CN101527195A - Variable impedance composition - Google Patents
Variable impedance composition Download PDFInfo
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- CN101527195A CN101527195A CNA2008101702237A CN200810170223A CN101527195A CN 101527195 A CN101527195 A CN 101527195A CN A2008101702237 A CNA2008101702237 A CN A2008101702237A CN 200810170223 A CN200810170223 A CN 200810170223A CN 101527195 A CN101527195 A CN 101527195A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/10—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material voltage responsive, i.e. varistors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/10—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material voltage responsive, i.e. varistors
- H01C7/105—Varistor cores
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/10—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material voltage responsive, i.e. varistors
- H01C7/105—Varistor cores
- H01C7/108—Metal oxide
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Abstract
Disclosed is a variable impedance composition according to this aspect of the present invention comprises a high conductive powder in an amount from 10% to 85% of the weight of the variable impedance composition, and an insulation adhesive in an amount from 10% to 30% of the weight of the variable impedance composition. The power containing carbonyl metal (such as carbonyl iron power or carbonyl nickel powder) can be added into the variable impedance composition, not only the voltage can be restrained but also the instantaneous current can be dispersed. Compared with the material used by conventional electrostatic discharge protection device, the discharge can be reduced and the trigger voltage of element can be reduced by using the metal power of carbonyl metal variable impedance composition, and the high conductive property can absorb the electromagnetic radiation which can cause signal damage and data loss.
Description
Technical field
The present invention relates to a kind of variable impedance composition, relate in particular a kind of comprise can reduce moment high pressure to the hurtful high electroconductive magnetic metal dust of electronic product.
Background technology
Integrated circuit is accepted outside power supply supply and pending input signal, and the signal after the output processing.In particular, because the input of integrated circuit is the grid that is directly connected in input stage switch, thereby suffer damage quite easily.When integrated circuit was welded on the circuit board by manual clamping or automatic equipment, predispose to damage input and output promptly may be subjected to static discharge and damage.For example, human body discharges via the integrated circuit of input to semiconductor element after can being charged via static again.
After also may being recharged, the instrument of automatic assembling platform or tester table discharges via the input of integrated circuit integrated circuit again to semiconductor element.Along with the continuous evolution of semiconductor technology, the live width of semiconductor element is also dwindled thereupon, and the demand of the protection mechanism of resisting static discharge also manifests thereupon.Integrated circuit component disposes static discharge mostly, and (electrostatic discharge, ESD) protection mechanism for example disposes resistive element in input to avoid too high input current, thereby limits input current.
US 6,642, and 297 disclose a kind of composition that the overvoltage/overcurrent protection is provided, and it comprises insulating adhesive, doping semiconduction particle and electroconductive particle.Described composition has high resistance when normal operating voltage, but switches to low resistance state and limit described overvoltage to reduced levels in described overvoltage temporal event when bearing the instantaneous overvoltage incident.
US 6,013, and 358 disclose a kind of overvoltage protection element, and it uses diamond saw to form the gap between earthing conductor and another conductor.The backing material of described overvoltage protection element can be selected from particular ceramic material, and its density is less than 3.8g/cm
3
US 5,068, and 634 disclose a kind of overvoltage protection element and material, and it makes the voltage protection material have nonlinear resistance characteristic by conducting particles is scattered in the binding agent equably.Nonlinear resistance characteristic depends on the spacing of particle in binding agent and the electrical characteristics of binding agent.By adjusting the spacing of conducting particles, the electrical characteristics of nonlinear material can be changed on a large scale one.
US 6; 498; 715 disclose a kind of stack overvoltage protective element with low capacitance, comprise substrate, be arranged at conductivity bottom electrode on the substrate, be arranged at the voltage sensitive material on the described conductivity bottom electrode and be arranged at conduction top electrode on the described voltage sensitive material.
US 6,645, and 393 disclose a kind of material that suppresses instantaneous voltage, comprise two kinds of mixed uniformly powder, and wherein a kind of powder has nonlinear resistance property, and another kind of powder is a conductive powder.Conductive powder is scattered in the powder with nonlinear resistance property to reduce the whole nonlinear resistance property of element, promptly reduces the breakdown voltage of element.
