CN101598824A - A kind of soft light enhancement anti-dazzle reflecting mirror - Google Patents

A kind of soft light enhancement anti-dazzle reflecting mirror Download PDF

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CN101598824A
CN101598824A CNA2009100630838A CN200910063083A CN101598824A CN 101598824 A CN101598824 A CN 101598824A CN A2009100630838 A CNA2009100630838 A CN A2009100630838A CN 200910063083 A CN200910063083 A CN 200910063083A CN 101598824 A CN101598824 A CN 101598824A
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layer
thickness
formula
sheen
light
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CN101598824B (en
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朱文
仝大利
杨君友
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Huazhong University of Science and Technology
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Huazhong University of Science and Technology
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Abstract

Soft light enhancement anti-dazzle reflecting mirror provided by the invention is characterized in that: it comprises and is followed successively by by the different refractivity material preparation the 1st to 5 layer transparent glass layer, selects reflection horizon, intermediate layer, sheen enhancement layer and substrate layer; Utilize the interference cooperative effect between the multi-layer nano film, by changing the optics geometric thickness of each nano thin-film medium composition (promptly changing the refractive index of film) and rete, the light that reflects from different film surfaces is interfered mutually, realization is to the selection reflection of incident light, with ultraviolet light harmful in the headlight high light to human eye, high-energy photons absorbs the filtering segregation to be fallen, and will strengthen the useful sheen of human eye.This soft light enhancement anti-dazzle reflecting mirror has overcome other glare reduction techniques and has reduced the bottleneck problem that causes sharpness to descend owing to reflectivity, can be used for making the glareproof mirror of automobile, also can develop, can solve the problem in the many safety and the energy (as the sun power) utilization equally to glass of entire vehicle and covil construction direction.

Description

A kind of soft light enhancement anti-dazzle reflecting mirror
Technical field
The present invention relates to a kind of catoptron, be specifically related to a kind of soft light enhancement anti-dazzle reflecting mirror, be a kind of interference cooperative effect principle of multi-layer nano film and the mirror assembly of selective control light reflectance, be particularly useful for glareproof mirror as the vehicles.
Background technology
Along with the development of society, rearview mirror is as the important safety attachment of automobile, and its performance requirement is also more and more higher.There are some disadvantages in traditional rear-view mirror, as reflectively dazzle the eyes, misty rain is fuzzy and dust contamination etc.According to statistics, in China, because the traffic hazard that the rearview mirror defective causes accounts for 30% of traffic hazard sum; In the U.S., this ratio is 20%; On highway, this ratio is then up to 70%.In these rearview mirror defectives, reflective harmfulness maximum of dazzling the eyes, it can not only make the people cause of short duration yctalopia, increase braking distance, and easily causes driver's fatigue for a long time.Experiment test proves that with the average braking Distance Calculation of 97km/h, braking distance is 42m during free from glare, is 80m when dazzle is arranged, and has totally had more one times.This shows that anti-dazzle is for driver's importance.
Consumer's (driver) strong appealing has caused the attention of countries in the world automobile dealer height, has all dropped into a large amount of man power and materials at present more feasible technology and technology are improved, and advanced in performance rearview mirror new product appears on the market one after another.Wherein, with dielectric sandwich type glareproof mirror market share maximum.This rearview mirror anti-glare technology is a folder dielectric low light level gel between two blocks of glass, the bright-dark degree that changes the control rearview mirror by the power of electric current.Two photoelectric sensors are housed on the automatic anti-glare rearview mirror detect back car light light intensity automatically, when intensity surpasses the dazzle standard of setting, then by switching on to glass mirror, make it become blackish green by normal bright state, thereby specular reflectance is descended, reach the purpose of eliminating dazzle.When light source away from after, stop the energising, rearview mirror then becomes normal bright color again.From it principle of work we as can be seen this rearview mirror still have some self defective.At first, this rearview mirror is to eliminate dazzle by the colour of lens deepening, after the colour of lens deepening, also cause eyeglass that the reflectivity of light is reduced when eliminating dazzle, sharpness descends, make the driver can't clearly see road, pedestrian and the vehicle of back clearly, thereby lost the effect of rearview mirror as automobile important safety annex.Secondly, this rearview mirror need be differentiated extraneous lamp and force light source by photoelectric sensor, will force the equation of light value input photoresistance of light source and extraneous lamp, thereby reach the ability that the eyeglass current switching is injected in control.This design concept influence factor is too many, except external high light, also wait whether control its work by gate light, body light and backup lamp, so this rearview mirror failure rate is higher, back investigation difficulty breaks down, except judging whether glareproof mirror itself has the problem, also to check fuse, body light circuit and backup lamp circuit lamp, maintenance is trouble very.At last, this rear-view mirror complexity, cost is higher.At present, 120 dollars~200 dollars/every of such rearview mirror price is unwell to domestic vast automobile consumption colony.
