CN101555665A - Identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing - Google Patents
Identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing Download PDFInfo
- Publication number
- CN101555665A CN101555665A CNA2008103010635A CN200810301063A CN101555665A CN 101555665 A CN101555665 A CN 101555665A CN A2008103010635 A CNA2008103010635 A CN A2008103010635A CN 200810301063 A CN200810301063 A CN 200810301063A CN 101555665 A CN101555665 A CN 101555665A
- Authority
- CN
- China
- Prior art keywords
- reel
- carbon dioxide
- reactor
- plasma
- dyestuff
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B23/00—Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
- D06B23/14—Containers, e.g. vats
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B13/00—Treatment of textile materials with liquids, gases or vapours with aid of vibration
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B19/00—Treatment of textile materials by liquids, gases or vapours, not provided for in groups D06B1/00 - D06B17/00
Abstract
The invention discloses an identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing system, comprising a general control console, a carbon dioxide storage bottle, a high-pressure pump, a dye tank, a heat exchange device, a reaction kettle, a dye recycling tank, a filter, a condenser, a liquid carbon dioxide storage tank, a flow meter, a valve and a pipeline, and characterized in that the reaction kettle is provided with an upper electrode and a lower electrode of a plasma generator, an exhaust valve and a vacuum pump, is internally provided with one or a plurality of groups of reel-to-reel or axis-to-axis wind and relative motors, is also internally provided with one or a plurality of groups of agitating devices and relative motors, and is embedded with an ultrasonic transducer connected with an ultrasonic wave generation device. The plasma realizes the modification for the surface of material, the ultrasonic wave disperses the dyes uniformly, the supercritical carbon dioxide realizes non-aqueous dyeing, and the reel-to-reel way realizes non-intermittent continuous industry production. The invention can meet the most rigorous environment-friendly demand and product safety demand.
Description
Technical field
The present invention relates to a kind of identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing method and system, the dyeing field that belongs to textiless such as yarn, cloth (comprising nonwoven fabric), ready-made clothes, but certain the present invention also can be applied to the surface modification and the dyeing of other coiling materials such as sheet metal, plastic sheeting, paper.
Background technology
The traditional dyeing processes expend great lot of water resources of textiless such as fiber, cloth (comprising nonwoven fabric), ready-made clothes is discharged large amount of sewage simultaneously.Water consumption is about 3.7-4.5 ton/100 meter (by 180 centimetres of fabric widths), and the use of various auxiliary agents makes the sewage recycling rate of waterused less than 10%.An enterprise that produces 100000000 meters dyeing cloths per year, annual water consumption is equivalent to medium-sized all residents' of city water consumption.China's printing and dyeing output was 36,200,000,000 meters in 2005.The development waterless staining technique is of far-reaching significance.
Existing supercritical carbon dioxide waterless staining technique can't solve the surface preparation problem of textiles, makes that the dyeing firmness is generally lower.And that the preliminary treatment of machine outer chemical product makes that toxic chemical has at textile surface unavoidably is residual, can't adapt to the requirement that more and more harsh All Pure Nature and human body are being obeyed security.
It can't commercial on a large scale Another reason be that existing apparatus is service intermittent, at the uniform velocity continuous operation basically that existing supercritical carbon dioxide waterless staining technique only rests on laboratory stage.At application number is 200710027112.6, name is called in the patent application of " adopting supercritical fluid to carry out the production system and the production technology thereof of continuous dyeing ", the inventor attempts to guarantee continuous production with the method that many group dyeing apparatuses alternately dye, but the polyphone or the parallel connections of the dyeing apparatus of many actually group service intermittents have just formed more intermittences, and can not make at the uniform velocity continuous operation of system inevitably.
Summary of the invention
Purpose of the present invention is exactly in order to address the above problem, and is commercial on a large scale for the supercritical carbon dioxide waterless staining technique, and a kind of identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing method and system is provided.
