CN101514274A - Ultraviolet light curing glass paint and preparation method thereof - Google Patents
Ultraviolet light curing glass paint and preparation method thereof Download PDFInfo
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- CN101514274A CN101514274A CNA2009100107188A CN200910010718A CN101514274A CN 101514274 A CN101514274 A CN 101514274A CN A2009100107188 A CNA2009100107188 A CN A2009100107188A CN 200910010718 A CN200910010718 A CN 200910010718A CN 101514274 A CN101514274 A CN 101514274A
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Abstract
The invention relates to an ultraviolet light curing glass paint and a preparation method thereof. The paint comprises organic silicon resin, modified epoxide resin, diluent and 1-hydroxide radical-cyclohexyl diphenyl ketone and is prepared by evenly mixing the materials. The paint is free from organic solvent and toxicity, and being combined, the materials have very good property of visible light penetration, prevent ultraviolet and infrared radiation and have very good heat-insulating property.
Description
Technical field
The present invention relates to a kind of ultraviolet light curing glass paint and prepare the method for this coating.
Background technology
Because glass does not have good isolated thermal-radiating performance, it is applied in the highly energy-consuming problem that is caused on buildings or structures or other field has caused many concerns.Particularly much architecturally be equipped with several thousand and even the daylighting glass of square meters up to ten thousand, when ambient temperature was higher, these daylighting glass had absorbed a large amount of heat energy, directly caused the room temp of buildings to raise, and what have reaches more than 40 ℃; And when ambient temperature was low, these daylighting glass can be to a large amount of heat energy of external irradiation, thereby cause the room temp step-down, and minimum temperature can reach subzero 30 ℃ in the winter time.In the prior art, adopt air-conditioning or heating installation to regulate room temp usually, run well, cause the significant wastage of the energy but air-conditioning or heating installation need electric energy or other energy to keep it.
The lighting for buildings area is big, though be unfavorable for indoor heat insulating,, consider that from living environment and aspect such as attractive in appearance people still do not stint and enlarge daylighting area in the mode that wastes energy, have in addition adopt glass curtain wall.In the prior art, solving daylighting area is to utilize low emissivity glass to make door and window with effective ways that are incubated this contradiction, described low emissivity glass such as low-e coated glass, this kind glass is that be coated with the film that multiple layer metal or other compounds form on its surface be product, its coatings has the high characteristic that reaches the high reflection of centering far infrared rays that sees through of visible light, excellent thermal characteristics and good optical performance are arranged, can reduce greatly the indoor heat energy that causes because of radiation through glass to outdoor transmission, reach the ideal energy-saving effect.But because the cost of manufacture of low-e glass is too high, pad pasting is complex process not only, and the film that is pasted comes off easily, and is not durable, so this kind low emissivity glass is difficult to big area and promotes the use of.
The disclosed name of Chinese patent 100999643A is called " crystal whisker wear-resistant ultraviolet ray solidified paint and preparation method thereof " and provides the mode of utilizing coating and prevent thermal-radiating technology.This kind coating comprises photosensitive oligomer, reactive thinner, and light trigger, whisker, filler and auxiliary agent can be used for being coated in timber, metal, glass and ceramic surface.Its meaning is to want to utilize whisker and auxiliary agent to improve the wear resisting property of film, utilizes the radiation of photosensitive oligomer ultraviolet light, but, this kind ADHESION OF PAINTS power and hardness, and work-ing life etc. the aspect problem also wait upon in further discussion.
The heat waste anergy of buildings China and foreign countries door and window accounts for more than 50% of its energy consumption, and particularly glass surface conducts heat based on radiation, so the performance that will change glass reduces the loss of heat energy, the most effective way is to suppress its surperficial radiation.Existing inhibition glass surface radiating glass paint is of common occurrence, but from its validity and hardness, aspects such as sticking power and work-ing life are taken all factors into consideration, and meet the coating of these requirements or film also not to be found in the prior art.
Summary of the invention
A task of the present invention provides a kind of have high rigidity and sticking power and resistant to pollution ultraviolet light curing glass paint.
Another task of the present invention provides a kind of method for preparing described ultraviolet light curing glass paint.
The ultraviolet light curing glass paint that the present invention proposes comprises the material of following weight part: silicone resin 3-5 part, modified epoxy 5-8 part, thinner 3-6 part, 1-hydroxyl-cyclohexyl diphenylmethanone 0.5-0.8 part.