Except ESD, electronic component also very easily is subjected to effect of electromagnetic radiation, and particularly the influence to digital computing system is bigger.Comprise the transistor that much more very comes switch and transmission signals in the digital computing system, and the result of its operation has produced considerable amount of electromagnetic radiation with flank speed.Transistor switch state, signal corruption and data degradation that the electromagnetic radiation of dissipation may lead to errors.
Have at present and manyly can be used to protect electronic component to avoid being subjected to the technology of electromagnetic radiation.Wherein, be a kind of method that is widely known by the people with metal shell as protection, it is to come block electromagnetic radiation by high conductive surface with reflection way.Yet metal shell is not only expensive, and lacks by the effect Chang Yin that reflection reaches protection and to allow the ability of radiation dissipation cause escape.European Patent Publication No discloses a kind of structure of bosom floor for EP0550373 number, and it is made with the material of the lower conductivity of the higher magnetic conductivity of tool and tool.When being subjected to effect of electromagnetic radiation, described intermediate layer will absorb most energy of electromagnetic field.Compare with high conductive material, the material of high magnetic conductivity and low electric conductivity shows more efficient aspect absorbed radiation.
In the reception and emitter of high frequency, the generation of static and electromagnetic coupling effect is common.U.S. Pat 5,565,878 disclose a kind of ring protection metal patterns that is arranged on the glass window, and it is to be arranged on the glass window for strong static of generation and electromagnetic coupled between the electric conductor of described ring protection metal patterns and glass window periphery.
U.S. Pat 6,058,000 discloses the method for a kind of electromagnetic interference and ESD protection.Described inventive method teaching realizes electromagnetic interference and ESD protection with shell, the internal Protection conducting plane on tool guard conductor surface, the conductor connector that is used to connect described guard conductor surface and described guard conductor plane, the formation that makes electromagnetic signal be passed the channel on described guard conductor plane, filter circuit and static clamp circuit etc.The realization means of electromagnetic protection then have: to input signal carry out filtering, signal that frequency range is not inconsistent demand is electrically connected to the protection potential barrier, and the signal that voltage is not inconsistent demand is electrically connected to protection potential barrier etc.And wherein, the guard conductor plane in the invention is what to separate on structural design with ground plane.
The application patent of electromagnetism and ESD protection has WO/1996/028951 " implanted device of tool electrostatic discharge protective ".Described patent is addressed the situation of the cochlea failure of apparatus of sub-fraction, and wherein, have in several devices with receive information-related element and be subjected to high-voltage electric shock and damage.In the laboratory, once carried out related experiment for several times, attempt on other cochlea device, to repeat similar inefficacy situation.In particular, implanted device is soaked in the normal saline solution of imitative body fluid and tissue, and it is because of causing the generation of ESD under the influence of high electromagnetic field intensity.Learn that thus the destruction of wanting protector to get shocked not only it should be noted that the protection of ESD aspect, and it is also noted that the influence of electromagnetic field aspect.
Among the guide for use SI97-01 that Shang Shengte company (SEMTECH CORPORATION) is published, how narration uses transient voltage suppressing, and (Transient Voltage Suppression, TVS) element comes protective device not to be subjected to the infringement of ESD.Point out in the described guide that the static discharge that is taken place can cause electromagnetic wave to pass through the transceiver circuit plate interface and arrives on the circuit board in the shielding of coaxial connector.This electromagnetic wave is to transmit along the lead that connects between described shielding and the motherboard ground plane (Groud Plane).The inductive effect of circuit board lead can intercept then that (Collision Detect Sense CDS) produces the voltage potential be higher than 1.5kV on the pin in collision detection.The voltage overload of this grade can be destroyed the insulation of transponder chip.Similarly, the current impulse of flowing at conductor can produce the electrical transition that takes place because of electromagnetic coupled near other element that is positioned on the circuit board it.The TVS diode promptly is to be designed to this transient current is shunted out from shielded Ethernet transceiver.The TVS diode can suppress overvoltage simultaneously and transient current is shunted.Yet high unit price and shortage dissipation capabilities are the major defects of TVS diode.
