CN101531948A - New technology for catalytically cracking light diesel oil from waste motor oil - Google Patents
New technology for catalytically cracking light diesel oil from waste motor oil Download PDFInfo
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- CN101531948A CN101531948A CN200910115184A CN200910115184A CN101531948A CN 101531948 A CN101531948 A CN 101531948A CN 200910115184 A CN200910115184 A CN 200910115184A CN 200910115184 A CN200910115184 A CN 200910115184A CN 101531948 A CN101531948 A CN 101531948A
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Abstract
The invention belongs to the diesel oil refining technology, especially a new technology for catalytically cracking light diesel fuel from waste motor oil. Currently, the drawbacks of the prior technology for refining the waste motor oil into diesel oil are that: the cetane number falls short of national standard and the chroma is deep and opaque, the recovery is low and the technology is complex. The new technology comprises the following steps: adding waste motor oil into a reaction kettle; adding a hone-made good catalyst accounting for 1/1000 of the weight of the waste motor oil; heating to 300-500 DEG C to make the waste motor oil catalytically crack, finally obtaining distillation product; putting the distillation product into a condenser, making the condensed liquid-sate light diesel oil and the tail gas through an oil-gas splitter, making the tail gas into a gas collector; split diesel oil flowing into a treatment tank, adding high efficiency treating agent with concentration of 5/10000 into the treatment tank, treating the diesel oil using a backflow spray head; finally layering and filtering the treated light diesel oil by an oil water splitter, namely the yellow transparent light diesel oil with flash point >55 DEG C is obtained, with recovery of higher 80%.
Description
Technical field
The invention belongs to the diesel oil refinement technique, particularly a kind of from used oil the novel process of catalytically cracking light diesel.
Background technology
Used oil is that outside contamination produces a large amount of colloids, thereby oxide compound reduces and even lost it answers the powerful depleted material that suffers to lubricating oil owing in use being subjected to.State Bureau of Environmental Protection has been classified used oil as 21 century at one of three big emphasis of environmental protection field major control, and make full use of regenerating waste oil reduction finished product machine oil, or used oil is refined into gasoline, diesel oil, can alleviate the China's oil shortage and the growing imbalance between supply and demand of demand, can promote environmental protection to turn waste into wealth again, create considerable economic, help the part crowd to shake off poverty and set out on the road to prosperity, be that country encourages the support project, prospect is very wide.In recent years, the annual growth of China's machine oil product consumption surpasses 5%, and by the end of the year 2008, national vehicle guaranteeding organic quantity surpasses 1.5 hundred million, and a year replacing used oil reaches about 6,000,000 tons.Whole nation ships that transport reaches 200,000, and big or small motor fishing vessel reaches 1,500,000, about about 8,000,000 tons of the used oil that domestic boats and ships change every year, and this numeral does not comprise that also other cities come the large-tonnage freighter at port.Only above-mentioned two item number certificates, the used oil that year is produced is just up to 1,500 ten thousand tons.Add the used oil that aircraft, train, various big machinery and organizational equipment produce, estimate that the used oil that the whole nation is produced adds up to 2500~3,000 ten thousand tons/year.The generation of external used oil is surprising especially, and conservative estimation will be above more than 200,000,000 tons.In general, can should be about 50% of consumption for the used oil amount that reclaims, yet the used oil rate of recovery is very low at present, the reclaimed lubricating oil product that returns usefulness every year only has less than 10%, a considerable amount of used oil flow to not clear, and wherein a part enters environment and pollutes.Though used oil also can be done fuel and use, during owing to the burning used oil, heat distributes little, can produce a large amount of dense smokes, and environment is had very big pollution, and to human body also harm to some extent, it is few to produce beneficial effect.
The shortcoming that at present used oil is refined into the diesel oil Technology is that cetane value does not reach GB, colourity is dark opaque, and the rate of recovery is low, and complex process.
Summary of the invention
It is simple that the object of the invention provides a kind of technology, and cetane value, colourity reach the GB requirement, and the high novel process of catalytically cracking light diesel from used oil of the rate of recovery.
