CN101472498A - Method for shaping hair with superabsorbent material - Google Patents
Method for shaping hair with superabsorbent material Download PDFInfo
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- CN101472498A CN101472498A CNA2007800229790A CN200780022979A CN101472498A CN 101472498 A CN101472498 A CN 101472498A CN A2007800229790 A CNA2007800229790 A CN A2007800229790A CN 200780022979 A CN200780022979 A CN 200780022979A CN 101472498 A CN101472498 A CN 101472498A
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- hair
- thin slice
- curling
- agent
- super
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D2/00—Hair-curling or hair-waving appliances ; Appliances for hair dressing treatment not otherwise provided for
- A45D2/12—Hair winders or hair curlers for use parallel to the scalp, i.e. flat-curlers
- A45D2/127—Hair winders or hair curlers for use parallel to the scalp, i.e. flat-curlers with a wrapping strip, e.g. flexible
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D7/00—Processes of waving, straightening or curling hair
- A45D7/04—Processes of waving, straightening or curling hair chemical
Abstract
A method for shaping hair comprising the steps of: (i) folding a curling sheet consisting of or comprising a superabsorbent material around the tips of the hair strand like an end-wrap, (ii) winding the hair around the folded sheet, thereby using said sheet as a curler, (iii) fixing the curlers with a clip, a pin or an other tool appropriate for fixing the hair on a curler, (iv) applying a aqueous hair shaping composition onto the hair on the curler, (v) leaving the shaping composition to act on the hair for 1 to 30 minutes, whereby said sheet is swelling and produces tension on the hair wound on it, and (vi) removing the said sheet. Also claimed is a sheet for the winding of hair during permanent hair shaping, according to anyone of claims 8 to 10, exclusively consisting of (a) a carrier material, (b) at least one superabsorbent polymer in non-swollen form and (c) at least one thickener.
Description
The present invention relates to a kind of method of shaping hair, wherein use a kind of curling-tong of lamella shape that hair is wound on the curling-tong, this curling-tong also can be used as terminal wrappage, and the thin slice that wherein is provided has the super-absorbent polymer of at least a unexpansive form at least in part.
In order on people's hair, to produce lasting Hairsetting, except using reducing agent and oxidant, also need coiling body.Hair is by extremely rolling near the longitudinal axis of scalp root from hair is terminal along it.The conventional curling-tong that uses has following shortcoming in hair salon: they demonstrate the rigidity profile, and for this reason, and when hair was subjected to the reducing agent effect and relaxes, the tension force on the hair reduced or complete obiteration.On the other hand, well-known is that the persistence of curling and elasticity can be by in the process of reshaping remaining on hair the tension force improvement of getting off.United States Patent (USP) 5,020 has been described a kind of curling-tong in 552, and the diameter of this curling-tong can enlarge or shrinks by the internal mechanical device.For all curling-tongs (about 30 to 50) are remained under the tension force, the hairdresser needs expensive time and effort, and can not use the tension force of same amount on each curling-tong.
Therefore, the purpose of this invention is to provide a kind of like this method, can bring tension force for like a cork the hair that is wound on the curling-tong by this method, and not need the help of internal mechanical device and do not have shortcoming discussed above.
Another object of the present invention provides a kind of like this method, can keep tension force on hair in whole hair-waving time-continuing process by this method.
Another object of the present invention provides a kind of automatic control method to keep hair under tension force.
Another object of the present invention provides a kind of simple, cheap and effective method to keep hair under tension force.
Another object of the present invention provides a kind of method of curling hair, can avoid after using, needing to clean curling-tong by this method, so more save time, more comfortable and much cleaner.
Another object of the present invention is to avoid in the most advanced and sophisticated effect of excessively curling that produces of hair; like this in the time of contact of hair-waving preparation; compare with conventional method, the length of hair and end are protected with a kind of special method, have therefore avoided known shortcoming.Hair structure sustains damage less, although and reel tighter, the length of hair and terminally will be endowed corresponding undaform radius at root near scalp.
The inventor finds surprisingly, and the tension force that is wound on the hair on the curling-tong can increase in hair hair-waving process automatically, and when using as described in the present invention method, all other shortcomings discussed above all can be avoided.
Method of the present invention is disclosed in the claim 1.Embodiment preferred illustrates in the dependent claims.
Arbitrary non-persistent or permanent shaping composition all can be used for implementing method of the present invention.
