CN101480810A - Method for preparing artificial quartz - Google Patents
Method for preparing artificial quartz Download PDFInfo
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- CN101480810A CN101480810A CNA2009100097792A CN200910009779A CN101480810A CN 101480810 A CN101480810 A CN 101480810A CN A2009100097792 A CNA2009100097792 A CN A2009100097792A CN 200910009779 A CN200910009779 A CN 200910009779A CN 101480810 A CN101480810 A CN 101480810A
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Abstract
The invention discloses a preparation method for synthetic quartz. The raw materials of the preparation method comprise quartz sand of 10 to 80 meshes, quartz sand of 80 to 200 meshes, quartz sand of 200 meshes, quartz of 325 meshes, unsaturated resin, accelerants, solidified agents and coupling agents. The preparation method comprises the following steps: unsaturated resin and color paste are stirred, the quartz sand is added into the unsaturated resin from small size to big size and is uniformly stirred with the unsaturated resin,, the accelerants, the coupling agents and the solidified agents are added in the mixture of the quartz sand and the unsaturated resin and are stirred uniformly, the mixture is injected into a forming mold and is put in the vacuum environment of 0.097MPa to -0.1MPa for about eight minutes, and then the product is naturally solidified under normal temperature and normal pressure, and is dimensioned, thickened and polished to obtain the finished product.
Description
Technical field
The present invention relates to a kind of preparation method's of artificial stone, particularly a kind of artificial quartz in lump preparation method, its raw material are by natural siliceous sand, unsaturated-resin, promoter, and coupling agent and curing agent and an amount of mill base constitute.
Background technology
Artificial stone is with blocks of natural stone or stone flour and mixed with resin, solidifies a kind of new material that the back forms.
Chinese invention patent application 200810214635.6 discloses a kind of artificial quartz in lump preparation technology, the material of this technology contains quartz 0～90%, silica flour 5～90%, fiber 1～25%, resin 0.1～20%, coupling agent 0.1～5%, curing agent 0.1～5%, cullet 0～70%, broken eyeglass 0～70%, pigment 0～5%, shell 0～5% and sheet metal 0～5%, above-mentioned raw material after fully mixing, is cured the needed artificial stone of formation at 10～200 vacuum conditions of spending.Its used quartz particle diameter of lay special stress on is 0.1～20 millimeter in this patent application, and used silica flour is 300～2000 orders, and its best solidification temperature is 15～30 degree, or 60～90 degree, or 120～150 degree.Owing to adopted bigger quartz particle of granularity and superfine little silica flour in the raw material, the resin use amount is increased in this technology, this will reduce the intensity of finished-product material; Owing to need to use superfine silica flour, the finished product manufacturing cost is improved on the other hand; And the quartz that two class granularities differ greatly in the raw material and silica flour can produce poly-ly partially in manufacture process, and the intensity of finished-product material is produced more negative influence; Because it needs to add hot pressing in making, energy consumption is higher in its preparation process, and the yield rate of press-formed product is not high simultaneously, has limited the large-scale production of artificial quartz in lump.
Chinese invention patent application 200710029148.8 discloses a kind of artificial quartz in lump and manufacturing process thereof with marbling and color.The material component of this technology and proportioning are 24～120 order quartz, 52%～78%, 120～2000 order quartz 17%～38%.Unsaturated-resin and attached material 6～14%, pigment 0.01%～10% of all kinds.Technology of the present invention seems advantages of simple, but the disclosed quartzy consumption of its patent application obviously is not enough according to its used amount of resin of general knowledge of this area; This technology still needs to use the superfine silica flour of larger amt on the other hand, and its cost can be than higher equally; Identical with the technology of aforementioned 200810214635.6 patent applications, this technology needs heating too in curing, and energy consumption can be than higher during it was made.
When material cured, also need special-purpose press device compacting in addition in the prior art, complicated process of preparation, production cost is higher.
Summary of the invention
The invention provides and a kind ofly can overcome the prior art deficiency, manufacturing cost is relatively low, does not need to be heating and curing, and does not need compression moulding, has the artificial quartz in lump material preparation method than high finished product rate simultaneously.
