CN101512353A - Determining quality of lubricating oils in use - Google Patents
Determining quality of lubricating oils in use Download PDFInfo
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- CN101512353A CN101512353A CNA2006800206915A CN200680020691A CN101512353A CN 101512353 A CN101512353 A CN 101512353A CN A2006800206915 A CNA2006800206915 A CN A2006800206915A CN 200680020691 A CN200680020691 A CN 200680020691A CN 101512353 A CN101512353 A CN 101512353A
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2888—Lubricating oil characteristics, e.g. deterioration
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/30—Oils, i.e. hydrocarbon liquids for lubricating properties
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R27/00—Arrangements for measuring resistance, reactance, impedance, or electric characteristics derived therefrom
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- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Lubrication Details And Ventilation Of Internal Combustion Engines (AREA)
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Abstract
Resistivity p values of a lubricating oil are repeatedly determined at a predetermined temperature (range) as it is in use in a working mechanism such as a vehicle engine. Such accumulated properties over operating time of the working lubricant can be plotted graphically to display a curve with, for example, a first portion where drho/dt>0, a maximum rhomax at a time t1 where drho/dt=O, a second portion where drho/dt<0, a minimum rhomin at a time t2 where drho/dt again is zero, and a third portion where drho/dt>0. Furthermore, there can exist another time t3, where drho/dt exhibits a discontinuous change (increase) with time. Characteristics of the rho vs. t curve, including, the values of T1, t2, t3, rhomax, rhomin, and the ratio rhomax/rhomin can be compared with like data on like lubricant oils in estimating the remaining useful life of the present operating lubricant oil.
Description
Technical field
The present invention relates to method that the quality that is used for the lubricating oil in engine, machine or other lubricating structure is determined.More specifically, the present invention relates to the use of electrically measuring, be used for estimating that this lubricant is in the quality of its running environment (such as, remaining useful life longevity).
Background of invention
Oil uses as in-engine lubricating fluid, and this engine is used for land vehicle, sea and air transport, generating and other explosive motor and uses.Oil also is used for the sliding contact surface in the lubrication machine, and they in using as plurality of devices heat transfer fluid and use.In many application of these engines and machine, oil is heated to more than the environment temperature in well-oxygenated environment well, and bears shearing force, and it has worsened oil on chemical property.Oil also may bear the pollution of spontaneous combustion or other external source.Therefore, the initial composition of oil changes gradually and its lubricating property worsens, and the initial composition of oil provides the specific lubricating property of oil.
One group of lubricant comprises oil, and it uses as lubricant and in motor car engine with in other engine of broad range widely in large quantity.These usually are low to moderate 250 low viscous lubricant as the rectifying product of crude oil and the scope of the oil of making from molecular weight, up to the lubricant of molecular weight up to about 1000 very thickness.The physical characteristics of this engine lubricant and Performance Characteristics depend on the relative distribution of paraffinic components, aromatised fraction and alicyclic ring (cycloalkanes) component.According to the application of engine, these essential oils are deployed into and comprise special adjuvant, such as oxidation inhibitor, rust preventive, wear-resistant high pressure agent, friction modifiers, detersive, pour-point depressant, viscosity index improver, foam inhibitor and the anti fouling agent of undermining.Commercial engine oils is deployed into most of in the adjuvant that comprises these kinds or all.Except petroleum base or ore deposit base (mineral-based) lubricant, synthetic molecules carbon containing and/or contain silicon grease and be developed out is used and other machine that need lubricate or mechanism use for use in automobile.
The exploitation of lubricating oil is a complicated technology, but is used to determine the lubricating oil that uses in engine or other mechanism, and the technology of terminal point that when arrives its useful life longevity is so not progressive.Typically, fixedly distance travelled, time or based on the algorithm of engine operational conditions are approached the terminal point of its useful life longevity and the sign that should change and using as oil.These indicators are exclusively used in the residual life of underestimating oil usually, so that avoid engine or other mechanism are caused damage.Need a kind of more accurate method, be used for determining the residue useful life longevity of in-house lubricating oil.This method should not have to abandon under the situation of material too soon, and the useful life longevity of lubricating oil is utilized, and should avoid long time ground to use fluid, to such an extent as to main frame or engine are worked the mischief.
Brief summary of the invention
Enforcement of the present invention will be showed such as the engine that uses Fuel Petroleum and the form of explosive motor with operating motor car engine.Yet be understood that: the present invention can be used for assessing the residue useful life longevity of high resistance lubricating oil, and in fact this high resistance lubricating oil run in any engine or the mechanism.
In representational motor car engine, the fuel tank of oil (ore deposit base) in crankcase is pumped, and around the rotation of engine and reciprocating member and above the rotation of engine and reciprocating member and splash and circulation.The launched machine of oil is heated to uniform temperature, and the scope of this temperature is from such as about 50 ℃ to about 150 ℃, and is exposed in the oxidizing atmosphere.In engine operation process, a small amount of part of representing of recycle oil is transferred via suitable compact impedance transducer every now and then, and this compact impedance transducer is positioned in the oil duct easily, oil sump is interior or any other is located on or near on the appropriate location of engine.Sensor setting and be configured to allow oil this sensor of flowing through, and flow with the form of one or more relative film threads, so that determine the resistance of the current time of fluid.In the operational process of engine, obtained the record (course) of the resistance value ρ of the oil of working.Simultaneously easily obtained DIELECTRIC CONSTANT, and this DIELECTRIC CONSTANT also can be used for the life-span of pre-detecting residual oil.
