CN101559075A - Biologic activated calcium ion constituent and manufacturing method thereof - Google Patents

Biologic activated calcium ion constituent and manufacturing method thereof Download PDF

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Publication number
CN101559075A
CN101559075A CNA2008100937076A CN200810093707A CN101559075A CN 101559075 A CN101559075 A CN 101559075A CN A2008100937076 A CNA2008100937076 A CN A2008100937076A CN 200810093707 A CN200810093707 A CN 200810093707A CN 101559075 A CN101559075 A CN 101559075A
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calcium ion
raw material
constituent
ion constituent
acive
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邱于恺
张肇元
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Abstract

The invention relates to a biologic activated calcium ion constituent and a manufacturing method thereof. The activated calcium ion constituent is formed by the steps of preliminary treatment, high temperature sintering, curing under a particular environment, grinding, and the like. The content of calcium hydroxide in main components is as high as 550000-650000ppm, and the main components further contain silicon, sodium, magnesium, potassium and 0-300ppm of trace element. Under the condition of different concentrations, the constituent can be used as a nutritious supplementary agent for calcium, or can be applied to activated alkaline calcium ion water, an activated calcium ion alkaline balneation agent, an activated calcium ion food and cosmetic additive, an activated calcium ion alkaline antimicrobial, an activated calcium supplementary agent, an activated calcium ion detergent, a fertilizer and fodder calciferous additive, a metal deactivator, a plastic filler, and the like.