This coating comprises that also weight part is that the particle of 1-6 part is nano level zinc oxide or silicon oxide or titanium oxide or zinc oxide and silicon oxide and titanium oxide three's a mixture.Nano level zinc, silicon, titanyl compound are used to prevent ultraviolet ray and infrared radiation.
Described silicone resin is to be made of one or both mixtures in γ-Bing Jisanjiayangjiguiwan acrylate and the γ-oxypropyl trimethyl silane resin.This silicone resin can improve ADHESION OF PAINTS power and hardness.
Described thinner is to be made of one or more the mixture in polyphosphoric acid Hydroxyethyl acrylate, epoxy chloropropane acrylate and the trimethylolpropane tris olefin(e) acid ester.Thinner adopts this class material can make coating have high adhesive force.
Described modified epoxy is to be made of epoxy acrylic resin.
Described coating comprises the material of following weight part: γ-Bing Jisanjiayangjiguiwan acrylate 1-2 part, γ-oxypropyl trimethyl silane resin 2-3 part, modified epoxy 5-8 part, thinner 3-6 part, 1-hydroxyl-cyclohexyl diphenylmethanone 0.5-0.8 part, each 1-2 part of zinc oxide and silicon oxide and titanium oxide.Also be added with the sterilant that the material of argentiferous that weight is 1-5 part and zine ion constitutes in the described coating.
The preparation method of above-mentioned coating may further comprise the steps: get silicone resin, modified epoxy, thinner, 1-hydroxyl-cyclohexyl diphenylmethanone, zinc oxide, titanium oxide, silicon oxide according to above-mentioned weight part, and will be coating after each mixing of materials, coating is coated in to form after UV-irradiation on the acceptor again films.
γ-Bing Jisanjiayangjiguiwan acrylate in the described silicone resin adopts following method preparation: earlier KH-560 is joined in the container that has agitator, reflux condensing tube, in this container, add triphenyl phosphine again, begin dropwise addition of acrylic acid and stopper in it when this container is heated to 85 ℃-115 ℃, react and be the γ-Bing Jisanjiayangjiguiwan acrylate in three hours; γ-oxypropyl trimethyl silane resin adopts following method preparation: earlier KH-570 and ethanol adding are had in the container of agitator and reflux condensing tube, and then in container, add acetate and water, container is heated to 60 ℃ begins to drip, 3.5 hours γ-oxypropyl trimethyl silane resins of reaction meter.
Described modified epoxy adopts epoxy acrylic resin, and its preparation method is as follows: extracting epoxy resin 180-240 part, para hydroxybenzene phenol 0.2-0.6 part, vinylformic acid 50-100 part, triphen phosphorus 1-3 part; Slowly be warming up to 70-90 ℃ after above-mentioned raw materials added reactor, and temperature of reaction is controlled between 100-125 ℃, react and be epoxy acrylic resin in 2-3 hour; Described thinner adopts epoxy chloropropane acrylate and Hydroxyethyl acrylate poly phosphate, wherein, the preparation method of epoxy chloropropane acrylate is as follows: get epoxy chloropropane 200-300 part, para hydroxybenzene phenol 0.08-0.1 part, vinylformic acid 150-200 part, triphen phosphorus 3-6 part; Said mixture slowly is warming up to 85 ℃ of beginning thermopositive reaction, temperature of reaction is controlled between 100-110 ℃, react and be the epoxy chloropropane acrylate in 2.5-3 hour; The preparation method of Hydroxyethyl acrylate poly phosphate is as follows: get Hydroxyethyl acrylate and put into container for 40.6 parts, add 0.1 part the Vanadium Pentoxide in FLAKES to methoxyl group phenol and 7.78 parts again in container, resultant of reaction is the Hydroxyethyl acrylate poly phosphate.
Ultraviolet light curing glass paint proposed by the invention so this coating can not produce volatile matter, does not have toxicity owing to do not contain any organic solvent; Simultaneously, the silicone resin and the thinner that adopt can improve ADHESION OF PAINTS power and hardness, adopt nano level zinc, silicon, titanyl compound can prevent ultraviolet ray and infrared radiation effectively, the performance that has well saturating visible light after the combinations such as these materials and modified epoxy, so, this coating light, and energy antiultraviolet and infrared radiation have good heat-insulating property; In addition, the argentiferous that adds in the coating and the material of zine ion can sterilizations, make the environmental protection more of this coating.