When requiring the data relevant with the characteristic of oil, sensor is started by suitable a-c cycle generator.The inner time-varying electric field that produces of the fluid of the voltage of input pickup in test.Output current, and output current sensed with the phasing degree between the voltage that applied, and these data are directed to local microprocessor with input voltage value, this microprocessor can be the control module of engine in the automobile application.Voltage, electric current and phase angle signal can be used for impedance amplitude, resistance and the reactance of calculating sensor-oil combination then, and these numerical value are used for determining the resistance by the oil of sensor successively, and the extra alternatively specific inductive capacity of determining by the oil of sensor.Oil performance data (resistance ρ and DIELECTRIC CONSTANT) is stored in the microprocessor of vehicle carrying (perhaps engine bearing or machine carrying), is used for subsequent treatment and analysis.When obtaining the electric characteristics data, the temperature of oil is also put down in writing.
The resistance ρ of oil is directly proportional with towing tension, this towing tension is stood by free charge carrier (free electron), therefore this free charge carrier moves via medium under applying electric field effects, and is directly proportional with the viscosities il of medium, and with the number density N of free charge carrier (free electron)
i, perhaps ρ～η/N
iBe inversely proportional to.Therefore, under the situation of the quantity constant (promptly not existing under the situation of the chemical reaction that discharges free electron) of free charge carrier, resistance is represented the measurement of fluid viscosity.Specific inductive capacity is to the more directed measurement of the molecular dipole in the lubricant under applying electric field effects.When the dipole moment d of its microscopic changes, the specific inductive capacity of oil will change, the change of dipole moment d is by adding in the oil such as water, ethanol or ethylene glycol such as chemical reaction (it is oxygen atom or nitrogen-atoms, or the chemical group that comprises oxygen atom or nitrogen-atoms is attached in the molecule key element of oil) or with polar liquid and carrying out.The electric field that applies except bearing, the dipole in the fluid also bears thermal motion.Electric field trends towards dipole is alignd in parallel and direction with respect to electric field, and thermal motion then trends towards destroying this alignment, and upsets the dipole orientation by molecular collision.In addition, the viscous force rotation of dipole in electric field that will trend towards slowing down, slow down simultaneously thermal motion to they alignment upset effect (randomizing effect), so specific inductive capacity also will depend on the viscosity of medium.Therefore, specific inductive capacity has ratio epsilon～η N
d, and N
dNumber density for the dipole in the medium.Be to be understood that: lubricant viscosity is that the inspiration purpose of data interpretation obtains with respect to the previous ratio of its resistance and specific inductive capacity, and the resistance of fluid and the accurate acquisition of the relation between the specific inductive capacity make and use the statistical mechanics with lot of complexity to necessitate.
The resistance change of oil has reflected oily physics and chemical modification as the function of engine working time, and its time dependence has the sign that has shown oily quality.The various features of these signs is used for determining the quality of lubricating oil, predicts its out-of-service time simultaneously.The method is preferably implemented by compact impedance-response sensor, compact impedance-response sensor is installed in the interior any appropriate location of lubricating system, and implement by control/interpretation algorithms, control/interpretation algorithms can be used as autonomous device and carries out, and perhaps is attached in the computing machine that is pre-existing on engine or other lubricating system.The present invention is applicable to automobile, but also is applicable to the device (such as ship, train, generator etc.) that other engine promotes, and have in office where manage the class oil substances (such as, oil is used as heat-exchange fluid) intrasystem potential application.
According to the frequency and the intensity of vehicle motor operation, engine oil was intended to be used in stage such as several months or several years.Therefore, such as after each a few hours of engine operation, the resistance data of oil is accumulation therefore and intermittently, so that write down the course of these oily characteristics.Preferably, this oily performance data obtains in roughly the same temperature place (or in narrow temperature range), and this temperature is selected in the oily service condition scope of routine, and the acquisition of this routine oil service condition scope and weather or weather conditions are irrelevant.
When the unit of being considered as on figure be megaohm centimetre M Ω cm oil resistance ρ (y axle) with respect to the accumulation and unit for hour test duration t (x axle) time, the accumulation resistance data that is stored in the microprocessor has shown curve, this curve has characteristic useful when estimating the residue useful life longevity of oil, and this oil runs in engine or the machine.Such as, under the situation of typical passenger car motor oils, resistance value (d ρ/dt〉0) in the hours run of accumulation stably is increased to maximal value (at t from the initial value that is used for fresh oil
1The place is in the time of d ρ/dt=0).This can think area I.Be accompanied by extra hours run, the resistance value of oil stably reduces (d ρ/dt＜0 now) and arrives minimum value (at t
2The place, and d ρ/dt is when being 0 once more) (area I I).After this, be accompanied by further working time, resistance value continues stably to increase, and exhausts at area I II up to the useful life longevity of oil.The end of lubricant useful life longevity is by at time t
3The very fast resistance value that (zone 4) located increases and learns.This " knee " can be identified by the rapid increase of the time-derivative value of resistance: (d ρ/dt)
T＜t3＜＜(d ρ/dt)
T〉t3
Therefore, the ρ of accumulation that is considered as continuous linearity curve has shown three continuous slopes (d ρ/dt) change with respect to time data.Curve has shown that also (minimum and maximum, at this, d ρ/dt=0), shown " knee " simultaneously is characterized in that the unexpected increase of slope d ρ/dt for two local extremums at the special time place in the process of the use of oil.These minimum and maximum ρ value time corresponding are observed the time of knee, and are comprised ratio ρ
Max/ ρ
Minρ value itself use as the indicator of oil quality, and use as the fallout predictor of out-of-service time of in-engine oil.
From the description of attached preferred embodiment down, it is obvious that other purpose of the present invention and advantage will become.