Preparation method of the present invention is:
A material composition proportioning is: 10～80 purpose natural siliceous sands account for 41～60% of gross weight, 80 orders～200 purpose natural siliceous sands account for 20～28% of gross weight, 200 purpose natural siliceous sands account for 5～7% of gross weight, 325 purpose natural siliceous sands account for 11～13% of gross weight, unsaturated-resin is 14～16% of a gross weight, promoter and curing agent are respectively 1% of unsaturated-resin weight, and coupling agent is 0.4% of a unsaturated-resin;
B stirs unsaturated-resin and mill base, the order ascending by granule size adds quartz sand in the unsaturated-resin, and stir, add promoter, coupling agent and curing agent more therein successively, stir rapidly simultaneously, again in the mould with the said mixture injection molding, and place 0.097MPa～-kept about 8 minutes under the vacuum environment of 0.1Mpa, allow product spontaneous curing at normal temperatures and pressures then, after treating that product solidifies fully, scale, fixed thick, polishing.
Preferred manufacturing procedure of the present invention is that granularity is the 6-30% that 10～20 purposes account for gross weight in the used natural siliceous sand, granularity is the 25-30% that 20～40 purposes account for gross weight, granularity is the 10-12% that 40～80 purposes account for gross weight, granularity is the 10-12% that 80～200 purposes account for gross weight, granularity be 200 orders account for gross weight 6%, granularity be 325 orders account for gross weight 12%.
Can be earlier among the preparation method of the present invention the mixture of quartz sand and unsaturated-resin be placed and keep after the vacuum taking out mould after 8 minutes, the 10-20 order quartz sand particle that takes a morsel in addition more evenly is sprinkling upon the surface, be cured to voluntarily when touching no longer sticking hand at it with hand, remove mould again, treat to carry out subsequent processes after it solidifies fully, as scale, fixed thick processing.
The preparation method of artificial quartz in lump of the present invention also can be in raw material adds again and accounts for gross weight 1%-10%, particle diameter 5-100 purpose luminescent powder.
Density owing to resin in the artificial stone preparation process is less, when vacuumizing, can be extracted into the surface to resin, make the skewness of the resin in the goods sheet material, cause surface resin content higher, the upper and lower degree of shrinkage difference of sheet material when causing solidifying, make sheet deformation easily, this also is to cause one of low reason of prior art yield rate.And the mixture at quartz sand and unsaturated-resin places vacuum tank to keep taking out mould behind the appropriate time among the present invention, get a certain amount of 10-20 order quartz sand particle more in addition and evenly be sprinkling upon the surface, reduce with regard to the resin content that makes the surface like this, concerning whole sheet material, reduced the inhomogeneous of resin distribution, so can reduce to shrink the inhomogeneous distortion that causes when sheet material solidifies, thereby improve the yield rate of goods.
The present invention also has following advantage:
1, the present invention has simplified preparation technology, does not need compression moulding fully, does not also need the operation that is heating and curing of prior art, and therefore energy consumption is significantly less than prior art in the manufacture process of the present invention;
2, do not adopt the superfine silica flour of granularity in the raw material of the present invention, therefore its manufacturing cost can be relatively low, and the cooperation of silica flour granularity of the present invention is suitable, both can overcome in the prior art because of the varigrained quartzy poly-partially bad deficiency of quality of finished change that makes that produces, and can use less resin, further reduce production costs.Also added 200 orders and 325 order natural siliceous sands among the present invention, correlation test shows that the strand that 200 orders and 325 purpose quartz sands and unsaturated-resin form mates the most, can farthest improve the mechanical performance of finished product;
3, because the technology of the present invention does not need the vacuum pressing moulding, the main equipment that this does not need compression moulding on the one hand can reduce equipment cost; On the other hand, overcome the not high problem of yield rate of press-formed product, for artificial quartz in lump production in enormous quantities provides advantageous conditions;
4, add luminescent powder in the raw material of the present invention and also can be made into artificial quartz in lump, make it that better decorative effect and indicative be arranged with noctilucence effect.
