CN101574612A - Non-contact method for dehumidifying liquid and dehumidifier - Google Patents
Non-contact method for dehumidifying liquid and dehumidifier Download PDFInfo
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- CN101574612A CN101574612A CNA2009100404057A CN200910040405A CN101574612A CN 101574612 A CN101574612 A CN 101574612A CN A2009100404057 A CNA2009100404057 A CN A2009100404057A CN 200910040405 A CN200910040405 A CN 200910040405A CN 101574612 A CN101574612 A CN 101574612A
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Abstract
The invention provides a non-contact method for dehumidifying liquid and a dehumidifier. The method comprises the following steps that: dehumidifying saline solution and air are separated by a membrane; when the air flows from the surface on one side of the membrane, water vapor in the air passes through the membrane selectively to reach the other side of the membrane; and then, the water vapor is absorbed by the dehumidifying saline solution contacted with the membrane, but salt molecules and liquid water cannot pass through the membrane so as to dry the air. The dehumidifier comprises a shell, an air passage and a saline solution passage, wherein the air passage and the saline solution passage are separated by the membrane; and the membrane is placed in the shell, and is a permselective membrane, so that the water vapor can pass through the membrane but the saline solution cannot pass through the membrane. The method and the dehumidifier can effectively prevent salt in the solution from being brought into the air, thereby preventing occurrence of corrosion.
Description
Technical field
The present invention relates to the liquid dehumidifying technology, particularly the non-contact method for dehumidifying liquid of field of air conditioning and dehumidifier.
Background technology
In recent years, along with Chinese society and expanding economy, people's living standard improves constantly, and the comfortableness of living environment is had higher requirement, and wherein the demand to dehumidifying is more and more stronger; In some special departments, as archives, tobacco, military project, medicine etc., and underground or semi-underground building in etc. occasion according to different purposes, higher dehumidifying requirement is also all arranged.Air conditioning comprises the adjusting of temperature and humidity; wherein; dehumidifying is a high energy consumption job; airborne vapour content seldom; only contain tens gram water vapours in the per kilogram air, but because the latent heat of vaporization of water is very high, the energy consumption of dehumidifying to account for 20%~40% of air-conditioning total energy consumption; therefore research and develop energy-conservation dehumidifying technology, the energy and environment protection of the whole society is had great importance.
The liquid absorption dehumidifying technology can be utilized low-temperature heat source regeneration owing to can reach low-down air dew point, can utilize salting liquid cold-storage and accumulation of heat and obtains the attention of air-conditioning technical.But the inherent defect of liquid dehumidifying technology is a dehumidified air can carry the salinity in the solution secretly, forms the salt fog in the similar sea wind, brings the corrosion of room, furniture, and health is also had harmful effect.Be exactly this reason, American-European developed country and Japan have forbidden the application of liquid absorption dehumidifying in civilian air-conditioning.Address this problem, must solve the problem that air is carried salinity in the salting liquid secretly.
Present liquid dehumidifier adopts the dehumidifying salting liquid and handles the mode that air directly contacts, and carries out air dewetting.The dehumidifying salting liquid comprises halogen solution such as lithium chloride solution, lithium-bromide solution, calcium chloride solution.Enter in the dehumidifier dehumidification process at air, because salting liquid directly contacts with air, the salt branch in the solution is entrained in the dehumidified air, forms salt fog, brings corrosion.
Summary of the invention
The objective of the invention is to overcome the above-mentioned shortcoming that prior art exists, a kind of non-contact method for dehumidifying liquid and dehumidifier are provided, the present invention can realize efficient dehumidifying, can avoid air directly to contact with salting liquid again.Concrete technical scheme is as follows:
A kind of non-contact method for dehumidifying liquid, will dehumidify separates with film between salting liquid and the air, when air flows through film one side surface, airborne water vapour can optionally pass film, arrives the opposite side of film, and the dehumidifying salting liquid that is contacted with film then absorbs, air obtains drying, realizes dehumidifying.
In the above-mentioned dehumanization method, described film can be the individual layer hydrophobic film, also can be hydrophilic/hydrophobic composite membrane or multilayer film.Described film can be a microporous barrier, also can be dense film.It can avoid salting liquid to soak membrane material, can guarantee that again water vapour passes film, is absorbed by solution.Described film can be made the doughnut formula, tubular type or flat.Described flat sheet membrane and nonwoven stick together.
A kind of contactless liquid dehumidifier, comprise housing, air flow channel and salting liquid runner, air flow channel and salting liquid runner separate with film, and film places housing, described film is the selective permeation film, and water vapour can pass this film but molecules of salt and liquid water can not pass this film.Described dehumidifier can be made shell-and-tube, also can make flat.If shell-and-tube uses doughnut or tubular membrane.If flat, use flat sheet membrane to do wall.
