CN101544800A - Formula of environment-friendly edge sealing tape - Google Patents
Formula of environment-friendly edge sealing tape Download PDFInfo
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- CN101544800A CN101544800A CN200810028245A CN200810028245A CN101544800A CN 101544800 A CN101544800 A CN 101544800A CN 200810028245 A CN200810028245 A CN 200810028245A CN 200810028245 A CN200810028245 A CN 200810028245A CN 101544800 A CN101544800 A CN 101544800A
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Abstract
The invention relates to the technical field of composite materials, in particular to a formula of an environment-friendly edge sealing tape. The formula comprises the following components: polyvinyl chloride, calcium carbonate, chlorinated polyethylene, external lubricant, calcium-zinc stabilizing agent and plasticizing agent. By using the plasticizing agent with different mixing ratios, edge sealing tape materials with different hardness can be prepared. The formula does not influence the physical properties of PVC such as mechanical property, fire resistance, high-strength weather resisting property and the like, uses little polyvinyl chloride and has low cost; and a product does not contain phthalate and heavy metals to damage human body; therefore, the environment-friendly requirement is achieved.
Description
Technical field:
The present invention relates to technical field of composite materials, particularly a kind of prescription of environment-friendly edge sealing tape.
Background technology:
Edge sealing bar commonly used in the home decoration generally divides log edge sealing bar and traditional polyvinyl chloride (PVC) edge sealing bar, and log edge sealing bar is made simple, but the cost costliness, its raw material is mainly derived from the log skin of trees; In recent years, various countries are in order to protect forest resources, and the felling of restriction forest makes that the raw material sources of log edge sealing bar are restricted; For this reason, people expect replacing the log skin as the main raw material of making the edge sealing bar with PVC; At present, PVC's mostly contains the toxic substance phthalate, and mostly to be to use heavy metallic salt stablizer, especially lead be stablizer; But the brain cell of heavy metal harm people such as lead, carcinogenic mutagenesis has comparatively severe impairment to people's health.
Summary of the invention:
The objective of the invention is to overcome the deficiencies in the prior art, and provide a kind of the prescription of the harmless environment-friendly edge sealing tape of human body.
For achieving the above object, the technical solution used in the present invention is:
A kind of prescription of environment-friendly edge sealing tape, by weight percentage, this prescription comprises following component:
Polyvinyl chloride 40%～70%
Lime carbonate 20%～40%
Chlorinatedpolyethylene 0.5%～1.5%
Outer lubrication prescription 0.3%～0.7%
Calcium zinc stabilizer 1%～5%
Softening agent 5%～30%
Its China and foreign countries' lubrication prescription is: hard acid ester, adipic acid, season penta tetracid polymkeric substance; Calcium zinc stabilizer is the solid composite calcium zinc stabilizing agent, can be stearate soap, lauric acid soap or oleate soap, wherein preferred stearate soap.
Wherein, by weight percentage, this prescription comprises following component:
Polyvinyl chloride 45%～60%
Lime carbonate 25%～35%
Chlorinatedpolyethylene 0.8%～1.2%
Outer lubrication prescription 0.4%～0.6%
Calcium zinc stabilizer 2%～4%
Softening agent 5%～25%
Its China and foreign countries' lubrication prescription is: hard acid ester, adipic acid, season penta tetracid polymkeric substance; Calcium zinc stabilizer is the solid composite calcium zinc stabilizing agent, can be stearate soap, lauric acid soap or oleate soap, wherein preferred stearate soap.
Described softening agent is made up of the material of following weight percent:
Epoxy soybean oil 40%～60%
Vinylbenzene 60%～40%.
Described softening agent is made up of the material of following weight percent:
Epoxy soybean oil 50%
Vinylbenzene 50%.
Described softening agent is made up of the material of following weight percent:
Butyl citrate 40%～80%
Epoxyfatty acid oil oxyphenisatin ester 20%～60%.
Described softening agent is made up of the material of following weight percent:
Butyl citrate 50%～70%
Epoxyfatty acid oil oxyphenisatin ester 30%～50%.
Preparation method of the present invention is: the raw material of above-mentioned amount is put in the mixing equipment stirred, stirring velocity remains on 740～1480 rev/mins, and churning time was controlled at 15～20 minutes, and temperature remains on 90～125 ℃; After stirring is finished, said mixture is put into cooling apparatus cool off, process of cooling requires that the action of stirring is arranged, and stirring velocity remains on 200～300 rev/mins, and churning time was controlled at 10～15 minutes, and temperature remains on 40～50 ℃; Above-mentioned cooled mixture is put into extrusion equipment, make the barrel temperature of extrusion equipment remain on 145～175 ℃, extruded velocity remains on 1～1.5kg/min, and mixture is at last by the molding die extrusion moulding of extrusion equipment, so far, base material completes; At the substrate surface printing pattern layer of making, last at the transparent protective membrane of patterned layer surface printing.
