CN101497782A - Powder material dust suppression agent and preparation - Google Patents
Powder material dust suppression agent and preparation Download PDFInfo
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- CN101497782A CN101497782A CNA2008100067133A CN200810006713A CN101497782A CN 101497782 A CN101497782 A CN 101497782A CN A2008100067133 A CNA2008100067133 A CN A2008100067133A CN 200810006713 A CN200810006713 A CN 200810006713A CN 101497782 A CN101497782 A CN 101497782A
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Abstract
The invention discloses a dust suppressing agent used for powder material, which comprises 0.1-0.7 percent of water soluble polyacrylic ester expressed by the general formula, 0.2-0.5 percent of polyacrylamide, 0.15-1.5 percent of polyacrylate sodium, 0.5-1.5 percent of surface active agent and 77-99 percent of water, wherein R1, R2, and R3 in the water soluble polyacrylic ester are OH, NH2, ONa, NHC(CH3)2CH2SO3H, or alkoxyl containing 2-12 carbon, the molecular weight is 1-40 millions, and the free radical polyreaction is performed for acrylic acid (AA), acrylamide (AM), 2-acrylamide-2-methypropanesulfonic acid (AMPS), sodium acrylate (SA) and alkyl acrylate (RA) so as to obtain the R1, the R2, and the R3. The frostbite-preventing dust-suppressing agent can form a net-like structure with better water keeping property and stronger adhering property when being sprayed on the powder material under the condition of less consumption, thereby meeting the requirement of suppressing the dust and controlling the left spraying of the prior various powder materials when in transportation and storage to a wide range.
Description
Technical field
The present invention relates to a kind of powder material dust suppression agent and preparation method, particularly relate to a kind of dust-inhibitor and production method and using method of in powder body material transportation and stacking process, using.
Background technology
In industrial production; various powders are a kind of material forms that are most widely used; comprise coal, mineral dust, sandstone etc.; but in its transportation and original place when stacking; because the mobilization of air or the effect of jolting of transportation means, and cause dust from flying and Yan Lu to drop through regular meeting, this has not only caused serious environmental pollution; also can cause the serious waste of resource, even also can cause some production safety accidents.If therefore can develop a kind of dust-inhibitor, it is sprayed at powder body material surface, make powder body material form a kind of metastable surface texture, will address this problem to a great extent.
There are some dust-inhibitors to be developed now, but all can not satisfy actual needs, as the aqueous solution that has plenty of volatile-resistant substances such as spent glycol, propylene glycol constitutes, this system can suppress slight airborne dust to a certain extent, can be applied in the environmental sanitation field, but its solid dirt effect is quite faint; Have plenty of with utilizing the styrenic material, obtain latex shape material by letex polymerization, and play the effect of dust suppression, when this system is used for the dust suppression field, addition is bigger, also needs relatively large tensio-active agent, and if this class material can not complete reaction, its environmental toxicity is also bigger, so purposes is limited; It is main body that another system is to use water miscible polyvinyl alcohol, cooperate some tensio-active agents to constitute, this material toxicity is less, but when it uses, can become the polymeric membrane of hard within a short period of time, this is comparatively suitable for the less powder body material of particle, and for the bigger material of particle, its effect that prevents airborne dust is very limited.
Therefore, the invention provides a kind of system based on a kind of water miscible polyacrylate polymer material, it is under the situation of very little usage quantity, in the time of on being sprayed onto powder body material, can form a kind of reticulated structure, thereby can go up very on a large scale when satisfying existing powder body material transportation and stacking suppressing the needs that airborne dust and control are spilt with fine water retention property and very strong viscosifying power.
Summary of the invention
The purpose of this invention is to provide a kind of powder material dust suppression agent, this dust-inhibitor can form the quasi-network structure with certain cohesive strength after being sprayed at the powder body material top layer, and this protective layer does not influence the functions of use of powder body material, but has bonding, dust suppression effect.
Powder material dust suppression agent composition of the present invention and compound method are as described below:
Water-soluble polyacrylate 0.1-0.7%
Polyacrylamide 0.1-0.5%
Sodium polyacrylate 0.15-1.5%
Tensio-active agent 0.5-1.5%
Water 97-99%
In the container of mechanical stirring equipment is housed, the water that adds 97-99%, the water-soluble polyacrylate that under agitation condition, in batches adds 0.1-0.7%, after treating that it dissolves fully, add the polyacrylamide of 0.1-0.5% and the sodium polyacrylate of 0.15-1.5%, the dissolving back adds the tensio-active agent of 0.5-1.5%, obtains the colourless thickness aqueous solution.
