CN101574536B - Glucoside-containing composition, preparation method thereof and use thereof - Google Patents
Glucoside-containing composition, preparation method thereof and use thereof Download PDFInfo
- Publication number
- CN101574536B CN101574536B CN2009100160315A CN200910016031A CN101574536B CN 101574536 B CN101574536 B CN 101574536B CN 2009100160315 A CN2009100160315 A CN 2009100160315A CN 200910016031 A CN200910016031 A CN 200910016031A CN 101574536 B CN101574536 B CN 101574536B
- Authority
- CN
- China
- Prior art keywords
- glucoside
- compositions
- acid
- application
- formaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a glucoside-containing composition, a preparation method thereof and use thereof. The composition mainly comprises glucoside, thiourea, modified starch, sodium alginate, sodiumthiosulfate, sulfanilic acid, propanetriol, ammonium molybdate, malic acid and tea polyphenol. The composition can be used in gas and liquid phases to reduce low molecular aldehydes and ketones and u sed in finishing and decorating materials to remove formaldehyde in both free and absorption states and accelerate the release of deep formaldehyde in a fixed state to capture the formaldehyde and canreact instantaneously to form a hydroxy salt without secondary pollution. When used in cigarette filament bundle filter rods, the composition can improve mouth feel during smoking, retain the origina l fragrance of cigarettes, reduce various harmful ingredients in smoke, remove the special hot taste and burning feel of polypropylene fibers and improve the quality of the smoke to the degree of thatof the smoke of cellulore. The composition can be used in cellulore filter rods to remove the low molecular aldehydes in the smoke and improve the quality of the cellulore filter rods. The compositio n can remove over 99 percent of the low molecular aldehydes in sewage.
Description
Technical field
The present invention relates to a kind of preparation of compositions method and application that reduces the glucoside-containing of low molecule aldehyde, low molecule ketone in the gas, liquid.
Background technology
Low molecule aldehyde (being less than five carbon atom aldehydes) is the main raw material of industry; Because low molecule aldehyde performance is active; Soluble in water; Be scattered in the air so be prone to form free state, be adsorbed in wall, indoor fabric and the ornament materials, urea-formaldehyde resin adhesive is used for most of wood furniture, has the harmful substances such as formaldehyde of free state, ADSORPTION STATE, stationary state.Therefore in the household fitment process, used the finishing material that contains harmful substances such as formaldehyde in a large number; Cause that harmful gas exceeds standard in the room air; Health to this environment that hangs up one's hat is brought threat; Domestic and international at present improvement indoor formaldehyde pollutes technology can be divided into watershed management and later stage improvement two big classes: the source is in Lauxite, to add formaldehyde catching agent, like carbamide, thiourea, starch, tripolycyanamide, polyvinyl alcohol or lower alcohol etc., but still contains micro-free aldehyde.Some developed countries adopt photocatalysts to reduce low molecule aldehyde in administering in the later stage, and photocatalyst (titanium dioxide) is processed liquid form, are sprayed at the ornament materials surface of containing formaldehyde, but since the effect that needs light to cause it to remove the function of hanging down molecule aldehyde limited.
Medicated cigarette filter material polypropylene fibre is the distinctive patriotic tow of China; Form by acroleic acid polymerization; During polymerization, part material is complete reaction not, the low molecule aldehyde (like acrylic aldehyde) of residual minim, acrylic acid etc. in the tow; Make the smoking property of cigarette process of the third fine rod contain the third fine distinctive acid, excitement, and with abnormal flavour, bitterness.The polypropylene fibre softening point is low, and the suction latter half has tangible burning sensation.Polypropylene tows surface smoother is significantly less than acetate fiber to holding back of harmful ingredients in flue gas.There is the low molecule aldehyde of trace in Medicated cigarette in the flue gas when burning; The interior stimulation taste of covering harmful gas with spice, Folium Camelliae sinensis extract etc. of present tobacco business; People are weakened the identification degree of harmful gas; Thereby reach sensuously and to take off harmful purpose, but harmful substance such as low molecule aldehyde still exists in the flue gas, polypropylene fibre, gather acetate fiber, Compound filtering material and other carrier and all not have to reduce the function of hanging down molecule aldehyde; The low molecule aldehyde of trace in the flue gas can get in people's the body along with flue gas, but does not see the report that the low molecule aldehyde of non-processor is arranged at present.Crotonic aldehyde has been classified State Tobacco Monopoly Bureau's one of emphasis scientific research task from now on as, and the striving direction that evil has become industry technical staff falls in flue gas.