Described selective permeation film comprises polymer membrane, organic zeolite membrane, liquid film.Described polymer membrane comprises cellulose acetate film, polyvinyl alcohol film, cellophane membrane, alginic acid film, chitosan film, aromatic polyimide film, polyacrylonitrile film, poly tetrafluoroethylene, polyvinylidene fluoride film, polychloroethylene film, polyethylene film, polypropylene screen, PS membrane, poly (ether sulfone) film; Described organic zeolite membrane comprises zeolite molecular sieve film, pellosil; The dehumidifying salting liquid comprises halogen solution such as lithium chloride solution, lithium-bromide solution or calcium chloride solution.
In the above-mentioned contactless liquid dehumidifier, when described film is doughnut formula or tubular membrane, contactless liquid dehumidifier is the shell-and-tube dehumidifier, comprises housing, doughnut or tubular membrane, air intlet runner, air outlet slit runner, salting liquid inlet channel, salting liquid outlet flow, end socket and deflection plate.The salting liquid entrance channel links to each other with the housing left end, the salting liquid outlet flow links to each other with the housing right-hand member, the air intlet runner links to each other with the opening of housing bottom righthand side, the air outlet slit runner links to each other with the opening of housing upper left side, place, two ends, the left and right sides respectively is provided with end socket in the housing, and these two end sockets block up two ends, the housing left and right sides, open a plurality of holes on the end socket, many doughnut formulas or tubular membrane are passed end socket by these holes respectively, and doughnut formula or tubular membrane are fixed on enclosure interior; Also be furnished with deflection plate in the middle of the housing, also open a plurality of holes on the deflection plate and pass for doughnut formula or tubular membrane., deflection plate is doughnut or tubular membrane fixedly, housing can be divided into circuitous cavity again, and the fluid of shell side is fully contacted with doughnut or tubular membrane.This structure is similar to shell-and-tube heat exchanger.Solution is walked tube side, and air is walked shell side.Also can air walk tube side, solution is walked shell side.
In the above-mentioned contactless liquid dehumidifier, when described film was flat sheet membrane, this dehumidifier was board-like dehumidifier, comprised housing, flat sheet membrane, end socket, air intlet runner, air outlet slit runner, salting liquid inlet channel, salting liquid outlet flow.Flat sheet membrane and nonwoven stick together, the salting liquid entrance channel links to each other with the housing left side, and the salting liquid outlet flow links to each other with the housing right side, and the air intlet runner links to each other with the housing upper end, the air outlet slit runner links to each other with the housing lower end, and the core body of being made by described flat film and sealing plate places housing; Core body is formed by stacking by the multi-layer planar film, is separated by dividing plate between each layer flat sheet membrane to form hollow layer, and both sides relative in the hollow layer are blocked by sealing plate, and both-side opening forms runner in addition; Described multi-layer planar film forms staggered air flow channel and solution runner, makes air and solution cross-current cross air flow channel and solution runner.A series of flat sheet membrane are arranged in parallel, and form the series of parallel runner.Salting liquid and air flow through these runners respectively at interval, carry out exchange of moisture.End socket links to each other with runner side two ends, avoids fluid to leak.
In order to strengthen the dehumidifier dehumidification process, in time take away the heat that dehumidification process discharges, the present invention proposes a kind of tubular membrane structure with interior cooling tube.Plastic tube of tubular membrane internal placement or corrosion-resistant pipe, the inside leads to cooling water, takes away the heat that the outer salting liquid moisture absorption process of cooling tube discharges.
Contactless liquid dehumidifier of the present invention, structure is similar to shell-and-tube heat exchanger, and doughnut or tubular membrane inside are tube sides, and the film outside is a shell side.Handle tube side and shell side that air and salting liquid flow through film two sides respectively, airborne water vapour selective permeation film is absorbed by salting liquid, realizes the dehumidifying of air.Also film can be made and flatly stack up from level to level, form the parallel-plate runner, handle air and solution respectively cross-current cross dull and stereotyped film formed runner, carry out exchange of moisture by film, realize air dewetting.This method has effectively been stopped the salinity in the solution and has been entrained in the air, thereby has avoided the generation of corrosion.In order to realize strengthening dehumidifying, tubular membrane internal placement cooling tube in dehumidifier inside.
Contactless liquid dehumidifier of the present invention also can work in regeneration mode, uses as regenerator.
