CN101546504A - Manufacturing method for self luminescent membrane with shading light of back side and luminescence of front side and product produced by same - Google Patents
Manufacturing method for self luminescent membrane with shading light of back side and luminescence of front side and product produced by same Download PDFInfo
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- CN101546504A CN101546504A CN200910049535A CN200910049535A CN101546504A CN 101546504 A CN101546504 A CN 101546504A CN 200910049535 A CN200910049535 A CN 200910049535A CN 200910049535 A CN200910049535 A CN 200910049535A CN 101546504 A CN101546504 A CN 101546504A
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Abstract
The invention relates to a manufacturing method for a self luminescent membrane with shading light of a back side and luminescence of a front side and a product produced by the same. Components comprising alkaline earth aluminum-silicate are mixed to manufacture a self luminescent material membrane which is adhered to a paper base and can be taken down from the paper base for use. The manufacturing method comprises the following steps: superposing the self luminescent material membrane, a polyvinyl chloride white membrane, and a polyvinyl chloride light shielding black membrane in turn, compounding the self luminescent material membrane, the polyvinyl chloride white membrane and the polyvinyl chloride light shielding black membrane into a whole by rolling; and adhering one surface of the polyvinyl chloride light shielding black membrane in the self luminescent membrane to the paper base, and punching the paper base. The manufacturing method has the advantages that: on the basis of manufacturing the self luminescent material membrane by mixing the components comprising the alkaline earth aluminium-silicate, the back side of the self luminescent material membrane is compounded with the polyvinyl chloride light shielding black membrane to manufacture the self luminescent membrane with the functions of the shading light of the back side and the luminescence of the front side; and the self luminescent membrane can effectively cover the background of an adhered surface to make the background not appeared, improve the visual effect of the product, and can be widely applicable to manufacturing an adhesive film, an advertisement sticker, and other film products.
Description
Technical field
The present invention relates to a kind of method for making of self-luminescent material, the method for making and the product of the shading of especially a kind of back side, positive luminous autoluminescence film.
Background technology
Traditional self-luminescent material mainly comprises sulfide based luminescent material, alkaline-earth aluminosilicate based luminescent material.
The poor stability of sulfide based luminescent material, can decompose under the strong out of doors ultraviolet radiation, luminance brightness descends, and the luminous duration of sulfide based luminescent material is short, have only dozens of minutes to arrive several hrs, want to prolong fluorescent lifetime and improve brightness, need to add radioelement, but pollute the environment like this;
And the alkaline-earth aluminosilicate based luminescent material is after the light source short irradiation, can radiate visible light at the dark place, its luminous duration was more than tens hours, and original intensity and afterglow property improve greatly, was better than sulfide base long persistence luminescent material in the past far away.
Disclose a kind of rare-earth activated aluminosilicate long after glow luminous material and preparation method thereof as Chinese Granted publication CN1130440, luminescent material comprises alkaline earth oxide, Al
2O
3And SiO
2, alkaline earth oxide comprises one or more among SrO, CaO, MgO and the BaO again.And for example Chinese patent publication number CN101138278 equally also discloses a kind of fluorescent material, is that a kind of general formula is (Ca
1-x-y-zSr
xBa
yMg
y)
1-n(Al
1-a+bB
a) Si
1-bN
3-bO
b: RE
nThe oxygen nitrogen aluminosilicate that activates of rare earth metal.
This alkaline earth aluminosilicate can be used as fluorescent material and uses in specific product, and CN101054292 discloses a kind of super-white polished brick as the Chinese patent publication number, is that a kind of silico-aluminate with MgO is the pottery of principal crystalline phase.
And existing luminescent material thin-film is made up of PVC material and netted leaded light glass fibre, and it is good to have pliability, and printing opacity is even, is convenient to the characteristics of cutting apart, splice, consigning, and also is fit to the air brushing manufacturing.But this material is all combined by organic material, and its hardness, heat distortion temperature, dimensional stability and reduction shrinkage factor are not fine, and its electrical insulating property and flame resistance are also undesirable sometimes in addition.
For solving the shortcoming that alkaline earth aluminosilicate is not suitable for making film products such as pad pasting or advertisement subsides, applicant of the present invention is in its patent of invention of having declared, a kind of self-luminescent material is disclosed in the application number 200910045523.7, with the Polyvinylchloride is matrix, mix with alkaline earth aluminosilicate, through the calendering film forming.
But in use, because this self-luminescent material is transparent material, behind the surface that pastes in building etc., can be appeared by the color of the face of pasting itself, thereby the whole visual effect of putting up film or advertisement subsides of influence, this becomes the problem that the applicant need capture again.
Summary of the invention
Technical matters to be solved by this invention is to provide the method for making of the shading of a kind of back side, positive luminous autoluminescence film, adopt not only partial front autoluminescence of product that this method for making obtains, and be easy to make the effect of pad pasting or advertisement subsides, also can effectively hide, further improve result of use by the face of pasting.