Take technical scheme to be for reaching this purpose the present invention:
A kind of from used oil the novel process of catalytically cracking light diesel, comprise following processing step:
A inserts used oil in the reactor, is controlled by bivalve by opening for feed, during oil-feed, opens gate valve earlier, opens stopping valve again, makes used oil add in the reactor smoothly by petrol-feed pump;
The b catalyzer adds inlet by catalyzer and joins in the reactor, after used oil and effective catalyst adding all finish, and valve-off, the effective catalyst add-on is 1/1000 of a used oil weight;
C reacting by heating still makes used oil reach 300~500 ℃ of temperature, makes the used oil catalytic pyrolysis, obtains diesel oil distillate gas;
D diesel oil distillate gas is by the cut of distillation tower to cut control sensing devices control diesel oil, and solar oil cut gas enters condenser condenses by pipeline, and condensed liquid solar oil enters oil-gas separator and carries out gas-oil separation;
Tail gas after e separates enters the water seal gas extractor by water-and-oil separator and spark arrester carries out collection and confinement of gases;
F separates the liquid solar oil in back and enters treatment tank, adds 5/10000 effectively refining agent in the treatment tank, and carry out countercurrent mass transfer through the countercurrent spray device and make with extra care, layering, through oily water separation, by filtering, solar oil gets product;
Effective catalyst component and weight percent are: Fe
2O
30.1~5%, active A l
2O
35~30%, MgO 0.1~10%, CaO5~30%, SiO
25~30%, NaOH 2~20%, and KOH 0.2~10%, Al
2(SO
4)
30.01~5%, mishmetal (Re
2O
3) 0.01~1%;
Effectively refining agent component and weight percent: KMnO
40.1~5%, K
2Cr
2O
70.1~5%, Ce (SO
4)
20.1~5%, NaOH 20~50%, KOH10~50%, Ca (OH)
22~5% the aqueous solution.
The present invention has summed up three biographies, one anti-rule in the Principles of Chemical Engineering, reduces temperature of reaction, save energy, eliminate the pollution of secondary " three wastes " to environment, real realization Green Chemistry, can from used oil, refine the high-quality solar oil easily, reduce environmental pollution, cut down the consumption of energy, reduce the wasting of resources.Use the present invention and produce the solar oil flash-point 55 ℃, colourity are yellow transparent, the rate of recovery is higher than 80%.
Embodiment
The equipment that the present invention uses is made up of reactor, heating unit, distillation tower, cut control sensing device, condenser, treatment tank, water-and-oil separator and oil-gas separator, gas extractor etc., is general commercially available equipment.
Processing step of the present invention is:
A inserts used oil in the reactor, is controlled by bivalve by opening for feed, during oil-feed, opens gate valve earlier, opens stopping valve again, by petrol-feed pump used oil is added in the reactor smoothly, overcomes the drawback of the necessary cold pot of tradition oil-feed.
The b catalyzer adds inlet by catalyzer and joins in the reactor, after used oil and effective catalyst adding all finish, and valve-off, the effective catalyst add-on is 1/1000 of a used oil weight.
C reacting by heating still makes used oil reach 300~500 ℃ of temperature, makes the used oil catalytic pyrolysis, obtains cut gas.
D diesel oil distillate gas is by the cut of distillation tower to cut control sensing devices control diesel oil, and solar oil cut gas enters condenser condenses by pipeline, and condensed liquid solar oil enters oil-gas separator and carries out gas-oil separation.
Tail gas after e separates enters the water seal gas extractor by water-and-oil separator and spark arrester carries out collection and confinement of gases.
F separates the liquid solar oil in back and enters treatment tank, adds 5/10000 effectively refining agent in the treatment tank, and carry out countercurrent mass transfer through the countercurrent spray device and make with extra care, layering, through oily water separation, by filtering, solar oil gets product.Described solar oil flash-point〉55 ℃.Described diesel oil colourity is yellow.
