CN101519508A - Diffusion scattering transmission safe glass and preparation method thereof - Google Patents
Diffusion scattering transmission safe glass and preparation method thereof Download PDFInfo
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- CN101519508A CN101519508A CN200810007571A CN200810007571A CN101519508A CN 101519508 A CN101519508 A CN 101519508A CN 200810007571 A CN200810007571 A CN 200810007571A CN 200810007571 A CN200810007571 A CN 200810007571A CN 101519508 A CN101519508 A CN 101519508A
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Abstract
A diffusion scattering transmission safe glass comprises transparent organic resin, transparent SiO2 granules or transparent inorganic glass granules and additives. The ball-shaped transparent SiO2 granules or ball-shaped transparent inorganic glass granules or ball-shaped transparent organic resin granules are equally distributed inside the transparent organic resin glass.
Description
Invention field:
The present invention relates to glasswork, particularly the glasswork made from the printing opacity organic materials.
Background technology:
Chinese patent ZL200510017125.6 " heat-resistant, high strength synthetic glass light-scattering material and preparation method thereof " discloses following content: with methyl-prop diluted acid formicester 70-85%, methyl-prop diluted acid 10-25% Diisopropyl azodicarboxylate 1.5-3%, nanometer SiO2 particle 2-3.5% mixes, make extremely preparation method of synthetic glass light-scattering material, this invention and difference of the present invention are: 1, only relate to pmma material of methyl-prop diluted acid formicester and methyl-prop diluted acid and Diisopropyl azodicarboxylate mixed solution manufacturing and preparation method thereof, do not relate to the manufacture method of making glasswork and glasswork.2, do not relate to nanometer SiO2 particulate form, and SiO2 particulate form is directly connected to the path and the dispersion effect of scattering of light, for example: spherical sio2 particulate incident light and reflected light are to carry out along sphere, has definite reflection direction, be the controllable light reflection, the transparency height, and many ribs type SiO2 particulate incident light and reflected light do not have definite reflection direction, be uncontrollable luminous reflectance, transparency is low.3, nanometer SiO2 particle add-on is 2-3.5%, and 2-3.5% nanometer SiO2 particle is very little to improving the influence of synthetic glass shock resistance.4, material is placed for a long time, is easy to generate nanometer SiO2 particle layering and skewness phenomenon in the synthetic glass resin.5, do not relate to spherical transparent organic resin particulate material.5, do not relate in the synthetic glass resin and to add the improvement problem of functional attached material the synthetic glass resin property.6, do not relate to the light-accumulating luminous material of adding in spherical transparent grain.
Summary of the invention:
The objective of the invention is: 1, the spherical transparent SiO of uniform distribution in the transparent organic resin glass
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle; making incident light and reflected light is the diffuse scattering of carrying out light along the particle sphere; improve organic transparent glass transparency, solve the light pollution problem of existing glass because of direct projection light generation time shadow problem and light reflection generation.2, by the spherical transparent SiO of uniform distribution in transparent organic resin glass
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle improve the glass shock resistance, sound insulation property, heat-insulating property, anti-cracking performance.3, by the functional attached material of interpolation in transparent organic resin glass or in transparent organic resin glass surface plated film or pad pasting or spray material method, improve transparent organic resin glass sunlight control characteristics, ultraviolet resistance, anti-infrared performance, pollution-proof performance, sterilizing function, the photoelectricity fluorescence property.4, pass through at the transparent SiO of sphere
2Add light-accumulating luminous material in particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle, strengthen the brightness of light-accumulating luminous glass, realize that bulk glass is luminous.5, has different performance, the transparent organic resin glass of different characteristics by changing the kind of transparent organic resin, producing.6, by the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or spherical transparent organic resin particle are mixed with the transparent organic resin particle; pressurization; the mode of heat fused; it is different because of proportion with the transparent organic resin particle to solve spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle; surface energy is different and produce skewness, the problem that shelf time is short.7, by mixing with being sprayed onto in the transparent organic resin aerosol particles after the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or the heating of spherical transparent organic resin particle; after the sorting; secondary mixes; pressurization; the mode of heat fused; solve spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle and transparent organic resin skewness problem, improve organic transparent safety glass diffusion scattering transmission effect.8, by being joined in the transparent organic resin liquid, the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or spherical transparent organic resin particle evenly stir; spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin uniform particles are distributed in the transparent organic resin liquid; simplify organic transparent glass manufacturing process, reduce cost.9, handle by diffusion scattering transmission safe glass being carried out the constant temperature homogenizing, solve the glass strain problem on deformation.
