CN101546505B - Manufacturing process for self luminescent membrane with shading light of back side and luminescence of front side and product produced by same - Google Patents
Manufacturing process for self luminescent membrane with shading light of back side and luminescence of front side and product produced by same Download PDFInfo
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- CN101546505B CN101546505B CN2009100495361A CN200910049536A CN101546505B CN 101546505 B CN101546505 B CN 101546505B CN 2009100495361 A CN2009100495361 A CN 2009100495361A CN 200910049536 A CN200910049536 A CN 200910049536A CN 101546505 B CN101546505 B CN 101546505B
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- autoluminescence
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Abstract
The invention relates to a manufacturing process for a self luminescent membrane with shading light of a back side and luminescence of a front side and a product produced by the same. Components comprising alkaline earth aluminium-silicate are mixed to manufacture a self luminescent material membrane which is adhered to a paper base and can be taken down from the paper base for use. The manufacturing process comprises the following steps: compounding the self luminescent material membrane and a polyvinyl chloride white membrane into a whole by heating and rolling; printing a layer of blacking coating on the back side of the polyvinyl chloride white membrane; and adhering the side printed with the black coating in the self luminescent membrane to the paper base. The manufacturing process has the advantages that: on the basis of manufacturing the self luminescent material membrane by mixing the components comprising the alkaline earth aluminium-silicate, the back side of the self luminescent material membrane is printed with the light shielding black coating to manufacture the self luminescent membrane with the functions of the shading light of the back side and the luminescence of the front side; and the self luminescent membrane can effectively cover the background of an adhered surface to make the background not appeared, improve the visual effect of the product, and can be widely applicable to manufacturing an adhesive film, an advertisement sticker, and other film products.
Description
Technical field
The present invention relates to a kind of manufacture craft of self-luminescent material, the manufacture craft and the product of the shading of especially a kind of back side, positive luminous autoluminescence film.
Background technology
Traditional self-luminescent material mainly comprises sulfide based luminescent material, alkaline-earth aluminosilicate based luminescent material.
The poor stability of sulfide based luminescent material, can decompose under the strong out of doors ultraviolet radiation, luminance brightness descends, and the luminous duration of sulfide based luminescent material is short, have only dozens of minutes to arrive several hrs, want to prolong fluorescent lifetime and improve brightness, need to add radioelement, but pollute the environment like this;
And the alkaline-earth aluminosilicate based luminescent material is after the light source short irradiation, can radiate visible light at the dark place, its luminous duration was more than tens hours, and original intensity and afterglow property improve greatly, was better than sulfide base long persistence luminescent material in the past far away.
Disclose a kind of rare-earth activated aluminosilicate long after glow luminous material and preparation method thereof as Chinese Granted publication CN1130440, luminescent material comprises alkaline earth oxide, Al
2O
3And SiO
2, alkaline earth oxide comprises one or more among SrO, CaO, MgO and the BaO again.And for example Chinese patent publication number CN101138278 equally also discloses a kind of fluorescent material, is that a kind of general formula is (Ca
1-x-y-zSr
xBa
yMg
z)
1-n(Al
1-a+bB
a) Si
1-bN
3-bO
b: RE
nThe oxygen nitrogen aluminosilicate that activates of rare earth metal.
This alkaline earth aluminosilicate can be used as fluorescent material and uses in specific product, and CN101054292 discloses a kind of super-white polished brick as the Chinese patent publication number, is that a kind of silico-aluminate with MgO is the pottery of principal crystalline phase.
And existing luminescent material thin-film is made up of PVC material and netted leaded light glass fibre, and it is good to have pliability, and printing opacity is even, is convenient to the characteristics of cutting apart, splice, consigning, and also is fit to the air brushing manufacturing.But this material is all combined by organic material, and its hardness, heat distortion temperature, dimensional stability and reduction shrinkage factor are not fine, and its electrical insulating property and flame resistance are also undesirable sometimes in addition.
For solving the shortcoming that alkaline earth aluminosilicate is not suitable for making film products such as pad pasting or advertisement subsides, applicant of the present invention is in its patent of invention of having declared, a kind of self-luminescent material is disclosed in the application number 200910045523.7, with the Polyvinylchloride is matrix, mix with alkaline earth aluminosilicate, through the calendering film forming.