If use non-persistent Hairstyling composition, except the step of this method (iv), said composition also can be preceding the using of step (i), wherein great majority, preferably (iv) be applied on the hair in step more than 2/3 non-persistent Hairstyling composition.Non-persistent Hairstyling composition preferably comprises by weight 0.1 to 10%, more preferably 0.2% to 5.0% hair shaping copolymer by weight, for example: homopolymers, CTFA that the allyl ether of PVP/VA copolymer, natural corn albumen, acrylic acid and pentaerythrite is crosslinked: octyl acrylamide/acrylate/butylamine ethyl-methyl acrylate copolymer (
OfNational Starch), vinyl pyrrolidone/styrol copolymer, CTFA: quaternary ammonium-79 hydrolyzed wheat protein, and vinyl pyrrolidone/vinyl acetate copolymer.Solvent is selected from water, ethanol, propyl alcohol, isopropyl alcohol and their mixture, and the amount of solvent counts 50% to 98% by the weight of composition in non-persistent Hairstyling composition, preferably counts 70% to 95% by the weight of composition.
The present invention also provides a kind of " curl thin slice (curling sheet) " as claimed in claim 8 to be used at the lasting Hairsetting process hair of reeling.
Described " curl thin slice ", except its actual functional capability promptly as a kind of curling-tong, also can be used as terminal wrappage and as the carrier of super-absorbent polymer, and guarantee to reach target effect, especially at the hair end.Described super-absorbent polymer exists with unexpansive form, so it comes down to anhydrous and is not with gel form.
Thin slice or be made up of the super-absorbent polymer of unexpansive form curls, perhaps by other known composition itself as the foil of support applications, paper, fabric, felt, non-woven material or plastics are preferred thus, and other foil that is provided contains a kind of super-absorbent polymer of unexpansive form at least in part.
The terminal foil itself that is used for lasting hair-waving is known, can use the terminal paper of being made by the wet strength paper usually, for example: long fibre paper, tissue paper or Japanese paper.Also can use the substitution material substitute paper, for example: the fabric mixture of non-woven material or supatex fabric, cotton fabric, synthetic fibers and natural fiber and other absorbing material, or other polymer film.Other natural or synthetic materials that are fit to are polyester, acetic acid esters, cotton, nylon, Orlon, silk, polypropylene, viscose rayon, wool, polyamide and polyethylene.Thin slice is not made up of super-absorbent polymer if curl, and the sheeting that provides so has the super-absorbent polymer of at least a unexpansive form at least in part.
Described super-absorbent polymer is known, and their purposes is as liquid-absorbant, for example in diaper.They are the polymer or the hydrophilic copolymers of acrylic acid, methacrylic acid, or starch and acrylic acid graft copolymer, and wherein polymer can be that salt exists with form neutral or that part is neutral.They are by forming with the partial cross-linked polymerisation of the crosslinking agent that is fit to, and crosslinking agent is the unsaturated hydrophilic monomer of alkylene, is acrylic acid, methacrylic acid or their alkali metal salt specifically.This base polymer and their preparation are described widely, and for example: EP-A 0 312 952, DE-A 4 418 818 and EP-A 0 441 507 all can be used as reference.US-A 5121762 has described a kind of water-soluble or water-soluble bloated terminal foil, this terminal foil by super-absorbent polymer make (
SAF), thioglycol acid ammonium resin solution be dispersed in it above.
Described super-absorbent polymer is characterised in that their big water absorbing capacity and their big water retention capacity.They are with powder or the commercially available acquisition of particle form.The super-absorbent polymer that is fit to for example
D (ElfAtochem S.A.),
IM 7015 (BASF AG),
3746-5 (BASF AG),
E 1290-00 (BASF AG) or
E 1291-00 (BASF AG).The particle mean size of dry polymer is preferably 5 to 850 μ m.Yet especially preferred is 200 μ m or following relatively little granularity.According to " Centrifuge Retention CapacityDetermination for Superabsorbent Samples " Edna Doc.87/RS7/037; The absorptive capacity of the demineralised water that the method for AbsorbencyII441.1-99 is measured is preferably 20g/g at least.
Here the curling thin slice that preparation has a super-absorbent polymer is typical example such as paper, fabric, non-woven material or the foil as all suitable materials, with the case description of the thin slice that curls.
The curling thin slice that is provided can combine with super-absorbent polymer in a different manner.A kind of mode is the surface that well distributed polymer beads is coated to equably the thin slice that curls.Except surface coatings, also polymer can be incorporated in the paper matrix and go to (inside of matrix=integral body, material).A kind of alternative preparation change is super-absorbent polymer is attached to and goes in the paper matrix of paper and do not have a covering surfaces.
The thin slice that curls as described in the present invention can be produced by the following method: for example the powdery super-absorbent polymer is coated on the surface of thin slice with a kind of known method (for example: sprayer coating, roller coating method " intaglio printing coating ") of flour that is applicable to itself.
