CN101522070A

CN101522070A - Hair treatment application system comprising an absorbent substrate

Info

Publication number: CN101522070A
Application number: CNA2007800378117A
Authority: CN
Inventors: 小罗伯特·W·格伦; 保罗·J·史密斯
Original assignee: Procter and Gamble Ltd
Current assignee: Procter and Gamble Ltd; Procter and Gamble Co
Priority date: 2006-10-09
Filing date: 2007-10-09
Publication date: 2009-09-02
Also published as: CN101522069A; CN101522069B

Abstract

The present invention describes a hair treatment application system, comprising at least one or more hair treatment compositions (15) having a viscosity of from 3,000 cPs to 150,000 cPs and a hair treatment application device (1) comprising a first plate (10) and a second plate (20) positionable in a juxtaposed relationship when said hair treatment application device (1) is in a closed state. The hair treatment application device (1) is characterized by having a first zone comprising at least one absorbent substrate (40) on the internal surface (101) of said at least said first plates (10) anda second zone (50) on said internal surface (101) which is free of said absorbent substrate (40). Said at least one absorbent substrate (40) has a median pore radius of from 300 microns to 3,000 micr on. The present invention describes also methods of treating the hair with said hair treatment application system (10) and kit comprising said hair treatment application system.

Description

The hair treatment application system that comprises absorption base

Invention field

The present invention relates to comprise the hair treatment application system of cosmetic composition and application device, described application device for example can be administered to the cosmetic composition orientation on the multiple matrix such as hair, skin and nail easily, accurately, softly and cleanly.Application device of the present invention especially is intended to be used for Hiar treatment compositions.

Background of invention

Using Hiar treatment compositions to indivedual topknots can realize using different outward appearances with whole head.Be used to provide the Hiar treatment compositions of this type of hair strand to comprise choosing and dye composition, colouring compositions and Hairstyling composition.Specifically, dyeing and Hairstyling composition can be used for adapting to the variation of popular pattern, and can be used for sheltering the gray hair that occurs the earliest.

Be understood that to select topknot and it dyed light for than shallow at least one tone of all the other hairs although term " is chosen and dyed ", the desired effect of consumer is very different: from trickle masstone effect and natural change color to more eye-catching and bold effect.In order to realize the customized of FINAL APPEARANCE, the consumer can select by adopting family expenses to choose to dye the cover box to choose to dye or can visiting professional hairstylist.

The professional person has many devices and technology to let alone domination, does some training very often and many years of experience in addition, makes and can realize the multiple result that the consumer expects.Yet because the precision of process and long-time property, consumer wants regularly spends the plenty of time in hair salon and finishes this process.Because the professional person will spend the plenty of time and energy could be realized the final effect of expectation, so also requires professional hairstylist that higher expense is collected in its service that provides.

Family expenses choose that to dye produce market huge, and the consumer can accept economically, and it can provide multiple product to beautify to send almost any desired hair.

Yet, handle relevant many shortcomings and some effort that address these problems are known in the art with under the situation that does not have the professional to help, using the family expenses hair to choose to dye.

Different materials and the goods of using formed of sponge that can the delivery of cosmetic composition by multilayer be known usually.This type of combination of using goods and device or instrument also is known.Example is the application device that comprises the cylindrical reservoir that is used to comprise Hiar treatment compositions, has embedded the transverse opening of elastic deformable material above wherein said reservoir has.The composition of topknot in passing that opening and being included in reservoir is communicated with.Another example is the application device that comprises application device part and buckling clamping part.Application device partly comprises the resiliency compressible container that wherein stores Hiar treatment compositions.The user places topknot between a finger and the container.When exerting pressure on compressible container, the composition that comprises within it promptly is released on the topknot.Other example comprises the hairdressing application device with two articulated slabs, and each plate is equipped with parcel or the impregnated thin plate brush that the supatex fabric covering of Hiar treatment compositions is arranged that comprises Hiar treatment compositions.Comprise that two application devices that are coated with the interlocking articulated slab of absorbing material also are known, and as the substitute of the used paper tinsel of hairstylist in the professional hair salon.

Generally believe that the oneself uses and chooses that to dye composition be difficult in essence, and if use unsuitable application device to carry out then can be more difficult.The application device that the oneself uses Hiar treatment compositions can be helped and several technological challenges need be considered and solve to obtain desired final effect with clean and clean and tidy mode/method.

At first, it is very complicated to use Hiar treatment compositions behind at head, because need the user to select topknot by the image in the mirror is judged.Topknot is selected and is used complicatedly more, and user's arm is forced to keep the overhead time just long more, and this will cause discomfort and influence general effect.In addition, user custom will install Rotate 180 and ° be dyed to be implemented in choosing of head behind.Therefore, even successfully comprise the application device that is used for using Hiar treatment compositions and also possibly can't finish the work effectively, and can cause adverse effect using head oneself behind in the front or the side of head.

How preventing that composition from spilling and oozing out this technological challenge from application device should be only not consider according to the orientation of application device during using.Be used for application device that the oneself of Hiar treatment compositions uses and should be designed to prevent that Hiar treatment compositions from spilling and ooze out from application device during using experience whole, because some compositions dyes composition and has the character of making us unhappy as choosing.If drop onto on consumer's surface, room, skin and the clothes, may cause bleaching.

Be not only not wish for the purpose of cleaning to spill and ooze out.For the final effect of realizing expecting, be necessary accurately to use to choose to dye composition in desired location.Even choose at a small amount of hair of application device edge and to dye composition and still may provide the result who does not expect, because it may easily transfer on the unselected topknot from selected topknot, especially at root of hair line place.Therefore, may produce the overall FINAL APPEARANCE of unexpected and non-expectation.

Also should consider toxicology and security reason, dye composition and be delivered to root of hair line place that it also may be transferred on the scalp so, thereby causes unnecessary stimulation because if unexpectedly hair is chosen.

At last, choose the Hiar treatment compositions that dyes composition such as hair and comprise needs generation active oxygen to bleach melanic component.Because hair is chosen the reactive chemical property of dying composition, hair is chosen the major applications of dying composition and is being produced slight and of short duration damage aspect the hair health.Application device such as top cover and suspension hook may push hair shaft, and if improper use, even the topknot that may root out.Therefore, general but especially be designed for and choose those hair treatment applicators that dye and must not can damage hair, and must be soft to hair when the user uses Hiar treatment compositions.

Therefore, still an open question to be hair treatment applicator dye that composition spills and use, take, grasping, satisfy the structure that family chooses the needs that dye the consumer aspect gripping and relay time with a hand easily avoiding choosing from application device.In addition, application device should be easy to guiding and pass hair, especially at root of hair line place, and be easy to repeatedly use, and irrelevant with hair length.Application device should have flexibility and dye and new design to be used to producing multiple choosing, and is used for shortening time and cost, and is used for simplifying to choose dying operation.Application device should can not damage hair yet when using Hiar treatment compositions.At last, application device should be light, cheap, disposable undoubtedly and maybe can recycle, and is easy to produce.

Have now found that, hair treatment application system (such as hereinafter definition) can be at home and significantly improve to choose in professional hair salon and dye the result.

Summary of the invention

According to the present invention, a kind of hair treatment application system is provided, described application system comprises at least aly or multiple having 3,000cPs to 150, Hiar treatment compositions of the viscosity of 000cPs (15) and hair treatment applicator (1), described hair treatment applicator (1) is included in its first plate (10) and second plate (20) with the juxtaposition relationship location when being in closure state, wherein said first plate (10) and second plate (20) are bound up via connector (30), and wherein said first plate (10) and second plate (20) respectively have inner surface (101; 201) and outer surface (102; 202) surface, and described first plate (10) and second plate (20) respectively have periphery edge (103; 203), it is characterized in that described at least first plate (10) has first area and second area (50) on inner surface (101), wherein said first area comprises at least a absorption base (40), wherein said at least a absorption base (40) have about 300 microns to about 3,000 micron intermediate value pore radius, and wherein said second area (50) does not contain described absorption base (40).

The invention still further relates to the method and the cover box that comprises described hair treatment application system of handling hair with described hair treatment application system.

Summary of drawings

Fig. 1 is the perspective view of an embodiment of hair treatment applicator of the present invention (1).Hair treatment applicator (1) comprises first plate (10) and second plate (20) that is bound up through connector (30).Each plate (10; 20) comprise inner surface (101; 201) and outer surface (102; 202) and periphery edge (103; 203).Absorption base (40) is connected to the first area of the inner surface (101) of first plate (10).The second area that does not contain absorption base is filled up by Hiar treatment compositions (15).In this embodiment, first plate (10) comprises concave recess on described first plate (10).Second area is sightless.

Fig. 2 is the perspective view of an embodiment of hair treatment applicator of the present invention (1).Hair treatment applicator (1) comprises first plate (10) and second plate (20) that is bound up through hinge (30).Each plate (10; 20) comprise inner surface (101; 201) and outer surface (102; 202) and periphery edge (103; 203).The belt of two kinds of different absorption bases (40) is connected to the first area of the inner surface (101) of first plate (10).The absorption base that extends internally most is higher than the absorption base of locating to extend at periphery edge (103).The second area that does not contain absorption base is filled up by Hiar treatment compositions (15).Second area is sightless.

Fig. 3 is the perspective view of another embodiment of hair treatment applicator of the present invention (1).First plate (10) of hair treatment applicator (1) is connected to second plate (20) through hinge (30).First area on first plate comprises absorption base (40) band that extends along the periphery edge of first plate (103).The second area that does not contain absorption base is filled up by Hiar treatment compositions (15).The side of absorption base (40) is covered by impervious barrier film (105) part.Second area is sightless.

Fig. 4 is the perspective view of a kind of hair treatment applicator of the present invention (1), and wherein first plate (10) and second plate (20) link together through hinge (30).Each plate (10; 20) has inner surface (101; 201) and outer surface (102; 202).The first area that comprises absorption base (40) is centrally placed on the inner surface (101) of described first plate (10) basically.Hiar treatment compositions (15) is loaded on the described absorption base (40).Second area (50) limits the scope of described absorption base (40).

Fig. 5 is the perspective view of one embodiment of the invention, and it illustrates a kind of comprising through first plate (10) of hinge (30) connection and the hair treatment applicator (1) of second plate (20).Each plate (10; 20) all has inner surface (101; 201) and outer surface (102; 202).First plate (10) comprises the first area that is attached with rectangle absorption base (40) band.Hiar treatment compositions (15) is loaded in the described absorption base (40).Second plate (20) also comprises the absorption base (40) in the specification scope of the present invention.Second area (50) limits the scope of described rectangle absorption base (40) band.

Fig. 6 is the perspective view of first plate (10) of another embodiment of the invention.The first area of described first plate (10) is attached with a plurality of corrugated absorption bases (40).Hiar treatment compositions (15) is loaded in the described absorption base (40).Second area (50) limits the scope of described a plurality of waveform absorption bases (40).

Detailed Description Of The Invention

The invention is characterized in the cooperative effect that when parts as herein described combine, is had.How in these parts each is relative to each other and how they facilitate the solution of above-mentioned technical problem to become apparent hereinafter jointly.

About 3,000cPs is to about 150, the specific selection of the Hiar treatment compositions viscosity of 000cPs; Have about 300 microns specific absorption matrix to about 3,000 microns intermediate value pore radius; And the element of application device all is critical so that send the technique effect of expectation.

Hair treatment applicator (1) comprises first plate (10) and second plate (20) that is bound up via connector (30), to allow the user can be through using arbitrary the hand hair treatment applicator (1) that accurately and easily leads, comprise the part that is difficult to touch, for example head is behind or near the root of hair of scalp.Absorption base (40) provides the excess deposition that prevents good device that Hiar treatment compositions spills from application device (1) and help to reduce Hiar treatment compositions on being applied to hair the time for application device (1).The special porous absorption base (40) of selecting is to realize soft and to use Hiar treatment compositions (15) glossily.The existence that does not contain the zone of absorption base (40) is convenient to make first and second plates (10; 20) become juxtaposition relationship when on hair, using Hiar treatment compositions (15),, can manage it better in case Hiar treatment compositions (15) is discharged from absorption base (40).

The combination of all these parts allow with evenly, soft, cleaning and clean mode send Hiar treatment compositions (15) to selected topknot.

The viscosity of Hiar treatment compositions also is high-importance.If viscosity is too high, just is not easy to be inhaled in the absorption base, and most possibly sticks in the zone that does not contain absorption base.In addition, can stop the mutual mixing of two or more different Hiar treatment compositions, this is desirable for the reactive hair treatment application such as oxidising dyeing and bleaching (if desired, comprise choosing dye).

On the other hand,, choose and dye experience and may become dirty and messy,, thereby cause worthless drippage and dirty and messy because Hiar treatment compositions can not be at absorption base and do not contain fully reservation in the zone of absorption base if the viscosity of Hiar treatment compositions is too low.

As hereinafter proving by the technology experiment data, the minimal viscosity of the Hiar treatment compositions of measuring according to method of testing hereinafter described is at least about 3,000cPs.With multiple prepared at concentrations so that comprehensive range of viscosities to be provided

The solution of 956 (deriving from Noveon) has on a large scale the absorption base of intermediate value pore radius and tests with polytype.By in deionized water, adding

956 use overhead type agitator mixed solution up to all simultaneously

956 dissolvings prepare 956 solution.In solution, add more

956 up to reaching required viscosity.With each Solution is loaded in the selected absorption base.Compress absorption base then as described in the method for testing hereinafter.Repeat each experiment three times, and use Student t check (∝=0.05) evaluation result, and for each absorption base different mean value on the letter representation statistical significances different in the square brackets.The average percent of the loading solution that oozes from absorption base when compression and corresponding viscosity are shown in table 1.

Table 1: viscosity changes the influence to the intermediate value pore radius of absorption base.

These results are clearly shown that, ooze from absorption base when viscosity increases The percentage of 956 solution significantly descends.Have surprisingly been found that, be independent of selected absorption base, have at least about 3 when absorption base loads, the viscosity of 000cPs

During 956 solution, there is not dropping basically.

In order further to support above-mentioned experimental data, the consumer tests that have 12 panelists to participate in have also been carried out about Hiar treatment compositions of the present invention.Give absorption base of each panelist (Libeltex 01-766DI-8, intermediate value pore radius are 550 microns) to test and to estimate its dirty and messy degree and droppings.As hereinafter as described in the Test Methods section, absorption base is installed on the side of plate.Two plates that so prepare are joined together to form clip with hinge, and wherein absorption base faces with each other.With having 1, the viscosity of 000cPs

956 solution load an absorption base of each clip.With having 2,500cPs and 5, the viscosity of 000cPs

956 solution are prepared other intermediate plate.

