CN101555915A - High-performance semi-metallic brake pad - Google Patents

High-performance semi-metallic brake pad Download PDF

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Publication number
CN101555915A
CN101555915A CNA2009100606701A CN200910060670A CN101555915A CN 101555915 A CN101555915 A CN 101555915A CN A2009100606701 A CNA2009100606701 A CN A2009100606701A CN 200910060670 A CN200910060670 A CN 200910060670A CN 101555915 A CN101555915 A CN 101555915A
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powder
brake
fibre
brake pad
order
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CN101555915B (en
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张泽伟
傅光明
张泽元
李波涛
张自立
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No1 That Rubs Braking Science And Technology Flat Peach co Ltd
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RUIYANG AUTOMOTIVE MATERIALS (XIANTAO) CO Ltd
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Abstract

A high-performance semi-metallic brake pad comprises the following components according to weight percentages: 4-6% of nitrile rubber powder, 2-4% of tyre powder, 3-5% of crystalline flake graphite, 6-9% of foam iron powder, 9-13% of boron containing phenolic resin, 8-12% of chopped steel fibre, 2-4% of alumina fibre, 8-11% of red copper fibre, 2-5% of cashew nut oil friction powder, 2-3% of graphite particle, 2-3% of calcined petroleum coke, 7-13% of barite, 3-4% of chromite, 2-3% of magnetite, 2-4% of diatomite, 7-10% of glued aluminium silicate fibre, 3-5% of flake aluminium powder, 2-4% of molybdenum disulfide, 0.2-0.5% of zinc stearate, 0.7-1% of antimony sulphide, 0.5-1% of copper sulphide, and 0.3-0.5% of tungsten carbide. After the brake pad is used, the car brake is sensitive, brake noise is low and comfort performance is good. The brake drum or brake disc has no damage in long-term use.

