CN101575175A - Ultraviolet light solidified glue film glass - Google Patents
Ultraviolet light solidified glue film glass Download PDFInfo
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- CN101575175A CN101575175A CNA2009101357903A CN200910135790A CN101575175A CN 101575175 A CN101575175 A CN 101575175A CN A2009101357903 A CNA2009101357903 A CN A2009101357903A CN 200910135790 A CN200910135790 A CN 200910135790A CN 101575175 A CN101575175 A CN 101575175A
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Abstract
The invention relates to ultraviolet light solidified glue film glass which comprises glass, oligomer, reactive diluent, photoinitiator, stabilizer, levelling agent and antifoaming agent, and a glass surface or a glass filming surface is sprayed or printed with a layer or a plurality of layers of ultraviolet light solidifying glue. After ultraviolet irradiation, an ultraviolet light solidified glue film is formed on the glass surface or the glass filming surface.
Description
Technical field;
The present invention relates to glass, pottery, stone material.
Background technology;
The UV printed glazing is finished picture and text printed matter surface exactly, prints one or many ultraviolet oil polish again with forme or picture and text forme on the spot, makes printed matter surface obtain the ultraviolet rete of light.The UV printed glazing can strengthen the light fastness of printing ink, increases ink lay solar heat protection, moistureproof ability, plays the protection trace, beautifies product, substitutes the effect of overlay film.
The characteristics of UV printed glazing are: 1) the ultraviolet oil polish contains solvent hardly, and the organic volatile quantity discharged is few, has reduced atmospheric pollution.2) energy-conservation and efficient height does not need heat energy during curing, and it solidifies required energy consumption and has only about 20% of infrared curing type oil polish.Curing speed can reach 100～300m/min under the irradiation of 80～120W/cm UV-lamp; 3) printed matter after the ultraviolet glazing process is handled, color is obviously bright-coloured beautiful than other working methods, and the coating after solidifying is wear-resisting, has more resistance to chemical reagents and chemical resistant properties, good stability, can water and ethanol clean; 4) volatilization of ultraviolet oil polish is few, and low-consuming, cost is about about 60% of overlay film cost; 5) ultraviolet glazing product adhesion can stack stacking after the curing, is beneficial to back operation processing operation; 6) can recycle.Solved that plastics compound paper substrate can not reclaim and the problem of environmental pollution that forms.
Do not retrieve as yet with the UV printed glazing technology or with ultraviolet cured adhesive and be coated with the relevant report that membrane technique is made ultraviolet light solidified glue film glass.
Chinese patent 200810030170.9 " a kind of antibiotic ultraviolet coating and manufacture craft thereof " is earlier nanometer silver powder and wetting dispersing agent to be mixed and made into an antibiotic stoste, again the polyester CALCIUM ACRYLATE in antibiotic stoste and the ultraviolet coating is mixed and made into antibiotic mother liquor, other component with antibiotic mother liquor and ultraviolet coating is mixed and made into antibiotic ultraviolet coating at last, because the polyester CALCIUM ACRYLATE is a kind of component in the ultraviolet coating, it has good pigment wettability, the polyester CALCIUM ACRYLATE can be miscible in the ultraviolet coating well, the nanometer silver powder can be dispersed in the polyester CALCIUM ACRYLATE well, therefore, the nanometer silver powder of blending dispersion in the polyester CALCIUM ACRYLATE also can be dispersed in the ultraviolet coating well, and be uniformly dispersed, the manufacture craft of antibiotic ultraviolet coating of the present invention is simple, be easy to process for processing, antibiotic ultraviolet coating has good antibiotic and sterilization idiocratic, can kill voluntarily attached to the bacterium on the coating, germ.
The deficiency of above-mentioned patent is: 1, nanometer silver powder mixed with resin is dispersed in the polyester CALCIUM ACRYLATE, wrap up the polyester CALCIUM ACRYLATE around the nanometer silver powder, bacterium or germ need could contact with the nanometer silver powder by parcel polyester acrylate resin layer, and parcel polyester acrylate resin coating reduces the sterilization usefulness of nanometer silver powder.2, above-mentioned patent does not propose the preparation method of ultraviolet light polymerization plastic powder and coating.3, above-mentioned patent does not propose the method that antibiotic and antiviral activity nano material is sprayed on the ultraviolet cured adhesive surface.4, above-mentioned patent does not propose the combining of other material and ultraviolet glue beyond the desilver.5, above-mentioned patent does not propose by polishing on the ultraviolet cured adhesive surface, makes antibiotic and the antiviral activity nano material exposes, and improves antibiotic and method antiviral activity nano material sterilization ability.6, above-mentioned patent does not propose at glass, the application in pottery, stone material field.7, above-mentioned patent does not propose to control the report that the manufacturing of particle ultraviolet cured adhesive has sunlight control or ripple controlled function doubling glass with sneaking into sunlight control or ripple.
