CN104258656A - Disinfecting and purifying agent for environment atmospheric membrane method and environment atmospheric disinfection and purification method - Google Patents
Disinfecting and purifying agent for environment atmospheric membrane method and environment atmospheric disinfection and purification method Download PDFInfo
- Publication number
- CN104258656A CN104258656A CN201410427502.2A CN201410427502A CN104258656A CN 104258656 A CN104258656 A CN 104258656A CN 201410427502 A CN201410427502 A CN 201410427502A CN 104258656 A CN104258656 A CN 104258656A
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- CN
- China
- Prior art keywords
- agent
- sodium
- ambient air
- embrane method
- disinfectant
- Prior art date
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- 230000000249 desinfective Effects 0.000 title claims abstract description 58
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 9
- 239000012528 membrane Substances 0.000 title abstract description 25
- 238000000746 purification Methods 0.000 title abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 116
- 239000004088 foaming agent Substances 0.000 claims abstract description 46
- -1 polyhexamethylene hydrochloric acid Polymers 0.000 claims description 78
- 239000012080 ambient air Substances 0.000 claims description 61
- CPELXLSAUQHCOX-UHFFFAOYSA-M bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 58
- 239000003570 air Substances 0.000 claims description 48
- 230000001954 sterilising Effects 0.000 claims description 34
- 230000003647 oxidation Effects 0.000 claims description 28
- 238000007254 oxidation reaction Methods 0.000 claims description 28
- 238000007667 floating Methods 0.000 claims description 21
- OSVXSBDYLRYLIG-UHFFFAOYSA-N Chlorine dioxide Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 20
- 229920000642 polymer Polymers 0.000 claims description 17
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 15
- 239000011347 resin Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 229920002401 polyacrylamide Polymers 0.000 claims description 14
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 13
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 13
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 13
- 239000003245 coal Substances 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 12
- 229910052731 fluorine Inorganic materials 0.000 claims description 11
- 239000011737 fluorine Substances 0.000 claims description 11
- YCKRFDGAMUMZLT-UHFFFAOYSA-N fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 11
- 239000004155 Chlorine dioxide Substances 0.000 claims description 10
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 10
- IMROMDMJAWUWLK-UHFFFAOYSA-N ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 10
- 239000006260 foam Substances 0.000 claims description 10
- 241000196324 Embryophyta Species 0.000 claims description 7
- 241001272567 Hominoidea Species 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 6
- YLMGFJXSLBMXHK-UHFFFAOYSA-M Potassium perchlorate Chemical compound [K+].[O-]Cl(=O)(=O)=O YLMGFJXSLBMXHK-UHFFFAOYSA-M 0.000 claims description 6
- MSFGZHUJTJBYFA-UHFFFAOYSA-M Sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 claims description 6
- 238000005660 chlorination reaction Methods 0.000 claims description 6
- 229940043237 diethanolamine Drugs 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 5
- ULUAUXLGCMPNKK-UHFFFAOYSA-N (±)-Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N Dodecanol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N Maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- 229920000881 Modified starch Polymers 0.000 claims description 4
- 239000004368 Modified starch Substances 0.000 claims description 4
- VZJVWSHVAAUDKD-UHFFFAOYSA-N Potassium permanganate Chemical compound [K+].[O-][Mn](=O)(=O)=O VZJVWSHVAAUDKD-UHFFFAOYSA-N 0.000 claims description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 4
- SUKJFIGYRHOWBL-UHFFFAOYSA-N Sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M Sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 4
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 229920000591 gum Polymers 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- 235000019426 modified starch Nutrition 0.000 claims description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 4
- 229920001888 polyacrylic acid Polymers 0.000 claims description 4
- 239000004584 polyacrylic acid Substances 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2R,3R,4S,5R,6S)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2S,3R,4S,5R,6R)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2R,3R,4S,5R,6R)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 3
- RPZANUYHRMRTTE-UHFFFAOYSA-N 2,3,4-trimethoxy-6-(methoxymethyl)-5-[3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxyoxane;1-[[3,4,5-tris(2-hydroxybutoxy)-6-[4,5,6-tris(2-hydroxybutoxy)-2-(2-hydroxybutoxymethyl)oxan-3-yl]oxyoxan-2-yl]methoxy]butan-2-ol Chemical compound COC1C(OC)C(OC)C(COC)OC1OC1C(OC)C(OC)C(OC)OC1COC.CCC(O)COC1C(OCC(O)CC)C(OCC(O)CC)C(COCC(O)CC)OC1OC1C(OCC(O)CC)C(OCC(O)CC)C(OCC(O)CC)OC1COCC(O)CC RPZANUYHRMRTTE-UHFFFAOYSA-N 0.000 claims description 3
- VUKAUDKDFVSVFT-UHFFFAOYSA-N 2-[6-[4,5-bis(2-hydroxypropoxy)-2-(2-hydroxypropoxymethyl)-6-methoxyoxan-3-yl]oxy-4,5-dimethoxy-2-(methoxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)-5-methoxyoxane-3,4-diol Chemical compound COC1C(OC)C(OC2C(C(O)C(OC)C(CO)O2)O)C(COC)OC1OC1C(COCC(C)O)OC(OC)C(OCC(C)O)C1OCC(C)O VUKAUDKDFVSVFT-UHFFFAOYSA-N 0.000 claims description 3
- CWSZBVAUYPTXTG-UHFFFAOYSA-N 5-[6-[[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxymethyl]-3,4-dihydroxy-5-[4-hydroxy-3-(2-hydroxyethoxy)-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxyoxan-2-yl]oxy-6-(hydroxymethyl)-2-methyloxane-3,4-diol Chemical compound O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)OCCO)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 CWSZBVAUYPTXTG-UHFFFAOYSA-N 0.000 claims description 3
- 229920000896 Ethulose Polymers 0.000 claims description 3
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 claims description 3
- 108060003756 HMBS Proteins 0.000 claims description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 3
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims description 3
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 3
- XAPRFLSJBSXESP-UHFFFAOYSA-N Oxycinchophen Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=C(O)C=1C1=CC=CC=C1 XAPRFLSJBSXESP-UHFFFAOYSA-N 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 241000048284 Potato virus P Species 0.000 claims description 3
- 229940033663 Thimerosal Drugs 0.000 claims description 3
- RTKIYNMVFMVABJ-UHFFFAOYSA-L Thiomersal Chemical compound [Na+].CC[Hg]SC1=CC=CC=C1C([O-])=O RTKIYNMVFMVABJ-UHFFFAOYSA-L 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzyl-dodecyl-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 claims description 3
