CN101525508A - Application of Eupatorium adenophorum extract as anti-fouling paint antifoulant - Google Patents
Application of Eupatorium adenophorum extract as anti-fouling paint antifoulant Download PDFInfo
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- CN101525508A CN101525508A CN200810008066A CN200810008066A CN101525508A CN 101525508 A CN101525508 A CN 101525508A CN 200810008066 A CN200810008066 A CN 200810008066A CN 200810008066 A CN200810008066 A CN 200810008066A CN 101525508 A CN101525508 A CN 101525508A
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- fouling paint
- hemp eupatorium
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Abstract
The invention provides application of a Eupatorium adenophorum extract as an anti-fouling paint antifoulant. The method takes a 10 to 100 percent aqueous solution of methanol, ethanol, ethyl acetate, ligroine, and chloroform as an extracting solvent to extract a Eupatorium adenophorum active ingredient which is added into anti-fouling paint and is applied as an antifoulant.
Description
Technical field
The present invention adopts 10%-100% methyl alcohol, ethanol, ethyl acetate, sherwood oil and chloroform water solution to go out the Hemp Eupatorium activeconstituents as extracting solvent extraction, uses as anti-fouling paint antifoulant by processing the back.
Background technology
Hemp Eupatorium (Eupatorium adenophorum Spreng) is a composite family Eupatorium per nnial herb, originate in Mexico, import the Yunnan Province of China south into from Burma and Vietnam before and after the 1950's, because of its growth and fecundity extremely strong, in Yunnan Province and peripheral many areas spread.Because it is herded sideline production to agricultural and has brought serious harm the destruction of ecotope.
In view of Hemp Eupatorium has become one of the most serious exotic invasive species of China's harm, various places are when the Hemp Eupatorium that tightens control spreads measure, and the numerous and confused research that launches its comprehensive utilization is tried hard to change harmful to treasure.Hu Jue etc.
1Studied the production potential that biogas continuously ferments after the Hemp Eupatorium pre-treatment.Yang Yazhou
2On basis to Hemp Eupatorium chemical constitution, fibre shape and surface free energy research, to the processing parameter of Hemp Eupatorium medium density fibre board (MDF) and studies show that of physical and mechanical property and influence factor thereof, the Hemp Eupatorium medium density fibre board (MDF) that experiment condition is made down, through suitably regulating processing condition, all can the be up to state standards requirement of indoor type medium density fibre board (MDF) of some performance index.Tian Guoting etc.
3Utilize Hemp Eupatorium as raw material cultivation the edge of a field mushroom, utilize straw and cotton seed hulls to compare simultaneously for raw material cultivation the edge of a field mushroom, result of study shows, in the culture medium prescription of generation material grog cultivation the edge of a field mushroom, the prescription effect that with the Hemp Eupatorium is main raw material is best, and the straw substratum of biology efficiency ratio contrast on average increases production more than 80%.Sun Qiming
4Studied the applied research of Hemp Eupatorium as wild organic fertilizer.Yang Yonghong etc.
5With the Hemp Eupatorium is raw material, produces Xylitol with the method for microbial fermentation.Ou Yanghua, Wang Houde adopt special microbial fermentation detoxification, mannosans detoxification, inorganic absorption detoxification, herbal medicine to detoxify and health care combines, and Deco method is developed as the plant protein fodder raw material of success with Hemp Eupatorium, and has applied for patent
6And the activeconstituents that we extract Hemp Eupatorium among the present invention is used as anti-fouling paint antifoulant.
Antifouling varnish is a kind of special coating that is coated on hull bottom and ocean underwater facility, and general coating is contained on the bottom anticorrosive paint, is in outermost layer.Its main effect is that the modes such as the oozing out of material, diffusion or hydrolysis of poisoning by paint film progressively discharge the poison material, reaches to prevent that marine attaching organism is attached to the purpose of hull bottom or ocean underwater facility.
More than 2000 kind of fouling organism arranged in the ocean, and majority is lived in offshore sea waters such as seashore and bay.The larva of fouling organism and spore can floatingly move about, develop into just to adhere to behind the certain phase and settle down, stained Offshore Units, for example hull, buoy, bridge pier, harbour, net cage and netting gear etc., its main harm comprises the resistance that increases boats and ships, block pipeline, quicken metallic corrosion, make instrument and the rotation machine is malfunctioning, to the influence of acoustic instrument and to the influence of water industry etc., be difficult to estimation by the loss that biodeterioration caused.The marine anti-pollution technology is to be used to prevent that marine organisms are stained to adhering to of Offshore Units, be started in the research of ship pollution prevention coating, and antifouling with poison material release type be the major technique approach, by stain control agents such as releasable copper, tin, mercury, lead in the coating, forming around material has the concentration of poisons layer of toxic action to marine plant spore and marine animal larva, thereby reaches anti-fouling effect.Yet, this type of antifouling paint in use, part toxic agent (as organotin, DDT) can cause the seawater water pollution, causes biomutation, jeopardizes marine food chain, and marine ecology balance and human health are had potential harm.
