CN101519507A - Light-storing-self-illuminating transparent glass and preparation method thereof - Google Patents
Light-storing-self-illuminating transparent glass and preparation method thereof Download PDFInfo
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- CN101519507A CN101519507A CN200810007570A CN200810007570A CN101519507A CN 101519507 A CN101519507 A CN 101519507A CN 200810007570 A CN200810007570 A CN 200810007570A CN 200810007570 A CN200810007570 A CN 200810007570A CN 101519507 A CN101519507 A CN 101519507A
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Abstract
A light-storing-self-illuminating transparent glass comprises transparent organic resin, a light-storing-self-illuminating material, transparent SiO2 granules or transparent inorganic glass granules or ball-shaped transparent organic resin granules and additives. The ball-shaped transparent SiO2 granules or ball-shaped transparent inorganic glass granules or ball-shaped transparent organic resin granules containing the light-storing-self-illuminating material are equally distributed inside the transparent organic resin.
Description
Invention field:
The present invention relates to glasswork, particularly the glasswork made from light-accumulating luminous material and organic materials and inorganic materials.
Background technology:
Chinese patent ZL02125081.2 " light-accumulating luminous glass and manufacture method thereof " discloses following content: light-accumulating luminous glass is made up of light-accumulating luminous material of different kinds of ions activated and host glass, and host glass is low melting glass or conventional silicate glass.Manufacture method is for to mix light-accumulating luminous material or with behind low melting glass particle and the light-accumulating luminous material thorough mixing, to become light-accumulating luminous glass in 700-1100 degree heat-treated in conventional silicate glass forming process.
Chinese patent ZL98101173.X " a kind of light-accumulative luminous plastics " discloses following content: the present invention is grouped into by resin, light-accumulative luminous powder, glass powder or three kinds of one-tenth of glass microballon, its preparation method is to be carrier with the resin, use glass powder or glass microballon to be filler, with three kinds of compositions heating mixing, fusion, granulation both light-accumulative luminous material.
Above-mentioned patent does not relate to the scheme with organic resin and spherical transparent SiO2 particle or spherical transparent inorganic glass particle and light-accumulating luminous material manufacturing glass; more do not relate to light-accumulating luminous particle as pointolite; by the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or the refraction of light of spherical transparent organic resin particulate and light diffuse-reflectance and optical superposition; strengthen the brightness of light-accumulating luminous glass, realize luminous scheme and the theory of bulk glass.Do not relate to particle end metallurgical method yet and place different colours at different sites, light-accumulating luminous material, display pattern or the literal of differing materials.
The aforesaid method patent does not relate to the method with organic resin and spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle and light-accumulating luminous material manufacturing glass, does not more relate to the metallurgical method in particle end and makes light-storing-self-illuminating transparent glass.
Summary of the invention:
The objective of the invention is: 1, by in transparent organic resin glass, adding light-accumulating luminous material and spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle; by the transparent SiO2 particle of sphere or spherical transparent inorganic glass particle or the refraction of light of spherical transparent organic resin particulate and light diffuse-reflectance and optical superposition; the brightness of enhancing light-accumulating luminous glass solves the light pollution problem of existing glass because of direct projection light generation time shadow problem and light reflection generation.2, light-accumulating luminous material is melted in spherical transparent SiO
2In particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle, light-accumulating luminous material passes through spherical transparent grain to irradiation all round with the spherical point light source, by optical superposition, manufactures luminous glass.3, light-accumulating luminous material is melted in spherical transparent SiO
2In particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle or be melted in the transparent organic resin glass, do not absorb water not oxidation, the work-ing life of improving light-accumulating luminous material.3, substitute spherical transparent grain with transparent silk, make light-accumulating luminous shellproof transparent organic glass.4, by placing different colours, the light-accumulating luminous material of differing materials, the light-accumulating luminous material of different colours, display pattern or literal in transparent organic resin glass at different sites.4, the manufacture method of four kinds of light-storing-self-illuminating transparent glass is proposed.