For achieving the above object, the present invention proposes identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing method, comprise yarn, textiles such as grey cloth or ready-made clothes is packed on the reel-to-reel or axle to axle wind in the reactor, with vavuum pump reactor is vacuumized, from gas cylinder to the mixture or the compressed air of reactor aerating oxygen or nitrogen or argon gas or fluorocarbons or above-mentioned gas, give the top electrode and the bottom electrode energising of plasma generator in the reactor, opening reel-to-reel or axle to axle wind makes textiles begin at the uniform velocity to reel, make textiles under the effect of the plasma of rf electric field discharge generation, surface modification take place, outage stops plasma reaction and will handle the small amount of exhaust gas discharge reactor that textiles produces, with high-pressure pump liquid carbon dioxide is pumped into reactor from carbon dioxide storage bottle and/or carbon dioxide basin, the First Astronautic Research Institute for Measurement and Test needs dyestuff and by a small amount of liquid carbon dioxide dyestuff is poured reactor from the dyestuff jar, make it be in the supercriticality that temperature reaches 10 ℃ to 170 ℃ by heat-exchange device heating carbon dioxide, with solvent and the dyeing medium of supercritical carbon dioxide fluid as dyestuff, open agitating device simultaneously and/or drive ultrasonic transducer and produce cavitation effect and cavitation effect and make dyestuff evenly dispersion and emulsification and contaminate textiles in supercritical CO 2 medium by ultrasonic generator, opening reel-to-reel or axle to axle wind makes textiles begin at the uniform velocity to reel, after coiling finishes, alternative oppositely at the uniform velocity backrush until even dyeing, by cooling or intensification means reactor temperature is returned to normal temperature, by valve and pipeline release of carbon dioxide, extraction is reclaimed uncured residual dye to the dyestuff recycling can, and by condenser carbon dioxide is recycled in the carbon dioxide basin for system and reuses, from reactor, take out dyed textiles when the pressure in the question response still is reduced to normal pressure and finish a workflow.
Described dyestuff is the disperse dyes or the synthetic dyestuffs of natural origin.
The present invention proposes identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing system simultaneously, comprise the master control platform, carbon dioxide storage bottle, high-pressure pump, the dyestuff jar, heat-exchange device, reactor, the dyestuff recycling can, filter, condenser, the liquid carbon dioxide basin, flowmeter, valve and pipeline, it is characterized in that: described reactor is equipped with the top electrode and the bottom electrode of plasma generator, air bleeding valve, vavuum pump, be built-in with one or more groups reel-to-reel or axle to axle wind and corresponding motor, be built-in with one or more groups agitating device and corresponding motor, be embedded with the ultrasonic transducer that is connected with ultrasonic generator.
Langmuir (Langmuir) probe that temperature sensor, pressure sensor, vacuum transducer, fluid sensor is housed in the described reactor and measures plasma parameter.
Because adopted above scheme,
1, the viscosity of supercritical fluid (viscosity) is close with gas, and diffusion coefficient is between gas and liquid, and penetrability is very big, and is because can obtain and density that liquid is equal, so dissolving power is also very big, fast to the dyestuff dissolving.In supercritical fluid non-aqueous dyeing technology, supercritical fluid promptly can dissolving dye, can infiltrate into textiles inside easily again, finish dyestuff dissolving → absorption → on the technical process of dying.Supercritical fluid non-aqueous dyeing dyeing rate is fast, and dyeing cycle only needs 5-60 minute (situation can be finished in following 10 minutes and dye mostly), and the tradition cycle needs 3-6 hour; Level dyeing, dye thoroughly, redying property is good; In most cases needn't reduction cleaning; Supercritical fluid dyeing only needs one dyeing process, and employed is the dyestuff filter cake that does not add any additives; Because carbon dioxide volatilization back fabric is dry, needn't dewater, dry after non-water dyes so belong to, therefore consume water does not produce waste water, does not need sewage treatment equipment yet; The dyestuff that dyes on uncured is reusable, and carbon dioxide recycles efficient can be up to 90%, the very simple thereby energy consumption minimizing of its operation.
Is temperature and pressure during the supercriticality of carbon dioxide CO2 (the middle character that promptly has gas and liquid) is lower, and (temperature 31.1? pressure is 7.4MPa), and do not fire, not quick-fried, nontoxic, non-corrosiveness, obtain easily again, so suitable solvent and medium as high temperature or low temperature dyeing utilize the powerful dissolving power of supercritical CO 2 that dyestuff dissolving and high diffusion are dyeed dyestuff penetration to textile fabric inside.