With low molecule aldehyde is that the sewage that the production technology of raw material is discharged exists part formaldehyde; And formaldehyde oneself be proved and have strong carcinogenecity; Some developed countries adopt photocatalyst to do the low molecule aldehyde of sewage disposal reduction at present, but owing to the effect that needs light causes the function of the low molecule aldehyde of its removal limited.
Summary of the invention
The purpose of this invention is to provide a kind of composition and method of making the same and application of glucoside-containing, can remedy the above-mentioned deficiency of prior art, to satisfy manufacturer and the both sides' of consumer demand.
A kind of compositions of glucoside-containing; The component and the percetage by weight scope that it is characterized in that it are respectively glycoside 6.0～8.0, thiourea or ammonium citrate 1.5～3.0, modified starch 0.5～1.5, sodium alginate or chitin 0.8～1.5, sodium thiosulfate 1.0～2.0, p-anilinesulfonic acid. 1.0～2.5, mannitol 4.0～6.0, glycerin or propylene glycol 2.0～3.0, xylitol or glucose 1.0～2.0, ammonium molybdate 0.6～1.5, malic acid or phytic acid 0.4～2.0, tea polyphenols 0.4～2.6, and all the other are water.
The preparation of compositions method of above-mentioned glucoside-containing is characterized in that sodium alginate or chitin, thiourea or ammonium citrate soluble in water; Other is soluble in water with p-anilinesulfonic acid., ammonium molybdate, malic acid or phytic acid, tea polyphenols; After two kinds of aqueous solution of gained; Add glycoside, modified starch, sodium thiosulfate, mannitol, glycerin or propylene glycol, xylitol or glucose again, stir under the room temperature then and process aqueous solution.
The compositions of above-mentioned glucoside-containing is discharged into airborne formaldehyde, total volatile organism or NH at the various decoration materials of removal
3Application in the harmful gas
The compositions of above-mentioned glucoside-containing has the application in the gas of zest abnormal flavour in removal.
The compositions of above-mentioned glucoside-containing is hanged down the application in molecule aldehyde or the acrylic acid in removing the Medicated cigarette third fine filter material.
Application in low molecule aldehyde, low molecule ketone, hydrocyanic acid, ammonia, hydrogen sulfide or the volatile nitrosamine harmful gas of the compositions of above-mentioned glucoside-containing in removing the fine filter material Medicated cigarette of vinegar.
The compositions of above-mentioned glucoside-containing reduces the application in volatile nitrosamine, CO, benzopyrene or the free radical harmful gas in composite filter.
The compositions of above-mentioned glucoside-containing is the application in the low molecule aldehyde in removing sewage.
Compositions of the present invention can be used for the content that gas, liquid reduces low molecule aldehyde, ketone; Be used for finishing, ornament materials, can not only remove the formaldehyde of free state, ADSORPTION STATE, and can the formaldehyde acceleration of stationary state deep layer be discharged and be captured; The moment reaction generates a kind of hydroxy salt, non-secondary pollution.Be used for cigarette tows mouth rod, can improve mouthfeel when sucking Medicated cigarette, when keeping the original fragrance of Medicated cigarette, can also reduce the multiple harmful components in the flue gas, remove third fine distinctive acid and the burning sensation, the flue gas quality can reach the fine level of vinegar; Be applied to remove low molecule aldehyde in the flue gas in the fine filter stick of vinegar, the fine Medicated cigarette of vinegar is improved the grade.Low molecule aldehyde reaches more than 99% in the sewage of this compositions removal discharging.
The specific embodiment
The component of the present composition and percetage by weight scope are respectively glycoside 6.0～8.0%, thiourea or ammonium citrate 1.5～3.0%, modified starch 0.5～1.5%, sodium alginate or chitin 0.8～1.5%, sodium thiosulfate 1.0～2.0%, p-anilinesulfonic acid. 1.0～2.5%, mannitol 4.0～6.0%, glycerin or propylene glycol 2.0～3.0%, xylitol or glucose 1.0～2.0%, ammonium molybdate 0.6～1.5%, malic acid or phytic acid 0.4～2.0%, tea polyphenols 0.4～2.6%, and all the other are water.During preparation, that sodium alginate or chitin, thiourea or ammonium citrate is soluble in water; Other is soluble in water with p-anilinesulfonic acid., ammonium molybdate, malic acid or phytic acid, tea polyphenols; After two kinds of aqueous solution of gained; Add glycoside, modified starch, sodium thiosulfate, mannitol, glycerin or propylene glycol, xylitol or glucose again, stir under the room temperature then and process aqueous solution.