The anti-dazzle inside rear-view mirror of another money, its anti-dazzle principle are to utilize two reflectings surface of a prismatic lens, and the primary reflection surface that is of reflection plated film is arranged, and its reflectivity is 70%, and the outside surface of glass is a subreflector, and its reflectivity is 4%.When the driver drives by day, rearview mirror is placed the primary reflection surface position, can make the driver clearly see the situation at automobile rear like this.The driver is when night running, can switch the position that handle places rearview mirror subreflector by switching, when the vehicle in high light directive the place ahead of back vehicle, because the reflectivity of subreflector is very little, therefore only there is very small percentage light to be reflected, the high light that other overwhelming majority is dazzle the eyes all falls by the subreflector scattering, thereby has prevented to dazzle the eyes sense because of what emergency light reflex produced.Switch by switching handle two working positions of the major and minor reflecting surface of this glareproof mirror, has increased driver's operational sequence.Simultaneously, because the reflectivity of subreflector is less, the minute surface sharpness descends when driving at night, has influence on traffic safety.
In addition, also have some rearview mirrors behind the visor two-way mirror, to plate TiO 2The isosol product coating, thus realize the purpose (being commonly called as " Lan Jing ") of anti-dazzle, but this coating process is comparatively complicated, adopts sol-gel process to be prepared usually.There are some problems in the rete of this method preparation: 1) cause film to chap easily in drying and the roasting process, even come off; 2) stress influence of film has limited the thickness of film; 3) film thickness and homogeneity are wayward; 4) film quality of the factor affecting such as fluctuation of the viscosity of colloidal sol, temperature, concentration and substrate preparation; 5) adhesion of rete relatively poor (see Chen Hong, Chinese folk art forms, Gao Jinyue, etc. sol-gel process prepares automobile rearview mirror. Physical Experiment, 2004,11:16~18).And difficult control (seeing Chinese patent literature CN2704507) of the aberration of this blue mirror stability.
In sum,, seek a kind of new anti-dazzle method and technology, make it when eliminating dazzle, still can optionally control light reflectance, keep the minute surface sharpness for overcoming some drawbacks of the current glareproof mirror that generally uses; Simultaneously technology is simple, and stable performance with low costly just seems particularly important.
Summary of the invention
The objective of the invention is to overcome the shortcoming of above-mentioned prior art and a kind of soft light enhancement anti-dazzle reflecting mirror is provided, this catoptron has the anti-dazzle effect of selection, when effectively eliminating glare phenomenon, will strengthen the useful sheen reflectivity of human eye selectively, thereby improve the minute surface sharpness.
Soft light enhancement anti-dazzle reflecting mirror provided by the invention is characterized in that: it comprises and is followed successively by by the different refractivity material preparation the 1st to 5 layer transparent glass layer, selects reflection horizon, intermediate layer, sheen enhancement layer and substrate layer; The optical path difference δ on the upper and lower surface of j layer jSatisfy the requirement of following formula (I) one of them expression formula to the formula (IV):
δ j = 2 d j n j 2 - n j + 1 2 sin 2 i = kλ Formula (I)
δ j = 2 d j n j 2 - n j + 1 2 sin 2 i + λ 2 = kλ Formula (II)
δ j = 2 d j n j 2 - n j + 1 2 sin 2 i = ( 2 k + 1 ) λ / 2 Formula (III)
δ j = 2 d j n j 2 - n j + 1 2 sin 2 i + λ 2 = ( 2 k + 1 ) λ / 2 Formula (IV)
In the formula, the sequence number of j presentation layer, value is 2,3 or 4 respectively, d jBe the thickness of j layer, n J-1, n j, n J+1Be respectively j-1, the refractive index of j and j+1 layer, λ is a lambda1-wavelength, and i represents the incident angle of light, and k is a natural number;
As min (n J-1, n J+1)<n j<max (n J-1, n J+1) time, the optical path difference of j layer satisfies formula (I) or formula (III);
Work as n j<min (n J-1, n J+1) or n j>max (n J-1, n J+1) time, the optical path difference of j layer satisfies formula (II) or (IV).