The light-storing-self-illuminating transparent glass that the present invention proposes comprises: transparent organic resin, light-accumulating luminous material, transparent SiO
2Particle or transparent inorganic glass particle or spherical transparent organic resin particle, attached material, one or more light-accumulating luminous materials of uniform distribution and spherical transparent SiO in the transparent organic resin
2Particle or spherical transparent inorganic glass particle or spherical transparent organic glass particle.Light-accumulating luminous material can be that light-accumulating luminous particle adds in the transparent organic resin, can also be that light-accumulating luminous material is melted in spherical transparent SiO
2In particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle; then; add in the transparent organic resin; light-accumulating luminous material passes through spherical transparent grain to irradiation all round with the spherical point light source; by optical superposition; the interference of light manufactures the luminous glass of unglazed shade and the dirt of luminous reflectance light.
In having shock proof splinter-proof glass, spherical transparent SiO
2The transparent SiO of particle
2Silk substitutes or spherical transparent inorganic glass particle substitutes with the transparent inorganic glass silk or spherical transparent organic glass particle substitutes with the transparent organic glass silk.
The manufacturing of self-luminescence advertisement screen and label is that different sites is placed different colours in light-storing-self-illuminating transparent glass, the light-accumulating luminous material of differing materials, and by the refraction of light of spherical transparent grain, display pattern or literal in transparent organic resin glass.
In light-storing-self-illuminating transparent glass, add attached material and can give the glass property.Attached material package is drawn together fluorescent grain, TiO
2, ZnO, Cu
2O, CuO, CdO, Co
2O
3, Ni
2O
3, MnO
2, AgCl, iron protoxide, dichromate, ferric oxide, tin indium oxide, europium sesquioxide, yttrium oxide, terbium sesquioxide, cerium oxide, rare earth, magnetic particle, coupling agent, stopper, gold and silver, copper, tin, platinum, titanium, magnesium, chromium, stainless steel, above-mentioned element metallic compound, silicon solar material, coupling agent or stopper.TiO is added on the light-storing-self-illuminating transparent glass top layer
2Have bacteriostasis antibiosis, gas pollutant formaldehyde, toluene function in the decontamination chamber, anti-glass pollutes function, function of shielding ultraviolet radiation.Add ZnO and have function of shielding ultraviolet radiation.Add Cu
2O makes glass have redness.Adding CuO makes glass have blue-greenish colour.It is light yellow that interpolation CdO has glass.Add Co
2O
3Make glass have blueness.Add Ni
2O
3It is blackish green that glass is had.Add MnO
2Make glass have purple.Adding AgCl makes glass have light sensitive characteristic.Add iron protoxide and absorb infrared rays and part visible light, add dichromate, ferric oxide absorbs ultraviolet ray and part visible light, adds europium sesquioxide, yttrium oxide, terbium sesquioxide, cerium oxide, makes glass have the characteristics of luminescence.The interpolation rare earth is made photo chromic glass, interpolation magnetic particle makes glass have magnetic, manufactures magnetic glass.Add fluorescent grain, manufacture fluorescent glass.Add the silicon solar material, as: mono-crystalline silicon solar particle, polycrystalline silicon solar particle, non-crystal silicon solar energy granule manufacture become photoelectric glass, add coupling agent and make transparent SiO
2Particle or transparent inorganic glass particle or spherical transparent organic resin particle and transparent organic resin better merge.Add stopper and make transparent SiO
2Particle or transparent inorganic glass particle or spherical transparent organic resin particle are not reunited.The attached material package of metal is drawn together: metal and metallic compound thereof, as: the metallic compound of gold and silver, copper, tin, platinum, titanium, magnesium, chromium or stainless steel and metal and other element.
Add extremely metallic compound of titanium, magnesium, chromium or stainless steel, making has suitable transmissivity to visible light, and infrared rays is had higher reflectivity, ultraviolet ray is had the organic transparent glass of heat reflection of higher absorption rate.