Water-soluble polyacrylate is the polymkeric substance by general formula (1) expression, wherein R
1, R
2, R
3Be OH, NH
2, ONa, NHC (CH
3)
2CH
2SO
3H or contain the alkoxyl group of 2-12 carbon, molecular weight is 100-4,000 ten thousand, be by vinylformic acid (AA), acrylamide (AM), 2-acrylamide-2-methyl propane sulfonic acid (AMPS), sodium acrylate (SA), alkyl acrylate (RA) obtains through Raolical polymerizable, and the related industries product has had how tame producer to produce.
Described Molecular Weight for Polyacrylamide is 500-800 ten thousand, and the sodium polyacrylate molecular weight is 10-20 ten thousand, and water is the general industry tap water, and tensio-active agent is nonionogenic tenside, anion surfactant or cats product.
Embodiment:
Application Example 1
In the container of mechanical stirring equipment is housed, the water of adding 97.4%, under agitation condition, add 0.1% molecular weight in batches and be water-soluble AA-AM-SA multipolymer of 1,000 ten thousand, after treating that it dissolves fully, the molecular weight that adds 0.5% molecular weight and be 5,000,000 polyacrylamide and 1.5% is 100,000 sodium polyacrylate, the dissolving back adds 0.5% tensio-active agent OP-10, obtains the colourless thickness aqueous solution, and soltion viscosity is 12cP.
The above-mentioned aqueous solution evenly is sprayed on the powder body material, and the sprinkling amount is 1500-2000ml/m
2, retain after five minutes, promptly can play the dust suppression effect.
Application Example 2
Water-soluble AM-AMPS-SA multipolymer (molecular weight 1,500 ten thousand) 0.2%
Polyacrylamide (molecular weight 7,000,000) 0.2%
Sodium polyacrylate (molecular weight 150,000) 0.1%
SPAN85 1.5%
Water 97.85%
Press the preparation of embodiment 1 method, solution viscosity is 25cP.
After construction, obtain having the material of anti-dust effect.
Application Example 3
Water-soluble AMPS-AM-butyl acrylate (molecular weight 2,000 ten thousand) 0.3%
Polyacrylamide (molecular weight 8,000,000) 0.2%
Sodium polyacrylate (molecular weight 200,000) 0.15%
Cetyl trimethylammonium bromide 0.5%
Water 98.85%
Press the preparation of embodiment 1 method, solution viscosity is 18cP.
After construction, obtain having the material of anti-dust effect.
More than embodiments of the invention are had been described in detail, but described content only is preferred embodiment of the present invention, can not be considered to be used to limit practical range of the present invention.All equalizations of doing according to the present patent application scope change and improve etc., all should still belong within the patent covering scope of the present invention.
Claims (6)
1, a kind of powder material dust suppression agent is characterized in that this dust-inhibitor is composed of the following components by weight percentage:
Water-soluble polyacrylate 0.1-0.7%
Polyacrylamide 0.1-0.5%
Sodium polyacrylate 0.15-1.5%
Tensio-active agent 0.5-1.5%
Water 97-99%
3, be 500-800 ten thousand as claim 1 described Molecular Weight for Polyacrylamide.
4, be 10-20 ten thousand as claim 1 described sodium polyacrylate molecular weight.
5, be nonionogenic tenside, anion surfactant or cats product as claim 1 described tensio-active agent.
6, be used for the transportation of solid mineral and powder thereof and the dust suppression of stacking process as claim 1 described this powder material dust suppression agent.