As first kind of optimal way of technique scheme, wherein, selecting the thickness in reflection horizon is 20~25nm, and material is the potpourri of aluminium and chromium, and wherein the atom percentage content of Al is 30%~40% in the potpourri; The material of intermediate layer is a ruthenium, and it interpenetrates with the element of selecting reflection horizon and sheen enhancement layer respectively, and the thickness between the infiltration area is 8~12nm; The thickness of sheen enhancement layer is 40~45nm, and its material is the potpourri of silver and gold, and wherein the atom percentage content of Ag is 90%~95%.
As second kind of optimal way of technique scheme, wherein, selecting the material in reflection horizon is TiO 2, thickness is 35~40nm; The thickness of intermediate layer is 8~12nm, and material is In 2O 3And SnO 2Potpourri, In in the potpourri wherein 2O 3Content be 90%~95%; The thickness of sheen enhancement layer is 4~8nm, and its material is the potpourri of silver and gold, and wherein the atom percentage content of Ag is 90%~95%.
As the third optimal way of technique scheme, wherein, selecting the material in reflection horizon is TiO 2, thickness is 25~30nm; The thickness of intermediate layer is 20~25nm, and material is In 2O 3And SnO 2Potpourri, In in the potpourri wherein 2O 3Content be 90%~95%; The material of sheen enhancement layer is a chromium, and thickness is 20~25nm.
A kind of soft light enhancement anti-dazzle reflecting mirror provided by the invention, be applied on the rearview mirror of the vehicles, it comprises: utilize the interference cooperative effect between the multi-layer nano film, adjust the act of interference of different-waveband spectrum by the optics geometric thickness (promptly changing the optical path difference of the light of different wave length) that changes each nano thin-film medium composition (promptly changing the refractive index of light in medium) and each rete at the multilayer interface in the generation reflection of multilayer interface, and then the wavelength location of adjustable lay the grain spectrum reflectivity maximal value and minimum value, realization is to the selection reflection of incident light, with ultraviolet light harmful in the headlight high light to human eye, high-energy photons absorbs the filtering segregation to be fallen, and will strengthen human eye useful gold-tinted or blue light.Like this, the driver can see road, pedestrian, the vehicle of back clearly under the light background of soft warmth.This sheen anti-dazzle reflecting mirror need not electric current of make-and-break, need not photoelectric sensor, also need not switching and switches handle, and very easy to use, cost is lower, almost the zero failure rate.And this sheen glare reduction techniques has also overcome the bottleneck problem that other glare reduction techniques causes sharpness to descend owing to the reflectivity reduction in anti-dazzle process.Have the anti-dazzle effect of selection owing to this sheen is anti-dazzle, it also will strengthen the useful sheen of human eye, so can not cause the decline of minute surface sharpness when the ultraviolet light that human eye is harmful, high-energy photons absorption filtering segregation are fallen.