Beneficial effect of the present invention is: the present invention by in polyvinyl chloride, add the softening agent be complementary with it and outside material such as lubrication prescription, according to the difference of interpolation softening agent, can prepare the different PVC material of soft durometer; The present invention does not only influence physicalies such as the mechanical property, flame retardant resistance, high strength weathering resistance of PVC, and the polyvinyl chloride materials are few, and is with low cost; Do not contain phthalate in the product, compare with European environmental protection standard, the content detection result of phthalate of the present invention is as follows:
Press ASTM F963-07 standard detection through U.S. SGS company, do not contain heavy metal, avoided these materials that human body is caused damage, thereby realize environmental requirement; Heavy metal detected result such as following table show:
Note: 1, mg/kg=ppm; 2, N.D.=does not detect; 3, MDL=method detectability.
Embodiment:
The following examples can make those skilled in the art more fully understand the present invention, but do not limit the present invention in any way.
Embodiment 1
A kind of prescription of environment-friendly edge sealing tape, by weight percentage, this prescription comprises following component:
Polyvinyl chloride 47%
Lime carbonate 40%
Chlorinatedpolyethylene 1.5%
Outer lubrication prescription 0.5%
Stearate soap 1%
Epoxy soybean oil 3%
Vinylbenzene 6%
Its China and foreign countries' lubrication prescription is: hard acid ester, adipic acid, season penta tetracid polymkeric substance.
The raw material of above-mentioned amount put in the mixing equipment stir, stirring velocity remains on 740～1480 rev/mins, and churning time was controlled at 15～20 minutes, and temperature remains on 90～125 ℃; After stirring is finished, said mixture is put into cooling apparatus cool off, process of cooling requires that the action of stirring is arranged, and stirring velocity remains on 200～300 rev/mins, and churning time was controlled at 10～15 minutes, and temperature remains on 40～50 ℃; Above-mentioned cooled mixture is put into extrusion equipment, make the barrel temperature of extrusion equipment remain on 145～175 ℃, extruded velocity remains on 1～1.5kg/min, and mixture is at last by the molding die extrusion moulding of extrusion equipment, so far, base material completes; At the substrate surface printing pattern layer of making, last at the transparent protective membrane of patterned layer surface printing.
Embodiment 2
A kind of prescription of environment-friendly edge sealing tape, by weight percentage, this prescription comprises following component:
Polyvinyl chloride 58%
Lime carbonate 33%
Chlorinatedpolyethylene 1.5%
Outer lubrication prescription 0.5%
Lauric acid soap 2%
Epoxy soybean oil 2.5%
Vinylbenzene 2.5%.
The concrete preparation method of present embodiment is with embodiment 1.
Embodiment 3
A kind of prescription of environment-friendly edge sealing tape, by weight percentage, this prescription comprises following component:
Polyvinyl chloride 60%
Lime carbonate 25%
Chlorinatedpolyethylene 1%
Outer lubrication prescription 0.5%
Oleate soap 5%
Epoxy soybean oil 3.5%
Vinylbenzene 5%.
The concrete preparation method of present embodiment is with embodiment 1.
Embodiment 4
A kind of prescription of environment-friendly edge sealing tape, by weight percentage, this prescription comprises following component:
Polyvinyl chloride 40%
Lime carbonate 35%
Chlorinatedpolyethylene 0.5%
Outer lubrication prescription 0.5%
Stearate soap 1%
Butyl citrate 20%
Epoxyfatty acid oil oxyphenisatin ester 3%.
Embodiment 5
A kind of prescription of environment-friendly edge sealing tape, by weight percentage, this prescription comprises following component:
Polyvinyl chloride 46%
Lime carbonate 28%
Chlorinatedpolyethylene 1%
Outer lubrication prescription 0.5%
Stearate soap 3%
Butyl citrate 15%
Epoxyfatty acid oil oxyphenisatin ester 7.5%.
Embodiment 6
A kind of prescription of environment-friendly edge sealing tape, by weight percentage, this prescription comprises following component:
Polyvinyl chloride 46%
Lime carbonate 25%
Chlorinatedpolyethylene 1%
Outer lubrication prescription 0.5%
Stearate soap 5%
Butyl citrate 12%
Epoxyfatty acid oil oxyphenisatin ester 7.5%.
