CN101492885A - Electrostatic resistant textile and method for producing the same - Google Patents
Electrostatic resistant textile and method for producing the same Download PDFInfo
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- CN101492885A CN101492885A CNA2008100195697A CN200810019569A CN101492885A CN 101492885 A CN101492885 A CN 101492885A CN A2008100195697 A CNA2008100195697 A CN A2008100195697A CN 200810019569 A CN200810019569 A CN 200810019569A CN 101492885 A CN101492885 A CN 101492885A
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Abstract
The invention discloses an anti-electrostatic textile in which the fiber is anti-electrostatic involucra-shaped resin coating fiber, the anti-electrostatic durability thereof having a standard measuring result below 3000 V by the JIS L 1094 friction voltage measuring method after being washed for 20 times via JIS L 0217 103 standard. The invention solves the problem that it is difficult, after finishing, to manufacture the anti-electrostatic textile containing daiamid with durability and yellowing resistance.
Description
Technical field:
The present invention relates to a kind of durable antistatic textiles and manufacture method thereof that obtains by the back arrangement.
Background technology:
Along with the development of development of technology and society, people are more and more higher to the requirement of quality of life, and are especially more and more higher to the environmental requirement of daily life.Thus, the product of high-tech content constantly enters into the textiles industry.The processing of the functional treatment of textiles constantly increases, and by giving these special functional added values that improve textiles of textiles, thereby improves people's living environment, satisfies the growing material requisite of people.
In processing of polyamide textiles and use, polyamide fiber all can produce electrification phenomenon each other or with other object contact frictions, if electric charge constantly accumulates and fails to eliminate, will cause various electrostatic phenomenons.Static makes polyamide textiles processing difficulties, easily adsorbs dust, and the electric spark that static produces can set off an explosion and fire.
The antistatic approach that polyamide fiber is commonly used is: antistatic additive is added fibrous inside and surface, but shortcomings such as its combination property is poor, feel is poor, lack of homogeneity, fastness to washing are poor, gas permeability difference; Utilize the blended union mode to sneak into conductive fiber in textiles, its antistatic property and durability be all than more excellent, but its production cost is than higher, the technology more complicated, and feel is relatively poor.
Summary of the invention:
The object of the present invention is to provide a kind of antistatic textile that contains polyamide with high-durability, soft feel.
Technical solution of the present invention is:
A kind of antistatic textile, it is characterized in that: fiber is antistatic epithelium shape resin parcel fiber in this textiles, described antistatic epithelium fiber is for being coated with antistatic epithelium shape resin bed filamentary, and its antistatic durability is for pressing determination method standard test result through after 0217 No. 103 standard wash of JIS L 20 times below 3000V in JIS L 1094 frictional electrifications.
This processing technology is not particularly limited the form of formation fiber construct, can be long fiber, also can be staple fibre.This fiber the cross section shape of monofilament can be different in nature tangent planes such as circle, triangle, flat, hollow.Do not limit described filamentary thickness is special.
The film forming agent composition of antistatic epithelium resin bed is one or more in EU, alkyl acrylate, alkyl alkylacrylate, the siloxane quaternary ammonium.
The polyamide composition is more than 20% of gross weight in this textile fiber.Polyamide in this textiles is nylon 6 or nylon 66.Contain the antistatic particle of nanoscale in the antistatic epithelium resin bed.The antistatic particle of nanoscale is the inorganic particulate that electric conductivity is arranged.The inorganic particulate that electric conductivity is arranged is one or more of nanometer-level silver particle, nanometer-level silver complex compound, Nano-class zinc oxide, nanoscale nickel, nanoscale nickel complex, nanoscale nickel-steel alloy, nanosized copper, nanosized copper complex compound, nanoscale copper-nickel alloy or Nano titanium dioxide.