With LSD statistical test (∝=0.05) evaluation result of Fisher, the result shows: for the problem that is proposed, have 1,000 and 2, two kinds of the viscosity fluid of 500cPs

The average rank of 956 solution is identical on the statistical significance, and has 5, and the solution of 000cPs is significantly different and is classified to more not dirty and messy.These results that are shown in table 2 support following technology experiment data: avoid dirty and messy required viscosity between 2,500cPs to 5 is in the scope between the 000cPs.Represent the mean value of adding up different with letters different in the square brackets.

Table 2: dirty and messy degree is carried out consumer tests.

Problem	Considering the sample that you had just used, how will you evaluate its dirty and messy degree?
Problem		Classification	Scale: the somewhat dirty and messy 8=of the not dirty and messy at all 4=of 0-8 0=is very dirty and messy
Viscosity [cPs]	The mean value of all grades	Classification
Viscosity [cPs]	The mean value of all grades	1000	3.83[B]
2500	3.92[B]	1000	3.83[B]
2500	3.92[B]	5000	2.00[A]

The inventor also surprisingly finds, needs the very absorption base of specific type.Specifically, absorption base of the present invention being chosen to make they have can hold one or more and have at least about 3 the intermediate value pore radius of the Hiar treatment compositions of the minimal viscosity of 000cPs.The porous of absorption base is accurately described by the intermediate value pore radius.Such as hereinafter definition, for the sample routine with the intermediate value pore radius that is less than or equal to 1000 microns via

Method determines, and determines by optical imagery for the sample routine that has greater than 1000 microns radius.As hereinafter as described in the Test Methods section, the fluid that operating weight is analyzed loads to determine the effect of the intermediate value pore radius of available within the scope of the invention absorption base.On behalf of the consumer, this method may how to load absorption base with Hiar treatment compositions admirably.Selected absorption base is BBA Fiberweb TenotexP101 (75 microns intermediate value pore radiuses); Freudenberg AL 1060 (300 microns); Libeltex01-766 DI-8 (550 microns); PGI FB-215 (700 microns) and Recticel BulprenS28280 (1,400 micron).Apparatus has an appointment 3 respectively, 000cPs, about 5,000cPs and about 10, the viscosity of 000cPs 956 solution load every kind of absorption base.Repeat each experiment three times, and use Student t check (∝=0.05) evaluation result, and for each

956 solution different mean value on the letter representation statistical significances different in the square brackets.Under corresponding viscosity, be loaded in every gram absorption base

The average magnitude of 956 solution (with the gram expression) is shown in Table 3.

Table 3: the minimum intermediate value pore radius of absorption base is for the influence of heap(ed) capacity.

The result shows: by increasing the intermediate value pore radius of absorption base, can be loaded in every kind of absorption base

The amount of 956 solution has also increased.In addition, the result points out, when absorption base has intermediate value pore radius less than 300 microns when (as having under 75 microns the situation of BBA Fiberweb Tenotex P101 of intermediate value pore radius), has 3, the minimal viscosity of 000cPs

956 solution can significantly not loaded.

Therefore, for purpose of the present invention, the intermediate value pore radius of absorption base is at least about 300 microns., have at least about 3 below the minimum intermediate value pore radius at this, the Hiar treatment compositions of the viscosity of 000cPs can not be adapted to use in prospective consumers of the present invention is used.

The maximum intermediate value pore radius of the selected absorption base of this paper is confirmed as that can make, commercially available acquisition and in the maximum radius that is used for still can keeping when prospective consumers of the present invention is used the open celled foam of shape.Maximum intermediate value pore radius open celled foam is provided by Recticel, and has 3,000 microns intermediate value pore radius.Absorption base with the intermediate value pore radius that is higher than 3,000 microns has the trend of the mechanical strength of losing, and does not therefore adopt within the scope of the invention.Therefore, absorption base of the present invention has about 300 microns to about 3,000 microns, and preferred about 400 microns to about 2,500 microns, more preferably from about 450 microns to about 2,000 microns, even 500 microns about 1,800 micron intermediate value pore radiuses extremely more preferably from about.

Hiar treatment compositions has very high viscosity, and the product of present commercially available acquisition have the highest by 600, the viscosity of 000cPs.Within the scope of the invention, still can be loaded on the as above selected absorption base and the peak viscosity that is delivered to the Hiar treatment compositions of hair is 150,000cPs.Two kinds of absorption base: the RecticelPottscorer 410 (2,200 microns) and the Recticel Bulpren S28280 (1,400 micron) of the above determined intermediate value pore radius scope of representative have been selected.Then, with having 100, the Hiar treatment compositions of the viscosity of 000cPs loads this two kinds of absorption bases, subsequently three topknots is contacted so that Hiar treatment compositions is administered on the hair with absorption base.In both cases, absorption base all can be enough to realize choosing the Hiar treatment compositions that dyes for hair provides.These the results are shown in following table 4.

Table 4: viscosity is to the influence of average consumption

Although these results are meant 100, the viscosity number of 000cPs, but the technical staff in Hiar treatment compositions field will readily appreciate that: have the highest approximately 150, the hair treatment of the viscosity of 000cPs is used composition and still can be loaded on the absorption base of the present invention and be administered on the hair.Therefore, it is about 3 that Hiar treatment compositions of the present invention is defined as having, and 000cPs is to about 150,000cPs, more preferably from about 5,000cPs is to about 125,000cPs, more preferably from about 7,000cPs is to about 100,000cPs, even more preferably from about 9,000cPs is to about 85, and the viscosity of 000cPs, wherein said viscosity are measured according to method of testing hereinafter described before in being applied to application device.

Except the intermediate value pore radius, determine that also the absorptive capacity of selecting to limit also can be improved Hiar treatment compositions using on hair.The absorptive capacity of absorption base of the present invention can be described with theoretical maximum suction gram number/gram matrix (g/g).The absorptive capacity of absorption base of the present invention preferably about 10 to about 80g Hiar treatment compositions/g absorption base, preferred about 15 to about 75g/g, more preferably from about 20 to about 70g/g, and even more preferably from about 25 to the scope of about 65g/g absorption base, as according to hereinafter determining in the described calculating of part of detecting.

The inventor determines that also the thickness range of selected absorption base also can help to send to hair the Hiar treatment compositions of aequum.Routine is measured thickness via mircrometer gauge according to method of testing hereinafter described at the lip-deep peak of absorption base place.The thickness of absorption base of the present invention is preferably about 2 to about 20mm, and preferred about 3 to about 17mm, and more preferably from about 4 to about 12mm, and even more preferably from about in 5 to about 10mm the scope.

Equally, the absorption base material of selecting to have special basic weight also can strengthen absorptive capacity.Preferably, also have about 20 to about 300g/m according to the absorption base of the present invention of method of testing hereinafter described ², preferred about 60 to about 250g/m ², more preferably from about 100 to about 200g/m ²Basic weight.

Not bound by theory, the inventor believes that the combination of selected intermediate value pore radius and thickness can influence the permeability for liquids of absorption base.Permeability for liquids is the measurement that material is transmitted fluid capacity.

For the present invention, the term hair had both referred to the life entity hair, and promptly on one's body life entity, referring to does not have the life hair yet, promptly in the aggregation of wig, artificial brow or other no life cutin fiber.The hair of mammal (preferred people) is expected.Yet wool, fur and other cutin fiber can be suitable for using together with hair treatment application system of the present invention (10).

For the present invention, term " topknot " (hair strand) is meant at least two cutin fibers, especially hair, people's hair specifically, and should be interpreted as topknot (hair bundle).

As used herein, term administering " when relating to Hiar treatment compositions, comprise coating, loading, absorption, adsorb and adhere to.

Particularly point out and claimed claims of the present invention clearly though after specification, provide, it is believed that by following description and can understand the present invention better.

1. plate

Hair treatment applicator of the present invention (1) comprises first plate (10) and second plate (20); Two plates (10; 20) all has the ergonomics size, arbitrary the hand of therefore can easily fitting.The shape of plate can change.Can use rectangle, square, circle, ellipse or rectangle, because they are convenient to make.But also can use other shape, especially easily those shapes of being discerned by the consumer.As shown in Figure 1, each plate (10; 20) comprise inner surface (101; 201) and outer surface (102; 202).At least described plate (10; 20); One of inner surface (101; 201) have first area that comprises absorption base (40) and the second area that does not contain described absorption base (40), as mentioned below.

Each plate (10; 20) inner surface (101; 201) and/or outer surface (102; 202) can be flat or crooked independently.Preferably, outer surface (102; 202) be crooked.Each plate or at least their part can comprise one or more v-depressions, one or more U-shaped groove or their combination.Described groove can be separately located in one or two plates (10; 20) surfaces externally and internally (101; 201; 102; 202) one of or on two.

Each plate can have identical or different size and dimension.Preferably, for ease of making, first plate be shaped as second plate (10; The mirror image of shape 20).

Described plate (10; 20) each inner surface (101; 201) can have about 2cm ²To about 70cm ², preferably about 3cm ²To about 50cm ², 4cm more preferably from about ²To about 30cm ²Area.

In certain embodiments, the part of described at least first plate (10) and/or second plate (20) can be included in the depression that forms in described first plate (10), the depression of preferred concave surface.In some other embodiment, the part of described at least first plate (10) and/or second plate (20) can form cavity, the cavity of preferred concave surface.The combination of cavity, groove and depression also can be present in the same hair treatment applicator (1).

Described first and/or second plate (10; 20) inner surface (101) also can comprise one or more and described inner surface (101; 201) district that as seen maybe can touch difference is arranged.Described one or more district needn't be corresponding to any zone, and with described inner surface (101; 201) directly contact.Describedly as seen maybe can touch the difference that difference comprises color or tone, the difference of pattern, mark or embossing.

Each plate (10; 20) can be independently by any known materials or combination of materials manufacturing that can the support hair treatment compositions.Suitable material is the fluoropolymer resin such as polyolefin (for example polypropylene, polyethylene or PETG).Spendable other material comprises polyvinyl chloride, polyamide, acetyl base class, acronitrile-butadiene-styrene, acrylic compounds, acrylonitrile styrene-acrylate, ethylene-vinyl alcohol, Merlon, polystyrene, siloxanes or thermoplastic elastomer (TPE), TPV or copolymer (suitably time); Pliable and tough easily curved matrix is as cardboard, based on the multiple lamination or the combination of material as described in the matrix of metal and aluminium foil, film matrix or the multilayer.

Make plate (10; 20) method can include but not limited to injection molding, altogether assembling in injection molding, over-molded, the mould, die forming, blowing, blister-type shell heat or vacuum forming and be laminated to level or vertical plane in the carrier plastics or sheet material on.

2. connector

The selection of the connector (30) that described first plate (10) and second plate (20) are bound up has improved the control feel of user to hair treatment applicator (1), and make the user accurately and easily to guide hair treatment applicator (1) through using arbitrary hand, and also make it possible to part near trouble, as head behind or near the root of hair of scalp.In addition, connector (30) allows the user hair treatment applicator (1) can be moved to another topknot by a topknot, and need not using the position of adjustment first plate (10) on second plate (20), back at every turn.

Plate (10 of the present invention; 20) connector between (30) makes hair treatment applicator (1) be in closure state or open mode.When hair treatment applicator (1) when being in closure state, described first plate (10) is juxtaposition relationship with described second plate (20), and when hair treatment applicator (1) when being in open mode, described first plate (10) is away from described second plate (20).When hair treatment applicator (1) when being in open mode, described first and second plates (10; 20) described inner surface (101; 201) angle between can be between 5 ° and 360 °, preferably between 30 ° and 185 °, and more preferably at least 50 °.Connector (30) between described first plate (10) and second plate (20) preferably has elasticity.In certain embodiments, hair treatment applicator (1) can be in open mode, and can be by the outer surface (102 at described first plate (10) and second plate (20); 202) exert pressure on and make them become juxtaposition relationship together.In certain embodiments, application device (1) can be in closure state, and must exert pressure on connector (30) to separate the inner surface (101 of first plate (10) and second plate (20); 201).In some other embodiment, application device (1) is in closure state, and each plate has buckling clamping part, wherein can place thumb and forefinger to assist separately first and second plates (10,20).Be independent of their original alignment, first plate (10) and second plate (20) are by relying on resilience to rebuild their original alignment around connector (30) rotation.The characteristic of connector (30) can be the inherent characteristic of the material that is used to make connector or can provide by the design of connector itself.Connector (30) should not break or damage to prevent influencing effect after using several times.Connector (30) should not have too big resistance to user institute applied pressure, otherwise user's hand and finger owing to reuse pain.On the other hand, connector (30) should be too not loose yet, otherwise can imperceptible guiding to application device (1).Resilient nature should be effective, otherwise described first and second plates (10; 20) can always keep juxtaposition relationship or separately.Yet resilience should be uncontrollably and is unexpectedly taken place, because otherwise it can cause being included in absorption base (40) material in the described first area or any other material of being included in any other additional areas (50) is torn.Uncontrolled resilience also may injure user's hand and finger, and may shift Hiar treatment compositions (15) from hair treatment applicator (1) inadvertently, thereby causes dirty and messy.The inventor finds that shockingly connector (30) should be at 0.01N/cm ²To 30.0N/cm ², more preferably 0.01N/cm ²To 15.0N/cm ², even more preferably 0.01N/cm ²To 10.0N/cm ²Scope in convenient pressure under work, and connector should have 0.01N/cm ²To 30.0N/cm ², more preferably 0.01N/cm ²To 15.0N/cm ², even more preferably 0.01N/cm ²To 10.0N/cm ²Scope in resilient pressure open.

First plate (10) and second (20) plate are bound up via any appropriate device that satisfies above-mentioned connector (30) needs.In one embodiment, each plate (10; 20) at outer surface (102; 202) comprise adapting device on to hold user's finger, connector is user's a hand.

In a preferred embodiment, described connector (30) is a hinge.Hinge can form in many ways, comprising: " activity " injection molding hinge, altogether inject assembling, sheet spring or any other suitable spring assembly in the hinge, over-molded hinge, mould, strap hinge, by cross cutting, delineation or wrinkle form folding.