Claims (6)
1, a kind of prescription of environment-friendly edge sealing tape is characterized in that: by weight percentage, this prescription comprises following component:
Polyvinyl chloride 40%～70%
Lime carbonate 20%～40%
Chlorinatedpolyethylene 0.5%～1.5%
Outer lubrication prescription 0.3%～0.7%
Calcium zinc stabilizer 1%～5%
Softening agent 5%～30%
Its China and foreign countries' lubrication prescription is: hard acid ester, hexanodioic acid, season penta tetracid polymkeric substance; Calcium zinc stabilizer is the solid composite calcium zinc stabilizing agent, can be stearate soap, lauric acid soap or oleate soap, wherein preferred stearate soap.
2, the prescription of a kind of environment-friendly edge sealing tape according to claim 1 is characterized in that: by weight percentage, this prescription comprises following component:
Polyvinyl chloride 45%～60%
Lime carbonate 25%～35%
Chlorinatedpolyethylene 0.8%～1.2%
Outer lubrication prescription 0.4%～0.6%
Calcium zinc stabilizer 2%～4%
Softening agent 5%～25%
Its China and foreign countries' lubrication prescription is: hard acid ester, hexanodioic acid, season penta tetracid polymkeric substance; Calcium zinc stabilizer is the solid composite calcium zinc stabilizing agent, can be stearate soap, lauric acid soap or oleate soap, wherein preferred stearate soap.
3, according to the prescription of any described a kind of environment-friendly edge sealing tape in claim 1 or 2, it is characterized in that: described softening agent is made up of the material of following weight percent:
Epoxy soybean oil 40%～60%
Vinylbenzene 60%～40%.
4, according to the prescription of any described a kind of environment-friendly edge sealing tape in claim 1 or 2, it is characterized in that: described softening agent is made up of the material of following weight percent:
Epoxy soybean oil 50%
Vinylbenzene 50%.
5, according to the prescription of any described a kind of environment-friendly edge sealing tape in claim 1 or 2, it is characterized in that: described softening agent is made up of the material of following weight percent:
Butyl citrate 40%～80%
Epoxyfatty acid oil oxyphenisatin ester 20%～60%.
6, according to the prescription of any described a kind of environment-friendly edge sealing tape in claim 1 or 2, it is characterized in that: described softening agent is made up of the material of following weight percent:
Butyl citrate 50%～70%
Epoxyfatty acid oil oxyphenisatin ester 30%～50%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810028245A CN101544800A (en) | 2008-05-23 | 2008-05-23 | Formula of environment-friendly edge sealing tape |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810028245A CN101544800A (en) | 2008-05-23 | 2008-05-23 | Formula of environment-friendly edge sealing tape |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101544800A true CN101544800A (en) | 2009-09-30 |
Family
ID=41192191
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200810028245A Pending CN101544800A (en) | 2008-05-23 | 2008-05-23 | Formula of environment-friendly edge sealing tape |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417675A (en) * | 2011-09-23 | 2012-04-18 | 安徽万朗磁塑集团有限公司 | Novel green environmental protection antibacterial door gasket rubber jacket material formula and preparation method |
| CN102985481A (en) * | 2010-05-10 | 2013-03-20 | 陶氏环球技术有限责任公司 | Flexible PVC compositions made with plasticizers derived from renewable sources |
| CN104312046A (en) * | 2014-10-30 | 2015-01-28 | 六安索伊电器制造有限公司 | Environment-friendly refrigerator door seal PVC granule and preparation method thereof |
| CN104312044A (en) * | 2014-10-30 | 2015-01-28 | 安徽电信器材贸易工业有限责任公司 | Oil-resistant polyvinyl chloride cable sheath material and preparation method thereof |
| CN107200952A (en) * | 2017-05-18 | 2017-09-26 | 东莞市兄奕塑胶制品有限公司 | A kind of tasteless environment-friendly type PVC edge band and preparation method thereof |
-
2008
- 2008-05-23 CN CN200810028245A patent/CN101544800A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102985481A (en) * | 2010-05-10 | 2013-03-20 | 陶氏环球技术有限责任公司 | Flexible PVC compositions made with plasticizers derived from renewable sources |
| CN102417675A (en) * | 2011-09-23 | 2012-04-18 | 安徽万朗磁塑集团有限公司 | Novel green environmental protection antibacterial door gasket rubber jacket material formula and preparation method |
| CN104312046A (en) * | 2014-10-30 | 2015-01-28 | 六安索伊电器制造有限公司 | Environment-friendly refrigerator door seal PVC granule and preparation method thereof |
| CN104312044A (en) * | 2014-10-30 | 2015-01-28 | 安徽电信器材贸易工业有限责任公司 | Oil-resistant polyvinyl chloride cable sheath material and preparation method thereof |
| CN107200952A (en) * | 2017-05-18 | 2017-09-26 | 东莞市兄奕塑胶制品有限公司 | A kind of tasteless environment-friendly type PVC edge band and preparation method thereof |
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Open date: 20090930 |