Embodiment
Chitin 0.8g and ammonium citrate 1.5g are dissolved in the 36g water; P-anilinesulfonic acid. 2.5g, ammonium molybdate 1.5g, phytic acid 1.7g and tea polyphenols 1.0g are dissolved in the 36g water; With adding glycoside 7g, modified starch 1.5g, sodium thiosulfate 2g, mannitol 4.5g, propylene glycol 2g and xylitol 2g after two kinds of aqueous solution again, process the 100g aqueous solution.
Ammonium citrate described in the present invention can change thiourea into; Described chitin can change sodium alginate into; Described propylene glycol can change glycerin into; Described glucose can change xylitol into; Described phytic acid can change malic acid into, all can obtain similar effects.
Chitin described in the present invention contains the positively charged polar substances of various active group, and flue gas Semi-polarity micromolecule is had very high absorbability and affinity.Described glycoside contains a large amount of hydroxyls, and is soluble in water, colorless and odorless, and PARA FORMALDEHYDE PRILLS(91,95) has capturing ability.Described mannitol has a large amount of hydroxyls, and it is active that glycerin can make a large amount of hydroxyls produce.Described ammonium molybdate can be emitted molybdenum ion in this compositions, can oxidation with decompose the intravital carcinogen of people, also can reduce the burning sensation of mouth rod latter half simultaneously.Described p-anilinesulfonic acid., thiourea, glycerin or propylene glycol have the function of catching formaldehyde.Seizure property behind the silica dioxide granule absorption p-anilinesulfonic acid. is stronger.
Compositions of the present invention can be used for removing the ornament materials that adopts in the finishing and is discharged into airborne formaldehyde, total volatile organism (TVOC), NH
3Harmful gas.Be sprayed on this compositions in the air uniformly during operation or the various material surfaces (like density board, battenboard, three-ply board, carpet, wallpaper, furniture etc.) of fitting-up; Mensuration result shows: the clearance rate of PARA FORMALDEHYDE PRILLS(91,95)＞96%; To TVOC clearance rate＞70%, to NH
3Clearance rate＞50%.
Compositions of the present invention can be used for removing the gas (abnormal flavour that distributes like toilet of zest abnormal flavour; H
2S etc. have the gas of zest abnormal flavour; The penetrating odor that produces after the smoking), during operation directly with this composition sprayed in toilet or space air, the moment reaction can make H
2S clearance rate＞80%, and non-secondary pollution.
Compositions of the present invention is pressed 0.1～10% interpolation of the Medicated cigarette third fine filter material weight, can make low molecule aldehyde residual in the medicated cigarette third fine filter material such as acrylic aldehyde, acrylic acid remove clearance＞90%.
Harmful substances such as low molecule aldehyde (like crotonic aldehyde), low molecule ketone, hydrocyanic acid, ammonia are removed in the flue gas that compositions of the present invention can be used for the fine filter material cigarette burning of vinegar is produced; Can it directly be added in the tow or be added in the tow glue during operation, go low molecule aldehyde can reach more than 90%, remove low molecule ketone and can reach more than 80%; Acid gas such as hydrocyanic acid can remove 70%; Ammonia can remove 60%, and volatile nitrosamine can remove 10%, and hydrogen sulfide can remove 20%.、
Compositions of the present invention can be used for removing in the Medicated cigarette composite filter harmful gass such as volatile nitrosamine, CO, benzopyrene, free radical; This compositions is coated in the porous carrier; The part by weight of this compositions and solid-state carrier is 80～150: 100; This carrier is used for composite filter, can reduces volatile nitrosamine 10% in the Medicated cigarette, carbon monoxide 20%, benzopyrene 10% and free radical 30%.Add 10～50 milligrams by every cigarette during operation.