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 claims description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 3
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 3
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 3
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 3
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 3
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 3
- 229920000609 methyl cellulose Polymers 0.000 claims description 3
- 239000001923 methylcellulose Substances 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- QBKSIHCSDPPLJI-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]tetradecan-1-ol;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCC(CO)N(CCO)CCO QBKSIHCSDPPLJI-UHFFFAOYSA-N 0.000 claims description 2
- IQGWPPQNIZBTBM-UHFFFAOYSA-N 2-aminoethanol;sulfuric acid Chemical compound NCCO.OS(O)(=O)=O IQGWPPQNIZBTBM-UHFFFAOYSA-N 0.000 claims description 2
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 claims description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-L 2-sulfobutanedioate Chemical compound OS(=O)(=O)C(C([O-])=O)CC([O-])=O ULUAUXLGCMPNKK-UHFFFAOYSA-L 0.000 claims description 2
- 239000004604 Blowing Agent Substances 0.000 claims description 2
- YMZACFJJXNHQCV-UHFFFAOYSA-N CCO.CCO.CCCCCCCCCCCCOS(O)(=O)=O Chemical compound CCO.CCO.CCCCCCCCCCCCOS(O)(=O)=O YMZACFJJXNHQCV-UHFFFAOYSA-N 0.000 claims description 2
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 claims description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M Cetrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 2
- OSDLLIBGSJNGJE-UHFFFAOYSA-N Chloroxylenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 claims description 2
- MDNWOSOZYLHTCG-UHFFFAOYSA-N Dichlorophene Chemical compound OC1=CC=C(Cl)C=C1CC1=CC(Cl)=CC=C1O MDNWOSOZYLHTCG-UHFFFAOYSA-N 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- SYELZBGXAIXKHU-UHFFFAOYSA-N Lauryldimethylamine oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 claims description 2
- 229950007687 Macrogol ester Drugs 0.000 claims description 2
- 241000539716 Mea Species 0.000 claims description 2
- 241001508687 Mustela erminea Species 0.000 claims description 2
- 229940051841 POLYOXYETHYLENE ETHER Drugs 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N Potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 claims description 2
- 229940045998 Sodium Isethionate Drugs 0.000 claims description 2
- 229940005550 Sodium alginate Drugs 0.000 claims description 2
- KIEOKOFEPABQKJ-UHFFFAOYSA-N Sodium dichromate Chemical compound [Na+].[Na+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KIEOKOFEPABQKJ-UHFFFAOYSA-N 0.000 claims description 2
- BAZAXWOYCMUHIX-UHFFFAOYSA-M Sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 claims description 2
- JXKPEJDQGNYQSM-UHFFFAOYSA-M Sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 claims description 2
- 229960003212 Sodium propionate Drugs 0.000 claims description 2
- KUAZQDVKQLNFPE-UHFFFAOYSA-N Thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 2
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 229960003237 betaine Drugs 0.000 claims description 2
- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
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- 229960005443 chloroxylenol Drugs 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- HQWKKEIVHQXCPI-UHFFFAOYSA-L disodium;phthalate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C([O-])=O HQWKKEIVHQXCPI-UHFFFAOYSA-L 0.000 claims description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-M dodecyl sulfate Chemical compound CCCCCCCCCCCCOS([O-])(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-M 0.000 claims description 2
- QCCKPZOPTXCJPL-UHFFFAOYSA-N dodecyl(dimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCC[NH+](C)C QCCKPZOPTXCJPL-UHFFFAOYSA-N 0.000 claims description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
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- 239000007788 liquid Substances 0.000 claims description 2
- 235000010981 methylcellulose Nutrition 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
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- 229910052700 potassium Inorganic materials 0.000 claims description 2
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- MSXHSNHNTORCAW-UHFFFAOYSA-M sodium 3,4,5,6-tetrahydroxyoxane-2-carboxylate Chemical compound [Na+].OC1OC(C([O-])=O)C(O)C(O)C1O MSXHSNHNTORCAW-UHFFFAOYSA-M 0.000 claims description 2
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- 230000035807 sensation Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000004936 stimulating Effects 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 229940086735 succinate Drugs 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 230000004083 survival Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000029663 wound healing Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/04—Separating dispersed particles from gases, air or vapours by liquid as separating agent by passing the gas or air or vapour through foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C3/00—Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
- B03C3/017—Combinations of electrostatic separation with other processes, not otherwise provided for
- B03C3/0175—Amassing particles by electric fields, e.g. agglomeration
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Abstract
The invention discloses a disinfecting and purifying agent for environment atmospheric membrane method and an environment atmospheric disinfection and purification method. The disinfecting and purifying agent is composed of the following components in percentage by weight: 2 to 25% of disinfecting agent, 20 to 60% of film forming agent, and 20 to 60% of foaming agent. The invention further provides an environment atmospheric disinfecting and purifying method. The resources of raw materials are wide, the raw materials are easy to process, the disinfecting and purifying agent is effective and economic, normal people can use the agent to cope with environment atmospheric disastrous pollution in time, the environment atmospheric disaster can be resolved by the agent, and a convenient and feasible technical scheme is especially provided for eliminating environment atmospheric dangerous dust pollution and possible atmospheric biochemical pollution.
Description
Technical field
The present invention relates to a kind of ambient air embrane method myristylpicolinum bromide agent and ambient air sterilizing and purifying method, especially relate to a kind of flexible, the negatively charged of stability or the water-solubility membrane phase carrier of positively charged---the embrane method myristylpicolinum bromide agent of killing livestock property film bubble and ambient air embrane method sterilizing and purifying method.