But in use, because this self-luminescent material is transparent material, behind the surface that pastes in building etc., can be appeared by the color of the face of pasting itself, thereby the whole visual effect of putting up film or advertisement subsides of influence, this becomes the problem that the applicant need capture again.
Summary of the invention
Technical matters to be solved by this invention is to provide the manufacture craft of the shading of a kind of back side, positive luminous autoluminescence film, adopt not only partial front autoluminescence of product that this manufacture craft obtains, and be easy to make the effect of pad pasting or advertisement subsides, also can effectively hide, further improve result of use by the face of pasting.
The back side shading that provides a kind of above-mentioned technology to make, positive luminous autoluminescence film are provided another technical matters to be solved by this invention.
The present invention solves the problems of the technologies described above the technical scheme of being taked: the manufacture craft of the shading of a kind of back side, positive luminous autoluminescence film, each component that will comprise alkaline earth aluminosilicate is mixed and made into the self-luminescent material film, the self-luminescent material film is bonded on the paper substrate and can takes off use on this paper substrate, and manufacture craft is:
The first step: self-luminescent material film and the logical hot calender of Polyvinylchloride tunica albuginea are combined into one;
Second step:, constitute back side shading, positive luminous autoluminescence film at back up one deck blackwash of Polyvinylchloride tunica albuginea;
The face that is printed with blackwash in the autoluminescence film is bonded on the paper substrate, and to its processing of punching.
On the basis of such scheme, shading overleaf, positive luminous autoluminescence film front are coated with advertisement picture by spray-drawing process, make back side shading, positive luminous self-luminescence advertisement film.
On the basis of such scheme, described self-luminescent material film is made by calendering with self-luminescent material, and this self-luminescent material comprises following component in weight portion:
100 parts of Polyvinylchloride
15～35 parts of alkaline earth aluminosilicates
20～40 parts in plastifier
0.1～8 part of stabilizing agent
0～10 part of acryl resin multipolymer and/or haloflex, wherein,
Described alkaline earth aluminosilicate is Powdered, and its fineness is 100～200 orders.
Concrete, in Polyvinylchloride 100 weight portions, the alkaline earth aluminosilicate powder can be 15,18,20,22,25,28,30,32 or 35 weight portions; Plastifier can be 20,22,25,28,30,32,35,38 or 40 weight portions; Stabilizing agent can be 0.1,0.5,1.0,2.0,3.0,3.5,4.0,5.0,6.0,7.0 or 8.0 weight portions; Acryl resin multipolymer and/or haloflex can be 0,1,2,3,4,5,6,7,8,9 or 10 weight portions.
Described alkaline earth aluminosilicate fineness of powder can be specifications such as 100,120,150,180 or 200 orders.
On the technique scheme basis, described plastifier is terephthalic acid (TPA) two (the 2-ethyl is an own) ester, diallyl phthalate, dioctyl phthalate, Bis(2-ethylhexyl) terephthalate, diethyl phthalate, diisobutyl phthalate, diisooctyl phthalate, dinonyl phthalate, diisooctyl phthalate, misery 13 esters of O-phthalic, phthalic acid fourth 14 esters, capryl octyl phthalate, O-phthalic ester butyl benzyl, phthalic acid two (methoxyl second) ester, phthalic acid two (methoxyl second) ester, phthalic acid C6～C10 n-alkanol mixed ester, phthalic acid C7～C10 alcohol mixed ester, dibutyl phthalate, di-sec-octyl phthalate, diisononyl phthalate, dicyclohexyl phthalate, trioctyl trimellitate, liquid nitrile rubber, the combination of one or several in chlorinated paraffin and the epoxidized soybean oil.
On the technique scheme basis, described stabilizing agent is one or two or more kinds the composition in barium-chromium-zinc stabilizer, zinc stearate, barium stearate, dolomol, liquid calcium zinc stabilizer, tribasic lead sulfate, dibasic lead phosphite, organic tin stabilizer, the liquid cadmium barium zinc stabilizer.
On the technique scheme basis, described Polyvinylchloride is for adopting the Polyvinylchloride of suspension method preparation.
On the basis of such scheme, the present invention adopts applicant's disclosed a kind of green black paint in its application for a patent for invention numbers 200710043721.0, can solve the shading problem of polychloroethylene film, and it is strong with the polychloroethylene film absorption affinity, strong again with the adhesion of pressure sensitive adhesive, can not occur separating or residual phenomena.