For example, production can at first come into effect from washing and dry support (thin slice) surface.Then the powdery super-absorbent polymer is suspended in the nonaqueous liquid, is suspended in the alcohol specifically.Then one or more sides of carrier are immersed in the suspension that has stirred.Fully wetting carrier sheet is removed from suspension then.At last, the dry thin slice (carrier+super-absorbent polymer) that curls.
Another produce to select to be to absorb and non-super-absorbent polymer (for example crosslinked or crosslinkable homopolymers or copolymer) is coated on the carrier material (paper, non-woven material, foil, fabric etc.) super, and only subsequently at carrier surface and contain the crosslinked polymer of suitable crosslinking agent (for example glyoxal etc.).
Produce and also can carry out like this, for example at first wash the surface of the carrier sheet of making by fabric with water, equably 10g to 20g powdery super-absorbent polymer is coated on the surface of wetting carrier sheet then.At last, the dry thin slice (carrier+super-absorbent polymer) that curls at 40 ℃ to 100 ℃, spends the night under preferred 60 ℃ to the 80 ℃ temperature in the cabinet of drying on glass plate, and if suitably, curling thin slice can smooth rolling.
Another produces the combination that change is similar sandwich, and wherein super-absorbent polymer is embedded between two foil layers, is (this last-minute change is meant that specifically unusable paper is as carrier material) between two ply of papers specifically.
In a particular of the present invention, super-absorbent polymer is adhered on the surface of the thin slice that curls or the inside of its paper matrix, this can carry out under thickener or gel generate the help of agent.Being fit to thickener at this purpose is carboxy vinyl polymer for example, and other acrylate copolymers of for example various level of polyacrylate specifically also have polyethylene glycol, cellulose derivative, hydroxy alkyl cellulose and alginate esters and carrageenan specifically.The preferred nonionic cellulose ether that uses, as methylcellulose, ethyl cellulose, for example Culminal (nonionic cellulose ether, Aqualon), Viscotran (methylcellulose, Aqualon) or Aquacoat ECD (ethyl cellulose, FMC Corporation).
These thickeners or gel generate agent and process easily with the form of aqueous gel.Preferably, these working concentrations in order to the material of generation gel are 0.1% to 10% by weight.The amount that is applied to the expanding water holding gel on terminal foil or the terminal paper is preferably every square centimeter of terminal foil or terminal paper areas is 0.1mg to 20mg.Preferably, then the powdery super-absorbent polymer is coated on the surface of terminal foil or terminal paper or and is attached in the paper matrix it, the amount of the super-absorbent polymer of coating is that every square centimeter of terminal paper tinsel or terminal paper areas are 0.05mg to 500mg, preferred every square centimeter of terminal foil or terminal paper areas are 0.1mg to 50mg, and especially preferred every square centimeter of terminal foil or terminal paper areas are 0.3mg to 10mg.
Cause that with the gel preliminary treatment particle of super-absorbent polymer adheres on the surface of the thin slice that curls and/or in the paper matrix, and cause the durable bonding of the mechanical stress that stands to use.
The curling thin slice that combines with super-absorbent polymer certainly comprises all additives known and Hiar treatment compositions routine as described herein.They for example are: be selected from the wetting agent or the emulsifying agent of the surfactant of nonionic, anion, cation or both sexes class surface active, as aliphatic alcohol sulfate ethoxylation or non-ethoxylatedization, alkylbenzenesulfonate, alkylation leptodactyline, alkyl betaine; Wetting agent, for example 1,2-pentanediol, perfumery oil; Opacifier is as for example glycol distearate; Pearling agent is as for example mixture of aliphatic acid monoalkyl alkylolamides and glycol distearate; Sterilization and Fungicidal active ingredient, for example 2,4,4-three chloro-2-dihydroxy diphenyl ether or methylchloroisothiazandnone; Buffer material, for example natrium citricum or sodium phosphate; Citric acid for example; Dyestuff; Care substance, for example plant and medicinal herbs extract, protein and silk hydrolysate, lanolin derivative; Compatible silicone derivative on the physiology, for example volatilization or nonvolatile silicone oil or HMW siloxane polymer; The deodorant activities composition for example preferably has the polyhydroxy-alcohol of 5 to 8 carbon atoms, and for example 1,2-pentanediol, 1,3-pentanediol, 1,5-pentanediol, 1,2-hexylene glycol, 1,3-hexylene glycol, 2,5-hexylene glycol, 1,5-hexylene glycol, 1,6-hexylene glycol, 1,2-heptandiol, 1,3-heptandiol, 1,2-ethohexadiol and 1,3-ethohexadiol, with the citric trialkyl ester, for example triethyl citrate, ATBC, trioctyl lemon acid, citric acid three-C
12-13-Arrcostab and citric acid three-C
14-15-Arrcostab, and perfumery oil; Bright protective agent, oxidant, antioxidant, free radical scavenger, anti-dandruff active component; Fatty alcohol, luminous agent, vitamin, betaine, softening agent, cardability improver, fatting agent and defoamer.
