CN105947978A - Combined mixed generation system of hydrogen energy module - Google Patents
Combined mixed generation system of hydrogen energy module Download PDFInfo
- Publication number
- CN105947978A CN105947978A CN201610281092.4A CN201610281092A CN105947978A CN 105947978 A CN105947978 A CN 105947978A CN 201610281092 A CN201610281092 A CN 201610281092A CN 105947978 A CN105947978 A CN 105947978A
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- Prior art keywords
- pipe
- reactor
- module combined
- boiler
- combined type
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Links
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 49
- 239000001257 hydrogen Substances 0.000 title claims abstract description 49
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 113
- 238000006243 chemical reaction Methods 0.000 claims abstract description 66
- 239000000446 fuel Substances 0.000 claims abstract description 45
- 239000007789 gas Substances 0.000 claims abstract description 45
- 238000001556 precipitation Methods 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 5
- 238000003860 storage Methods 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims description 28
- 239000002184 metal Substances 0.000 claims description 28
- 239000002904 solvent Substances 0.000 claims description 22
- 238000002156 mixing Methods 0.000 claims description 21
- 238000007599 discharging Methods 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000002283 diesel fuel Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 239000003345 natural gas Substances 0.000 claims description 3
- 238000005859 coupling reaction Methods 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 3
- 239000003863 metallic catalyst Substances 0.000 abstract 1
- 238000009423 ventilation Methods 0.000 abstract 1
- 238000001914 filtration Methods 0.000 description 23
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 238000005452 bending Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 239000000779 smoke Substances 0.000 description 5
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical group [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 4
- -1 pro-oxidant Substances 0.000 description 4
- 229910052722 tritium Inorganic materials 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 3
- 230000009172 bursting Effects 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000013528 metallic particle Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 230000003244 pro-oxidative effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 210000003437 trachea Anatomy 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052792 caesium Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229910052805 deuterium Inorganic materials 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910000471 manganese heptoxide Inorganic materials 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- JOJPFQVZNUNZBO-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mn+2].[Mn+2].[Mn+2].[Mn+2].[Mn+2].[Mn+2].[Mn+2] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mn+2].[Mn+2].[Mn+2].[Mn+2].[Mn+2].[Mn+2].[Mn+2] JOJPFQVZNUNZBO-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical group [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0495—Composition of the impurity the impurity being water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
Abstract
The invention discloses a combined mixed generation system of a hydrogen energy module, which comprises a hot water boiler. The hot water boiler is connected with a module combined reaction kettle through a solenoid valve expansion tank. The top of the module combined reaction kettle is communicated with a gas collecting cylinder. The bottom of the module combined reaction kettle is communicated with a precipitation tank. The gas collecting cylinder is sequentially communicated with a secondary filter, a gas collecting tank and a gas storage tank. The module combined reaction kettle consists of a plurality of independent reaction kettles and the plurality of independent reaction kettles are connected together through a pipeline and a ventilation valve. A fuel rod is arranged inside each independent reaction kettle and the fuel rod is provided with metallic catalyst fuel materials. The right sidewall of the hot water boiler is communicated with a boiler water outlet pipe at a position closer to the top of the hot water boiler. The boiler water outlet pipe is connected with the solenoid valve expansion tank. The solenoid valve expansion tank is provided with an expansion tank water outlet pipe. The sidewall of each independent reaction kettle is provided with a reaction kettle water inlet pipe. All reaction kettle water inlet pipes are communicated with the expansion tank water outlet pipe. The system generates the clean energy, and reduces the pollution. Meanwhile, the system is small in occupied area, safe in operation and low in cost. The raw materials of the system are easily available.
Description
Technical field
The present invention relates to energy field, particularly relate to a kind of hydrogen energy source module combined type mixing generation system.
Background technology
Along with the depletion rate of socioeconomic development, the energy and resource is increasingly faster, the world is to energy shortage
The most surging with the cry of environmental conservation, save the energy, protection environment has become as human kind sustainable development
Essential condition, the attention of people is just turning to utilization and the exploitation of the renewable sources of energy.Fuel energy is wherein to consume
The one that at most usage amount is maximum, it is widely used in commercial production and family life etc..Traditional fuel energy
Source relies on diesel oil, coal gas etc. mostly, and the combustion utilization efficiency of these energy is the highest, and is non-renewable energy resources
And the discharge after Ran Shao is relatively big to the pollution of air and environment, and the health of the person is had the harm lain dormant.