Described blackwash comprises following component by weight percentage:
Black dyes 8～12%
Butyl acrylate 15～25%
Chlorosulfonation polypropylene 5～10%
Teflon 15～25%
Polystyrene 4～6%
Auxiliary agent 0.05～0.15%
Surplus is a solvent.
Wherein, by weight percentage:
Black dyes can be any amount in 8%, 9%, 10%, 11%, 12%; Butyl acrylate can be any amount in 15%, 17%, 19%, 21%, 23%, 25%; The chlorosulfonation polypropylene can be any amount in 5%, 6%, 7%, 8%, 9%, 10%; Teflon can be any amount in 15%, 17%, 19%, 21%, 23%, 25%; Polystyrene can be any amount in 4%, 4.5%, 5%, 5.5%, 6%; Auxiliary agent can be any amount in 0.05%, 0.075%, 0.1%, 0.125%, 0.15%.
Described auxiliary agent comprises wetting agent, catalyzer, levelling agent, antioxidant and hardening agent, and wherein, described wetting agent is a glycerine, and catalyzer is a tygon, and levelling agent is a polyacrylate, and antioxidant is amine type antioxidant, and hardening agent is an epoxy resin.
Described organic solvent is a toluene.
At back side shading, positive luminous autoluminescence film that above-mentioned manufacture craft makes, wherein, described autoluminescence film is a layer structure, is followed successively by self-luminescent material film and the back up Polyvinylchloride tunica albuginea by black coating from top to bottom.
The invention has the beneficial effects as follows:
1, the present invention is mixed and made on the basis of self-luminescent material film in each component that comprises alkaline earth aluminosilicate, coat the blackwash of shading at the back side of self-luminescent material film, the autoluminescence film of making has back side shading, positive luminous effect, can make it not appear with being covered effectively, improve the visual effect of product by the background on the face of pasting;
2, can be widely used in making on the film product of pad pasting or advertisement subsides and so on, not contain any radiomaterial and noxious material, fully compliance with environmental protection requirements;
3, luminescenjt powder can absorb various visible lights with particulate form below 450 nanometers and particulate polyvinyl chloride combination, various light sources is all had well hold light, illumination effect, especially the shortwave light below 450 nanometers is had very strong receptivity.
Embodiment
The manufacture craft of the shading of a kind of back side, positive luminous autoluminescence film, each component that will comprise alkaline earth aluminosilicate is mixed and made into the self-luminescent material film, and the self-luminescent material film is bonded on the paper substrate and can takes off use on this paper substrate, and manufacture craft is:
The first step: self-luminescent material film and the logical hot calender of Polyvinylchloride tunica albuginea are combined into one;
Second step:, constitute back side shading, positive luminous autoluminescence film at back up one deck blackwash of Polyvinylchloride tunica albuginea;
The face that is printed with blackwash in the autoluminescence film is bonded on the paper substrate, and to its processing of punching.
Wherein, described self-luminescent material comprises following component in weight portion:
100 parts of suspension type polyvinyl-chlorides
15 parts in alkaline earth aluminosilicate powder (200 order)
40 parts in plastifier (DOP)
1 part of stabilizing agent (zinc stearate: barium-chromium-zinc stabilizer is 2: 1)
1 part of haloflex;
Described alkaline earth aluminosilicate is Powdered, and its fineness is 100～200 orders.
With the method for the manufacturing autoluminescence film of self-luminescent material, carry out according to the following step:
Step 1,100 parts of Polyvinylchloride, 40 parts of plastifier, 1 part of stabilizing agent, 1 part of haloflex are added the mixer high speed and stir, it is standby to make the pasty state slip;
Add 15 parts of alkaline earth aluminosilicate powder in step 2, the pasty state slip in step 1 and stir, make compound;
Step 3, compound is sent into calender calendering film forming.
Wherein, described blackwash, each components based on weight percentage is:
Dyestuff 8.4%
Butyl acrylate 15.2%
Chlorosulfonation polypropylene 8.2%
Teflon 23.6%
Polystyrene 4.1%
Glycerine 0.05%
Tygon 0.02%
Polyacrylate 0.03%
Amine type antioxidant 0.02%
Epoxy resin 0.01%
Toluene 40.37%.