Compositions of the present invention is coated in porous carrier such as silicon dioxide, kieselguhr, active carbon, molecular sieve, cellulose or the magnet ring, behind high-temperature activation, can be used for contaminated water purification, low molecule aldehyde can reach 99% in the removal water.
Claims (9)
1. the compositions of a glucoside-containing; The component and the percetage by weight scope that it is characterized in that it are respectively glycoside 6.0～8.0, thiourea or ammonium citrate 1.5～3.0, modified starch 0.5～1.5, sodium alginate or chitin 0.8～1.5, sodium thiosulfate 1.0～2.0, p-anilinesulfonic acid. 1.0～2.5, mannitol 4.0～6.0, glycerin or propylene glycol 2.0～3.0, xylitol or glucose 1.0～2.0, ammonium molybdate 0.6～1.5, malic acid or phytic acid 0.4～2.0, tea polyphenols 0.4～2.6, and all the other are water.
2. the preparation of compositions method of the said glucoside-containing of claim 1 is characterized in that sodium alginate or chitin, thiourea or ammonium citrate soluble in water; Other is soluble in water with p-anilinesulfonic acid., ammonium molybdate, malic acid or phytic acid, tea polyphenols; After two kinds of aqueous solution of gained; Add glycoside, modified starch, sodium thiosulfate, mannitol, glycerin or propylene glycol, xylitol or glucose again, stir under the room temperature then and process aqueous solution.
3. the compositions of the said glucoside-containing of claim 1 is discharged into airborne formaldehyde, NH at the removal decoration material
3Application in the harmful gas.
4. the compositions of the said glucoside-containing of claim 1 has the application in the gas of zest abnormal flavour in removal.
5. the compositions of the said glucoside-containing of claim 1 is hanged down the application in molecule aldehyde or the acrylic acid in removing the Medicated cigarette third fine filter material.
6. the application in low molecule aldehyde, low molecule ketone, hydrocyanic acid, ammonia, hydrogen sulfide or the volatile nitrosamine harmful gas of the compositions of the said glucoside-containing of claim 1 in removing the fine filter material Medicated cigarette of vinegar.
7. the compositions of the said glucoside-containing of claim 1 reduces the application in volatile nitrosamine, CO, benzopyrene or the free radical harmful gas in composite filter.
8. the compositions of the said glucoside-containing of claim 1 application in the low molecule aldehyde in removing sewage.
9. in removing the Medicated cigarette third fine filter material, hang down the application in molecule aldehyde or the acrylic acid like the compositions of the said glucoside-containing of claim 5, it is characterized in that the percetage by weight of compositions in the Medicated cigarette third fine filter material of described glucoside-containing is 0.1～10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100160315A CN101574536B (en) | 2009-05-30 | 2009-05-30 | Glucoside-containing composition, preparation method thereof and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100160315A CN101574536B (en) | 2009-05-30 | 2009-05-30 | Glucoside-containing composition, preparation method thereof and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101574536A CN101574536A (en) | 2009-11-11 |
| CN101574536B true CN101574536B (en) | 2012-10-31 |
Family
ID=41269696
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100160315A Active CN101574536B (en) | 2009-05-30 | 2009-05-30 | Glucoside-containing composition, preparation method thereof and use thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101574536B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4893864B2 (en) * | 2010-07-21 | 2012-03-07 | 三浦工業株式会社 | Determination of total phosphorus |
| CN103141940B (en) * | 2013-02-27 | 2014-08-27 | 湖北中烟工业有限责任公司 | Entrapment agent for selectively lowering crotonaldehyde content in cigarette smoke and filter stick |
| CN105111711B (en) * | 2015-07-23 | 2017-06-09 | 赵伟 | The composition and preparation method of breakdown type purifying formaldehyde and application |
| CN106075797A (en) * | 2016-05-20 | 2016-11-09 | 崔文艳 | A kind of preparation method and application decomposing low molecule aldehyde compositions without illumination |
| CN109012132A (en) * | 2018-08-09 | 2018-12-18 | 王中文 | A kind of composition of changeable colour and its preparation method and application decomposing low molecule aldehyde |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002079085A (en) * | 2000-09-04 | 2002-03-19 | Masayuki Muto | Adsorbent, gas dispersion suppressing method, building material, furniture material and inner material |