In certain embodiments, first plate (10) and second plate (20) all have the auxiliary assembly of the hinge in the design that is attached to them.The auxiliary assembly of hinge is at first and second plates (10; 20) (for example in injection molded process) produces in the manufacture process.Bearing pin is designed to be engaged in two auxiliary assemblies of first plate (10) and the last hinge that produces of second plate (20).Bearing pin is preferably rectangular shape, by the fluoropolymer resin manufacturing such as polyolefin (optimization polypropylene).Bearing pin is assembled to plate (10; 20) in the auxiliary assembly to produce hinge.

In certain embodiments, first plate (10) and second plate (20) all can be by for example polypropylene manufacturings in same injection molding.Can produce the hinges of making by polypropylene equally between first plate (10) and second plate (20).Can utilize polypropylene to provide deflection repeatedly and unabroken hinges.Hinges is closed in knockout course usually.

In certain embodiments, first plate (10) and second plate (20) all can be by for example polypropylene manufacturings in same injection molding, and hinge can or can be used for by thermoplastic elastomer (TPE) or TPV providing assembling or over-molded generation in the common injection, mould of any other material of above-mentioned characteristic for hinge.

3. regional

The first area is a zone of the described inner surface (101) of described at least the first plate (10), it is characterized in that existing at least a absorption base (40).Described at least a absorption base (40) comprises inner surface, outer surface and side, and described inner surface directly contacts with the described inner surface (101) of described first plate (10).Absorption base (40) provides dirty and messy when avoiding using Hiar treatment compositions (15) of good measure for hair treatment applicator (1), prevent spilling or oozing out of Hiar treatment compositions (15), therefore prevent the formation of drop, drop can cause the Hiar treatment compositions (15) of volume to deposit on the hair, particularly in the place near root.This type of drop of Hiar treatment compositions (15) also can pass other topknot and flow out, thereby near the unacceptable and clumsy processing of topknot causing perhaps is exuded to outside the application device (1).In addition, Hiar treatment compositions (15) may arrive scalp, thereby causes skin irritatin.

Second area (50) is the zone that does not contain described absorption base (40).Described second area (50) is a zone on the inner surface (101) of described at least the first plate (10), its preferably contiguous described first area and comprise void space, porous compressible material, porous incompressible material, atresia compressible material, atresia incompressible material, at least one pointed tooth, at least one bristle or their combination.

The existence that does not contain the zone of absorption base (40) makes it possible to make first and second plates (10; 20) become juxtaposition relationship when on hair, using Hiar treatment compositions (15), can manage described Hiar treatment compositions (15).

Compressible and/or the incompressible material of porous can help to prevent that Hiar treatment compositions is from wherein oozing out or spilling when making hair treatment applicator (1) become closure state.In addition, those materials can hold the Hiar treatment compositions (15) of bigger amount, have therefore increased the volume that can be loaded into the Hiar treatment compositions in the hair treatment applicator (1).

Compressible and the incompressible material of atresia can help also to prevent that Hiar treatment compositions (15) from oozing out or spill from hair treatment applicator (1), but those materials can help to stop or seriously reduce Hiar treatment compositions (15) mobile hair treatment applicator (1) in specifically.

Incompressible material (comprising pointed tooth) can help the user to avoid excess compression plate (10; 20), therefore can be used as effective stop mechanism.

Bristle can help to unclamp topknot when pending topknot contacts with hair treatment application system of the present invention.

Also comprise the combination of these materials in the second area (50) within the scope of the invention.

In certain embodiments, at least a absorption base (40) of described first area can be used as periphery edge (103) extension of continuous band along described first plate (10), shown in Fig. 1,2 and 3.In these particular, absorption base (40) can have about 1.00cm to about 80.00cm, and preferably about 3.00cm is about 50.00cm extremely, and the 6.00cm length of about 30.00cm extremely more preferably from about.Absorption base (40) can have constant or variable width.Absorption base (40) can be continuous or discrete; Be meant that continuously absorption base (40) does not form joint or island or its and do not interrupt.Absorption base (40) is preferably continuous.When absorption base (40) consecutive hours, described absorption base (40) has about 0.05cm to about 4.00cm, and preferably about 0.10cm is to about 3.00cm, and more preferably from about 0.50cm is to the width of about 2.50cm.When absorption base (40) is discontinuous, it has about 0.00cm to about 4.00cm, preferred about 0.00cm is to about 3.00cm, the 0.00cm width of about 2.50cm extremely more preferably from about, and wherein said absorption base (40) does not have the width of about 0.00cm in the place of existence at absorption base (40).When absorption base (40) was discontinuous, at least some parts had 0.05cm at least, preferred 0.10cm at least, the more preferably width of 0.50cm at least.

In some preferred embodiments, at least a absorption base (40) extends as the continuous band on the described inner surface (101), from described inner surface (101) upwards and described continuous band in zone that wherein can load Hiar treatment compositions (15) of described inner surface (101) qualification of described first plate (10).Some examples in these embodiments are shown among Fig. 1,2 and 3.The geometry of absorption base (40) can help to point out the correct amount that loads Hiar treatment compositions (15) wherein and/or will be loaded into the Hiar treatment compositions (15) in the described hair treatment applicator (1) to the user.

In certain embodiments, at least a portion in the outside of described absorption base (40) can comprise impervious barrier film (105), as shown in Figure 3.Preferably, the side of described absorption base (40) comprises impervious barrier film (105).The material that is applicable to impervious barrier film comprises polyethylene, polypropylene or PETG, siloxanes or natural and synthetic rubber, thermoplastic elastomer (TPE), TPV or copolymer.Spendable other material comprise polyvinyl chloride, polyamide, acetyl base class, acronitrile-butadiene-styrene, acrylic compounds, acrylonitrile styrene-acrylate, ethylene-vinyl alcohol, Merlon, polystyrene or copolymer or static plant the hair or the sealing non-woven material or the foaming structure of sealing.

(one of them is shown in Fig. 4) in certain embodiments, first area are centrally placed on the inner surface (101) of described first plate (10) basically.Second area (50) does not contain any material, and can limit the whole absorption base (40) of first area.

In some other embodiment, the first area can comprise a plurality of absorption bases (40).They are connected on the inner surface (101) of described first plate (10) as illustrated in Figures 5 and 6.In Fig. 5, rectangle absorption base (40) is positioned on the inner surface (101) of described first plate (10).The shape of absorption base (40) and size and type can change.In some other embodiment, absorption base (40) can have multiple shape, as other shape of star, heart, flower shape, cross or the easy identification of consumer.The shape of a plurality of absorption bases (40) or arrangement can form pattern, as ethnic pattern, east character, as ideographic symbol and similar pattern.Specifically, Fig. 6 illustrates one embodiment of the invention, and wherein a plurality of corrugated absorption bases (40) are connected on the first area of described inner surface (101) of described first plate (10).In Fig. 5 and 6, second area (50) does not contain any material and limits the described a plurality of rectangles or the corrugated absorption base (40) of first area.

In the embodiment shown in Fig. 1,2,3 and 4, second plate (20) is not shared by any optional feature, but within the scope of the invention, the inner surface at described second plate as mentioned below (201) go up to connect porous and/or atresia, compressible and/or incompressible material, pointed tooth or bristle, comb shape structure and other optional feature also be considered to embodiment.Second plate (20) can be the mirror image of described first plate (10).Specifically, Fig. 5 shows an embodiment, wherein two inner surfaces (101; 201) all has the first area that connects the absorption base (40) in the scope of the invention.

4. absorption base and other material

Be used for suitable absorption matrix of the present invention and can be selected from non-woven material, woven material, porous foam and foamed material, porous plastics, pliable and tough frit, twine and their combination, comprise have physics be superimposed, be bonded together continuously (lamination), with the recirculation and the composite of discontinuous pattern or the one or more synusia by the outer peripheral identical or different material that bonds at discrete joint place, precondition is that these structures satisfy functional requirement mentioned above.

Absorption base of the present invention preferably is selected from non-woven material and/or porous foam.

Non-woven material perhaps can be formed on the spot by the fiber production that can be short fiber or continuous filament yarn, and comprises the directed or randomly-oriented fiber of thin slice, fleece or cotton-wool of manufacturing, by the friction and/or the cohesion and/or bond.The method that is used to make non-woven webs comprises three steps: fiber becomes net, precursor web to be shaped and the fiber bonding.Fiber becomes the net step to comprise to form that fibroreticulate fiber spinning becomes net, melts and sprays, carded, air lay, wet-laying be to profiled surface and their combination.The precursor web forming step can prevent to form fibroreticulate fiber and split during adhesion step.Precursor web is shaped and can carries out via pre-adhesion step (for example being the pre-adhesion step of chemistry or engineering properties).Adhesion step can be given finished fiber net intensity subsequently.Adhesion step can comprise make form fibroreticulate fiber stand water tangle (HET), cold pressing prolong, the constituting of hot calender, ventilative bonding, chemical bonding, acupuncture and they.Suitable non-woven material can be made of natural or synthetic fibers, and they are selected from typel; Acrylic fiber; Cellulose ester fiber; The improvement acrylic fiber; Fypro; Polyester fiber; Polyolefine fiber; Vinal; Staple fibre; Keratin fiber; Cellulose fibre; Silk fiber; And their combination.Non-woven material can be made of homofil (for example polyolefin or polyester) or bicomponent fibre (for example skin of polyethylene/polypropylene or polyethylene/polyester/core pattern fiber or bilateral fibre) or the biconstitutent fibre of being made up of the blend of two or more thermoplastic polymers.

Preferred nonwoven substrate is selected from carding, air lay and melt-blown non-woven material or composite.More preferably, nonwoven substrate of the present invention is selected from the carding fleece of producing with one or more dissimilar fibers by the carded machine.Even more preferably, nonwoven substrate of the present invention is selected from multilayer or lofty fleece, and they merge by through-air bonded or needle point method, are commonly referred to cotton-wool.The example that can be used for the suitable carded nonwoven materials of this paper comprises: LibeltexThermo-contact 01-766 DI-8; Libeltex Loftfill HC2; PGI FB-215; PGIFB-204B, PGI FB-185 and PGI FB-217.

Porous foam and foamed material are made by having multiple porous low-density elastomer, plastics and other material, and can be selected from opening born of the same parents shape foam; Elastic foam; Rigid foams; With reticulated polymer foam and composite foam, they can use molded, pour into a mould, extrude, squeeze draw, machining, hot forming, plasticity welding, blowing mould, model machine technology, grinding and/or other ad hoc approach are processed to net shape fast.Porous foam and foamed material can be made of the number of chemical system, and described chemical system comprises acronitrile-butadiene-styrene (ABS); Acrylic compounds; Epoxy resin; Fluoropolymer polymer; Isoprene styrene (SIS) and s-B-S (SBS); Based on the synthetic rubber or the elastomer of multiple system, for example siloxanes, polyurethane and neoprene; Nitrile rubber; By plastics or elastomer natural or that the plant-origin material forms, for example natural rubber (polyisoprene) or vulcanised fibre; Water base and water-base resin and latex material.The chemical system that is used for porous foam and foamed material can comprise ethylene copolymer, expanded polystyrene, Merlon, polyester, polyethers, PEI, polyimides, polyolefin, polypropylene, polyurethane, phenol, polyureas and vinyl-based.

Porous plastics can be made of a variety of materials, and these materials comprise polytetrafluoroethylene (PTFE), polyethylene (PE), polypropylene (PP) and poly-difluoroethylene (PVDF).They can followingly be made: fill mould with small plasticity pellet, to this mold heated or pressurization, thereby make pellet be bonded in its place that touches.Then, in this part of mould externally heating; This part is significantly shunk during this strengthens step.

Porous foam is preferably polyurethane foam.The suitable example of porous foam derives from RecticelInternational (Belgium), and comprises Sweepex S 31CS/R, Bulpren S28280, Bulpren D32133, Filtren T23220 and Filtren TM23133.

Can any suitable method absorption base (40) be connected to described plate (10; 20) inner surface (101; 201) on, precondition is the performance that absorption base (40) were not destroyed or changed to described method.Adoptable method for but be not limited to that thermal weld (comprising pressure), ultrasonic force, radio or high-frequency, coextrusion thermal activation are bonding, the bonding for example fiber of static is planted hair.Also can absorption base (40) be attached on the application device (1) by adhesive (comprising two sides adhesive tape, thermosetting, heat fusing and cold seal, bonding or extrude lamination).For example also can adopt mechanical interlocking or entanglement

Anchor clamps, springlock, sealing bubble, lock pin and magnetic force arrive material adhesion on the application device (1).

At last, absorption base of the present invention (40) is an inertia basically to Hiar treatment compositions (15) preferably.

Be used for the compressible or incompressible material of the suitable porous of more additional areas and can be selected from non-woven material; Woven material; Porous foam and foamed material; Porous plastics; Pliable and tough frit; Twine; Sponge; And their combination, comprise have physics be superimposed, be bonded together continuously (lamination), with the recirculation and the composite of discontinuous pattern or the one or more synusia by the outer peripheral identical or different material that bonds at discrete joint place, precondition is that these structures satisfy functional requirement mentioned above.

Adoptable atresia compressible material comprises such as siloxanes or natural and materials such as synthetic rubber, thermoplastic elastomer (TPE), TPV or copolymer.Suitable thermoplastic comprises polyolefin, PETG, polyvinylidene chloride and polystyrene.Suitable example includes but not limited to ethylene-propylene diene monomers rubber, for example by Monsanto, and Inc., St.Louis, Mo. sells

Halogenated polyolefin, for example by DuPont Polymer Products, Wilmington, the Alcryn that Del. sells; The hydrogenation addition product of styrene-butadiene block copolymer and maleic anhydride, for example by Shell Chemical Company, Houston, the Craton that Tex. sells; SEBS (sequence styrene-ethylene-butadiene) polymer.Adoptable other material comprises polyvinyl chloride, polyamide, acetyl base class, acronitrile-butadiene-styrene, acrylic compounds, acrylonitrile styrene-acrylate or ethylene-vinyl alcohol.

The suitable material that is used for bristle is a synthetic material, for example polyethylene, polypropylene or PETG, siloxanes or natural and synthetic rubber, thermoplastic elastomer (TPE), TPV or copolymer.Adoptable other material comprise polyvinyl chloride, polyamide, acetyl base class, acronitrile-butadiene-styrene, acrylic compounds, acrylonitrile styrene-acrylate, ethylene-vinyl alcohol, Merlon, polystyrene or copolymer or static plant the hair or non-woven material or foaming structure or natural resources such as horse-hair.The wire-form of bristle or brush can be straight, crooked or curl to obtain desired properties.