Background technology
Now, progressing greatly of science and technology comprises the progress of Measurement for Biochemistry, but the simultaneously also process of dangerous thing and diffusion, the generation of environmental disaster, the pollution disaster haze of ambient air is heavy, especially environment for human survival, atmosphere can biochemical pollution problem, still not simple, directly effective technical measures response environment air biochemical pollution, carry out ambient air sterilization.
On the other hand, people produce and in life and the superfine micro dust particle of PM10, PM2.5 of positively charged produced in natural calamity take the atmospheric haze caused as the leading factor and pollute, very serious, and badly influence the health of people, large-and-medium size cities have to move or close down coal-fired industrial furnace enterprise, and implement stricter enterprise and vehicle and limit and arrange, however, the ambient air haze be on the rise pollutes and is still difficult to effective control, the haze micronic dust time of the drift aloft length of these positively chargeds, distance, coverage is very large.
Current, 1), the filtration method of the interior air-conditioning of the confined space, humidifier, freshener etc. generally acknowledge that feasible administering method includes:; 2), the absorption method of indoor ultrasonic atomizer, cascade, pond, fish jar etc.; 3) plant leaf blade, is utilized to absorb the plant absorption method of absorption; 4), the interior space utilizes the anion sedimentation of power load ion generator.Although these administering method are effective to local space, very weak for the pollution problem of solution atmospheric fallout haze.How to solve the electropositive micro dust particle haze of air to pollute, various countries' technological staff carried out unremitting effort over more than hundred year always, but worldwide environmental protection cooperation, the purifying problem of air, does not find a kind of simple and easy to do solution so far yet.Therefore, a kind of simple, effective ambient air sterilizing and purifying technique is needed.
Summary of the invention
Technical problem to be solved by this invention is, overcome the deficiencies in the prior art, there is provided a kind of and prepare ambient air embrane method myristylpicolinum bromide agent simple, easy to use and ambient air sterilizing and purifying method, can directly to the sterilization of ambient air biochemical pollution, direct purification air haze dust pollution simultaneously.
The technical scheme that the present invention solves the employing of its technical problem is:
The ambient air embrane method myristylpicolinum bromide agent of the present invention, be made up of disinfectant, film forming agent, foaming agent, its mass percent is disinfectant 2 ~ 25%, film forming agent 20 ~ 60%, foaming agent 20 ~ 60%, and each constituent mass percentage sum is 100%.
The preferred mass percent of disinfectant, film forming agent, foaming agent is: disinfectant 5 ~ 20%, film forming agent 30 ~ 50%, foaming agent 30 ~ 60%.
More preferably disinfectant 10 ~ 15%, film forming agent 30 ~ 40%, foaming agent 40 ~ 60%.
Described each component mixes, obtain powdery or paste ambient air embrane method myristylpicolinum bromide agent, or add water and mix, obtain aqueous ambient air embrane method myristylpicolinum bromide agent, or Bian gets, and each component packing or film forming agent and foaming agent mix, the packing of disinfectant component, allocate in proportion in use, add water and make ambient air embrane method myristylpicolinum bromide agent.
Described disinfectant is the toxicity biocide that goes out, preferably as one or more in clorox, calcium hypochlorite, chlorine dioxide, sodium dichloro cyanurate, dichlord isocyanurice acid, potassium hyperchlorate, sodium perchlorate, hydrogen peroxide, potassium permanganate, sodium dichromate, potassium bichromate, tetramethylthiuram disulfide, Efficacious Disinfeitant, toluene-sodium-sulfonchloramide, antiphen, polyhexamethylene hydrochloric acid two guanidine (PHMB), triclosan DP300, chloroxylenol, sodium propionate etc.
Described disinfectant is more preferably one or more in chlorine dioxide, clorox, sodium dichloro cyanurate, potassium hyperchlorate etc.
Water-soluble high-molecular compound or the compound of described film forming agent for there being short-term (in 5 hours) oxidation resistance also can form negatively charged or electropositive water-solubility membrane, as water-soluble fluorine carbon resin, open Pu Shi resin (KEPS resin) (originating from Japanese Di-ichi Kogyo Seiyaku Co., Ltd.), water-soluble poval, anionic or cationic-type polyacrylamide, 2-acrylamide-2-methyl propane sulfonic (AMPS) salt and homopolymerization thereof and copolymer, water-soluble modified starch, natural plant gum, methylcellulose (MC), sodium carboxymethylcellulose (CMC), hydroxyethylcellulose (HEC), hydroxypropyl cellulose (HPC), HEMC (HEMC), hydroxypropyl methylcellulose (HPMC), hydroxy butyl methyl cellulose (HBMC), ethylhydroxyethylcellulose (EHEC), polyanion cellulose (PAC), polyacrylamide, polyacrylic acid and polymethylacrylic acid and copolymer thereof, polyacrylic acid potassium, Sodium Polyacrylate, polyacrylate and copolymer, sodium alginate, macrogol ester, polyvinyl alcohol (PVA), polyethylene glycol oxide (PEO), PVP (PVP), HPMA, copolymer of maleic anhydride and acrylic acid (MBB), at least one in Sulfonated Copolymer of Styrene and Maleic Anhydride etc.
Described film forming agent is more preferably water-soluble fluorine carbon resin, at least one in open Pu Shi resin (KEPS resin) (originating from Japanese Di-ichi Kogyo Seiyaku Co., Ltd.), water-soluble poval, sodium carboxymethylcellulose, water-soluble modified starch, natural plant gum, cationic-type polyacrylamide, sodium carboxymethylcellulose (CMC), polyacrylamide etc.