Above-mentioned additive uses usually to be used for this type of purpose amount.The percentage by weight that below provides relates to the amount of super-absorbent polymer.For example: the material of surface active, but material and the nursing property material of conditioning component as improving cardability, the amount of using under situation separately is 0.1% to 20% by weight, the total concentration of ultra-violet absorber is 0.1% to 5% by weight, perfumery oil, anti-grease active component, plant extracts, vitamin and vitamin derivative, the pH stabilizing agent, the total amount of anti-dandruff active component and sterilization or fungicidal substance is 0.1% to 10% by weight, with anticorrisive agent and dyestuff, described anticorrisive agent and the dyestuff amount under situation separately is 0.01% to 5% by weight.
The application of the following description of the present invention is the example explanation as the representative of various carrier materials with the thin slice that curls.Therefore, to terminal paper (Jumbo End Wraps, Sally Beauty Company, the area 60cm of routine
2) test with the difference between the present invention who describes in the comparison example 1.
The permanent shaping agent that can be used for this paper describing method be those based on typical hair-keratin-reducing material, for example sulfate or some sulfhydryl compound, especially mercaptan carboxylic acid's salt or ester.The permanent shaping composition comprises the keratin-reducing compound, the amount of this compounds be generally used for the recombinating ammonium salt of TGA for example or thiolactic acid or cysteine, and this type of compound concentrations is 6% to 12% by weight.The pH value of described alkaline permanent shaping composition is generally 7 to 10, and wherein said pH preferably uses ammonia, MEA, ammonium carbonate or carbonic hydroammonium to regulate.
If described permanent shaping composition is adjusted to acidity (for example to pH=6.5 to 6.9), use mercapto-carboxylic ester then, for example single sulfo-two alkyd binary alcohol esters or-glyceride, preferred mercaptoacetylamide or 2 mercaptopropionic acid acid amides, its concentration is 2% to 14% by weight; Or sulfate, for example sodium, ammonium or MEA sulphite, its concentration is 3% to 8% (with SO by weight
2Calculate).
Preferably, the hair-keratin-reducing compound that is used is mercaptan carboxylic acid's salt or derivative.Especially preferably, described keratin-reducing compound selected from mercapto acetate, cysteine and thiolactic acid or their salt.
In order to increase effect, can will expand and bleeding agent, for example the alcohol of urea, multivalence, ether, melamine, alkali or ammonium thiocyanate, isopropyl alcohol, imidazoline-2-ketone, 2-Pyrrolidone and 1-Methyl-2-Pyrrolidone add in the permanent shaping composition, its concentration is about 0.5% to 50% by weight, or preferably by weight 2% to 30%.
If described permanent shaping composition also comprises the disulphide of hair-keratin-reducing compound (mercaptan), especially two thiodiethanol hydrochlorates are favourable.The preferred amounts of using is 2% to 20% weight, or preferred 3% to 10% weight, and the ratio between wherein said hair-keratin-reducing compound and the described disulphide is 2:1 to 1:2 preferably, or 2:1 to 1:1 especially.
The amount of water counts 50% to 98% by composition weight in the permanent shaping composition, preferably counts 70% to 95% by composition weight.
After having crossed the action time that enough is used for lasting reorganization, be 1 to 30 minute action time, or preferred 2 to 20 minutes, this depends on the reorganization effect of hair quality, pH value and permanent shaping composition, and application temperature; If desired, water flushing hair, and fix with oxidant then.
The use amount of Hairstyling composition is about 50g to 200g (1.76 to 7.05oz), and this depends on hair thickness.Any used oxidant in the past can be used for fixing in the fixative.The example of this type of oxidant is potassium bromate, sodium bromate, sodium perborate, hydroascorbic acid, hydrogen peroxide and urea peroxide.The concentration of oxidant changes with coating time (common 1 to 40 minute, or preferred 5 to 20 minutes) and application temperature (25 ℃ to 50 ℃ (77 ℉ to 122 ℉)).Normally, the oxidant working concentration is about 0.5% to 12.0% by weight in the moisture fixative.Obviously, fixative can comprise other material, for example weak acid or peroxide stabiliser.