Description of drawings
Fig. 1 is a structural principle synoptic diagram of the present invention;
Fig. 2 is the X diffraction spectrum of the prepared nano-multilayer film of embodiment 1;
Fig. 3 is embodiment 1 a nano-multilayer film cross section field emission scanning electron microscope photo;
Fig. 4 is that embodiment 1 adopts plasma etching+photoelectron spectroscopy technology for detection to distribute and stoicheiometry along the element on the depth of film direction;
Fig. 5 detects the situation of change of this rearview mirror assemblies at ultraviolet-visible light-infrared range of spectrum internal reflection rate curve for embodiment 1 adopts the ultraviolet-visible photometer;
Fig. 6 is embodiment 2 nano-multilayer film cross section field emission scanning electron microscope photos;
Fig. 7 is that embodiment 2 adopts plasma etching+photoelectron spectroscopy technology for detection to distribute and stoicheiometry along the element on the depth of film direction;
Fig. 8 detects the situation of change of this rearview mirror assemblies at ultraviolet-visible light-infrared range of spectrum internal reflection rate curve for embodiment 2 adopts the ultraviolet-visible photometer;
Fig. 9 is embodiment 3 nano-multilayer film cross section field emission scanning electron microscope photos;
Figure 10 is that embodiment 3 adopts plasma etching+photoelectron spectroscopy technology for detection to distribute and stoicheiometry along the element on the depth of film direction;
Figure 11 detects the situation of change of this rearview mirror assemblies at ultraviolet-visible light-infrared range of spectrum internal reflection rate curve for embodiment 3 adopts the ultraviolet-visible photometer.
Embodiment
The present invention is further detailed explanation below in conjunction with accompanying drawing and example.
The present invention is according to the interference cooperative effect principle between the multi-layer nano film, and wherein the collocation of each layer assembly thin film dielectrics composition and each rete optics geometric thickness are determined according to the required sheen wave band of practical application.Its multi-layer nano film is selected anti-dazzle interference cooperative effect structural principle synoptic diagram as shown in Figure 1.Catoptron of the present invention comprises five layers of part, and wherein the bottom is a mirror substrate layer 5, mainly plays the effect (can select whether to add this substrate layer by layer according to practical situations) of supporting reflex mirror; Be sheen enhancement layer 4 on the substrate layer, its thin film dielectrics composition can be metals such as silver, gold, rhodium, chromium, and this type of superficial film mainly plays the effect that sheen is strengthened to the sheen partial reflectance height in the visible light; Be intermediate layer 3 on the sheen enhancement layer, this intermediate layer can be metal or SnO such as iridium, osmium, ruthenium 2, ITO sulls such as (tin indium oxides), this type of intermediate layer is interfered the cooperative effect except playing, mainly as the adjuvant of top layer metal, to improve hardness, tensile strength, wearing quality, corrosion stability and the fusing point of superficial film; For selecting reflection horizon 2, its medium composition can be aluminium, chromium, TiO on the intermediate layer 2, SnO 2, ITO films such as (tin indium oxides).This type of rete mainly reduces the reflectivity of ultraviolet light and high-energy photons, improves the reflectivity to especially soft gold-tinted of low frequency spectral coverage and blue light simultaneously; Outermost layer is a transparent glass layer 1.
When incident light A is radiated at this mirror assembly surface, will reflect in each nano thin-film laminar surface, and the behavior of film surface reflection of incident light depends on that film is to the interference of light effect.According to film equal inclination interference principle, the optical path difference δ on the upper and lower surface of thin layer satisfies the requirement of one of them expression formula in the formula (I) to (IV).
The difference of formula (I), formula (III) and formula (II), formula (IV) is whether will add λ/2, whether to consider that promptly the additional light path difference will see the medium refraction index of j-1 layer and j+1 layer and the relation between the refractive index three of j layer own: when film refractive index is between upper and lower surface dielectric refractive index, do not consider the additional light path difference; And when film refractive index all is greater than or less than the upper and lower surface dielectric refractive index of film, just need add λ/2.According to thin film interference effects, if the optical path difference on the upper and lower surface of thin film dielectrics is the integral multiple of incident wavelength, promptly k λ (k=1,2....) (corresponding to formula (I) or (II)) then produces bright field image; If (2k+1) λ/2 (k=0,1,2....) (corresponding to formula (III) or (IV)) then produces dark field image, frosting phenomenon occurs.When the polychromatic light that contains different-waveband is incident on the multi-layer nano film surface, the similarly effect of interference all can take place in every layer film surface, by optics geometric thickness and the thin film dielectrics composition (promptly changing the refractive index of film) of adjusting each rete, the light that reflects from different film surfaces is interfered mutually, the light reflection of certain wave band color is strengthened, and the light of some wave band color disappear.Promptly utilize and interfere cooperative effect B, realization is to the selection reflection of incident light, and with ultraviolet light harmful to human eye in the headlight high light, high-energy photons filtering segregation is fallen, and will the useful sheen of human eye be strengthened, the final viewed reflected light C of human eye is the free from glare source of soft warmth.