Description

High-performance semi-metallic brake pad
Technical field
The present invention relates to a kind of automobile brake sheet, especially relate to a kind of high-performance semi-metallic brake pad.
Background technique
Semi-metallic brake pad has higher temperature control capacity and higher brake temperature, and it is fast, accurate that the position is eaten in its brake.Therefore become one of asbestos-free friction material that China mainly applies.But in the application process of semi-metallic brake pad, its noise is higher, and pyroconductivity is too high, and problems such as the damage of brake drum or brake disc is bigger are also displayed.How to allow semi-metallic brake pad have low wear rate, low noise, high stable performance, high-comfort energy are people's main directions of research at present.
Summary of the invention
The present invention solves the existing easy corrosion of semi-metallic brake pad, and noise is higher during brake, and pyroconductivity is too high, and brake drum or brake disc are damaged technical problems such as bigger.
Above-mentioned technical problem of the present invention is mainly solved by following technical proposals: this brake block is made up of following compositions in weight percentage:
Nitrile rubber powder 4-6%, tyre talc 2-4%, crystalline flake graphite 3-5%, foam ferrous powder 6-9%, boron bakelite resin 9-13%, crush type Steel Fibre 8-12%, alumina fibre 2-4%, red copper fiber 8-11%, cashew nut oil friction powder 2-5%, graphite granule 2-3%, calcined petroleum coke 2-3%, barite 7-13%, chromite 3-4%, magnetite 2-3%, silicious marl 2-4%, spray glue aluminum silicate fiber 7-10%, scale aluminium powder 3-5%, molybdenum disulfide 2-4%, zine stearate 0.2-0.5%, antimony sulphide 0.7-1%, copper sulfide 0.5-1%, Tungsten carbite 0.3-0.5%.
In the present invention, the crush type Steel Fibre has characteristics such as braking is steady, thermal diffusivity good, wear rate is low, stable friction factor, low noise.
Chromite is the oxide mineral of chromium and iron, is used for friction material, can adjust friction.
Soft, the light specific gravity of scale aluminium powder.In friction material, play the effect of stablizing friction factor and reducing wearing and tearing.The fusing of metallic aluminium has absorbed a large amount of heat energy in friction process, has played the effect of heat radiation; And do not hinder dish, can prolong the working life of brake system.In addition, aluminium is very even in the surface distributed of friction material, makes the surface aesthetic of friction material beautiful.
Carbine abrasion-proof damage, high temperature resistant, even under higher temperature, it can keep extraordinary friction factor, adds a certain amount of Tungsten carbite component in prescription, can effectively reduce the decline of friction material high-temperature brake.
Barite can be stablized the frictional strength and the durability of friction material.Silicious marl has characteristics such as porosity is big, absorptivity is strong, chemical property is stable, wear-resisting, heat-resisting, can provide excellent surface property for brake block, increases the wear resistance of brake block.
Graphite granule is used for the heat fade that friction material can reduce friction material, stablizes the friction factor of friction material.The surface metal that prevents the friction material antithesis shifts, and satisfies the disc brake pad stable performance, wearing and tearing are little, the brake noise that the antithesis damage is little and people are concerned about day by day, travelling comfort requirements such as shake.
Add certain calcining coke and graphite in the friction material and can make friction material have perfect combination property, help preventing the metal adhesion, improve frictional behaviour than row.In addition, the empty rate of the gas of calcining coke is higher, has improved the friction factor of friction material, has reduced brake noise, the heat fade of friction material when having alleviated high temperature.
Tyre talc claims the rubber break flour again, is the tire glue face of junked tire, removes curtain radial, and pulverizing processes.It is used for friction material as elastic filler, plays to increase to wear away the effect of making an uproar.
The heat resistance of boron bakelite resin, instantaneous heat-resisting quantity, ablation resistance and mechanical property are more much better than common phenolic resin, and heat fade performance, restorability, polishing machine and the mechanical property of material are improved.
The present invention has characteristics such as wear resistance is good, high temperature resistance heat fade performance is good, long service life.After adopting the present invention, the braking automobile sensitivity, brake noise is low, and comfort property is fine, is particularly useful for big discharge capacity car such as SUV, pick up, go-anywhere vehicle system.Long-term use, brake drum or brake disc not damaged.
Embodiment
Below by embodiment, technological scheme of the present invention is described in further detail.