Add gold and silver, copper, tin, its metallic compound of platinode, making has high transmittance to visible light, and infrared rays is had very high reflectivity, has the organic transparent glass of low radiation of good heat-proof quality.
Add silver ions, make organic transparent glass with good bactericidal properties.
At the spherical transparent SiO of uniform distribution
2Add light-accumulating luminous material in particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particulate transparent organic resin glass, make the organic transparent light-accumulating luminous glass of the full light of diffuse scattering.Light-accumulating luminous material comprises: the light-accumulating luminous particle of rare earth aluminate, as: glow color is that hepatic europium, neodymium activate CaAl2O4:Eu, Nb particle, glaucous europium, activated by dysprosium Sr4Al14O25:Eu, the Dy particle, yellowish green europium, activated by dysprosium SrAl2O4:Eu, Dy particle.The light-accumulating luminous particle of rare earth silicate, as: the pyrosilicate blue-light-emitting particle of europium, activated by dysprosium, europium, neodymium activated aluminate blue-light-emitting particle, the white luminous particle of the orthosilicate of magnesium activated.The light-accumulating luminous type light-emitting particles of sulfide, as: yellowish green ZnS:Cu series particle, blue CaS:Bi series particle, red CaS:Eu series particle.The characteristics of diffuse scattering light-storing-self-illuminating transparent glass are: after light-accumulating luminous material is initiatively inhaled visible light 5-10min such as holding sunlight, light, UV-light, stray light, just can continue in the dark more than the luminous 12h, adopt different light-accumulating luminous materials, can send multiple coloramas such as red, green, blue, Huang, purple.Light-accumulating luminous material excites luminous energy by absorption, and store, after optical excitation stops, the luminescent material that energy stored is come out with the form slow release of light again, because the light-accumulating luminous material of particulate state is a twinkler, light is by putting to emission everywhere, in organic transparent light-accumulating luminous glass, add light-accumulating luminous material for a long time, glass is opaque, adds light-accumulating luminous material after a little while, and the some luminous source in the glass is high-visible, influence the outward appearance of transparent light-accumulating luminous glass, the spherical transparent SiO of uniform distribution in the transparent organic resin glass
2When particle or spherical transparent inorganic glass particle and light-accumulating luminous material; the problems referred to above just can be well solved; when light-accumulating luminous material is a twinkler; light is by putting when launching everywhere; light runs into spherical transparent grain; part light sees through spherical transparent grain; part light reflects on spherical transparent grain surface; because spherical transparent grain can carry out multi-faceted refraction; adjacent spherical transparent grain birefringence light carries out birefringence; and a plurality of light-accumulating luminous materials light source light or the refracted light mutual superposition sent, making the organic transparent light-accumulating luminous glass whole body uniform illuminating of the full light of diffuse scattering, luminance brightness increases.Another advantage of transparent light-accumulating luminous glass is: efficiency of light energy utilization height.
The another kind of method that improves the light-storing-self-illuminating transparent glass heat-insulating property is to make double glazing with light-storing-self-illuminating transparent glass by existing double glazing manufacturing process.Further improve insulation, defening effect by the air in the double glazing chamber.
Transparent organic resin comprises: any in PMA, transparent PP, PC, PET, PETG, PVB, PSF (polysulfones), MMA (fluorinated polyimide), poly-fragrant fat, polyarylsulphone, the transparent anti-impact resin of butylbenzene, organosilicon transparent resin, ADC (allyl diglycol carbonates), PEN (PEN), Resins, epoxy, bulk alicyclic polyene resin or the PC-PMMA blend transparent resin.