Summary of the invention:
The objective of the invention is: 1, the UV printed glazing technology is migrated to and make ultraviolet light solidified glue film glass or ultraviolet light solidified glue film double glazing, by ultraviolet light solidified glue film on glass, improve the anti-crushing performance of glass, solve the glass fragment problem of hurting sb.'s feelings of being scattered.2,, improve the heat-insulating property and the sound insulation property of glass by ultraviolet light solidified glue film on glass.3, the UV printed glazing technology is migrated to make ultraviolet light solidified glue film glass, make ultraviolet light solidified glue film glass form high-level efficiency suitability for industrialized production and quality-guarantee, solve manual adhering film to glass quality instability, production efficiency is hanged down problem.4, according to ultraviolet light solidified glue film glass destructible characteristics under the strong impact force effect, when producing danger, can escape glass.5, be coated with ultraviolet light polymerization anti-crushing glued membrane on the toughened glass surface, solve the toughened glass self-explosion glass fragment problem of hurting sb.'s feelings of being scattered.6, the ultraviolet light solidified glue film glass surface is inlayed antibiotic and antivirus activity material, ultraviolet light solidified glue film glass is carried had antibiotic and antiviral and sterilization usefulness.7, mix sunlight control nano particle in the ultraviolet cured adhesive, solve ultraviolet cured adhesive surface contamination and problem of aging, improve the ultraviolet cured adhesive life-span.8, with sneaking into the doubling glass that sunlight control or the manufacturing of ripple control particle ultraviolet cured adhesive have sunlight control or ripple controlled function
The ultraviolet light solidified glue film glass that the present invention proposes comprises glass, oligopolymer, reactive thinner, light trigger, stablizer, flow agent and defoamer, glass surface or glass coating surface spraying or print one or more layers ultraviolet cured adhesive, after the uviolizing, form ultraviolet light solidified glue film at glass surface or glass coating surface.
The another kind of ultraviolet light solidified glue film glass that the present invention proposes comprises glass, oligopolymer, reactive thinner, light trigger, stablizer, flow agent and defoamer, UV curing powder coating sprays or is printed on glass surface or glass coating surface, the heating UV curing powder coating is to molten state, after uviolizing, form ultraviolet light solidified glue film at glass surface or glass coating surface.
For improving the luminance brightness of UV curing powder coating glue film glass, polish with polishing machine on the ultraviolet cured adhesive surface.
Ultraviolet cured adhesive is by oligopolymer, reactive thinner, light trigger, stablizer, flow agent and defoamer are formed, and oligopolymer comprises: epoxy acrylic resin, poly-ammonia enzyme acrylic resin, the polyester acrylic resin, the epoxy methacrylic resin, polyalcohol modified epoxy methacrylic resin, fatty acid modified epoxy methacrylic resin, the epoxy soybean oil methacrylic resin, the methacrylic acid polyurethane resin, polyether-modified methacrylic resin, fatty acid modified methacrylic acid polyurethane resin, in the polyester methacrylic acid polyurethane resin one or more are used.Reactive thinner comprises: acrylate (HDDA), neopentyl glycol diacrylate enzyme (NPGDA), tri (propylene glycol) diacrylate (TPGDA), Viscoat 295 (TMPTA), water or thickening material.Light trigger comprises: benzophenone, α monohydroxy isopropyl benzene ketone, α monohydroxy phenylcyclohexane ketone.Stablizer comprises: Resorcinol, p methoxy phenol, para benzoquinone, 2,6 one di-t-butyl cresylol, the simple function group acrylate monomer, the bifunctional acrylate monomer, the trifunctional acrylate monomer, the four-functional group acrylate monomer, five functional group's acrylate monomer, the water dispersible acrylate monomer, simple function group methacrylic acid alicyclic monomer, bifunctional methacrylic acid alicyclic monomer, trifunctional methacrylic acid alicyclic monomer, four-functional group methacrylic acid alicyclic monomer, five functional group's methacrylic acid alicyclic monomers or monomeric one or more of water dispersible methacrylate are used, its effect is to regulate the glued membrane viscosity, curing speed is participated in photocuring reaction.