The diffusion scattering transmission safe glass that the present invention proposes comprises: transparent organic resin, spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle, attached material, the spherical transparent SiO of uniform distribution in the transparent organic resin glass
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle, spherical transparent SiO
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particulate add-on require according to product performance and use the different of transparent organic resin, are controlled between the transparent organic resin weight ratio 2%-90% spherical transparent SiO
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particulate particle size diameter are the 5nm-60 order; wherein: 5nm-0.1 μ m is a nano-scale particle; 0.1-1 μ m super-fine powder grade particles; when adopting nano-scale particle or adopting the super-fine powder grade particles; light can be walked around spherical transparent grain, does not influence the transparence of light-storable self luminous transparent film.
Organic transparent glass resin and spherical transparent organic resin particle can be the identical type resin materials, different temperature of fusion, also can be the different sorts resin material, different temperature of fusion, spherical transparent organic resin particulate temperature of fusion is higher than organic transparent glass resin temperature.
Less demanding in transparency, under the low situation of cost requirement, can substitute spherical transparent SiO with the transparent SiO2 particle of many ribs
2Particle substitutes spherical transparent inorganic glass particle with many ribs transparent inorganic glass particle.
Less demanding in transparency, under the demanding situation of shock resistance, can be with transparent SiO2 silk or organic resin fiber yarn as carbon fiber, assorted fibre, substitute spherical transparent SiO2 particle, or, make organic transparent anti-bomb glass with the alternative spherical transparent inorganic glass particle of transparent inorganic glass silk.
Transparent organic resin comprises: any in PMMA, transparent PP, PC, PET, PETG, PVB, PSF (polysulfones), MMA (fluorinated polyimide), poly-fragrant fat, polyarylsulphone, the transparent anti-impact resin of butylbenzene, organosilicon transparent resin, ADC (allyl diglycol carbonates), PEN (PEN), Resins, epoxy, bulk alicyclic polyene resin or the PC-PMMA blend transparent resin.
In diffusion scattering transmission safe glass, add attached material and can give the glass property.Nonmetal attached material package is drawn together: TiO
2, ZnO, Cu
2O, CuO, CdO, Co
2O
3, Ni
2O
3, MnO
2, AgCl, iron protoxide, dichromate, ferric oxide, tin indium oxide, europium sesquioxide, yttrium oxide, terbium sesquioxide, cerium oxide, rare earth, magnetic particle, fluorescent grain, silicon solar material, coupling agent or stopper.TiO is added on the diffusion scattering transmission safe glass top layer
2Have bacteriostasis antibiosis, gas pollutant formaldehyde, toluene function in the decontamination chamber, anti-glass pollutes function, function of shielding ultraviolet radiation.Add ZnO and have function of shielding ultraviolet radiation.Add Cu
2O makes glass have redness.Adding CuO makes glass have blue-greenish colour.It is light yellow that interpolation CdO has glass.Add Co
2O
3Make glass have blueness.Add Ni
2O
3It is blackish green that glass is had.Add MnO
2Make glass have purple.Adding AgCl makes glass have light sensitive characteristic.Add iron protoxide and absorb infrared rays and part visible light, add dichromate, ferric oxide absorbs ultraviolet ray and part visible light, adds europium sesquioxide, yttrium oxide, terbium sesquioxide, cerium oxide, makes glass have the characteristics of luminescence.The interpolation rare earth is made photo chromic glass, interpolation magnetic particle makes glass have magnetic, manufactures magnetic glass.Add fluorescent grain, manufacture fluorescent glass.Add the silicon solar material; as: mono-crystalline silicon solar particle, polycrystalline silicon solar particle, non-crystal silicon solar energy granule manufacture become photoelectric glass, add coupling agent spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle and transparent organic resin are better merged.Adding stopper does not reunite spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle.