Described foaming agent for there is good foaming capacity and can not antagonism water-solubility membrane elecrtonegativity or electropositive surfactant, as APES (OP-1 ~ 18), fluorine carbon carboxylate, fluorine carbon sulfuric acid, fluorine carbon sulfonate, fluorine oxidation of coal amine (FN-3,2), neopelex, lauryl alcohol sulfuric acid ethanolamine salt (K
12eA), lauryl sodium sulfate (K
12), F-873 blowing agent, ortho-xylene sodium alkyl sulfonate, sodium phthalate of mono lauryl alcohol (PAS
12), sodium isethionate, rosin soap, colophonium pyrolytic polymer, Teepol (SAS), ammonium alkyl sulfate (NAS), Disodium Undecenylamide Sulfosccinates, sodium alkyl sulfate (K
14), dodecyl sulphate MEA, dodecyl sulphate diethanol amine, dodecyltriethanolamine sulfate, Nonyl pheno (10) ether sodium sulfate, C
12 ~ 14aliphatic alcohol polyethenoxy ether carboxylate (AEC), C12 ~ 14 ammonium alkyl sulfate (NAS), alkoxyethanol acid amides succinic acid monoester sodium salt, dodecyl dihydroxy ethyl betaine, dodecyldimethylammonium hydroxide inner salt (BS-12), C
16 ~ 18alkyldihydxyethyl betaines, hexadecanol mono succinate sodium sulfonate (MS16), cocounut oil acyl diethanol amine amine oxide (GD-4501), oxidation Cocamidopropyl amine (CAO), alcohol ether phthalic monoester sodium salt (PAES), alkyl dimethyl amine oxide (OA), alcohol ether mono sulfosuccinates (SM series), AEO sulfosuccinic acid monoesters ammonium salt (JHZ-120), sulfosuccinate 403, sulfosuccinic acid list lauryl disodium (succinate 201), polyoxyethylene carboxylate, AEO, polyoxyethylene polyoxypropylene copolyether, APES, alkyl polyoxyethylene ether, ethoxylated fatty amines, chlorination cocotrimonium ammonium, dodecyl dimethyl benzyl ammonium chloride, cetyltrimethylammonium chloride, octadecyl trimethyl ammonium chloride, chlorination dihydroxypropyl dimethyl dodecyl base ammonium (1251), ermine oleamide propyl group amine shitosan, cationic guar gum, oxidation of alkyl dimethylamine (OA), dodecyldimethylamine oxide (OA-12), at least one in cocounut oil acyl diethanol amine amine oxide (CAO-30) etc.
Described foaming agent is APES (OP-1 ~ 18), fluorine oxidation of coal amine (FN-3,2), lauryl sodium sulfate (K more preferably
12), neopelex, colophonium pyrolytic polymer, oxidation Cocamidopropyl amine (CAO), at least one in oxidation of alkyl dimethylamine (OA) etc.
The ambient air embrane method myristylpicolinum bromide agent of the present invention, high molecular polymer water-solubility membrane phase carrier is converted into the film forming agent and foaming agent, disinfectant polyphase interactions that have short-term (in 5 hours) oxidation resistance in use procedure---killing livestock property film bubble, there are good mechanical strength and stability in a large number with what produce and have the negatively charged of ultra-high surface area or killing livestock property of the high molecular polymer film bubble of positively charged, contaminated or containing floating movement in haze (PM10, PM2.5 micro dust particle of positively charged) atmosphere.The film bubble if use negatively charged is killed livestock, on the one hand, the superfine micro dust particle (PM10, PM2.5 micronic dust) assembling positively charged in atmosphere is attracted with the negative electrostatic of water-soluble film bubble of killing livestock, on the other hand, with the adhesiveness adsorpting aggregation superfine micro dust particle in an atmosphere (PM10, PM2.5 micronic dust) of the water-soluble film bubble of killing livestock of the high molecular polymer of ultra-high surface area and other floating pollutant as virus, bacterium, fungal spore etc., and killing microorganisms, simultaneously, the water-soluble film phase carrier solubilising of killing livestock of the macromolecular compound of drift absorbs assembles gaseous organic pollutant in atmosphere and possible biochemical poison gas and rapid in the active function groups Oxidative demage of its compound molecule, thus play the effect of sterilization, thus micronic dust superfine in atmosphere and pollutant are condensed into macromolecular compound water-solubility membrane phase carrier---the comparatively big particle that film bubble is loaded with, finally, the elecrtonegativity water-solubility membrane phase carrier of floating movement in atmosphere---film bubble is along with the cohesion of superfine micronic dust and electrical counteract, and air is to high molecular polymer water-solubility membrane phase carrier---the dehumidification of film bubble and be condensed into big particle, gravitate is settled down to earth's surface, microorganism pollutant in ambient air layer being comprised be inactivated and oxidized toxic gas aggregation enter in the powerful micropopulation bacterium operation circle in earth's surface and clear up, thus pollutant effectively in Cleaning Air layer sterilizing.
The film bubble if use positively charged is killed livestock, on the one hand, with the superfine micro dust particle (PM10 in the adhesiveness adsorpting aggregation air of the water-soluble film bubble of killing livestock of the high molecular polymer of ultra-high surface area, PM2.5 micronic dust) and other floating pollutant as virus, bacterium, fungal spore etc., and inactivating microbial, simultaneously, the water-soluble film phase carrier solubilising of killing livestock of the macromolecular compound of drift absorb assemble gaseous organic pollutant in atmosphere and possible biochemical poison gas and rapid by its compound molecule active function groups Oxidative demage the poison that goes out, thus micronic dust superfine in atmosphere and pollutant are condensed into macromolecular compound water-solubility membrane phase carrier---the big particle that film bubble is loaded with, finally, the electropositive water-solubility membrane phase carrier of floating movement in atmosphere---film bubble is along with the cohesion of superfine micronic dust and electrical counteract, and air is to high molecular polymer water-solubility membrane phase carrier---the dehumidification of film bubble and be condensed into big particle, gravitate is settled down to earth's surface, microorganism pollutant in ambient air layer being comprised be inactivated and oxidized toxic gas aggregation enter in the powerful micropopulation bacterium operation circle in earth's surface and clear up, thus pollutant effectively in Cleaning Air layer sterilizing.
The ambient air sterilizing and purifying method of the present invention, the ambient air embrane method myristylpicolinum bromide agent of Bian the present invention, it is the elecrtonegativity of 0.5 ~ 10% or electropositive high molecular polymer foam disinfectant liquid that the stirring that adds water is made containing ambient air embrane method myristylpicolinum bromide agent mass ratio, use film bubble device, elecrtonegativity or electropositive polymeric foam thimerosal are dispensed in the air from aircraft, forming the macromolecular water-soluble film phase carrier of a large amount of negatively charged or positively charged---killing livestock property film bubble is floating to be displaced in contaminated atmosphere, or shoot high machinery from ground or plateau cloth film bubble, dispense negatively charged or electropositive macromolecular water-soluble film phase carrier---killing livestock property film bubble is floating is displaced into contaminated atmosphere zone.