The manufacturing process of product of the present invention comprises the following steps: successively
The preparation of a, machining textile;
B, working solution modulation: with film forming agent (EU, alkyl acrylate, alkyl alkylacrylate, siloxane quaternary ammonium one or both), bleeding agent (penetrating agent JFC or alkylsulfonate etc.), dispersant (polyacrylate, amido silicon oil, dispersant PAS or hexametaphosphate etc.), oxidant (peroxide, sulphite or persulfate etc.), adhesive (carbodiimides, isocyanates or aziridine etc.) catalyst (selecting different catalyst according to film forming agent) and water is according to following mixed, fully stir and be modulated into antistatic epithelium working solution;
Working solution (1L):
(film forming agent is preferred for film forming agent 5-100g
10-40g decides according to converted goods and performance requirement)
Adhesive 0-20g
Catalyst 0-10g
Bleeding agent 0-10g
Oxidant 0-10g
Dispersant 0～10g
All the other all are soft water;
C, heat treatment: heat treatment is 2～25 minutes under the condition of 80～120 ℃ of temperature, makes antistatic epithelium be wrapped in filamentary surface;
D, washing (deciding choice): after the heat treatment, be to wash 0～20 minute in 50～80 ℃ of water-baths, remove the medicament that is adsorbed on fiber surface in temperature on the processing situation;
E, oven dry, typing: fully dry after the washing, bake out temperature is 80～150 ℃, and it is to finalize the design 0～120 second under 130～190 ℃ the condition in temperature that the back is handled in oven dry.
After above-mentioned processing, the quality of the antistatic resin layer that this fiber surface adheres to is 0.25-50% with respect to fiber quality, preferred 0.4-7%.This adhesion amount was less than 0.25 o'clock its skin membrane thickness low LCL, and antistatic property and durability all compare lowly; This adhesion amount is reasonable greater than 50% o'clock antistatic property, but durability is lower, and cost is also than higher.This adhesion amount in the 0.25-50% scope in, can require regulate according to different fabric.
The adhesion amount formula:
Adhesion amount=((W2-W1)/W1) * 100 (%)
W1: be the quality of fabric body before this processing.
W2: the quality of this processing back fabric body.
Product of the present invention has the characteristic of high-durability, soft feel.
In the scope of harmless purpose of the present invention, can also needs according to look, in fiber, contain dyeing used additives such as acid stain, dispersion dyeing agent, cationic colourant, vital staining agent, direct dyeing agent; Also can in fiber, add functional medicines such as antioxidant, heat stabilizer, fire retardant, antiseptic, anti ultraviolet agent according to other special property needs.
For the conducting particles that is contained in the antistatic skin membrane, preferably more stable to ratio of specific heat, particle diameter below 2000nm, preferred 50-1300nm.
Description of drawings:
The invention will be further described below in conjunction with drawings and Examples.
Fig. 1 is embodiment 1 processing fabric T EM observed result figure later.
Fig. 2 is embodiment 2 processing fabric T EM observed result figure later.
Fig. 3 is embodiment 3 processing fabric T EM observed result figure later.
Fig. 4 is embodiment 4 processing fabric T EM observed result figure later.
Fig. 5 is embodiment 5 processing fabric T EM observed result figure later.
Fig. 6 is embodiment 7 processing fabric T EM observed result figure later.
Fig. 7 is embodiment 8 processing fabric T EM observed result figure later.
Fig. 8 is embodiment 12 processing fabric T EM observed result figure later.
Fig. 9 is embodiment 13 processing fabric T EM observed result figure later.
The specific embodiment:
The article of required preparation and instrument in the processing: converted goods, processing medicament, balance, agitator, ultrasonic disperser, padding machine, steam engine, infrared drier, small-sized drying machine and analytical instrument.
Embodiment 1:
Converted goods:
Nylon 6 (100%) thin fabrics (56T-40-FDY * 56T-40-FDY, density 188 * 109) make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| Methoxy polyethylene glycol methacrylate-styrene polymer |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 20g
Methoxy polyethylene glycol methacrylate-styrene polymer 3g
Ammonium persulfate 2g
Add water and make it become 1 liter, stir.
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: transfer liquid → pad (pick-up rate 36.9%) → steamer (105 ℃ * 3 minutes) → common needle plate setting machine of hot blast type (175 ℃ * 45 seconds)
(3) fabric evaluation and test
(4) the polyamide anti-static fabric that obtains later through above-mentioned processing has the characteristic of high-durability, high washing resistance, soft feel; And reservation fibrillation characteristic.
Embodiment 2:
Converted goods:
Nylon 6 (100%) thin fabrics (56T-40-FDY * 56T-40-FDY, density 188 * 109)
Make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| Nano silver solution (10000ppm) |
| Sodium metasilicate |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 20g
Nano silver solution 4g
Ammonium persulfate 2g
Add water and make it become 1 liter, stir (can adopt ultrasonic dispersing in case of necessity).
