，把破碎后的物料送入接料 箱；接料箱上部的抽风机将废气吸入冷凝系统中对汞和荧光粉实现分离，其中， 汞通过真空加热器实现回收，生成纯度可达99.9%，气体达标排空。破碎后的
玻璃和金属物料送入磁选机中从而实现玻璃和金属的分离；将分离后的金属送
入洗涤机，通过三级逆流喷淋洗涤回收金属。洗涤机利用振动输送原理，达到 水洗和输送的目的。
Claims (1)
1、一种废灯管资源化回收方法，其特征在于其方法工艺如下： 将废灯管投入破碎机中在负压状态下进行破碎，把破碎后的物料送入接料箱； 接料箱上部的抽风机将废气吸入冷凝系统中对汞和荧光粉实现分离，其中，汞通过真空加热器实现回收； 破碎后的玻璃和金属物料送入磁选机中从而实现玻璃和金属的分离； 将分离后的金属送入洗涤机，通过三级逆流喷淋洗涤回收金属。
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| CN112264037A (zh) * | 2020-10-21 | 2021-01-26 | 优赛环保工程(天津)有限公司 | 利用废弃led灯珠制备臭氧分解催化剂的方法、由该方法制备的臭氧分解催化剂及其应用 |
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