Consider that from environmental angle people wish to use nuisanceless anti-soil technology, realize preventing and kill off marine fouling organism.So we are developed as anti-fouling paint antifoulant with Eupatorium adenophorum extract.
Reference
1. recklessly feel, open unmatched, Yin Fang, Liu Shiqing, the official understands woods, Hemp Eupatorium is continuously fermented and produces biogas experimental study, agricultural and technology, 2006,26 (4) 33-36
2. poplar Asia, Hemp Eupatorium is made the research of medium density fibre board (MDF), Chinese wood-based plate, 2006,10:13-16
3. Tian Guoting, Xu Xuezhong, Yang Qiongfen, Xu Yuran utilizes the research of Hemp Eupatorium cultivation the edge of a field mushroom, edible fungi of china, 23 (4): 13-15
4. Sun Qi inscription, the utilization of wild organic fertilizer resource Hemp Eupatorium, agricultural science and technology communication, 2002,4:28-29
5. Yang Yong is red, Li Guoquan, and the Hemp Eupatorium microbial fermentation is produced the technology of Xylitol, plant resources and environment, 1999,8 (1): 61-62
6. Ou Yanghua, Wang Houde, the preparation method of purple eupatoria feed, application (patent) number: CN02113759.5, open (bulletin) number: CN1383731,2002-05-18
Summary of the invention
The objective of the invention is to develop new anti-fouling paint antifoulant, this method is starting raw material with the Hemp Eupatorium, adopt 10%-100% methyl alcohol, ethanol, ethyl acetate, sherwood oil and chloroform water solution to go out the Hemp Eupatorium activeconstituents, use as anti-fouling paint antifoulant by processing the back as extracting solvent extraction.The Hemp Eupatorium poisonous weeds can be used by oneself, change harmful to treasure, and what opened is eco-friendly stain control agent, can not pollute environment.
The objective of the invention is to realize by the following technical solutions:
Step of the present invention is as follows:
1) bright cauline leaf of Hemp Eupatorium and dry cauline leaf are ground into powder;
2) with the Hemp Eupatorium powder that obtains in the step 1), add methyl alcohol or ethanol or ethyl acetate or sherwood oil or the chloroform water solution of 10%-100%, behind the immersion 48h, solids removed by filtration behind the employing vacuum distillation recovered solvent, obtains sticky shape dark solution;
3) adopt vacuum freezing drying device with 2) in the solution drying that obtains;
4) with 3) in the dry thing that obtains add to according to a certain percentage in the antifouling varnish and use as stain control agent.
Annex: Eupatorium adenophorum extract is as the anti-fouling paint antifoulant determination of activity
1. coating (antifouling varnish) is filled a prescription
1), superpolymer: be combined into by physics and chemistry institute of Chinese Academy of Sciences coating, be the polymer of methacrylic acid and butyl methacrylate copolymerization generation, add-on (w/w) is 20% of total coating.
2), mineral dye ZnO 5%
3), inorganic Fe2O3 pigment does not add
4), solvent: burnt No. 200 solvents of dimethylbenzene and matchmaker, about 20-25%
5), permeate agent SiO2 a small amount of (2-4%)
6), permeate agent (1-2%)
7), tensio-active agent (0.5-1.0%)
8), biopolymer rosin (0.5-1.0%)
9), purple stem boneset extract 10% (w/w)
Said components is ground in ball mill, till graininess and other rerum naturas all satisfy GB and require, generally will grind 25-30 hour (room temperature)
2. board experiment
1) coating (each component of coating) is taken to the Xiamen boats and ships and detect authorized by state unit (725) check
2) coating is coated onto on the link plate (25 * 15cm2)), after the drying, goes into to do under the environment of 1.5 meters in seawater antifouling test (whether have seashells animal, barnacle, Ascidian, oyster, mussel, lime worm etc. adhere to onboard, adhered area>8% lost efficacy if detecting).
3. test-results
Go into seawater after one month link plate intact; The link plate reverse side is intact after two months.
From experimental result as can be seen, do not adding (20%) under the Red copper oxide condition, eupatorium adenophorum extracting solution has good repellent action to marine organisms.