The relative prior art of the present invention has following advantage and effect: air and salting liquid are isolated, both guaranteed that water vapour penetrated film, absorbed by solution, can avoid the salinity in the salting liquid to be entrained in the air again, bring corrosion and pollution.Solved the drawback of solution dehumidification.Interior cooling tubular membrane has been strengthened dehumidification process and regenerative process, has improved systematic function.
Description of drawings
Fig. 1 is the structural representation of dehumidifier when the selective permeation film is doughnut or tubular membrane in the specific embodiment.
Fig. 2 is the hollow fiber film structure schematic diagram in the dehumidifier shown in Figure 1.
Fig. 3 is that dehumidifier shown in Figure 1 works in regeneration mode, as the structural representation of regenerator use.
Fig. 4 is the structural representation of selecting property dehumidifier when to see through film be flat film in the specific embodiment.
Fig. 5 is the core schematic diagram of dehumidifier shown in Figure 4.
Fig. 6 is the tubular membrane structural representation of cooling tube in the band.
Fig. 7 is the liquid dehumidification system figure that adopts film dehumidifier and regenerator.
The specific embodiment
The present invention is described in further detail below in conjunction with embodiment and accompanying drawing, but embodiments of the present invention are not limited thereto.
Embodiment 1
Doughnut or tubular membrane dehumidifier structure are as shown in Figure 1, as seen from Figure 1, the film dehumidifier is linked to each other with housing 3 left ends by dehumidifying salting liquid (as lithium chloride solution, lithium-bromide solution etc.) entrance channel 1, dehumidifying salting liquid outlet flow 5 links to each other with housing 3 right-hand members, dehumidified air inlet channel 6 links to each other with the opening of housing 3 bottom righthand sides, and dehumidified air outlet flow 2 links to each other with the opening of housing 3 upper left sides.End socket 4 places two ends in the housing, and two ends, the housing left and right sides are blocked up, and opens a plurality of holes above it, and a plurality of doughnuts or tubular membrane 8 are passed end socket 4 by these holes, are fixed on enclosure interior.Fluid in the pipe is called tube side, and the outer fluid of pipe is called shell side.Housing intermediate arrangement deflection plate 7 is also opened a plurality of holes above it, doughnut or tubular membrane are passed these holes, are fixed up.Under the deflection plate effect, the fluid in the housing wriggles and flows, and fully contacts with film.
The film dehumanization method of being realized by the said equipment is: air is sent into the dehumidifier shell side by dehumidified air entrance channel 6, advance tortuously under deflection plate 7 effects, discharge by dehumidified air outlet flow 2 at last.In the process of advancing, the salting liquid in air and the tube side carries out exchange of moisture, is dried, and what flow out at last is air after the dehumidifying.Dense dehumidifying salting liquid enters the dehumidifier tube side by dehumidification solution entrance channel 1, in flow process,, carry out exchange of moisture with the outer humid air of pipe by doughnut or tubular membrane surface, discharge by dehumidification solution outlet flow 5 after absorbing airborne moisture, become weak solution.
In the above-mentioned embodiment, dehumidification solution also can be walked shell side, and dehumidified air also can be walked tube side.
The structure of described doughnut of Fig. 1 or tubular membrane as shown in Figure 2.Duct 9 is arranged in the middle of the film 8, and solution passing hole channel 9 flows, and forms tube side.
Embodiment 2
Doughnut of the present invention or tubular membrane dehumidifier also can be used as regenerator and use.Structure as shown in Figure 3, as seen from Figure 3, when using as regenerator, regenerant salt solution (as lithium chloride solution, lithium-bromide solution etc.) entrance channel 13 links to each other with housing 3 bottom righthand sides, regenerant salt taphole runner 11 links to each other with housing 3 left upper ends, regeneration air inlet channel 10 links to each other with housing 3 left sides, and regeneration air outlet flow 12 links to each other with housing 3 right sides.End socket 4 places two ends in the housing, and housing two side seals are blocked up, and opens a plurality of holes above it, and the perforate that doughnut or tubular membrane 8 are passed end socket 4 is fixed on enclosure interior.Fluid in the pipe is called tube side, and the outer fluid of pipe is called shell side.Housing intermediate arrangement deflection plate 7 is also opened many holes above it, doughnut or tubular membrane are passed these holes, and each fiber passes a hole, is fixed up.Under the deflection plate effect, the fluid in the housing wriggles and flows, and fully contacts with film.