Light trigger is a free radical photo-initiation; comprise: α monohydroxy isopropyl benzene ketone; α monohydroxy phenylcyclohexane ketone; 2; 4,6-(trimethylbenzoyl) diphenyl phosphate oxidation (TPO); 4-methylbenzene sulfenyl benzophenone (BMS); 2-methyl isophthalic acid-[4--methylthio group phenyl]-2-morpholinyl-1-acetone; 1-hydroxyl-cyclohexyl-phenyl ketone; 2-hydroxy-2-methyl-1-phenyl-1-acetone; sec.-propyl thia anthraquinone (2; 4 heterogeneous mixtures); 4-dimethylamino-phenylformic acid second fat; 4-dimethylamino-phenylformic acid (2-ethyl) fat; the benzoylbenzoic acid formicester; trisbromomethyl phenyl sulfone; the 4-chlorobenzophenone; 4-methyldiphenyl ketone; o-benzoylbenzoic acid formicester or benzophenone (BP).
Stablizer is used for improving the ultraviolet cured adhesive stability in storage.Stablizer commonly used has Resorcinol, p methoxy phenol, para benzoquinone, 2,6 one di-t-butyl cresylol.
Flow agent is used for improving the levelling property of ultraviolet light solidified glue film face, increases the glossiness of ultraviolet light solidified glue film, comprising: cellulose acetate butyrate (CAB), polyacrylic acid.
Defoamer is used for preventing and eliminate the bubble that ultraviolet cured adhesive produces in manufacturing and use, comprises: silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polyoxypropylene glyceryl ether and polyoxypropylene.
For improving ageing-resistant performance and the heat-insulating property of UV curing powder coating glue film glass; Sneak into sunlight control or ripple control particle in the ultraviolet cured adhesive or in the UV curing powder coating, sunlight control or ripple control particle comprise: silicon nanocrystal or nanometer silicon carbide crystal grain or Nano titanium dioxide or nano mica pearl essence or nanometer aluminium powder or nanoscale tin ash or nanoscale chromium trioxide or nanoscale metatitanic acid barium or nanoscale Fe3O4 or nano zine oxide or Nano Silver or nano-graphite or nano-indium stannum oxide or nano oxidized antimony or oxide nano rare earth or nanometer TCO or carbonyl iron dust or nickel powder or ferrite powder.
For improving the sterilizing function of UV curing powder coating glue film glass, to sneak into antibiotic and the antiviral activity nano material in the ultraviolet cured adhesive or in the powder coating, antibiotic and antiviral activity nano material comprises: nanometer Ag particle, nano-TiO
2Particle, nano-ZnO particle, nanometer SiO
2Particle, nano SnO
2Particle, nanometer ZrO
2Particle, nanometer Cu particle, nanometer CuO
2Particle, nanometer sodium zirconium phosphate particle.
For improving the sterilization usefulness of ultraviolet light solidified glue film glass, antibiotic and antiviral activity nano material spraying or be printed onto the ultraviolet cured adhesive outside surface or antibiotic and antiviral activity nano material sprays or be printed onto the ultraviolet cured adhesive outside surface after sneaking in the ultraviolet cured adhesive, polish with polishing machine on the ultraviolet cured adhesive surface, polishing back ultraviolet cured adhesive is antibiotic to be exposed with the antiviral activity nano material, directly contact killing pathogenic bacteria with germ.
For making the UV curing powder coating glue film glass have light-accumulating luminous function, sneak into light-accumulating luminous material in the ultraviolet cured adhesive or in the powder coating, light-accumulating luminous material comprises: the light-accumulating luminous particle of rare earth aluminate, the light-accumulating luminous particle of rare earth silicate, the light-accumulating luminous particle of sulfide.