Summary of the invention
For problem present in background technology, it is an object of the present invention to provide a kind of hydrogen energy source module combined type and mix
Closing generation system, this system is a kind of to regard concrete energy demand by each independent reaction still as the combination of module
Hybrid reaction body structure, can produce high heating value and clean mixed hydrogen by continuous print, have function admirable, mould
Block formula combine, takes up an area less, fuel is easy to get, cost is relatively low, operation safety, the advantage of high financial profit.
For realizing described technical purpose, the present invention adopts the following technical scheme that and is achieved.
A kind of hydrogen energy source module combined type mixing generation system, including hot-water boiler, hot-water boiler passes through electromagnetism
Valve expansion tank link block combination type reactor, module combined type reactor top connected set inflator, bottom
Connection multi stage precipitation groove, gas collecting jar with ground-on cover plate is sequentially communicated secondary filter, air collector and air accumulator；Described module
Combination type reactor is formed by connecting by pipeline and gas valve by multiple independent reaction stills, each independent reaction
Being provided with fuel rod in still, fuel rod is provided with metal solvent fuel thing；Hot-water boiler right side wall is near groove top
Connection boiler discharging tube road, position, boiler discharging tube road connects electromagnetic valve expansion tank；Electromagnetic valve expansion tank
It is provided with expansion tank outlet pipe, the sidewall of each independent reaction still is equipped with a reactor water inlet pipe, institute
Some reactor water inlet pipes are all communicated to expansion tank outlet pipe, and each independent reaction still water inlet pipe is provided with one
High-temperature solenoid valve；A reactor escape pipe, each reactor escape pipe is connected on each independent reaction still top
On be equipped with explosion-proof solenoid valve；The bottom of each independent reaction still also connects reactor blow-off pipe, each reaction
Still blow-off pipe is provided with electric blowdown valve and manual blowdown valve, reactor blow-off pipe connection multi stage precipitation groove.
Further, the left side wall of hot-water boiler connects combustor near the position of furnace bottom, and combustor uses sky
So hot-water boiler is heated by any one in gas, diesel oil and these incendiary materials of liquefied gas.
Further, the metal solvent fuel thing in fuel rod be by three kinds of different metal catalyst, pro-oxidant,
Alkali compound and acidulants are prepared from.
Further, three kinds of different metal solvents are aluminum, zinc and copper respectively.
Further, metal solvent fuel is strip.
Further, described multi stage precipitation groove comprises the one-level stillpot being sequentially connected in series, two-stage precipitation groove and
Three grades of stillpots；Described one-level stillpot connects described reactor blow-off pipe, and described three grades of stillpots are by anti-
Answer the top of still circulation pipe connection hot-water boiler.
Further, described reactor circulation pipe is provided with reactor circulating pump at three grades of stillpots.
Further, described multi stage precipitation groove is also associated with scraper-type tipping wagons.
Further, air collector connects air collector escape pipe, and air accumulator connects air accumulator escape pipe, and air collector goes out
It is equipped with explosion-proof solenoid valve on trachea and air accumulator escape pipe.
Further, the tank bottoms place of air accumulator is provided with air accumulator blow-off pipe, and air accumulator blow-off pipe is provided with blowdown
Valve, air accumulator blow-off pipe connects air accumulator vacuum pump by pipeline.
The invention have the benefit that the metal solvent fuel thing in native system can induce water in a kettle.
Clean energy resource needed for producing with hydrogen-oxygen separating reaction, it is possible to reduce the dependence to traditional fossil energy, and allow
The energy uses the harm to environment to be greatly reduced with pollution, therefore to energy industry and the harmonious development of environmental ecology
Having great importance, this system footprint area is less, raw material is easy to get, operate safety, low cost, is suitable for
Large-scale promotion utilizes.