The suitable material that is used for pointed tooth comprises polyethylene, polypropylene or PETG, siloxanes or natural and synthetic rubber, thermoplastic elastomer (TPE), TPV or copolymer.Adoptable other material comprise polyvinyl chloride, polyamide, acetyl base class, acronitrile-butadiene-styrene, acrylic compounds, acrylonitrile styrene-acrylate, ethylene-vinyl alcohol, Merlon, polystyrene or copolymer or static plant the hair or non-woven material or foaming structure.

Above-mentioned material can inject altogether, in over-molded, the mould assembling or by adhesive lamination connect, hot adhesion, and they can be removable or permanent the connection.This paper can utilize any method that is suitable for these materials are connected to application device (1), and precondition is the performance that described material can not destroyed or change to described method.Adoptable method for but be not limited to thermal weld, comprise that pressure, ultrasonic force, radio or high-frequency, coextrusion thermal activation are bonding, the bonding for example fiber of static is planted hair.Also can be connected on the application device (1) by these materials that adhesive (comprising two sides adhesive tape, thermosetting, heat fusing and cold seal, bonding or extrude lamination) will be included in the second area.For example also can adopt mechanical interlocking or entanglement

Anchor clamps, springlock, sealing bubble, lock pin and magnetic force are connected to material on the application device (1).

5. Hiar treatment compositions

As indicated above, the inventor recognizes that surprisingly the viscosity of Hiar treatment compositions (15) must combine with other basic element of character of the present invention and select so that the technique effect of expectation to be provided.Therefore, find surprisingly, in order to use Hiar treatment compositions (15) effectively, it is about 3 that described at least a Hiar treatment compositions (15) has, and 000cPs is to about 150,000cPs, preferred about 5,000cPs is to about 125,000cPs, more preferably 7,000cPs is to about 100,000cPs, even more preferably from about 9,000cPs is about 85,000 viscosity extremely.

Before being loaded into Hiar treatment compositions (15) in the hair treatment applicator (1), measure the viscosity of Hiar treatment compositions (15).Only measure the viscosity of liquid Hiar treatment compositions (15).As used herein; term " liquid Hiar treatment compositions " is meant the Hiar treatment compositions (15) of liquid form; for example paste, gel, solution, water-in-oil emulsion or other suitable form; precondition is that they are liquid form when being delivered to head, and has the viscosity that is subjected in this paper claims protection domain.Preferably, use composition with the gel form that good adhesion character is provided.Hydrogel is especially preferred, because they provide the water source, and water helps diffusion and the absorption of Hiar treatment compositions (15) in the absorption base (40) of application device (1).

According to the present invention, have many modes that required Hiar treatment compositions (15) mixture can be provided:

When two kinds of same Hiar treatment compositions of independent loads (15) mix then, one of described Hiar treatment compositions (15) is being loaded into the last viscosity of measuring Hiar treatment compositions (15) before of described hair treatment applicator (1) in described hair treatment applicator (1).

During two kinds of different Hiar treatment compositions of premixed (15), before described mixing Hiar treatment compositions being loaded in the described hair treatment applicator (1), measured the viscosity of gained mixing Hiar treatment compositions (15) before in being loaded into described hair treatment applicator (1).

When Hiar treatment compositions (15) independent loads that two kinds (or multiple) is different is mixed in the described application device (1) then, in being loaded into described hair treatment applicator (1), measure the viscosity of each independent Hiar treatment compositions (15) before described hair treatment applicator (1) in.For relating to the embodiment that arrives two kinds of different composition loaded in the described hair treatment applicator (1) and in described hair treatment applicator (1), mix them subsequently, preferably gained mixing Hiar treatment compositions (15) has about 3,000cPs is to about 150, the viscosity of 000cPs.For this type of embodiment, by before two kinds of (or multiple) Hiar treatment compositions (15) being loaded in the described hair treatment applicator (1), mixing the viscosity of determining gained mixing Hiar treatment compositions (15), as hereinafter as described in the Test Methods section.

When one of Hiar treatment compositions (15) is powder, measure so by the viscosity of mixing the Hiar treatment compositions (15) that produces of described powder with another kind of liquid Hiar treatment compositions (15).

Also it is believed that, for some Hiar treatment compositions (15), the shear thinning rheology of wishing to have height to be helping only using Hiar treatment compositions (15) with cleaning, premium properties and accurate way in selected topknot, thereby avoids the cross pollution to all the other hairs.

6. the type of Hiar treatment compositions

Be characterised in that any Hiar treatment compositions (15) with the viscosity in the selected scope of this paper can be used in the following invention, and can be loaded into selected absorption base (30) upward to realize above-mentioned technique effect.The example that may be used on the Hiar treatment compositions (15) on the absorption base (30) is discussed hereinafter.Suitable Hiar treatment compositions (15) comprises shampoo, conditioner, Hairstyling composition, hair coloring agents, bleaching agent and chooses and dye composition.

Therefore, it is known, conventional that uses or in other words can be used for the especially component of oxidation bleaching and dye composite of Hiar treatment compositions (15) effectively that described composition can comprise, and it includes but not limited to: the developer dye composition; The coupling agent dye composition; Direct dyes; Oxidant; Thickener; Chelating agent; PH conditioning agent and buffer; Carbanion source and free radical scavenger system; Anion surfactant, cationic surfactant, non-ionic surface active agent, amphoteric surfactant or zwitterionic surfactant or their mixture; Anionic polymer, cationic polymer, non-ionic polymers, amphiphilic polymers or amphoteric ion polymer or their mixture; Aromatic; Dispersant; Peroxide stabiliser; Protein and derivative thereof, plant material (for example, aloe, yellow chamomile and garden balsam extract); Siloxanes (volatility or nonvolatile, modification or non-modification), film forming agent, ceramide, anticorrisive agent, color indicator and opacifier.But above mention and hereinafter do not have more specifically described suitable assistant agents to list in International Cosmetics IngredientDictionary and Handbook (the 8th edition, The Cosmetics, Toiletry, and FragranceAssociation).Especially the 2nd volume the 3rd part (chemical classification) and the 4th part (functional group) can be used for determining that concrete assistant agent is to reach specific purpose or multiple use.

A. solvent

The medium that is suitable for dyeing can be selected from the mixture of water or water and at least a organic solvent, and described organic solvent solubilized usually can not fully water-soluble compound.The suitable organic solvent that can be used for this paper includes but not limited to: C1-C4 low-level chain triacontanol (for example ethanol, propyl alcohol, isopropyl alcohol), fragrant and mellow (for example benzylalcohol and phenoxetol); Polyalcohol and polyol ethers (for example carbitol, butoxy ethanol, propane diols, Glycol Monomethyl ether, diethylene glycol (DEG) monoethyl ether, monomethyl ether, hexylene glycol, glycerine, ethyoxyl ethylene glycol) and propylene carbonate.Organic solvent is usually to exist by the weight of composition about 1% to the content in about 30% scope.Preferred solvent is water, ethanol, propyl alcohol, isopropyl alcohol, glycerine, 1,2-propane diols, hexylene glycol, ethoxydiglycol and their mixture.

B. oxidation dye compound

Composition of the present invention can comprise the oxidation dye compound that is main intermediate or coupling agent form.The compound (comprise optional add those) that is suitable for the present composition at them for can be used as free alkali under the condition of alkali or with they form uses with the physiology compatible salt of organic or inorganic acid (example hydrochloric acid).

Optional coupling agent exists with certain amount usually, makes that the total concentration of coupling agent and discrete particle aggregates of the present invention and/or agglomerate counts about 0.002% to about 10%, preferred about 0.01% to about 5% by the weight of hair colouring compositions in the composition.Optional main intermediate exists with effective dyeing concentration, and its content is generally about 0.001% to about 10%, preferred about 0.01% to about 5% by the weight of hair colouring compositions.Usually about 0.002% to about 20%, preferred about 0.04% to about 10%, more preferably from about 0.1% to about 7% scope by the weight of described hair colouring compositions for the total amount of dye composition in the hair colouring compositions of the present invention.

These compounds are well known in the art, and comprise aromatic diamine, amino-phenol, aromatic diol and their derivative (representativeness of oxidation dye precursors but non-exhaustive tabulation be found in Sagarin's " Cosmetic Science and Technology ", Interscience, special edition, the 2nd volume, the 308th to 310 page).Should be understood that the only explanation of describing in detail below as an example of precursor, they are not intended to limit composition and the method for this paper.Toluene-2,4-diisocyanate; the 5-diamines; p-phenylenediamine (PPD); N-phenyl-p-phenylenediamine (PPD); resorcinol; the 4-chloro resorcinol; m-aminophenol; para-aminophenol; the 1-naphthols; 1; the 5-naphthalenediol; 2; the 7-naphthalenediol; p-methylaminophenol; the hydroxy benzo morpholine; 4-amino-2-hydroxy-methylbenzene; 2-methyl-5-hydroxyethyl amino-phenol; 1; 2; the 4-trihydroxy benzene; Phenyl Methyl Pyrazolone 98Min; 2; 4-diamino phenoxy ethanol; 3-amino-2; the 4-chlorophenesic acid; the 2-methylresorcinol; N; two (2-the hydroxyethyl)-p-phenylenediamine (PPD) of N-; 2; 4; 5; the 6-4-aminopyridine; the amino metacresol of 4-; the amino metacresol of 6-; 1; 3-two (2; the 4-diamino phenoxy) propane; the hydroxyethyl P-pHENYLENE dI AMINE; 2-amino-4-hydroxy ethylamino methyl phenyl ethers anisole; 5-amino-6-chlorine orthoresol; hydroxyethyl-3; 4-methylene dihydroxy aniline; 2; 6-dihydroxy-3; the 4-lutidines; 2; 6-dimethoxy-3; 5-pyridine diamines; dihydroxy indole; 5-amino-4-chlorine orthoresol; hydroxypropyl-two (N-hydroxyethyl p-phenylenediamine (PPD)); the 6-oxyindole; isatin; 3-amino-2-methyl amino-6-methoxypyridine; 2-amino-3-pyridone; 2; 6-dihydroxy ethyl amino toluene; 2; 5; 6-triamido-4-ancymidol; the hydroxyl indoline; 1-acetoxyl group-2-methyl naphthalene; 1-hydroxyethyl-4; the 5-diamino-pyrazole; 2,2 '-di-2-ethylhexylphosphine oxide-4-amino-phenol; 2-methyl isophthalic acid-naphthols; 4-formoxyl-1-methylquinoline tosilate.But these material molecular forms or to use with the form of the salt of peroxide compatible.

Hair colourant compositions of the present invention also can comprise non-oxidizable hair dyes, i.e. direct dyes.Described direct dyes can use separately or be used in combination with above-mentioned oxidation dye.Suitable direct dyes comprises nitro-derivative and/or the melanocyte precursor and their mixture of azo or anthraquinone dye and benzene series row.This type of direct dyes especially can be used to send tone variations or choose and dye.Especially preferredly be that alkalescence is red 51, Basic Orange 31, basic yellow 87 and their mixture.

C. basifier

According to the present invention, composition also can comprise at least a basifier source.Can use any reagent known in the art, as alkanolamide, for example MEA, diethanol amine, triethanolamine, single Propanolamine, dipropanolamine, tripropanol amine, 2-amino-2-methyl-1, ammediol, 2-amino-2-methyl-1-propanol and 2-amino-2-methylol-1, ammediol; And guanidinesalt; Ammonium chloride; Ammonium sulfate; Ammonium nitrate; Ammonium phosphate; Ammonium acetate; Ammonium carbonate; Carbonic hydroammonium; Aminoquinoxaline; Ammonium hydroxide; Percarbonate; Ammonia; Ammonium carbonate; Aminoquinoxaline; Ammonia; Sodium metasilicate; Sodium metasilicate; Sodium disilicate; Ammonium persulfate; Sodium peroxydisulfate; Potassium peroxydisulfate; And their mixture.

Composition of the present invention can comprise about by weight 0.1% to about 40%, and preferred about 1.0% to about 35%, 2% to about 30% basifier most preferably from about, preferred ammonium ion.

D. oxidant

Composition can comprise oxidant, and the amount of its existence is enough to bleach the melanin in the hair and/or causes forming dye chromophore by oxidation dye precursors (if present, comprising developer and/or coupling agent).Usually, about 1% to about 20%, preferred about 3% to about 15%, more preferably from about 6% to about 12% scope by the weight of reagent composition for this amount.The inorganic peroxide that can produce hydrogen peroxide in water-bearing media is preferred, and includes but not limited to: hydrogen peroxide; Inorganic base metal peroxide (for example sodium metaperiodate and sodium peroxide); Organic peroxide (for example urea peroxide, peroxidating melamine); Inorganic perhydrate salt bleaching compounds (for example ammonium persulfate, sodium peroxydisulfate, potassium peroxydisulfate and their mixture).Preferably hydrogen peroxide and persulfate.The persulfate powder can mix by as mentioned below and another kind of liquid Hiar treatment compositions, or can powder particle be applied to the inner surface of absorption base and/or outer surface and physically fixing via following mode alternatively: they are physically comprised and can easily not left matrix under the gravity effect.This can realize via middle empty wallet that comprises the persulfate blend in the absorption base or reservoir.

E.pH conditioning agent and buffer

Composition also can comprise the pH value that is enough to effectively composition and be adjusted to about 3 to about 13, preferred about 8 to about 12, more preferably from about 8 the pH conditioning agent and/or the buffers of amount to about 11 the scope.The suitable pH conditioning agent and/or the buffer that can be used for this paper include but not limited to: ammonia; Alkanolamide is as MEA, diethanol amine, triethanolamine; The hydroxide of alkali metal and ammonium and carbonate, preferred NaOH and ammonium carbonate; And silicate (as sodium metasilicate and sodium metasilicate); And ammonium chloride.

F. carbanion source

In a preferred embodiment, composition of the present invention also can comprise at least a mistake one carbanion source, is preferably formed on the spot by hydrogen peroxide source and carbanion source.According to the present invention, therefore described composition also can comprise at least a carbanion source or carbamic acid radical ion source or bicarbonate ion source or their any mixture.Can use any source of these ions.The suitable source that can be used for this paper comprises the sodium salt of carbonate, carbamic acid root and bicarbonate ion, sylvite, guanidinesalt, arginine salt, lithium salts, calcium salt, magnesium salts, barium salt, ammonium salt and their mixture, as sodium carbonate, sodium acid carbonate, potash, saleratus, guanidine carbonate, bicarbonate guanidine, lithium carbonate, calcium carbonate, magnesium carbonate, brium carbonate, ammonium carbonate, carbonic hydroammonium and their mixture.Also can use percarbonate that carbanion source and oxidizer source are provided.Preferred carbanion, carbamic acid root and bicarbonate ion source are sodium acid carbonate, saleratus, aminoquinoxaline and their mixture.Composition of the present invention can comprise about by weight 0.1% to about 15%, and preferred about 0.1% to about 10%, more preferably about by weight 1% to about 8% carbanion.