According to glass purposes difference, the one side that ultraviolet cured adhesive is coated in glass manufactures the single face ultraviolet light solidified glue film glass, the two sides that ultraviolet cured adhesive is coated in glass manufactures two-sided ultraviolet light solidified glue film glass, ultraviolet cured adhesive is coated in the part of glass with intaglio plate coating machine or flexographic plate coating machine or screen process press, manufacture the ultraviolet light solidified glue film that has decorative pattern, by the different decorative patterns that present of ultraviolet light solidified glue film with the reflected light of glass.
For improving glue film glass protecting against shock and anti-crushing function, ultraviolet cured adhesive surface coverage transparent resin film, transparent resin film comprises: PET resin molding or polycarbonate resin film (PC) or polyethylene resin film (PE) or polypropylene resin film (PP) or fluoroplastics resin film.When making ultraviolet curing transparent Resin adhesive film glass, at first, with roll coater ultraviolet cured adhesive evenly is coated onto glass surface, make solvent evaporates with infrared heating, at ultraviolet cured adhesive surface coverage transparent resin film, after UV-irradiation, make ultraviolet light solidified glue film with glass with transparent resin film is bonding is integral.
For improving ultraviolet light solidified glue film glass intensity and decorate properties, ultraviolet light solidified glue film is made up of multilayer, comprising: whole gluing and local gummed multiple layer combination, the combination of band coloring agent film and transparent adhesive film, the combination of function glued membrane and transparent adhesive film.
Ceramic glaze glass is to add ceramic powdered frit in ultraviolet cured adhesive, at glass surface, after UV-irradiation, ceramic powdered frit is fixed on glass through printing or colored drawing, behind the high temperature sintering, ceramic powdered frit and glass is combined into one.
Above-mentioned ultraviolet light solidified glue film glass, glass can substitute with stone material or pottery, manufactures anti-crushing glued membrane stone material or pottery.
A kind of ultraviolet light solidified glue film glass manufacture method: 1, glass enters cleaning machine cleaning and oven dry; 2, contain the ultraviolet cured adhesive printing of antibiotic and antiviral activity nano material or spray to glass surface; 3, uviolizing is sneaked into antibiotic and the ultraviolet cured adhesive antiviral activity nano particle is solidificated in glass surface; 4, polish with polishing machine on the ultraviolet cured adhesive surface.
A kind of ultraviolet light solidified glue film glass manufacture method: 1, glass enters cleaning machine cleaning and oven dry; 2, sneaking into sunlight control or ripple controls particle ultraviolet cured adhesive printing or sprays to glass surface; 3, uviolizing will be sneaked into sunlight control or ripple control particle ultraviolet cured adhesive is solidificated in glass surface.
A kind of ultraviolet light solidified glue film glass manufacture method: 1, glass enters cleaning machine cleaning and oven dry; 2, mix the UV curing powder coating printing of antibiotic and antiviral activity nano particle or spray to glass surface; 3, the heating UV curing powder coating is to molten state, and insulation makes the glass surface after ultraviolet light polymerization powder glue is tiled in cleaning; 4, uviolizing is solidificated in glass surface with sneaking into the antibiotic and ultraviolet cured adhesive liquid antiviral activity nano particle.
A kind of ultraviolet light solidified glue film glass manufacture method: 1, glass is entered cleaning machine and clean and dry; 2, sneaking into sunlight control or ripple controls particle ultraviolet cured adhesive printing or sprays to glass surface; 3, another piece cleaning glass is placed on sneaks into sunlight control or ripple control particle ultraviolet cured adhesive surface: 4, vacuumize and pressurize; 5, uviolizing will be sneaked into sunlight control or ripple control particle ultraviolet cured adhesive is solidificated between inside and outside glass.
Advantage of the present invention is: the glass of 1, the UV printed glazing technology being migrated, improve the anti-crushing performance of glass, and solve the glass fragment problem of hurting sb.'s feelings of being scattered.2, sneak into sunlight control or ripple control particle in the ultraviolet light solidified glue film on glass, improve the heat-insulating property and the weather resistance of glass.3, sneak into antibiotic in the ultraviolet light solidified glue film on glass and antiviral activity nano material and make antibiotic and the antiviral activity nano material exposes, improve the antibiotic and antiviral performance of glass by polishing.4, be coated with ultraviolet light polymerization anti-crushing glued membrane on the toughened glass surface, solve the toughened glass self-explosion glass fragment problem of hurting sb.'s feelings of being scattered.