Embodiment 1: by weight with nitrile rubber powder 4%, tyre talc (60-80 order) 3%, crystalline flake graphite 5%, foam ferrous powder 6%, boron bakelite resin 13%, crush type Steel Fibre 8%, alumina fibre 4%, red copper fiber 11%, cashew nut oil friction powder 5%, graphite granule 2%, calcined petroleum coke 3%, barite (500-600 order) 13%, chromite powder (300-350 order) 3%, magnetite powder 2%, silicious marl (500-600 order) 2%, spray glue aluminum silicate fiber 7%, scale aluminium powder 4%, molybdenum disulfide 3%, zine stearate 0.5%, antimony sulphide 0.7%, copper sulfide 0.5%, tungsten carbide powder (250-300 order) 0.3% is put into high speed dispersor, stirring into Powdered back takes out, put into the forming die press forming again, put into vulcanizing press in 270 ℃ of high temperature with steel backing after compound then, pressure is under the condition of 18MPa, kept 15 minutes, take out brake block then, remove deburring be finished product.
Embodiment 2: by weight with nitrile rubber powder 6%, tyre talc (60-80 order) 4%, crystalline flake graphite 3%, foam ferrous powder 9%, boron bakelite resin 9%, crush type Steel Fibre 11%, alumina fibre 2%, red copper fiber 10%, cashew nut oil friction powder 3%, graphite granule 3%, calcined petroleum coke 2%, barite (500-600 order) 10%, chromite powder (300-350 order) 4%, magnetite powder 3%, silicious marl (500-600 order) 3%, spray glue aluminum silicate fiber 9%, scale aluminium powder 3.8%, molybdenum disulfide 2.5%, zine stearate 0.2%, antimony sulphide 1%, copper sulfide 1%, tungsten carbide powder (250-300 order) 0.5% is put into high speed dispersor, stirring into Powdered back takes out, put into the forming die press forming again, put into vulcanizing press in 270 ℃ of high temperature with steel backing after compound then, pressure is under the condition of 18MPa, kept 15 minutes, take out brake block then, remove deburring be finished product.
Embodiment 3: by weight with nitrile rubber powder 5%, tyre talc (60-80 order) 2.5%, crystalline flake graphite 4%, foam ferrous powder 7%, boron bakelite resin 10%, crush type Steel Fibre 9%, alumina fibre 3%, red copper fiber 8%, cashew nut oil friction powder 4%, graphite granule 3%, calcined petroleum coke 2.5%, barite (500-600 order) 12%, chromite powder (300-350 order) 4%, magnetite powder 3%, silicious marl (500-600 order) 3.5%, spray glue aluminum silicate fiber 10%, scale aluminium powder 3%, molybdenum disulfide 4%, zine stearate 0.4%, antimony sulphide 0.9%, copper sulfide 0.8%, tungsten carbide powder (250-300 order) 0.4% is put into high speed dispersor, stirring into Powdered back takes out, put into the forming die press forming again, put into vulcanizing press in 270 ℃ of high temperature with steel backing after compound then, pressure is under the condition of 18MPa, kept 15 minutes, take out brake block then, remove deburring be finished product.
Embodiment 4: by weight with nitrile rubber powder 5%, tyre talc (60-80 order) 2%, crystalline flake graphite 5%, foam ferrous powder 8%, boron bakelite resin 12%, crush type Steel Fibre 10%, alumina fibre 3.5%, red copper fiber 9%, cashew nut oil friction powder 5%, graphite granule 2%, calcined petroleum coke 2%, barite (500-600 order) 9%, chromite powder (300-350 order) 3%, magnetite powder 2.5%, silicious marl (500-600 order) 4%, spray glue aluminum silicate fiber 9%, scale aluminium powder 3.4%, molybdenum disulfide 3%, zine stearate 0.4%, antimony sulphide 1%, copper sulfide 0.9%, tungsten carbide powder (250-300 order) 0.3% is put into high speed dispersor, stirring into Powdered back takes out, put into the forming die press forming again, put into vulcanizing press in 270 ℃ of high temperature with steel backing after compound then, pressure is under the condition of 18MPa, kept 15 minutes, take out brake block then, remove deburring be finished product.
Embodiment 5: by weight with nitrile rubber powder 6%, tyre talc (60-80 order) 2%, crystalline flake graphite 5%, foam ferrous powder 7.5%, boron bakelite resin 11%, crush type Steel Fibre 12%, alumina fibre 3%, red copper fiber 11%, cashew nut oil friction powder 2%, graphite granule 2.3%, calcined petroleum coke 2.2%, barite (500-600 order) 7%, chromite powder (300-350 order) 3.5%, magnetite powder 2%, silicious marl (500-600 order) 4%, spray glue aluminum silicate fiber 10%, scale aluminium powder 5%, molybdenum disulfide 2%, zine stearate 0.3%, antimony sulphide 0.8%, copper sulfide 0.6%, tungsten carbide powder (250-300 order) 0.3% is put into high speed dispersor, stirring into Powdered back takes out, put into the forming die press forming again, put into vulcanizing press in 270 ℃ of high temperature with steel backing after compound then, pressure is under the condition of 18MPa, kept 15 minutes, take out brake block then, remove deburring be finished product.
In order to verify effect of the present invention, by Chinese GB5763-1998 NBS, the brake block of embodiment's 4 preparations and the semi-metallic brake pad of domestic other manufacturer production are tested on the constant speed tester for friction between respectively, its result is as follows:
The friction and wear behavior comparative test result of two kinds of brake blocks:
Figure A20091006067000061
Checking is the result show: compare domestic like product, adopt the semi-metallic brake pad of formulation of the present invention, have better friction and wear behavior and high temperature resistance heat fade performance.
Brake block of the present invention is installed on the SUV of the Toyota car, shows after the braking repeatedly: the present invention's sensitivity of braking, braking steadily, noise is little simultaneously, feel is comfortable.