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: pre-dispersed 5 minutes of Nano Silver medicament ultrasonic wave → transfer liquid → pad (pick-up rate 35%) → steamer (100 ℃ * 3 minutes) → hot blast type needle plate setting machine (175 ℃ * 45 seconds)
(3) fabric evaluation and test
(4) the polyamide anti-static fabric that obtains later through above-mentioned processing has the characteristic of high-durability, high washing resistance, soft hand feeling and antibiotic property; Keeping above-mentioned performance also to have humidity is to have good antistatic property under 40% situation also to keep the fibrillation characteristic simultaneously.
Embodiment 3:
Converted goods:
Heavy back fabric (160T-68-FDY * 56T-40-FDY, density 82 * 109) in the nylon 6 (100%)
Make with medicament:
| The medicament title |
| EU |
| Sodium thiosulfate |
Processing technology: the composition of (1) used working fluid
EU 30g
Sodium thiosulfate 2g
Add water and make it become 1 liter, stir.
(2) process: fabric is prepared: grey cloth preparation → dyeing; Processing: transfer liquid → pad (pick-up rate 37%) → steamer (100 ℃ * 5 minutes) → common needle plate setting machine of hot blast type (175 ℃ * 45 seconds)
(3) fabric evaluation and test
(4) the polyamide anti-static fabric that obtains later through above-mentioned processing has the characteristic of high-durability, high washing resistance, soft feel; And keep the fibrillation characteristic, and the advantage of this processing for embodiment 1 is that its influence to other processing is less, the range of work is wideer.
Embodiment 4:
Converted goods:
Nylon 6 (100%) thin fabrics (56T-40-FDY * 56T-40-FDY, density 188 * 109)
Make with medicament:
| The medicament title |
| EU |
| Siloxane quaternary ammonium |
Processing technology:
(1) composition of used working fluid
EU 40g
Siloxane quaternary ammonium 5g
Add water and make it become 1 liter, stir.
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: transfer liquid → pad (pick-up rate 37%) → steamer (100 ℃ * 5 minutes) → common needle plate setting machine of hot blast type (170 ℃ * 45 seconds)
(3) fabric evaluation and test
(4) the polyamide anti-static fabric that obtains later through above-mentioned processing has the characteristic of high-durability, high washing resistance, soft feel; And reservation fibrillation characteristic.
Embodiment 5:
Converted goods:
Heavy back fabric (76T-68-FDY * 160T-96-FDY/ density 131 * 71) in the nylon 6 (100%)
Make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| Methoxy polyethylene glycol methacrylate-styrene polymer |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 40g
Methoxy polyethylene glycol methacrylate-styrene polymer 4g
Ammonium persulfate 2g
Add water and make it become 1 liter, stir.
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: transfer liquid → pad (pick-up rate 71%) → steamer (100 ℃ * 5 minutes) → common needle plate setting machine of washing (60 ℃ * 10 minutes) → hot blast type (130 ℃ * 120 seconds) → common needle plate setting machine of hot blast type (175 ℃ * 45 seconds)
(3) fabric evaluation and test
(4) the polyamide anti-static fabric that obtains later through above-mentioned processing has the characteristic of high-durability, high washing resistance, soft feel; And reservation fibrillation characteristic.
Embodiment 6:
Converted goods:
Nylon 6 (100%) thin fabrics (56T-68-FDY * 56T-68-FDY, density 110 * 97)
Make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| Methoxy polyethylene glycol methacrylate-styrene polymer |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 20g
Methoxy polyethylene glycol methacrylate-styrene polymer 3g
Ammonium persulfate 2g
Add water and make it become 1 liter, stir.
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: accent liquid → padding (pick-up rate 36.9%) → decatize heats the common needle plate setting machine of (100 ℃ * 1 minute) → hot blast type (175 ℃ * 45 seconds)
(3) fabric evaluation and test
(4) the polyamide anti-static fabric that obtains later through above-mentioned processing has the characteristic of high-durability, high washing resistance, soft feel; And reservation fibrillation characteristic.
Embodiment 7:
Converted goods:
Nylon 6 (100%) thin fabrics (56T-40-FDY * 56T-40-FDY, density 85 * 91)
Make with medicament:
| The medicament title |
| EU |
| Sodium thiosulfate |
Processing technology:
(1) composition of used working fluid
EU 30g
Sodium thiosulfate 2g
Add water and make it become 1 liter, stir.