2, plasma producing apparatus (includes but not limited to oxygen by the low-pressure gas to the input reactor, nitrogen, argon gas, fluorocarbons, compressed air or C2F4, C3F6, the mist of CF4 and H2 etc.) apply a rf electric field and make (or left electrode and right electrode between interior top electrode of reactor and the bottom electrode, external electrode and interior electrode, or electrodless discharge) produce corona discharge (Corona Discharge), dielectric barrier discharge (Dielectric Barrier Discharge, DBD) or glow discharge (Glow Discharge) etc., make ambient gas molecule absorption electric energy form low temperature plasma.Plasma is the high material aggregation attitude of a kind of energy, and it has comprised atom, molecule and the free radical isoreactivity particle of a large amount of electronics, ion, ultraviolet photon, excitation state.These particles always are in constant motion, and bump each other and effects such as ionization excites, compound and light radiation take place.These high energy particles are by radiation, ion stream, neutral molecule stream bump fiber and polymer surface, energy is transferred to fibrous material, dissipation along with energy, cause fiber, polymer surface produces the etching of a series of complexity, physical modifications such as parsing and ionization change and dehydrogenation, addition, oxidation, reduction, crosslinked, polymerization, chemical modification such as cracking and grafting changes, surface chemistry is formed and physics dynamically all changes, thereby make the material surface performance obtain to optimize, increased surperficial wettability (reducing surface tension makes some polymer fiber have water imbibition), WATER REPELLENCY (making some cloth have the antifouling character of waterproof), stainability (is introduced and a large amount of contained oxygen and oxygen-free hydrophilic radical thereby improved colouring speed and the dyeing saturation value of fabric to dyestuff greatly, thereby simultaneously the roughening of fiber surface increased absorption of incident light produced hyperchromic effect improved the coloration of textile materials performance), cementability (improve adhesive property and increase rate of dyeing), crease and shrink resistance (especially fleece material being had the passivation shrinkproof result of shrinkage factor reduction more than 90%), anti-UV, fungi-proofing property, antistatic behaviour etc., also can eliminate formaldehyde residual on the fabric, volatile materials, harmful substances such as sensitiveness gas and peculiar smell, there is destarch concise and remove the effect of natural impurity, the target that realizes producing ecological textile to COTTON FABRIC.
Textiles helps the absorption of dyestuff in the dyeing course subsequently and to the fibrous inside diffusion, dyeing time shortening, production efficiency is improved through plasma pretreatment.Plasma pretreatment has been save the use that influence weaving official ceremonial dresses such as traditional printing and dyeing assistant, salt, reductant, surfactant the material of security.Low temperature plasma is gas-solid two alternate cleaning technologies to the processing of the textiles dry method treatment technology as a kind of anhydrous processing, and water consumption does not have waste liquid and discharges, and environment is not polluted.Surface modification of low temperature plasma only influences material surface top layer as thin as a wafer, have only tens of dusts (＜8-10nm) do not decrease material matrix, keep the original integrality of material.
3, adopt the ultrasonic oscillation technology, can in liquid, produce cavitation effect and cavitation effect, except the even dispersion and emulsification that help dyestuff, can also remove the rigidity of textiles, strengthen chromatophilia.
4, be built-in with one or more groups reel-to-reel or axle to axle wind, make that twining (folding and unfolding of textiles) at the uniform velocity carries out in reactor inside, realizes non-intermittent serialization industrial production.
Description of drawings
Fig. 1 is first kind of embodiment schematic diagram of the present invention.
The specific embodiment
Also the present invention is described in further detail in conjunction with the accompanying drawings below by specific embodiment.