Advantage of the present invention is: 1, by add light-accumulating luminous material and spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle in transparent organic resin glass; refraction of light and light diffuse-reflectance and optical superposition by spherical transparent grain; strengthen the brightness of light-accumulating luminous glass; the realization bulk glass is luminous, solves the light pollution problem of existing glass because of direct projection light generation time shadow problem and light reflection generation.2, light-accumulating luminous material is melted in spherical transparent SiO
2In particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle, light-accumulating luminous material passes through spherical transparent grain to irradiation all round with the spherical point light source, by optical superposition, manufactures luminous glass.3, light-accumulating luminous material is melted in spherical transparent SiO
2In particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle or be melted in the transparent organic resin glass, do not absorb water not oxidation, the work-ing life of improving light-accumulating luminous material.4, make double glazing with light-storing-self-illuminating transparent glass, improve insulation, defening effect by the air in the double glazing chamber.3, by placing different colours, the light-accumulating luminous material of differing materials, the light-accumulating luminous material of different colours, display pattern or literal in transparent organic resin glass at different sites.
One of manufacture method of light-storing-self-illuminating transparent glass: comprising: transparent organic resin; spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle; light-accumulating luminous material; attached material; transparent sphere SiO2 particle or transparent sphere unorganic glass particle or spherical transparent organic resin particle are mixed with light-accumulating luminous particle and transparent organic resin particle; pack in shaper or the mould; pressurization; be heated to the above 5-100 degree of transparent organic resin temperature of fusion; transparent organic resin is fused into liquid state; be filled in light-accumulating luminous particle and transparent sphere SiO2 particle or transparent sphere unorganic glass particle or the spherical transparent organic resin particle slit; light-accumulating luminous particle and transparent sphere SiO2 particle or transparent sphere unorganic glass particle or spherical transparent organic resin particle and transparent organic resin are combined into one; after the cooling, manufacture light-storing-self-illuminating transparent glass.
Two of light-storing-self-illuminating transparent glass manufacture method; with transparent SiO2 particle or transparent inorganic glass particle or transparent organic resin particles fuse one-tenth liquid state; add light-accumulating luminous material; after mixing; atomizing; cooling; make spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle; the transparent light-accumulating luminous SiO2 particle of sphere or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle are mixed with the transparent organic resin uniform particles; pack in shaper or the mould; pressurization; be heated to the above 5-100 degree of transparent organic resin temperature of fusion; transparent organic resin is fused into liquid state; be filled in spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or the spherical transparent light-accumulating luminous organic resin particle slit; spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle and transparent organic resin are combined into one; after the cooling, manufacture light-storing-self-illuminating transparent glass.
Three of light-storing-self-illuminating transparent glass manufacture method; with transparent SiO2 particle or transparent inorganic glass particle or transparent organic resin particles fuse one-tenth liquid state; add light-accumulating luminous material; after mixing; atomizing; cooling; make spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle; after the transparent light-accumulating luminous SiO2 particle of sphere or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle heating; be sprayed onto in the transparent organic resin aerosol particles and mix; transparent organic resin is attached on the transparent light-accumulating luminous SiO2 particle of sphere or spherical transparent light-accumulating luminous unorganic glass particle or the spherical transparent light-accumulating luminous organic resin particle; be combined into one with the transparent light-accumulating luminous SiO2 particle of sphere or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle; after the sorting; make the spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or the spherical transparent light-accumulating luminous organic resin particle that adhere to transparent organic resin; to adhere to the spherical transparent light-accumulating luminous SiO2 particle of transparent organic resin or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle packs in shaper or the mould; pressurization; be heated to the above 5-100 degree of transparent organic resin temperature of fusion; transparent organic resin is fused into liquid state; be filled in spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or the spherical transparent light-accumulating luminous organic resin particulate slit; spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle and transparent organic resin are combined into one; after the cooling, make light-storing-self-illuminating transparent glass.
Four of light-storing-self-illuminating transparent glass manufacture method; transparent SiO2 particle or transparent inorganic glass particle or transparent organic resin particle are heated into liquid state; add light-accumulating luminous material; stir; atomizing; cooling; manufacture the spherical transparent SiO2 particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle that contain light-accumulating luminous material; it is liquid that the transparent organic resin heat fused becomes; to contain the spherical transparent SiO2 particle of light-accumulating luminous material or spherical transparent inorganic glass particle or spherical transparent organic resin particle and put into the liquid clear organic resin; after stirring; put into pressing machine or roller press or mould cooling forming, make light-storing-self-illuminating transparent glass.