G. free radical scavenger system

Composition can comprise free radical scavenger, presents in an amount at least sufficient to reduce in coloring process the damage to hair.Usually, this amount by the weight of described composition 0.1% to 10%, in preferred 1% to 7% the scope.Preferably, free radical scavenger is chosen to make itself and basifier are not same kind.Free radical scavenger is to react the carbonate group is transformed into the component of active low component by a series of fast reactions with the carbonate group.Preferred free radical scavenger can be selected from alkanolamine; amino sugar; amino acid and their mixture; and can include but not limited to: MEA; 3-amino-1-propyl alcohol; 4-amino-1-butanols; 5-amino-1-amylalcohol; 1-amino-2-propyl alcohol; 1-amino-2-butanols; 1-amino-2-amylalcohol; 1-amino-3-amylalcohol; 1-amino-4-amylalcohol; 3-amino-2-methyl-1-propyl alcohol; 1-amino-2-methyl-2-propyl alcohol; 3-amino-1, the 2-propane diols; aminoglucose; the N-acetyl glucosamine; glycine; arginine; lysine; proline; glutamine; histidine; serine; the sylvite of tryptophan and above-mentioned substance; sodium salt and ammonium salt; and their mixture.Other preferred radicals scavenging immunomodulator compounds comprises benzylamine, glutamic acid, imidazoles, di-tert-butyl hydroxy toluene, quinhydrones, catechol and their mixture.

H. chelating agent

The chelating agent that composition can comprise capacity with reduce can with the interactional tenor of formulation components (especially oxidant more particularly is a peroxide).This content by the weight of described composition usually at least about 0.25%, preferably at least about in 0.5% the scope.The suitable chelating agent that can be used for this paper includes but not limited to: diamines-N, N '-two polyacid, monoamine monoamides-N, N '-two polyacid and N, N '-two (2-hydroxybenzyl) ethylenediamine-N, N '-oxalic acid chelating agent (preferred EDDS (EDDS)), carboxylic acid (preferred amino carboxylic acid), phosphonic acids (preferred aminophosphonic acid) and polyphosphoric acid (straight chain polyphosphoric acid specifically), their salt and derivative.

I. wetting agent

Composition can comprise wetting agent.Usually, in the Hiar treatment compositions amount of wetting agent by the weight of described composition at least about 1% to about 50%, preferred about 5% to about 40%, and more preferably from about 10% to about 30% scope.The suitable wetting agent that can be used for this paper includes but not limited to: polyalcohol, and as glycerine, polyethylene glycol and propane diols and their mixture.

J. thickener

Hiar treatment compositions also can comprise thickener.The content that thickener exists counts about 0.01% to about 20%, preferred about 0.1% to about 10% by the weight of described composition, and more preferably from about 0.3% to about 5%, and even more preferably from about 0.5% to about 3%.

Gel network thickener can be used as the thickener that is used for the object of the invention.Gel network thickener comprises at least a low HLB surfactant or has dystectic amphiphile, amphiphilic molecule and at least a other second surface activating agent.

Low HLB surfactant or amphiphile, amphiphilic molecule have 6 or lower HLB and at least 30 ℃ fusing point.Representative example comprises following compound (" solid " is meant the physical form under the temperature that is being lower than 30 ℃ in following example): solid fatty alcohol, solid oxyethylation fatty alcohol, solid diol ester, solid oxyethylation alkyl phenol, solid sorbitan ester, solid sugar ester, solid methyl glucosamine ester, solid polyglycerol ester, solid alkyl glycerol base ether, solid methyl glycol fatty acid ester, cholesterol and ceramide.Preferably, low HLB surfactant be selected from the straight or branched that comprises about 14 to 30 carbon atoms fatty alcohol, comprise about 16 to 30 carbon atoms and the oxyethylation fatty alcohol of about 2 ethylene oxide units and the fatty mono glyceride that comprises about 16 to 30 carbon atoms at most.Most preferably, low HLB surfactant comprises cetanol, stearyl alcohol, 16-18 mixed alcohol or docosanol, stearyl APEO-2 and glyceryl monostearate.

The second surface activating agent of gel network thickener is anionic, non-ionic or cationic.The example of anion surfactant includes but not limited to have the mixture of those and they of formula RnXmYM, wherein R is alkyl, alkenyl or the alkylaryl that contains 8 to 30 carbon atoms, X is the polar group that comprises at least one carbon atom and at least one oxygen atom or nitrogen-atoms, Y is the anionic group that is selected from carboxylate radical, sulfate radical, sulfonate radical or phosphate radical, n and m are 1 or 2 independently, and M is hydrogen or salt-forming cation; The example of non-ionic surface active agent comprises having 7 or bigger HLB and comprise those of one or more polyethylene oxide chain (wherein every polyethylene oxide chain on average comprises at least about 50 ethylene oxide units).Also being suitable for what make non-ionic surface active agent is to have 7 or the non-ionic surface active agent that does not contain polyethylene oxide chain of higher HLB.The example of cationic surfactant includes but not limited to have quaternary ammonium salt or the amidoamines and their mixture of at least one aliphatic chain that comprises 8 to 30 carbon atoms.Quaternary ammonium salt has general formula N+ (R1R2R3R4) X-, wherein R1 is selected from the straight chain that comprises about 12 to 30 carbon atoms and the group of side chain, R2 is selected from the group or the group identical with radicals R 3 to R4 of the straight chain that comprises about 12 to 30 carbon atoms and side chain, radicals R 3 to R4 identical or different, and be selected from the straight chain that comprises about 1 to 4 carbon atom and the aliphatic group of side chain, and aromatic group such as aryl and alkylaryl, described aliphatic group can comprise at least one hetero atom such as oxygen, nitrogen, sulphur and halogen, described aliphatic group is selected from for example alkyl, alkoxyl and alkylamide group, and wherein X for being selected from the halogen ion (as chlorion, bromide ion and iodide ion), (C2-C6) alkyl sulfate (as methylsulfate), phosphate radical, the anion of alkyl and alkyl aryl sulphonic acid root, and derived from organic acid anion (as acetate and lactate).Cationic surfactant is selected from for example INCROQUAT TMC-80, docosane acylamino-oxypropyl trimethyl methylsulfuric acid ammonium, the amino oxypropyl trimethyl ammonium chloride of stearoyl, eicosyl trimethyl ammonium chloride and their mixture.Amidoamines has general formula R ' 1-CONH (CH2) nNR ' 2R ' 3: wherein R ' 1-is selected from the straight chain that comprises about 12 to 30 carbon atoms and the group of side chain, radicals R ' 2 and R ' 3 identical or different, be selected from hydrogen, comprise the straight chain of about 1 to 4 carbon atom and aliphatic group and aromatic group such as the aryl and the alkylaryl of side chain, described aliphatic group can comprise at least one hetero atom such as oxygen, nitrogen, sulphur and halogen, described aliphatic group is selected from (for example) alkyl, alkoxyl and alkylamide group, and wherein n is 1 to 4 integer.Amidoamines is selected from for example docosane acylamino-propyl-dimethyl amine, the amino propyl group dimethylamine of stearoyl and their mixture.

Can use above the surfactant of specified type above a kind of or any combination of these surfactants, and the weight rate of the low HLB surfactant and the second designated surface activating agent is that about 100:1 is to about 1:10, preferred 20:1 to 1:2, and more preferably 10:1 to 1:1.

Acidamide surfactant also is a suitable thickening, preferably when mixing with the carbanion source.Optional selfpolyoxyethylene acid amides of acidamide surfactant or polyhydroxy amides.Polyoxyethylate amide is selected from the compound that meets formula R-(OCH2CH2) x-(OCH2) y-C (O) NH (CH2CH2O) z-H, wherein x is independently selected from 0 to 100, y is 0 or 1, z is independently selected from 1 to 100, and R is independently selected from alkyl, alkenyl or the alkylaryl that contains 8 to 30 carbon atoms, or meets the polyhydroxy amides of following formula:

Vermiculate glues phase thickened systems also is used for the suitable thickener of the object of the invention.Vermiculate glues thickened systems of the present invention is defined as the thickened systems that comprises at least a ionic surface active agent and be used for the electrolyte source of counter ions of described ionic surface active agent.The appropriate ions surfactant that can be used for this paper can be selected from anion surfactant, cationic surfactant and/or their mixture.

The suitable thickener that can be used for this paper also comprises synthetic polymer, as cellulose derivative (methylcellulose for example, carboxymethyl cellulose, hydroxyethylcellulose, hydroxypropyl cellulose, hydroxypropyl methylcellulose etc.), carbomer polymer (for example crosslinked polypropylene acid copolymer or homopolymers, and acrylic acid and polyalkenyl polyether crosslinked copolymers), the acrylic acid polymer of hydrophobically modified, natural and paragutta, karaya, guar gum, gelatin, algin, mosanom, bassora gum, chitosan, PEO, acrylamide polymer, polyacrylic acid, polyvinyl alcohol, polyamine, poly-quaternary ammonium compound, ethylene oxide polymer, polyvinylpyrrolidone, cationic polyacrylamide polymer, and their mixture.

Other relevant thickener comprises Rohm and Haas (the soluble acrylic polymer emulsions of the alkali of hydrophobically modified for example

ICS-1 and The nonionic polyol of 22 and 28 thickeners and hydrophobically modified

44 and 46 thickeners).

Preferred thickening is selected from polymer (comprising gelling agent), is called the gel phase of white cream or emulsion and their combination.

The representativeness of polymer and thickener but non-exhaustive tabulation is found in " The Encyclopaedia ofPolymers and Thickeners for Cosmetics ", doctor RobertY.Lochhead and William R.Fron compiling and editor by polymer science system of University of Southern Mississippi (Department of Polymer Science, University of Southern Mississippi).

The suitable gel phase that is known as white cream or emulsion can be selected from cetanol, stearyl alcohol, aliphatic acid and their mixture.

7. optional feature

Provide the detailed description that can be used for some optional features of the basic element of character of the present invention combination below.These optional features can randomly be positioned at the inner surface (101 of described first plate (10) and second plate (20); 201) or outer surface (102; 202) on.Preferably, some in these parts can be positioned at described plate (10; 20) inner surface (101; 201) on.Also imagining this paper optional feature described below within the scope of the invention makes up in same hair treatment applicator (1).

7.1 scraper

Hair treatment applicator (1) also can comprise scraper.Scraper is the periphery edge (103 at least one described plate (10); 203) locate the continuous or discrete non-pored wood strip that provides.Preferably, scraper is continuous, as shown in Figure 3.Make first plate (10) become juxtaposition relationship and hair treatment applicator (1) when being in closure state with described second plate (20), scraper is wiped the excess deposition of Hiar treatment compositions (15).When scraper was discontinuous, scraper repeated to form castellated building configuration with rule or irregular interval along periphery edge (103).In one embodiment, scraper is present in two plates (10; 20) periphery edge (103; 203) locate, and the scraper on scraper on first plate (10) and second plate (20) interlocks, so that making plate (10; The scraper of two plates provides continuous boundary when 20) becoming juxtaposition relationship.Scraper comprises the atresia compressible material.Available atresia compressible material comprises such as siloxanes or natural and materials such as synthetic rubber, thermoplastic elastomer (TPE), TPV or copolymer.Suitable thermoplastic comprises polyolefin, PETG, polyvinylidene chloride and polystyrene.Suitable example includes but not limited to ethylene-propylene diene monomers rubber, for example by Monsanto, and Inc., St.Louis, Mo. sells

Halogenated polyolefin, for example by DuPont PolymerProducts, Wilmington, the Alcryn that Del. sells; The hydrogenation addition product of styrene-butadiene block copolymer and maleic anhydride, for example by Shell Chemical Company, Houston, the Craton that Tex. sells; Sequence styrene-ethylene-butadiene polymer.Adoptable other polymer comprises polyvinyl chloride, polyamide, acetyl base class, acronitrile-butadiene-styrene, acrylic compounds, acrylonitrile styrene-acrylate and ethylene-vinyl alcohol.

7.2 reservoir

Hair treatment applicator (1) also can comprise the reservoir that is used for Hiar treatment compositions (15).Reservoir can be present in the outer surface (102 of one or two plate; 202) or inner surface (101; 201) on.Preferably, reservoir is communicated with described absorption base (40) in the inner surface (101) by aperture, and described aperture passes described plate (10) location.Valve can be positioned on the reservoir.In some embodiments, unidirectional or two way valve can be attached to the inner surface (101 of described first plate (10) and/or second plate (20); 201) in and/or in the reservoir, so that by engaging bottle or anyly being suitable for distributing the container of Hiar treatment compositions to load Hiar treatment compositions (15).But reservoir can be fixing, attachable or slave plate (10; 20) remove on, and promptly discardable after discharging Hiar treatment compositions (15).

Reservoir can comprise such as polyethylene, polypropylene or PETG, polyvinyl chloride, siloxanes or natural and materials such as synthetic rubber, thermoplastic elastomer (TPE), TPV or copolymer.Reservoir can many modes form, and comprising: the hot adhesion of assembling in altogether injection, over-molded, the mould, vacuum forming, casting, bonding lamination or laminated material.

Can be measured layer, barrier material or liner of aperture covers, described measuring layer, barrier material or liner cover can via peel off, break, bore a hole, damaged, tear, pierce through, slide, fold and compression removes.

7.3 stop mechanism

One or more stop mechanisms can be attached to described first and second plates (10; 20) at least one inner surface (101; 201) on.Stop mechanism guarantees that Hiar treatment compositions (15) can not be forced to exceed described first and second plates (10; 20) periphery edge (103 of (when being placed in juxtaposition relationship); 203).In certain embodiments, by at plate (10; 20) outer surface (102; 202) exert pressure on and make hair treatment applicator (1) be in closure state.When at described first and second plates (10; 20) outer surface (102; When applying too high pressure 202) and making described plate become juxtaposition relationship, Hiar treatment compositions (15) may ooze from hair treatment applicator (1) or it may form droplet, thereby produces unacceptable dirty and messy.Too high pressure even may cause being included in the material that the absorption base (40) in the first area damages and/or be included in described one or more additional areas and influence Hiar treatment compositions (15) using on hair.