Description of drawings:
Below in conjunction with Figure of description and embodiment the present invention is further described.
Fig. 1 is the ultraviolet light solidified glue film glass sectional drawing with feature of the present invention.
Fig. 2 is the ultraviolet light solidified glue film glass sectional drawing that contains nano-indium stannum oxide with feature of the present invention.
Fig. 3 is the ultraviolet light polymerization sterilization glue film glass sectional drawing that contains nanometer silver with feature of the present invention.
Fig. 4 is the ultraviolet light polymerization doubling glass sectional drawing that contains sunlight control nano particle with feature of the present invention.
Fig. 5 is the self-luminous sign ultraviolet light solidified glue film glass sectional drawing with feature of the present invention
Fig. 6 is the ultraviolet powder photocuring doubling glass sectional drawing that contains sunlight control nano particle with feature of the present invention.
Fig. 7 be have a feature of the present invention contain nano-ZnO particulate ultraviolet powder photocuring stone material sectional drawing.
Fig. 8 is the ultraviolet powder photocuring shock resistance glass sectional drawing with covering PET resin molding of feature of the present invention.
Embodiment:
Embodiment 1:
A kind of ultraviolet light solidified glue film glass sectional drawing as shown in Figure 1, wherein: the 1st, glass, the 2nd, bottom ultraviolet cured adhesive, the 3rd, medium ultraviolet optic-solidified adhesive, the 2nd, surface layer ultraviolet cured adhesive.When making ultraviolet light polymerization single face glue film glass, at first, with roll coater bottom ultraviolet cured adhesive 2 evenly is coated onto glass 1 surface, make solvent evaporates with infrared heating, make solvent evaporates with infrared heating, after UV-irradiation, make bottom ultraviolet cured adhesive liquid be solidificated in glass 1 surface and form bottom ultraviolet glued membrane 2, with roll coater middle level ultraviolet cured adhesive 3 evenly is coated onto bottom ultraviolet cured adhesive 2 surfaces, make solvent evaporates with infrared heating, after UV-irradiation, make middle level ultraviolet cured adhesive liquid be solidificated in bottom ultraviolet cured adhesive 2 surfaces, form ultraviolet glued membrane 3, with roll coater surface layer ultraviolet cured adhesive 4 evenly is coated onto middle level ultraviolet cured adhesive 3 surfaces, makes solvent evaporates with infrared heating, after the UV-irradiation, surface layer ultraviolet cured adhesive liquid is solidificated in middle level ultraviolet cured adhesive 3 surfaces, forms ultraviolet light solidified glue film 4.
Embodiment 2:
A kind of ultraviolet light solidified glue film glass sectional drawing that contains nano-indium stannum oxide as shown in Figure 2, wherein: the 5th, glass, the 6th, bottom ultraviolet cured adhesive, the 7th, nano-indium stannum oxide ultraviolet cured adhesive, the 8th, surface layer ultraviolet cured adhesive.When manufacturing contains the ultraviolet light solidified glue film glass of nano-indium stannum oxide, at first, with roll coater bottom ultraviolet cured adhesive 6 evenly is coated onto glass 5 surfaces, make solvent evaporates with infrared heating, after UV-irradiation, make bottom ultraviolet cured adhesive liquid be solidificated in glass 5 surfaces and form bottom ultraviolet glued membrane 6, with roll coater middle level nano-indium stannum oxide ultraviolet cured adhesive evenly is coated onto bottom ultraviolet cured adhesive 6 surfaces, make solvent evaporates with infrared heating, after UV-irradiation, make middle level nano-indium stannum oxide ultraviolet cured adhesive liquid be solidificated in bottom ultraviolet cured adhesive 6 surfaces, form nano-indium stannum oxide ultraviolet light solidified glue film 7, with roll coater surface layer ultraviolet cured adhesive 8 evenly is coated onto nano-indium stannum oxide ultraviolet light solidified glue film 7 surfaces, middle level, make solvent evaporates with infrared heating, after UV-irradiation, make surface layer ultraviolet cured adhesive liquid be solidificated in nano-indium stannum oxide ultraviolet light solidified glue film 7 surfaces, middle level, form ultraviolet glued membrane 8.