The accompanying drawing summary
Fig. 1 is the figure of the resistance ρ of the representative engine oil in the spark ignition engine with respect to test duration t, and this spark ignition engine runs under the steady-state condition;
Fig. 2 is the figure of the viscosities il of the engine oil among Fig. 1 with respect to test duration t, and engine oil is positioned at engine, and this engine runs under the steady-state condition;
Fig. 3 is that the ratio of resistance (M Ω cm) and viscosity (cSt) of standard ore deposit base engine oil S (empty circles data point) and improved hybrid-engine oil A (hollow triangle data point) is with respect to hour figure of the test duration of expression;
Fig. 4 is discarded ore deposit base engine oil O (upper curve), standard ore deposit base engine oil S (middle part curve) and the resistance ρ of improved hybrid-engine oil A (lower curve), and M Ω cm is with respect to the figure with engine working time of hour representing;
Fig. 5 is the side cross-sectional, view of flow type (flow-through) impedance transducer, and this sensor is used for determining the electrical characteristics of lubricating oil such as in the operational process of the engine of implementation process of the present invention;
Fig. 6 is the functional-block diagram that combines the electronic device of operation with impedance transducer, is used for determining at engine operation process the electrical characteristics of lubricating oil; And
Fig. 7 is the view of instrument, and it is used for monitoring at engine operation process the electrical characteristics of lubricating oil.
Preferred embodiment describes in detail
The present invention is used for determining the quality of engine oil and the method for useful life longevity.This method is used suitable flow of lubricant general formula electric impedance sensor, is used to monitor in engine or the electrical characteristics of the oil that uses in other travelling mechanism.And the enforcement of this method is supported by suitable electronic instrument.
Method
It is difficult that the time dependence of the specific inductive capacity of relevant engine oil and conductance is made the reasoning prediction, because they are complicacy fluids, the potpourri that comprises a large amount of molecular compounds, and in the limited phase process of engine oil operation life, a factor or another factor can be occupied an leading position with respect to all other factorses, and balance changes along with the use of oil.Yet, in the useful life longevity of oil, based on the average operating of oil, and according to the known behavioral trait of oil viscosity, measurable to a small amount of general trend, wait to determine the material impact of factor thereby hindered other.In most useful life longevity processes of in-engine oil, oil viscosity stably increases, and except stage short period when its life-span begins (nearly 10-15 hour), this moment, it may reduce owing to the cause of shear shinning.Viscosity be increased in the terminal point of useful life longevity of oil the time quicken, and through the turning point in dependent slope d of its time ρ/dt.Therefore, existence is used for resistance and specific inductive capacity and the expectation of the trend of increase usually along with the time simultaneously.Engine oil as all hydrocarbons, more belong to a kind of nonpolar dielectric fluid, and the scope of its specific inductive capacity is from 2-3.The specific inductive capacity of expectation oil increases in the whole process in the life-span of oil, because combustion process will cause the oxidation of molecular components of engine oil and nitrated, and also water may be incorporated in the engine oil.The resistance value very high (scope from M Ω cm to G Ω cm) of expectation oil is removed nonspecific service condition and is caused the accumulation of water from combustion process, and it will reduce resistance by charge carrier (proton) being incorporated in the oil.The existence of water in engine oil even quantity seldom, also can cause the remarkable increase of its specific inductive capacity, because the DIELECTRIC CONSTANT of water=80.The remarkable quantity of water in engine oil also can reduce the numerical value of measured resistance, because the automatic ionization of water can be discharged into free charge carrier (proton) in the oil.As these true consequences, must cautiously select measuring condition (to measure in temperature and the engine operation cyclic process, promptly start, steady state (SS) operation, transition be such as quickening or slowing down or accurate measurements moment when closing), so that the possibility of mistake in reducing to diagnose, this mistake is caused by effect, rather than caused by the effect relevant with oil deterioration, this oil deterioration is caused by engine operation institute.
When engine moved under steady-state condition, the example of the resistance of oil and the time dependence of viscosity was showed in respectively among Fig. 1 and Fig. 2.When the unit of being considered as on figure be megaohm centimetre M Ω cm oil resistance ρ (y axle) with respect to unit for hour accumulation test duration t (x axle) time, the accumulation resistance data that is stored in the microprocessor has shown curve, this curve has characteristic useful when estimating the residue useful life longevity of oil, and this oil runs in engine or the machine.As shown in Figure 1, in the time dependence of resistance, there are four different zones.In area I (d ρ/dt〉0), resistance value is along with the hours run of accumulation, and stably is increased at time t from the initial value that is used for fresh oil
1Or t
MaxThe maximal value ρ at place
Max(in the time of d ρ/dt=0).In area I I, the resistance value of oil stably reduces along with extra hours run (now d ρ/dt＜0), up to them at time t
2Or t
MinThe place reaches minimum value ρ
Min(when d ρ/dt equals 0 once more).After this, in area I II, be accompanied by further working time, resistance value continues stably to increase, and exhausts up to the useful life longevity of oil.This can pass through at time t
3(t
Knee) in the time dependence of the resistance located " knee " (" knee ") and obtain, this shows the startup of area I V, area I V is characterised in that increasing very fast of resistance value.This " knee " can be identified by the rapid increase of the time-derivative value of resistance (being almost discontinuous " jump " in some cases): (d ρ/dt)
T＜t3＜＜(d ρ/dt)
T〉t3
Therefore, the accumulation ρ that is considered as continuous linearity curve has shown the sign change of three continuous slope d ρ/dt with respect to time data.Curve has shown that also (minimum and maximum, at this, d ρ/dt=0), shown " knee " simultaneously is characterized in that the unexpected increase of slope d ρ/dt for two local extremums at the special time place in oily use.