The Hairstyling composition and the fixative of method use can be aqueous solution or emulsion form as described herein, and the thickening form on the moisture basis, and especially the form with white cream, gel or paste exists.
Especially preferably fix with the low-viscosity (mobile) liquid form.Preferably, fixative is to comprise oxidant, and the preparation liquid that has 1mPa.s to 100mPa.s viscosity under 25 degrees centigrade (77 ℉) wherein especially preferably has 1mPa.s to 10mPa.s viscosity under 25 degrees centigrade (77 ℉).Viscosity number is to be that the basis is measured with HaakeVT501 type rotation viscometer with the shear rate of 64.5 per seconds.
Also this reagent can be inserted in the aerosol can under pressure, and be discharged as aerosol foam.
About the compound of quoting in an embodiment, with reference to " International Cosmetic IngredientDictionary and Handbook ", 2004 the 10th edition, by The Cosmetic, Toiletry and Fragrance Association publish, and 1,101 17
ThStreet, NW, Suite 300, Washington, D.C.20036-4702.
Embodiment
Embodiment 1
A kind of wool Sawaloom 06615SO16 eedle-punched non-wovens of non-woven material, it comprises 50% superabsorbent fibre PP/30%CV/20%SAP180g/m
2, and have 3mm thickness, with the thin slice of its cutting growth 120mm and wide 70mm.Longitudinally axis is folding in the mode as a kind of terminal wrappage around the hair tip with this curling thin slice.
With hand or under the help of clip without curling-tong, the thin slice that just will curl is rolled hair as curling-tong.To perm with clip Wella Creative for example
Fixing.The lasting hair-waving composition that will have a kind of routine of following formula is evenly distributed on the curling hair.Will be as the curling thin slice of curling-tong by absorbing liquid, aqueous swelling and the superincumbent hair of reeling being produced tension force.
Lasting hair-waving composition
12.00g thioglycol acid ammonium, 70% aqueous solution
5.00g two thiodiethanol hydrochlorates
1.00g ammoniacal liquor, 25% aqueous solution
4.00g carbonic hydroammonium
1.00g castor oil ethylizes with 35 moles oxirane oxygen
1.00g PDDA homopolymers
(CTFA: polyquaternium-6)
0.50g perfumery oil
Add to 100.00g water
The composition of will perming lastingly is retained in hair last 15 minute, and maintains the temperature at 40 ℃ with the bell-type infrared radiator.Then with the water flushing of hair with tepor.Then the hair that curls is handled with the following fixative of 80g:
The liquid fixative
4.00g hydrogen peroxide, 50% aqueous solution
0.10g salicylic acid
0.20g sodium hydrogen phosphate
0.15g orthophosphoric acid
1.00g castor oil ethylizes with 35 moles oxirane oxygen
0.10g vinyl pyrrolidone/styrol copolymer
0.10g perfumery oil
Surplus is to 100g water
Be 10 minutes action period then.After having crossed action period, the thin slice that will curl is removed and is thoroughly cleaned with warm water, and handles with known acid wash liquid.Create hair style with blowing dryer and brush according to normal mode then.The hair that curls presents from the tip evenly curling and need not consider excessively curling at the tip to root.Curling seems very natural, and is keeping their elasticity in the time more than 3 weeks.
Embodiment 2
The natural hair that left side of head 25cm is long is wound on (Wella Creative Shaper No.23) on the curling-tong that diameter is 30mm with the terminal wrappage of commercial paper.The right side hair is wound on the curling thin slice of example 1.Then, with the hair of head both sides according to disclosed processing in the example 1.
The hair (right side) of using the thin slice that curls to handle as described herein shows the processed conventionally hair of comparing the left side and curls from the tip to root is more uniform.Do not find excessively to curl at the tip.In addition, the hair on the right side shows more natural and the clean and tidy outward appearance of combing more.
Embodiment 3
A kind of wool Sawaloom 06615SO16 eedle-punched non-wovens of non-woven material, it comprises 50% superabsorbent fibre PP/30%CV/20% SAP 180g/m
2, and have 3mm thickness, with the thin slice of its cutting growth 120mm and wide 70mm.Longitudinally axis is folding in the mode as a kind of terminal wrappage around the hair tip with this curling thin slice.
The natural hair that 20cm is long is rolled it as curling-tong with curling thin slice under the help of clip.Curl with hairpin is fixing.A kind of non-aerosol Hairspray compositions that will have following formula is sprayed on the curling hair equably.