Description

Biologic activated calcium ion constituent and manufacture method thereof
Technical field
Relevant a kind of acive calcium ion constituent of the present invention and manufacture method thereof are mainly utilized natural calcic raw material, make and contain calcium hydroxide [Ca (OH) 2] be main component, and content and up to the acive calcium ion constituent of 550000~650000ppm.
Background technology
Owing to contain beavy metal impurity or water purification chemicals in the employed tap water in the mass society, other add its water pipe can dissolved gradually corrosion and the apartment in not the cleaning of accumulator tank, tend to cause and contain filth and antibacterial in the water, therefore now, general family is many can to install filter and RO reverse osmosis filter, eliminate impurity and harmful substance in the water, but fine bacterium in the tap water and doubtful organohalogen compounds with carcinogenecity, but do not have too big effect, therefore most machine is when the filterability activated carbon layer is stranded in the water, more can see the reproductive patterns of general antibacterial, and this filter relatively also filters out the mineral that water Central Plains is contained, therefore, and originally can be by the various mineral that absorb in the water, can be filtered device and filter out, and can't be absorbed by people.
Because public hazards are polluted, the general acidification of water quality and air, add that life is nervous and add a large amount of phosphate, the beverage of glucide etc., like pure white rice and flour and carnivorous custom with compatriots and more allow health and blood slant acidity, in order to keep self pH value, calcium in a large amount of loss skeletons of health meeting maintains pH=7.4 by blood, so calcareous meeting is run off the many acidic materials of neutralization in a large number and is excreted, mostly be acid and must cooperate vitamin D just can be absorbed by trace in conjunction with kenel because of calcium in the food again, so supplement calcium is difficulty very, therefore the additional deficiency of modern's calcium amount is definitely reasonable, if the abundant supply " calcium ion " of will keeping fit is the main purposes of people's today.
Summary of the invention
Main purpose of the present invention is promptly providing a kind of natural calcic raw material that utilizes, and makes and contains the acive calcium ion constituent of calcium hydroxide up to 550000~650000ppm.
For reaching above-mentioned purpose, the present invention contains calcium hydroxide [Ca (OH) via steps such as maturation and grinding under pre-treatment, high temperature sintering, the specific environment to form in the acive calcium ion constituent 2] up to 550000~650000ppm, wherein more include the trace element of silicon, sodium, magnesium, potassium and 0~300ppm.
Wherein, constituent is under the different situations of concentration, can be used as the supplementary of calcium, perhaps can be applicable to active alkaline calcium-ionic water, acive calcium ion alkalescence balneation agent, acive calcium ion edible cosmetic product additive, acive calcium ion alkalescence antibacterial, activated calcium supplement, acive calcium ion cleaning agent, matal deactivator, fertilizer and feedstuff calcium additive, filler for plastic etc.
Description of drawings
Fig. 1 is the manufacturing process of first embodiment of the invention;
Fig. 2 is the manufacturing process of second embodiment of the invention;
Fig. 3 is the XRD figure spectrum of acive calcium ion constituent of the present invention.
The specific embodiment
Characteristics of the present invention can be consulted the detailed description of the graphic and embodiment of this case and obtained to be well understood to.
The present invention mainly discloses a kind of acive calcium ion constituent and manufacture method thereof with high-load calcium hydroxide, and wherein this manufacture method includes the following step as shown in Figure 1 in regular turn:
Step 101, provide the calcic raw material, this calcic raw material can be natural materials such as Concha Ostreae, Margarita, shell, Crusta Penaeus seu Panulirus, clam shell, oyster shell, scallop shell, Corallium Japonicum Kishinouye or Stalactitum, and this calcic raw material mainly contains a large amount of calcium carbonate and trace mineral;
Step 102, this calcic raw material carry out pre-treatment step, and to remove the Organic substance and the impurity on this calcic raw material surface, wherein, this pre-treatment step further includes the oxidant flushing and the back is cleaned, and this oxidant can be 20~35% sulphuric acid (H 2SO 4), 20~30% nitric acid (HNO 3), 5~25% hydrogen peroxide (H 2O 2), phosphorous acid dipotassium (K 2PO 3), phosphorous acid (H 2PO 3), phosphoric acid (H 3PO 4), carbonic acid dipotassium (K 2CO 3) or tripotassium phosphate (K 3PO 4), the organic matter removal on the calcic raw material can be utilized afterwards with pure water again and carries out ultrasound concussion back cleaning by the cleaning of this oxidant, residual oxidant is cleaned;
Step 103, pulverising step form the granule that diameter is about 1~2cm size with this calcic raw material;
Step 104, high temperature sintering step are utilized 1000~1500 ℃ temperature, and about 10~15 hours of sintering time is removed the carbon dioxide in this calcic raw material, and wherein the calcium carbonate in this calcic raw material carries out following chemical reaction:
Figure A20081009370700061
The carbon dioxide of calcium carbonate is removed, and formed calcium oxide;
Step 105, maturation step, the calcic raw material of removing carbon dioxide is positioned over constant temperature, constant humidity and do not have carbon dioxide and the environment of carbon based compound under carry out maturation, wherein the calcium carbonate in this calcic raw material carries out following chemical reaction:
Figure A20081009370700062
To form semi-finished product, contain calcium hydroxide up to 550000~650000ppm in these semi-finished product;
Step 106, grinding steps are in containing nitrogen (N 2) environment under carry out to avoid the quick-fried situation of dirt to take place, semi-finished product are formed diameter be about powder less than 1 μ m size, and form pulverous acive calcium ion constituent, the result that this acive calcium ion constituent utilizes the X-ray diffraction analysis as shown in Figure 3, wherein, main crystalline phase is calcium hydroxide [Ca (OH) 2].
Wherein, further include a step 104 between this step 101 and the step 102, this step 107 is preceding pulverising step, and this preceding pulverising step forms the granule that diameter is about the 5cm size earlier with the calcic raw material, carries out the pre-treatment step of step 102 afterwards again; And further include a step 108 between step 103 and the step 104, and this step 108 is a drying steps, this drying steps carries out carrying out the high temperature sintering step again after drying removes earlier the moisture content of pore in this calcic raw material under vacuum environment.
Moreover, be illustrated in figure 2 as another embodiment of the present invention, when if this calcic raw material is Concha Ostreae, the pre-treatment step of this step 102 further includes oxidant flushing, acid solution cleaning, alkali liquor neutralization and back and cleans, this acid solution can be hydrochloric acid (HCl), acetic acid, sodium carbonate, sodium acetate or ammonia, and this alkali liquor can be sodium hydroxide.
And by including at least in the formed Powdered acive calcium ion constituent of above-mentioned processing procedure: calcium hydroxide 550000~650000ppm, silicon 2800~3200ppm, sodium 2500~2800ppm, magnesium 2300~2600ppm, potassium 500~560ppm, the trace element of strontium 1400~1600ppm and 0~300ppm, wherein this trace element can include at least: aluminum, boron, ferrum, manganese, phosphorus, zinc, contain high-load calcium hydroxide and plural trace mineral in this acive calcium ion constituent, adding under the different situations of concentration, can be used as the supplementary of calcium, perhaps can be applicable to active alkaline calcium-ionic water, acive calcium ion alkalescence balneation agent, acive calcium ion edible cosmetic product additive, acive calcium ion alkalescence antibacterial, the activated calcium supplement, the acive calcium ion cleaning agent, matal deactivator, fertilizer and feedstuff calcium additive, filler for plastic etc.
Wherein, if this acive calcium ion constituent weight is in 50mg and the RO filtered water that is incorporated in 1500ml, what can form pH value about 8~9 contains the mineral alkaline water, but human body is drunk this and is contained pH-value in the mineral alkaline water balanced body, and in this alkaline water and contain trace mineral (as: useful ions such as calcium, magnesium, potassium, sodium), do not contain harmful substances such as acid chlorine, sulphuric acid, nitric acid, nitrous acid, and can in and the acid poison that can't get rid of in the body, good for health.
Technology contents of the present invention and technical characterstic disclose as above, yet the personage who is familiar with this technology still may do various replacement and the modifications that do not deviate from this case invention spirit based on announcement of the present invention.Therefore, protection scope of the present invention should be not limited to those disclosed embodiments, and should comprise various do not deviate from replacement of the present invention and modifications, and is contained by following claim.