The preparation method of this blackwash comprises the steps:
The first step: butyl acrylate, chlorosulfonation polypropylene, teflon and the polystyrene of above-mentioned prescription are placed solvent toluene by prescription, and at normal pressure, 20～36 ℃ of following butyl acrylates fully dissolve;
Second step: after 1 hour, add dyestuff, stir and decomposed 20～40 minutes;
The 3rd step: add tygon, polyacrylate, amine type antioxidant, epoxy resin, make viscous paste;
The 4th step: in three-roller, ground 3～4 hours, and, made coating through 5 μ m strainer filterings.
Claims (5)
1. the manufacture craft of a back side shading, positive luminous autoluminescence film, each component that will comprise alkaline earth aluminosilicate is mixed and made into the self-luminescent material film, the self-luminescent material film is bonded on the paper substrate and can takes off use on this paper substrate, it is characterized in that manufacture craft is:
The first step: preparation self-luminescent material film, this self-luminescent material comprises following component in weight portion:
100 parts of Polyvinylchloride
15～35 parts of alkaline earth aluminosilicates
20～40 parts in plastifier
0.1～8 part of stabilizing agent
0～10 part of acryl resin multipolymer and/or haloflex,
Described alkaline earth aluminosilicate is Powdered, and its fineness is 100～200 orders, and self-luminescent material film and the logical hot calender of Polyvinylchloride tunica albuginea are combined into one;
Second step:, constitute back side shading, positive luminous autoluminescence film at back up one deck blackwash of Polyvinylchloride tunica albuginea;
The face that is printed with blackwash in the autoluminescence film is bonded on the paper substrate, and to its processing of punching.
2. the manufacture craft of the back side according to claim 1 shading, positive luminous autoluminescence film, it is characterized in that: shading overleaf, positive luminous autoluminescence film front are coated with advertisement picture by spray-drawing process, make back side shading, positive luminous self-luminescence advertisement film.
3. the manufacture craft of the back side according to claim 1 shading, positive luminous autoluminescence film, it is characterized in that: described Polyvinylchloride is for adopting the Polyvinylchloride of suspension method preparation.
4. the manufacture craft of the back side according to claim 1 shading, positive luminous autoluminescence film, it is characterized in that: described blackwash comprises following component by weight percentage:
Black dyes 8～12%
Butyl acrylate 15～25%
Chlorosulfonation polypropylene 5～10%
Teflon 15～25%
Polystyrene 4～6%
Auxiliary agent 0.05～0.15%
Surplus is a solvent.
5. the back side shading that makes as the described manufacture craft of one of claim 1 to 4, positive luminous autoluminescence film, it is characterized in that: described autoluminescence film is a layer structure, is followed successively by self-luminescent material film and the back up Polyvinylchloride tunica albuginea by black coating from top to bottom.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100495361A CN101546505B (en) | 2009-04-17 | 2009-04-17 | Manufacturing process for self luminescent membrane with shading light of back side and luminescence of front side and product produced by same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100495361A CN101546505B (en) | 2009-04-17 | 2009-04-17 | Manufacturing process for self luminescent membrane with shading light of back side and luminescence of front side and product produced by same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101546505A CN101546505A (en) | 2009-09-30 |
| CN101546505B true CN101546505B (en) | 2010-07-21 |
Family
ID=41193617
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100495361A Expired - Fee Related CN101546505B (en) | 2009-04-17 | 2009-04-17 | Manufacturing process for self luminescent membrane with shading light of back side and luminescence of front side and product produced by same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101546505B (en) |
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2009
- 2009-04-17 CN CN2009100495361A patent/CN101546505B/en not_active Expired - Fee Related
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|---|---|
| CN101546505A (en) | 2009-09-30 |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Zhejiang Shengfeng Plastics Co., Ltd. Assignor: Shanghai Fushun Unidirectional Vision Material Co., Ltd. Contract record no.: 2010330001719 Denomination of invention: Manufacturing process for self luminescent membrane with shading light of back side and luminescence of front side and product produced by same Granted publication date: 20100721 License type: Exclusive License Open date: 20090930 Record date: 20100824 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100721 Termination date: 20150417 |
|
| EXPY | Termination of patent right or utility model |