The non-aerosol hair jelly
6.00g CTFA: octyl acrylamide/acrylate/butylamine ethyl-methacrylate
Copolymer (
Of National Starch)
1.10g 2-aminoisobutanol
0.20g triethyl citrate
0.20g the polyethyleneglycol derivative of dimethyl silicone polymer comprises 12 moles of averages
Oxirane
(CTFA:PEG-12 dimethyl silicone polymer)
0.10g vinyl pyrrolidone/vinyl acetate copolymer
0.10g perfumery oil
90.00g ethanol
Surplus is to 100g water
Will-pure liquid swelling moisture by absorbing and the superincumbent hair of reeling produced tension force as the curling thin slice of curling-tong.Hairspray compositions is retained in hair last 15 minute, uses the infrared radiator of bell-type during this period 40 ℃ Temperature Treatment.After this curling-tong is removed and hair is combed into hair style.Hair shows excellent elasticity and lasting wave.
Embodiment 4
The natural golden hair that 18cm is long is handled according to mode identical in the example 3.The lotion of using following conditioning and typing replaces the non-aerosol hair jelly:
The lotion of conditioning and typing
8.00g PVP/N, N-dimethylaminoethyl methacrylic acid copolymer dithyl sulfate
(CTFA: polyquaternium-11)
2.50g CTFA: quaternary ammonium-79 hydrolyzed wheat protein matter
0.50g cetanol
0.10g perfumery oil
Surplus is to 100g water
Will be as the curling thin slice of curling-tong by absorbing liquid, aqueous swelling and the superincumbent hair of reeling being produced tension force.Hairspray compositions is retained in hair last 12 minute, in this process with the infrared radiator of bell-type in 42 ℃ of processing of temperature.After this curling-tong is removed, and hair is combed into hair style.Hair shows excellent elasticity and lasting wave.
Embodiment 4
The hair of the bleaching that 22cm is long is handled according to method identical in the example 3.Use following spraying hair gel to replace the non-aerosol hair jelly:
Spraying hair gel
0.30g acrylic acid homopolymers is through the crosslinked (CTFA: card ripple of the allyl ether of pentaerythrite
Nurse)
8.00g thiazolinyl pyrrolidones/vinyl acetate copolymer
2.00g glycerine
0.12g triethanolamine
0.10g have 45 moles of averages oxirane palm-kernel oil monoglyceride and
The polyethyleneglycol derivative of diester (CTFA:PEG-45 palm kernel glyceride)
0.20g methyl p-hydroxybenzoate
0.10g perfumery oil
Surplus is to 100g water
Will be as the curling thin slice of curling-tong by absorbing liquid, aqueous swelling and the superincumbent hair of reeling being produced tension force.Hairspray compositions is retained in hair last 20 minute, and the infrared radiator of bell-type uses with 39 ℃ temperature in the reason process herein.After this curling-tong is removed, and hair is combed into hair style and drying.Hair shows excellent elasticity and lasting wave.
Claims (22)
1. the method for a shaping hair said method comprising the steps of:
(i) as terminal wrappage around the tip of topknot the folding curling thin slice that comprises superabsorbent material or form by superabsorbent material;
(ii) hair is centered on described folding winding of webs, thereby described thin slice is used as curling-tong;
(iii) be fit to hair is fixed on the fixing curling-tong of instrument on the curling-tong with clip, hairpin or other;
(iv) moisture Hairsetting compositions is coated on the hair on the described curling-tong;
(v) keep described Hairstyling composition so that it acted on hair 1 to 30 minute, wherein said thin slice will swelling and to hair wound thereon produce tension force and
(vi) remove described thin slice.
2. the method for a permanent shaping hair, described way may further comprise the steps:
(a) as terminal wrappage around the tip of topknot the folding curling thin slice that comprises superabsorbent material or form by superabsorbent material;
(b) hair is centered on described folding winding of webs, thereby described thin slice is used as curling-tong;
(c) be fit to hair is fixed on the fixing curling-tong of instrument on the curling-tong with clip, hairpin or other;
(d) lasting Hairsetting compositions is coated on the hair on the described curling-tong;
(e) keep described hair-waving composition so that it acted on hair 3 to 20 minutes, wherein said thin slice will swelling and hair wound thereon is produced tension force;
(f) if desired, water flushing hair,
(g) Hairstyling composition is coated on the described curling-tong and
(h) final rinse water hair and remove described thin slice.
3. method as claimed in claim 1 or 2, wherein said curling thin slice has the thickness of 0.5mm to 10mm.
4. as each described method in the claim 1 to 3, wherein said curling thin slice has the thickness of 0.5mm to 10mm, the width of 20mm to 100mm and the length of 60mm to 200mm.