Embodiment one, identical reaction kettle reel-to-reel plasma ultrasonic supercritical textiles non-aqueous dyeing, grey cloth is packed on the reel-to-reel or axle to axle wind (21) in the reactor, the reactor of the high pressure resistant clear glass of airtight usefulness being made with vavuum pump (Roots vaccum pump of preferred big rate of air sucked in required) (11) vacuumizes (to 10Pa), from gas cylinder (34) to reactor (11) aerating oxygen, give the top electrode (32) and bottom electrode (33) energising of the interior plasma generator of reactor (11) (31), by Langmuir (Langmuir) probe measurement plasma parameter, opening reel-to-reel or axle to axle wind (21) makes textiles begin at the uniform velocity to reel, adopt the low pressure glow discharge of capacitive couplings to make the surface of textiles that modification take place, outage stops plasma reaction and will handle the small amount of exhaust gas discharge reactor that textiles produces, with high-pressure pump (12) liquid carbon dioxide is pumped into reactor (11) from carbon dioxide storage bottle (13) and/or carbon dioxide basin (16), the First Astronautic Research Institute for Measurement and Test needs the DISPERSE DYES of natural origin or special-purpose synthetic dyestuffs and by a small amount of liquid carbon dioxide dyestuff is poured reactor (11) from dyestuff jar (14), make it be in temperature by heat-exchange device (preferably being installed in the PTC formula heater of reactor outer bottom) heating carbon dioxide and reach 10 ℃ to 170 ℃ (preferred 70-90 ℃), pressure reaches the supercriticality of 10 to 30MPa (preferred 28MPa), with supercriticality CO 2 fluid as the solvent and the dyeing medium of dyestuff, opening the agitating device (42) be equipped with the inferior joint of Weir (power transmission shaft with external motor linked to each other fetch guarantee dynamic seal (packing) by this joint) and/or ultrasonic generator simultaneously drives ultrasonic transducer (41) and produces cavitation effect and cavitation effect and make dyestuff even dispersion and emulsification and contaminate textiles in supercritical CO 2 medium, opening reel-to-reel or axle to axle wind (21) (be equipped with the inferior joint of Weir and guarantee dynamic seal (packing)) makes textiles begin at the uniform velocity to reel, after coiling finishes, alternative oppositely at the uniform velocity backrush until even dyeing, by the cooling means the interior temperature of reactor (11) is returned to normal temperature, by valve (18) and pipeline (19) release of carbon dioxide, extraction is reclaimed uncured residual dye to dyestuff recycling can (15), and it is middle for system's repeated use by condenser (17) carbon dioxide to be recycled to carbon dioxide basin (16), takes out dyed textiles when the pressure in the question response still is reduced to normal pressure and finish a workflow from reactor.
Plasma is realized the modification of material surface is handled, and ultrasonic wave is uniformly dispersed dyestuff, and supercritical carbon dioxide is realized non-aqueous dyeing, and reel-to-reel is realized non-intermittent serialization industrial production.The present invention is widely used in the non-aqueous dyeing of textiles such as the yarn, cloth (comprising nonwoven fabric), ready-made clothes of natural fabric, artificial synthetic fiber or blending, but comprise the surface modification and the dyeing of other coiling materials (comprising biomaterial) such as sheet metal, plastic sheeting, paper, can satisfy the harshest environmental protection and the requirement of Product Safety.
Claims (4)
1. identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing method, it is characterized in that comprising the following steps: with yarn, textiles such as grey cloth or ready-made clothes is packed on the reel-to-reel or axle to axle wind in the reactor, with vavuum pump reactor is vacuumized, from gas cylinder to the mixture or the compressed air of reactor aerating oxygen or nitrogen or argon gas or fluorocarbons or above-mentioned gas, give the top electrode and the bottom electrode energising of plasma generator in the reactor, opening reel-to-reel or axle to axle wind makes textiles begin at the uniform velocity to reel, make textiles under the effect of the plasma of rf electric field discharge generation, surface modification take place, outage stops plasma reaction and will handle the small amount of exhaust gas discharge reactor that textiles produces, with high-pressure pump liquid carbon dioxide is pumped into reactor from carbon dioxide storage bottle and/or carbon dioxide basin, the First Astronautic Research Institute for Measurement and Test needs dyestuff and by a small amount of liquid carbon dioxide dyestuff is poured reactor from the dyestuff jar, make it be in the supercriticality that temperature reaches 10 ℃ to 170 ℃ by heat-exchange device heating carbon dioxide, with solvent and the dyeing medium of supercritical carbon dioxide fluid as dyestuff, open agitating device simultaneously and/or drive ultrasonic transducer and produce cavitation effect and cavitation effect and make dyestuff evenly dispersion and emulsification and contaminate textiles in supercritical CO 2 medium by ultrasonic generator, opening reel-to-reel or axle to axle wind makes textiles begin at the uniform velocity to reel, after coiling finishes, alternative oppositely at the uniform velocity backrush until even dyeing, by cooling or intensification means reactor temperature is returned to normal temperature, by valve and pipeline release of carbon dioxide, extraction is reclaimed uncured residual dye to the dyestuff recycling can, and by condenser carbon dioxide is recycled in the carbon dioxide basin for system and reuses, from reactor, take out dyed textiles when the pressure in the question response still is reduced to normal pressure and finish a workflow.
2. identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing method as claimed in claim 1 is characterized in that: described dyestuff is the disperse dyes or the synthetic dyestuffs of natural origin.
3. identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing system, comprise the master control platform, carbon dioxide storage bottle, high-pressure pump, the dyestuff jar, heat-exchange device, reactor, the dyestuff recycling can, filter, condenser, the liquid carbon dioxide basin, flowmeter, valve and pipeline, it is characterized in that: described reactor is equipped with the top electrode and the bottom electrode of plasma generator, air bleeding valve, vavuum pump, be built-in with one or more groups reel-to-reel or axle to axle wind and corresponding motor, be built-in with one or more groups agitating device and corresponding motor, be embedded with the ultrasonic transducer that is connected with ultrasonic generator.
4. identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing as claimed in claim 3 system is characterized in that: the Langmuir probe that temperature sensor, pressure sensor, vacuum transducer, fluid sensor is housed in the described reactor and measures plasma parameter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008103010635A CN101555665A (en) | 2008-04-11 | 2008-04-11 | Identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008103010635A CN101555665A (en) | 2008-04-11 | 2008-04-11 | Identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101555665A true CN101555665A (en) | 2009-10-14 |
Family
ID=41173929
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008103010635A Pending CN101555665A (en) | 2008-04-11 | 2008-04-11 | Identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101555665A (en) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101812810A (en) * | 2010-04-27 | 2010-08-25 | 大连工业大学 | Supercritical carbon dioxide dyeing method of ready-made clothes |
| CN101824760A (en) * | 2010-04-07 | 2010-09-08 | 大连工业大学 | Supercritical carbon dioxide art dyeing method |
| CN101922121A (en) * | 2010-08-11 | 2010-12-22 | 浙江理工大学 | New dyeing method of active dye taking methylsiloxane as medium |
| CN101994219A (en) * | 2010-12-09 | 2011-03-30 | 张家港三得利染整科技有限公司 | Equipment for dying cotton-containing yarn |
| CN102286861A (en) * | 2010-06-21 | 2011-12-21 | 香港纺织及成衣研发中心 | Low-pressure dyeing device for cloths and dyeing method thereof |
| CN102493135A (en) * | 2011-11-14 | 2012-06-13 | 淄博兰雁集团有限责任公司 | Surface treatment method and equipment of fabrics |
| CN106460278A (en) * | 2014-04-09 | 2017-02-22 | Akmey巴西化学工业贸易有限公司 | Method for dyeing cellulose fibres in gaseous medium and method of applying method in textile |
| CN104786666B (en) * | 2014-01-19 | 2017-03-15 | 佛山市顺德区高宝实业发展有限公司 | The manufacturing process of printer ink-providing sponge and dye ink-stick machine |
| CN106757915A (en) * | 2016-12-02 | 2017-05-31 | 青岛即发集团股份有限公司 | A kind of cylinder yarn non-aqueous dyeing equipment, colouring method and product |
| WO2018090488A1 (en) * | 2016-11-21 | 2018-05-24 | 大连工业大学 | Integrated waterless scouring, bleaching, and dyeing device using supercritical carbon dioxide fluid |
| CN108744713A (en) * | 2018-05-21 | 2018-11-06 | 江苏亿茂滤材有限公司 | A kind of the ultrasonic wave sputtering liquid charging unit and charging method of electret |
| CN110565415A (en) * | 2019-10-11 | 2019-12-13 | 上海复璐帝流体技术有限公司 | Supercritical carbon dioxide printing and dyeing process and printing and dyeing system thereof |