Claims (1)

1. high-performance semi-metallic brake pad is characterized in that it mainly is made up of following compositions in weight percentage: nitrile rubber powder 4-6%, tyre talc 2-4%, crystalline flake graphite 3-5%, foam ferrous powder 6-9%, boron bakelite resin 9-13%, crush type Steel Fibre 8-12%, alumina fibre 2-4%, red copper fiber 8-11%, cashew nut oil friction powder 2-5%, graphite granule 2-3%, calcined petroleum coke 2-3%, barite 7-13%, chromite 3-4%, magnetite 2-3%, silicious marl 2-4%, spray glue aluminum silicate fiber 7-10%, scale aluminium powder 3-5%, molybdenum disulfide 2-4%, zine stearate 0.2-0.5%, antimony sulphide 0.7-1%, copper sulfide 0.5-1%, Tungsten carbite 0.3-0.5%.
CN 200910060670 2009-01-25 2009-01-25 High-performance semi-metallic brake pad Active CN101555915B (en)

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Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101813149A (en) * 2010-05-20 2010-08-25 湖南博云汽车制动材料有限公司 Low-metal ceramic-based drum-type brake pad and preparation method thereof
CN102352899A (en) * 2011-09-22 2012-02-15 山东金麒麟集团有限公司 Low-noise powder metallurgy brake pad and preparation method thereof
CN102635654A (en) * 2012-04-25 2012-08-15 杭州九鼎汽车部件有限公司 Brake pad for motor vehicles and preparation method thereof
CN102720779A (en) * 2012-05-25 2012-10-10 广东富华重工制造有限公司 Drum brake lining comprising plate alumina and manufacturing method thereof
CN102766436A (en) * 2012-07-11 2012-11-07 杭州菲英汽车零部件有限公司 New friction material and application thereof
CN103225228A (en) * 2013-04-15 2013-07-31 杭州安凯机械有限公司 Flexible paper based friction material and its production method
CN103591196A (en) * 2013-10-09 2014-02-19 贵州新安航空机械有限责任公司 Yaw brake pad made of various materials
CN104165202A (en) * 2014-08-28 2014-11-26 安徽省中力车辆制动系统制造有限公司 Novel semimetal brake block
CN104371647A (en) * 2014-09-25 2015-02-25 盐城市天驰汽配有限公司 Multi-metal friction material
CN104455128A (en) * 2014-11-04 2015-03-25 安徽省中力车辆制动系统制造有限公司 Large-particle graphite ceramic-based brake pad with less metal
CN105240429A (en) * 2015-10-27 2016-01-13 张荣斌 Vanadium-contained semimetallic brake block
CN105526286A (en) * 2014-09-30 2016-04-27 比亚迪股份有限公司 Friction material, friction plate made of friction material and manufacturing method for friction plate
CN105542387A (en) * 2016-02-24 2016-05-04 吉林大学 Biofiber-reinforced friction material and preparation method thereof
EP2980181A4 (en) * 2013-03-29 2016-11-16 Akebono Brake Ind Friction material
CN106118597A (en) * 2016-06-29 2016-11-16 晋江凯燕新材料科技有限公司 The friction material of transmission braking and goods
CN106589802A (en) * 2017-02-20 2017-04-26 马乐群 Disc brake pad
CN107401568A (en) * 2017-09-26 2017-11-28 安徽博耐克摩擦材料有限公司 A kind of disk brake brake block liner and its method for preparation
CN107504110A (en) * 2017-09-26 2017-12-22 安徽博耐克摩擦材料有限公司 A kind of drum brake brake shoe friction material and preparation method thereof
CN107642571A (en) * 2017-09-26 2018-01-30 安徽博耐克摩擦材料有限公司 A kind of drum brake brake shoe friction material and its method for preparation
CN107654538A (en) * 2017-09-26 2018-02-02 安徽博耐克摩擦材料有限公司 A kind of disk brake brake block liner and preparation method thereof
CN108916278A (en) * 2018-09-17 2018-11-30 安徽博耐克摩擦材料有限公司 A kind of wear-resistant ceramic brake block
CN109372919A (en) * 2018-12-03 2019-02-22 宁波凯硕汽车部件有限公司 A kind of high performance brake piece and its production technology
CN109628065A (en) * 2019-01-04 2019-04-16 上海华信摩擦材料有限公司 A kind of brake block friction material and preparation method thereof
CN110102754A (en) * 2019-05-20 2019-08-09 中南大学 A kind of heavy-duty vehicle dry clutch copper based powder metallurgy friction material and preparation method thereof

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GB1278746A (en) * 1969-05-08 1972-06-21 Toyota Motor Sales Co Ltd Disc brake
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CN1143662A (en) * 1995-08-23 1997-02-26 叶家铃 Method for producing sound- and water-absorbing friction material
CN1554530A (en) * 2003-12-22 2004-12-15 西安交通大学 Brake gasket and its preparng metod
CN1781972A (en) * 2004-11-30 2006-06-07 韩国轮胎株式会社 Steel friction material composition for raceing car
CN1888463A (en) * 2006-07-26 2007-01-03 张新波 Foam ferrous powder braking plate