Summary of the invention
The present invention proposes a kind of variable impedance composition that comprises conductive powder, semiconductor powder and insulation adhesive thing, and it applies voltage status and present high-ohmic low, then presents low resistance characteristic but apply voltage status at height.
Variable impedance composition of the present invention comprises conductive powder, semiconductor powder and insulation adhesive thing.The content of conductive powder can between described variable impedance composition weight 10% to 30% between, the content of semiconductor powder can between described variable impedance composition weight 30% to 90% between, the content of insulation adhesive thing can between described variable impedance composition weight 3% to 50% between.Described variable impedance composition applies voltage status and presents high-ohmic low, then presents low resistance characteristic but apply voltage status at height.Described variable impedance composition is arranged at the gap between the conductor of overvoltage protection element, the integral body of described overvoltage protection element promptly has low and presents low resistance and then present low-resistance electrical characteristics when height applies voltage when applying voltage.
The present invention also proposes a kind of variable impedance composition that comprises high conductive magnetism powder, and it can reduce the trigger voltage of element, and presents high-ohmic and apply voltage status at height and then present low resistance characteristic in the low voltage status that applies.
Variable impedance composition of the present invention comprises high conductive magnetism powder and insulation adhesive thing.The content of high conductive magnetism powder can between described variable impedance composition weight 10% to 85% between, the content of insulation adhesive thing can between described variable impedance composition weight 10% to 30% between.
In variable impedance composition, add and comprise that the powder (for example carbonyl iron dust or carbonyl nickel powder) of metal carbonyl can not only suppress overvoltage, and the transient current that can dissipate.Compare the material that the conventional electrostatic electric discharge device uses, the metal dust of the high electroconductive magnetic of use metal carbonyl can reduce the trigger voltage of element, and its high conductive magnetism characteristic also can absorb the electromagnetic radiation that partly can cause distorted signals and error in data.
In an embodiment of the present invention, described variable impedance composition applies voltage status and presents high-ohmic low, then presents low resistance characteristic but apply voltage status at height.By described variable impedance composition being arranged at the gap between two conductors in the overvoltage protection element, the integral body of described overvoltage protection element promptly has low and presents high resistance and then present low-resistance electrical characteristics when height applies voltage when applying voltage.
Above sketch out technical characterictic of the present invention and advantage make the specific embodiment of the invention hereinafter be obtained preferable understanding.Other technical characterictic and the advantage that constitute claims target of the present invention will be described in hereinafter.The those skilled in the art should understand, and hereinafter the notion of Jie Shiing can be used as the basis with specific embodiment and revised or design other structure quite easily or technology and realize the purpose identical with the present invention.The those skilled in the art also should understand, and the construction of this class equivalence also can't break away from the spirit and scope of the present invention that claims proposed of enclosing.
Description of drawings
Fig. 1 is to the overvoltage protection element of Fig. 5 illustration first embodiment of the invention;
The overvoltage protection element of Fig. 6 illustration second embodiment of the invention;
Fig. 7 illustration overvoltage protection element and load parallel circuits schematic diagram;
Fig. 8 is the resistance and the graph of a relation that applies voltage of variable impedance composition of the present invention;
Fig. 9 shows the response the when overvoltage protection element of first embodiment of the invention bears instantaneous voltage;
The overvoltage protection element of Figure 10 illustration third embodiment of the invention; And
Figure 11 shows the response the when overvoltage protection element of the third embodiment of the present invention bears instantaneous voltage.
Embodiment
Fig. 1 is to the overvoltage protection element 10 of Fig. 5 illustration first embodiment of the invention.With reference to figure 1, form electrode structure 20 on substrate 12, substrate 12 can be made of insulating material (for example plastic material), that is to say that substrate 12 can be plastic, and has upper surface 12A and lower surface 12B.Electrode structure 20 comprises the first non-rectangle conductor 14, the second non-rectangle conductor 16, first side electrode 22 and second side electrode 24.The first non-rectangle conductor 14 has the first protuberance 14A that is arranged at upper surface 12A, the second non-rectangle conductor 16 has the second protuberance 16A that is arranged at upper surface 12A, first side electrode 22 is arranged at a side of substrate 12 and is connected in the first non-rectangle conductor 14, and second side electrode 24 is arranged at another side of substrate 12 and is connected in the second non-rectangle conductor 16.