Accompanying drawing explanation
Fig. 1 be the present invention system in hot-water boiler, module combined type reactor and the company of multi stage precipitation groove
Connect structural representation；
Fig. 2 be the present invention system in hot-water boiler, module combined type reactor, gas collecting jar with ground-on cover plate, air collector with
And the attachment structure schematic diagram of air accumulator；
Fig. 3 be the present invention system in reactor, gas collecting jar with ground-on cover plate, filter, air collector, air accumulator and scrape
The attachment structure schematic diagram of board-like tipping wagons；
Fig. 4 be the present invention system in the structural representation of hot-water boiler；
Fig. 5 be the present invention system in the annexation schematic diagram of gas collecting jar with ground-on cover plate and miscellaneous part；
Fig. 6 be the present invention system in the structural representation of independent reaction still；
Fig. 7 be the present invention system in the structural representation of module combined type reactor of multiple reactors composition；
Fig. 8 be the present invention system in fuel rod and metal solvent fuel thing structural representation；
Fig. 9 be the present invention system in the structural representation of multi stage precipitation groove；
Figure 10 be the present invention system in the structural representation of filter；
Figure 11 be the present invention system in the structural representation of air collector；
Figure 12 be the present invention system in the structural representation of air accumulator；
In figure: hot-water boiler 1；Electromagnetic valve expansion tank 2；Module combined type reactor 3；Gas collecting jar with ground-on cover plate 4；
Multi stage precipitation groove 5；Secondary filter 6；Air collector 7；Air accumulator 8；Combustor 9；Boiler water blow-down pipe 10；
Blowoff valve 11；Boiler water inlet pipe 12: boiler feed water electromagnetic valve 13；Boiler discharging tube road 14；Expansion tank
Outlet pipe 15；Independent reaction still 16；Reactor bursting tube 17；Pressure gauge 18；Exhaust-valve 19；Relief valve
20；Reactor water inlet pipe 21；High-temperature solenoid valve 22；Reactor escape pipe 23；Explosion-proof solenoid valve 24；Instead
Answer still blow-off pipe 25；Electric blowdown valve 26；Valve 27 is moved in hands blowdown；Scraper-type tipping wagons 28；Stillpot follows
Endless tube 29；Stillpot circulating pump 30；One-level stillpot 31；Two-stage precipitation groove 32；Three grades of stillpots 33；
Serial pipe 34；Bending pipeline 35；Single filter groove water inlet pipe 36；Filter tank water intaking valve 37；Two grades of mistakes
Filter pocket water inlet pipe 38；Single filter groove blow-off pipe 39；Cascade filtration groove blow-off pipe 40；Going out of cascade filtration groove
Trachea 41；Air collector escape pipe 42；Air accumulator escape pipe 43；Air accumulator blow-off pipe 44；Air accumulator vacuum
Pump 45；Single filter groove 46；Cascade filtration groove 47；Fuel rod 48；Metal solvent fuel thing 49；Gas collection
Cylinder escape pipe 50.
Detailed description of the invention
The invention will be further described below in conjunction with the accompanying drawings:
Refer to 1 and Fig. 2, the described hydrogen energy source module combined type mixing that the embodiment of the present invention provides is
System, in order to produce efficient heat energy, clean energy resource with low cost, free of contamination.It includes hot-water boiler 1；Institute
State hot-water boiler 1 by electromagnetic valve expansion tank 2 link block combination type reactor 3；Module combined type reacts
Still 3 top connected set inflator 4, bottom connection multi stage precipitation groove 5；Described gas collecting jar with ground-on cover plate 4 is sequentially communicated two grades of mistakes
Filter 6, air collector 7 and air accumulator 8.
Referring to Fig. 1 and Fig. 4, described hot-water boiler 1 can use general tap water, hot-water boiler 1 to enter
The water yield and water level in module combined type reactor 3 are controlled by electromagnetic valve expansion tank 2.Hot-water boiler 1
Left side wall connects combustor 9 near the position of furnace bottom, and combustor 9 can use natural gas, diesel oil and liquefied gas
Hot-water boiler 1 is heated or prevents it from freezing by any one in these incendiary materials.Described water bath
It is provided with boiler water blow-down pipe 10 bottom stove 1, if desired, the dirt in water or impurity can be got rid of or carry out quickly
Draining.Described boiler water blow-down pipe 10 is provided with blowoff valve 11, opens and closes boiler by blowoff valve 11
Blow-off pipe 10.Boiler water inlet pipe 12 is also connected, on described boiler water inlet pipe 12 bottom described hot-water boiler 1
Being provided with boiler feed water electromagnetic valve 13, described boiler feed water electromagnetic valve 13 is in order to control the water level of hot-water boiler 1.