By contrast, as shown in Figure 2, viscosity has only represented the monotone variation on the identical time interval, and between the time interval feature of as broad as long property, this time interval is corresponding to the area I in the time dependence of resistance, II and III.Yet, at t sometime
KneeExist in the time dependence of viscosity " knee ", this is t constantly
KneeThe moment when fierce the variation taken place in the time dependence of resistance is identical.Area I among Fig. 2 has shown the stably ever-increasing viscosity of oil, arrives t up to the use or the test duration of oil
KneeOccur in greater than t
KneeThe precipitous viscosity in the moment (the area I I among Fig. 2) increase, shown the end of oily useful life longevity.At engine in the working time corresponding to the area I among Fig. 1, II and III, the analysis data of oil (and, especially viscosity) have not represented fierce variation.Yet viscosity has represented fierce increase in area I V, thereby has shown by the improper lubricated upcoming power failure that causes.
The end of the useful life longevity that some though (but not being whole) traditional oil analysis method can detection of engine oil, yet corresponding to the moment of maximal value in the time dependence of resistance value ρ and minimum value, and the ρ value self can be used as the indicator of oil quality and uses, and can be used as engine interior oil out-of-service time fallout predictor and use.In addition, the t in the time dependence of resistance
3" knee " located can be used as the end-of-life indicator of engine oil and uses, and overlaps with the moment that sign engine oil viscosity begins fierce increase because moment takes place for it.The existence that area I in the time dependence of resistance and II (with reference to figure 1) have disclosed two (may be relevant) chemical processes, it betides on two visibly different time scales.The time dependence of the resistance in the area I by the rapid chemical process (current for example in, have from 1-20 hour characteristic time scale) control, this rapid chemical process exhausts charge carrier, and the time dependence of the resistance in the area I I by chemical process at a slow speed (current for example in, have from 40-150 hour characteristic time scale) control, this at a slow speed chemical process the free charge carrier is discharged in the oil.It should be noted that: as shown in Figure 3, the resistance increase that betides in area I II and the IV only is because the cause that viscosity increases, it is that the oil of two kinds of different qualities has shown the ratio between resistance and the viscosity, this ratio with area I II and IV time corresponding in almost constant, it shows: all are discharged into the interior chemical process of oil with free ion, stop on any appreciable degree, at this moment, resistance is at time t
2Reach minimum value.
The basis of this method is being represented in above-mentioned discovery, and this method is used for determining the useful life longevity of lubricating oil, and this lubricating oil is used for explosive motor, and this basis causes following algorithm.
(1) survey sensor impedance Z (f on one or more frequencies of separating by the decimal system step pitch on the known temperature; T, T)=Z ' (f; T, T)+iZ " (f; T, T), it is as the function of time.
(2) determine the resistance ρ of oil and make up its time course.
(3) estimate oily useful life longevity from derivative d ρ/dt:
If I. in measurement time t ',
And
T then
M=t '; Use t
MObtain first estimation of oil out-of-service time.
If II. when measuring, ask t ",
And
T then
m=t "; Use t now simultaneously
mAnd t
MThe improvement that obtains the oil out-of-service time is estimated.In addition, or alternatively, numerical value ρ
Max, ρ
MinAnd/or ratio ρ
Max/ ρ
MinAlso can compare, so that estimate the out-of-service time with previous data.
Alternatively, ask derivative d in the time of also can selecting to calculate second order
2P/dt
2,, rather than use inequality so that distinguish minimum and maximumly
Distinguish the 3rd minimum and maximum method and be to use relational expression ρ (t ')＜ρ (t ≠ t ') and ρ (t ") simply in order ρ (t ≠ t ") near its correspondingly position acquisition maximum and minimum.
(4) before the out-of-service time of being predicted reaches, trigger oil and become indicator.
(5) if oil changes as yet, and the time-derivative of resistance is at certain time t " ' experienced unexpected increase, (d ρ/dt)
T＜t " '＜＜(d ρ/dt)
T〉t " ', cry then and issue warning to vehicle or machine operator.
The performance of this method is showed among Fig. 4, and this figure has shown the resistance and the viscosity of the engine oil of three kinds of different qualities respectively.In these oil each is commercial crude oil, and by unspecified additive formulations, adjuvant comprises oxidation inhibitor, rust preventive, wear-resistant high pressure agent, friction modifiers, detersive, pour-point depressant, viscosity index improver, foam inhibitor and the anti fouling agent of undermining.
Fig. 4 is the previous ore deposit base engine oil that forms (O, thick dot-and-dash line), standard oil (S, length dot-and-dash line) and improves oil (A, solid line) with respect to hour resistance data figure of the test duration of expression.Oil O promptly specifies the ore deposit base oil that is used for vehicle tested, so that assess the inventive method in oil component (composition) scope of broad at present.Standard oil S is a GF-3 ore deposit base engine oil, such as being used for the in-engine oil of new vehicle.Improving oily A is to have the synthetic fully GF-3 oil that improves prescription, such as the oil that can be used for the engine break-in by some car owners.Oil sample is respectively applied in the examination of high temperature high capacity engine capacity instrumentation, and in this test, tested engine speed with 3000 rev/mins under the constant load of 103Nm is moved.In the time of taking impedance data away, the oil temperature on the sensor is 130 ℃.
Circulate by its oil pump through the part of the oil of engine, transmit through impedance transducer, as following will as described in, it is showed in the sectional view among Fig. 5.Use electronic instrument and provide exchange current as impedance transducer in the selected time and in known sensor temperature.The feature of impedance transducer system electronic and function demonstration and be summarized in Fig. 6 and Fig. 7 in.In in test first 20 hours, this instrument and relevant microprocessor induce the impedance of the sensor that is filled with mobiloil, and determine that unit is the resistance ρ of M Ω cm with time interval of 15 minutes clocklike, then determine with 30 minutes the time interval for the remainder in each test.