| CN112225582A (en) * | 2020-11-23 | 2021-01-15 | 航天建筑设计研究院有限公司阳泉航天材料应用技术分公司 | Coiled material modification device |
| WO2021121409A1 (en) * | 2019-12-18 | 2021-06-24 | 上海复璐帝流体技术有限公司 | Pulse-type supercritical carbon dioxide printing and dyeing device |
| CN113039215A (en) * | 2018-11-19 | 2021-06-25 | Cens材料有限公司 | Dispersion of small-sized materials via cavitation |
| CN114044531A (en) * | 2021-11-24 | 2022-02-15 | 李枭 | Production equipment and production process of magnesium hydroxide |
| CN115595811A (en) * | 2022-10-29 | 2023-01-13 | 广东御纺新材料科技有限公司（Cn） | Zero-emission production process for cloth dyeing |
-
2008
- 2008-04-11 CN CNA2008103010635A patent/CN101555665A/en active Pending
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101824760A (en) * | 2010-04-07 | 2010-09-08 | 大连工业大学 | Supercritical carbon dioxide art dyeing method |
| CN101812810A (en) * | 2010-04-27 | 2010-08-25 | 大连工业大学 | Supercritical carbon dioxide dyeing method of ready-made clothes |
| CN102286861A (en) * | 2010-06-21 | 2011-12-21 | 香港纺织及成衣研发中心 | Low-pressure dyeing device for cloths and dyeing method thereof |
| CN102286861B (en) * | 2010-06-21 | 2012-11-28 | 香港纺织及成衣研发中心 | Low-pressure dyeing device for cloths and dyeing method thereof |
| CN101922121A (en) * | 2010-08-11 | 2010-12-22 | 浙江理工大学 | New dyeing method of active dye taking methylsiloxane as medium |
| CN101922121B (en) * | 2010-08-11 | 2012-09-26 | 浙江理工大学 | New dyeing method of active dye taking methylsiloxane as medium |
| CN101994219A (en) * | 2010-12-09 | 2011-03-30 | 张家港三得利染整科技有限公司 | Equipment for dying cotton-containing yarn |
| CN102493135A (en) * | 2011-11-14 | 2012-06-13 | 淄博兰雁集团有限责任公司 | Surface treatment method and equipment of fabrics |
| CN102493135B (en) * | 2011-11-14 | 2013-12-04 | 淄博兰雁集团有限责任公司 | Surface treatment method and equipment of fabrics |
| CN104786666B (en) * | 2014-01-19 | 2017-03-15 | 佛山市顺德区高宝实业发展有限公司 | The manufacturing process of printer ink-providing sponge and dye ink-stick machine |
| CN106460278A (en) * | 2014-04-09 | 2017-02-22 | Akmey巴西化学工业贸易有限公司 | Method for dyeing cellulose fibres in gaseous medium and method of applying method in textile |
| WO2018090488A1 (en) * | 2016-11-21 | 2018-05-24 | 大连工业大学 | Integrated waterless scouring, bleaching, and dyeing device using supercritical carbon dioxide fluid |
| US10801146B2 (en) | 2016-11-21 | 2020-10-13 | Dalian Polytechnic University | System for anhydrous boiling, bleaching and dyeing using supercritical carbon dioxide fluid |
| WO2018098885A1 (en) * | 2016-12-02 | 2018-06-07 | 青岛即发集团股份有限公司 | Waterless dyeing device and method for bobbin yarn, and product |
| CN106757915A (en) * | 2016-12-02 | 2017-05-31 | 青岛即发集团股份有限公司 | A kind of cylinder yarn non-aqueous dyeing equipment, colouring method and product |
| US11168424B2 (en) | 2016-12-02 | 2021-11-09 | Qingdao Jifa Group Co., Ltd. | Waterless dyeing device and method for bobbin yarn, and product |
| CN108744713A (en) * | 2018-05-21 | 2018-11-06 | 江苏亿茂滤材有限公司 | A kind of the ultrasonic wave sputtering liquid charging unit and charging method of electret |
| CN113039215A (en) * | 2018-11-19 | 2021-06-25 | Cens材料有限公司 | Dispersion of small-sized materials via cavitation |
| CN110565415A (en) * | 2019-10-11 | 2019-12-13 | 上海复璐帝流体技术有限公司 | Supercritical carbon dioxide printing and dyeing process and printing and dyeing system thereof |
| WO2021068277A1 (en) * | 2019-10-11 | 2021-04-15 | 上海复璐帝流体技术有限公司 | Supercritical carbon dioxide printing and dyeing process and printing and dyeing system thereof |