For eliminating the stress that in making the light-storing-self-illuminating transparent glass process, produces, light-storing-self-illuminating transparent glass is carried out the constant temperature homogenizing handle, prevent glass deformation.
Description of drawings:
Below in conjunction with Figure of description and embodiment the present invention is further described.
Fig. 1 is the light-accumulating luminous outer refraction transparent glass sectional view with feature of the present invention.
Fig. 2 is the light-accumulating luminous interior radiation transparent glass sectional view with feature of the present invention.
Fig. 3 is the spherical transparent SiO of Fig. 2
2Single particle pointolite irradiation synoptic diagram.
Fig. 4 is spherical transparent single particle pointolite of Fig. 2 and spheric reflection optical superposition synoptic diagram.
Fig. 5 is the light-accumulating luminous transparent splinter-proof glass sectional view with feature of the present invention.
Fig. 6 is the light-accumulating luminous transparent antipollution glass sectional view with feature of the present invention.
Fig. 7 is the light-accumulating luminous transparent pattern glass with feature of the present invention.
Fig. 8 is the light-accumulating luminous clear hollow glass sectional view with feature of the present invention.
Embodiment:
Embodiment 1:
A kind of light-accumulating luminous outer refraction transparent glass sectional view as shown in Figure 1, wherein: the 1st, transparent organic resin glass, the 2nd, spherical transparent SiO
2Particle, the 3rd, the light-accumulating luminous particle of rare earth aluminate, spherical transparent SiO
2The light-accumulating luminous uniform particles of particle and rare earth aluminate is distributed in the transparent organic resin glass.
Embodiment 2:
A kind of light-accumulating luminous in radiation transparent glass sectional view as shown in Figure 1, Fig. 3 is the spherical transparent SiO of Fig. 2
2Single particle pointolite irradiation synoptic diagram, Fig. 4 are spherical transparent single particle pointolite of Fig. 2 and spheric reflection optical superposition synoptic diagram, wherein: the 4th, transparent organic resin glass, the 5th, the light-accumulating luminous particle of rare earth aluminate, the 6th, spherical transparent SiO
2Particle, the 7th, the light-accumulating luminous particle pointolite of rare earth aluminate ray, the 8th, sphere incident light, the 9th, spheric reflection light, the spherical transparent SiO of the light-accumulating luminous particle external parcel of rare earth aluminate
2Evengranular being distributed in the organic resin glass 4, the pointolite light ray 7 that the light-accumulating luminous particle 5 of rare earth aluminate sends sees through transparent SiO
2Ball 6 is to the four sides radiation, and sphere incident light 8 and spheric reflection light 9 are interfered mutually with pointolite light ray 7, stack, and the luminosity of the light-accumulating luminous particle 5 of enhancing rare earth aluminate, the shade of minimizing line reflection light reduces light pollution.
Embodiment 3:
A kind of light-accumulating luminous transparent splinter-proof glass sectional view as shown in Figure 5, wherein: the 10th, organic resin glass, the 11st, the light-accumulating luminous particle of rare earth aluminate, the 12nd, transparent glass fibre, light-accumulating luminous particle 11 of rare earth aluminate and transparent glass fibre 12 are evenly distributed in the organic resin glass 10, in bomb attacks and accidental explosion incident, transparent glass fibre 12 reduces the direct injury that the glass fragmentation causes to greatest extent, the light-accumulating luminous particle of rare earth aluminate can send light and reach 12 hours intense light irradiation 15 minutes.
Embodiment 5:
A kind of light-accumulating luminous transparent antipollution glass sectional view as shown in Figure 6, wherein: the 13rd, organic resin glass, the 14th, the light-accumulating luminous particle of rare earth silicate, the 15th, the TiO2 particle, the light-accumulating luminous particle 14 of rare earth silicate is evenly distributed in the organic resin glass 13, TiO2 particle 15 is evenly distributed on organic resin glass 13 surfaces, the TiO2 particle has decomposition, dispersion and dissolved dirt and other organic residue, and that it is not sticked to is on glass, make rainwater spread over glass surface, and wash away dust, prevent to pollute.The light-accumulating luminous particle 11 of rare earth silicate can send light and reach 12 hours intense light irradiation 15 minutes, saves the night lighting energy.