Claims (10)

1, a kind of natural activity calcium ion constituent is characterized in that, its per unit includes at least:
Calcium hydroxide 550000~650000ppm;
Silicon 2800~3200ppm;
Sodium 2500~2800ppm;
Magnesium 2300~2600ppm;
Potassium 500~560ppm;
Strontium 1400~1600ppm;
And the trace element of 0~300ppm.
2, acive calcium ion constituent according to claim 1 is characterized in that this trace element can include at least: aluminum, boron, ferrum, manganese, phosphorus, zinc, selenium.
3, a kind of manufacture method of acive calcium ion constituent is characterized in that, includes the following step in regular turn:
A, provide the calcic raw material;
B, this calcic raw material carry out pre-treatment step, to remove the Organic substance and the impurity on this calcic raw material surface;
C, pulverising step form granule with this calcic raw material;
D, high temperature sintering step are removed carbon dioxide in this calcic raw material and carbon based compound;
E, maturation step to form semi-finished product, contain calcium hydroxide up to 550000~650000ppm in these semi-finished product;
F, grinding steps then form pulverous acive calcium ion constituent.
4, as the manufacture method of acive calcium ion constituent as described in the claim 3, it is characterized in that, this calcic raw material mainly contains calcium carbonate and trace mineral, and this calcic raw material can be Concha Ostreae, Margarita, shell, Crusta Penaeus seu Panulirus, clam shell, oyster shell, scallop shell, Corallium Japonicum Kishinouye or Stalactitum.
5, as the manufacture method of acive calcium ion constituent as described in the claim 3, it is characterized in that, the pre-treatment step of this step B further includes: oxidant flushing, acid solution are cleaned, alkali liquor neutralizes and the back is cleaned, and perhaps this pre-treatment step further includes: oxidant flushing and back cleaning.
6, as the manufacture method of acive calcium ion constituent as described in the claim 5, it is characterized in that, this oxidant can be for 20~35% sulphuric acid, 20~30% nitric acid, be 5~25% hydrogen peroxide, phosphorous acid dipotassium, phosphorous acid, phosphoric acid, carbonic acid dipotassium or tripotassium phosphate, this acid solution can be hydrochloric acid, acetic acid, sodium carbonate, sodium acetate or ammonia.
7, as the manufacture method of acive calcium ion constituent as described in the claim 3, it is characterized in that this step D utilizes 1000~1500 ℃ temperature, about 10~15 hours of sintering.
8, as the manufacture method of acive calcium ion constituent as described in the claim 3, it is characterized in that, the maturation step of this step e be the calcic raw material that will remove carbon dioxide be positioned over constant temperature, constant humidity and do not have carbon dioxide and the environment of carbon based compound under carry out maturation.
9, as the manufacture method of acive calcium ion constituent as described in the claim 3, it is characterized in that the grinding steps of this step F is to carry out under the environment that contains nitrogen.
10, as the manufacture method of acive calcium ion constituent as described in the claim 3, it is characterized in that further include a step H between this step C and the step D, this step H is a drying steps, this drying steps carries out under vacuum environment, and removes the moisture content in this calcic raw material.
CNA2008100937076A 2008-04-16 2008-04-16 Biologic activated calcium ion constituent and manufacturing method thereof Pending CN101559075A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102308919A (en) * 2011-07-17 2012-01-11 张奎昌 Active calcium feed additive used for livestock and poultry and preparation method thereof
CN102640859A (en) * 2012-05-17 2012-08-22 颜送贵 Selenium strontium feed additive as well as production process and use method of selenium strontium feed additive
CN103190580A (en) * 2013-04-18 2013-07-10 何流 Preparation method of tender bud product
CN103222570A (en) * 2013-03-29 2013-07-31 崔顺哲 Alkaline ionic mineral complex food additive for enhancing immunity
CN103704531A (en) * 2013-12-30 2014-04-09 防城港市宇洋科技开发有限责任公司 Calcium supplement for aquaculture and preparation method of calcium supplement
CN105166330A (en) * 2015-09-15 2015-12-23 青岛大学 Invisible chlorine dioxide oyster shell calcium supplementing and odor removing antibacterial material and preparation method thereof
CN107244685A (en) * 2017-06-01 2017-10-13 广东荣辉珍珠养殖有限公司 The preparation method that a kind of utilization sea water pearls shell makes the water-disintegrable material of highly basic
CN113018229A (en) * 2021-02-02 2021-06-25 上海彤颜实业有限公司 Application and preparation method of carrot seed extracting solution and firming water