Embodiment
Embodiment 1
Get silicone resin 21Kg, modified epoxy 54Kg, thinner 21Kg, 1-hydroxyl-cyclohexyl diphenylmethanone 5.4Kg is ultraviolet light curing glass paint with described mixing of materials after evenly.Wherein, silicone resin is to be made of one or both mixtures in γ-Bing Jisanjiayangjiguiwan acrylate and the γ-oxypropyl trimethyl silane resin; Thinner is to be made of one or more the mixture in polyphosphoric acid Hydroxyethyl acrylate, epoxy chloropropane acrylate and the trimethylolpropane tris olefin(e) acid ester; Modified epoxy is to be made of epoxy acrylic resin.
Embodiment 2
Get silicone resin 30Kg, modified epoxy 31Kg, thinner 36Kg, 1-hydroxyl-cyclohexyl diphenylmethanone 3Kg is ultraviolet light curing glass paint with described mixing of materials after evenly.Wherein, silicone resin, thinner and modified epoxy adopt the material identical with embodiment 1.
Embodiment 3
Get silicone resin 25Kg, modified epoxy 38Kg, thinner 32Kg, 1-hydroxyl-cyclohexyl diphenylmethanone 4.5Kg is ultraviolet light curing glass paint with described mixing of materials after evenly.Wherein, silicone resin, thinner and modified epoxy adopt the material identical with embodiment 1.
Embodiment 4
Get γ-Bing Jisanjiayangjiguiwan acrylate 5Kg, γ-oxypropyl trimethyl silane resin 15Kg, modified epoxy 25.3Kg, thinner 30Kg, 1-hydroxyl-cyclohexyl diphenylmethanone 4Kg, zinc oxide 5Kg, silicon oxide 5Kg, titanium oxide 10Kg.Wherein, thinner and modified epoxy adopt the material identical with embodiment 1.
Embodiment 5
Get γ-Bing Jisanjiayangjiguiwan acrylate 9.7Kg, γ-oxypropyl trimethyl silane resin 9.8Kg, modified epoxy 39Kg, thinner 14.7Kg, 1-hydroxyl-cyclohexyl diphenylmethanone 2.5Kg, zinc oxide 9.7Kg, silicon oxide 9.7Kg, titanium oxide 4.9Kg.Wherein, thinner and modified epoxy adopt the material identical with embodiment 1.
Embodiment 6
Get γ-Bing Jisanjiayangjiguiwan acrylate 7.3Kg, γ-oxypropyl trimethyl silane resin 12Kg part, modified epoxy 31Kg, thinner 24Kg, 1-hydroxyl-cyclohexyl diphenylmethanone 2.9Kg, zinc oxide 7.3Kg, silicon oxide 7.3Kg, titanium oxide 7.3Kg.Wherein, thinner and modified epoxy adopt the material identical with embodiment 1.
In embodiment 4 to 6, zinc oxide and silicon oxide and titanium oxide can adopt one or both materials in these three kinds of materials, and its quality is corresponding with three kinds of material sums respectively.
In addition, in embodiment 1-6, produce the γ-Bing Jisanjiayangjiguiwan acrylate and adopt following method: get 236 kilograms KH-560 resin, it is joined in the container that has agitator, reflux condensing tube, in container, add 0.5 kilogram of triphenyl phosphine again, begin in it, to drip 7.2 kilograms vinylformic acid and 0.05 kilogram stopper when this container is heated to 85 ℃ or 90 ℃ or 100 ℃ or 115 ℃, reacted three hours, promptly obtain the γ-Bing Jisanjiayangjiguiwan acrylate; Produce γ-oxypropyl trimethyl silane resin and adopt following method: at first get 50 kilograms of KH-570 resins and 50 kilograms of ethanol and add and have in the container of agitator and reflux condensing tube, and then in container, add the water of 10 kilograms of acetate and 25 kilograms, container is heated to 60 ℃ begins to drip, the reaction meter promptly obtained γ-oxypropyl trimethyl silane resin in 3.5 hours; When Resins, epoxy adopts epoxy acrylic resin, adopt following method preparation: extracting epoxy resin 180-240 kilogram, optimum value is 200 kilograms, and then get para hydroxybenzene phenol 0.2-0.6 kilogram successively, optimum value is 0.4 kilogram, vinylformic acid 50-100 kilogram, optimum value is 70 kilograms, triphen phosphorus 1-3 kilogram, optimum value is 2 kilograms, slowly be warming up to 70 ℃ or 80 ℃ or 90 ℃ after above-mentioned raw materials added reactor, and temperature of reaction is controlled between 100-125 ℃, react and be epoxy acrylic resin in 2-3 hour; When adopting epoxy chloropropane acrylate and Hydroxyethyl acrylate poly phosphate as thinner, wherein, the preparation method of epoxy chloropropane acrylate is as follows: get epoxy chloropropane 200-300 part, optimum value is 250 parts, para hydroxybenzene phenol 0.08-0.1 part, vinylformic acid 150-200 part, triphen phosphorus 3-6 part; Said mixture slowly is warming up to 85 ℃ of beginning thermopositive reaction, temperature of reaction is controlled between 100-110 ℃, react and be the epoxy chloropropane acrylate in 2.5-3 hour; The preparation method of Hydroxyethyl acrylate poly phosphate is as follows: get Hydroxyethyl acrylate and put into container for 40.6 parts, add 0.1 part the Vanadium Pentoxide in FLAKES to methoxyl group phenol and 7.78 parts again in container, resultant of reaction is the Hydroxyethyl acrylate poly phosphate.