In the embodiment that investigates sheen enhancing control method, further describe characteristics of the present invention and effect by three kinds of embodiment.But this implementation detail only is used to illustrate characteristics of the present invention but not is used to limit to category of the present invention.
Embodiment 1
As shown in Figure 1, this soft light enhancement anti-dazzle reflecting mirror comprises five layer assemblies, comprises clear glass 1 from top to bottom successively, selects reflection horizon 2, intermediate layer 3, sheen enhancement layer 4 and substrate layer 5.Clear glass 1 is a back surface mirror; Selecting the thickness in reflection horizon 2 is 24nm, and by the aluminium and the chromium unity of possession bottom, the content of Al is 35%, and the content of Cr is 65% (being atomic percent); Selecting after the reflection horizon 2 is intermediate layer 3, and element is a ruthenium, and thickness is 9nm, but this intermediate layer does not occupy independently geometric space, but interpenetrates with bottom and outer field element, forms a thin transition bed; Sheen enhancement layer 4 is between intermediate layer 3 and substrate layer 5, and thickness is 42nm, and by the silver and the golden unity of possession, wherein the content of Ag is 95%, and the content of Au is 5%.
Selection reflection horizon 2 among this embodiment and sheen enhancement layer 4 are the common mixing binary film of forming of two kinds of elements.This type of mixes the binary film and adopts the intermediate frequency reactive magnetron sputtering method to be prepared.Adopt the intermediate frequency reactive magnetron sputtering method to prepare this two constituent elements mixing thin layer two kinds of methods are arranged: 1) utilize composition target; As prepare when selecting reflection horizon 2, this target is composited by aluminium and two kinds of monometallics of chromium.This composition target adopts hot pressed sintering or plasma activated sintering method to be prepared from, and goes hot pressed sintering or plasma activated sintering after in advance aluminium and two kinds of monometallic powder of chromium fully being mixed with certain atomic percent (being about 1: 2) again.In the intermediate frequency reaction magnetocontrol sputtering, use the plasma emission spectroscopy method for supervising that sputter procedure is controlled, and then regulate the stoichiometric proportion of film.Based on the content of control chromium, the content of aluminium is auxilliary during sputter, and the content that finally reaches Al is 35%, and the content of Cr is 65%, and thickness is 24nm.2) adopt two targets; Adopt two kinds of monometallic targets simultaneously, and substrate layer is rotated, the about atomic layer of each layer obtains this two constituent elements mixed membranous layer through mutual deposition, by the speed of control basal plate layer rotation and the time that stops on each monometallic target the content of two constituent elements realized control.Adopted second method in this example.Before plated film, in advance various metal targets are all placed in the furnace chamber of magnetron sputtering apparatus, prepare by the above second method and to select after the two constituent element mixed film layers of reflection horizon, substrate layer is rotated to the top of ruthenium target, the aura starting the arc rapidly, sputter ruthenium atom intermediate layer 3 on substrate layer.Because substrate layer is selected still to have residual temperature behind the film of reflection horizon in deposition, therefore the ruthenium atom of intermediate layer can fully spread, form and do not occupy independently geometric space, with the interpenetrative thin transition bed of element of selecting reflection horizon 2 and sheen enhancement layer 4, its thickness is 9nm.Then, substrate is rotated between silver-colored target and gold target, prepare sheen enhancement layer 4, to control the content of silver, the content of gold is auxilliary during sputter, and the content that finally reaches Ag is 95%, and the content of Au is 5%, and thickness is 42nm.Adopted means analysis such as XRD, FE-SEM, the XPS tissue of nano-multilayer film, pattern and structure.Fig. 2 is the X diffraction spectrum of prepared nano-multilayer film; Fig. 3 is a nano-multilayer film cross section field emission scanning electron microscope photo; Fig. 4 distributes and stoicheiometry along the element on the depth of film direction for adopting plasma etching+photoelectron spectroscopy technology for detection.Fig. 5 detects the situation of change of this catoptron at ultraviolet-visible light-infrared range of spectrum internal reflection rate curve for adopting the ultraviolet-visible photometer.From reflectance spectrum as can be seen: this selection anti-dazzle reflecting mirror has multi-layer nano film interference cooperative effect, and its maximum reflectivity has reached 77%~78%, and the maximum reflection spectral wavelength is 555nm, optionally the soft gold-tinted in the visible light is strengthened.