In certain embodiments, stop mechanism can with plate in same manufacturing step with identical or different material manufacturing.

The existence of stop mechanism, size and height are relevant with interior other material that uses of described second area with the compressibility of absorption base (40).In certain embodiments, stop mechanism can be one or more pointed tooths, and perhaps it can comprise the tusk of pectinate texture in previously described any material.In certain embodiments, stop mechanism can be positioned within the absorption base (40) or under.In some other embodiment, stop mechanism can be bonded to the periphery edge (103 of first plate (10) and/or second plate (20); 203) locate, perhaps be bonded to the inner surface (101 of contiguous connector (30); 201) on.In some other embodiment, stop mechanism can be integrated in the connector (30) itself.

7.4 topknot selecting arrangement

The consumer can use finger to select expectation that Hiar treatment compositions is administered to topknot on it.Yet hair treatment applicator of the present invention (1) also can have the topknot selecting arrangement.The example of topknot selecting arrangement is but is not limited to suspension hook (as the crochet hook suspension hook) and hair clip or sends out pearl.The topknot selecting arrangement can be attached to one or two plate (10; 20) in.Also can attach the device to plate (10 by snap-fastener mechanism; 20) on, make the topknot selecting arrangement to swing to position far away, for example take place with the blade of pocket knife by the position near plate.The assembly that the topknot selecting arrangement also can be used as cover box as mentioned below is provided to separately on the hair treatment applicator of the present invention (1).

7.5 grip area

Usually the consumer is with gloves during using Hiar treatment compositions (15).Gloves are usually by making such as polyvinyl chloride or polyethylene or elastomeric material such as materials such as isoprene, neoprene or latex, and can increase the difficulty of consumer's grasping hair treatment applicator (1).Therefore, hair treatment applicator disclosed herein (1) also can be at one or two plate (10; 20) outer surface (102; 202) comprise the grip area that is designed to provide grasping on.These grip area can be utilized injection or over-molded technology manufacturing altogether when making plate.Available material includes but not limited to such as polyethylene, polypropylene or siloxanes or natural and materials such as synthetic rubber, thermoplastic elastomer (TPE), TPV or copolymer.Adoptable other material comprise polyvinyl chloride, polyamide, acetyl base class, acronitrile-butadiene-styrene, acrylic compounds, acrylonitrile styrene-acrylate, ethylene-vinyl alcohol, Merlon and polystyrene or static plant the hair or non-woven material or foaming structure.In addition, can or use one or two plates (10 by embossing, the recessed pattern of generation; 20) outer surface (102; 202) form grip area.Grip device can only be positioned at outer surface (102; 202) in the part or they can cover whole outer surface (102; 202).At last, grip area can be and is present in described plate (10; 20) outer surface (102; 202) cavity on.

7.6 release liner or barrier

Can exist release liner or barrier not contaminated with the material of protecting absorption base (40) and/or be present in the described second area.Release liner or barrier are strippable or resealable, and can be made of plastics, aluminium lamination pressure.Some examples of these materials comprise: the layered product of the blend of low density polyethylene (LDPE) or polyethylene and polyisobutene and aluminium foil and PETG or the peelable paillon foil of Bioriented polypropylene, and can make by gas-barrier material, especially for the Hiar treatment compositions that comprises hydrogen peroxide, comprise metallization aluminium on aluminium lamination blocking sheet, the plastic carrier,

Polytrifluorochloroethylene, polyvinylidene chloride, ethylene-vinyl alcohol copolymer, silica and aluminium oxide.

7.7 be used for Hiar treatment compositions is loaded into the device of application device

Can there be one or more devices that are suitable for connecting, connecting or install distribution or charger, so that Hiar treatment compositions (15) is loaded in the hair treatment applicator of the present invention (1).The example of described parts is but is not limited to nozzle and aperture, pouch or is present in the unidirectional or two way valve that connector (30) was gone up or passed at least one plate (10).Described parts can permanently be connected to hair treatment applicator (1) and go up or can be removable, and they can be and disposablely maybe can recycle, and they can be used as the independent assembly that hereinafter described overlaps box and provide.

8. the loading of Hiar treatment compositions and mixing

According to the present invention, described one or more Hiar treatment compositions (15) can be loaded in the application device (1).One or more Hiar treatment compositions (15) can be administered on the described absorption base that is included in the first area, perhaps be administered to plate (10; 20) in the depression or cavity, as shown in Figure 1.When absorption base (40) extend upward along the periphery edge (103) of described at least the first plate (10) from described inner surface (101) as continuous band and wherein said continuous band when one of described inner surface (101) qualification of described first plate (10) is regional, Hiar treatment compositions (15) can be loaded in the zone of described qualification, shown in Fig. 2 and 3.When reservoir is chosen in existence wantonly, can Hiar treatment compositions (15) be loaded in the described reservoir by unidirectional or two way valve.

Can Hiar treatment compositions (15) be loaded in the hair treatment applicator (1) by any device.In one embodiment, by for example use from bottle that Hiar treatment compositions (15) directly is loaded into Hiar treatment compositions (15) on the absorption base (40) or among.

When before Hiar treatment compositions (15) is being administered on the hair, needing to mix with activation, the single component of Hiar treatment compositions (15) can perhaps can be mixed by special use two Room or the multichamber vessel that adopts the connection static mixer during load step by shaking or mixing before loading.Also can mix by inserting attachment device, described device can mix two or more Hiar treatment compositions (15) or can mixed-powder with water or other solvent with manufacturing Hiar treatment compositions (15).The device of described insertion also can have injects or is loaded into parts on the application device (1) with the Hiar treatment compositions (15) that mixes.

In case described one or more Hiar treatment compositions (15) are loaded in the hair treatment applicator (1), make plate (10 at once; 20) become juxtaposition relationship once, preferably twice more preferably surpasses twice, so that Hiar treatment compositions (15) can evenly distribute in application device (1) and finally penetrate in the porous absorption base of first area.

The amount that is administered to the Hiar treatment compositions (15) on the application device (1) depends on its size and capacity and required final effect.The amount that can preferably be loaded into the Hiar treatment compositions (15) on the application device (1) is extremely about 120 grams of about 0.5 gram, more preferably from about 1 restrains to about 50 grams, even more preferably from about 1.5 restrains the Hiar treatment compositions (15) that restrain to about 25.

9. using method

The present invention also relates to by handle the method for hair with hair treatment application system contact hair of the present invention.Described one or more Hiar treatment compositions (15) can be pre-loaded on the described hair treatment applicator (1), but preferably before with described hair treatment application system contact hair, described at least a or multiple Hiar treatment compositions (15) be loaded on the described hair treatment applicator (1).For Hiar treatment compositions (15) can be distributed in porous absorption base (40) equably, before with described hair treatment application system contact hair, make described first plate (10) of described hair treatment applicator (1) become juxtaposition relationship once with second plate (20), preferably twice is more preferably above twice.In case be ready to use hair treatment application system, the user is just by described first and second plates (10; 20) outer surface (102; 202) hair treatment applicator (1) is held in the hand, preferably is held between thumb and the forefinger.In case the user has chosen pending topknot, just application device (1) is navigated on the topknot, preferably at root of hair line place, make hair treatment applicator (1) be in open mode simultaneously.Then by making plate (10; 20) become the inner surface (101 of juxtaposition relationship with application device (1); 201) be clipped in around the topknot.By making hair treatment applicator (1) keep this closure state, the user drags application device (1) by the whole length along selected topknot and uses Hiar treatment compositions (15).Also Hiar treatment compositions (15) only can be administered on the finite region of hair, promptly the user can only use the root of hair line with Hiar treatment compositions (15).These steps comprise the step that loads application device (1), can repeat to surpass once.

By contacting hair, Hiar treatment compositions (15) is delivered on the hair with hair treatment application system.

In certain embodiments, before being administered on the hair, must mix two or more Hiar treatment compositions (15).Preferably, described Hiar treatment compositions (15) is different and can reacts the Hiar treatment compositions that forms mixing.

Can before Hiar treatment compositions (15) being loaded in the hair treatment applicator (1) and/or before being administered to Hiar treatment compositions (15) on the hair, mix.In a preferred embodiment, described one or more Hiar treatment compositions (15) comprise first and second Hiar treatment compositions, and mix described first and second Hiar treatment compositions to form the 3rd Hiar treatment compositions.Before with described hair treatment application system contact hair, described the 3rd Hiar treatment compositions is loaded on the described hair treatment applicator (1).In this embodiment preferred, described first Hiar treatment compositions comprises oxidant, and described second Hiar treatment compositions comprises basifier.In a preferred embodiment, described oxidant comprises hydrogen peroxide, and perhaps described basifier comprises the component that is selected from by the following group of forming: ammonium persulfate, sodium peroxydisulfate, potassium peroxydisulfate, sodium metasilicate, sodium metasilicate, ammonium chloride and their mixture.When described first and second Hiar treatment compositions mixed, they form to choose dyed composition.

Hiar treatment compositions of the present invention (15) is not intended to be administered on the hair with fixed form, but move by using shearing force to be close to hair surface, promptly, hit single topknot, along root of hair line friction, rub and clip in the hair, be coated with and put hair surface on the skin, be pulled through hair etc., thereby as requiredly deposit Hiar treatment compositions (15) equably along the whole length of hair.

In having the embodiment of release liner, the user peels release liner off, Hiar treatment compositions (15) is loaded in the described application device (1) and with it be administered on the hair.During using, the one or more release liners of resealable perhaps avoid Hiar treatment compositions (15) to pollute user's furniture with protection application device (1) and Hiar treatment compositions (15).

In another embodiment, via any known conventional method first Hiar treatment compositions (15) is administered on the hair, with as preliminary treatment or post processing for any other second Hiar treatment compositions (15) that can use by hair treatment applicator of the present invention (1).

In having the embodiment of reservoir, the user can load Hiar treatment compositions (15) by any distributor, and the user can remove liner or barrier before being administered to Hiar treatment compositions on the hair then.The user can mix Hiar treatment compositions (15) before using, the described Hiar treatment compositions (15) of using by squeezable reservoir and promoting to be included in wherein flow to absorption base (40) along the aperture that passes described first plate (10) location.

At last, using of Hiar treatment compositions (15) can occur on the wetting or dry hair, and randomly comprises the step that flushing or shampoo are sent out between being administered to first and second compositions on the hair.

10. cover box

Hair treatment application system of the present invention can be used as at least a hair treatment application system and provides as an assembly that overlaps box.In addition, the cover box can comprise the Hiar treatment compositions (15) of at least a or multiple independent packing, and described composition comprises shampoo Compositions, care composition, Hairstyling composition, hair colourant compositions, bleaching hair composition, chooses and dye composition or their combination.In addition, surpassing the assembly that a kind of hair treatment applicator (1) can be used as cover box of the present invention provides.

In one embodiment of the invention, first container can comprise oxidation dye precursors and basifier, and second container can comprise oxidant.In some other embodiment of cover box, first container can comprise ammonium ion source, and second container can comprise oxidant.Other container can be present in the cover box, the independent packaged composition that for example comprises annexing ingredient, for example oxidant, conditioner, chelating agent, free radical scavenger, solvent, direct dyes, shampoo, buffer, coloring agent, thickener, enzyme, anion surfactant, non-ionic surface active agent, amphoteric surfactant and cationic surfactant, carrier, antioxidant, stabilizing agent, spices, shelter aromatic, vanilla and plant extracts, pearling agent, opacifier, hair swelling agent and/or polymer, wetting agent, NMF, viscosity intensifier, gelling agent, chelating agent, ultraviolet filtering agent, antimicrobial, anticorrisive agent, protein, or their mixture.

Cover box of the present invention also can comprise add-on assemble, as be used to select the device of topknot, the device that loads application device of the present invention (1), mixing and/or load as described in device, comb or brush, gloves, the top cover that the hole is arranged, tweezers, tongue, suspension hook or their combination of Hiar treatment compositions (15) of independent packing.

In another embodiment, the cover box also comprises independent packaged composition that contains oxidant and the independent packaged composition that contains basifier.Preferably, described oxidant is a hydrogen peroxide.More preferably, the Hiar treatment compositions of at least a described independent packing comprises persulfate.

Hair treatment applicator of the present invention (1) can be unassembled form provide in the box at cover, and the explanation of how to construct application device of the present invention (1) also can provide in above-mentioned cover box.The external member that comprises application device of the present invention (1) can comprise also how consumption guidance person loads and/or use the explanation of application device (1), described explanation is for example overlapped packing, paper material, CD or the hair treatment applicator (1) of box itself itself with the media record of any kind.

11. method of testing

The intermediate value pore radius

There is not independent method to measure to be used for the intermediate value pore radius in the scope of the selected absorption base of purpose of the present invention.At first by TRI Autoporosimeter ^TMMeasure the intermediate value pore radius of absorption base.For surpassing 1000 microns income value, and will get with the value of optical imagery gained and make end value via the optical imagery replication.

TRI Autoporosimeter ^TMBe the equipment of the computer control of automation, its be used to measure pore radius and their corresponding accumulation pore volumes (B.Miller and I.Tyomkin, Journal of Colloid andInterface Science, 162 (1994), 163-170).The intermediate value pore radius of sample is the cylindrical radius of equivalent, wherein absorb/cumulative volume of desorb fluid equal test sample saturated capacity 50%.The cylindrical radius of equivalent can be by hydrostatic pressure when saturated (50% pressure) the Laplace formula (I) relevant with pore radius provided:

R = \frac{2 γ \cos θ}{ΔP} - - - (I)

Wherein R is an effective radius, and γ is the surface tension of wetting liquid, and θ is that the contact of liquid is advanced or receding contact angle, and Δ P is the pressure differential of striding the hydrostatic pressure head of sample.Usually equivalent pore radius in the middle of being measured to determine by desorb, wherein θ is a receding contact angle.If 50% value does not correspond to the equivalent radius of preliminary election, can determine by the interpolation diagram so.

The test sample that typically has a diameter from 50mm put into the measuring flume on the Millipore glass filter barrier film (1.2 microns holes) that is connected to the Monel gripper shoe.Prepare filtering diaphragm and Monel metallic supports and adhere to according to the introduction of manufacturer by epoxy radicals coating (Krylon High Gloss derives from Swerin-Williams Corp.).Measure to guarantee test sample contacting with fluid test barrier film with 0.1 pound/square inch exert pressure (maximum weight).