The attached material package of metal is drawn together: metal and metallic compound thereof, as: the metallic compound of gold and silver, copper, tin, platinum, titanium, magnesium, chromium or stainless steel and metal and other element.
Add extremely metallic compound of titanium, magnesium, chromium or stainless steel, making has suitable transmissivity to visible light, and infrared rays is had higher reflectivity, ultraviolet ray is had the organic transparent glass of heat reflection of higher absorption rate.
Add gold and silver, copper, tin, its metallic compound of platinode, making has high transmittance to visible light, and infrared rays is had very high reflectivity, has the organic transparent glass of low radiation of good heat-proof quality.
Add silver ions, make organic transparent glass with good bactericidal properties.
In special purpose glass, the spherical transparent SiO of uniform distribution in the transparent organic resin glass
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle substitute with attached material, as: magnetization glass, antimagnetic glass, fluorescent glass, photoelectric glass, conductive glass.
At the spherical transparent SiO of uniform distribution
2Add light-accumulating luminous material in particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particulate transparent organic resin glass, make the organic transparent light-accumulating luminous glass of the full light of diffuse scattering.Light-accumulating luminous material comprises: the light-accumulating luminous particle of rare earth aluminate, as: glow color is that hepatic europium, neodymium activate CaAl2O4:Eu, Nb particle, glaucous europium, activated by dysprosium Sr4Al14O25:Eu, the Dy particle, yellowish green europium, activated by dysprosium SrAl2O4:Eu, Dy particle.The light-accumulating luminous particle of silicate systems, as: the pyrosilicate blue-light-emitting particle of europium, activated by dysprosium, europium, neodymium activated aluminate blue-light-emitting particle, the white luminous particle of the orthosilicate of magnesium activated.The light-accumulating luminous type light-emitting particles of sulfide, as: yellowish green ZnS:Cu series particle, blue CaS:Bi series particle, red CaS:Eu series particle.
The characteristics of the organic transparent light-accumulating luminous glass of the full light of diffuse scattering are: after light-accumulating luminous material is initiatively inhaled visible light 5-10min such as holding sunlight, light, UV-light, stray light, just can continue in the dark more than the luminous 12h, adopt different light-accumulating luminous materials, can send multiple coloramas such as red, green, blue, Huang, purple.Light-accumulating luminous material excites luminous energy by absorption, and store, after optical excitation stops, the luminescent material that energy stored is come out with the form slow release of light again, because the light-accumulating luminous material of granular particles is a twinkler, light is by putting to emission everywhere, in organic transparent light-accumulating luminous glass, add light-accumulating luminous material for a long time, glass is opaque, adds light-accumulating luminous material after a little while, and the some luminous source in the glass is high-visible, influence the outward appearance of transparent light-accumulating luminous glass, the spherical transparent SiO of uniform distribution in the transparent organic resin glass
2When particle or spherical transparent inorganic glass particle and light-accumulating luminous material; the problems referred to above just can be well solved; when light-accumulating luminous material is a twinkler; light is by putting when launching everywhere; light runs into spherical transparent grain; part light sees through spherical transparent grain; part light reflects on spherical transparent grain surface; because spherical transparent grain can carry out multi-faceted refraction; adjacent spherical transparent grain birefringence light carries out birefringence; and a plurality of light-accumulating luminous materials light source light or the refracted light mutual superposition sent, making the organic transparent light-accumulating luminous glass whole body uniform illuminating of the full light of diffuse scattering, luminance brightness increases.Another advantage of transparent light-accumulating luminous glass is: efficiency of light energy utilization height.