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: transfer liquid → the pad common needle plate of (pick-up rate 37%) → steamer (100 ℃ * 5 minutes) → washing (60 ℃ * 8 minutes) → hot blast type common needle plate setting machine of (130 ℃ * 100 seconds) → machine hot blast type (175 ℃ * 45 seconds) of finalizing the design
(3) fabric evaluation and test
(4) the polyamide anti-static fabric that obtains later through above-mentioned processing has the characteristic of high-durability, high washing resistance, soft feel; And reservation fibrillation characteristic.
Embodiment 8:
Converted goods:
Nylon 6 (100%) thin fabrics (56T-40-FDY * 56T-40-FDY, density 188 * 109)
Make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| Nano silver solution (10000ppm) |
| Penetrating agent JFC-1 |
| Sodium metasilicate |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 20g
Nano silver solution 4g
JFC-1 2g
Sodium metasilicate 3g
Ammonium persulfate 2g
Add water and make it become 1 liter, stir (can adopt ultrasonic dispersing in case of necessity).
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: pre-dispersed 5 minutes of Nano Silver medicament ultrasonic wave → transfer liquid → pad (pick-up rate 35%) → steamer (100 ℃ * 3 minutes) → hot blast type needle plate setting machine (175 ℃ * 45 seconds)
(3) fabric evaluation and test
(4) the polyamide anti-static fabric that obtains later through above-mentioned processing has the characteristic of high-durability, high washing resistance, soft feel and antibacterial characteristics; This embodiment is that with respect to the advantage of embodiment 2 the conducting particles distribution is more even, and performance is more stable, and durability has many raisings, and antistatic effect is more outstanding under the low humidity condition, also keeps the fibrillation characteristic simultaneously.
Embodiment 9:
Converted goods:
Nylon 6 (100%) thin fabrics (56T-40-FDY * 56T-40-FDY, density 188 * 109)
Make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| Isocyanates NEO |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 20g
NEO 6g
Ammonium persulfate 2g
Add water and make it become 1 liter, stir.
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: transfer liquid → pad (pick-up rate 36.9%) → steamer (100 ℃ * 4 minutes) → common needle plate setting machine of hot blast type (175 ℃ * 45 seconds)
(3) fabric evaluation and test
(4) the polyamide anti-static fabric that obtains later through above-mentioned processing has high-durability, high washing resistance characteristic; Be compared to embodiment 1 and it is advantageous that to be used to take pliability less demanding but use under the situation that frictional behaviour is had relatively high expectations, and keep the most of performance of fibrillation.
Embodiment 10:
Converted goods:
Nylon 6 (100%) thin fabrics (56T-40-FDY * 56T-40-FDY, density 188 * 109)
Make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| 2-acrylamido-2-methyl propane sulfonic acid |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 20g
2-acrylamido-2-methyl propane sulfonic acid 3g
Ammonium persulfate 3g
Add water and make it become 1 liter, stir.
(2) the process fabric is prepared: grey cloth preparation → dyeing; Processing: transfer liquid → pad (pick-up rate 36.9%) → steamer (100 ℃ * 3 minutes) → common needle plate setting machine of hot blast type (160 ℃ * 45 seconds).(3) fabric evaluation and test:
(4) the polyamide anti-static fabric that obtains later through above-mentioned processing has the characteristic of high-durability, high washing resistance, soft feel; And the overwhelming majority keeps the fibrillation characteristic.
Embodiment 11:
Converted goods:
Nylon 6 (100%) thin fabrics (56T-40-FDY * 56T-40-FDY, density 188 * 124)
Make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| Methacrylate |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 20g
Methacrylate 10g
Ammonium persulfate 3g
Add water and make it become 1 liter, stir.
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: transfer liquid → pad (pick-up rate 36.9%) → steamer (100 ℃ * 3 minutes) → common needle plate setting machine of hot blast type (160 ℃ * 45 seconds)
(3) fabric evaluation and test
(4) the polyamide anti-static fabric that obtains later through above-mentioned processing has the characteristic of high-durability, high washing resistance, soft feel; And the overwhelming majority keeps the fibrillation characteristic.