Glareproof mirror coating often adopts sol-gel process at present, and there are some problems in this method.Compare with sol-gel process, it is simple to adopt magnetron sputtering method to prepare the nano-multilayer film operation, and is easy to realize large-scale continuous production.The thin layer surface smoothing that adopts the intermediate frequency reactive magnetron sputtering method to be coated with, better in large tracts of land scope theca interna homogeneity; And the film adhesion height is in conjunction with firm; Thickness is easy to accurate control simultaneously.
Embodiment 2
The soft light enhancement anti-dazzle reflecting mirror structural representation of present embodiment preparation comprises five layer assemblies still as shown in Figure 1, is made up of five kinds of nano thin-film media altogether, is respectively Ag, Au, In 2O 3, SnO 2And TiO 2Medium.Wherein ground floor is a glass-mirror 1.The thickness in the selection reflection horizon 2 of glass below is 36nm, by TiO 2Occupy.At TiO 2 Intermediate layer 3 thickness of below are 10nm, are In 2O 3And SnO 2The unity of possession, wherein In 2O 3Content be 90%, SnO 2Content be 10%.Sheen enhancement layer 4 thickness are 4nm, and by silver and golden unity of possession outermost layer, the content of Ag is 95%, and the content of Au is 5%.After the sheen enhancement layer 4 is mirror substrate layer 5.This catoptron in the present embodiment adopts the method for metal film oxygenates media coating to improve the reflectivity of catoptron in the sheen spectral range.Control the peaked wavelength location of spectral reflectivity in the visible-range by the optical thickness of adjusting media coating, thereby play the effect that sheen strengthens.Fig. 6 is the nano-multilayer film cross section field emission scanning electron microscope photo of this embodiment; Fig. 7 distributes and stoicheiometry along the element on the depth of film direction for this embodiment adopts plasma etching+photoelectron spectroscopy technology for detection.Fig. 8 detects the situation of change of this catoptron at ultraviolet-visible light-infrared range of spectrum internal reflection rate curve for this embodiment adopts the ultraviolet-visible photometer.Adjusting the peaked wavelength location of spectral reflectivity is 550nm, realizes the selection reflection to incident light.
Embodiment 3
The structure of present embodiment and embodiment 2 is formed identical, adopts the method for metal film oxygenates media coating to improve the reflectivity of catoptron in the sheen spectral range equally.Different is: the optics geometric thickness by changing multi-layer nano film rete in the present embodiment and the composition of metal film make that the ripple of maximum reflectivity occurs frequently in the sheen and have showed blue shift.This sheen for preparing in the present embodiment strengthens catoptron to be made up of four kinds of nano thin-film media, is respectively Cr, In 2O 3, SnO 2And TiO 2Medium comprises five layer assemblies equally.Wherein glass-mirror 1 is positioned at outermost layer.It is 30nm that reflection horizon 2 thickness are selected in its below, by TiO 2Occupy.At TiO 2 Intermediate layer 3 thickness of below are 24nm, are In 2O 3And SnO 2The unity of possession, wherein In 2O 3Content be 90%, SnO 2Content be 10%.Sheen enhancement layer 4 thickness of intermediate layer below are 24nm, are occupied by crome metal.After the sheen enhancement layer 4 is mirror substrate layer 5.Fig. 9 is the nano-multilayer film cross section field emission scanning electron microscope photo of this embodiment; Figure 10 distributes and stoicheiometry along the element on the depth of film direction for this embodiment adopts plasma etching+photoelectron spectroscopy technology for detection.Figure 11 detects the situation of change of this catoptron at ultraviolet-visible light-infrared range of spectrum internal reflection rate curve for this embodiment adopts the ultraviolet-visible photometer.With respect to embodiment 2, this soft light enhancement anti-dazzle reflecting mirror becomes to assign to control the peaked wavelength location of spectral reflectivity in the visible-range by the optical thickness of adjusting multi-layer nano film rete and the metal medium that changes the sheen enhancement layer, making the wavelength of its maximum spectral reflectivity is 445nm, thereby plays the effect that the blue light in the visible light is strengthened.