In addition, electrode structure 20 comprise in addition first electric-conductor 22 ' and second electric-conductor 24 ', it can be electroplated metal layer or conductive through hole.First electric-conductor 22 ' be located between substrate 12 and the first side electrode 22, second electric-conductor 24 ' be located between substrate 12 and the second side electrode 24.Preferably, one among the first protuberance 14A and the second protuberance 16A is taper protuberances, and it has the width of convergent.The second protuberance 16A towards the first protuberance 14A to form between the discharge path between the two 18.
Preferably, the first non-rectangle conductor 14 and the second non-rectangle conductor 16 be trapezoidal and with mirror mutually mode be arranged on the substrate 12.In particular, the profile of the first non-rectangle conductor 14 can be different from the second non-rectangle conductor 16.The first protuberance 14A has the first orle 14B, and the second protuberance 16A has the second orle 16B, and the second orle 16B is towards the first orle 14B.
With reference to figure 2, it is the cut-away view of the electrode structure 20 of Fig. 1.The width of the upper end of the first protuberance 14A and the second protuberance 16A that is to say that greater than the width in stage casing the first protuberance 14A and the second protuberance 16A have thickness heterogeneous.Therefore, compare the middle section, the first protuberance 14A and the second protuberance 16A are more close each other at upper end, so discharge path 18 is formed between first protuberance 14A upper end and the second protuberance 16A upper end.
With reference to figure 3, variable impedance composition 26 is formed between the first protuberance 14A and the second protuberance 16A.Variable impedance composition 26 can comprise conductive powder, semiconductor powder and insulation adhesive thing.The content of conductive powder can between variable impedance composition weight 10% to 30% between, the content of semiconductor powder can between variable impedance composition weight 30% to 90% between, the content of insulation adhesive thing can between variable impedance composition weight 3% to 50% between.
Preferably, in the group that the optional free aluminium of conductive powder, silver, palladium, platinum, gold, nickel, copper, tungsten, chromium, iron, zinc, titanium, niobium, molybdenum, ruthenium, lead and iridium are formed one, semiconductor powder can comprise zinc oxide or carborundum, and the insulation adhesive thing comprises epoxy resin or silica gel.In addition, variable impedance composition 26 can comprise insulating powder in addition, its content between variable impedance composition weight 10% to 60% between, wherein insulating powder can comprise metal oxide, for example aluminium oxide or zirconia.
With reference to figure 4 and Fig. 5, discharge prevention layer 30 covers variable impedance composition 26, and insulating barrier 32 covers discharge prevention layer 30.Preferably, discharge prevention layer 30 can comprise inorganic insulating material and organic insulating material, and wherein inorganic insulating material can comprise metal oxide, and organic insulating material can comprise epoxy resin or silica gel.Insulating barrier 32 can comprise inorganic insulating material and organic insulating material, and wherein inorganic insulating material comprises metal oxide, and organic insulating material comprises epoxy resin or silica gel.
The overvoltage protection element 10 of Fig. 6 illustration second embodiment of the invention '.Compare overvoltage protection element shown in Figure 5 10, the overvoltage protection element 10 of Fig. 6 ' comprise the in addition contraposition block 34 that at least one is arranged at lower surface 12B.When overvoltage protection element 10 ' in the time of being attached on the circuit board, contraposition block 34 can be in order to another contraposition block on the alignment circuit plate.In addition, contraposition block 34 be not electrically connected on over-current protecting element 10 ' conducting element, and contraposition block 34 also can optionally be designed to more than two or two.
The parallel circuits 40 of Fig. 7 illustration overvoltage protection element 10 and load 44.Overvoltage protection element 10 is in parallel with load 44, and when high instantaneous voltage 42 put on overvoltage protection element 10, overvoltage protection element 10 switched to low resistance state and low voltage value is arrived in instantaneous voltage 42 limits.That is to say that the load 44 that is parallel to overvoltage protection element 10 will be born the instantaneous voltage after the limit.