The specific embodiment
The present invention is further illustrated below in conjunction with the specific embodiment:
Embodiment 1: the production technology of white artificial quartz in lump plate.With raw material gross weight 1kg is example.The raw material proportioning is as shown in table 1
Raw material proportioning table among table 1 embodiment 1
Take by weighing stock white 3 grams, it is added in the 140 gram resins, stir, add 120 grams, 325 purpose quartz sands again, fully stir, the quartz that adds other order numbers then according to the descending order of order number respectively, behind each adding quartz, all need fully to stir, add promoter at last, coupling agent and curing agent obtain the making sheet raw material after stirring rapidly.Be poured in the making sheet mould, mould is sent into vacuum tank to vacuumize, in vacuum be-keep about 8 minutes backs to take out moulds under the condition of 0.1MPa, other evenly is sprinkling upon die surface at the 10-20 purpose quartz sand that takes a morsel, and allows it solidify voluntarily again, is cured to voluntarily when touching no longer sticking hand with hand to plate surface, remove mould, maintained at normal temperatures 15 days, last, the fixed thick i.e. quartzite slate of system of polishing.
As stock white being changed to the mill base of other colors, other technologies are constant, just can make the synthetic quartz slabstone of polychrome.
Embodiment 2: the production technology of artificial luminous quartz sheet material.With raw material gross weight 1kg is example.The raw material proportioning is as shown in table 2
Raw material proportioning among table 2 embodiment 2
Take by weighing mill base 3 grams respectively, luminescent powder 10 grams add them in 140 gram resins, stir, and other operations are identical with embodiment 1.
Embodiment 3: containing the production technology of noctilucence particle synthetic quartz stone slab, is example with raw material gross weight 1kg.The raw material proportioning is as shown in table 3
Raw material proportioning among table 3 embodiment 3
At first for making the operation of noctilucence particle: with unsaturated-resin 40g, light-accumulated luminous powder 25 grams, aluminium hydrate powder 30 grams, promoter 0.4 gram, curing agent 0.4 gram fully stirs, after mixing, pour in the mould, mould is sent into vacuum tank vacuumize, in vacuum be-keep 3-5 minute outlet under the condition of 0.1MPa, place a period of time under the room temperature, it is solidified fully, carry out fragmentation, sub-sieve again, promptly make 20-40 purpose luminescent powder particle.Getting 30 gram 20-40 purpose luminescent powder particles and 240 restrains 20-40 purpose quartzs and mixes standby; Other operation is identical with embodiment 1.
Artificial quartz in lump with method preparation of the present invention checks its performance highly desirable through national experiment of building material center, sees following table for details:
National building materials test center
Survey report
| Sequence number | Interventions Requested | Test value | Reference standard |
| 1 | Stain resistance | Pollution index 44 greatest contamination values 5 maximum stain degree of depth 0.08mm | JC 908-2002 |
| 2 | Chemical proofing | The test rear surface does not have obvious damage | JC 908-2002 |
| 3 | Heat-resisting quantity | Test rear surface crack-free, crack and foaming | JC 908-2002 |
| 4 | Ball falling impact | 1kg steel ball drop 45cm impacts not have and destroys | SN/T 0308-93 |
| 5 | Bending strength | 42.4MPa | SN/T 0308-93 |
| 6 | Density | 2.27g/cm 2 | SN/T 0308-93 |
| 7 | Water absorption rate | 0.03％ | SN/T 0308-93 |
| 8 | Mohs' hardness | 6 grades | SN/T 0308-93 |
| 9 | Thermal coefficient of expansion | 2.90×10 -5℃ -1 | SN/T 0308-93 |
| 10 | Compressive strength | 147MPa | SN/T 0308-93 |
| 11 | Anti-wear performance | 2.90×10 -3g/cm 2 | SN/T 0308-93 |
Claims (4)
1, a kind of preparation method of artificial quartz in lump, its raw material are by natural siliceous sand, unsaturated-resin, promoter, and coupling agent and curing agent and an amount of mill base constitute, and it is characterized in that:
A material composition proportioning is: 10～80 purpose natural siliceous sands account for 41～60% of gross weight, 80 orders～200 purpose natural siliceous sands account for 20～28% of gross weight, 200 purpose natural siliceous sands account for 5～7% of gross weight, 325 purpose natural siliceous sands account for 11～13% of gross weight, unsaturated-resin is 14～16% of a gross weight, promoter and curing agent are respectively 1% of unsaturated-resin weight, and coupling agent is 0.4% of a unsaturated-resin;
B stirs unsaturated-resin and mill base, the order ascending by granule size adds quartz sand in the unsaturated-resin, and stir, add promoter, coupling agent and curing agent more therein successively, stir rapidly simultaneously, again in the mould with the said mixture injection molding, and place 0.097MPa～-following about 8 minutes of the vacuum environment of 0.1Mpa, allow product spontaneous curing at normal temperatures and pressures then, after treating that product solidifies fully, scale, fixed thick, polishing.