The another kind of method that improves the diffusion scattering transmission safe glass property is at transparent organic resin glass surface plated film or pad pasting or spray material.As: at glass surface plating LOW-E film or plating solar control film, paste the look film, spray TiO
2Coating, spray silver ions coating.
The another kind of method that improves the diffusion scattering transmission safe glass heat-insulating property is to make double glazing with diffusion scattering transmission safe glass.Further improve insulation, defening effect by the air in the double glazing chamber.
Advantage of the present invention is: 1, the spherical transparent SiO of uniform distribution in the transparent organic resin glass
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle; making incident light and reflected light is the diffuse scattering of carrying out light along the spheroidal particle sphere; improve organic transparent glass transparency, solve the light pollution problem of existing glass because of direct projection light generation time shadow problem and light reflection generation.2, by the spherical transparent SiO of uniform distribution in transparent organic resin glass
2Particle (silk) or spherical transparent inorganic glass particle (silk) or spherical transparent organic resin particle or organic resin fiber yarn improve the glass shock resistance, sound insulation property, heat-insulating property, anti-cracking performance.3, by the functional attached material of interpolation in transparent organic resin glass or in transparent organic resin glass surface plated film or pad pasting or spray material method, improve the sunlight control characteristics of transparent organic resin glass, ultraviolet resistance, anti-infrared performance, pollution-proof performance, sterilizing function, antimagnetic function, conducting function, light-accumulating luminous performance and fluorescence property.4, has different performance, the diffusion scattering transmission transparent organic resin glass of different characteristics by changing transparent organic resin or spherical transparent organic resin particulate kind, producing.
One of manufacture method of diffusion scattering transmission safe glass comprises: transparent organic resin, and transparent SiO2 particle or transparent inorganic glass particle, coupling agent, attached material is with the transparent SiO of sphere
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle and transparent organic resin mix, and are heated to the above 5-100 degree of transparent organic resin temperature of fusion, and transparent organic resin is fused into liquid state and is filled into spherical transparent SiO
2In particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle slit, transparent SiO2 particle or transparent inorganic glass particle and transparent organic resin are combined into one, after the cooling, manufacture diffusion scattering transmission safe glass.
For eliminating the stress that in making the diffusion scattering transmission safe glass process, produces, diffusion scattering transmission safe glass is carried out the constant temperature homogenizing handle.
Two of the manufacture method of diffusion scattering transmission safe glass will have the spherical transparent SiO of coupling agent
2Be sprayed onto in the transparent organic resin aerosol particles after particle or spherical transparent inorganic glass particle or the heating of spherical transparent organic resin particle and mix, transparent organic resin is attached to the transparent SiO of sphere
2On particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle, with the transparent SiO of sphere
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle are combined into one, and after the sorting, will adhere to the spherical transparent SiO of transparent organic resin
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle are packed in shaper or the mould, are heated to the above 5-100 degree of transparent organic resin temperature of fusion, and it is liquid that the transparent organic resin particles fuse becomes, and is filled into spherical transparent SiO
2In particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particulate slit, make spherical transparent SiO
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle and transparent organic resin are combined into one, and after the cooling, manufacture diffusion scattering transmission safe glass.For eliminating the stress that in making the diffusion scattering transmission safe glass process, produces, diffusion scattering transmission safe glass is carried out the constant temperature homogenizing handle.
In method two one or method two, mix with transparent organic resin spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle heating back, the preferred microparticle air stream turbulence that adopts disperses and the surface modification treatment technology, its method is, at first adopt pyritous strong turbulence air-flow that the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or spherical transparent organic resin particle are carried out dispersion treatment, the monodisperse spherical particle is broken up and formed to the coacervate spheroidal particle, then the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or spherical transparent organic resin particle are heated to more than the transparent organic resin temperature of fusion, spherical transparent SiO2 particle that will heat with atomizing nozzle or spherical transparent inorganic glass particle or spherical transparent organic resin particle spray in the transparent organic resin aerosol, make transparent organic resin equably attached to the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or spherical transparent organic resin particle surface, and be combined into one with the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or spherical transparent organic resin particle, coated the spherical transparent SiO2 particle of transparent organic resin or spherical transparent inorganic glass particle or spherical transparent organic resin particle subsequently by the nozzle ejection, it has been cooled off aftertreatment with the mode of injecting gas; The spherical transparent SiO2 particle that coated transparent organic resin or spherical transparent inorganic glass particle or spherical transparent organic resin particle are collected at last, obtained adhering to spherical transparent SiO2 particle or the spherical transparent inorganic glass particle or the spherical transparent organic resin particle of transparent organic resin by rotoclone collector.Usually, the attached material of the metal of commute oxidation adopts the protective gas cooling, as: CO2 gas, rare gas element adopts air cooling to the material that is difficult for oxidation.