Fig. 8 is the resistance and the graph of a relation that applies voltage of variable impedance composition 26 of the present invention.Variable impedance composition 26 applies voltage status and presents high-ohmic low, then presents low resistance characteristic but apply voltage status at height.By variable impedance composition 26 being arranged at the gap of the first non-rectangle conductor 14 and the second non-rectangle conductor 16, the integral body of overvoltage protection element 10 promptly has low and presents low resistance and then present low-resistance electrical characteristics when height applies voltage when applying voltage.
Fig. 9 shows the response the when overvoltage protection element 10 of first embodiment of the invention bears instantaneous voltage 42.With reference to figure 7 and Fig. 9; under overvoltage protection element 10 and load 44 situation in parallel; when 1900 volts instantaneous voltages 42 put on the first non-rectangle conductor 14 of overvoltage protection element 10 and the second non-rectangle conductor 16, overvoltage protection element 10 switched to low resistance state and 1900 volts instantaneous voltage 42 limits is about 518 volts.That is to say, be about 518 volts instantaneous voltage after the load 44 that is parallel to overvoltage protection element 10 will be born limit, rather than bear 1900 volts instantaneous voltage 42.
Conventional overvoltage protection element all adopts two wide and conductors that separated with the gap, and therefore the discharge path position of conventional overvoltage protection element is unpredictable.Relatively, overvoltage protection element 10 of the present invention has two non-rectangle conductors 14,16, and protuberance 14A, the 16A of two non-rectangle conductors 14,16 are toward each other, and therefore the spacing of two non-rectangle conductors 14,16 is not a uniformity.In particular, the gap of two non-rectangle conductors 14,16 is narrower than other position at the width of its protuberance 14A, 16A position, so discharge path promptly designs in protuberance 14A, 16A position, and variable impedance composition 26 covers protuberance 14A, 16A.
The overvoltage protection element 10 of Figure 10 illustration third embodiment of the invention ".Overvoltage protection element 10 " comprises substrate 12 and is arranged at first conductor 52 and second conductor 54 on the substrate 12, and separated with gap 56 between first conductor 52 and second conductor 54, and variable impedance composition 26 ' place gap 56.Need to prove that in addition first conductor 52 and second conductor 54 can be Any shape and still do not deviate from the disclosed scope of the present invention.In an embodiment of the present invention, variable impedance composition 26 ' can comprise high conductive magnetism powder and insulation adhesive thing.The content of high conductive magnetism powder can between variable impedance composition weight 10% to 90% between, its content be preferably variable impedance composition weight 20% to 86% between; The content of insulation adhesive thing can between variable impedance composition weight 10% to 90% between, its content be preferably variable impedance composition weight 14% to 80% between.
Figure 11 shows the overvoltage protection element 10 " response when bearing instantaneous voltage 42 of the third embodiment of the present invention.With reference to figure 7 and Figure 10; first conductor 52 that the overvoltage protection element 10 of Fig. 7 " is tested and can be found after the displacement; when 2000 volts instantaneous voltages 42 put on overvoltage protection element 10 " with voltage protection element 10 and during, overvoltage protection element 10 with first conductor, 54 ground connection " switch to low resistance state and with 2000 volts instantaneous voltage 42 limits to the trigger voltage that is about 307 volts.That is to say, be parallel to overvoltage protection element 10 " load 44 be about 307 volts instantaneous voltage after will bearing limit, rather than bear 2000 volts instantaneous voltage 42.