The film renovation process of being realized by the said equipment is: rare salting liquid is sent into the regenerator shell side by regenerant salt solution entrance channel 13, advance tortuously under deflection plate 7 effects, discharge by regenerant salt taphole runner 11 at last, become concentrated solution.In the process of advancing, the regeneration air in regenerant salt solution and the tube side carries out exchange of moisture, is dried, and what flow out at last is concentrated solution after the dry regeneration.Regeneration air enters the regenerator tube side by regeneration air entrance channel 10, in flow process, by doughnut or tubular membrane surface, carries out exchange of moisture with the outer weak solution of pipe, discharges by regeneration air outlet flow 12 behind the moisture in the absorbent solution.
In the above-mentioned embodiment, actified solution also can be walked tube side, and regeneration air also can be walked shell side.
The structure of flat film dehumidifier of the present invention as shown in Figure 4, as seen from Figure 4, flat sheet membrane dehumidifier of the present invention is linked to each other with housing 3 left sides by salting liquid (as lithium chloride solution, lithium-bromide solution etc.) entrance channel 14 with regenerator, salting liquid outlet flow 16 links to each other with housing 3 right sides, air intlet runner 15 links to each other with housing 3 upper ends, and air outlet slit runner 18 links to each other with housing 3 lower ends.The core body 17 that the parallel-plate film is made places housing 3.The structure of core body as shown in Figure 5, core body is formed by stacking by the multi-layer planar film, is separated by dividing plate between each layer flat sheet membrane to form hollow layer, both sides relative in the hollow layer are stopped up by sealing plate 20, prevent that fluid from leaking, both-side opening forms runner in addition; The parallel-plate film forms staggered air flow channel and solution runner, and air and solution cross-current are crossed air flow channel and solution runner.
The film dehumanization method of being realized by the said equipment is: salting liquid is sent into dehumidifier by salting liquid entrance channel 14, air is sent into dehumidifier by air intake runner 15, solution and air be staggered flowing in the runner of core body, carries out exchange of moisture in flow process.Airborne moisture is absorbed by solution, reaches the purpose of dehumidifying.When inlet solution was weak solution, solution was given air with the moisture transmission of self, and this moment, mode of operation was a regenerator mode.Described flat sheet membrane sticks on the nonwoven, and is sturdy and durable, can bear pressure.
Embodiment 4
The tubular membrane structure of cooling tube as shown in Figure 6 in the band of the present invention.As seen, in tubular membrane inner flow passage 9, a cooling tube 21 is set, it is plastic tube or other corrosion-resistant pipes, the logical cold water of cooling tube 21, and the heat that produces when taking away film 8 outside solution dehumidifications plays the purpose of strengthening dehumidifying.It can replace doughnut or tubular membrane among described Fig. 1.
Embodiment 5
Fig. 7 is the liquid dehumidification system flow chart that adopts film dehumidifier and regenerator.As seen, film dehumidifier 22 links to each other with solution reservoir 23, and solution reservoir 23 links to each other with 24 solution coolers, and solution cooler 24 links to each other with solution heat exchanger 27.Film dehumidifier 22 also links to each other with solution heat exchanger 27, and solution heat exchanger 27 links to each other with regenerator 25 with heater 26.
The method for dehumidifying liquid of being realized by said system is: the salting liquid of dense saline solution reservoir 23 flows through film dehumidifier 22, with airborne moisture removal, the salting liquid that absorbs moisture becomes weak solution, enter solution heat exchanger 27 heat absorptions, after temperature raises, further heating in heater 26, enter regeneration in the film regenerator 25 again, with the moisture removal in the solution, become concentrated solution, concentrated solution is introduced into cooling in the solution heat exchanger 27, enters further cooling in the solution cooler 24 then, enter at last in the concentrated solution reservoir 23, finish a circulation.
Claims (10)
1, a kind of non-contact method for dehumidifying liquid, it is characterized in that dehumidifying and separate with film between salting liquid and the air, when air flows through film one side surface, airborne water vapour can optionally pass this film, arrive the opposite side of film, the dehumidifying salting liquid that is contacted with film then absorbs, and salting liquid can not pass this film, make air obtain drying, realize dehumidifying.
2, method according to claim 1 is characterized in that described film is individual layer hydrophobic film or hydrophilic/hydrophobic composite membrane.
3, method according to claim 1 is characterized in that described film is microporous barrier or dense film.
4, method according to claim 1 is characterized in that the doughnut formula that is shaped as, the tubular type or flat of described film, when film be shaped as flat sheet membrane the time, flat sheet membrane and nonwoven stick together.
5, a kind of contactless liquid dehumidifier, it is characterized in that comprising housing, air flow channel and salting liquid runner, air flow channel and salting liquid runner separate with film, and film places housing, described film is the selective permeation film, and water vapour can pass this film but salting liquid can not pass this film.