Embodiment 3:
A kind of ultraviolet light polymerization that contains nanometer silver is sterilized the glue film glass sectional drawing as shown in Figure 3, wherein: the 9th, glass, the 10th, bottom ultraviolet cured adhesive, the 11st, nanometer silver ultraviolet cured adhesive.When making ultraviolet light polymerization sterilization glue film glass, at first, with roll coater bottom ultraviolet cured adhesive 10 evenly is coated onto glass 9 surfaces, make solvent evaporates with infrared heating, after UV-irradiation, make bottom ultraviolet light polymerization glue 10 be solidificated in glass 9 surfaces, the glass 9 that will have a bottom ultraviolet light polymerization glue-line 10 is sent into once more and is used roll coater, roll coater evenly is coated onto bottom ultraviolet light polymerization glue-line 10 surfaces with surface layer nanometer silver ultraviolet cured adhesive 11, make solvent evaporates with infrared heating, after UV-irradiation, make surface layer nanometer silver ultraviolet cured adhesive 11 be solidificated in bottom ultraviolet light solidified glue film 10 surfaces, with polishing machine surface layer nanometer silver ultraviolet light polymerization glue-line 11 is polished, make nano-Ag particles exposed, improve the sterilization ability of surface layer nanometer silver coating.
Embodiment 4:
A kind of ultraviolet light polymerization doubling glass sectional drawing that contains sunlight control nano particle as shown in Figure 4, wherein: the 12nd, lower floor's glass, the 13rd, bottom ultraviolet cured adhesive, the 14th, upper strata glass, the 15th, upper strata ultraviolet cured adhesive, the 16th, nanometer silicon dioxide particle ultraviolet light polymerization glue-line.When making the ultraviolet light polymerization doubling glass of sunlight control nano particle, at first, with roll coater bottom ultraviolet cured adhesive 13 evenly is coated onto lower floor's glass 12 surfaces, make solvent evaporates with infrared heating, after UV-irradiation, make bottom ultraviolet light polymerization glue 13 be solidificated in lower floor's glass 12 surfaces, with roll coater upper strata ultraviolet cured adhesive 15 evenly is coated onto upper strata glass 14 surfaces, make solvent evaporates with infrared heating, after UV-irradiation, make upper strata ultraviolet light polymerization glue 15 be solidificated in upper strata glass 14 surfaces, roll coater evenly is coated onto lower floor's glass 12 bottom ultraviolet cured adhesives 13 surfaces with nanometer silicon dioxide particle ultraviolet light polymerization glue-line 16, make solvent evaporates with infrared heating, glass 14 ultraviolet light solidified glue films 15 in upper strata are covered on the nanometer silicon dioxide particle ultraviolet light polymerization glue-line 16, vacuumize, pressurization, after the UV-irradiation, bottom ultraviolet light polymerization glue-line 13 and upper strata ultraviolet light polymerization glue-line 15 bond together by nanometer silicon dioxide particle ultraviolet light polymerization glue-line nanometer silicon dioxide particle ultraviolet light polymerization glue-line 16, manufacture the ultraviolet light polymerization doubling glass that contains sunlight control nano particle.
Embodiment 5:
A kind of self-luminous sign ultraviolet light solidified glue film glass sectional drawing as shown in Figure 5, wherein: the 17th, glass, the 18th, bottom ultraviolet cured adhesive, the 19th, self-luminous sign particle ultraviolet cured adhesive, the 20th, surface layer ultraviolet cured adhesive.When manufacturing contains self-luminous sign particulate ultraviolet light solidified glue film glass, at first, with roll coater bottom ultraviolet cured adhesive 18 evenly is coated onto glass 17 surfaces, make solvent evaporates with infrared heating, after UV-irradiation, make bottom ultraviolet cured adhesive liquid be solidificated in glass 17 surfaces and form bottom ultraviolet glued membrane 18, with roll coater middle level self-luminous sign particle ultraviolet cured adhesive 19 evenly is coated onto bottom ultraviolet cured adhesive 18 surfaces, make solvent evaporates with infrared heating, after UV-irradiation, make middle level self-luminous sign particle ultraviolet cured adhesive 19 be solidificated in bottom ultraviolet cured adhesive 18 surfaces, form self-luminous sign particle ultraviolet light solidified glue film 19, with roll coater surface layer ultraviolet cured adhesive 20 evenly is coated onto self-luminous sign particle ultraviolet cured adhesive 19 surfaces, middle level, make solvent evaporates with infrared heating, after UV-irradiation, surface layer ultraviolet cured adhesive liquid is solidificated on the middle level self-luminous sign particle ultraviolet cured adhesive 19, form ultraviolet glued membrane 20.