Embodiment 12:
Converted goods:
Nylon 6 (100%) thin fabrics (56T-40-FDY * 56T-40-FDY, density 190 * 109)
Make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 5g
Ammonium persulfate 0.5g
Add water and make it become 1 liter, stir.
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: transfer liquid → pad (pick-up rate 34%) → steamer (100 ℃ * 3 minutes) → common needle plate setting machine of hot blast type (175 ℃ * 45 seconds)
(3) fabric evaluation and test
(4) by the thickness of its film is at 10nm as can be seen on the TEM, its antistatic property and antistatic durability are all not all right.
Embodiment 13:
Converted goods:
Weft-knitted fabric (nylon 78T, Lycra 20D)
Make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| Methacrylate |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 20g
Methacrylate 5g
Ammonium persulfate 3g
Add water and make it become 1 liter, stir.
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: transfer liquid → pad (pick-up rate 43%) → steamer (100 ℃ * 3 minutes) → common needle plate setting machine of washing (60 ℃ * 8 minutes) → hot blast type (150 ℃ * 180 seconds)
(3) fabric evaluation and test
(4) the polyamide anti-static fabric that obtains later through above-mentioned processing has the characteristic of high-durability, high washing resistance, soft feel; And the overwhelming majority keeps the fibrillation characteristic.
Embodiment 14:
Converted goods:
Tricot (nylon 78T, Lycra 20D)
Make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| Methacrylate |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 20g
Methacrylate 5g
Ammonium persulfate 3g
Add water and make it become 1 liter, stir.
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: transfer liquid → pad (pick-up rate 67%) → steamer (100 ℃ * 3 minutes) → common needle plate setting machine of washing (60 ℃ * 8 minutes) → hot blast type (160 ℃ * 180 seconds)
(3) fabric evaluation and test
(4) the polyamide anti-static fabric that obtains later through above-mentioned processing has the characteristic of high-durability, high washing resistance, soft feel; And the overwhelming majority keeps the fibrillation characteristic.
Embodiment 15:
Converted goods:
Nylon 6 (100%) thin fabrics (56T-40-FDY * 56T-40-FDY, density 190 * 109)
Make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 5g
Ammonium persulfate 0.5g
Add water and make it become 1 liter, stir.
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: transfer liquid → pad (pick-up rate 34%) → steamer (100 ℃ * 3 minutes) → common needle plate setting machine of hot blast type (175 ℃ * 45 seconds)
(3) fabric evaluation and test
(4) by the thickness of its film is at 10nm as can be seen on the TEM, its antistatic property and antistatic durability are all not all right.
Embodiment 16:
Converted goods:
Nylon 6 (100%) thin fabrics (56T-40-FDY * 56T-40-FDY, density 190 * 109)
Make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 200g
Ammonium persulfate 20g
Add water and make it become 1 liter, stir.
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: transfer liquid → pad (pick-up rate 34%) → steamer (100 ℃ * 3 minutes) → common needle plate setting machine of hot blast type (175 ℃ * 45 seconds)
(3) fabric evaluation and test
(4) by the thickness of its film is at 1500nm as can be seen on the TEM, its antistatic property initial stage, the result was pretty good, but fabric feeling is harder, and durability is low.
Embodiment 17:
Converted goods:
Nylon 6 (70%) thin fabrics (56T-40-FDY * 56T-40-FDY, density 190 * 109)
Make with medicament:
| The medicament title |
| Polyethylene glycol dimethyl ester acrylate |
| The terminal isocyanates that blocks |
| Ammonium persulfate |
Processing technology:
(1) composition of used working fluid
Polyethylene glycol dimethyl ester acrylate 20g
The terminal isocyanates 5g that blocks
Ammonium persulfate 2g
Add water and make it become 1 liter, stir.
(2) process
Fabric is prepared: grey cloth preparation → dyeing
Processing: transfer liquid → pad (pick-up rate 34%) → steamer (105 ℃ * 2 minutes) → common needle plate setting machine of hot blast type (170 ℃ * 45 seconds)
(3) fabric evaluation and test
Attached stating:
The foregoing description is only as the explanation of claim item.
Processing conditions can be according to processing base cloth different (fabric also can be weft-knitted fabric, tricot and bondedfibre fabric) in the foregoing description, change dosing, revise processing technology (padding condition, drying condition, typing condition) to obtain at the good processing prescription of different converted goodss.