Described hot-water boiler 1 right side wall connects boiler discharging tube road 14, described boiler discharging tube near the position on groove top
Road 14 connects electromagnetic valve expansion tank 2, and described electromagnetic valve expansion tank 2 is by expansion tank outlet pipe 15 points
Not connecting multiple independent reaction still 16, the present invention controls entering of hot-water boiler 1 by electromagnetic valve expansion tank 2
Water, to allow metal solvent fuel thing can induce water and hydrogen atom, the height of oxygen atom in independent reaction still 16
Speed reaction.
Described module combined type reactor 3 connected by pipeline and gas valve by multiple independent reaction stills 16 and
Become, so arrange and the metal solvent fuel thing in each reactor can be made individually can to carry out high speed react with water,
And can be because of the breather line communicated, the hydrogen aqueous vapor body allowing each independent reaction still 16 upper strata produce, can be divided
Not collecting gas collecting jar with ground-on cover plate 4, then another rising supplies.The quantity of independent reaction still 16 is according to system dimension size
Or mix the demand of the yield of hydrogen energy source gas and set.About the architectural feature of each independent reaction still 16,
And the interconnected relationship of multiple independent reaction still 16 refer to hypomere and describes.
Refer to Fig. 1, Fig. 2 and Fig. 6, the left side wall of each independent reaction still 16 connects a reactor bursting tube
17, described independent reaction still bursting tube 17 is sequentially provided with Pressure gauge 18, exhaust-valve 19 and relief valve 20.
Changed by the pressure in Pressure gauge 18 observing response still；It is used for control module combination type by relief valve 20
Pressure in reactor 3 is less than setting with to protection reactor.On the sidewall of each independent reaction still 16
Being equipped with a reactor water inlet pipe 21, all of reactor water inlet pipe 21 is all communicated to expansion tank outlet pipe
15.In order to individually control the water inlet in each independent reaction still 16, each described independent reaction still 16 is intake
Pipe is provided with a high-temperature solenoid valve 22, can individually control independent reaction still 16 by this high-temperature solenoid valve 22
Interior water inlet.Connecting a reactor escape pipe 23 on each independent reaction still 16 top, all of reactor goes out
Trachea 23 all converges to gas collecting jar with ground-on cover plate 4, allows the hydrogen aqueous vapor body that each independent reaction still 16 upper strata produces, can be by
Collecting gas collecting jar with ground-on cover plate 4 respectively, then another rising supplies.It is equipped with anti-explosion electric on each reactor escape pipe 23
Magnet valve 24.The bottom of each independent reaction still 16 also connects reactor blow-off pipe 25, each described reactor
Blow-off pipe 25 is provided with electric blowdown valve 26 and manual blowdown valve 27, and reactor blow-off pipe 25 connects multistage heavy
Shallow lake groove 5.Each independent reaction still 16 is owing to being respectively provided with respective water inlet pipe and escape pipe, and water inlet pipe
Be the most individually provided with valve on outlet pipe, so can the most automatically or manually control to close down reactor
Overhead gas pipe fitting and lower section water body pipe fitting, to be individually replaced the gold in fuel rod therein and displacement fuel rod
Belong to catalyst fuel thing 29, and hydrogen energy source module combined type mixing generation system can hour be continuously run；With
Time be respectively provided with respective reactor blow-off pipe 25 due to each independent reactor, and each reactor row
It is equipped with single electric blowdown valve 26 and manual blowdown valve 27, when metal solvent fuel thing 29 on dirty pipe 25
Time excessively violent with the reaction at a high speed of the hydrogen-oxygen of water, or operator are intended at any time or this hydrogen-oxygen of emergent stopping is the most anti-
At once, blowoff valve can be opened the most safely and fast, by the water in reactor, drain into peace
In full multi stage precipitation groove 5, to slow down or to stop the reaction at a high speed of its hydrogen-oxygen.