Embodiment 6:
A kind of light-accumulating luminous transparent pattern glass as shown in Figure 7, wherein: the 16th, organic resin glass, the 17th, the white luminous particle of the orthosilicate of magnesium activated, the 18th, the red light-accumulating luminous particle of CaS:Eu, the white luminous particle 17 of the orthosilicate of magnesium activated is evenly distributed in the organic resin glass 16, in organic resin glass 16, undercut the cavity with engraving machine, in the cavity, add red light-accumulating luminous particle of CaS:Eu and UV transparent heat colloidal sol, heating makes fusing, with light-accumulating luminous particle of the CaS:Eu of redness and organic resin glass 16 bonding being integral.The advantage of this product is that the light-accumulating luminous particle of different colours shows different colours.
Embodiment 7:
A kind of light-accumulating luminous clear hollow glass sectional view as shown in Figure 8, wherein: the 19th, organic resin glass, the 20th, spherical transparent SiO
2Particle, spherical transparent SiO
2 Particle 20 is evenly distributed in the organic resin glass 19, and the 21st, the light-accumulating luminous particle of rare earth silicate, the 22nd, gas, the 23rd, unorganic glass, the 24th, double glazing parting bead, the 25th, siccative, the 26th, seal gum.The spherical transparent SiO of uniform distribution in the organic resin glass 19
2The light-accumulating luminous particle 21 of particle 20 and rare earth silicate after the light-accumulating luminous particle 21 of rare earth silicate absorbs luminous energy, sends a light ray, and irradiate light is at the transparent SiO of sphere
2Particle 20 surfaces produce refraction of light, some light ray and spherical transparent SiO
2The refraction of particle 20 surface light is interfered mutually, make organic resin glass not produce direct reflected light, the shadow pollution problem that solution produces because of luminous reflectance, air in the double glazing chamber is the propagation of trap heat and sound effectively, further improves insulation, the defening effect of light-accumulating luminous clear hollow glass.
Claims (10)
1, a kind of light-storing-self-illuminating transparent glass comprises: transparent organic resin, light-accumulating luminous material, transparent SiO
2Particle or transparent inorganic glass particle or spherical transparent organic resin particle, attached material is characterized in that containing the spherical transparent SiO of light-accumulating luminous material
2Particle or spherical transparent inorganic glass particle or spherical transparent organic resin uniform particles are distributed in the transparent organic resin.
2, light-storing-self-illuminating transparent glass as claimed in claim 1 is characterized in that different sites is placed different colours, the light-accumulating luminous material of differing materials in the light-storing-self-illuminating transparent glass.
3, light-storing-self-illuminating transparent glass as claimed in claim 1 is characterized in that spherical transparent SiO
2The transparent SiO of particle
2Silk substitutes or spherical transparent inorganic glass particle substitutes with the transparent inorganic glass silk or spherical transparent organic glass particle substitutes with the transparent organic glass silk.
4, light-storing-self-illuminating transparent glass as claimed in claim 1 is characterized in that attached material package draws together fluorescent grain, TiO
2, ZnO, Cu
2O, CuO, CdO, Co
2O
3, Ni
2O
3, MnO
2, AgCl, iron protoxide, dichromate, ferric oxide, tin indium oxide, europium sesquioxide, yttrium oxide, terbium sesquioxide, cerium oxide, rare earth, magnetic particle, coupling agent, stopper, gold and silver, copper, tin, platinum, titanium, magnesium, chromium, stainless steel, above-mentioned element metallic compound, silicon solar material, coupling agent or stopper.