5. as each described method in the claim 1 to 4, wherein said curling thin slice has the thickness of 1mm to 8mm, the width of 50mm to 100mm and the length of 80mm to 150mm.
6. as each described method in the claim 1 to 5, wherein said curling thin slice has the thickness of 2mm to 6mm, the width of 60mm to 80mm and the length of 100mm to 140mm.
7. as each described method in the claim 1 to 6, wherein said curling thin slice mainly is made up of non-woven material.
8. the curling thin slice of the hair that in lasting Hairsetting process, is used to reel, described curling thin slice comprises superabsorbent material or is made up of superabsorbent material, and wherein said curling thin slice has the thickness of 0.5mm to 10mm, the width of 20mm to 100mm and the length of 60mm to 200mm.
9. thin slice as claimed in claim 8, wherein said thin slice have the thickness of 1mm to 8mm, the width of 50mm to 100mm and the length of 80mm to 150mm.
10. as claim 9 or 10 described thin slices, wherein said curling thin slice has the thickness of 2mm to 6mm, the width of 60mm to 80mm and the length of 100mm to 140mm.
11. as the thin slice of each described hair that is used to reel in lasting Hairsetting process in the claim 8 to 10, described thin slice only is made up of following:
(a) carrier material;
(b) super-absorbent polymer of at least a non-swelling form and
(c) at least a thickener.
12. thin slice as claimed in claim 11, wherein said carrier material is selected from down group: paper, fabric, felt, non-woven material or plastics.
13. as each described thin slice in the claim 11, wherein said super-absorbent polymer is selected from down group: super copolymer and the salt their neutralizations or the part neutralization that absorbs cross linked polyacrylate, polymethylacrylic acid, starch and acrylic acid graft copolymer, acrylic acid and methacrylic acid.
14., it is characterized in that the particle mean size of described dried super-absorbent polymer is 5 μ m to 850 μ m as each described thin slice in the claim 11 to 13.
15., it is characterized in that described dried super-absorbent polymer is 20g/g at least to the absorbability (centrifugal reserve capacity) of the water that removes mineral matter as each described thin slice in the claim 11 to 14.
16. as each described thin slice in the claim 1 to 15, wherein said superabsorbent material is embedded between two ply of papers.
17. as each described thin slice in the claim 11 to 16, wherein said super-absorbent polymer generates on the surface that agent adheres to terminal foil or in the matrix by thickener or gel.
18. thin slice as claimed in claim 17, wherein said thickener or gel generate agent and are selected from the group of being made up of following: carboxy vinyl polymer, polyethylene glycol, cellulose derivative, alginate esters and carrageenan.
19., wherein water-soluble bloated thickener or gel are generated agent and are coated on the terminal foil with the amount of every square centimeter of terminal foil area 0 .1mg to 20mg as each described thin slice in claim 11 or 17.
20. as each described thin slice in the claim 11 to 19, wherein said super-absorbent polymer is present in the amount of every square centimeter of slice region 0.05mg to 500mg on the surface of described thin slice or in the paper matrix.
21. as each described thin slice in the claim 11 to 20, wherein said super-absorbent polymer is present in the amount of every square centimeter of terminal foil area 0 .1mg to 50mg on the surface of described terminal foil or in the paper matrix.
22. the thin slice of the hair that is used to reel in lasting Hairsetting process, described thin slice only is made up of following:
(i) carrier material;
The super-absorbent polymer of (ii) at least a non-swelling form and
(iii) randomly at least a known and custom are used for the additive of hair treating agent, and this additive is selected from: thickener, and gel generates agent; be selected from nonionic; anion; the wetting agent or the emulsifying agent of the kinds of surfactants of cation or amphoteric surface's activation, wetting agent, perfumery oil; opacifier, pearling agent, sterilization and Fungicidal active ingredient; buffer substance, acid, dyestuff; care substance, compatible silicone derivative on the physiology, deodorant activities composition; polyalcohol with 5 to 8 carbon atoms; the citric trialkyl ester, bright protective agent, oxidant; antioxidant; free radical scavenger, anti-dandruff active component, fatty alcohol; luminous agent; vitamin, betaine, softening agent; cardability improver, fatting agent and defoamer.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06012480.7 | 2006-06-19 | ||