In sum; the present invention has the effect that selection is anti-dazzle and sheen strengthens really; the foregoing description only is a preferable embodiment of the present invention; the protection domain that is not intended to limit the invention; all change and modifications of carrying out according to spirit of the present invention and design all should be included in protection scope of the present invention.

Claims (4)

1, soft light enhancement anti-dazzle reflecting mirror provided by the invention is characterized in that: it comprises and is followed successively by by the different refractivity material preparation the 1st to 5 layer transparent glass layer, selects reflection horizon, intermediate layer, sheen enhancement layer and substrate layer; The optical path difference δ on the upper and lower surface of j layer jSatisfy the requirement of following formula (I) one of them expression formula to the formula (IV):
δ j = 2 d j n j 2 - n j + 1 2 sin 2 i = kλ Formula (I)
δ j = 2 d j n j 2 - n j + 1 2 sin 2 i + λ 2 = kλ Formula (II)
δ j = 2 d j n j 2 - n j + 1 2 sin 2 i = ( 2 k + 1 ) λ / 2 Formula (III)
δ j = 2 d j n j 2 - n j + 1 2 sin 2 i + λ 2 = ( 2 k + 1 ) λ / 2 Formula (IV)
In the formula, the sequence number of j presentation layer, value is 2,3 or 4 respectively, d jBe the thickness of j layer, n J-1, n j, n J+1Be respectively j-1, the refractive index of j and j+1 layer, λ is a lambda1-wavelength, and i represents the incident angle of light, and k is a natural number;
As min (n J-1, n J+1)<n j<max (n J-1, n J+1) time, the optical path difference of j layer satisfies formula (I) or formula (III);
Work as n j<min (n J-1, n J+1) or n j>max (n J-1, n J+1) time, the optical path difference of j layer satisfies formula (II) or (IV).
2, soft light enhancement anti-dazzle reflecting mirror according to claim 1 is characterized in that:
Selecting the thickness in reflection horizon is 20~25nm, and material is the potpourri of aluminium and chromium, and wherein the atom percentage content of Al is 30%~40% in the potpourri;
The material of intermediate layer is a ruthenium, and it interpenetrates with the element of selecting reflection horizon and sheen enhancement layer respectively, and the thickness between the infiltration area is 8~12nm;
The thickness of sheen enhancement layer is 40~45nm, and its material is the potpourri of silver and gold, and wherein the atom percentage content of Ag is 90%~95%.
3, soft light enhancement anti-dazzle reflecting mirror according to claim 1 is characterized in that:
Selecting the material in reflection horizon is TiO 2, thickness is 35~40nm;
The thickness of intermediate layer is 8~12nm, and material is In 2O 3And SnO 2Potpourri, In in the potpourri wherein 2O 3Content be 90%~95%;
The thickness of sheen enhancement layer is 4~8nm, and its material is the potpourri of silver and gold, and wherein the atom percentage content of Ag is 90%~95%.
4, soft light enhancement anti-dazzle reflecting mirror according to claim 1 is characterized in that:
Selecting the material in reflection horizon is TiO 2, thickness is 25~30nm;
The thickness of intermediate layer is 20~25nm, and material is In 2O 3And SnO 2Potpourri, In in the potpourri wherein 2O 3Content be 90%~95%;
The material of sheen enhancement layer is a chromium, and thickness is 20~25nm.
CN2009100630838A 2009-07-07 2009-07-07 Soft light enhancement anti-dazzle reflecting mirror Expired - Fee Related CN101598824B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102158127A (en) * 2010-02-11 2011-08-17 群赞科技(深圳)有限公司 Solar module
CN106324731A (en) * 2016-10-28 2017-01-11 宜昌南玻显示器件有限公司 Multi-functional reflective film of on-board exterior mirror and preparation method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102158127A (en) * 2010-02-11 2011-08-17 群赞科技(深圳)有限公司 Solar module
CN106324731A (en) * 2016-10-28 2017-01-11 宜昌南玻显示器件有限公司 Multi-functional reflective film of on-board exterior mirror and preparation method

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