The reactor lower end is equipped with slag notch, is used to remove waste residue.Waste residue is discharged by slag notch after hours.
Embodiment one
The double centner used oil is added by opening for feed, during oil-feed, open gate valve earlier, open stopping valve again, used oil is added in the reactor smoothly by petrol-feed pump.(catalyzer is by 5%Fe with 100 gram catalyzer
2O
3, 30% active A l
2O
3, 5%MgO, 30%CaO, 10%SiO
2, 15%NaOH, 5%KOH, 1%Al
2(SO
4)
3, 0.1% mishmetal forms).Add inlet by catalyzer and join in the reactor, after used oil and catalyzer adding all finish, valve-off.The reacting by heating still makes used oil reach 300 ℃ of temperature, makes the used oil catalytic cracking reaction 5 hours, obtains cut gas, 180 ℃ of cut gas temperatures.Diesel oil distillate gas is by the cut of distillation tower to cut control sensing devices control diesel oil, and solar oil cut gas enters condenser condenses by pipeline, and condensed liquid solar oil enters oil-gas separator and carries out gas-oil separation.Tail gas after the separation enters the water seal gas extractor by water-and-oil separator and spark arrester carries out collection and confinement of gases.Separate the liquid solar oil in back and enter treatment tank, (the effectively refining agent is by NaOH45%+KOH47%+Ca (OH) to add 2L in the treatment tank
25%+KMnO
41%+K
2Cr
2O
71%+Ce (SO
4)
21% is made into water, and content is 0.05%) the effectively refining agent, it is refining to carry out countercurrent mass transfer through the countercurrent spray device, layering, through oily water separation, by filtering, solar oil gets product.The solar oil flash-point〉55 ℃, colourity is yellow.Catalytic cracking reaction after hours, reactor is cooled to normal temperature after, waste residue is discharged by slag notch.
Experiment test manufacture proof: the double centner used oil can refine 80 kilograms solar oil.
Embodiment two
The double centner used oil is added by opening for feed, during oil-feed, open gate valve earlier, open stopping valve again, used oil is added in the reactor smoothly by petrol-feed pump.(catalyzer is by 10%Fe with 100 gram catalyzer
2O
3, 20% active A l
2O
3, 10%MgO, 20%CaO, 10%SiO
2, 10%NaOH, 10%KOH, 2%Al
2(SO
4)
3, 0.2% mishmetal forms).Add inlet by catalyzer and join in the reactor, after used oil and catalyzer adding all finish, valve-off.The reacting by heating still makes used oil reach 400 ℃ of temperature, makes the used oil catalytic cracking reaction 5 hours, obtains cut gas, 260 ℃ of cut gas temperatures.Diesel oil distillate gas is by the cut of distillation tower to cut control sensing devices control diesel oil, and solar oil cut gas enters condenser condenses by pipeline, and condensed liquid solar oil enters oil-gas separator and carries out gas-oil separation.Tail gas after the separation enters the water seal gas extractor by water-and-oil separator and spark arrester carries out collection and confinement of gases.Separate the liquid solar oil in back and enter treatment tank, (the effectively refining agent is by NaOH47%+KOH48.5%+Ca (OH) to add 2L in the treatment tank
23%+KMnO
40.5%+K
2Cr
2O
70.5%+Ce (SO
4)
20.5% is made into water, and content is 0.05%) the effectively refining agent, it is refining to carry out countercurrent mass transfer through the countercurrent spray device, layering, through oily water separation, by filtering, solar oil gets product.The solar oil flash-point〉55 ℃, colourity is yellow.Catalytic cracking reaction after hours, reactor is cooled to normal temperature after, waste residue is discharged by slag notch.
Experiment test manufacture proof: the double centner used oil can refine 81 kilograms solar oil.