5, light-storing-self-illuminating transparent glass as claimed in claim 1, it is characterized in that light-accumulating luminous material comprises: the light-accumulating luminous particle of rare earth aluminate, as: glow color is that hepatic europium, neodymium activate CaAl204:Eu, the Nb particle, glaucous europium, activated by dysprosium Sr4A114025:Eu, the Dy particle, yellowish green europium, activated by dysprosium SrAl204:Eu, Dy particle.The light-accumulating luminous particle of rare earth silicate, as: the pyrosilicate blue-light-emitting particle of europium, activated by dysprosium, europium, neodymium activated aluminate blue-light-emitting particle, the white luminous particle of the orthosilicate of magnesium activated.The light-accumulating luminous type light-emitting particles of sulfide, as: yellowish green ZnS:Cu series particle, blue CaS:Bi series particle, red CaS:Eu series particle.
6, light-storing-self-illuminating transparent glass as claimed in claim 1 is characterized in that transparent organic resin comprises: any in PMMA, transparent PP, PC, PET, PETG, PVB, PSF (polysulfones), MMA (fluorinated polyimide), poly-fragrant fat, polyarylsulphone, the transparent anti-impact resin of butylbenzene, organosilicon transparent resin, ADC (allyl diglycol carbonates), PEN (poly-dioctyl phthalate glycol ester), Resins, epoxy, bulk alicyclic polyene resin or the PC-PMMA blend transparent resin.
7; one of manufacture method of light-storing-self-illuminating transparent glass: comprising: transparent organic resin; spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle; light-accumulating luminous material; attached material; it is characterized in that transparent sphere SiO2 particle or transparent sphere unorganic glass particle or spherical transparent organic resin particle are mixed with light-accumulating luminous particle and transparent organic resin particle; pack in shaper or the mould; pressurization; be heated to the above 5-100 degree of transparent organic resin temperature of fusion; transparent organic resin is fused into liquid state; be filled in light-accumulating luminous particle and transparent sphere SiO2 particle or transparent sphere unorganic glass particle or the spherical transparent organic resin particle slit; light-accumulating luminous particle and transparent sphere SiO2 particle or transparent sphere unorganic glass particle or spherical transparent organic resin particle and transparent organic resin are combined into one; after the cooling, manufacture light-storing-self-illuminating transparent glass.
8; two of light-storing-self-illuminating transparent glass manufacture method; it is characterized in that transparent SiO2 particle or transparent inorganic glass particle or transparent organic resin particles fuse one-tenth liquid state; add light-accumulating luminous material; after mixing; atomizing; cooling; make spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle; the transparent light-accumulating luminous SiO2 particle of sphere or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle are mixed with the transparent organic resin uniform particles; pack in shaper or the mould; pressurization; be heated to the above 5-100 degree of transparent organic resin temperature of fusion; transparent organic resin is fused into liquid state; be filled in spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or the spherical transparent light-accumulating luminous organic resin particle slit; spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle and transparent organic resin are combined into one; after the cooling, manufacture light-storing-self-illuminating transparent glass.
9; three of light-storing-self-illuminating transparent glass manufacture method; it is characterized in that transparent SiO2 particle or transparent inorganic glass particle or transparent organic resin particles fuse one-tenth liquid state; add light-accumulating luminous material; after mixing; atomizing; cooling; make spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle; after the transparent light-accumulating luminous SiO2 particle of sphere or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle heating; be sprayed onto in the transparent organic resin aerosol particles and mix; transparent organic resin is attached on the transparent light-accumulating luminous SiO2 particle of sphere or spherical transparent light-accumulating luminous unorganic glass particle or the spherical transparent light-accumulating luminous organic resin particle; be combined into one with the transparent light-accumulating luminous SiO2 particle of sphere or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle; after the sorting; make the spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or the spherical transparent light-accumulating luminous organic resin particle that adhere to transparent organic resin; to adhere to the spherical transparent light-accumulating luminous SiO2 particle of transparent organic resin or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle packs in shaper or the mould; pressurization; be heated to the above 5-100 degree of transparent organic resin temperature of fusion; transparent organic resin is fused into liquid state; be filled in spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or the spherical transparent light-accumulating luminous organic resin particulate slit; spherical transparent light-accumulating luminous SiO2 particle or spherical transparent light-accumulating luminous unorganic glass particle or spherical transparent light-accumulating luminous organic resin particle and transparent organic resin are combined into one; after the cooling, make light-storing-self-illuminating transparent glass.