The back side shading that provides a kind of said method to make, positive luminous autoluminescence film are provided another technical matters to be solved by this invention.
The present invention solves the problems of the technologies described above the technical scheme of being taked: the method for making of the shading of a kind of back side, positive luminous autoluminescence film, each component that will comprise alkaline earth aluminosilicate is mixed and made into the self-luminescent material film, the self-luminescent material film is bonded on the paper substrate and can takes off use on this paper substrate, and method for making is:
Self-luminescent material film, Polyvinylchloride tunica albuginea, Polyvinylchloride shading black film is stacked successively, be combined into one by calendering again, make back side shading, positive luminous autoluminescence film;
The one side of Polyvinylchloride shading black film in the autoluminescence film is bonded on the paper substrate, and to its processing of punching.
On the basis of such scheme, shading overleaf, positive luminous autoluminescence film front are coated with advertisement picture by method for spray-drawing, make back side shading, positive luminous self-luminescence advertisement film.
On the basis of such scheme, described self-luminescent material film is made by calendering with self-luminescent material, and this self-luminescent material comprises following component in weight portion:
100 parts of Polyvinylchloride
15～35 parts of alkaline earth aluminosilicates
20～40 parts in plastifier
0.1～8 part of stabilizing agent
0～10 part of acryl resin multipolymer and/or haloflex, wherein,
Described alkaline earth aluminosilicate is Powdered, and its fineness is 100～200 orders.
Concrete, in Polyvinylchloride 100 weight portions, the alkaline earth aluminosilicate powder can be 15,18,20,22,25,28,30,32 or 35 weight portions; Plastifier can be 20,22,25,28,30,32,35,38 or 40 weight portions; Stabilizing agent can be 0.1,0.5,1.0,2.0,3.0,3.5,4.0,5.0,6.0,7.0 or 8.0 weight portions; Acryl resin multipolymer and/or haloflex can be 0,1,2,3,4,5,6,7,8,9 or 10 weight portions.
Described alkaline earth aluminosilicate fineness of powder can be specifications such as 100,120,150,180 or 200 orders.
On the technique scheme basis, described plastifier is terephthalic acid (TPA) two (the 2-ethyl is an own) ester, diallyl phthalate, dioctyl phthalate, Bis(2-ethylhexyl) terephthalate, diethyl phthalate, diisobutyl phthalate, diisooctyl phthalate, dinonyl phthalate, diisooctyl phthalate, misery 13 esters of O-phthalic, phthalic acid fourth 14 esters, capryl octyl phthalate, O-phthalic ester butyl benzyl, phthalic acid two (methoxyl second) ester, phthalic acid two (methoxyl second) ester, phthalic acid C6～C10 n-alkanol mixed ester, phthalic acid C7～C10 alcohol mixed ester, dibutyl phthalate, di-sec-octyl phthalate, diisononyl phthalate, dicyclohexyl phthalate, trioctyl trimellitate, liquid nitrile rubber, the combination of one or several in chlorinated paraffin and the epoxidized soybean oil.
On the technique scheme basis, described stabilizing agent is one or two or more kinds the composition in barium-chromium-zinc stabilizer, zinc stearate, barium stearate, dolomol, liquid calcium zinc stabilizer, tribasic lead sulfate, dibasic lead phosphite, organic tin stabilizer, the liquid cadmium barium zinc stabilizer.
On the basis of such scheme, described Polyvinylchloride is for adopting the Polyvinylchloride of suspension method preparation.
At back side shading, positive luminous autoluminescence film that above-mentioned method for making makes, wherein, described autoluminescence film is a layer structure, is followed successively by self-luminescent material film, Polyvinylchloride tunica albuginea and Polyvinylchloride shading black film from top to bottom.
The invention has the beneficial effects as follows:
1, the present invention is mixed and made on the basis of self-luminescent material film in each component that comprises alkaline earth aluminosilicate, at the back side of self-luminescent material film composite polrvinyl chloride shading black film, the autoluminescence film of making has back side shading, positive luminous effect, can make it not appear with being covered effectively, improve the visual effect of product by the background on the face of pasting;
2, can be widely used in making on the film product of pad pasting or advertisement subsides and so on, not contain any radiomaterial and noxious material, fully compliance with environmental protection requirements;
3, luminescenjt powder can absorb various visible lights with particulate form below 450 nanometers and particulate polyvinyl chloride combination, various light sources is all had well hold light, illumination effect, especially the shortwave light below 450 nanometers is had very strong receptivity.