In method two one or method two; mix with transparent organic resin spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle heating back; can adopt after the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or the heating of spherical transparent organic resin particle; be sprayed in the transparent organic resin particle end; mechanically mixing; make transparent organic resin particle end equably attached to the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or spherical transparent organic resin particle surface; after the sorting, obtain coating spherical transparent SiO2 particle or the spherical transparent inorganic glass particle or the spherical transparent organic resin particle at transparent organic resin particle end.
Three of the manufacture method of diffusion scattering transmission safe glass; the transparent organic resin heat fused is become liquid; the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or spherical transparent organic resin particle are put into the liquid clear organic resin; after stirring; to have spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particulate transparent organic resin liquid is put into pressing machine or roller press or die for molding; after the cooling, manufacture diffusion scattering transmission safe glass.
For eliminating the stress that in making the diffusion scattering transmission safe glass process, produces, diffusion scattering transmission safe glass is carried out the constant temperature homogenizing handle.
The advantage of the inventive method is: 1, by the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or spherical transparent organic resin particle are mixed with the transparent organic resin particle; pressurization; the mode of heat fused solves spherical transparent SiO2 particle of high temperature or spherical transparent inorganic glass particle or spherical transparent organic resin particle and low-temperature transparent organic resin particulate fusion problem.2, by placing the attached material of mixing of heterogeneity at different positions, solved diffusion scattering transmission safe glass and had the different problems of forming at different sites, as: add TiO at glass surface
2The nano particle manufacturing has the glass of antifouling property.Add the silver nano-grain manufacturing at glass surface and have glass antibacterial, anti-microbial property.Different positions is placed the attached material of heterogeneity, can reduce the consumption of attached material, reduces cost, and produces the new glass kind with specific function.3, by mixing with being sprayed onto in the transparent organic resin aerosol particles after the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or the heating of spherical transparent organic resin particle; after the sorting; secondary mixes; pressurization; the mode of heat fused; solve spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle and transparent organic resin skewness problem, improve organic transparent safety glass diffusion scattering transmission effect.3, by the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or spherical transparent organic resin particle are joined in the transparent organic resin liquid; carry out even stirring method; spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin uniform particles are distributed in the transparent organic resin liquid; simplify the manufacturing process of organic transparent safety glass; improve mechanize and make efficient, reduce cost.4, by in transparent organic resin glass, adding light-accumulating luminous material and spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle; by the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or the refraction of light of spherical transparent organic resin particulate and light diffuse-reflectance and optical superposition; strengthen the brightness of light-accumulating luminous glass, realize that bulk glass is luminous.
Description of drawings:
Below in conjunction with Figure of description and embodiment the present invention is further described.
Fig. 1 is the diffusion scattering transmission safe glass cross-section structure with feature of the present invention.
Fig. 2 is the spherical transparent SiO of Fig. 1
2Single particle light reflection principle synoptic diagram.
Fig. 3 is the spherical transparent SiO of Fig. 1
2Many particles light reflection principle synoptic diagram.
Fig. 4 has the transparent anti-riot glass cross-section structure of feature diffusion scattering transmission of the present invention.
Fig. 5 is the diffusion scattering transmission clear hollow glass cross-section structure with feature of the present invention.
Fig. 6 has feature diffusion scattering transmission transparent dressing film glass cross-section structure of the present invention.