Below the reaction medium within independent reaction still 16 is described in detail: each described independent reaction
Being provided with a fuel rod 48 in still 16, described fuel rod 48 is provided with metal solvent fuel thing 29, described gold
Belong to catalyst fuel thing 29 to react with water, produce hydrogen and release heat.Metal in fuel rod 48 touches
Matchmaker's fuel thing 29 is by three kinds of different metal catalyst, pro-oxidant, alkali compounds, and acidulants preparation and
Becoming, wherein pro-oxidant is manganese, ferrum, chromium, nickel and vanadium etc.；Alkali compound is potassium, rubidium, caesium anion, potassium,
Rubidium, caesium anion；Acidulants can be manganese heptoxide Mn2O7(the namely anhydride of permanganic acid)；Three oxidations
Chromium CrO3(the namely anhydride of chromic acid).In metal solvent fuel thing 29 the highest with the content of metallic aluminium, aluminum
Percentage composition can be up to more than 70%, secondly take second place with the content of metallic zinc, the percentage composition of zinc
Up to more than 20%, remaining is copper.When preparing metal solvent fuel thing 29, raw material is blended into many
Strip.The length diameter of strip can be depending on follow-up required hydrogen energy source yield, and length diameter is the biggest,
Producing hydrogen energy source reaction the most lasting, hydrogen energy source yield can be the biggest.Time prepared by metal solvent fuel thing 29, first,
Use mechanical polishing mode, the oxide-film of each strip surface of metal particles is abraded；Or by bar
Shaped metal is soaked in dilute sulfuric acid aqueous solution or sodium hydrate aqueous solution, to remove strip metallic particles
The oxide-film on surface；Thereafter, with clean water strip metallic particles, and drained, standby.Reaction
Before, the strip metallic particles after draining, uniformly put in fuel rod 48, then fuel rod 48 is put into
In the module combined type reactor 3 added water, react with the hydrogen energy source carried out with water.
Referring to Fig. 1 and Fig. 9, described multi stage precipitation groove 5 comprises the one-level stillpot 31 being sequentially connected in series,
Two-stage precipitation groove 32 and three grades of stillpots 33.Described one-level stillpot 31 connects described reactor blow-off pipe
25, described three grades of stillpots 33 connect the top of hot-water boiler 1 by stillpot circulation pipe 29.Described heavy
At three grades of stillpots 33, it is provided with stillpot circulating pump 30, it is provided that the power of circulation on shallow lake groove circulation pipe 29,
So that the supernatant liquid in three grades of stillpots 33 is transmitted back to hot-water boiler 1.Metal solvent fuel thing 29 is in combustion
While charge bar 48 causes the at a high speed reaction of strong hydrogen-oxygen with water, the water of reactor and the oxygen separated can be allowed
Atom reacts immediately, and produces the trickleest side-product, and trickle side-product is metal solvent oxidation
Thing or sulfide, trickle side-product also suspends in water, and becomes reaction solution, and this reaction solution can
Three grades of stillpots 5 are entered, so that metal solvent oxide or sulfide wherein can according to its concentration or timing
Gradually to precipitate, and reclaimed.Reaction solution clear liquor after one-level, two grades and three grades of precipitations,
Available stillpot circulating pump 30 is returned hot-water boiler 1 again and is heated, and can reuse, and by hot-water boiler
Electromagnetic valve expansion tank 2 between 1 and independent reaction still 16 controls, to supplement hot water at any time to independent reaction
Still 16.The top of three grades of stillpots 5 is designed with one and releases automatic exhaust steam valve, can aerofluxus automatically so that three grades
5 bearing operations of stillpot.This function mode can make the water in hydrogen energy source module combined type mixing generation system
Can constantly recycle, shut down without midway.As it is shown on figure 3, for the precipitation in scavenger precipitation groove
Material, described multi stage precipitation groove 5 is also associated with scraper-type tipping wagons 28.
The aqueous vapor that in module combined type reactor 3, reaction produces can not directly use with water smoke, therefore need to be by reacting
Still escape pipe 23 collects water hydrogen to after gas collecting jar with ground-on cover plate 4, imports in the secondary filter 6 connected up and down, profit
With secondary filter 6 structure and aqueous water therein, with water hydrogen is carried out aqueous vapor and water smoke filtration and
The cooling of gas, after secondary filter 6, unnecessary aqueous vapor and water smoke in the most removable water hydrogen,
And become mixed hydrogen.