Embodiment 6:
A kind of ultraviolet powder photocuring doubling glass sectional drawing that contains sunlight control nano particle as shown in Figure 6, wherein: the 21st, lower floor's glass, the 22nd, contain the ultraviolet cured adhesive powder of sunlight control nano particle, the 23rd, upper strata glass.When manufacturing contains the ultraviolet light polymerization doubling glass of sunlight control nano particle, at first, the ultraviolet cured adhesive powder 22 that will contain sunlight control nano particle with spraying machine evenly is coated onto lower floor's glass 21 surfaces, upper strata glass 23 is pressed ultraviolet cured adhesive powder 22 surfaces of sunlight control nano particle, use infrared heating, make the ultraviolet cured adhesive powder 22 that contains sunlight control nano particle be melted into liquid state, vacuumize, pressurization, after the UV-irradiation, lower floor's glass 21 and upper strata glass 23 bond together by the ultraviolet light polymerization glue 22 that contains sunlight control nano particle, manufacture the ultraviolet light polymerization doubling glass that contains sunlight control nano particle.
Embodiment 7:
A kind ofly contain nano-ZnO particulate ultraviolet powder photocuring stone material sectional drawing as shown in Figure 6, wherein: the 24th, stone material, the 25th, contain nano-ZnO particulate ultraviolet cured adhesive powder.When manufacturing contains nano-ZnO particulate ultraviolet light polymerization stone material, at first, to contain nano-ZnO particulate ultraviolet cured adhesive powder 25 with spraying machine and evenly be coated onto stone material 24 surfaces, use infrared heating, contain nano-ZnO particulate ultraviolet cured adhesive powder 25 and be melted into liquid state, after the UV-irradiation, contain nano-ZnO particulate ultraviolet cured adhesive 25 and bond together, manufacture ultraviolet light solidified glue film stone material with sterilizing function with stone material 24.
Embodiment 8:
A kind of ultraviolet powder photocuring shock resistance glass sectional drawing that covers the PET resin molding as shown in Figure 8, wherein: the 26th, glass, the 27th, the light-accumulating luminous particle ultraviolet light polymerization of mishmetal aluminate powder, the 28th, PET resin molding.When making the ultraviolet powder photocuring shock resistance glass that covers the PET resin molding, at first, with spraying machine the light-accumulating luminous particle ultraviolet light polymerization of mishmetal aluminate powder 27 is evenly sprayed to glass 26 surfaces, use infrared heating, make the light-accumulating luminous particle ultraviolet light polymerization of mishmetal aluminate powder 27 be melted into liquid film, PET resin molding 28 is covered the light-accumulating luminous particle ultraviolet light polymerization of mishmetal aluminate liquid film 27 surfaces, after the UV-irradiation, PET resin molding 28 bonds together by the light-accumulating luminous particle ultraviolet light polymerization of mishmetal aluminate liquid film 27 and glass 26.
The advantage of present embodiment is: 1, the light-accumulating luminous particle surface of rare earth aluminate covers the PET resin molding, prevents the light-accumulating luminous particulate oxidation of rare earth aluminate, improves the work-ing life of light-accumulating luminous glass of rare earth aluminate.2, cover the shock resistance that the PET resin molding improves glass.
Claims (10)
1, a kind of ultraviolet light solidified glue film glass comprises glass, oligopolymer, reactive thinner, light trigger, stablizer, flow agent and defoamer, it is characterized in that: glass surface or glass coating surface spraying or print one or more layers ultraviolet cured adhesive, after the uviolizing, form ultraviolet light solidified glue film at glass surface or glass coating surface.
2, a kind of ultraviolet light solidified glue film glass comprises glass, oligopolymer, reactive thinner, light trigger, stablizer, flow agent and defoamer, it is characterized in that: UV curing powder coating sprays or is printed on glass surface or glass coating surface, the heating UV curing powder coating is to molten state, after uviolizing, form ultraviolet light solidified glue film at glass surface or glass coating surface.