Fig. 7 has the transparent anti-pollution glass cross-section structure of feature diffusion scattering transmission of the present invention.
Fig. 8 has the transparent light-accumulating luminous glass cross-section structure of feature diffuse scattering of the present invention.
Fig. 9 has feature light-accumulating luminous glass pointolite rayed synoptic diagram of the present invention.
Figure 10 is Fig. 9 light-accumulating luminous glass pointolite rayed and spheric reflection optical superposition synoptic diagram.
Embodiment:
Embodiment 1:
A kind of diffusion scattering transmission safe glass cross-section structure as shown in Figure 1, Fig. 2 is the spherical transparent SiO of Fig. 1
2Single particle light reflection principle synoptic diagram, Fig. 3 are the spherical transparent SiO of Fig. 1
2Many particles light reflection principle synoptic diagram, wherein: the 1st, organic resin glass, the 2nd, spherical transparent SiO
2Particle, the 3rd, spherical transparent SiO
2The particle incident light, the 4th, spherical transparent SiO
2The particle reflected light, the 5th, spherical transparent SiO
2Particle sees through light, and the 6th, organic resin glass incident light, the 7th, organic resin glass-reflected light, Fig. 1 show spherical transparent SiO
2Uniform particles is distributed in the transparent organic resin glass, and Fig. 2 shows spherical transparent SiO
2Single particle light reflection principle synoptic diagram, spherical transparent SiO
2 Particle incident light 3 is at the transparent SiO of sphere
2The surface produces luminous reflectance, spherical transparent SiO
2Particle reflected light 4 is in the spheroidal particle angled reflection in surface, and incident light 3 is different with reflected light 4 radiation directions, and Fig. 3 shows the transparent SiO of a plurality of spheries
2The situation of particle luminous reflectance and organic resin glass planar luminous reflectance light because the interference of light and stack make organic resin glass planar light that direct reflected light not take place, solves the shadow pollution problem that produces because of the vertical light reflection.
Embodiment 2:
The organic transparent anti-riot glass cross-section structure of a kind of diffusion scattering transmission as shown in Figure 4, wherein: the 13rd, organic resin glass, the 14th, transparent glass fibre, transparent glass fibre 14 is evenly distributed in the organic resin glass 13, in bomb attacks and accidental explosion incident, transparent glass fibre 14 reduces the direct injury that the glass fragmentation causes to greatest extent, and another effect of transparent glass fibre 14 is by refraction of light, prevents that light from directly passing transparent glass.
Embodiment 3:
The organic clear hollow glass of a kind of diffusion scattering transmission cross-section structure as shown in Figure 5, wherein: the 15th, organic resin glass, the 16th, spherical transparent SiO
2Particle, spherical transparent SiO
2 Particle 16 is evenly distributed in the organic resin glass 15, and the 17th, gas, the 18th, unorganic glass, the 19th, double glazing parting bead, the 20th, siccative, the 21st, seal gum.The spherical transparent SiO of uniform distribution in the organic resin glass 15
2 Particle 16, organic resin glass does not produce direct reflected light, solves the shadow pollution problem that produces because of the vertical light reflection, and the air in the double glazing chamber further improves insulation, defening effect.
Embodiment 4:
The organic transparent dressing film glass of a kind of diffusion scattering transmission cross-section structure, as shown in Figure 6, wherein: the 22nd, organic resin glass, the 23rd, spherical transparent SiO
2Particle, spherical transparent SiO
2Particle 23 is evenly distributed in the organic resin glass 22, and the 24th, the LOW-E film, the effect of LOW-E film 24 is to intercept far infrared radiation, reduce glass combination K value, the thermal radiation in the reflection sun makes in the outdoor solar thermal energy inlet chamber, reduce indoor heat and scatter and disappear, improve the heat-insulating property of glass.The 23rd, spherical transparent SiO
2Particle, spherical transparent SiO
2Particle prevents to pollute because of the shadow that the vertical light reflection produces.