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102308919A (en) * 2011-07-17 2012-01-11 张奎昌 Active calcium feed additive used for livestock and poultry and preparation method thereof
CN102640859A (en) * 2012-05-17 2012-08-22 颜送贵 Selenium strontium feed additive as well as production process and use method of selenium strontium feed additive
CN103222570A (en) * 2013-03-29 2013-07-31 崔顺哲 Alkaline ionic mineral complex food additive for enhancing immunity
CN103222570B (en) * 2013-03-29 2014-07-16 崔顺哲 Alkaline ionic mineral complex food additive for enhancing immunity
CN103190580A (en) * 2013-04-18 2013-07-10 何流 Preparation method of tender bud product
CN103704531A (en) * 2013-12-30 2014-04-09 防城港市宇洋科技开发有限责任公司 Calcium supplement for aquaculture and preparation method of calcium supplement
CN103704531B (en) * 2013-12-30 2015-05-27 防城港市宇洋科技开发有限责任公司 Calcium supplement for aquaculture and preparation method of calcium supplement
CN105166330A (en) * 2015-09-15 2015-12-23 青岛大学 Invisible chlorine dioxide oyster shell calcium supplementing and odor removing antibacterial material and preparation method thereof
CN105166330B (en) * 2015-09-15 2019-03-15 青岛大学 A kind of stealth chlorine dioxide oyster shell is replenished the calcium smelly eliminating anti-biotic material and preparation method thereof
CN107244685A (en) * 2017-06-01 2017-10-13 广东荣辉珍珠养殖有限公司 The preparation method that a kind of utilization sea water pearls shell makes the water-disintegrable material of highly basic
CN113018229A (en) * 2021-02-02 2021-06-25 上海彤颜实业有限公司 Application and preparation method of carrot seed extracting solution and firming water
CN113018229B (en) * 2021-02-02 2022-10-28 上海彤颜实业有限公司 Application and preparation method of carrot seed extracting solution and firming water

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Open date: 20091021