| TWI703254B (en) * | 2019-10-11 | 2020-09-01 | 大陸商上海複璐帝流體技術有限公司 | Supercritical carbon dioxide printing and dyeing process and the system thereof |
| JP2022507993A (en) * | 2019-10-11 | 2022-01-19 | 上海複▲路▼帝流体技術有限公司 | Supercritical carbon dioxide dyeing process and its dyeing system |
| WO2021121409A1 (en) * | 2019-12-18 | 2021-06-24 | 上海复璐帝流体技术有限公司 | Pulse-type supercritical carbon dioxide printing and dyeing device |
| CN112225582A (en) * | 2020-11-23 | 2021-01-15 | 航天建筑设计研究院有限公司阳泉航天材料应用技术分公司 | Coiled material modification device |
| CN112225582B (en) * | 2020-11-23 | 2024-01-19 | 航天建筑设计研究院有限公司阳泉航天材料应用技术分公司 | Coiled material modifying device |
| CN114044531A (en) * | 2021-11-24 | 2022-02-15 | 李枭 | Production equipment and production process of magnesium hydroxide |
| CN115595811A (en) * | 2022-10-29 | 2023-01-13 | 广东御纺新材料科技有限公司（Cn） | Zero-emission production process for cloth dyeing |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101555665A (en) | Identical reaction kettle reel-to-reel plasma ultrasonic supercritical non-aqueous dyeing | |
| CN100494561C (en) | Technology for dyeing ramie fiber with supercritical carbon dioxide method | |
| Hou et al. | Using supercritical carbon dioxide as solvent to replace water in polyethylene terephthalate (PET) fabric dyeing procedures | |
| CN101602299A (en) | Plasma on-line real-time pretreating printing system | |
| CN106757915A (en) | A kind of cylinder yarn non-aqueous dyeing equipment, colouring method and product | |
| CN106337283A (en) | Preparation method of hydrophilic mesh cloth or fabric applicable to oil-water separation | |
| CN104195854A (en) | Dyeing and finishing process with zero emission | |
| Li et al. | The application of He/O2 atmospheric pressure plasma jet and ultrasound in desizing of blended size on cotton fabrics | |
| CN102433700B (en) | Ultrasonic atomization bleaching equipment | |
| CN201627072U (en) | Cleaner production device in printing and dyeing industry | |
| CN109082792A (en) | A kind of ethyl alcohol overflow dyeing machine | |
| CN106757919B (en) | A kind of efficiently comprehensive water reuse dye vat | |
| CN108486789A (en) | A kind of textile high-efficient automatic dyeing and printing device | |
| CN105568591B (en) | The hydrogen peroxide desizing pretreatment process of cotton in a kind of supercritical carbon dioxide fluid | |
| CN205275949U (en) | Anhydrous dyeing system of overcritical CO2 | |
| CN110106721A (en) | A kind of emission reduction plasma dyeing and finishing technology | |
| CN110318268A (en) | A kind of reactive dyeing raffinate recycling method | |
| CN206127641U (en) | Quick automatic line equipment that dyes | |
| CN113046957B (en) | Feather fiber supercritical CO 2 Anhydrous dyeing device and dyeing method thereof | |
| CN104631149A (en) | Anhydrous and little-water environment-friendly dyeing technology | |
| CN107596893A (en) | Exhaust gas purification and treatment device | |
| CN109455856A (en) | A method of waste water containing acrylic acid is handled using microwave irradiation technology | |
| CN111021071A (en) | Mosquito-proof waterproof finishing agent and supercritical carbon dioxide anhydrous finishing method thereof | |
| CN206616365U (en) | The zero-emission HTHP dye vat of comprehensive Water circulation | |
| CN208486058U (en) | Textile high-efficient automatic dyeing and printing device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20091014 |