In an embodiment of the present invention, high conductive magnetism powder comprises carbonyl ligands (Carbonyl Ligand).For example, high conductive magnetism powder comprises metal carbonyl powder (Carbonyl Metal), and it can comprise for example carbonyl iron dust (CarbonylIron), carbonyl nickel powder (Carbonyl Nickel) or carbonyl nickel cobalt alloy powder (Carbonyl Nickel/Cobalt Alloy).In an embodiment of the present invention, the insulation adhesive thing comprises epoxy resin or silica gel.Following Table I show the variable impedance composition 26 of different mixing proportion ' example:
Table I:
| The example numbering | The conductive magnetism powder | The insulation adhesive thing | Trigger voltage |
| Example 1 | 86％ | 14％ | 353V |
| Example 2 | 70％ | 30％ | 500V |
| Example 3 | 50％ | 50％ | 600V |
| Example 4 | 20％ | 80％ | 1157V |
The employed conductive magnetism powder of above-mentioned example is carbonyl iron dust (the Carbonyl Iron Power of BASF (BASF) metal carbonyl that company produced; CIP), its model is enpulver SW-S, and the employed insulation adhesive thing of above-mentioned example is the silica gel of Qiaoyue Industrial Co., Ltd. (SIL-MORE INDUSTRIAL LTD) manufacturing, and its model is SLR9530A﹠amp; B.(model: ESD-8012A) test its experimental condition: the ESD-8012A output voltage is 2kV, INT.90, discharge 30 times to the electro-static discharging generator that trigger voltage is then produced with three (SANKI).Example 1 all shows to example 4, variable impedance composition 26 ' middle adding with the carbonyl iron dust and insulation adhesive thing that mix in the certain proportion after, can be with trigger voltage limit 1200 volts times in the esd protection upper voltage limit.Show the content of conductive magnetism powder from 20% to 86% and still can be under 1200 volts in the Table I with the trigger voltage limit.But inference thus, the proper content of conductive magnetism powder can be between 10% to 90%.In addition, the content of insulation adhesive thing from 14% to 80% in the Table I and still can be under 1200 volts with the trigger voltage limit, but also the proper content level of inference insulation adhesive thing can be between 10% to 90% thus.
In another embodiment of the present invention, variable impedance composition 26 ' comprise in addition semiconductor powder.Semiconductor powder comprises zinc oxide or carborundum.The content of semiconductor powder can between variable impedance composition weight 0.001% to 10% between, its content with between variable impedance composition weight 0.001% to 8% serve as preferred, and content with between variable impedance composition weight 1% to 6.5% for more preferably.Following Table II promptly show the variable impedance composition 26 of different mixing proportion ' example:
Table II:
| The example numbering | The conductive magnetism powder | Semiconductor powder | The insulation adhesive thing | Trigger voltage |
| Example 5 | 75.80％ | 6.20％ | 18.00％ | 1050V |
| Example 6 | 76.77％ | 5.63％ | 17.60％ | 892V |
| Example 7 | 78.35％ | 4.19％ | 17.46％ | 763V |
| Example 8 | 80.04％ | 2.75％ | 17.21％ | 639V |
| Example 9 | 81.71％ | 1.36％ | 16.93％ | 560V |
| Example 10 | 84.50％ | 1.00％ | 14.50％ | 390V |
This embodiment with semiconductor powder (for example: zinc oxide) sneak in carbonyl iron dust and the silica gel mixture of polymers is.The content that shows zinc oxide in the Table II between 1.00% to 6.20%, and still can the limit trigger voltage in 1200 volts times.But inference in view of the above, the appropriate level of zinc oxide is between 0.001% to 10%.
In another embodiment of the present invention, variable impedance composition 26 ' comprise in addition insulating powder.Insulating powder comprises metal oxide, and it can be as aluminium oxide or zirconia.The content of insulating powder can between variable impedance composition weight 0.001% to 10% between, its content with between variable impedance composition weight 0.001% to 8% serve as preferred, and content with between variable impedance composition weight 1% to 6% for more preferably.Following Table III promptly show the variable impedance composition 26 of different mixing proportion ' example:
Table III:
| The example numbering | The conductive magnetism powder | Insulating powder | The insulation adhesive thing | Trigger voltage |
| Example 11 | 76％ | 6.00％ | 18.00％ | 1150V |
| Example 12 | 80.04％ | 2.75％ | 17.21％ | 752V |
| Example 13 | 84.50％ | 1.00％ | 14.50％ | 420V |
This embodiment with insulating powder (for example: alundum (Al) sneak in carbonyl iron dust and the silica gel mixture of polymers is.The content that shows alundum (Al in the Table III is between 1.00% to 6.00%, and this still can the limit trigger voltage descend in 1200 volts.But inference in view of the above, the appropriate level of alundum (Al is between 0.001% to 10%.Moreover, in this mixture, variable impedance composition 26 ' can comprise semiconductor powders such as zinc oxide or carborundum, its content can account for variable impedance composition weight 0.001% to 10% between.