Embodiment three
The double centner used oil is added by opening for feed, during oil-feed, open gate valve earlier, open stopping valve again, used oil is added in the reactor smoothly by petrol-feed pump.(catalyzer is by 8%Fe with 100 gram catalyzer
2O
3, 10% active A l
2O
3, 20%MgO, 10%CaO, 20%SiO
2, 20%NaOH, 5%KOH, 5%Al
2(SO
4)
3, 0.3% mishmetal forms).Add inlet by catalyzer and join in the reactor, after used oil and catalyzer adding all finish, valve-off.The reacting by heating still makes used oil reach 500 ℃ of temperature, makes the used oil catalytic cracking reaction 5 hours, obtains cut gas, 350 ℃ of cut gas temperatures.Diesel oil distillate gas is by the cut of distillation tower to cut control sensing devices control diesel oil, and solar oil cut gas enters condenser condenses by pipeline, and condensed liquid solar oil enters oil-gas separator and carries out gas-oil separation.Tail gas after the separation enters the water seal gas extractor by water-and-oil separator and spark arrester carries out collection and confinement of gases.Separate the liquid solar oil in back and enter treatment tank, (the effectively refining agent is by NaOH46%+KOH45%+Ca (OH) to add 2L in the treatment tank
21%+KMnO
42.5%+K
2Cr
2O
73.5%+Ce (SO
4)
22.0% is made into water, and content is 0.05%) the effectively refining agent, it is refining to carry out countercurrent mass transfer through the countercurrent spray device, layering, through oily water separation, by filtering, solar oil gets product.The solar oil flash-point〉55 ℃, colourity is yellow.Catalytic cracking reaction after hours, reactor is cooled to normal temperature after, waste residue is discharged by slag notch.
Experiment test manufacture proof: the double centner used oil can refine 83 kilograms solar oil.
Claims (3)
1, a kind of from used oil the novel process of catalytically cracking light diesel, comprise following processing step:
A inserts used oil in the reactor, is controlled by bivalve by opening for feed, during oil-feed, opens gate valve earlier, opens stopping valve again, makes used oil add in the reactor smoothly by petrol-feed pump;
The b catalyzer adds inlet by catalyzer and joins in the reactor, after used oil and effective catalyst adding all finish, and valve-off, the effective catalyst add-on is 1/1000 of a used oil weight;
C reacting by heating still makes used oil reach 300~500 ℃ of temperature, makes the used oil catalytic pyrolysis, obtains diesel oil distillate gas;
D diesel oil distillate gas is by the cut of distillation tower to cut control sensing devices control diesel oil, and solar oil cut gas enters condenser condenses by pipeline, and condensed liquid solar oil enters oil-gas separator and carries out gas-oil separation;
Tail gas after e separates enters the water seal gas extractor by water-and-oil separator and spark arrester carries out collection and confinement of gases;
F separates the liquid solar oil in back and enters treatment tank, adds 5/10000 effectively refining agent in the treatment tank, and carry out countercurrent mass transfer through the countercurrent spray device and make with extra care, layering, through oily water separation, by filtering, solar oil gets product.
2, according to claim 1 described a kind of from used oil the novel process of catalytically cracking light diesel, it is characterized in that: effective catalyst component and weight percent are: Fe
2O
30.1~5%, active A l
2O
35~30%, MgO 0.1~10%, and CaO 5~30%, SiO
25~30%, NaOH 2~20%, and KOH 0.2~10%, Al
2(SO
4)
30.01~5%, Re
2O
30.01~1%, Re
2O
3It is mishmetal.
3, according to claim 1 described a kind of from used oil the novel process of catalytically cracking light diesel, it is characterized in that: effectively refining agent component and weight percent: KMnO
40.1~5%, K
2Cr
2O
70.1~5%, Ce (SO
4)
20.1~5%, NaOH 20~50%, KOH 10~50%, Ca (OH)
22~5% the aqueous solution.