Embodiment
The method for making of the shading of a kind of back side, positive luminous autoluminescence film, each component that will comprise alkaline earth aluminosilicate is mixed and made into the self-luminescent material film, and the self-luminescent material film is bonded on the paper substrate and can takes off use on this paper substrate, and method for making is:
Self-luminescent material film, Polyvinylchloride tunica albuginea, Polyvinylchloride shading black film is stacked successively, be combined into one by calendering again, make back side shading, positive luminous autoluminescence film;
The one side of Polyvinylchloride shading black film in the autoluminescence film is bonded on the paper substrate, and to its processing of punching.
Wherein, described self-luminescent material comprises following component in weight portion:
100 parts of suspension type polyvinyl-chlorides
15 parts in alkaline earth aluminosilicate powder (200 order)
40 parts in plastifier (DOP)
1 part of stabilizing agent (zinc stearate: barium-chromium-zinc stabilizer is 2:1)
1 part of haloflex;
Described alkaline earth aluminosilicate is Powdered, and its fineness is 100～200 orders.
With the method for the manufacturing autoluminescence film of self-luminescent material, carry out according to the following step:
Step 1,100 parts of Polyvinylchloride, 40 parts of plastifier, 1 part of stabilizing agent, 1 part of haloflex are added the mixer high speed and stir, it is standby to make the pasty state slip;
Add 15 parts of alkaline earth aluminosilicate powder in step 2, the pasty state slip in step 1 and stir, make compound;
Step 3, compound is sent into calender calendering film forming.
Claims (5)
- The method for making of 1, a kind of back side shading, positive luminous autoluminescence film, each component that will comprise alkaline earth aluminosilicate is mixed and made into the self-luminescent material film, the self-luminescent material film is bonded on the paper substrate and can takes off use on this paper substrate, it is characterized in that method for making is:Self-luminescent material film, Polyvinylchloride tunica albuginea, Polyvinylchloride shading black film is stacked successively, be combined into one by calendering again, make back side shading, positive luminous autoluminescence film;The one side of Polyvinylchloride shading black film in the autoluminescence film is bonded on the paper substrate, and to its processing of punching.
- The method for making of 2, back side shading according to claim 1, positive luminous autoluminescence film, it is characterized in that: shading overleaf, positive luminous autoluminescence film front are coated with advertisement picture by method for spray-drawing, make back side shading, positive luminous self-luminescence advertisement film.
- The method for making of 3, back side shading according to claim 1, positive luminous autoluminescence film, it is characterized in that: described self-luminescent material film is made by calendering with self-luminescent material, and this self-luminescent material comprises following component in weight portion:100 parts of Polyvinylchloride15～35 parts of alkaline earth aluminosilicates20～40 parts in plastifier0.1～8 part of stabilizing agent0～10 part of acryl resin multipolymer and/or haloflex, wherein,Described alkaline earth aluminosilicate is Powdered, and its fineness is 100～200 orders.
- The method for making of 4, back side shading according to claim 3, positive luminous autoluminescence film, it is characterized in that: described Polyvinylchloride is for adopting the Polyvinylchloride of suspension method preparation.
- 5, the back side shading that makes at the described method for making of one of claim 1 to 4, positive luminous autoluminescence film, it is characterized in that: described autoluminescence film is a layer structure, is followed successively by self-luminescent material film, Polyvinylchloride tunica albuginea and Polyvinylchloride shading black film from top to bottom.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910049535A CN101546504A (en) | 2009-04-17 | 2009-04-17 | Manufacturing method for self luminescent membrane with shading light of back side and luminescence of front side and product produced by same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910049535A CN101546504A (en) | 2009-04-17 | 2009-04-17 | Manufacturing method for self luminescent membrane with shading light of back side and luminescence of front side and product produced by same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101546504A true CN101546504A (en) | 2009-09-30 |
Family
ID=41193616
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910049535A Pending CN101546504A (en) | 2009-04-17 | 2009-04-17 | Manufacturing method for self luminescent membrane with shading light of back side and luminescence of front side and product produced by same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101546504A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102896848A (en) * | 2011-07-29 | 2013-01-30 | 上海大巨龙蓬盖新材料有限公司 | Manufacturing method of unidirectional perspective paste with single-sided printing and picture displayed at both inside and outside |
| CN111204102A (en) * | 2020-01-11 | 2020-05-29 | 深圳市博耀新材料有限公司 | Plastic smooth surface and injection molding process |
-
2009
- 2009-04-17 CN CN200910049535A patent/CN101546504A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102896848A (en) * | 2011-07-29 | 2013-01-30 | 上海大巨龙蓬盖新材料有限公司 | Manufacturing method of unidirectional perspective paste with single-sided printing and picture displayed at both inside and outside |
| CN102896848B (en) * | 2011-07-29 | 2015-08-19 | 上海大巨龙蓬盖新材料有限公司 | The manufacture method of the one way perspective paste of display frame inside and outside a kind of one side air brushing |
| CN111204102A (en) * | 2020-01-11 | 2020-05-29 | 深圳市博耀新材料有限公司 | Plastic smooth surface and injection molding process |
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Open date: 20090930 |