It is to be selected from the group that is made up of nickel, cobalt, iron, aluminium and neodymium that high conductive magnetism powder comprises at least a element, and described element and organo-functional group (as carbonyl, siloxanes, amido etc.) form compound.In particular, high conductive magnetism powder is to be selected from carbonyl iron dust, carbonyl nickel powder or carbonyl nickel cobalt alloy powder etc.And wherein, carbonyl iron dust (CIP) is chosen as the usefulness of research especially.Semiconductor powder comprises zinc oxide or carborundum, and the insulation adhesive thing comprises epoxy resin or silica gel.In addition, variable impedance composition 26 ' more can the comprise insulating powder of aluminium oxide or zirconia etc.
Comprise that in variable impedance composition 26 ' middle adding metal carbonyl powder (as carbonyl iron dust or carbonyl nickel powder) can not only suppress overvoltage, and the transient current that can dissipate.Be to reduce the trigger voltage of element with conventional static discharge device difference with the relative high conductive magnetism metal dust of metal carbonyl.High conductive magnetism characteristic also can absorption can cause the electromagnetic radiation of signal corruption and data degradation.
Technology contents of the present invention and technical characterstic disclose as above, yet the those skilled in the art still may be based on teaching of the present invention and announcement and done all replacement and modifications that does not deviate from spirit of the present invention.Therefore, protection scope of the present invention should be not limited to that embodiment discloses, and should comprise various do not deviate from replacement of the present invention and modifications, and is contained by following claims.
Claims (21)
1, a kind of variable impedance composition is characterized in that comprising:
Conductive powder, its content between described variable impedance composition weight 10% to 30% between;
Semiconductor powder, its content between described variable impedance composition weight 30% to 90% between; And
The insulation adhesive thing, its content between described variable impedance composition weight 3% to 50% between.
2, variable impedance composition as claimed in claim 1 is characterized in that the material of described conductive powder is selected from one in the group that is made up of aluminium, silver, palladium, platinum, gold, nickel, copper, tungsten, chromium, iron, zinc, titanium, niobium, molybdenum, ruthenium, lead and iridium.
3, variable impedance composition as claimed in claim 1 is characterized in that described semiconductor powder comprises zinc oxide or carborundum.
4, variable impedance composition as claimed in claim 1 is characterized in that described insulation adhesive thing comprises epoxy resin or silica gel.
5, variable impedance composition as claimed in claim 1 is characterized in that comprising in addition insulating powder, its content between described variable impedance composition weight 10% to 60% between.
6, variable impedance composition as claimed in claim 5 is characterized in that described insulating powder comprises metal oxide.
7, variable impedance composition as claimed in claim 6 is characterized in that described metal oxide is aluminium oxide or zirconia.
8, a kind of variable impedance composition is characterized in that comprising:
High conductive magnetism powder, its content between described variable impedance composition weight 10% to 90% between; And
The insulation adhesive thing, its content between described variable impedance composition weight 10% to 90% between.
9, variable impedance composition as claimed in claim 8, wherein said high conductive magnetism powder comprises carbonyl ligands.
10, variable impedance composition as claimed in claim 8 is characterized in that described high conductive magnetism powder comprises metal carbonyl powder.
11, variable impedance composition as claimed in claim 8 is characterized in that described high conductive magnetism powder comprises carbonyl iron dust, carbonyl nickel powder or carbonyl nickel cobalt alloy powder.
12, variable impedance composition as claimed in claim 8 is characterized in that described insulation adhesive thing comprises epoxy resin or silica gel.
13, variable impedance composition as claimed in claim 8 is characterized in that comprising in addition semiconductor powder.
14, variable impedance composition as claimed in claim 13, the content that it is characterized in that described semiconductor powder between described variable impedance composition weight 0.001% to 10% between.
15, variable impedance composition as claimed in claim 13 is characterized in that described semiconductor powder comprises zinc oxide or carborundum.
16, variable impedance composition as claimed in claim 8 is characterized in that comprising in addition insulating powder, its content between described variable impedance composition weight 0.001% to 10% between.
17, variable impedance composition as claimed in claim 16 is characterized in that described insulating powder comprises metal oxide.