Be shown in the resistivity history ρ (t) of data represented oil in the engine operation process of reality among Fig. 4.The initial resistivity value of oil O is 680M Ω cm, and the initial resistivity value of oily S is 231M Ω cm, and the initial resistivity value of oily A is 77M Ω cm.Along with the progress of power meter test duration, every kind of oil sample has experienced reducing of charge carrier density N, and the quick increase of their respective resistivity values ρ.The short relatively time in the past after, the resistance value of every kind of oil sample reaches maximal value: oily O is 780M Ω cm in the resistance value of 1.5 tests hour, oily S is 360M Ω cm in the resistance value of 6 tests hour, and oily A is 149M Ω cm in the resistance value of 12 tests hour.Therefore, the resistance of these samples is with respect to the first order derivative of time (d ρ/dt) initially greater than 0.Under every kind of resistance situation, then at t=t
MaxThe time, promptly when slope value be 0, (in the time of d ρ/dt)=0, reach maximal value.The corresponding time of every kind of its maximum resistance of oil arrival is: t
Max, O=1.5 hours, t
Max, S=6 hours, and t
Max, A=12 hours.
After ρ reached local maximum, resistance value subsequently reduced monotonously along with the further test duration (d ρ/dt＜0), up at time t=t
MinWhen (specially corresponding to every kind of oil sample), the local minimum of ρ is detected, and this moment, slope value was zero once more, (d ρ/dt)=0.Oil O is at t
Min=102 hours low value ρ is 148M Ω cm, and oily S is at t
Min=75 hours low value ρ is 200M Ω cm, and oily A is at t
Min=148 hours low value ρ is 86M Ω cm.
Be reflected in test among Fig. 4 before oily S or oily A experience lost efficacy and stop, this inefficacy will be confirmed by the undue increase of its viscosity.O is tested in a period of time that surmounts " dangerous point " for oil.Yet shockingly similarly the characteristic figure is represented corresponding oily sign, and this sign is useful when their residue useful life longevity of prediction or out-of-service time.
For the life prediction of oil supply provides reference data, oil sample can be tested up to inefficacy, so that obtain more detailed d ρ/dt course.These courses can be stored in the storer of microprocessor, and this storer is that the oil sample in the work at present detects and record d ρ/dt data.Though every kind of oil sample (no matter be of identical composition, having composition comparable on function) has experienced different loads and environmental baseline, however d ρ/dt data class like and can be compared, for use in predicting the remaining effectively lubricating life-span reliably.In this way, lubricating oil can fully be used, and does not also abandon obtainable limitedly material too early lavishly.
Impedance transducer
Fig. 5 has described the sectional view of impedance transducer, and this impedance transducer is preferably used in the implementation process of the present invention.The sensor that is showed among Fig. 5 can be positioned such as in the oil duct of operating vehicle motor or in the oil sump.In the operational process of engine, lubricating oil continuously in its fuel tank pump release, this fuel tank is positioned at oil sump, this oil sump around and be positioned at the top of the moving parts of engine.Typically, the temperature of recycle oil measured and be sent to engine control module (or power train control module, PCM) on, it is used to control the operation of engine (and variator).According to the present invention, cause the sensor that it is suitable that oil is flowed through, such as the impedance transducer 10 that is showed among Fig. 5.
In the time of in being positioned oil duct, sensor 10 needs metal shell, and this metal shell comprises cell enclosure 12 and lower unit mounting flange 14.Except can make oil via sensor by the time, case member 12,14 also provides the electric shield of sensor tip to electrical interference, this electrical interference can be caused by pilot spark.Cell enclosure 12 has oily flow port 16.Use for vehicle motor, but these case members can be made such as aluminium alloy by suitable casting or the form metal alloy.Chassis self is placed at sensor under the situation of oil sump inside, do not need special housing, because can provide sufficient electric shield.
Several circular slabs that pile up have formed staggered electric capacity in cell enclosure 12, and have six groups and circumferentially reach vertically Metal Contact pipe 18,19 at interval (in each in 18 and 19 wherein a group be showed among Fig. 5), it is placed perpendicular to plate, and is supporting plate.This group Metal Contact pipe 18,19 electrically contacts providing between a plate.Plate distributes equably with about 1 millimeter interval.First web joint 20 is connected to first group five and replaces on the inner capacitor plate 22 by three groups (wherein one group is showed among Fig. 5) five contact tubes that replace 18.Be positioned at the top of first web joint 20, and with second web joint 24 that this first web joint 20 separates, be connected on second group four the inner capacitor plates 26 that replace by three groups of other four contact tubes that replace 19.Six circumferentially distribute and nonconducting fastening bolt 28 (in the sectional view that two are showed among Fig. 5) is attached to capacitor assembly on the unit mounting flange 14, and this fastening bolt 28 is the vertical set of contact pipe 18,19 of extend past vertically.The insulation course 30 that is positioned on the outside surface of each contact tube 18 has been guaranteed: the current vertical of electric field line and unit is in condenser armature. Circular capacitor plates 20,22,24 and 26 is suitably made by stainless steel (or any other suitable metal or metal alloy, such as nickel, Ying Kenaier, Hastelloy etc.), and has and be approximately 43 millimeters diameter.
As the institute narrate and show, capacitor part utilizes six fastening bolts 28 and is retained on mutually together, and is installed to securely on the unit mounting flange 14, this fastening bolt 28 is made by hard plastic material, so that prevent the short circuit of condenser armature.Six cross-over blocks 32 between web joint 20 and the mounting flange 14 (having showed two) be used to simultaneously to prevent cell capaciator plate 20,22,24 and 26 and mounting flange 14 between short circuit.