| EP06012480A EP1869992B1 (en) | 2006-06-19 | 2006-06-19 | Method for shaping hair with superabsorbent material |
| PCT/IB2007/052356 WO2007148286A2 (en) | 2006-06-19 | 2007-06-19 | Method for shaping hair and curling sheet with superabsorbent material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101472498A true CN101472498A (en) | 2009-07-01 |
| CN101472498B CN101472498B (en) | 2011-12-28 |
Family
ID=37547746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007800229790A Expired - Fee Related CN101472498B (en) | 2006-06-19 | 2007-06-19 | Method for shaping hair with superabsorbent material |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20080011315A1 (en) |
| EP (1) | EP1869992B1 (en) |
| JP (1) | JP2009539543A (en) |
| CN (1) | CN101472498B (en) |
| AT (1) | ATE446693T1 (en) |
| DE (1) | DE602006010046D1 (en) |
| MX (1) | MX2008016025A (en) |
| WO (1) | WO2007148286A2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102984967A (en) * | 2010-05-11 | 2013-03-20 | 欧莱雅 | Hair treatment method |
| CN108741563A (en) * | 2018-05-07 | 2018-11-06 | 肖忠波 | A kind of 50 degree of low temperature Nursing health method for permanent waving hair |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010159254A (en) * | 2008-12-16 | 2010-07-22 | L'oreal Sa | Method of permanent re-formation by using heating mechanical tensilizing device |
| JP5735222B2 (en) * | 2010-05-26 | 2015-06-17 | 花王株式会社 | Permanent wave kit |
| US8627829B2 (en) | 2010-12-31 | 2014-01-14 | Goody Products, Inc. | Water removing hair brush |
| US20150216292A1 (en) * | 2010-12-31 | 2015-08-06 | Goody Products, Inc. | Water Removing Hair Brush |
| USD709291S1 (en) | 2011-12-30 | 2014-07-22 | Goody Products, Inc. | Hair brush |
| WO2023183324A1 (en) * | 2022-03-21 | 2023-09-28 | Isp Investments Llc | Hair spray composition comprising cellulose blends and process for preparing the same |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE621043A (en) * | 1961-08-04 | |||
| DE8535210U1 (en) * | 1985-10-21 | 1987-01-15 | Henkel Kgaa, 4000 Duesseldorf, De | |
| US5121762A (en) * | 1990-07-16 | 1992-06-16 | Inno/Genics, Inc. | Water soluble end wrap and method of use |
| IL110134A (en) * | 1993-07-09 | 1998-07-15 | Stockhausen Chem Fab Gmbh | Polymers capable of absorbing aqueous liquids and body fluids their preparation and use |
| CN100515262C (en) * | 2001-07-19 | 2009-07-22 | 花王株式会社 | Hair treating implement |
| US6905986B2 (en) * | 2001-10-09 | 2005-06-14 | Kimberly-Clark Worldwide, Inc. | Composites comprising superabsorbent materials having a bimodal particle size distribution and methods of making the same |
| DE10150765A1 (en) * | 2001-10-13 | 2003-04-17 | Wella Ag | Lace film for winding hair and process for permanent hair shaping |
| EP1714576A4 (en) * | 2004-02-09 | 2007-04-11 | Kao Corp | Hair holder |
-
2006
- 2006-06-19 DE DE602006010046T patent/DE602006010046D1/en active Active
- 2006-06-19 EP EP06012480A patent/EP1869992B1/en not_active Not-in-force
- 2006-06-19 AT AT06012480T patent/ATE446693T1/en not_active IP Right Cessation
-
2007
- 2007-06-19 US US11/820,385 patent/US20080011315A1/en not_active Abandoned
- 2007-06-19 MX MX2008016025A patent/MX2008016025A/en not_active Application Discontinuation
- 2007-06-19 JP JP2009514978A patent/JP2009539543A/en active Pending
- 2007-06-19 WO PCT/IB2007/052356 patent/WO2007148286A2/en active Application Filing
- 2007-06-19 CN CN2007800229790A patent/CN101472498B/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102984967A (en) * | 2010-05-11 | 2013-03-20 | 欧莱雅 | Hair treatment method |
| CN102984967B (en) * | 2010-05-11 | 2016-03-09 | 欧莱雅 | Hair treating method |
| CN108741563A (en) * | 2018-05-07 | 2018-11-06 | 肖忠波 | A kind of 50 degree of low temperature Nursing health method for permanent waving hair |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2009539543A (en) | 2009-11-19 |
| ATE446693T1 (en) | 2009-11-15 |
| DE602006010046D1 (en) | 2009-12-10 |
| EP1869992B1 (en) | 2009-10-28 |
| WO2007148286A2 (en) | 2007-12-27 |
| US20080011315A1 (en) | 2008-01-17 |
| EP1869992A1 (en) | 2007-12-26 |
| MX2008016025A (en) | 2009-01-16 |
| CN101472498B (en) | 2011-12-28 |
| WO2007148286A3 (en) | 2008-02-28 |
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