18, variable impedance composition as claimed in claim 16 is characterized in that described metal oxide is aluminium oxide or zirconia.
19, variable impedance composition as claimed in claim 16 is characterized in that comprising in addition semiconductor powder.
20, variable impedance composition as claimed in claim 19, the content that it is characterized in that described semiconductor powder between described variable impedance composition weight 0.001% to 10% between.
21, variable impedance composition as claimed in claim 19 is characterized in that described semiconductor powder comprises zinc oxide or carborundum.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/043,550 | 2008-03-06 | ||
| US12/043,550 US20090224213A1 (en) | 2008-03-06 | 2008-03-06 | Variable impedance composition |
| US12/139,860 US7708912B2 (en) | 2008-06-16 | 2008-06-16 | Variable impedance composition |
| US12/139,860 | 2008-06-16 |
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| CN101527195A true CN101527195A (en) | 2009-09-09 |
| CN101527195B CN101527195B (en) | 2012-07-18 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102298999A (en) * | 2010-06-28 | 2011-12-28 | 国巨股份有限公司 | OVP (over voltage protection) element and manufacturing method thereof |
| CN103077790A (en) * | 2012-09-20 | 2013-05-01 | 立昌先进科技股份有限公司 | Low-capacity laminated chip varistor and overvoltage protective layer used by the same |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6209966B2 (en) * | 2013-12-26 | 2017-10-11 | Tdk株式会社 | ESD protection parts |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5068634A (en) * | 1988-01-11 | 1991-11-26 | Electromer Corporation | Overvoltage protection device and material |
| US5507439A (en) * | 1994-11-10 | 1996-04-16 | Kerr-Mcgee Chemical Corporation | Method for milling a powder |
| US6013358A (en) * | 1997-11-18 | 2000-01-11 | Cooper Industries, Inc. | Transient voltage protection device with ceramic substrate |
| US6251513B1 (en) * | 1997-11-08 | 2001-06-26 | Littlefuse, Inc. | Polymer composites for overvoltage protection |
| TW511103B (en) * | 1998-01-16 | 2002-11-21 | Littelfuse Inc | Polymer composite materials for electrostatic discharge protection |
| US6645393B2 (en) * | 2001-03-19 | 2003-11-11 | Inpaq Technology Co., Ltd. | Material compositions for transient voltage suppressors |
| US6498715B2 (en) * | 2001-05-15 | 2002-12-24 | Inpaq Technology Co., Ltd. | Stack up type low capacitance overvoltage protective device |
| US7132922B2 (en) * | 2002-04-08 | 2006-11-07 | Littelfuse, Inc. | Direct application voltage variable material, components thereof and devices employing same |
| EP1548758A4 (en) * | 2003-03-25 | 2007-07-11 | Tdk Corp | Organic positive temperature coefficient thermistor |
| TW200617087A (en) * | 2004-11-19 | 2006-06-01 | Polytronics Technology Corp | Conductive composition exhibiting ptc behavior and over-current protection device using the same |
| CN1996513B (en) * | 2006-12-27 | 2011-03-30 | 上海长园维安电子线路保护股份有限公司 | A thermal concretion PTC thermal resistor and its making method |
-
2008
- 2008-03-06 US US12/043,550 patent/US20090224213A1/en not_active Abandoned
- 2008-10-14 CN CN2008101702237A patent/CN101527195B/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102298999A (en) * | 2010-06-28 | 2011-12-28 | 国巨股份有限公司 | OVP (over voltage protection) element and manufacturing method thereof |
| CN102298999B (en) * | 2010-06-28 | 2013-03-06 | 国巨股份有限公司 | OVP (over voltage protection) element and manufacturing method thereof |
| CN103077790A (en) * | 2012-09-20 | 2013-05-01 | 立昌先进科技股份有限公司 | Low-capacity laminated chip varistor and overvoltage protective layer used by the same |
| CN103077790B (en) * | 2012-09-20 | 2015-09-02 | 立昌先进科技股份有限公司 | A kind of low electric capacity lamination cake core rheostat and the over voltage protector used thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101527195B (en) | 2012-07-18 |
| US20090224213A1 (en) | 2009-09-10 |
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