Beneficial effect of the present invention: 1), ambient air embrane method myristylpicolinum bromide agent, the Bian elecrtonegativity or electropositive high molecular polymer water-solubility membrane phase carrier---the killing livestock property film bubble that have short-term oxidation resistance (as 5 hours), utilize the good mechanical strength of high molecular polymer water-solubility membrane, toughness and stability, be displaced in atmosphere so that the form of film bubble is floating, on the one hand, with all kinds of micronic dust and virus in the adhesiveness adsorpting aggregation air of the water-soluble film bubble of killing livestock of high molecular polymer, the floating thing such as bacterium and fungal spore deactivation harmful microorganism, simultaneously, with the gaseous organic pollutant in the solubilization suction air of the water-soluble film phase of killing livestock of high molecular polymer and its active function groups of rapid oxidation and the malicious biochemical reagents that go out, on the other hand, the PM10 in air is assembled with the electrical electrostatic attraction of ultra-high surface area water-solubility membrane, the haze micronic dust of PM2.5 aerosol state, finally, sink to earth's surface after the pollutant (through Oxidative demage active function groups and bacteria inactivation rate) in all atmospheres of cohesion being assembled with polymer membrane, atmosphere pollution is made to enter the operation circle of the powerful microorganism species in earth's surface and clear up, reach the effect of effective sterilizing and purifying ambient air, method simply and effectively.2), wide, the handling ease of embrane method myristylpicolinum bromide agent raw material sources, application is effectively economical, can participate in or response environment air calamity pollution in time for general public, dissolve ambient air pollution disaster, especially the dust haze pollution of removing ambient air harmfulness and possible air biochemical pollution provide easy and feasible technological means.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment 1
A kind of ambient air embrane method myristylpicolinum bromide agent, is made up of disinfectant, film forming agent, foaming agent.Stability chlorine dioxide selected by disinfectant, film forming agent selects elecrtonegativity film forming agent to open Pu Shi resin and sodium carboxymethylcellulose, lauryl sodium sulfate selected by foaming agent, colophonium pyrolytic polymer, APES OP-2, be disinfectant 10% by mass percentage: elecrtonegativity film forming agent 30%(wherein opens Pu Shi resin 10%, sodium carboxymethylcellulose 20%): foaming agent 60%(is lauryl sodium sulfate 35% wherein, colophonium pyrolytic polymer 10%, APES OP-2 15%) ratio batching, first by film forming agent and foaming agent mixing, add the water being equivalent to film forming agent and foaming agent gross weight 3 times to mix, disinfectant packing, obtain ambient air embrane method myristylpicolinum bromide agent.
Get above-mentioned ambient air embrane method myristylpicolinum bromide agent, the morphologic region, gully being provided with consumer waste incineration station to certain is tested.This gully geomorphic province is ringed on three sides by mountains, and air is outstanding dirt all day, and in air, foreign odor very, and around ten several kilometers of residents quite feel uncomfortable and for several times Mass disturbance occur, and detect PM2.5 430.Draft and discharge elecrtonegativity water-solubility membrane phase carrier at each 2 points in highland, both sides---film bubble of killing livestock, to remove peculiar smell and dust haze.
Get above-mentioned embrane method myristylpicolinum bromide agent, by disinfectant, film forming agent, foaming agent mixes, use film bubble device, adding water, to make containing embrane method myristylpicolinum bromide agent mass ratio be the foam solution of 1%, to dispense aqueous fusion in the air from each 2 points of south and north flanks to gully atmospheric region with film bubble device to kill livestock film bubble, the floating moving state of Visual Observations Observations whole gully region film bubble, the initial stage film bubble sedimentation of drift is very fast, peculiar smell rapidly disappears, along with gully regional air becomes transparent, film bubble sedimentation is very slow, aerial film bubble view is beautiful, after about four hours, in the regional atmospheric of gully, film bubble disappears from the visual field, fly worm disappears, air is transparent, people feels pure and fresh, detecting PM2.5 is 12, check that the membrane vesicle being settled down to earth's surface all parcel by micronic dust adhesive aggregation, part film dirt capsule collection fan is blown without dust raising phenomenon.
This test have employed killing livestock property Chlorine Dioxide In Disinfectant, the foreign odor volatilization gas thing molecule that can produce in rubbish in flash disruption air, the ability of Atmospheric Organic Pollutants is removed for improving water soluble polymer film phase carrier, lower molecular weight selected by its elecrtonegativity film forming agent, negative electrical charge group radix is large, film-strength is high, toughness is large opens Pu Shi resin, and it is composite with sodium carboxymethylcellulose, the OP-2 that its surfactant compound lipophile is extremely strong, absorbs ability of aggregation with the solubilising of the relative organic pollution of fortified water soluble film.This embrane method myristylpicolinum bromide agent of test display is respond well to this gully regional atmospheric sterilizing and purifying.
Embodiment 2
A kind of ambient air embrane method myristylpicolinum bromide agent, is made up of disinfectant, film forming agent, foaming agent.Potassium hyperchlorate selected by disinfectant, film forming agent selects elecrtonegativity film forming agent polyacrylamide and sodium carboxymethylcellulose, foaming agent selects oxidation Cocamidopropyl amine and the fluorine oxidation of coal amine FN-3 of sterilizing function, it is disinfectant 5% by mass percentage: elecrtonegativity film forming agent 35%(wherein polyacrylamide 15%, sodium carboxymethylcellulose 20%): foaming agent 60%(is wherein oxidized Cocamidopropyl amine 20%, fluorine oxidation of coal amine 40%) ratio batching, first by film forming agent and foaming agent mixing, add the water being equivalent to film forming agent and foaming agent gross weight 3 times, mix, disinfectant packing, obtain ambient air embrane method myristylpicolinum bromide agent.