As shown in figures 1 and 11, the structure of secondary filter 6 is described below in detail: described secondary filter 6
Including the single filter groove 46 being sequentially connected in series and cascade filtration groove 47.In the present embodiment, described single filter
It is arranged in series on groove 46 and described cascade filtration groove 47 times, can also be that left and right series connection sets the most as required
Put.The left side wall of described single filter groove 46 is near the lower end of the external serial pipe in position 34 on groove top, institute
State serial pipe 34 upper end connect described cascade filtration groove 47 left side wall near the position on groove top, described
Being provided with bending pipeline 35 in cascade filtration groove 47, the upper end of described bending pipeline 35 connects described serial pipe
The upper end of 34, the lower end of described bending pipeline 35 is positioned at the bottom land of described cascade filtration groove 47.From described
Gas collecting jar with ground-on cover plate 4 flow out mixed hydrogen at the bottom land that gas collecting jar with ground-on cover plate escape pipe 50 enters described single filter groove 46,
After the water filtration in single filter groove 46, enter serial pipe 34, serial pipe 34 enter described two
Bending pipeline 35 in level filter tank 47, is arrived the groove of described cascade filtration groove 47 by described bending pipeline 35
Bottom, by the air collector escape pipe on the groove top of cascade filtration groove 47 after the water filtration in cascade filtration groove 47
42 flow into air collector 7.The left side wall of described single filter groove 46 is near the position external single filter groove on groove top
Water inlet pipe 36, described single filter groove water inlet pipe 36 is provided with filter tank water intaking valve 37, in order to control entrance
The water yield in single filter groove 46.The left side wall of described cascade filtration groove 47 is near the position on groove top external two
Level filter tank water inlet pipe 38, cascade filtration groove water inlet pipe 38 is provided with filter tank water intaking valve 37, in order to control into
Enter the water yield in cascade filtration groove 47, cascade filtration groove water inlet pipe 38 and described single filter groove water inlet pipe 36
Converge.The right side wall of described single filter groove 46 near the position of bottom land external single filter groove blow-off pipe 39,
Described single filter groove blow-off pipe 39 is provided with blowoff valve 11, and the right side wall of described cascade filtration groove 47 is close
The position external cascade filtration groove blow-off pipe 40 of bottom land, described cascade filtration groove blow-off pipe 40 also is provided with blowdown
Valve 11, described single filter groove blow-off pipe 39 downwardly extends and converges with described cascade filtration groove 47 blow-off pipe 40.
As shown in figure 11, the gas outlet of the escape pipe 41 of the tank deck connection cascade filtration groove of described air collector 7
With the air inlet of air collector escape pipe 42, described air collector escape pipe 42 connects air accumulator 8.Described air collector
Pressure gauge 18, exhaust-valve 19 and relief valve 20 it is respectively equipped with on the tank deck of 7.Through secondary filter 6 mistake
After filter produce mixed hydrogen, can again through air collector 7, this air collector 7 system every time start shooting operating time,
Can be as system release of pressure and the function of air-out；Thereafter, the mixed hydrogen after buffered imports gas storage again
Tank 8, so that the output that mixed hydrogen can be stable, and reach to prevent gas backstreaming and protection secondary filter 6
Purpose with gas collecting jar with ground-on cover plate 4.
As shown in figure 12, it is available for subsequent use after the mixed hydrogen voltage stabilizing in described air accumulator 8.Described storage
The tank deck of gas tank 8 connects gas outlet and the air accumulator escape pipe 43 of described air collector escape pipe 42.Described gas collection
At described air accumulator 8, it is provided with explosion-proof solenoid valve 24 on tank escape pipe 42.On the tank deck of described air accumulator 8
It is additionally provided with also Pressure gauge 18, exhaust-valve 19 and relief valve 20.The tank bottoms place of described air accumulator 8 is provided with
Air accumulator blow-off pipe 44, described air accumulator blow-off pipe 44 is provided with blowoff valve 11, and air accumulator blow-off pipe 44 leads to
Piping connects air accumulator vacuum pump 45.