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101813149B (en) * 2010-05-20 2011-07-27 湖南博云汽车制动材料有限公司 Low-metal ceramic-based drum-type brake pad and preparation method thereof
CN101813149A (en) * 2010-05-20 2010-08-25 湖南博云汽车制动材料有限公司 Low-metal ceramic-based drum-type brake pad and preparation method thereof
CN102352899A (en) * 2011-09-22 2012-02-15 山东金麒麟集团有限公司 Low-noise powder metallurgy brake pad and preparation method thereof
CN102635654A (en) * 2012-04-25 2012-08-15 杭州九鼎汽车部件有限公司 Brake pad for motor vehicles and preparation method thereof
CN102635654B (en) * 2012-04-25 2014-01-01 杭州九鼎汽车部件有限公司 Brake pad for motor vehicles and preparation method thereof
CN102720779A (en) * 2012-05-25 2012-10-10 广东富华重工制造有限公司 Drum brake lining comprising plate alumina and manufacturing method thereof
CN102720779B (en) * 2012-05-25 2014-10-29 广东富华重工制造有限公司 Drum brake lining comprising plate alumina and manufacturing method thereof
CN102766436B (en) * 2012-07-11 2015-03-11 杭州菲英汽车零部件有限公司 New friction material and application thereof
CN102766436A (en) * 2012-07-11 2012-11-07 杭州菲英汽车零部件有限公司 New friction material and application thereof
EP2980181A4 (en) * 2013-03-29 2016-11-16 Akebono Brake Ind Friction material
CN103225228B (en) * 2013-04-15 2015-11-25 杭州安凯机械有限公司 A kind of extensible paper base frication material and production method thereof
CN103225228A (en) * 2013-04-15 2013-07-31 杭州安凯机械有限公司 Flexible paper based friction material and its production method
CN103591196A (en) * 2013-10-09 2014-02-19 贵州新安航空机械有限责任公司 Yaw brake pad made of various materials
CN103591196B (en) * 2013-10-09 2017-02-08 贵州新安航空机械有限责任公司 Yaw brake pad made of various materials
CN104165202A (en) * 2014-08-28 2014-11-26 安徽省中力车辆制动系统制造有限公司 Novel semimetal brake block
CN104371647A (en) * 2014-09-25 2015-02-25 盐城市天驰汽配有限公司 Multi-metal friction material
CN105526286A (en) * 2014-09-30 2016-04-27 比亚迪股份有限公司 Friction material, friction plate made of friction material and manufacturing method for friction plate
CN104455128A (en) * 2014-11-04 2015-03-25 安徽省中力车辆制动系统制造有限公司 Large-particle graphite ceramic-based brake pad with less metal
CN105240429A (en) * 2015-10-27 2016-01-13 张荣斌 Vanadium-contained semimetallic brake block
CN105542387A (en) * 2016-02-24 2016-05-04 吉林大学 Biofiber-reinforced friction material and preparation method thereof
CN106118597A (en) * 2016-06-29 2016-11-16 晋江凯燕新材料科技有限公司 The friction material of transmission braking and goods
CN106589802A (en) * 2017-02-20 2017-04-26 马乐群 Disc brake pad
CN107401568A (en) * 2017-09-26 2017-11-28 安徽博耐克摩擦材料有限公司 A kind of disk brake brake block liner and its method for preparation
CN107504110A (en) * 2017-09-26 2017-12-22 安徽博耐克摩擦材料有限公司 A kind of drum brake brake shoe friction material and preparation method thereof
CN107642571A (en) * 2017-09-26 2018-01-30 安徽博耐克摩擦材料有限公司 A kind of drum brake brake shoe friction material and its method for preparation
CN107654538A (en) * 2017-09-26 2018-02-02 安徽博耐克摩擦材料有限公司 A kind of disk brake brake block liner and preparation method thereof
CN108916278A (en) * 2018-09-17 2018-11-30 安徽博耐克摩擦材料有限公司 A kind of wear-resistant ceramic brake block
CN109372919A (en) * 2018-12-03 2019-02-22 宁波凯硕汽车部件有限公司 A kind of high performance brake piece and its production technology
CN109628065A (en) * 2019-01-04 2019-04-16 上海华信摩擦材料有限公司 A kind of brake block friction material and preparation method thereof
CN110102754A (en) * 2019-05-20 2019-08-09 中南大学 A kind of heavy-duty vehicle dry clutch copper based powder metallurgy friction material and preparation method thereof
CN110102754B (en) * 2019-05-20 2020-04-24 中南大学 Copper-based powder metallurgy friction material for dry clutch of heavy-duty vehicle and preparation method thereof

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Effective date of registration: 20230313

Address after: 433000 No.1 Ruiyang Avenue, Xiantao Industrial Park, Hubei Province

Patentee after: The No.1 that rubs braking science and technology(Flat peach)Co., Ltd.

Address before: 433000 No. 1 Yang drive road, Hubei, Xiantao

Patentee before: Ruiyang Automotive Materials (Xiantao) Co.,Ltd.

PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: High performance semi metal brake pads

Effective date of registration: 20231226

Granted publication date: 20130612

Pledgee: Bank of China Limited Xiantao branch

Pledgor: The No.1 that rubs braking science and technology(Flat peach)Co., Ltd.

Registration number: Y2023980074306