2, the preparation method of artificial quartz in lump according to claim 1, it is characterized in that granularity is the 6-30% that 10～20 purposes account for gross weight in the used natural siliceous sand, granularity is the 25-30% that 20～40 purposes account for gross weight, granularity is the 10-12% that 40～80 purposes account for gross weight, granularity is the 10-12% that 80～200 purposes account for gross weight, granularity be 200 orders account for gross weight 6%, granularity be 325 orders account for gross weight 12%.
3, the preparation method of artificial quartz in lump according to claim 1 and 2, it is characterized in that placing vacuum tank to keep about 8 minutes backs to take out mould in the mixture of quartz sand and unsaturated-resin, the 10-20 order quartz sand particle that takes a morsel in addition more evenly is sprinkling upon the surface, be allowed to condition at and be cured to voluntarily under the normal temperature and pressure when touching no longer sticking hand, remove mould with hand.
4, the preparation method of artificial quartz in lump according to claim 3 is characterized in that in raw material adding accounting for gross weight 1%-10%, particle diameter 5-100 purpose luminescent powder again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100097792A CN101480810B (en) | 2009-01-21 | 2009-01-21 | Method for preparing artificial quartz |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100097792A CN101480810B (en) | 2009-01-21 | 2009-01-21 | Method for preparing artificial quartz |
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| CN101480810A true CN101480810A (en) | 2009-07-15 |
| CN101480810B CN101480810B (en) | 2011-08-17 |
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| CN2009100097792A Expired - Fee Related CN101480810B (en) | 2009-01-21 | 2009-01-21 | Method for preparing artificial quartz |
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Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101824888A (en) * | 2010-04-21 | 2010-09-08 | 廖荣刚 | Quartz composite board |
| CN101832008A (en) * | 2010-04-21 | 2010-09-15 | 廖荣刚 | Reconstructed quartz composite board |
| CN101885592A (en) * | 2010-06-10 | 2010-11-17 | 武汉大学 | Mold material and preparation method and application thereof |
| CN102408201A (en) * | 2011-08-12 | 2012-04-11 | 新云石业（云浮）有限公司 | Raw material for health-care man-made quartz stone slabs, man-made quartz stone slab and preparation method thereof |
| CN102643052A (en) * | 2012-04-24 | 2012-08-22 | 本益实业（福建）有限公司 | Manufacture method for staining resistant artificial quartz stone |
| CN102898070A (en) * | 2011-11-03 | 2013-01-30 | 苏州拓博琳新材料科技有限公司 | Bio-based artificial quartz stone and production process thereof |
| CN103553430A (en) * | 2013-11-06 | 2014-02-05 | 江门市德山复合材料科技有限公司 | Artificial acrylic quartz stone slab and preparation method thereof |
| CN104003653A (en) * | 2014-05-20 | 2014-08-27 | 深圳市国大长兴科技有限公司 | Tempered artificial quartz stone and preparation method thereof |
| CN104402277A (en) * | 2014-09-30 | 2015-03-11 | 仁新实业发展（信阳）有限公司 | Quartz sand used for synthetic quartzite |
| CN104402216A (en) * | 2014-09-30 | 2015-03-11 | 仁新实业发展（信阳）有限公司 | Synthetic quartzite |
| CN104556826A (en) * | 2015-01-12 | 2015-04-29 | 黄明超 | Process for producing artificial stone |
| CN104628301A (en) * | 2015-01-29 | 2015-05-20 | 中盐金坛盐化有限责任公司 | Artificial stones prepared by using lime flue gas method salty mud |
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| CN105271934A (en) * | 2015-10-29 | 2016-01-27 | 景德镇风益高分子材料科技有限公司 | Novel environmental-friendly man-made quartz stone and preparation technology thereof |
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| WO2016041324A1 (en) * | 2014-09-17 | 2016-03-24 | 常州明清新材料技术有限公司 | Method for the preparation of a high-gloss, high-transparency artificial colored silica stone slab |