Measurement of capacitor with measure being electrically connected between the electronics, by two or preferably four concentric cable (showing) influenced, this concentric cable enters measuring appliance via the coaxial cable port 36 (being arranged in the back in the cross section that is showed in Fig. 5) of unit mounting flange 14, and enter in the unitary space 38, and their inner wire is connected on two lower connecting plates 20 and 24 in couples.Under the situation of four concentric cable, inner wire is connected on two web joints in couples.Concentric cable utilizes high-temperature insulation epoxy resin and is sealed in the unit mounting flange, and their outer conductor then is connected on the cell enclosure electrically.
Certainly, be filled with the fluid in the test in the impedance transducer 10, so that determine the electrical characteristics of fluid.Sensor can become batch mode (by filler cells via one in the port, and then with stopper with the port closure) in operation, also can operation in circulation pattern (making the liquid flows through sensor in the test).When oil when closely flowing between at interval the condenser armature, oil usually or near its running temperature.Oil-filled sensor is connected on the impedance measuring Instrument (LCA instrument, self-poise AC bridge, frequency response analyzer etc.) then, and its electrical impedance is determined on the more interested frequency ranges of institute.The resistance of fluid then can be by measured resistance and location constant and is determined that the specific inductive capacity of fluid then can be determined by the vacuum capacitance of measured electric capacity and unit.
Sensor can be used for determining the resistance (or equivalently, conductance) and the specific inductive capacity of any fluid (engine oil, transmission fluid, be used for engine interior or be used for mach cooling medium, hydraulic fluid, battery electrolyte) of the interested automobile of institute.The characteristic of the engine oil after it has been used to determine fresh engine oil and use.
In addition, in the process of high temperature power meter test, sensor can be used for engine oil is carried out in-service monitoring, and the performance of engine oil surpass 1200 hours and after 130 ℃ test without any remarkable deterioration.
The circuit and the instrument that are used for the life of oil test
Fig. 6 has showed the resistance that is used for definite lubricating oil that uses in a flowchart, and the functional step of extra alternatively specific inductive capacity.Fig. 7 also is a block flow diagram, and it has showed the relation between the electronic installation (instrument) that is used for this fluid monitoring system.These are showed with operating four cycle internal combustion engines is example.
With reference to five process blocks among the figure 6, this process blocks starts from first (top) square frame.When data that need be relevant with the characteristic of oil, sensor is started by suitable a-c cycle generator (being shown in the square frame 1 among Fig. 7), and this a-c cycle generator produces the waveform of known amplitude and frequency.Such as down scanning from 100MHz to 0.1MHz, and each decimal system frequency has 3 to 20 data points to frequency by suitably.This is input in the fluid of voltage in test of oily characteristic impedance sensor and produces time-varying electric field.The timing of input voltage is set by the power train control module (PCM) of the type that is used for modern vehicle, so that the operation of management engine and variator.Oily temperature in the sensor is also sensed and be transferred to PCM, perhaps is transferred to the oily property microprocessor under PCM control.
Output current and output current and pass impedance transducer and phasing degree between the voltage that applies is sensed, and these data and input voltage value together be directed to PCM, as shown in the square frame among Fig. 62.
PCM and phase-locked loop circuit (PLL) interact, so that determine to differ (square frame 3).
Working voltage, electric current and phase angle signal are come impedance amplitude, resistance and the reactance (square frame 4) of calculating sensor-oil combination then.These numerical value are used for definite resistance and/or specific inductive capacity (square frame 5) that passes through the oil of sensor then successively.Oil performance data (resistance ρ and DIELECTRIC CONSTANT) is stored in the PCM, is used for follow-up processing and analysis.
Fig. 7 is by providing the suitable schematic flow diagram that is used for instrument, PCM and is used for determining the special microprocessor of oil, and Fig. 6 is replenished.
The AC signal that frequency generator 1 usefulness has predetermined amplitude and frequency excites oily impedance transducer 2A.Signal is received by phase-sensitive detector 4 simultaneously.Special-purpose 5 pairs of data from frequency generator 1 of microprocessor are sampled, and to sampling from the data of phase-sensitive detector 4.Microprocessor 5 is encouraged by PCM, perhaps under its control and be energized.Therefore, the oily temperature data from oil temperature sensor 2B are provided for microprocessor 5.
Output current signal from sensor 2A is received by current-voltage converter 3.Voltage signal from converter 3 is sent to phase-sensitive detector 4, and sends to the electric current and the phase angles data of being sampled by microprocessor 5.Impedance amplitude, resistance and the reactance of microprocessor 5 calculating sensors.Data that calculate by use and the relevant constant of being stored of the characteristic with sensor 2A, the current resistance value and the dielectric constant values of the oil in microprocessor 5 evaluation works.As part of this manual method as described, these value storage and are used in the algorithm in the microprocessor of special use, this algorithm based on the timing resistor data and/or the time base specific inductive capacity data.
Consequent oil life data is transferred to PCM6 from microprocessor 5, and PCM6 notifies current deep-fried twisted dough sticks spare to vehicle operator regularly.
By being described with reference to certain embodiment, these embodiment are the purpose of explanation in enforcement of the present invention, rather than provide for limiting purpose of the present invention.