Get above-mentioned ambient air embrane method myristylpicolinum bromide agent, the knob of doing sorting consumer waste compost and burning to certain is tested.This regional atmospheric is outstanding dirt all day, and in air, foreign odor very, and around ten several kilometers of residents quite feel uncomfortable and for several times Mass disturbance occur, and detect PM2.5 460.Draft and discharge elecrtonegativity water-solubility membrane phase carrier on structures top, center---film bubble of killing livestock, to remove peculiar smell and dust haze.
Get above-mentioned embrane method myristylpicolinum bromide agent, by disinfectant, film forming agent, foaming agent mixes, use film bubble device, adding water, to make containing embrane method myristylpicolinum bromide agent mass ratio be the foam solution of 3%, aqueous fusion film bubble is dispensed in the air to this regional atmospheric with film bubble device, the floating moving state of Visual Observations Observations whole region film bubble, the initial stage film bubble sedimentation of drift is very fast, along with regional air becomes transparent, film bubble sedimentation is very slow, aerial film bubble view is beautiful, about one hour, periphery and superior air peculiar smell except in compost canopy disappears, air is transparent, fly mosquito disappears, people feels pure and fresh, detecting PM2.5 is 9, check that the membrane vesicle being settled down to earth's surface all parcel by micronic dust adhesive aggregation, part film dirt capsule collection fan is blown without dust raising phenomenon.
This test have employed killing livestock property disinfectant potassium hyperchlorate, the foreign odor volatilization gas thing molecule produced in rubbish in air can be destroyed, for improving water soluble polymer film phase carrier--the sterilizing ability of film bubble, its surfactant has been selected has CAO and FN-3 of bactericidal action composite, film bubble is apart from outside killing livestock property, also have stronger sterilizing ability, so that this factory's garbage compost canopy makes because sedimentation has film bubble rubbish fermentation speed significantly delay.Test display this ambient air embrane method myristylpicolinum bromide agent to this garbage compost and the atmospheric sterilizing and purifying of incineration area effective.
Embodiment 3
A kind of ambient air embrane method myristylpicolinum bromide agent, is made up of disinfectant, film forming agent, foaming agent.Sodium dichloro cyanurate selected by disinfectant, film forming agent selects water-soluble poval and sodium carboxymethylcellulose, the fluorine oxidation of coal amine FN-2 of sterilizing function selected by foaming agent, be disinfectant 20% by mass percentage: film forming agent 40%(is water-soluble poval 10%, sodium carboxymethylcellulose 30% wherein): foaming agent 40% ratio is prepared burden, first film forming agent water-soluble poval is added the water-soluble solution being equivalent to water-soluble poval weight 20 times, add sodium carboxymethylcellulose, foaming agent and disinfectant again, mix, obtain paste ambient air embrane method myristylpicolinum bromide agent.
Get above-mentioned ambient air embrane method myristylpicolinum bromide agent, test to the large-scale landfill yard of certain gully house refuse.This region adopts coal fired power generation because be provided with landfill methane power generation factory, and gully regional atmospheric is outstanding dirt all day, and in air, foreign odor very, and around ten several kilometers of residents quite feel uncomfortable and for several times Mass disturbance occur, and detect PM2.5 > 500.Draft and discharge elecrtonegativity water-solubility membrane phase carrier on structures top, center---film bubble of killing livestock, to remove peculiar smell and dust haze.
Get above-mentioned embrane method myristylpicolinum bromide agent, use film bubble device, adding water, to make containing embrane method myristylpicolinum bromide agent mass ratio be the foam solution of 6%, water-soluble film bubble of killing livestock is dispensed in the air to this regional atmospheric with film bubble device, the floating moving state of Visual Observations Observations whole region film bubble, the initial stage film bubble sedimentation of drift is very fast, along with regional air becomes transparent, film bubble sedimentation is very slow, aerial film bubble view is beautiful, about one hour, periphery and superior air peculiar smell disappear, air is transparent, people feels pure and fresh, detecting PM2.5 is 21, check that the membrane vesicle being settled down to earth's surface all parcel by micronic dust adhesive aggregation, part film dirt capsule collection fan is blown without dust raising phenomenon.
This test have employed killing livestock property disinfectant sodium dichloro cyanurate and can destroy the foreign odor volatilization gas thing molecule produced in rubbish in air, for improving water soluble polymer film phase carrier--the sterilizing ability of film bubble, the FN-2 having bactericidal action selected by its surfactant, film bubble is apart from outside killing livestock property, also have stronger sterilizing ability, region mosquito disappears.Test display this ambient air embrane method myristylpicolinum bromide agent to this garbage loading embeading and the atmospheric sterilizing and purifying of power generation region respond well.
Embodiment 4
A kind of ambient air embrane method myristylpicolinum bromide agent, is made up of disinfectant, film forming agent, foaming agent.Stability chlorine dioxide selected by disinfectant, film forming agent selects electropositive film forming agent cationic-type polyacrylamide and water-soluble fluorine carbon resin, the oxidation of alkyl dimethylamine of sterilizing function selected by foaming agent, oxidation dodecyl dimethyl benzyl amine and fluorine oxidation of coal amine FN-2, it is disinfectant 20% by mass percentage: electropositive film forming agent 35%(wherein polyacrylamide 25%, water-soluble fluorine carbon resin 10%): foaming agent 45%(is oxidation of alkyl dimethylamine 10% wherein, oxidation dodecyl dimethyl benzyl amine 20% and fluorine oxidation of coal amine FN-2 15%) ratio batching, first by film forming agent and foaming agent mixing, add the water being equivalent to film forming agent and foaming agent gross weight 3 times to mix, disinfectant packing, obtain ambient air embrane method myristylpicolinum bromide agent.
Get above-mentioned ambient air embrane method myristylpicolinum bromide agent, test to certain area, gully.This regional atmospheric poor fluidity, miasma accumulation in air, fungal spore floating quantity is large, and almost hang dirt all day, people feels very uncomfortable, detects PM2.5 300.Draft and discharge electropositive water-solubility membrane phase carrier at the highest side roof part in gully---film bubble of killing livestock, to remove peculiar smell and dust haze and spore suspension thing.