Measuring flume is connected on the reservoir that is placed on the test liquid on the balance.Use TRIAutoporosimeter ^TMCome wetting absorption base with hexadecane.The liquid weight (volume) that is absorbed matrix absorption/desorb is noted by balance as the function of applying air pressure.When air pressure increase and reduction, the radius groups of different sizes are desorbs and absorption liquid respectively.The radius volume of each group equals the volume of this institute transfer liquid.Testing near under the EQUILIBRIUM CONDITION equally in order to ensure all samples, recommend to use following parameter: (i) equilibrium constant (the liquid stream under each pressure step) less than 90mg/min, was (ii) collected the balance weights data up to reaching required equilibrium constant value every 15 seconds.The result provides with capillary pressure (cm) (g) function as fluid weight on the balance.

Have greater than the test sample of 1000 microns intermediate value pore radius and determine by optical imagery.The test sample of about 50 x 50mm is put into the Olympus stereoscope (Stereo-Microscope) that is connected to digital camera.Use the dark-ground illumination technology to strengthen the visual appearance that contrasts and improve three-dimensional structure.Select applied enlargement ratio with the area-of-interest (ROI) that a) obtains the representative sample structure and b) to allow to measure reliably the aperture.The hole area of all focal apertures of manual measurement in ROI, subsequently with Olympus analySIS FIVE software analysis so that the function of cumulative surface hole area as equivalent circular port radius to be provided.When the accumulation hole area equal all surfaces hole area 50% the time, the intermediate value pore radius of sample is the equivalent circular radius.Measurement comprises and not exclusively is parallel to the focal plane but from hole that viewing angle (owing to be three-dimensional structure) is observed.

With the intermediate value pore radius extremely immediate micron of report (μ m).Intermediate value pore radius in some absorption bases of the present invention and other technical parameter show in following table 5.Table 5 also illustrates the absorption base that discontented unabridged version literary composition is subjected to the specification of claims protection.

Absorptive capacity

For porous matrix, absorptive capacity be defined as the drying solid liquid that matrix absorbs of per unit mass quality (referring to, Absorbent Technology for example, by Chatterjee and Gupta, Elsevier, 2002):

C = \frac{ρ_{l}}{ρ} \times \frac{φ}{1 - φ}

Wherein ρ is a density of forming the material of matrix, ρ ₁Be that density of liquid (is used the density-1.00g/cm of pure water for the absorptive capacity of defined ³) and φ 1 deduct ρ _{Stacking volume}Merchant (ρ divided by ρ _{Stacking volume}Be the bulk density of porous matrix).For multicomponent fibre/blend and non-cylindrical fiber, use average weighted solid fiber density.The result is reported as gram fluid/gram matrix (g/g).

Thickness

Determine the thickness of absorption base by the method for testing (ERT30.5-99) of EDANA recommendation.Use has the Abram2000 type mircrometer gauge (Technische Beratung Abram GmbH) of the gaging pressure of the falling speed of the precision of 0.01mm and 3mm/s and 0.1kPa.Use identical method and measure the thickness of foam matrix.

Basic weight

Determine the quality of the basic weight-per unit area of absorption base by the method for testing (ERT40.3-90) of EDANA recommendation.Accurately cut and the matrix test zone of the 100 x 100mm that weigh.The result is reported as every square metre of (g/m of gram ²).Use identical method and measure the basic weight of foam.

Table 5: the technical parameter of some absorption bases.

Absorption base	Intermediate value pore radius [micron]	Absorptive capacity [g/g]	Thickness [mm]	Basic weight [g/m ²]
Absorption base	Intermediate value pore radius [micron]	Absorptive capacity [g/g]	Thickness [mm]	Basic weight [g/m ²]	Libeltex?01-766 01-766DI-08	550	41	6.24	148
PGI?FB-215	700	57	7.83	136	Libeltex?01-766 01-766DI-08	550	41	6.24	148
PGI?FB-215	700	57	7.83	136	PGI?FB-185	500	45	7.17	156
Recticel?Bulpren Foam?S28280	1400	40	6.02	143	PGI?FB-185	500	45	7.17	156
Recticel?Bulpren Foam?S28280	1400	40	6.02	143	Polyscorer?Foam 410 ^*	2200	29	11.12	365
PGI?FB-213A	700	41	4.94	118	Polyscorer?Foam 410 ^*	2200	29	11.12	365
PGI?FB-213A	700	41	4.94	118	BBA?Fiberweb Tenotex?PL60L ^*	70	? 7	0.46	59
Freundenberg?AL 1060	300	16	0.99	60	BBA?Fiberweb Tenotex?PL60L ^*	70	? 7	0.46	59

The mixed method of Hiar treatment compositions

When mixing two or more Hiar treatment compositions before being loaded in the absorption base, can use following program when as described herein.With described at least two kinds of Hiar treatment compositions (both are liquid or a kind of liquid and a kind of powder), put into container with the weight rate between 1:10 and 10:1.This container can be different forms, for example with the bottle or the opening compartment of capping.Under the situation of bottle, it is even up to mixture to shake two kinds of compositions 2 minutes.Under the situation of opening compartment, mix one period that is enough to produce even mix products of two kinds of compositions with blend tool.The mix products of producing via this method identical with by following acquisition: two kinds of composition loaded are mixed in different absorbing materials and when two kinds of absorbing materials are forced together.

The viscosity measurement method of testing

The Brookfield viscometer determining that use is furnished with cone and plate annex is loaded into the viscosity of the Hiar treatment compositions in the absorption base.For at about 0cPs to 12, the viscosity in the 000cPs scope is used the Brookfield DV-II+ viscosimeter of being furnished with the S42 plate.Before measuring with Hiar treatment compositions or

The 2ml sample of 956 solution 26.7 ℃ in 1rpm balance one minute, wherein take the reading at 1rpm.For about 12, the viscosity of 000cPs, the another kind that carries out as mentioned below is measured.

For 12,000cPs is to about 100, and the viscosity in the 000cPs scope is used the Brookfield DV-II+ viscosimeter of being furnished with the S52 plate.Before measuring with Hiar treatment compositions or

The 0.5ml sample of 956 solution 26.7 ℃ in 1rpm balance one minute, wherein take the reading at 1rpm.Once more as top explanation, for 100, the viscosity of 000cPs, the another kind that carries out as mentioned below is measured.

For 100,000 to 150, the viscosity in the 000cPs scope is used the BrookfieldDV-II+ viscosimeter of being furnished with the S52 plate.Before measuring with Hiar treatment compositions or

The 0.5ml sample of 956 solution 26.7 ℃ in about 0.5rpm balance one minute, wherein take the reading at 0.5rpm.

The test of minimal viscosity boundary

All absorption bases that use in following method of testing all have the thickness of about 6mm to about 10mm.For BBA Fiberweb Tenotex P101 and Freudenberg AL 1060 absorption bases, by realizing required thickness by being placed on the absorption base that each lip-deep diameter is not more than the circular droplet hot-melt adhesive laminated multilayer sheet of about 2mm.Periphery at absorption base carries out lamination.

With planchet (the surface area 10.0cm of absorption base cutting into about the 3.57cm diameter ²), weigh and be placed on about 80cm ³Pyrex Buchner funnel (derives from Fisher; On the porous glass disk of 4cm diameter code name FPJ-400-110D).Will 956 solution carefully are added on the absorption base degree of depth to about 1cm, inflate and be used for forcing the fluid in the absorption base about 1 minute for hand bellow (being connected with single hole rubber stopper of suitable funnel opening) afterwards.From funnel, carefully remove the absorption base of loading like this with tweezers.Remove unnecessary surfactant fluid by following steps: with two-layer laboratory tissue paper be placed on experimental bench top go up and carefully make loading absorption base (operating) with tweezers on thin paper through the distance of about 30cm, absorption base and another side repeated then overturns.On the flat sides of the circular test board (making) of weighing the absorption base that loads and being fixed to about 4.97cm diameter by the 3M two-sided tape between two parties by white rigidity acetal.With three fixing relative plates of the brass bearing pin of suitably selecting, absorbent is compressed about 3mm when making when the surperficial parallel of two plates and by vertical compression.Is about 3mm for BBA FiberwebTenotex P101 and Libeltex 01-766DI-8 with the height setting of brass bearing pin, and should highly be about 7mm for Recticel Bulpren S28280.The plate that will comprise the brass bearing pin is put the jail above weighing pan, make its surface perpendicular to the cavity of experimental bench and the 4th bearing pin on extreme lower position perpendicular to top brass bearing pin.Be close to about 1 minute of the plate that bearing pin plate vertical compression comprises absorption base then.Write down weighing pan and any Hiar treatment compositions that drips or The weight of 956 solution calculates the whole percentages that add carrying object that ooze between compression period.Repeat this measurement three times for each experiment.

The minimal viscosity boundary is determined: the consumer participates in research

Libeltex 01-766DI-8 absorption base is cut into planchet (the surface area 10.0cm of two about 3.57cm diameters ²), apparatus has an appointment 1 as mentioned above then, 000cPs, about 2,500cPs or about 5, the viscosity of 000cPs

956 solution load.By the 3M two-sided tape Libeltex01-766DI-8 absorption base that loads is fixed on two plates that hinge between two parties.Give the mean for applying of participant's preparation like this and require them to brush people's hair (the Caucasion Light Brown-International Hair Imports and Products that smears twice about 30.5cm of the about 0.75g length of a branch of weight, Valhalla, NewYork).Estimate its performance with following problem: " consider the sample that you had just used, how you will evaluate its dirty and messy grade? " answer classified on 0 to 8 scale, and (0=is dirty and messy not at all; 8=is very dirty and messy).

The test of minimum intermediate value pore radius boundary

Absorption base sample (BBA Fiberweb Tenotex P101, Freudenberg AL 1060, Libeltex 01-766DI-8, PGI FB-215 and Recticel Bulpren S28280) is cut into planchet (the about 5.03cm of surface area of 2.53cm diameter ²), weigh and be placed on 30cm ³On the fritted glass filter disk in the Duran filter assembly (Duran is with reference to 24.720/24).Then the Viton ring is placed on and makes on the absorption base that the absorbent that exposes has diameter (about 2.54cm of about 1.8cm ²).Duran filter assemblies and avoid the absorbent disturbance to use in the connection by slowly adding along glass-beaded side

956 solution are filled to the degree of depth of about 1cm.To be more then

956 solution are poured in the beading up to 30cm ³Calibration.After about 5 minutes, separate remaining fluid and remove absorption base with tweezers.By making absorption base distance through about 30cm on each face of two-layer laboratory tissue paper remove any unnecessary surfactant fluid carefully.Based on absorption base (the about 2.54cm of surface area that exposes ²) the following calculating heap(ed) capacity of weight (

Gram number/gram the absorption base of 956 solution) and report to two decimal places:

Wherein AS is meant absorption base.

The test of peak viscosity boundary

Recticel Pottscorer 410 and Recticel Bulpren S28280 foam are cut into two 3.57cm diameter (surface area 10.0cm ²) planchet and with 100,000cPs's

956 solution load, as described in the determining of minimal viscosity boundary method of testing.The pad that will load by the 3M two-sided tape is fixed on the flat sides of test board of two 4.97cm diameters between two parties then.A plate is installed and is put the jail on hold-down support with three 12mm bearing pins, wherein the surface of Recticel Pottscorer 410 foams of Jia Zaiing is in extreme lower position perpendicular to experimental bench and the 4th bearing pin cavity.The hair of a branch of 0.75g of vertical compression between the Recticel Pottscorer 410 on the bearing pin plate and the Recticel Bulpren S28280 foam and second parallel-plate (length 30.5cm is fan-shaped to scatter to the width of 3cm).Brush is smeared the whole length of the twice feasible cost of hair process in three seconds topknot between compression foam.Repeat this process for the second and the 3rd different topknots.Aforesaid each experiment triplicate.Write down the weight of topknot and the result is calculated as every gram hair deposited

The gram number of 956 solution.

12. embodiment

Several intramatrical several exemplary Hiar treatment compositions of one or more exemplary absorbent that are used to be attached to are described below.The absorption base of following examples can randomly be adhered on the mean for applying.Preferably, absorption base is installed to two of connecting together and has about 12.5cm with hinge ²On the injection molded polypropylene plate of surface area, wherein absorption base faces with each other.

Embodiment A: use peroxide and basifier composition to carry out hair and choose and dye via absorption base

(derive from Libeltex, the 01-766 DI-8 of Belgium from the high fluffy cotton-shaped matrix of nonwoven filament of polyester of every square metre of about 150 gram; Derive from PGI, the FB-215 of New Jersey) go up to downcut the disk of two about 12.5cm2.In this embodiment, also can use polyurethane sponge (deriving from RecticelInternational, the Bulpren S28280 of Belgium).

Peroxide compositions (1)%w/w Basifier composition (2)%w/w

Deionized water in right amount to 100% deionized water in right amount to 100%

Glycerine 5.00 ammonium hydroxide (30% active material) 0.00

Hydrogen peroxide

(35% active material) 17.20 carbonic hydroammonium (100% active material) 20.0

Disodium ethylene diamine tetraacetate 0.04

956 1.80

956 2.25 pH values 8.80

NaOH

In right amount to pH2.9

(50% aqueous solution)

Viscosity 15,400cPs viscosity 8,100cPs

Composition (1) and (2) mixed viscosity=24,000cPs

By slowly manually adding or being used to prepare peroxide compositions (1) in the hydration of rapid mixing water by the similar device that uses injector or be used for the fast hydrating powder

956 up to homogenization.This embodiment will

956 clearly are reported as the thickener that is used for peroxide compositions (1) and basifier composition (2), but also have been susceptible to other thickener.Then, under stirring, appropriateness adds hydrogen peroxide, to avoid introducing excessive bubble in the system.Then, suitably Dropwise 5 0% NaOH is adjusted to indicated value with pH.Randomly, can add other peroxide stabiliser such as sodium stannate further to reduce the possibility of peroxide premature decomposition.In case prepared peroxide compositions (1), just measured viscosity according to method of testing mentioned above.

By slowly manually adding or by using injector or being used for the similar device of fast hydrating powder, by hydration in rapid mixing water

956 produce basifier composition (2).When

956 disperse fully and homogenization after, under appropriateness stirs, add ammonium hydroxide or carbonic hydroammonium to avoid carrying secretly excessive bubble.Along with the adding of basifier, this batch of material is with thickening and become limpid.In case prepared basifier composition (2), just measured viscosity according to method of testing mentioned above.