3; as claim 1; 2 described ultraviolet light solidified glue film glass; it is characterized in that: sneak into sunlight control or ripple control particle in the ultraviolet cured adhesive or in the UV curing powder coating, sunlight control or ripple control particle comprise: silicon nanocrystal grain or nanometer silicon carbide crystal grain or Nano titanium dioxide or nano mica pearlescence or nanometer aluminium powder or nano level tindioxide or nano level chromium trioxide or nano level metatitanic acid barium or nano level Fe3O4 or nano zine oxide or nanometer silver or nano-graphite or nano-indium stannum oxide or nano oxidized antimony or oxide nano rare earth or nanometer TCO or carbonyl iron dust or nickel powder or ferrite powder.
4, as claim 1,2 described ultraviolet light solidified glue film glass, it is characterized in that: sneak into antibiotic and the antiviral activity nano material in the ultraviolet cured adhesive or in the powder coating, antibiotic and antiviral activity nano material comprises: nanometer Ag particle, nano-TiO
2Particle, nano-ZnO particle, nanometer SiO
2Particle, nano SnO
2Particle, nanometer ZrO
2Particle, nanometer Cu particle, nanometer CuO
2Particle, nanometer sodium zirconium phosphate particle.
5, as claim 1,2 described ultraviolet light solidified glue film glass, it is characterized in that: sneak into light-accumulating luminous material in the ultraviolet cured adhesive or in the powder coating, light-accumulating luminous material comprises: the light-accumulating luminous particle of rare earth aluminate, the light-accumulating luminous particle of rare earth silicate, the light-accumulating luminous particle of sulfide.
6, as claim 1,2 described ultraviolet light solidified glue film glass, it is characterized in that: the ultraviolet cured adhesive outside surface covers transparent resin film.
7, as claim 1,2 described ultraviolet light solidified glue film glass, it is characterized in that: the ultraviolet cured adhesive outside surface is coated with antibiotic and the nanometer antiviral material.
8, a kind of ultraviolet light solidified glue film glass manufacture method: 1, glass enters cleaning machine cleaning and oven dry; 2, contain the ultraviolet cured adhesive printing of antibiotic and antiviral activity nano material or spray to glass surface; 3, uviolizing is sneaked into antibiotic and the ultraviolet cured adhesive antiviral activity nano particle is solidificated in glass surface; 4, polish with polishing machine on the ultraviolet cured adhesive surface.
9, a kind of ultraviolet light solidified glue film glass manufacture method: 1, glass enters cleaning machine cleaning and oven dry; 2, sneaking into sunlight control or ripple controls particle ultraviolet cured adhesive printing or sprays to glass surface; 3, uviolizing will be sneaked into sunlight control or ripple control particle ultraviolet cured adhesive is solidificated in glass surface.
10, a kind of ultraviolet light solidified glue film glass manufacture method: 1, glass is entered cleaning machine and clean and dry; 2, sneaking into sunlight control or ripple controls particle ultraviolet cured adhesive printing or sprays to glass surface; 3, another piece cleaning glass is placed on sneaks into sunlight control or ripple control particle ultraviolet cured adhesive surface: 4, vacuumize and pressurize; 5, uviolizing will be sneaked into sunlight control or ripple control particle ultraviolet cured adhesive is solidificated between inside and outside glass.
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| CNA2009101357903A CN101575175A (en) | 2008-05-06 | 2009-04-29 | Ultraviolet light solidified glue film glass |
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| CN200820104625.2 | 2008-05-06 | ||
| CN200820104625 | 2008-05-06 | ||
| CNA2009101357903A CN101575175A (en) | 2008-05-06 | 2009-04-29 | Ultraviolet light solidified glue film glass |
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| CN103459338A (en) * | 2011-03-28 | 2013-12-18 | 康宁股份有限公司 | Antimicrobial action of copper in glass |
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| CN107032601B (en) * | 2017-06-13 | 2019-03-15 | 湖南荣耀玻璃科技有限公司 | Functional glass and its color additive, preparation and application with uvioresistant, near infrared ray and antibacterial |
| CN107814492A (en) * | 2017-11-07 | 2018-03-20 | 太仓经济开发区蕴源吉光工艺美术品工作室 | Method for adhering film to glass |
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