Priority Applications (1)
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CNA2008100067133A CN101497782A (en) | 2008-01-29 | 2008-01-29 | Powder material dust suppression agent and preparation |
Applications Claiming Priority (1)
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CNA2008100067133A CN101497782A (en) | 2008-01-29 | 2008-01-29 | Powder material dust suppression agent and preparation |
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CN101497782A true CN101497782A (en) | 2009-08-05 |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102925107A (en) * | 2012-11-26 | 2013-02-13 | 周洪卫 | Dust particle falling agent and application method thereof as well as dust falling method |
WO2013156127A1 (en) | 2012-04-17 | 2013-10-24 | Bk Giulini Gmbh | Use of a polymer dispersion as dust control agent |
CN104147888A (en) * | 2014-08-28 | 2014-11-19 | 尹无忌 | Electronegativity membrane-method haze-removing agent and environment atmosphere haze-removing method |
CN104258656A (en) * | 2014-08-28 | 2015-01-07 | 尹无忌 | Disinfecting and purifying agent for environment atmospheric membrane method and environment atmospheric disinfection and purification method |
CN104726064A (en) * | 2015-02-11 | 2015-06-24 | 成都科衡环保技术有限公司 | Macromolecular organic dust suppressant and preparation method thereof |
CN105154091A (en) * | 2015-08-05 | 2015-12-16 | 安徽皖维高新材料股份有限公司 | Sand stabilizing agent for high-saline-alkaline-content desert |
US9821271B2 (en) | 2014-08-28 | 2017-11-21 | Wuji Yin | Gas purification agent and method of using the same |
CN108289816A (en) * | 2015-09-30 | 2018-07-17 | 株式会社爱茉莉太平洋 | The composition containing negatively charged substance for anti-fine dust |
CN112940680A (en) * | 2021-03-27 | 2021-06-11 | 兰州天际环境保护有限公司 | Pavement dust suppressant |
CN113025275A (en) * | 2021-02-26 | 2021-06-25 | 李伟 | Environment-friendly universal multifunctional dust suppressant and preparation method, use method and application thereof |
CN114149789A (en) * | 2021-12-24 | 2022-03-08 | 张伟 | Dust suppressant for preventing construction raise dust and preparation method thereof |
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2008
- 2008-01-29 CN CNA2008100067133A patent/CN101497782A/en active Pending
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013156127A1 (en) | 2012-04-17 | 2013-10-24 | Bk Giulini Gmbh | Use of a polymer dispersion as dust control agent |
US9803121B2 (en) | 2012-04-17 | 2017-10-31 | Kurita Water Industries Ltd. | Use of a polymer dispersion as dust control agent |
CN102925107A (en) * | 2012-11-26 | 2013-02-13 | 周洪卫 | Dust particle falling agent and application method thereof as well as dust falling method |
CN104258656A (en) * | 2014-08-28 | 2015-01-07 | 尹无忌 | Disinfecting and purifying agent for environment atmospheric membrane method and environment atmospheric disinfection and purification method |
CN104147888A (en) * | 2014-08-28 | 2014-11-19 | 尹无忌 | Electronegativity membrane-method haze-removing agent and environment atmosphere haze-removing method |
US9821271B2 (en) | 2014-08-28 | 2017-11-21 | Wuji Yin | Gas purification agent and method of using the same |
CN104726064A (en) * | 2015-02-11 | 2015-06-24 | 成都科衡环保技术有限公司 | Macromolecular organic dust suppressant and preparation method thereof |
CN105154091A (en) * | 2015-08-05 | 2015-12-16 | 安徽皖维高新材料股份有限公司 | Sand stabilizing agent for high-saline-alkaline-content desert |
CN105154091B (en) * | 2015-08-05 | 2018-03-09 | 安徽皖维高新材料股份有限公司 | A kind of high salinity desert ground sand-consolidating agent |
CN108289816A (en) * | 2015-09-30 | 2018-07-17 | 株式会社爱茉莉太平洋 | The composition containing negatively charged substance for anti-fine dust |
CN108289816B (en) * | 2015-09-30 | 2021-09-28 | 株式会社爱茉莉太平洋 | Composition containing negatively charged substance for preventing fine dust |
CN113025275A (en) * | 2021-02-26 | 2021-06-25 | 李伟 | Environment-friendly universal multifunctional dust suppressant and preparation method, use method and application thereof |
CN112940680A (en) * | 2021-03-27 | 2021-06-11 | 兰州天际环境保护有限公司 | Pavement dust suppressant |
CN114149789A (en) * | 2021-12-24 | 2022-03-08 | 张伟 | Dust suppressant for preventing construction raise dust and preparation method thereof |
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Open date: 20090805 |