Embodiment 5:
The organic transparent anti-pollution glass cross-section structure of a kind of diffusion scattering transmission, as shown in Figure 7, wherein: the 25th, organic resin glass, the 26th, spherical transparent SiO
2Particle, spherical transparent SiO
2Particle 26 is evenly distributed in the organic resin glass 25, the 27th, the TiO2 particle, the TiO2 uniform particles is distributed in organic resin glass 25 surfaces, the TiO2 particle has decomposition, dispersion and dissolved dirt and other organic residue, and that it is not sticked to is on glass, make rainwater spread over glass surface, and wash away dust, prevent to pollute.Spherical transparent SiO
2Particle prevents the shadow pollution problem because of vertical light reflection generation.
Embodiment 6:
The transparent light-accumulating luminous glass cross-section structure of a kind of diffuse scattering as shown in Figure 8, Fig. 9 is a light-accumulating luminous glass pointolite rayed synoptic diagram, Figure 10 is Fig. 9 light-accumulating luminous glass pointolite rayed and spheric reflection optical superposition synoptic diagram.Wherein: the 28th, organic resin glass, the 29th, comprise light-accumulating luminous particle transparent glass ball, the 30th, light-accumulating luminous particle, the 31st, the transparent glass ball, the 32nd, pointolite light, the 33rd, the sphere incident light, the 34th, spheric reflection light, comprising light-accumulating luminous particle transparent glass ball 29 is evenly distributed in the organic resin glass 28, the pointolite light 32 that light-accumulating luminous particle 30 sends sees through transparent glass ball 31 to the four sides radiation, sphere incident light 33 and spheric reflection light 34 are interfered mutually with pointolite light 32, stack, strengthen the luminosity of light-accumulating luminous particle 30, solve the light pollution problem of existing glass because of direct projection light generation time shadow problem and light reflection generation.Light-accumulating luminous material is initiatively inhaled and is held sunlight, light, UV-light, stray light etc. after visible light 5-10 minute, just can continue luminously more than 12 hours in the dark, is used for building, car, ship, road markings, can bring light at night, save energy.
Claims (10)
1, a kind of diffusion scattering transmission safe glass comprises: transparent organic resin, transparent SiO
2Particle or transparent inorganic glass particle, attached material is characterized in that the spherical transparent SiO of uniform distribution in the transparent organic resin glass
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle.
2, diffusion scattering transmission safe glass as claimed in claim 1; it is characterized in that spherical transparent SiO2 particle substitutes with the transparent SiO2 particle of many ribs or transparent SiO2 silk or organic resin fiber yarn, spherical transparent inorganic glass particle is alternative with many ribs transparent inorganic glass particle or transparent inorganic glass silk.
3, diffusion scattering transmission safe glass as claimed in claim 1 is characterized in that spherical transparent SiO
2Add light-accumulating luminous material in particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle.
4, diffusion scattering transmission safe glass as claimed in claim 1 is characterized in that transparent organic resin glass surface plated film or pad pasting or spray material.
5, diffusion scattering transmission safe glass as claimed in claim 1 is characterized in that attached material package draws together: TiO
2, ZnO, Cu
2O, CuO, CdO, Co
2O
3, Ni
2O
3, MnO
2, AgCl, iron protoxide, dichromate, ferric oxide, europium sesquioxide, yttrium oxide, terbium sesquioxide, cerium oxide, rare earth, magnetic particle, fluorescent grain, coupling agent, stopper, gold and silver, copper, tin, platinum, titanium, magnesium, chromium, stainless steel, above-mentioned element metallic compound or silicon solar material.
6, diffusion scattering transmission safe glass as claimed in claim 1 is characterized in that the spherical transparent SiO of uniform distribution in the transparent organic resin glass
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle substitute with attached material.
7, diffusion scattering transmission safe glass as claimed in claim 1 is characterized in that transparent organic resin comprises: PMMA, transparent PP, PC, PET, PETG, PVB, PSF, MMA (fluorinated polyimide), poly-fragrant fat, polyarylsulphone, the transparent anti-impact resin of butylbenzene, organosilicon transparent resin, ADC (allyl diglycol carbonates), PEN (PEN), Resins, epoxy, bulk alicyclic polyene resin or PC-PMMA blend transparent resin.