The operation principle of native system, as described below,
Equipped with the fuel rod 48 of metal solvent fuel thing 29, put in the independent reaction still added water and make water temperature reach
During to more than 80 DEG C Celsius, metal solvent fuel thing 29 can start fast reaction with water, and makes in hydrone
The D-atom of hydrogen, tritium atom, oxygen atom extremely fast separate, and synchronize occur D-atom, tritium atom,
The high speed bounce-back of electronics between oxygen atom, hydrone, high speed impact, high speed are to the resonance motion hitting formation
In, then produce the hydrogen aqueous vapor body of High water cut gas and water mist.Hydrogen aqueous vapor body is being removed through secondary filter 6
After aqueous vapor in hydrogen aqueous vapor body, water smoke, become required efficient heat energy, with low cost, absolute without dirty
The clean energy resource of dye: mixing hydrogen energy source gas.
In aforesaid high speed bounce-back, high speed impact, high speed are to the resonance motion hitting formation, hydrogen atom
Hypervelocity impact can occur mutually between deuterium, tritium and hydrone, and then small part atom, intermolecular occurs
Fusion phenomenon, and produce the hydrogen aqueous vapor body of aqueous gas and water mist.During the reaction at a high speed of this hydrogen-oxygen, system
As exothermic phenomenon occurs in the polymerization of reaction, and then the cavity inner temperature of reactor, pressure is made gradually to rise
Height, and form reaction fiercer, more at a high speed.At this moment, it is being not required to the electric energy in the external world, heat energy
In the case of, just can cause water in reactor heats the situation with supercharging naturally.Inside it is contained in the water of fuel rod 48
Under the thermal source and the pressure environment that run into more than 100 DEG C, the deuterium in hydrogen atom, tritium, oxygen can be disengaged faster
Atom, and there is fiercer high speed head-on collision, and produce more high-speed turbine resonance effect, so becoming
Chain high speed hydrogen-oxygen separating reaction phenomenon.Aqueous vapor, water smoke is filtered through secondary filter 6, hydrogen aqueous vapor body,
Being mixing hydrogen energy source gas, it has combustibility, and calorific value can reach every cubic metre 10, and 000-11500 is big
Card, and ignition temperature is up to 1,100-1,350 DEG C (ignition temperature of pure hydrogen about 3, about 200 DEG C).Due to,
Mixing hydrogen energy source gas is without any impurity, therefore after burning (oxidation) and discharging a large amount of calorific value, only can go back
The moisture that former one-tenth is pure, without polluting any environment.
The sustainable continuous generation efficient heat energy of hydrogen energy source module combined type mixing generation system and perfection cleaning
Mixing hydrogen energy source gas, therefore can be extensively instead of using coal, natural gas, the fossil energy oil such as vapour bavin is used for
Electricity, heating, automobile, steamer, Aeronautics and Astronautics etc. uses, and can be more that national energy-saving subtracts carbon, pollutes and prevent
Controlling, administer haze, major contribution is made in economic development, ecological protection.
Obviously, those skilled in the art can carry out various change and modification without deviating from this to the present invention
Bright spirit and scope.So, if the present invention these amendment and modification belong to the claims in the present invention and
Within the scope of its equivalent technologies, then the present invention is also intended to comprise these change and modification.
Claims (10)
1. a hydrogen energy source module combined type mixing generation system, it is characterised in that: include hot-water boiler, heat
Homogeneous solution-type reactor passes through electromagnetic valve expansion tank link block combination type reactor, and module combined type reactor top is even
Logical gas collecting jar with ground-on cover plate, bottom connection multi stage precipitation groove, gas collecting jar with ground-on cover plate is sequentially communicated secondary filter, air collector and storage
Gas tank；Module combined type reactor is formed by connecting by pipeline and gas valve, often by multiple independent reaction stills
Being provided with fuel rod in one independent reaction still, fuel rod is provided with metal solvent fuel thing；Hot-water boiler right side wall
Near the connection boiler discharging tube road, position on groove top, boiler discharging tube road connects electromagnetic valve expansion tank；Electromagnetism
Valve expansion tank is provided with expansion tank outlet pipe, and the sidewall of each independent reaction still is equipped with a reactor
Water inlet pipe, all of reactor water inlet pipe is all communicated to expansion tank outlet pipe, and each independent reaction still is intake
Pipe is provided with a high-temperature solenoid valve；Connect a reactor escape pipe on each independent reaction still top, each instead
Answer and be equipped with explosion-proof solenoid valve on still escape pipe；The bottom of each independent reaction still also connects reactor blow-off pipe,
Each reactor blow-off pipe is provided with electric blowdown valve and manual blowdown valve, and the connection of reactor blow-off pipe is multistage heavy
Shallow lake groove.