6, contactless liquid dehumidifier according to claim 5, when it is characterized in that described film is doughnut formula or tubular membrane, air flow channel comprises air intlet runner and air outlet slit runner, the salting liquid runner comprises salting liquid inlet channel and salting liquid outlet flow, the salting liquid entrance channel links to each other with the housing left end, the salting liquid outlet flow links to each other with the housing right-hand member, the air intlet runner links to each other with the opening of housing bottom righthand side, the air outlet slit runner links to each other with the opening of housing upper left side, place, two ends, the left and right sides respectively is provided with end socket in the housing, these two end sockets block up two ends, the housing left and right sides, open a plurality of holes on the end socket, many doughnut formulas or tubular membrane are passed end socket by these holes respectively, and doughnut formula or tubular membrane are fixed on enclosure interior; Also be furnished with deflection plate in the middle of the housing, also open a plurality of holes on the deflection plate and pass for doughnut formula or tubular membrane.
7, dehumidifier according to claim 6 is characterized in that a cooling tube is set in the tubular membrane inner flow passage when described film is tubular membrane, and cooling tube leads to cold water, the heat that produces when taking away film outside solution dehumidification.
8, contactless liquid dehumidifier according to claim 5, when it is characterized in that described film is flat sheet membrane, flat sheet membrane and nonwoven stick together, air flow channel comprises air intlet runner and air outlet slit runner, the salting liquid runner comprises salting liquid inlet channel and salting liquid outlet flow, the salting liquid entrance channel links to each other with the housing left side, the salting liquid outlet flow links to each other with the housing right side, the air intlet runner links to each other with the housing upper end, the air outlet slit runner links to each other with the housing lower end, and the core body of being made by described flat film and sealing plate places housing; Core body is formed by stacking by the multi-layer planar film, is separated by dividing plate between each layer flat sheet membrane to form hollow layer, and both sides relative in the hollow layer are blocked by sealing plate, and both-side opening forms runner in addition; Described multi-layer planar film forms staggered air flow channel and solution runner, makes air and solution cross-current cross air flow channel and solution runner.
9,, it is characterized in that described film is polymer membrane, organic zeolite membrane or liquid film according to each described contactless liquid dehumidifier of claim 5~8; Described salting liquid is lithium chloride solution, lithium-bromide solution or calcium chloride solution.
10, contactless liquid dehumidifier according to claim 9 is characterized in that described polymer membrane is cellulose acetate film, polyvinyl alcohol film, cellophane membrane, alginic acid film, chitosan film, aromatic polyimide film, polyacrylonitrile film, poly tetrafluoroethylene, polyvinylidene fluoride film, polychloroethylene film, polyethylene film, polypropylene screen, PS membrane or poly (ether sulfone) film; Described organic zeolite membrane is zeolite molecular sieve film or pellosil; Described liquid film is a composite support liquid film.
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CN101975421A (en) * | 2010-09-21 | 2011-02-16 | 华南理工大学 | Heat pump-driven membrane-type liquid dehumidification and energy storage device |
CN102430323A (en) * | 2011-09-09 | 2012-05-02 | 中国船舶重工集团公司第七一八研究所 | Dehumidify device for indoor environment |
CN102607126A (en) * | 2012-03-23 | 2012-07-25 | 魏宝利 | External pressure hollow fiber membrane humidifier |
CN103920375A (en) * | 2014-04-25 | 2014-07-16 | 中山大学 | Hollow fiber membrane liquid dehumidification device driven by capillary force |
CN105771674A (en) * | 2016-03-02 | 2016-07-20 | 山东美诺邦马节能科技有限公司 | Tubular hollow fiber membrane, preparation method and application |
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CN106377979A (en) * | 2016-09-08 | 2017-02-08 | 东莞理工学院 | Inside cooling film dehumidifier and air dehumidification purification device using same |
CN107126843A (en) * | 2017-03-02 | 2017-09-05 | 华南理工大学 | A kind of hollow fiber film assembly and its application |
CN107036191A (en) * | 2017-04-18 | 2017-08-11 | 中国海洋大学 | Dehumidifier and the cool-down dehumidification joint air handling system with the dehumidifier |
CN107036191B (en) * | 2017-04-18 | 2023-02-14 | 中国海洋大学 | Cooling and dehumidifying combined air conditioning system with dehumidifier |
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CN110908419A (en) * | 2019-11-04 | 2020-03-24 | 北京航空航天大学 | Thermoelectric refrigeration and moisture permeable film combined temperature and humidity control system |
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CN111282446A (en) * | 2020-03-26 | 2020-06-16 | 东华大学 | Preparation method of dehumidification membrane for solution dehumidification system |
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