| CN105924034A (en) * | 2016-06-30 | 2016-09-07 | 禹州市远大塑料电器有限责任公司 | High-temperature-resistant quartzite and preparation process thereof |
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| IT1244480B (en) * | 1990-12-21 | 1994-07-15 | Enichem Sintesi | ARTIFICIAL MARBLE OR GRANITE FORMING COMPOSITION |
| KR20030091846A (en) * | 2003-08-26 | 2003-12-03 | 노성태 | Imitation stone using resin and method for manufacturing the same |
| CN101125744A (en) * | 2007-07-13 | 2008-02-20 | 李华章 | Synthetic quartz with marble pattern and color and manufacturing technique thereof |
| CN101337805B (en) * | 2008-08-25 | 2012-01-11 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
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| CN101832008A (en) * | 2010-04-21 | 2010-09-15 | 廖荣刚 | Reconstructed quartz composite board |
| CN101832008B (en) * | 2010-04-21 | 2011-07-20 | 廖荣刚 | Production method of reconstructed quartz composite board |
| CN101824888B (en) * | 2010-04-21 | 2012-04-18 | 廖荣刚 | Quartz composite board |
| CN101824888A (en) * | 2010-04-21 | 2010-09-08 | 廖荣刚 | Quartz composite board |
| CN101885592A (en) * | 2010-06-10 | 2010-11-17 | 武汉大学 | Mold material and preparation method and application thereof |
| CN102408201A (en) * | 2011-08-12 | 2012-04-11 | 新云石业（云浮）有限公司 | Raw material for health-care man-made quartz stone slabs, man-made quartz stone slab and preparation method thereof |
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| CN102898070A (en) * | 2011-11-03 | 2013-01-30 | 苏州拓博琳新材料科技有限公司 | Bio-based artificial quartz stone and production process thereof |
| CN102643052A (en) * | 2012-04-24 | 2012-08-22 | 本益实业（福建）有限公司 | Manufacture method for staining resistant artificial quartz stone |
| CN103553430A (en) * | 2013-11-06 | 2014-02-05 | 江门市德山复合材料科技有限公司 | Artificial acrylic quartz stone slab and preparation method thereof |
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| WO2016041324A1 (en) * | 2014-09-17 | 2016-03-24 | 常州明清新材料技术有限公司 | Method for the preparation of a high-gloss, high-transparency artificial colored silica stone slab |
| CN104402277A (en) * | 2014-09-30 | 2015-03-11 | 仁新实业发展（信阳）有限公司 | Quartz sand used for synthetic quartzite |
| CN104402216A (en) * | 2014-09-30 | 2015-03-11 | 仁新实业发展（信阳）有限公司 | Synthetic quartzite |
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| CN105271934A (en) * | 2015-10-29 | 2016-01-27 | 景德镇风益高分子材料科技有限公司 | Novel environmental-friendly man-made quartz stone and preparation technology thereof |
| CN105384390A (en) * | 2015-12-01 | 2016-03-09 | 广州市奥维装饰材料有限公司 | Quartz stone board and preparation method thereof |
| CN105924034A (en) * | 2016-06-30 | 2016-09-07 | 禹州市远大塑料电器有限责任公司 | High-temperature-resistant quartzite and preparation process thereof |
| CN106186804A (en) * | 2016-06-30 | 2016-12-07 | 禹州市远大塑料电器有限责任公司 | A kind of antiseptical artificial quartz stone plate and preparation technology thereof |
| CN106242360A (en) * | 2016-07-29 | 2016-12-21 | 山东康洁利人造石有限公司 | A kind of antibacterial artificial quartz and production technology thereof |
| CN106277920A (en) * | 2016-07-29 | 2017-01-04 | 山东康洁利人造石有限公司 | A kind of artificial stone decorative pattern board stone material and production method thereof |
| WO2018099204A1 (en) * | 2016-11-29 | 2018-06-07 | 安徽省安美利特环保材料科技有限公司 | Non-sintered filled vacuum stone and preparation process |
| CN107628770A (en) * | 2017-08-28 | 2018-01-26 | 北京宝莲纳新材料技术有限公司 | Efficient seamless stone level ground compound soft material, stone level ground hard plate material and its manufacture craft |
| CN108947321A (en) * | 2018-08-21 | 2018-12-07 | 甘洪清 | A kind of artificial quartz stone fire symbol board and preparation method thereof |
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| CN101480810B (en) | 2011-08-17 |
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