Claims (7)
1. the Hemp Eupatorium methyl alcohol, ethanol, ethyl acetate, sherwood oil and the chloroform extract that provide are as anti-fouling paint antifoulant, and step is as follows:
1) bright cauline leaf of Hemp Eupatorium and dry cauline leaf are ground into powder;
2) with the Hemp Eupatorium powder that obtains in the step 1), the adding volume ratio is respectively methyl alcohol, ethanol, ethyl acetate, sherwood oil and the chloroform water solution of 10%-100%, behind the immersion 48h, and solids removed by filtration, adopt vacuum distillation recovered solvent, obtain sticky shape dark solution;
3) adopt vacuum freezing drying device with 2) in the solution drying that obtains;
4) with 3) in the dry substance that obtains add in the antifouling varnish by-certainty ratio and use as stain control agent.
2, purple stem boneset extract as claimed in claim 1 is characterized in that as anti-fouling paint antifoulant: extract active ingredient in the Hemp Eupatorium described step 2), adopt the methanol aqueous solution of 10%-100% to cook extraction agent.
3, purple stem boneset extract as claimed in claim 1 is characterized in that as anti-fouling paint antifoulant: extract active ingredient in the Hemp Eupatorium described step 2), adopt the aqueous ethanolic solution of 10%-100% to cook extraction agent.
4, purple stem boneset extract as claimed in claim 1 is as anti-fouling paint antifoulant: extract active ingredient in the Hemp Eupatorium described step 2), adopt the ethyl acetate aqueous solution of 10%-100% to cook extraction agent.
5, purple stem boneset extract as claimed in claim 1 is characterized in that as anti-fouling paint antifoulant: extract active ingredient in the Hemp Eupatorium described step 2), adopt the sherwood oil aqueous solution of 10%-100% to cook extraction agent.
6, purple stem boneset extract as claimed in claim 1 is characterized in that as anti-fouling paint antifoulant: extract active ingredient in the Hemp Eupatorium described step 2), adopt the chloroform water solution of 10%-100% to cook extraction agent.
7, purple stem boneset extract as claimed in claim 1 is characterized in that as anti-fouling paint antifoulant: the Eupatorium adenophorum extract that handle extracts with all kinds of SOLVENTS in the described step 4) adds in the antifouling varnish by a certain percentage to be used as stain control agent.
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CN 200810008066 CN101525508B (en) | 2008-03-06 | 2008-03-06 | Application of Eupatorium adenophorum extract as anti-fouling paint antifoulant |
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CN 200810008066 CN101525508B (en) | 2008-03-06 | 2008-03-06 | Application of Eupatorium adenophorum extract as anti-fouling paint antifoulant |
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CN101525508A true CN101525508A (en) | 2009-09-09 |
CN101525508B CN101525508B (en) | 2013-07-24 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103254761A (en) * | 2013-05-30 | 2013-08-21 | 江苏亚宝绝缘材料股份有限公司 | Anti-aging corrosion-proof polyimide coating material |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1788570A (en) * | 2005-12-27 | 2006-06-21 | 云南农业大学 | Purple stem boneset extract for prevention and treatment of plant disease |
KR20060074046A (en) * | 2004-12-27 | 2006-07-03 | 주식회사 코오롱 | Anti-fouling paint composition |
CN1817983A (en) * | 2006-03-08 | 2006-08-16 | 武汉百信生物科技有限公司 | Environmental-protective maceration extract for preventing from adhersion of marine living things |
CN1948256A (en) * | 2005-10-14 | 2007-04-18 | 中国农业科学院植物保护研究所 | New compound possessing insecticidal bactericidal activity |
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- 2008-03-06 CN CN 200810008066 patent/CN101525508B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20060074046A (en) * | 2004-12-27 | 2006-07-03 | 주식회사 코오롱 | Anti-fouling paint composition |
CN1948256A (en) * | 2005-10-14 | 2007-04-18 | 中国农业科学院植物保护研究所 | New compound possessing insecticidal bactericidal activity |
CN1788570A (en) * | 2005-12-27 | 2006-06-21 | 云南农业大学 | Purple stem boneset extract for prevention and treatment of plant disease |
CN1817983A (en) * | 2006-03-08 | 2006-08-16 | 武汉百信生物科技有限公司 | Environmental-protective maceration extract for preventing from adhersion of marine living things |
Non-Patent Citations (1)
Title |
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童忠良等: "《功能涂料及其应用》", 30 September 2007, 中国纺织出版社 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103254761A (en) * | 2013-05-30 | 2013-08-21 | 江苏亚宝绝缘材料股份有限公司 | Anti-aging corrosion-proof polyimide coating material |
CN103254761B (en) * | 2013-05-30 | 2015-12-09 | 江苏亚宝绝缘材料股份有限公司 | A kind of ageing-resistant rot-resistant polyimide paint |
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