| CN1413750A (en) * | 2001-10-23 | 2003-04-30 | 陈玉春 | Formaldehyde removing agent |
| CN1515321A (en) * | 2003-01-09 | 2004-07-28 | 王洪栋 | Deodorization air purifying agent |
| CN1724142A (en) * | 2005-06-07 | 2006-01-25 | 武汉大学 | Process for preparing shell glycan composite adsorbent |
-
2009
- 2009-05-30 CN CN2009100160315A patent/CN101574536B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002079085A (en) * | 2000-09-04 | 2002-03-19 | Masayuki Muto | Adsorbent, gas dispersion suppressing method, building material, furniture material and inner material |
| CN1413750A (en) * | 2001-10-23 | 2003-04-30 | 陈玉春 | Formaldehyde removing agent |
| CN1515321A (en) * | 2003-01-09 | 2004-07-28 | 王洪栋 | Deodorization air purifying agent |
| CN1724142A (en) * | 2005-06-07 | 2006-01-25 | 武汉大学 | Process for preparing shell glycan composite adsorbent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101574536A (en) | 2009-11-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101574536B (en) | Glucoside-containing composition, preparation method thereof and use thereof | |
| CN105111711B (en) | The composition and preparation method of breakdown type purifying formaldehyde and application | |
| KR102177137B1 (en) | Graphene adsorbent, its manufacturing method and use, and cigarette filter tips and tobacco | |
| JP4959342B2 (en) | Tobacco filter material and tobacco filter | |
| CN104403794A (en) | Preparation method and application of Pu'er tea extract to cigarettes | |
| JPWO2006082748A1 (en) | Tobacco filter material and tobacco filter | |
| EP3248476B1 (en) | Cellulose acetate particle aggregate, and preparation method therefor and application thereof | |
| CN103355743A (en) | Preparation and application of crop waste cigarette filter additive carrier materials | |
| CN102553543A (en) | Cigarette filter tip adsorbing material and preparation method thereof | |
| CN101317695B (en) | Adsorption material for cigarette filter-tip and preparation method thereof | |
| KR100984681B1 (en) | The cigarette filters added natural herb granules | |
| CN103800932B (en) | Full effect automobile eliminating smell agent | |
| TW200946042A (en) | Cigarette main stream smoke component adsorbing agent and cigrette filter | |
| JP5005017B2 (en) | Production method of regenerated sliced bamboo leaf and its application in tobacco products | |
| CN111501128A (en) | Nanofiber with fragrance continuously released, and preparation method and application thereof | |
| CN205409658U (en) | Fragrant smell adjustable piston cigarette filter | |
| CN103611505A (en) | Preparation method, product and application of copper ion functionalized porous cellulose composite microsphere | |
| CN202514579U (en) | Cigarette filter | |
| JP5383577B2 (en) | Composition for preventing novel influenza A (H1N1) virus infection comprising ginkgo biloba extract, air filter comprising the composition, and air purifier comprising the filter | |
| CN103919305A (en) | Tea polyphenol dust mask and manufacturing method thereof | |
| JP2007070534A (en) | Cellulose acetate composition | |
| JP2007077533A (en) | Treating liquid containing polysaccharide having amino group and plasticizer | |
| CN102154924A (en) | Paper for cigarette filter tip and preparation method thereof | |
| CN202819620U (en) | Cigarette filter tip | |
| CN202030987U (en) | Paper for cigarette filter stick and cigarette filter stick |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: QINGDAO GERUI ER ENVIRONMENT PROTECTION TECHNOLOGY Free format text: FORMER OWNER: CUI WENYAN Effective date: 20150128 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 266071 QINGDAO, SHANDONG PROVINCE TO: 266108 QINGDAO, SHANDONG PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20150128 Address after: 266108, Chengyang District, Shandong City, Liuting Qingdao Street on the west side of the dual Road Patentee after: Qingdao geruier Environmental Protection Technology Co., Ltd. Address before: Four, unit 12, building 201, No. 102, Ningxia Road, Qingdao, Shandong 266071 Patentee before: Cui Wenyan |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160219 Address after: Shinan District 266071 Shandong city of Qingdao province Ningxia road 201, building 12, unit four, 102 Patentee after: Cui Wenyan Address before: 266108, Chengyang District, Shandong City, Liuting Qingdao Street on the west side of the dual Road Patentee before: Qingdao geruier Environmental Protection Technology Co., Ltd. |