Coating described in the embodiment 1-6 is coated in glass surface, can becomes of the present invention filming through UV-irradiation again.
Claims (10)
1, a kind of ultraviolet light curing glass paint is characterized in that comprising the material of following weight part: silicone resin 3-5 part, modified epoxy 5-8 part, thinner 3-6 part, 1-hydroxyl-cyclohexyl diphenylmethanone 0.5-0.8 part.
2, coating according to claim 1 is characterized in that: this coating comprises that also weight part is that the particle of 1-6 part is nano level zinc oxide or silicon oxide or titanium oxide or zinc oxide and silicon oxide and titanium oxide three's a mixture.
3, coating according to claim 1 is characterized in that: described silicone resin is to be made of one or both mixtures in γ-Bing Jisanjiayangjiguiwan acrylate and the γ-oxypropyl trimethyl silane resin.
4, coating according to claim 1, its domestic animal is levied and is: described thinner is to be made of one or more the mixture in polyphosphoric acid Hydroxyethyl acrylate, epoxy chloropropane acrylate and the trimethylolpropane tris olefin(e) acid ester.
5, coating according to claim 1, its domestic animal is levied and is: described modified epoxy is to be made of epoxy acrylic resin.
6, coating according to claim 3, its domestic animal is levied the material that is to comprise following weight part: γ-Bing Jisanjiayangjiguiwan acrylate 1-2 part, γ-oxypropyl trimethyl silane resin 2-3 part, modified epoxy 5-8 part, thinner 3-6 part, 1-hydroxyl-cyclohexyl diphenylmethanone 0.5-0.8 part, each 1-2 part of zinc oxide and silicon oxide and titanium oxide.
7, coating according to claim 6, its domestic animal is levied and is: also be added with the sterilant that the material of argentiferous that weight is 1-5 part and zine ion constitutes in the described coating,
8, according to the preparation method of claim 1 or 2 or 3 or 4 or 5 or 6 or 7 described ultraviolet light curing glass paints, it is characterized in that may further comprise the steps:
Get silicone resin, modified epoxy, thinner, 1-hydroxyl-cyclohexyl diphenylmethanone, zinc oxide, titanium oxide, silicon oxide according to above-mentioned weight part, and will be coating after each mixing of materials, coating is coated in to form after UV-irradiation on the acceptor again films.
9, preparation method according to claim 8, it is characterized in that: the γ-Bing Jisanjiayangjiguiwan acrylate in the described silicone resin adopts following method preparation: earlier KH-560 is joined in the container that has agitator, reflux condensing tube, in this container, add triphen phosphorus again, begin dropwise addition of acrylic acid and stopper in it when this container is heated to 85 ℃-115 ℃, react and be the γ-Bing Jisanjiayangjiguiwan acrylate in three hours; γ-oxypropyl trimethyl silane resin adopts following method preparation: earlier KH-570 and ethanol adding are had in the container of agitator and reflux condensing tube, and then in container, add acetate and water, container is heated to 60 ℃ begins to drip, 3.5 hours γ-oxypropyl trimethyl silane resins of reaction meter.