Claims (24)
1. the method for the residue useful life longevity of the certain gauging in the fluid lubrication of determining to be used in travelling mechanism, described method comprises:
Working time of described mechanism at interval in, repeatedly determine the numerical value of the resistance (ρ) of described oil when predetermined oil temperature;
Write down the course of the resistance-time ρ (t) of described oil, thereby when the lasting resistance value that start from initial value along with the working time that disappears the time of accumulation, continuous ρ (t) linearity curve is formed, described curve comprises: (1) has d ρ/dt〉first of 0 slope, up to very first time t
1, the ρ value increases in described first; And (2) are at time t
1The time maximal value, at described time t
1The time d ρ/dt=0, and have corresponding ρ
Max
The part that described ρ (t) linearity curve was existed at that time compares with similar tentation data every now and then, and described tentation data is the data of comparable oil component on similar or the function; And
Use described fiducial value to predict the residue useful life longevity of described oil.
2. the method that is used for the residue useful life longevity of definite certain gauging as claimed in claim 1 is characterized in that described method further comprises:
Continue the course of the resistance-time ρ (t) of the described oil of record, thereby continuous ρ (t) linearity curve is formed, described curve comprises: (3) have the second portion of the slope of d ρ/dt＜0, and the ρ value reduces in described second portion, up to the second time t
2(4) at time t
2The time minimum value, at described time t
2The time d ρ/dt=0, and have corresponding ρ
MinAnd (5) d ρ/dt〉0 third part;
The part that described ρ (t) linearity curve was existed at that time compares with similar tentation data every now and then, and described tentation data is the data of comparable oil component on similar or the function; And
Use described fiducial value to predict the residue useful life longevity of described oil.
3. the method that is used for the residue useful life longevity of definite certain gauging as claimed in claim 2 is characterized in that described method further comprises:
Continue the course of the resistance-time ρ (t) of the described oil of record in the described third part of described ρ (t) curve, up to time t
3, this moment, the time-derivative value of described resistance had unexpected increase, thus the useful life longevity that shows described oil exhausts; And next
Produce signal, described signal shows that the useful life longevity of described oil exhausts.
4. the method for claim 1 is characterized in that, described oil comprises the ore deposit base oil that obtains from oil.
5. the method for claim 1 is characterized in that, described oil comprises synthetic oil, and described synthetic oil comprises carbon-based material and/or silica-base material.
6. the method for claim 1 is characterized in that, described mechanism is the hydrocarbon fuel h type engine h.
7. the method for claim 1 is characterized in that, described in-house oil runs on and is higher than about 100 ℃ temperature.
8. method as claimed in claim 2 is characterized in that t
2/ t
1Be approximately 10 or bigger.
9. the method for claim 1 is characterized in that, t
1Be used to predict the residue useful life longevity of described oil.
10. method as claimed in claim 2 is characterized in that t
1And t
2Be used to predict the residue useful life longevity of described oil.
11. the method for claim 1 is characterized in that, ρ
MaxBe used to predict the residue useful life longevity of described oil.
12. method as claimed in claim 2 is characterized in that, ρ
MinAnd/or ρ
MaxBe used to predict the residue useful life longevity of described oil.
13. method as claimed in claim 2 is characterized in that, described ratio ρ
Max/ ρ
MinBe used to predict the residue useful life longevity of described oil.
14. the method for the residue useful life longevity of the certain gauging in the fluid lubrication of determining to be used in travelling mechanism, described method comprises:
Working time of described mechanism at interval in, and under time-varying electric field, repeatedly determine the numerical value of the resistance (ρ) of described oil when predetermined oil temperature;
Write down the course of the resistance-time ρ (t) of described oil, thereby when the lasting resistance value that start from initial value along with the working time that disappears the time of accumulation, continuous ρ (t) linearity curve is formed, described curve comprises: (1) has d ρ/dt〉first of 0 slope, up to very first time t
1, the ρ value increases in described first; (2) at time t
1The time maximal value, at described time t
1The time d ρ/dt=0, and have corresponding ρ
Max(3) have the second portion of the slope of d ρ/dt＜0, the ρ value reduces in described second portion, up to the second time t
2(4) at time t
2The time minimum value, at described time t
2The time d ρ/dt=0, and have corresponding ρ
MjnAnd (5) d ρ/dt〉0 third part;
The part that described ρ (t) linearity curve was existed at that time compares with similar tentation data every now and then, and described tentation data is the data of comparable oil component on similar or the function; And
Repeatedly use described fiducial value to predict the residue useful life longevity of described oil.
15. the method that is used for the residue useful life longevity of definite certain gauging as claimed in claim 14 is characterized in that described method further comprises:
Continue the course of the resistance-time ρ (t) of the described oil of record in the described third part of described ρ (t) curve, up to time t
3, this moment, the time-derivative value of described resistance had unexpected increase, thus the useful life longevity that shows described oil exhausts; And next
Produce signal, described signal shows that the useful life longevity of described oil exhausts.
16. method as claimed in claim 14 is characterized in that, the ore deposit base oil of described oil for obtaining from oil.
17. method as claimed in claim 14 is characterized in that, described oil is synthetic oil, and described synthetic oil comprises carbon-based material and/or silica-base material.
18. method as claimed in claim 14 is characterized in that, described mechanism is the hydrocarbon fuel h type engine h.
19. method as claimed in claim 14 is characterized in that, described in-house oil runs on and is higher than about 100 ℃ temperature.
20. method as claimed in claim 14 is characterized in that, t
1And t
2Be used to predict the residue useful life longevity of described oil.
21. method as claimed in claim 14 is characterized in that, ρ
MinAnd/or ρ
MaxBe used to predict the residue useful life longevity of described oil.
22. method as claimed in claim 14 is characterized in that, described ratio ρ
Max/ ρ
MinBe used to predict the residue useful life longevity of described oil.