10; four of light-storing-self-illuminating transparent glass manufacture method; it is characterized in that transparent SiO2 particle or transparent inorganic glass particle or transparent organic resin particle are heated into liquid state; add light-accumulating luminous material; stir; atomizing; cooling; manufacture the spherical transparent SiO2 particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle that contain light-accumulating luminous material; it is liquid that the transparent organic resin heat fused becomes; to contain the spherical transparent SiO2 particle of light-accumulating luminous material or spherical transparent inorganic glass particle or spherical transparent organic resin particle and put into the liquid clear organic resin; after stirring; put into pressing machine or roller press or mould cooling forming, make light-storing-self-illuminating transparent glass.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102050573B (en) * | 2009-10-30 | 2013-03-06 | 海洋王照明科技股份有限公司 | Luminous glass and manufacturing method thereof |
| CN103554851A (en) * | 2013-10-31 | 2014-02-05 | 广汉市国腾复合材料有限公司 | Polyester resin extruding light-emitting plate and preparation method thereof |
| CN103755864A (en) * | 2014-01-20 | 2014-04-30 | 扬州大学 | Preparation method of fluorescent organic glass |
| CN104369477A (en) * | 2014-11-18 | 2015-02-25 | 广西远大玻璃节能科技股份有限公司 | Luminous, safe, energy-saving and environment-friendly glass |
| CN106832845A (en) * | 2015-12-05 | 2017-06-13 | 大连希光科技有限公司 | A kind of luminescent plastic section bar and its manufacture method |
| CN108046592A (en) * | 2017-11-24 | 2018-05-18 | 新沂博瑞工业设计有限公司 | A kind of preparation method of nanoscale sound control glass material |
| CN109705842A (en) * | 2018-12-25 | 2019-05-03 | 温州大学 | A kind of new type long-persistence luminescent composite and preparation method thereof |
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2008
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102050573B (en) * | 2009-10-30 | 2013-03-06 | 海洋王照明科技股份有限公司 | Luminous glass and manufacturing method thereof |
| CN103554851A (en) * | 2013-10-31 | 2014-02-05 | 广汉市国腾复合材料有限公司 | Polyester resin extruding light-emitting plate and preparation method thereof |
| CN103755864A (en) * | 2014-01-20 | 2014-04-30 | 扬州大学 | Preparation method of fluorescent organic glass |
| CN103755864B (en) * | 2014-01-20 | 2016-06-22 | 扬州大学 | A kind of preparation method of fluorescence lucite |
| CN104369477A (en) * | 2014-11-18 | 2015-02-25 | 广西远大玻璃节能科技股份有限公司 | Luminous, safe, energy-saving and environment-friendly glass |
| CN104369477B (en) * | 2014-11-18 | 2015-12-23 | 广西远大玻璃节能科技股份有限公司 | Noctilucent safety energy-saving environment-friendly glass |
| CN106832845A (en) * | 2015-12-05 | 2017-06-13 | 大连希光科技有限公司 | A kind of luminescent plastic section bar and its manufacture method |
| CN108046592A (en) * | 2017-11-24 | 2018-05-18 | 新沂博瑞工业设计有限公司 | A kind of preparation method of nanoscale sound control glass material |
| CN108046592B (en) * | 2017-11-24 | 2020-05-29 | 临泉县强钢钢化玻璃有限公司 | Preparation method of nano-grade sound insulation glass material |
| CN109705842A (en) * | 2018-12-25 | 2019-05-03 | 温州大学 | A kind of new type long-persistence luminescent composite and preparation method thereof |
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