Get above-mentioned embrane method myristylpicolinum bromide agent, after wearing safety device, by disinfectant, film forming agent, foaming agent mixes, use film bubble device, adding water, to make containing embrane method myristylpicolinum bromide agent mass ratio be the foam solution of 2%, aqueous fusion film bubble is dispensed in the air to this gully regional atmospheric with film bubble device, the floating moving state of Visual Observations Observations whole region film bubble, the initial stage film bubble sedimentation of drift is very fast, along with regional air becomes transparent, film bubble sedimentation is very slow, beautiful with aerial film bubble view in gully, about one hour, air is transparent, in air, floating thing disappears, detecting PM2.5 is 3, check that the membrane vesicle being settled down to earth's surface all parcel by micronic dust and spore adhesive aggregation, part film dirt capsule collection fan is blown without dust raising phenomenon.
This test have employed killing livestock property Chlorine Dioxide In Disinfectant, can odor molecules in flash disruption air and rapid killing microorganisms, for improving electropositive water soluble polymer film phase carrier--the sterilizing ability of film bubble, its surfactant has selected oxidation dodecyl dimethyl benzyl amine and the oxidation of alkyl dimethylamine of the sterilizing effect having strong stimulation effect (use need with safety device), FN-2 is composite, film bubble is apart from outside killing livestock property by force, the film bubble of sedimentation also has strong sterilizing power, so that this region, gully fly mosquito disappears, in about week age after disappearing in the stimulating effect three hours of its dodecyl dimethyl benzyl ammonium chloride, check the perishable items that this gully region memory puts not rot.This ambient air embrane method myristylpicolinum bromide agent of test display is respond well to the atmospheric sterilizing and purifying of this miasma haze gully atmosphere zone.
Embodiment 5
Ambient air embrane method myristylpicolinum bromide agent described in Example 4; by disinfectant, film forming agent, foaming agent mixing; test to a certain large-scale chicken farm; with film bubble device the institute of normally feeding chicken activity had living space and discharge electropositive film bubble of killing livestock and to carry out disinfection purification; movable without impact on chicken, institute's micronic dust floating thing sedimentation of having living space is thorough, and peculiar smell disappears; mosquito disappears, and foster because of chicken bucket, injured chicken wound healing is very fast wherein.Test display is to large-scale chicken farm space disinfection good purification.
Embodiment 6
A kind of ambient air embrane method myristylpicolinum bromide agent, stability chlorine dioxide selected by disinfectant, film forming agent selects electropositive film forming agent cationic-type polyacrylamide and water-soluble poval, the cationic surfactant octadecyl trimethyl ammonium chloride of sterilizing function selected by foaming agent, chlorination dihydroxypropyl dimethyl dodecyl base ammonium and fluorine oxidation of coal amine FN-3, it is disinfectant 25% by mass percentage: electropositive film forming agent 45%(wherein cationic-type polyacrylamide 25%, water-soluble poval 20%): foaming agent 30%(is agent octadecyl trimethyl ammonium chloride 10% wherein, chlorination dihydroxypropyl dimethyl dodecyl base ammonium 10%, fluorine oxidation of coal amine FN-3 10%) ratio batching, first film forming agent and foaming agent are added the water being equivalent to film forming agent and foaming agent gross weight 5 times to mix, disinfectant packing, obtain ambient air embrane method myristylpicolinum bromide agent.
Get above-mentioned ambient air embrane method myristylpicolinum bromide agent, test to certain large-scale plant in area, gully.This regional atmospheric mobility deviation, due to large-scale pig farm and excrement composting fermentation, in air, peculiar smell is heavier, and fungal spore floating quantity is also large, almost hangs dirt all day, and people's sensation is a little uncomfortable, detects PM2.5 290.Draft and discharge electropositive water-solubility membrane phase carrier respectively in the highest side roof part in gully and pig farm---film bubble of killing livestock, to remove peculiar smell and dust haze and spore suspension thing.
Get above-mentioned embrane method myristylpicolinum bromide agent, use film bubble device, by disinfectant, film forming agent, foaming agent adds water mixing, making containing embrane method myristylpicolinum bromide agent mass ratio is the foam solution of 0.8%, aqueous fusion film bubble is dispensed in the air and in pig farm to this gully regional atmospheric with film bubble device, the floating moving state of film bubble in Visual Observations Observations region, whole gully and pig farm, in region, gully and pig farm, the floating changed condition of film bubble is similar, the initial stage film bubble sedimentation of drift is very fast, along with regional air becomes transparent, film bubble sedimentation is very slow, beautiful with aerial film bubble view in gully, about one hour, air is transparent, in air, floating thing disappears, detecting PM2.5 is 6, check that the membrane vesicle being settled down to earth's surface all parcel by micronic dust and spore adhesive aggregation, part film dirt capsule collection fan is blown without dust raising phenomenon.
This test have employed killing livestock property Chlorine Dioxide In Disinfectant, can odor molecules in flash disruption air and rapid killing microorganisms, for improving electropositive water soluble polymer film phase carrier--the sterilizing ability of the long period of film bubble, its surfactant has been selected has the cationic surfactant of sterilizing effect composite, film bubble is apart from outside killing livestock property by force, the film bubble of sedimentation also has strong sterilizing power, so that this region, gully comprises fly mosquito disappearance in pig farm.This ambient air embrane method myristylpicolinum bromide agent of test display is respond well to the sterilizing and purifying in this gully atmosphere zone atmosphere and pig farm.
Claims (10)
1. an ambient air embrane method myristylpicolinum bromide agent, is characterized in that, is made up of disinfectant, film forming agent, foaming agent, and its mass percent is disinfectant 2 ~ 25%, film forming agent 20 ~ 60%, foaming agent 20 ~ 60%, and each constituent mass percentage sum is 100%.
2. ambient air embrane method myristylpicolinum bromide agent according to claim 1, it is characterized in that, the mass percent of disinfectant, film forming agent, foaming agent is: disinfectant 5 ~ 20%, film forming agent 30 ~ 50%, foaming agent 30 ~ 60%.