10, preparation method according to claim 8, it is characterized in that: described modified epoxy adopts epoxy acrylic resin, and its preparation method is as follows: earlier with Resins, epoxy 180-240 part, and para hydroxybenzene phenol 0.2-0.6 part, vinylformic acid 50-100 part, triphen phosphorus 1-3 part; Slowly be warming up to 70-90 ℃ after above-mentioned raw materials added reactor, and temperature of reaction is controlled between 100-125 ℃, react and be epoxy acrylic resin in 2-3 hour; Described thinner adopts epoxy chloropropane acrylate and Hydroxyethyl acrylate poly phosphate, wherein, the preparation method of epoxy chloropropane acrylate is as follows: get epoxy chloropropane 200-300 part, para hydroxybenzene phenol 0.08-0.1 part, vinylformic acid 150-200 part, triphen phosphorus 3-6 part; Said mixture slowly is warming up to 85 ℃ of beginning thermopositive reaction, temperature of reaction is controlled between 100-110 ℃, react and be the epoxy chloropropane acrylate in 2.5-3 hour; The preparation method of Hydroxyethyl acrylate poly phosphate is as follows: get Hydroxyethyl acrylate and put into container for 40.6 parts, add 0.1 part the Vanadium Pentoxide in FLAKES to methoxyl group phenol and 7.78 parts again in container, resultant of reaction is the Hydroxyethyl acrylate poly phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN 200910010718 CN101514274B (en) | 2009-03-18 | 2009-03-18 | Ultraviolet light curing glass paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 200910010718 CN101514274B (en) | 2009-03-18 | 2009-03-18 | Ultraviolet light curing glass paint and preparation method thereof |
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| CN101514274A true CN101514274A (en) | 2009-08-26 |
| CN101514274B CN101514274B (en) | 2013-01-09 |
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| CN 200910010718 Expired - Fee Related CN101514274B (en) | 2009-03-18 | 2009-03-18 | Ultraviolet light curing glass paint and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102627900A (en) * | 2012-03-20 | 2012-08-08 | 江苏同辉照明科技有限公司 | Preparation method of anti-ultraviolet paint |
| CN103012634A (en) * | 2012-12-10 | 2013-04-03 | 苏州市明大高分子科技材料有限公司 | Organic phosphate modified acrylate oligomer cured by ultraviolet light and preparation method of organic phosphate modified acrylate oligomer |
| EP2832705A4 (en) * | 2012-03-27 | 2016-03-02 | Nippon Sheet Glass Co Ltd | Glass sheet on which is formed coating suitable for preventing burning, and method for producing same |
| CN108034028A (en) * | 2018-01-11 | 2018-05-15 | 浙江鸿安建设有限公司 | A kind of novel building outer wall thermal insulation material and preparation method thereof |
| CN108137401A (en) * | 2015-09-28 | 2018-06-08 | 积水化学工业株式会社 | Intermediate film for laminated glasses and laminated glass |
| CN114956590A (en) * | 2022-05-05 | 2022-08-30 | 顾晓明 | Anti-ultraviolet heat-insulating glass and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1114331A (en) * | 1994-07-01 | 1996-01-03 | 李珊瑚 | Ultraviolet light fast solidification paint |
| CN100455635C (en) * | 2003-04-07 | 2009-01-28 | 深圳市海川实业股份有限公司 | Uv light solidified paint capable of being used as optical fibre coating layer |
-
2009
- 2009-03-18 CN CN 200910010718 patent/CN101514274B/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102627900A (en) * | 2012-03-20 | 2012-08-08 | 江苏同辉照明科技有限公司 | Preparation method of anti-ultraviolet paint |
| EP2832705A4 (en) * | 2012-03-27 | 2016-03-02 | Nippon Sheet Glass Co Ltd | Glass sheet on which is formed coating suitable for preventing burning, and method for producing same |
| US9802859B2 (en) | 2012-03-27 | 2017-10-31 | Nippon Sheet Glass Company, Limited | Glass sheet on which is formed coating suitable for preventing weathering and method for producing same |
| CN103012634A (en) * | 2012-12-10 | 2013-04-03 | 苏州市明大高分子科技材料有限公司 | Organic phosphate modified acrylate oligomer cured by ultraviolet light and preparation method of organic phosphate modified acrylate oligomer |
| CN103012634B (en) * | 2012-12-10 | 2015-09-23 | 苏州市明大高分子科技材料有限公司 | Phosphate modified origoester acrylate of a kind of ultraviolet light polymerization and preparation method thereof |
| CN108137401A (en) * | 2015-09-28 | 2018-06-08 | 积水化学工业株式会社 | Intermediate film for laminated glasses and laminated glass |
| CN108137401B (en) * | 2015-09-28 | 2021-09-28 | 积水化学工业株式会社 | Interlayer film for laminated glass and laminated glass |
| CN108034028A (en) * | 2018-01-11 | 2018-05-15 | 浙江鸿安建设有限公司 | A kind of novel building outer wall thermal insulation material and preparation method thereof |
| CN114956590A (en) * | 2022-05-05 | 2022-08-30 | 顾晓明 | Anti-ultraviolet heat-insulating glass and preparation method thereof |
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| CN101514274B (en) | 2013-01-09 |
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