23. the method for claim 1, it is characterized in that, described oil is contained in the impedance transducer, described impedance transducer has known resistance constant, and described sensor is started by input voltage by the a-c cycle generator in time-varying electric field, and the frequency range of described time-varying electric field is from about 100MHz to 0.1Hz;
Phasing degree between detecting sensor output current and described output current and the input voltage;
Determine impedance amplitude, resistance and the reactance of described sensor-oil combination according to described input voltage, output current and phasing degree; And
Determine the resistance of described oil when the described predetermined temperature according to described definite resistance and sensor resistance constant.
24. the method for claim 1, it is characterized in that, described oil is contained in the impedance transducer, described impedance transducer has known resistance constant, and described sensor is started by input voltage by the a-c cycle generator in time-varying electric field, and the frequency range of described time-varying electric field is from about 100MHz to 0.1Hz;
Detect the phasing degree between described current output sensor and described output current and the input voltage;
Determine impedance amplitude, resistance and the reactance of described sensor-oil combination according to described input voltage, output current and phasing degree; And
Determine the resistance of described oil when the described predetermined temperature according to described definite resistance and sensor resistance constant.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/106,309 | 2005-04-14 | ||
| US11/106,309 US7370514B2 (en) | 2005-04-14 | 2005-04-14 | Determining quality of lubricating oils in use |
| PCT/US2006/009743 WO2006113012A2 (en) | 2005-04-14 | 2006-03-17 | Determining quality of lubricating oils in use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101512353A true CN101512353A (en) | 2009-08-19 |
| CN101512353B CN101512353B (en) | 2013-08-21 |
Family
ID=37107888
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006800206915A Expired - Fee Related CN101512353B (en) | 2005-04-14 | 2006-03-17 | Method for determining residual service life of lubricating oils in use |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7370514B2 (en) |
| KR (1) | KR100957597B1 (en) |
| CN (1) | CN101512353B (en) |
| DE (1) | DE112006000894T5 (en) |
| WO (1) | WO2006113012A2 (en) |
Cited By (4)
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| CN102667461A (en) * | 2009-11-25 | 2012-09-12 | 出光兴产株式会社 | Method and device for measuring deterioration and deterioration degree of lubricating oil |
| CN104792973A (en) * | 2015-04-21 | 2015-07-22 | 西南石油大学 | Detection device and detection method for estimating vehicle-mounted engine oil life |
| CN105388270A (en) * | 2014-08-25 | 2016-03-09 | 通用电气公司 | Industrial machine lubricating oil monitoring system, and related methods |
| CN106197530A (en) * | 2015-05-08 | 2016-12-07 | 丹佛斯（天津）有限公司 | Measure the method for lubricating oil dilution degree, sensor and the method for detection oil level |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| US8340928B2 (en) | 2007-09-05 | 2012-12-25 | Yizhong Sun | Sensor and method for detecting oil deterioration and oil level |
| US7729870B2 (en) * | 2007-09-05 | 2010-06-01 | Yizhong Sun | Methods for detecting oil deterioration and oil level |
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Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7043402B2 (en) * | 2001-12-20 | 2006-05-09 | The Precision Instrument Corp. | On-line oil condition sensor system for rotating and reciprocating machinery |
| US6810717B2 (en) * | 2003-03-10 | 2004-11-02 | Delphi Technologies, Inc. | Method for determining engine lubricating oil condition |
| US6876193B2 (en) * | 2003-08-12 | 2005-04-05 | Exxonmobil Research And Engineering Company | Method for deconvolution of impedance spectra |
| WO2005050228A2 (en) * | 2003-11-14 | 2005-06-02 | Impact Technologies, Llc | Electrochemical impedance measurement system and method for use thereof |
-
2005
- 2005-04-14 US US11/106,309 patent/US7370514B2/en not_active Expired - Fee Related
-
2006
- 2006-03-17 KR KR1020077025790A patent/KR100957597B1/en not_active IP Right Cessation
- 2006-03-17 WO PCT/US2006/009743 patent/WO2006113012A2/en active Application Filing
- 2006-03-17 CN CN2006800206915A patent/CN101512353B/en not_active Expired - Fee Related
- 2006-03-17 DE DE112006000894T patent/DE112006000894T5/en not_active Withdrawn
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| CN102667461A (en) * | 2009-11-25 | 2012-09-12 | 出光兴产株式会社 | Method and device for measuring deterioration and deterioration degree of lubricating oil |
| CN102667461B (en) * | 2009-11-25 | 2016-01-06 | 出光兴产株式会社 | Method and device for measuring deterioration and deterioration degree of lubricating oil |
| CN105388270A (en) * | 2014-08-25 | 2016-03-09 | 通用电气公司 | Industrial machine lubricating oil monitoring system, and related methods |
| CN104792973A (en) * | 2015-04-21 | 2015-07-22 | 西南石油大学 | Detection device and detection method for estimating vehicle-mounted engine oil life |
| CN106197530A (en) * | 2015-05-08 | 2016-12-07 | 丹佛斯（天津）有限公司 | Measure the method for lubricating oil dilution degree, sensor and the method for detection oil level |
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Also Published As
| Publication number | Publication date |
|---|---|
| WO2006113012A2 (en) | 2006-10-26 |
| CN101512353B (en) | 2013-08-21 |
| KR100957597B1 (en) | 2010-05-13 |
| US20060232267A1 (en) | 2006-10-19 |
| US7370514B2 (en) | 2008-05-13 |
| WO2006113012A8 (en) | 2007-11-29 |
| KR20080007239A (en) | 2008-01-17 |
| DE112006000894T5 (en) | 2008-06-05 |
| WO2006113012A3 (en) | 2009-04-16 |
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