3. ambient air embrane method myristylpicolinum bromide agent according to claim 2, it is characterized in that, the mass percent of disinfectant, film forming agent, foaming agent is: disinfectant 10 ~ 15%, film forming agent 30 ~ 40%, foaming agent 40 ~ 60%.
4. ambient air embrane method myristylpicolinum bromide agent according to claim 1 and 2, it is characterized in that, described each component mixes, obtain powdery or paste ambient air embrane method myristylpicolinum bromide agent, or add water and mix, obtain aqueous ambient air embrane method myristylpicolinum bromide agent, or Bian gets, and each component packing or film forming agent and foaming agent mix, the packing of disinfectant component, add water in use and make ambient air embrane method myristylpicolinum bromide agent.
5. ambient air embrane method myristylpicolinum bromide agent according to claim 1 and 2, it is characterized in that, described disinfectant is one or more in clorox, calcium hypochlorite, chlorine dioxide, sodium dichloro cyanurate, dichlord isocyanurice acid, potassium hyperchlorate, sodium perchlorate, hydrogen peroxide, potassium permanganate, sodium dichromate, potassium bichromate, tetramethylthiuram disulfide, Efficacious Disinfeitant, toluene-sodium-sulfonchloramide, antiphen, polyhexamethylene hydrochloric acid two guanidine, triclosan DP300, chloroxylenol, sodium propionate.
6. ambient air embrane method myristylpicolinum bromide agent according to claim 5, it is characterized in that, described disinfectant is one or more in chlorine dioxide, clorox, sodium dichloro cyanurate, potassium hyperchlorate.
7. ambient air embrane method myristylpicolinum bromide agent according to claim 1 and 2, it is characterized in that, described film forming agent is water-soluble fluorine carbon resin, open Pu Shi resin, water-soluble poval, anionic or cationic-type polyacrylamide, 2-acrylamide-2-methyl propane sulfonic salt and homopolymerization thereof and copolymer, water-soluble modified starch, natural plant gum, methylcellulose, sodium carboxymethylcellulose, hydroxyethylcellulose, hydroxypropyl cellulose, HEMC, hydroxypropyl methylcellulose, hydroxy butyl methyl cellulose, ethylhydroxyethylcellulose, polyanion cellulose, polyacrylamide, polyacrylic acid and polymethylacrylic acid and copolymer thereof, polyacrylic acid potassium, Sodium Polyacrylate, polyacrylate and copolymer, sodium alginate, macrogol ester, polyvinyl alcohol, polyethylene glycol oxide, PVP, HPMA, copolymer of maleic anhydride and acrylic acid, at least one in Sulfonated Copolymer of Styrene and Maleic Anhydride.
8. ambient air embrane method myristylpicolinum bromide agent according to claim 7, it is characterized in that, described film forming agent is water-soluble fluorine carbon resin, at least one opened in Pu Shi resin, water-soluble poval, water-soluble modified starch, natural plant gum, cationic-type polyacrylamide, sodium carboxymethylcellulose, polyacrylamide.
9. ambient air embrane method myristylpicolinum bromide agent according to claim 1 and 2, it is characterized in that, described foaming agent is APES OP-1 ~ 18, fluorine carbon carboxylate, fluorine carbon sulfuric acid, fluorine carbon sulfonate, fluorine oxidation of coal amine FN-3, fluorine oxidation of coal amine FN-2, neopelex, lauryl alcohol sulfuric acid ethanolamine salt, lauryl sodium sulfate, F-873 blowing agent, ortho-xylene sodium alkyl sulfonate, sodium phthalate of mono lauryl alcohol, sodium isethionate, rosin soap, colophonium pyrolytic polymer, Teepol, ammonium alkyl sulfate, Disodium Undecenylamide Sulfosccinates, sodium alkyl sulfate, dodecyl sulphate MEA, dodecyl sulphate diethanol amine, dodecyltriethanolamine sulfate, Nonyl pheno (10) ether sodium sulfate, C
12 ~ 14aliphatic alcohol polyethenoxy ether carboxylate, C12 ~ 14 ammonium alkyl sulfate, alkoxyethanol acid amides succinic acid monoester sodium salt, dodecyl dihydroxy ethyl betaine, dodecyldimethylammonium hydroxide inner salt, C
16 ~ 18alkyldihydxyethyl betaines, hexadecanol mono succinate sodium sulfonate, cocounut oil acyl diethanol amine amine oxide, oxidation Cocamidopropyl amine, alcohol ether phthalic monoester sodium salt, alkyl dimethyl amine oxide, alcohol ether mono sulfosuccinates, AEO sulfosuccinic acid monoesters ammonium salt, sulfosuccinate 403, sulfosuccinic acid list lauryl disodium, polyoxyethylene carboxylate, AEO, polyoxyethylene polyoxypropylene copolyether, APES, alkyl polyoxyethylene ether, ethoxylated fatty amines, chlorination cocotrimonium ammonium, dodecyl dimethyl benzyl ammonium chloride, cetyltrimethylammonium chloride, octadecyl trimethyl ammonium chloride, chlorination dihydroxypropyl dimethyl dodecyl base ammonium, ermine oleamide propyl group amine shitosan, cationic guar gum, oxidation of alkyl dimethylamine, dodecyldimethylamine oxide, at least one in cocounut oil acyl diethanol amine amine oxide.
10. one kind uses the ambient air sterilizing and purifying method of ambient air embrane method myristylpicolinum bromide agent as described in one of claim 1-9, it is characterized in that, it is the elecrtonegativity of 0.5 ~ 10% or electropositive high molecular polymer foam disinfectant liquid that the stirring that adds water is made containing ambient air embrane method myristylpicolinum bromide agent mass ratio, use film bubble device, elecrtonegativity or electropositive polymeric foam thimerosal are dispensed sterilization film bubble in the air from aircraft, be displaced in air so that film bubble is floating, or shoot high machinery by film bubble, by polymeric foam thimerosal from ground or plateau to dispensing sterilization film bubble in the air.
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Application publication date: 20150107 |