Priority Applications (1)
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CN200910115184A CN101531948B (en) | 2009-04-10 | 2009-04-10 | New technology for catalytically cracking light diesel oil from waste motor oil |
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CN200910115184A CN101531948B (en) | 2009-04-10 | 2009-04-10 | New technology for catalytically cracking light diesel oil from waste motor oil |
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CN101531948A true CN101531948A (en) | 2009-09-16 |
CN101531948B CN101531948B (en) | 2012-08-29 |
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Cited By (7)
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CN102311774A (en) * | 2011-08-17 | 2012-01-11 | 苏华山 | Method for producing low freezing point diesel fuel by using mixing oil |
WO2012104769A1 (en) * | 2011-02-02 | 2012-08-09 | Basf Se | Process for separation of water from pyrolysis gasoline |
CN103484157A (en) * | 2013-08-29 | 2014-01-01 | 连力生 | Method and device for utilizing waste lubricating oil to produce diesel oil |
CN103484156A (en) * | 2013-08-29 | 2014-01-01 | 连力生 | Method for producing diesel through spent lubrication oil and production device thereof |
CN106140237A (en) * | 2016-07-06 | 2016-11-23 | 唐山寰通源生物柴油科技有限公司 | A kind of catalyst and application thereof refining biodiesel for the steel rolling oil that gives up |
US20210197181A1 (en) * | 2018-05-25 | 2021-07-01 | Rd&C Research, Development & Consulting Gmbh | Kits comprising containers with at least one solid catalytically active compound, and their uses in solid state reaction |
CN114317030A (en) * | 2021-12-31 | 2022-04-12 | 广州科技职业技术大学 | Method for preparing diesel oil by taking waste engine oil as raw material |
Family Cites Families (2)
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CN1236016C (en) * | 2003-04-25 | 2006-01-11 | 谢福胜 | Method and device for producing vapour, coal, diesel oil using waste plastic, rubber, machine oil |
CN1854272A (en) * | 2005-04-26 | 2006-11-01 | 李平 | Method for reducing finished product mobile oil and refining gasoline and diesel from waste mobile oil and its apparatus thereof |
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2009
- 2009-04-10 CN CN200910115184A patent/CN101531948B/en not_active Expired - Fee Related
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012104769A1 (en) * | 2011-02-02 | 2012-08-09 | Basf Se | Process for separation of water from pyrolysis gasoline |
US9567533B2 (en) | 2011-02-02 | 2017-02-14 | Basf Se | Process for separation of water from pyrolysis gasoline |
CN102311774A (en) * | 2011-08-17 | 2012-01-11 | 苏华山 | Method for producing low freezing point diesel fuel by using mixing oil |
CN102311774B (en) * | 2011-08-17 | 2014-04-16 | 苏华山 | Method for producing low freezing point diesel fuel by using mixing oil |
CN103484157A (en) * | 2013-08-29 | 2014-01-01 | 连力生 | Method and device for utilizing waste lubricating oil to produce diesel oil |
CN103484156A (en) * | 2013-08-29 | 2014-01-01 | 连力生 | Method for producing diesel through spent lubrication oil and production device thereof |
CN103484157B (en) * | 2013-08-29 | 2016-01-13 | 连力生 | Waste lubricating oil produces method and the device thereof of diesel oil |
CN103484156B (en) * | 2013-08-29 | 2016-03-02 | 连力生 | A kind of waste lubricating oil produces method and the production equipment thereof of diesel oil |
CN106140237A (en) * | 2016-07-06 | 2016-11-23 | 唐山寰通源生物柴油科技有限公司 | A kind of catalyst and application thereof refining biodiesel for the steel rolling oil that gives up |
CN106140237B (en) * | 2016-07-06 | 2019-05-21 | 李仁国 | A kind of catalyst and its application for refining biodiesel for the steel rolling oil that gives up |
US20210197181A1 (en) * | 2018-05-25 | 2021-07-01 | Rd&C Research, Development & Consulting Gmbh | Kits comprising containers with at least one solid catalytically active compound, and their uses in solid state reaction |
CN114317030A (en) * | 2021-12-31 | 2022-04-12 | 广州科技职业技术大学 | Method for preparing diesel oil by taking waste engine oil as raw material |
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