Thereby reach more property if can change the performance particle of 2 kinds of embodiment when requiring for other characteristics.(as functional nano level particles such as organic antistatic particle, uvioresistant, far infrareds)
Claims (10)
1, a kind of antistatic textile, it is characterized in that: fiber is an antistatic epithelium shape resin parcel fiber in this textiles, and its antistatic durability is for pressing determination method standard test result through after 0217 No. 103 standard wash of JIS L 20 times below 3000V in JIS L 1094 frictional electrifications.
2, antistatic textile according to claim 1 is characterized in that: contain the polyamide composition in this textile fiber, the quality of polyamide composition is more than 20% of gross mass.
3, antistatic textile according to claim 1 and 2 is characterized in that: the polyamide in this textiles is nylon 6 or nylon 66 or its mixture.
4, antistatic textile according to claim 1 and 2 is characterized in that: the film forming agent composition of antistatic epithelium resin bed is one or more in EU, alkyl acrylate, alkyl alkylacrylate, the siloxane quaternary ammonium.
5, antistatic textile according to claim 4 is characterized in that: the quality of the antistatic resin layer that this fiber surface adheres to is 0.35-50% with respect to fiber quality.
6, antistatic textile according to claim 5 is characterized in that: contain the antistatic particle of nanoscale in the antistatic epithelium resin bed.
7, antistatic textile according to claim 6 is characterized in that: the antistatic particle of nanoscale is the nano particle that electric conductivity is arranged.
8, antistatic textile according to claim 7 is characterized in that: the nano particle that electric conductivity is arranged is one or more of nanometer-level silver particle, nanometer-level silver complex compound, Nano-class zinc oxide, nanoscale nickel, nanoscale nickel complex, nanoscale nickel-steel alloy, nanosized copper, nanosized copper complex compound, nanoscale copper-nickel alloy or Nano titanium dioxide.
9, a kind of manufacture method of antistatic textile, it is characterized in that: the aqueous dispersion that at first will contain the antistatic behaviour resin is being paid on textiles, then with textiles in 80-120 ℃ saturated vapor heat treated 2-25 minute, washing is 0-10 minute in 50-80 ℃ water-bath, after oven dry or typing are handled in 80-190 ℃ temperature again, obtain antistatic textile, fiber is an antistatic epithelium shape resin parcel fiber in this textiles, and its antistatic durability is for pressing determination method standard test result through after No. 0217103 standard wash of JIS L 20 times below 3000V in JIS L 1094 frictional electrifications.
10, the manufacture method of antistatic textile according to claim 9 is characterized in that: add antistatic particle in the described aqueous dispersion that contains the antistatic behaviour resin.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810019569A CN101492885B (en) | 2008-01-22 | 2008-01-22 | Electrostatic resistant textile and method for producing the same |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810019569A CN101492885B (en) | 2008-01-22 | 2008-01-22 | Electrostatic resistant textile and method for producing the same |
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| CN101492885A true CN101492885A (en) | 2009-07-29 |
| CN101492885B CN101492885B (en) | 2012-09-12 |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102363914A (en) * | 2011-06-30 | 2012-02-29 | 江苏金辰针纺织有限公司 | Anti-static mesh silver velveteen |
| CN102373622A (en) * | 2010-08-26 | 2012-03-14 | 上海亿金纳米科技有限公司 | Preparation method of novel anti-static fiber |
| CN102965937A (en) * | 2011-08-30 | 2013-03-13 | 东丽纤维研究所（中国）有限公司 | Durable antistatic textile and making method thereof |
| CN103174025A (en) * | 2011-12-23 | 2013-06-26 | 东丽纤维研究所（中国）有限公司 | Antistatic nylon textile |
| CN104562643A (en) * | 2015-01-12 | 2015-04-29 | 四川大学 | Preparation method for thin layer by compounding polymeric superfine fiber surface/inorganic particles |
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| US3366507A (en) * | 1963-12-09 | 1968-01-30 | Du Pont | Textile coated with antistatic composition |
| CA995071A (en) * | 1972-07-14 | 1976-08-17 | Dow Badische Company | Electrically-conductive textile fiber |
| CN100395395C (en) * | 2005-08-04 | 2008-06-18 | 东华大学 | Nano functional textile finishing method |
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