About 4 gram peroxide compositions (1) are loaded in one of two absorption base sheets and will about 4 restrain basifier compositions (2) and be loaded in another absorption base sheet.Load composition by on the absorption base surface, evenly using with pipette or syringe.With pipette or syringe mechanical compression gently, absorb the integrality of not sacrificing absorption base in the matrix fully to guarantee most of composition.

Plate is forced together two to ten times, so that extruding absorption base and abundant mixed peroxides composition (1) and basifier composition (2).

In case be ready to hair treatment application system, just handle hair with it according to hair treating agent test described below.With tuft approved for distribution is compared, so the hair of handling is visually more shallow.

The hair treating agent test

Bundle an end of topknot and further cement and prepare hair (the Caucasion Light Brown-International Hair Imports and Products that a tuft is about 30.5cm and heavily about 0.8 people who restrains by sending out terminal about 2cm place at bullet with the electrical adhesive tape bar of 3cm with the plasticity hawser, Valhalla, New York).This lock of hair is suspended on the stainless steel slotted bracket.Sending out the top of tuft with the hair treatment application system contact then is between two absorption bases that are connected on the plate so that send out tuft.Then, keep two plates and put the pulling hair treatment application system up to the end of sending out tuft.Can repeat this again uses.Then, send out tuft between about 0.3 to the gained of Hiar treatment compositions between about 0.8 gram and be placed on the weighing pan, and be housed in about 30 ℃ baking oven about 30 minutes having deposited on it.The water flushing is sent out tuft and is made its drying then.

Embodiment B: use peroxide and oxidation dyeing composition to carry out hair and via absorption base Look is chosen and is dyed

Described in top embodiment A, prepare absorption base.

Peroxide compositions (3)%w/w oxidation dye+basifier composition (4) %w/w

In right amount extremely

Deionized water is in right amount to 100% deionized water

100％

Glycerine 5.00 monoethanolamines 4.00

Hydrogen peroxide (35% active material) 17.20 propane diols 5.00

Disodium ethylene diamine tetraacetate 0.04

956 1.00

956 1.00 glycerine 5.00

NaOH

In right amount to pH3.5 sodium sulfite 0.30

(50% aqueous solution)

Viscosity 10,500cPs ethylenediamine tetra-acetic acid 0.10

Arabo-ascorbic acid 0.40

1-naphthols 0.10

Para-aminophenol 0.85

1-hydroxyl-4,5-diamino-pyrazole sulfate 0.30

Phenyl Methyl Pyrazolone 98Min 0.20

2-methyl-5-hydroxyethyl

1.50

Amino-phenol

PH value 10.0

Viscosity 6,800cPs

Composition (3) and (4) mixed viscosity=17,100cPs

Can be by mixing

956 and glycerine and be stirred to and obtain the homogenization slurries and produce peroxide compositions (3).The deionized water size of packing into is enough to comprise by the gross in the single container of material.Slowly guide in the water slurries and mixing under appropriateness stirs, up to observing stable homogenization composition.Under stirring, appropriateness adds hydrogen peroxide then, in order to avoid introduce excessive bubble in the system.Then, dropping sodium is so that pH increases to about 3.5.Randomly, can add other peroxide stabiliser such as sodium stannate, further to reduce the possibility of peroxide premature decomposition.

956 produce oxidation dye and basifier composition (4).

956 disperse fully and homogenization after, add all residual components (being glycerine, dyestuff former, pH buffer and antioxidant) except that monoethanolamine.In case their dissolvings just add monoethanolamine to avoid carrying secretly excessive bubble under appropriateness stirs.Along with the adding of basifier, this batch of material is with thickening and become limpid.Described in the hair treating agent test, handle a tuft as top.When tuft approved for distribution is compared, vision determines that shallow coppery transfers on handled tuft.

Embodiment C: use persulfate and peroxide compositions to carry out hair and choose via absorption base Dye

Described in top embodiment A, prepare absorption base.

About 6 gram peroxide compositions (3) are mixed with scraper in weighing pan with about 4 gram persulfate powder (5).About 4 gram gained mixtures are loaded in each absorption base and as toply send out a tuft handling described in the hair treating agent test.

Persulfate powder (5)%w/w

Ammonium persulfate 28.6

Potassium peroxydisulfate 50.0

Sodium peroxydisulfate 7.1

Sodium metasilicate 14.3

Composition (3) and (5) mixed viscosity=6,000cPs

Prepare peroxide compositions (3) as mentioned described in the Embodiment B.Produce the persulfate powder by in suitable blending equipment such as vee-blender, doing mixed all the components with any order.Composition should be mixed to homogeneous.Then, with the persulfate powder and peroxide compositions (3) premixed that so form.Mixing can be carried out in bottle, bowl or dish, wherein by shaking or stirring each composition is mixed.Resulting composition is loaded in the absorption base, is administered on the hair then.

This hair is chosen and is dyed composition high-caliber decolorizing effect can be provided at short notice.Gained is sent out tuft and has been experienced remarkable bleaching with tuft approved for distribution is compared, as determining on Minolta Spectograph.

Embodiment D: use direct dyes composition or peroxide compositions and oxidation dye via suction Receive matrix and carry out the root of hair modification

From the high fluffy cotton-shaped matrix of nonwoven filament of polyester (deriving from Libeltex, the 01-766DI-8 of Belgium) of every square metre of about 150 gram of a volume, cut next square (about 25cm ²).Absorbent block is adhered to the center of the thick clean polyethylene film of the 1mm of about 6 x 6cm with 3M two sides adhesive tape.Use pipette or syringe that about 7.5 gram direct dyes compositions (6) are loaded in the absorption base (every square metre of absorption base 3,000 gram direct dyes compositions (6)) on the weighing pan.On the absorption base surface, evenly use direct dyes composition (6) with pipette or syringe with slight mechanical pressure, be drawn onto in the matrix fully to guarantee most of direct dyes composition (6).Then, with the finger contact polyethylene face of band gloves and the absorption base face is rubbed into and passes the root of hair line loading absorption base that gained adheres on the polyethylene film is rubbed in the root of hair line of manikin head (deriving from Salons Direct (Pro-hair)).Make gained manikin head static 30 minutes, and washed and use the shampoo rinsing then.It is painted that the root of hair line of manikin head has experienced light brown.

Direct dyes composition (6) %w/w

Deionized water is in right amount to 100%

Yellow No. 2 0.20 of HC

Disperse black 9 0.05

Red No. 3 0.15 of HC

Disperse violet 1 0.05

Arabo-ascorbic acid 0.03

Citric acid 0.5

Monoethanolamine 2.5

?956 0.83

HC orange No. 1 0.1

PH value 10.1

Viscosity 12,100cPs

Can modify by adopting above-mentioned definite program to finish root of hair, but the about 4 gram peroxide compositions (3) of premix described in the Embodiment B and about 4 restrain oxidation dye and basifier compositions (4) as mentioned with oxidation dye.As mentioned above, the gained mixture with about 7.5 gram amounts is loaded in the absorption base.Resulting composition is administered on the head of aforesaid manikin at root of hair line place.After removing composition, it is painted to observe light brown.

Have as other Hiar treatment compositions of the selected viscosity of this paper and the non-limiting additional embodiment of cosmetic composition and be shown in hereinafter.

Embodiment E: shampoo Compositions %w/w

Deionized water is in right amount to 100%

Sodium laureth sulfate 12.0

Cocoamidopropyl 3.0

Viscosity 3,750cPs

Embodiment F: conditioner shampoo %w/w

Deionized water is in right amount to 100%

Laureth ammonium sulfate 10.00

Ammonium lauryl sulfate 6.00

Coconut oleoyl amine MEA 0.80

Cetanol 0.90

Glycol distearate 1.50

Dimethyl silicone polymer (Viscasil 330,000) 1.35

Polyquaternium-10 (LR30M) 0.50

Polyox?PEG7M 0.10

Puresyn 6 (1-decene homopolymers) 0.30

Spices 0.50

Citric acid 0.04

Two hydration natrium citricums 0.40

Disodium ethylene diamine tetraacetate 0.10

Kathon (0.5% active material) 0.01

Sodium Benzoate 0.25

Sodium chloride is in right amount to 8,000cPs

Ammonium xylene sulfonate is in right amount to 8,000cPs

Viscosity 8,000cPs

Embodiment G: conditioner %w/w

Deionized water is in right amount to 100%

Cetanol ^*1 1.0

Stearyl alcohol ^*2 0.6

The amino propyl group dimethylamine of stearoyl ^*3 1.0

1-oxygen-2-mercaptopyridine zinc ^*4 2.0

Benzylalcohol 0.4

Phenoxetol 0.3

Methyl p-hydroxybenzoate 0.2

Propylparaben 0.1

Hydroxyethylcellulose 0.3

PEG-2M 0.5

Emulsifying wax 0.5

Spices 0.4

Citric acid is in right amount to pH6

Viscosity 11,500cPs

^*1 cetanol: Konol series derives from Shin Nihon Rika.

^*2 stearyl alcohols: Konol series derives from Shin Nihon Rika.

^*The amino propyl group dimethylamine of 3 stearoyls: SAPDMA derives from Inolex.

^*4 1-oxygen-2-mercaptopyridine zinc: 1-oxygen-2-mercaptopyridine zinc U/2 derives from Olin

Embodiment H: Hairsetting compositions %w/w

Deionized water is in right amount to 100%

Esters of acrylic acid/docosyl alcohol polyethers-25 methyl acrylate copolymer 2.5

NATRASOL250 0.6

Benzylalcohol 0.5

Acrylate copolymer 0.4

Polyquaternium 4 1.4

Laureth 23 (polyoxyethylene (23) lauryl+1.6

Viscosity 57,500cPs

Dimension disclosed herein and value are not intended to be understood that strictly to be limited to described exact value.On the contrary, except as otherwise noted, each such dimension is meant the numerical value of being quoted and centers on the scope that is equal on the function of this numerical value.For example, the dimension that is disclosed as " 40mm " is intended to expression " about 40mm ".

Claims

1. hair treatment application system, described system comprises:

A) at least a or multiple have 3,000cPs to 150, the Hiar treatment compositions of the viscosity of 000cPs (15) and

B) hair treatment applicator (1), described device be included in described hair treatment applicator (1) can juxtaposition relationship when being in closure state first plate (10) and second plate (20) of location, wherein said first plate (10) and second plate (20) are bound up via connector (30), and wherein said first plate (10) and second plate (20) respectively have inner surface (101; 201) and outer surface (102; 202) and described first plate (10) and second plate (20) respectively have periphery edge (103; 203),

It is characterized in that,

At least described first plate (10) has first area and second area (50) at least at least on described inner surface (101), wherein said first area at least comprises at least a absorption base (40), wherein said at least a absorption base (40) has 300 microns to 3,000 micron intermediate value pore radius, and wherein said second area at least (50) does not contain described absorption base (40).

2. system as claimed in claim 1, the contiguous described first area of the described second area at least (50) of the described inner surface (101) of wherein said first plate (10).

3. system as claimed in claim 1, the contiguous described first area of the described second area at least (50) of the described inner surface (101) of wherein said first plate (10) and comprise and be selected from following material: porous compressible material, porous incompressible material, atresia compressible material, atresia incompressible material, at least one pointed tooth, at least one bristle and their combination.

4. the described system of each claim as described above, at least a portion of wherein said first plate (10) comprises depression, preferably the concave recess that forms in described first plate (10).

5. the described system of each claim as described above, at least a portion of wherein said first plate (10) forms cavity, preferably concave surface cavity.

6. the described system of each claim as described above, wherein said at least a absorption base (40) extends upward as being with continuously along described periphery edge (103) extension of described at least the first plate (10) and from described inner surface (101), and wherein said continuous band is gone up the zone that qualification can load described Hiar treatment compositions (15) at the described inner surface (101) of described first plate (10).

7. the described system of each claim as described above, wherein said at least a absorption base (40) comprises inner surface, outer surface and the side of the described inner surface (101) of described first plate of direct contact (10), and at least a portion of the described side of wherein said at least a absorption base (40) comprises impervious barrier film (105).

8. the described system of each claim as described above, wherein said at least the first plate (10) locates to comprise continuous or discrete non-pored wood strip at described periphery edge (103), to make described first plate (10) and described second plate (20) wipe the Hiar treatment compositions (15) of excess deposition when becoming juxtaposition relationship.

9. the described system of each claim as described above, wherein said connector (30) is a hinge.

10. method of handling hair, described method comprise use as in the claim 1 to 9 each described as described in the step of hair treatment application system contact hair.

11. method as claimed in claim 10 wherein before contacting hair with described hair treatment application system, is loaded into described at least a or multiple Hiar treatment compositions (15) on the described hair treatment applicator (1).

12. as each described method in claim 10 or 11, wherein said one or more Hiar treatment compositions (15) comprise first and second Hiar treatment compositions, and wherein mix described first and second Hiar treatment compositions to form the 3rd Hiar treatment compositions, and wherein before contacting hair, described the 3rd Hiar treatment compositions (15) is loaded on the described hair treatment applicator (1) with described hair treatment application system.

13. method as claimed in claim 12, wherein said first Hiar treatment compositions comprises oxidant, and described second Hiar treatment compositions comprises basifier.

14. method as claimed in claim 13, wherein said first or second composition comprises persulfate.

15. as each described method in the claim 10 to 14, wherein before contacting hair with described hair treatment application system, make described first plate (10) become juxtaposition relationship once with second plate (20), preferably twice is more preferably more than twice.

16. a cover box, described cover box comprises that at least one is as each described hair treatment application system (1) in the claim 1 to 10.

17. cover box as claimed in claim 15, wherein said cover box comprises a plurality of described hair treatment applicators (1).

18. as each described cover box in claim 15 or 16, wherein said cover box also comprises one or more Hiar treatment compositions of packing separately, and described composition comprises shampoo Compositions, care composition, Hairstyling composition, hair colourant compositions, bleaching hair composition, chooses and dye composition or their combination.

19. as each described cover box in the claim 16 to 18, wherein said cover box comprises the Hiar treatment compositions that comprises oxidant and the independent Hiar treatment compositions of packing that comprises basifier of packing at least separately.

20. cover box as claimed in claim 19, at least a persulfate that comprises in the Hiar treatment compositions of wherein said independent packing.

21. as each described external member in the claim 16 to 20, wherein said external member comprises also how consumption guidance person loads and/or use the explanation of described hair treatment applicator (1).