8, a kind of manufacture method of diffusion scattering transmission safe glass: comprising: transparent organic resin, transparent SiO2 particle or transparent inorganic glass particle, coupling agent, attached material is characterized in that the transparent SiO of sphere
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle and transparent organic resin mix, and are heated to the above 5-100 degree of transparent organic resin temperature of fusion, and transparent organic resin is fused into liquid state and is filled into spherical transparent SiO
2In particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle slit, transparent SiO2 particle or transparent inorganic glass particle and transparent organic resin are combined into one, after the cooling, manufacture diffusion scattering transmission safe glass.
9, method as claimed in claim 7 is characterized in that and will have the spherical transparent SiO of coupling agent
2Be sprayed onto in the transparent organic resin aerosol particles after particle or spherical transparent inorganic glass particle or the heating of spherical transparent organic resin particle and mix, transparent organic resin is attached to the transparent SiO of sphere
2On particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle, with the transparent SiO of sphere
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle are combined into one, and after the sorting, will adhere to the spherical transparent SiO of transparent organic resin
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle are packed in shaper or the mould, are heated to the above 5-100 degree of transparent organic resin temperature of fusion, and it is liquid that the transparent organic resin particles fuse becomes, and is filled into spherical transparent SiO
2In particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particulate slit, make spherical transparent SiO
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle and transparent organic resin are combined into one, and after the cooling, manufacture diffusion scattering transmission safe glass.
10, method as claimed in claim 7 is characterized in that the transparent organic resin heat fused is become liquid, with the transparent SiO of sphere
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle are put into the liquid clear organic resin, after stirring, will have spherical transparent SiO
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin particulate transparent organic resin liquid are put into pressing machine or roller press or die for molding, after the cooling, manufacture diffusion scattering transmission safe glass.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102489065A (en) * | 2011-12-14 | 2012-06-13 | 贵州瓮福蓝天氟化工股份有限公司 | Filter |
| CN102676053A (en) * | 2012-05-31 | 2012-09-19 | 慈溪市国兴电子有限公司 | Transmitting coating for turning transparent glass into ground glass |
| CN104650518A (en) * | 2015-03-09 | 2015-05-27 | 江苏亚太新能源科技有限公司 | Transparent bullet-proof material |
| CN108269871A (en) * | 2016-12-29 | 2018-07-10 | Ls 产电株式会社 | For the protective glass and its manufacturing method of solar battery module |
| CN108467568A (en) * | 2018-02-27 | 2018-08-31 | 榛硕（武汉）智能科技有限公司 | A kind of organosilicon epoxy resin composite material and preparation method |
| CN108467568B (en) * | 2018-02-27 | 2021-03-23 | 榛硕（武汉）智能科技有限公司 | Organic silicon epoxy resin composite material and preparation method thereof |
| CN108659342A (en) * | 2018-05-29 | 2018-10-16 | 杭州鼎好新材料有限公司 | A kind of high light transmission polypropylene material and preparation method thereof |
| CN110265566A (en) * | 2019-06-04 | 2019-09-20 | 深圳市华星光电技术有限公司 | Display panel and preparation method thereof |
| CN110819050A (en) * | 2019-11-29 | 2020-02-21 | 安徽大学 | Epoxy resin modified PMMA blend and preparation method thereof |
| CN110819050B (en) * | 2019-11-29 | 2021-11-19 | 安徽大学 | Epoxy resin modified PMMA blend and preparation method thereof |
| CN114457489A (en) * | 2022-03-23 | 2022-05-10 | 合肥工业大学 | Fluorescent polylactic acid fiber fabric with core-shell structure |
| CN114457489B (en) * | 2022-03-23 | 2023-08-22 | 合肥工业大学 | Fluorescent polylactic acid fiber fabric with core-shell structure |
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