Hydrogen energy source module combined type mixing generation system the most according to claim 1, it is characterised in that: hot water
The left side wall of boiler connects combustor near the position of furnace bottom, and combustor uses natural gas, diesel oil and liquefaction
Hot-water boiler is heated by any one in these incendiary materials of gas.
Hydrogen energy source module combined type mixing generation system the most according to claim 1, it is characterised in that: fuel
Metal solvent fuel thing in rod is to be prepared from by three kinds of different metal catalyst, alkali compound and acidulants.
Hydrogen energy source module combined type mixing generation system the most according to claim 3, it is characterised in that: three kinds
Different metal solvents is aluminum, zinc and copper respectively.
Hydrogen energy source module combined type mixing generation system the most according to claim 3, it is characterised in that: metal
Catalyst fuel is strip.
Hydrogen energy source module combined type mixing generation system the most according to claim 1, it is characterised in that: multistage
Stillpot comprises the one-level stillpot being sequentially connected in series, two-stage precipitation groove and three grades of stillpots；One-level stillpot
Coupled reaction still blow-off pipe, three grades of stillpots connect the top of hot-water boiler by reactor circulation pipe.
Hydrogen energy source module combined type mixing generation system the most according to claim 6, it is characterised in that: reaction
At three grades of stillpots, it is provided with reactor circulating pump on still circulation pipe.
Hydrogen energy source module combined type mixing generation system the most according to claim 6, it is characterised in that: multistage
Stillpot is also associated with scraper-type tipping wagons.
Hydrogen energy source module combined type mixing generation system the most according to claim 1, it is characterised in that: gas collection
Tank connects air collector escape pipe, and air accumulator connects air accumulator escape pipe, and air collector escape pipe and air accumulator are given vent to anger
Explosion-proof solenoid valve it is equipped with on pipe.
Hydrogen energy source module combined type mixing generation system the most according to claim 1, it is characterised in that: storage
The tank bottoms place of gas tank is provided with air accumulator blow-off pipe, and air accumulator blow-off pipe is provided with blowoff valve, air accumulator blow-off pipe
Air accumulator vacuum pump is connected by pipeline.
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| CN201610281092.4A CN105947978A (en) | 2016-04-29 | 2016-04-29 | Combined mixed generation system of hydrogen energy module |
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| CN201610281092.4A CN105947978A (en) | 2016-04-29 | 2016-04-29 | Combined mixed generation system of hydrogen energy module |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110111668A (en) * | 2018-02-01 | 2019-08-09 | 中国石油大学(北京) | More kettle interconnection type Gas Hydrate Deposition/exploitation analogue simulation devices and purposes |
| CN113526463A (en) * | 2021-08-27 | 2021-10-22 | 重庆创新燃料电池技术产业研究院有限公司 | Modularization hydrogen production device |
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| TW201105574A (en) * | 2009-08-11 | 2011-02-16 | Yu-Chung Chin | Method for producing fusion |
| CN105439085A (en) * | 2015-12-11 | 2016-03-30 | 杨中梁 | System for generating energy through hydrogen oxygen separation |
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- 2016-04-29 CN CN201610281092.4A patent/CN105947978A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201105574A (en) * | 2009-08-11 | 2011-02-16 | Yu-Chung Chin | Method for producing fusion |
| CN105439085A (en) * | 2015-12-11 | 2016-03-30 | 杨中梁 | System for generating energy through hydrogen oxygen separation |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110111668A (en) * | 2018-02-01 | 2019-08-09 | 中国石油大学(北京) | More kettle interconnection type Gas Hydrate Deposition/exploitation analogue simulation devices and purposes |
| CN110111668B (en) * | 2018-02-01 | 2021-02-05 | 中国石油大学(北京) | Multi-kettle interconnection type natural gas hydrate accumulation/exploitation simulation device and application |
| CN113526463A (en) * | 2021-08-27 | 2021-10-22 | 重庆创新燃料电池技术产业研究院有限公司 | Modularization hydrogen production device |
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